CN102757143A - Well drilling wastewater flocculation precipitation treatment device and wastewater treating method - Google Patents

Well drilling wastewater flocculation precipitation treatment device and wastewater treating method Download PDF

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Publication number
CN102757143A
CN102757143A CN2012102886338A CN201210288633A CN102757143A CN 102757143 A CN102757143 A CN 102757143A CN 2012102886338 A CN2012102886338 A CN 2012102886338A CN 201210288633 A CN201210288633 A CN 201210288633A CN 102757143 A CN102757143 A CN 102757143A
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water
flocculation
pond
well
communicated
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CN2012102886338A
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CN102757143B (en
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田庆华
杨斌中
王维
孙蜀
任永杰
钟润之
徐鹏
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Sichuan Environmental Protection Science and Technology Engineering Co., Ltd.
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Chengdu K & M Metals Co Ltd
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Abstract

The invention relates to a well drilling wastewater flocculation precipitation treatment device. The device comprises a flocculation reaction tank, a flocculation settling basin and an intermediate tank, the flocculation reaction tank is provided with a stirring device, the flocculation settling basin and the intermediate tank are arranged on a well site, the flocculation reaction tank is provided with a water feeding port, a chemical feed port and a water discharge port, the water feeding port, the chemical feed port and the water discharge port are communicated to the outside, a communication valve is arranged between the flocculation settling basin and the intermediate tank, a first water pump is disposed between the flocculation settling basin and the flocculation reaction tank, the flocculation settling basin is communicated with a water inlet end of the first water pump, a water outlet end of the first water pump is communicated with the flocculation reaction tank, the flocculation reaction tank is communicated with the flocculation settling basin and the intermediate tank which are arranged on the well site to form a water circulation to collaboratively store water bodies, defects that the transportation is difficult, and uniform stirring is hardly achieved when the flocculation reaction tank is oversize are overcome, the required volume of the flocculation settling basin is reduced, besides, the water bodies formed by well drilling wastewater and flocculating agents are maintained in a flow state all the time, and the dissolving efficiency of the flocculating agents is improved.

Description

The method of a kind of well-drilling waste water flocculation sediment treatment unit and processing waste water
Technical field
The present invention relates to a kind of waste disposal plant and sewage water treatment method, especially a kind of well-drilling waste water flocculation sediment treatment unit and utilize the method for this apparatus processes waste water.
Background technology
In the process of oilfield drilling, the waste water that mud during owing to tripping operation on the seepage of the loss of mud, mud circulating system, flushing uphole equipment and the drilling tool and greasy dirt form is called well-drilling waste water.Well-drilling waste water is the important source of pollution of petroleum prospecting enterprise, and characteristics such as that well-drilling waste water has is a little many, wide, pollutant kind is complicated, high stability, intermittent discharging and the difficult control of discharging are petroleum industries than one of water pollution source of unmanageable and disposal.
Well-drilling waste water contains the various ingredients in the mud; Form complicated; Principal pollutant have suspended substance, heavy metal, oil, phenol, sulfide etc.; Well-drilling waste water totally has the colourity height, suspension content is high, the CODcr value is high, the characteristics of its organic biodegradability difference, and pollutent mainly contains following several kinds:
(1) CODcr: from various organic sludge treatment agents and tensio-active agent such as tannin, pore forming material and skimmer etc.;
(2) oil: from oil-base mud, diesel coolant, drilling unit wash-down water etc.;
(3) heavy metal: mainly by adding the Cr6+ that inorganic treatment additive chromic salt is introduced, the chromic salt ligninsulfonate is also introduced chromium ion in addition, and other source of heavy metal pollution also has Pb2+, Cd2+ plasma.
Prior art adopts the mode of flocculation to purify, handle well-drilling waste water usually; See also the 387th page~390 pages disclosed documents " well-drilling waste water and acid fracturing operation wastewater Processing Technology Research progress " on December 25th, 2002 " oilfield chemistry "; Short, waste water quality of, cycle big to flowability changes well-drilling waste water greatly; Usually adopt modes such as flocculation, sedimentation, filtration, absorption to handle; Like application number is 201010209919.3 the disclosed well-drilling waste water treatment process of Chinese invention patent " a kind of deep-well gathers sulphur DWM wastewater treatment method ", through flocculation and be aided with absorption and oxidizing process is more efficiently removed the impurity in the well-drilling waste water.
The research that recycles after handling for well-drilling waste water at present still belongs to blank at home; Being used to join slurry after well-drilling waste water is handled is the main application of well-drilling waste water; The slurry water is joined in drilling well does not at present still have national standard, requires chroma in waste water to need less than 300, to the CODcr no requirement (NR) during wellbore construction.Because D.D. is dark more, the well-drilling waste water amount of generation is big more, contains a large amount of suspended substances and oily substance in the waste water; Colourity is greater than 5000; Waste water COD cr10000~40000mg/L, and good stability, the mud-water separation difficulty; Cause the considerable part sewage can not reuse, must build enough ponds and store drilling waste water.
There is following weak point usually in the existing device that utilizes flocculence to handle well-drilling waste water:
1, the flocculation agent use-pattern is generally to the wastewater disposal basin of storing well-drilling waste water and directly adds flocculation agent; Well-drilling waste water and flocculation agent react in wastewater disposal basin; Because wastewater disposal basin is built at situ of drilling well temporarily; Whipping appts is not installed usually, and flocculation agent and well-drilling waste water reaction times are longer, and have the inadequate problem of reaction.
2, when adding like low solubility flocculation agents such as white limes, because its solubleness is low, need add excessive flocculation agent usually, a large amount of flocculation agents are deposited in the wastewater disposal basin, have both caused the flocculation agent waste, have taken the wastewater disposal basin pond again and have held.
3, owing to contain more polar soluble material in the well-drilling waste water; Only adopting conventional flocculation agent to handle well-drilling waste water is difficult to pollutants in waste water and colourity are effectively handled; Well-drilling waste water after the processing can not satisfy the requirement of wellbore construction, can not reuse.
The storage pool of revising when 4, fld is handled well-drilling waste water in the drilling well phase at present need take a large amount of surrounding grounds, causes the project cost of land too high, and the sewage environmental pollution of storage has a big risk.
Summary of the invention
The technical problem that the present invention solves is to overcome the above-mentioned deficiency of prior art, and the well-drilling waste water flocculation sediment treatment unit that a kind of land occupation is few, the flocculation agent utilising efficiency high, treatment effect is good is provided.Further, the well-drilling waste water after the processing can be back to wellbore construction.
For solving the problems of the technologies described above; The invention provides following technical scheme: a kind of well-drilling waste water flocculation sediment treatment unit; Comprise the flocculation reaction jar that is provided with whipping appts and the flocculating settling pond that is arranged at the well site and middle pond; Said flocculation reaction jar is provided with and is communicated to outside admission port, dosing mouth and water port, is provided with valve between said flocculation sedimentation tank and the middle pond; Be provided with first water pump between said flocculating settling pond and the flocculation reaction jar, said flocculating settling pond is communicated with the feed-water end of first water pump, and the water side of said first water pump is communicated with said flocculation reaction jar; Be provided with second water pump and electrofloatation device between pond and the flocculation reaction jar in the middle of said; Said electrofloatation device comprises housing, is provided with at least two pole plates in the said housing, and said pole plate links to each other with the pulse power; Said pole plate is installed on the housing middle part; Leave spacing between said pole plate bottom and the housing bottom inwall, said housing internal polar plate region forms electrolysis zone, and the pitch area that is positioned at the electrolysis zone below in the said housing is the contraminated zone; The zone that is positioned at the electrolysis zone top in the said housing is a clean water area; The pond is communicated with the feed-water end of second water pump in the middle of said, and the water side of said second water pump is communicated with the contraminated zone of electrofloatation device, and the clean water area of said electrofloatation device is communicated with the flocculation reaction jar.
Adopt such structure, constitute water cycle, the collaborative water body that stores through the flocculation reaction jar is communicated with flocculating settling pond that is arranged at the well site and middle pond; Slowed down and be difficult to the defective of transporting, being difficult to stir when the flocculation reaction tank volume is excessive, also reduced the required volume of flocculation sedimentation tank, and; The water body that well-drilling waste water and flocculation agent are formed is in flow state always, has improved the dissolved efficiency of flocculation agent, and through reaching preset equilibrium concentration after the several times circulation; Improved the utilization ratio of the flocculation agent of slightly soluble or indissoluble; Waste water electrolysis and physics sedimentation in electrofloatation device are carried out simultaneously, have significantly improved cleaning water, and the waste water Semi-polarity material modification under electrochemical action after handling; Can add flocculation agent once more and further remove organism and colourity, the recovering and reutilizing waste water after the processing is in wellbore construction.
Preferably, the angle of said pole plate and housing bottom surface is 55 °~65 °, and the frequency of the said pulse power is 20kHz~25kHz.Fine particle to forming after tiny solid impurity in the well-drilling waste water and the impurity metal ion electrolysis is prone to be adsorbed in the problem on the pole plate; Pole plate is obliquely installed and is aided with the vibrations of high-frequency pulse power supply with 55 °~65 ° oblique angle; Impurity shakes on pole plate and comes off and be settled down to the contraminated zone with the landing of taking advantage of a situation of the oblique angle of pole plate, has avoided the accumulation of impurity on the pole plate.
Preferably; Said flocculation reaction jar comprises first tank body and second tank body; Said admission port is arranged at the top of first tank body, and said whipping appts is arranged in first tank body, is provided with middle siphunculus between said first tank body and second tank body; An end of siphunculus is communicated to the inside of first tank body in said by the side of first tank body; The other end of siphunculus is communicated to the inside of second tank body by the top of second tank body in said, and said water port is arranged at the side of second tank body, and said second tank body is provided with the secondary reaction water-in; Said secondary reaction water-in be arranged at second tank body the side, and tangentially be communicated to the inside of second tank body, be provided with second water inlet pipe between the water outlet of said secondary reaction water-in and water pump.
Said flocculating settling pond comprises landwaste pond and the muddy water pond that is arranged at the well site; A said landwaste pond side adjacent with the muddy water pond is provided with at least one connected entrance; Said landwaste pond is provided with into water ramp away from a side in muddy water pond, and the bottom surface in said landwaste pond is along the inclination that is directed downwards of water inlet ramp to connected entrance, and the bottom in said muddy water pond is tapered; It is inner that the feed-water end of said first water pump is communicated to the muddy water pond, and said water port is communicated with the flocculating settling pond.
Preferably; Said dosing mouth is connected with dispensation apparatus through dosing pipe; Said dispensation apparatus comprises first dispensing canister and second dispensing canister, and the said first dispensing canister upper top is provided with clear water import and medicine import, and said second dispensing canister is arranged at the below of first dispensing canister; Be provided with in said first dispensing canister and mix the medicine whisking appliance; Be provided with the soup transfer lime between said first dispensing canister and second dispensing canister, the sidewall of said second dispensing canister is provided with medicine liquid outlet, and said medicine liquid outlet is communicated with the dosing mouth of flocculation reaction jar.
Preferably; Be provided with the secondary back pipeline between the dosing mouth of said medicine liquid outlet and flocculation reaction jar; Said secondary back pipeline comprises first ball valve and second ball valve, and the input terminus of the input terminus of said first ball valve, second ball valve all is communicated to the inside of second dispensing canister; The output terminal of said first ball valve is connected with first plunger metering pump; The output terminal of said first plunger metering pump is parallel with the delivery conduit and first return line; Said delivery conduit is communicated with the output terminal of first plunger metering pump with the dosing mouth of flocculation reaction jar, said first return line is with the internal communication of the output terminal and second dispensing canister of said first plunger metering pump; The output terminal of said second ball valve is connected with second plunger metering pump; Be provided with second return line between the output terminal of said second plunger metering pump and second dispensing canister, said second return line is with the output terminal and the second dispensing canister internal communication of second plunger metering pump.
Preferably; Said well site is provided with the skid body, and said skid body is hollow casing, and it is inner that said flocculation reaction jar, electrofloatation device and dispensation apparatus all are arranged at the skid body; Said skid body bottom is provided with at least two support posts, is provided with stull between the said support post.
A kind of method of utilizing above-mentioned well-drilling waste water cyclic processing device to handle well-drilling waste water comprises following step:
A, well-drilling waste water and coagulating agent are directed in first tank body through admission port and dosing mouth; The whipping appts that starts on the flocculation reaction jar mixes well-drilling waste water and coagulating agent; The mixed solution of well-drilling waste water and coagulating agent is through in middle siphunculus overflow to the second tank body, and through being arranged at the lateral water outlet overflow of second tank body to the flocculating settling pond;
B, liquid left standstill in the flocculating settling pond 12~16 hours;
C, unlatching are arranged at the valve between flocculation sedimentation tank and the middle pond, the liquid in the middle pond are pumped in the contraminated zone of electrofloatation device with second water pump;
D, starting impulse power supply, electrolysis also makes the sedimentation of sewage physics;
E, the liquid in the clean water area is directed in the flocculation reaction jar; After leaving standstill 12~16 hours in the liquid return in the contraminated zone to the flocculating settling pond; Unlatching is arranged at the valve between flocculation sedimentation tank and the middle pond, with pond in the middle of the supernatant liquid importing of flocculation sedimentation tank.In this step; Through dosing mouth coagulating agent is directed in first tank body; The whipping appts that starts on the flocculation reaction jar mixes liquid and coagulating agent; The mixed solution of liquid and coagulating agent is through in middle siphunculus overflow to the second tank body, and through being arranged at the lateral water outlet overflow of second tank body to the flocculating settling pond;
Preferably, after the step e, liquid in the middle pond is back to wellbore construction; In this step, liquid in the middle pond is through after sedimentation and the flocculation, and the supernatant liquid of flocculation sedimentation tank is back to wellbore construction, and the water quality certain mass promotes, and can be back to wellbore construction, as the water source of work such as flushing.
Preferably, in said step a, said coagulating agent comprises the component of following mass ratio: 2~4 parts in 0.01~0.12 part of SEPIGEL 305, calcium hydroxide or 1~3 part in quicklime, ferric sulfate or ferrous sulfate.
Said components is to draw through the long-term a large amount of experiment of contriver, is used for handling that to gather sulphur mud sewage coagulation effect good.Calcium hydroxide or quicklime can provide the flocculation nucleus for the colloid that gathers in the sulphur mud sewage.Calcium hydroxide or quicklime are soluble in water to be that pH raises, the adding of ferric sulfate or ferrous sulfate, and iron ion that provides or ferrous ion combine to form ironic hydroxide or ferrous hydroxide colloid, the suspended substance in the sewage that can flocculate effectively with hydroxide radical.The part calcium ion can combine with the sulfonic group in gathering sulphur mud, makes effectively to gather the sulfonic acid substance flocculation, and part calcium ion and sulfate radical production deposition form new flocculation nucleus.Adding SEPIGEL 305 can accelerate precipitation.The coagulating agent that adopts processing provided by the invention to gather sulphur mud sewage is handled and is gathered sulphur mud sewage; Discharge calcium ion and hydroxide ion after calcium hydroxide or quicklime are water-soluble; Hydroxide radical raises pH; Alkaline environment can make the iron ion or the ferrous ion that add generate ferrous hydroxide or ferric hydroxide colloid, gathers sulphur salt binding production deposition or complex compound in part calcium ion and the water, destroys well-drilling waste water and gathers the sulphur system; Thereby let effectively and gather the sulphur system in the well-drilling waste water and change property, with water sepn.COD of sewage Cr and chroma removal rate after the processing are improved significantly, and auxiliary through twice dosing coagulant, the CODCr clearance reaches as high as 92% with after the electrofloatation processing, and the maximum chroma clearance reaches as high as 96%.
Compared with prior art, beneficial effect of the present invention is following:
1, constitute water cycle through the flocculation reaction jar is communicated with flocculating settling pond that is arranged at the well site and middle pond, the collaborative water body that stores has slowed down and has been difficult to the defective of transporting, being difficult to stir when the flocculation reaction tank volume is excessive; Also reduced the required volume of flocculation sedimentation tank; And the water body that well-drilling waste water and flocculation agent are formed is in flow state always, has improved the dissolved efficiency of flocculation agent; And through reaching preset equilibrium concentration after the several times circulation; Improved the utilization ratio of the flocculation agent of slightly soluble or indissoluble, waste water electrolysis and physics sedimentation in electrofloatation device are carried out simultaneously, have significantly improved cleaning water; And the waste water Semi-polarity material modification under electrochemical action after handling; Can add flocculation agent once more and further remove organism and colourity, the recovering and reutilizing waste water after the processing is joined the slurry water in drilling well, also can carry out next step advanced treatment to qualified discharge.
2, reduce the well-drilling waste water floor space greatly: big volumetrical sewage storage pool need not repaiied, according to well-drilling waste water maximum amount of water every day 20m3 in the well site after building the necessary landwaste pond of this treatment process, muddy water pond, flocculating settling pond, middle pond; Drilling well was calculated in 150 days, with the waste water generation of the 3000m3 that has an appointment, if build storage pool; Calculate by the dark 3m in average pond, with taking about land area more than 2 mu, and adopt after this technology; The function pond cubic capacity of building is less than 1000m3, calculates by mean depth 3m, only takies about 0.5 mu land area; The land seizure area has reduced more than 75%, and this will greatly reduce the soil cost of drilling operation.
3, reduce the intact back of clear water usage quantity and drilling well residue wastewater flow rate: drilling water needs to use clear water more than 90% at present; Only about 10% well-drilling waste water has obtained recycling, and in some water-deficient areas, this has greatly restricted carrying out of drilling well work; After adopting this art breading well-drilling waste water; About 90% well-drilling waste water has obtained recycling, and only need replenish about 10% clear water, has reduced the demand to clear water greatly.Simultaneously after the drilling well completion, remaining waste water is merely a small amount of waste water that drilling well produces in last processing cycle, can be pulled to next situ of drilling well after treatment and do and join the slurry water, also can be transported to and concentrate sewage works to handle back up to standard discharging.
Description of drawings
Fig. 1 is the structural representation of one embodiment of the present invention;
Fig. 2 is the structural representation of flocculation reaction jar among the present invention;
Fig. 3 is the vertical view of Fig. 2;
Fig. 4 is the structural representation of chemicals dosing plant among the present invention;
Fig. 5 is the structural representation of a kind of embodiment in flocculating settling pond among the present invention;
Fig. 6 is the structural representation of electrofloatation device among the present invention.
Reference numeral is following: flocculation reaction jar-1; Admission port-1a; Dosing mouth-1b; Water port-1c; First tank body-101; Second tank body-102; Whipping appts-2; Flocculating settling pond-3; Middle pond-4; First water pump-5; Second water pump-6; Middle siphunculus-7; Secondary reaction water-in-8; Secondary water inlet pipe-9; Electrofloatation device-10; Electrolysis zone-10a; Contraminated zone-10b; Clean water area-10c; Housing-10d; Pole plate-10e; First dispensing canister-11; Clear water import-11a; Medicine import-11b; Mix medicine whisking appliance-11c; Second dispensing canister-12; Medicine liquid outlet-12a; Soup transfer lime-13; Secondary back pipeline-14; First ball valve-15a; Second ball valve-15b; First plunger metering pump-16a; Second plunger metering pump-16b; Delivery conduit-17; First return line-18a; Second return line-18b; Skid body-19; Support post-20; Stull-21; Landwaste pond-22; Muddy water pond-23; Connected entrance-24; Water inlet ramp-25.
Embodiment
Below in conjunction with accompanying drawing and embodiment the present invention is further described.
Embodiment of the present invention is not limited to following examples, and the various variations of under the prerequisite that does not break away from aim of the present invention, making all belong within protection scope of the present invention.
Embodiment 1
Extremely shown in Figure 6 like Fig. 1; Flocculating settling pond 3 and middle pond 4 that present embodiment well-drilling waste water flocculation sediment treatment unit is provided with the flocculation reaction jar 1 of whipping appts 2 and is arranged at the well site; Flocculation reaction jar 1 is provided with and is communicated to outside admission port 1a, dosing mouth 1b and water port 1c; Be provided with valve between said flocculation sedimentation tank and the middle pond 4; The two ends of valve are communicated with the top water body of flocculation sedimentation tank with middle pond 4, when liquid level in the flocculation sedimentation tank higher and open valve after, in the liquid communication in the flocculation sedimentation tank to the middle pond 4.Be provided with first water pump 5 between said flocculating settling pond 3 and the flocculation reaction jar 1; Said flocculating settling pond 3 is communicated with the feed-water end of first water pump 5; The water side of said first water pump 5 is communicated with said flocculation reaction jar 1, and with after flocculation reaction jar 1 is communicated with, flocculation reaction jar 1 is communicated with the flocculating settling pond 3 that is arranged at the well site and constitutes the collaborative water body that stores of water cycle with flocculation sedimentation tank; When having avoided independent dependence flocculation reaction jar 1 water storage; Flocculation reaction jar 1 volume is excessive to be difficult to transport, internal liquid stirs the big problem of difficulty, when also having slowed down independent dependence flocculation sedimentation tank water storage, takies the well site than big area; And; In the circulating water system of flocculation sedimentation tank and flocculation reaction jar 1 composition; The water body that well-drilling waste water and flocculation agent are formed is in flow state always; Improved the dissolved efficiency of flocculation agent, and, improved the utilization ratio of the flocculation agent of slightly soluble or indissoluble through reaching preset equilibrium concentration after the several times circulation.Be provided with second water pump 6 and electrofloatation device 10 in the middle of said between pond 4 and the flocculation reaction jar 1, said electrofloatation device 10 comprises housing 10d, is provided with at least two pole plate 10e in the said housing 10d; Said pole plate 10e links to each other with the pulse power; Said pole plate 10e is installed on housing 10d middle part, leaves spacing between said pole plate 10e bottom and the housing 10d bottom interior wall, and said housing 10d internal polar plate 10e region forms electrolysis zone 10a; The pitch area that is positioned at electrolysis zone 10a below in the said housing 10d is contraminated zone 10b; The zone that is positioned at electrolysis zone 10a top in the said housing 10d is clean water area 10c, and said middle pond 4 is communicated with the feed-water end of second water pump 6, and the water side of said second water pump 6 is communicated with the contraminated zone 10b of electrofloatation device 10; The clean water area 10c of said electrofloatation device 10 is communicated with flocculation reaction jar 1; Waste water electrolysis and physics sedimentation in electrofloatation device 10 are carried out simultaneously, have significantly improved cleaning water, and the waste water Semi-polarity material modification under electrochemical action after handling; Can add flocculation agent once more and further remove organism and colourity, the recovering and reutilizing waste water after the processing is in wellbore construction.
In the present embodiment; The angle of pole plate 10e and housing 10d bottom surface is 55 °; The frequency of the pulse power is 20kHz; Pole plate 10e is obliquely installed and is aided with the vibrations of the high-frequency pulse power supply of 20kHz with 55 ° oblique angle, and impurity shakes on pole plate 10e and comes off and be settled down to contraminated zone 10b, the accumulation of having avoided pole plate 10e to go up impurity with the landing of taking advantage of a situation of the oblique angle of pole plate 10e.
Embodiment 2
Extremely shown in Figure 6 like Fig. 1; Flocculation reaction jar 1 comprises first tank body 101 and second tank body 102 in the present embodiment; Said admission port 1a is arranged at the top of first tank body 101; Said whipping appts 2 is arranged in first tank body 101; Siphunculus 7 in being provided with between said first tank body 101 and second tank body 102, said in an end of siphunculus 7 be communicated to the inside of first tank body 101 by the side of first tank body 101, said in the other end of siphunculus 7 be communicated to the inside of second tank body 102 by the top of second tank body 102; Said water port 1c is arranged at the side of second tank body 102; Said second tank body 102 is provided with secondary reaction water-in 8, said secondary reaction water-in 8 be arranged at second tank body 102 the side, and tangentially be communicated to the inside of second tank body 102, be provided with secondary water inlet pipe 9 between the water outlet of said secondary reaction water-in 8 and water pump.Adopt such structure; Not only guaranteed that slightly soluble or indissoluble medicine fully stirred, but also can behind mixing, be spilled over to second dispensing canister 12 in further slowly-releasing in first dispensing canister 11, when having guaranteed liquid fluidity in first dispensing canister 11, increased coagulating agent in water body dissolution time and dissolve probability.
In the present embodiment, the angle of pole plate 10e and housing 10d bottom surface is 65 °, and the frequency of the pulse power is 25kHz.All the other structures see also embodiment 1.
Utilize present embodiment well-drilling waste water cyclic processing device to handle the method for well-drilling waste water, comprise following step:
A, well-drilling waste water and coagulating agent are directed in first tank body 101 through admission port 1a and dosing mouth 1b; The 2 pairs of well-drilling waste waters of whipping appts and the coagulating agent that start on the flocculation reaction jar 1 mix; The mixed solution of well-drilling waste water and coagulating agent is through in middle siphunculus 7 overflow to the second tank bodies 102, and through being arranged at the 102 lateral water outlet overflows of second tank body to flocculating settling pond 3;
B, liquid left standstill in flocculating settling pond 3 12 hours;
C, unlatching are arranged at the valve between flocculation sedimentation tank and the middle pond 4, the liquid in the middle pond 4 are pumped in the contraminated zone 10b of electrofloatation device 10 with second water pump 6;
D, starting impulse power supply, electrolysis also makes the sedimentation of sewage physics;
E, the liquid among the clean water area 10c is directed in the flocculation reaction jar 1, leaving standstill 12 hours in the liquid return among the 10b of contraminated zone to the flocculating settling pond 3;
F, the supernatant liquid in the middle pond 4 is back to wellbore construction.
Among the step a of present embodiment; Earlier calcium hydroxide or quicklime are added pending gathering in the sulphur mud sewage with powder or solution form; Mixed 5 ~ 15 minutes, and again ferric sulfate or ferrous sulfate were added in the sewage after the above-mentioned processing, stir flocculation 5 ~ 15 minutes; At last, add SEPIGEL 305 in the sewage after above-mentioned steps is handled.Following embodiment all adopts aforesaid method to gather the WWT of sulphur mud.Get drilling waste water analysis, obtain the sewage related data, adopt provided by the invention gather the WWT of sulphur mud after; Treatment process adopts the method in the embodiment; The related data of the sewage after the analyzing and processing, concrete, that chooses the somewhere, Sichuan gathers sulphur mud sewage sample I 1L; Analyze in the sewage CODCr and with extension rate method mensuration colourity; Be sequentially added into the coagulating agent that processing provided by the invention gathers sulphur mud sewage then it is handled, wherein the calcium hydroxide add-on is 8g, and the ferrous sulfate add-on is 17.5g; And then to the sewage adding 100mg SEPIGEL 305 processing after handling through above-mentioned treatment step, the sewage index after the analyzing and processing is as shown in table 1.
Table 1 is a parameter comparison table before and after the present embodiment WWT
Figure BDA00002008968300121
Embodiment 3
Extremely shown in Figure 6 like Fig. 1; Flocculating settling pond 3 described in the present embodiment well-drilling waste water flocculation sediment treatment unit comprises adjacent landwaste pond 22 and muddy water pond 23; Said landwaste pond 22 is provided with three connected entrances 24 with muddy water pond 23 adjacent sides, and in all the other embodiments, the quantity of connected entrance 24 can also be one, two or several; Said landwaste pond 22 is provided with into water ramp 25 away from a side in muddy water pond 23; The bottom surface in said landwaste pond 22 is along the inclination that is directed downwards of water inlet ramp 25 to connected entrance 24, and the bottom in said muddy water pond 23 is tapered, and the feed-water end of said first water pump 5 is communicated to 23 inside, muddy water pond.Well-drilling waste water is directed into after the landwaste pond 22; The silt that wherein proportion is bigger precipitates in landwaste pond 22; And all the other waste water flow automatically to muddy water pond 23; Can be effectively with well-drilling waste water with separate through the waste water of treating subsequent disposal of sediment deposition, be convenient to directly extract and must handle before pending waste water utilizes again, and be easy to the settling water conservancy diversion after the gradient and be easy to follow-up desilting blowdown being provided with at the bottom of the pond.
All the other structures see also embodiment 2.
Utilize present embodiment well-drilling waste water cyclic processing device to handle the method for well-drilling waste water, comprise following step:
A, well-drilling waste water and coagulating agent are directed in first tank body 101 through admission port 1a and dosing mouth 1b; The 2 pairs of well-drilling waste waters of whipping appts and the coagulating agent that start on the flocculation reaction jar 1 mix; The mixed solution of well-drilling waste water and coagulating agent is through in middle siphunculus 7 overflow to the second tank bodies 102, and through being arranged at the 102 lateral water outlet overflows of second tank body to flocculating settling pond 3;
B, liquid left standstill in flocculating settling pond 3 16 hours;
C, unlatching are arranged at the valve between flocculation sedimentation tank and the middle pond 4, the liquid in the middle pond 4 are pumped in the contraminated zone 10b of electrofloatation device 10 with second water pump 6;
D, starting impulse power supply, electrolysis also makes the sedimentation of sewage physics;
E, the liquid among the clean water area 10c is directed in the flocculation reaction jar 1; After in the liquid return among the 10b of contraminated zone to the flocculating settling pond 3 static 16 hours; Unlatching is arranged at the valve between flocculation sedimentation tank 3 and the middle pond 4, with pond 4 in the middle of the supernatant liquid importing of flocculation sedimentation tank 3.And the supernatant liquid in flocculating settling pond 3 entered to middle pond 4, can as required the liquid in the middle pond 4 be back to wellbore construction afterwards.
In the present embodiment, step a calcium hydroxide add-on is 8g, and the ferrous sulfate add-on is 12g, and then the sewage after handling through above-mentioned treatment step is added the processing of 500mg SEPIGEL 305, and the sewage index after the analyzing and processing is as shown in table 2.
Table 2 is a parameter comparison table before and after the present embodiment WWT
Figure BDA00002008968300141
Embodiment 4
Extremely shown in Figure 6 like Fig. 1; Dosing mouth 1b is connected with dispensation apparatus through dosing pipe in the present embodiment well-drilling waste water flocculation sediment treatment unit; Dispensation apparatus comprises that first dispensing canister 11 and second dispensing canister, 12, the first dispensing canisters, 11 upper tops are provided with clear water import 11a and medicine import 11b, and second dispensing canister 12 is arranged at the below of first dispensing canister 11; Be provided with in first dispensing canister 11 and mix medicine whisking appliance 11c; The sidewall that is provided with soup transfer lime 13, the second dispensing canisters 12 between first dispensing canister 11 and second dispensing canister 12 is provided with medicine liquid outlet 12a, and medicine liquid outlet 12a is communicated with the dosing mouth 1b of flocculation reaction jar 1.Adopt such structure; Not only guaranteed that slightly soluble or indissoluble medicine fully stirred, but also can behind mixing, be spilled over to second dispensing canister 12 in further slowly-releasing in first dispensing canister 11, when having guaranteed liquid fluidity in first dispensing canister 11, increased coagulating agent in water body dissolution time and dissolve probability.Be provided with secondary back pipeline 14 between the dosing mouth 1b of medicine liquid outlet 12a and flocculation reaction jar 1; Secondary back pipeline 14 comprises the first ball valve 15a and the second ball valve 15b, and the input terminus of the input terminus of the first ball valve 15a, the second ball valve 15b all is communicated to the inside of second dispensing canister 12; The output terminal of the first ball valve 15a is connected with the first plunger metering pump 16a; The output terminal of the first plunger metering pump 16a is parallel with the delivery conduit 17 and the first return line 18a; Delivery conduit 17 is communicated with the output terminal of the first plunger metering pump 16a with the dosing mouth 1b of flocculation reaction jar 1, the first return line 18a is with the internal communication of the output terminal and second dispensing canister 12 of the first plunger metering pump 16a; The output terminal of the second ball valve 15b is connected with the second plunger metering pump 16b; Be provided with the second return line 18b between the output terminal of the second plunger metering pump 16b and second dispensing canister 12, the second return line 18b is with output terminal and second dispensing canister, 12 internal communication of the second plunger metering pump 16b.Adopt such structure, can be as required adjust the dissolution time of coagulating agent in water body and dissolving probability, simultaneously, return line passes back into second and mixes current in the medicinal cupping and mix water body in the medicinal cupping to second and play and wash away effect of uniform.
All the other structures see also embodiment 3.
Utilize present embodiment well-drilling waste water cyclic processing device to handle the method for well-drilling waste water, comprise following step:
A, well-drilling waste water and coagulating agent are directed in first tank body 101 through admission port 1a and dosing mouth 1b; The 2 pairs of well-drilling waste waters of whipping appts and the coagulating agent that start on the flocculation reaction jar 1 mix; The mixed solution of well-drilling waste water and coagulating agent is through in middle siphunculus 7 overflow to the second tank bodies 102, and through being arranged at the 102 lateral water outlet overflows of second tank body to flocculating settling pond 3;
B, liquid left standstill in flocculating settling pond 3 16 hours;
C, unlatching are arranged at the valve between flocculation sedimentation tank and the middle pond 4, the liquid in the middle pond 4 are pumped in the contraminated zone 10b of electrofloatation device 10 with second water pump 6;
D, starting impulse power supply, electrolysis also makes the sedimentation of sewage physics;
E, the liquid among the clean water area 10c is directed in the flocculation reaction jar 1; With in the liquid return among the 10b of contraminated zone to the flocculating settling pond 3 static 16 hours; And the supernatant liquid in flocculating settling pond 3 entered to middle pond 4, can as required the liquid in the middle pond 4 be back to wellbore construction afterwards.
In the present embodiment, step a calcium hydroxide add-on is 8g, and the ferrous sulfate add-on is 30g, and then the sewage after handling through above-mentioned treatment step is added the processing of 960mg SEPIGEL 305, and the sewage index after the analyzing and processing is as shown in table 2.
Table 3 is a parameter comparison table before and after the present embodiment WWT
Figure BDA00002008968300161
Embodiment 5
Extremely shown in Figure 6 like Fig. 1; Be provided with skid body 19 in the present embodiment well-drilling waste water flocculation sediment treatment unit in the well site; Said skid body 19 is hollow casing; Said flocculation reaction jar 1, electrofloatation device 10 and dispensation apparatus all are arranged at skid body 19 inside, and said skid body 19 bottoms are provided with at least two support posts 20, are provided with stull 21 between the said support post 20.Adopt such structure, at first confirm to carry out the position that well-drilling waste water is handled, then support is arranged on this position; After support has set, again skid body 19 is arranged on the support, such being provided with guaranteed the stable of skid body 19 structures; Guaranteed the position stability of well-drilling waste water treatment unit simultaneously; Avoid the influence of factor such as for example floor surface infiltration, if transportation well-drilling waste water treatment unit then directly transports casing; The safety that has guaranteed the intravital device of case on the one hand makes on the other hand that with stable transportation becomes simple.
All the other structures see also embodiment 4.
Combine accompanying drawing that embodiments of the invention are described in detail above; But the present invention is not limited to the foregoing description; In the ken that those of ordinary skills possessed, can also make various variations, these variations all belong within protection scope of the present invention.

Claims (10)

1. well-drilling waste water flocculation sediment treatment unit; Comprise the flocculation reaction jar (1) that is provided with whipping appts (2) and the flocculating settling pond (3) that is arranged at the well site and middle pond (4); Said flocculation reaction jar (1) is provided with and is communicated to outside admission port (1a), dosing mouth (1b) and water port (1c), it is characterized in that: be provided with valve between said flocculation sedimentation tank and middle pond (4); Be provided with first water pump (5) between said flocculating settling pond (3) and the flocculation reaction jar (1), said flocculating settling pond (3) is communicated with the feed-water end of first water pump (5), and the water side of said first water pump (5) is communicated with said flocculation reaction jar (1); Be provided with second water pump (6) and electrofloatation device (10) between pond (4) and the flocculation reaction jar (1) in the middle of said; Said electrofloatation device (10) comprises housing (10d); Be provided with at least two pole plates (10e) in the said housing (10d); Said pole plate (10e) links to each other with the pulse power; Said pole plate (10e) is installed on housing (10d) middle part; Leave spacing between said pole plate (10e) bottom and housing (10d) bottom interior wall, said housing (10d) internal polar plate (10e) region forms electrolysis zone (10a), and the pitch area that is positioned at electrolysis zone (10a) below in the said housing (10d) is contraminated zone (10b); The zone that is positioned at electrolysis zone (10a) top in the said housing (10d) is clean water area (10c); Pond (4) are communicated with the feed-water end of second water pump (6) in the middle of said, and the water side of said second water pump (6) is communicated with the contraminated zone (10b) of electrofloatation device (10), and the clean water area (10c) of said electrofloatation device (10) is communicated with flocculation reaction jar (1).
2. well-drilling waste water flocculation sediment treatment unit according to claim 1; It is characterized in that: said flocculation reaction jar (1) comprises first tank body (101) and second tank body (102); Said admission port (1a) is arranged at the top of first tank body (101); Said whipping appts (2) is arranged in first tank body (101); Be provided with middle siphunculus (7) between said first tank body (101) and second tank body (102); An end of siphunculus (7) is communicated to the inside of first tank body (101) in said by the side of first tank body (101); The other end of siphunculus (7) is communicated to the inside of second tank body (102) by the top of second tank body (102) in said, and said water port (1c) is arranged at the side of second tank body (102), and said second tank body (102) is provided with secondary reaction water-in (8); Said secondary reaction water-in (8) be arranged at second tank body (102) the side, and tangentially be communicated to the inside of second tank body (102), be provided with secondary water inlet pipe (9) between the water outlet of said secondary reaction water-in (8) and water pump.
3. well-drilling waste water flocculation sediment treatment unit according to claim 1; It is characterized in that: said flocculating settling pond (3) comprises landwaste pond (22) and muddy water pond (23) that are arranged at the well site; Said landwaste pond (a 22) side adjacent with muddy water pond (23) is provided with at least one connected entrance (24); Said landwaste pond (22) is provided with into water ramp (25) away from a side of muddy water pond (23); The bottom surface in said landwaste pond (22) is along the inclination that is directed downwards of water inlet ramp (25) to connected entrance (24); The bottom in said muddy water pond (23) is tapered, and the feed-water end of said first water pump (5) is communicated to inside, muddy water pond (23), and said water port (1c) is communicated with flocculating settling pond (3).
4. well-drilling waste water flocculation sediment treatment unit according to claim 1 is characterized in that: said pole plate (10e) is 55 °~65 ° with the angle of housing (10d) bottom surface, and the frequency of the said pulse power is 20kHz~25kHz.
5. well-drilling waste water flocculation sediment treatment unit according to claim 1; It is characterized in that: said dosing mouth (1b) is connected with dispensation apparatus through dosing pipe; Said dispensation apparatus comprises first dispensing canister (11) and second dispensing canister (12); Said first dispensing canister (11) upper top is provided with clear water import (11a) and medicine import (11b); Said second dispensing canister (12) is arranged at the below of first dispensing canister (11), is provided with in said first dispensing canister (11) to mix medicine whisking appliance (11c), is provided with soup transfer lime (13) between said first dispensing canister (11) and second dispensing canister (12); The sidewall of said second dispensing canister (12) is provided with medicine liquid outlet (12a), and said medicine liquid outlet (12a) is communicated with the dosing mouth (1b) of flocculation reaction jar (1).
6. well-drilling waste water flocculation sediment treatment unit according to claim 5; It is characterized in that: be provided with secondary back pipeline (14) between the dosing mouth (1b) of said medicine liquid outlet (12a) and flocculation reaction jar (1); Said secondary back pipeline (14) comprises first ball valve (15a) and second ball valve (15b), and the input terminus of the input terminus of said first ball valve (15a), second ball valve (15b) all is communicated to the inside of second dispensing canister (12); The output terminal of said first ball valve (15a) is connected with first plunger metering pump (16a); The output terminal of said first plunger metering pump (16a) is parallel with delivery conduit (17) and first return line (18a); Said delivery conduit (17) is communicated with the output terminal of first plunger metering pump (16a) with the dosing mouth (1b) of flocculation reaction jar (1), said first return line (18a) is with the internal communication of the output terminal and second dispensing canister (12) of said first plunger metering pump (16a); The output terminal of said second ball valve (15b) is connected with second plunger metering pump (16b); Be provided with second return line (18b) between the output terminal of said second plunger metering pump (16b) and second dispensing canister (12), said second return line (18b) is with the output terminal and second dispensing canister (12) internal communication of second plunger metering pump (16b).
7. well-drilling waste water flocculation sediment treatment unit according to claim 1; It is characterized in that: said well site is provided with skid body (19); Said skid body (19) is hollow casing; Said flocculation reaction jar (1), electrofloatation device (10) and dispensation apparatus all are arranged at skid body (19) inside, and said skid body (19) bottom is provided with at least two support posts (20), is provided with stull (21) between the said support post (20).
8. method of utilizing arbitrary well-drilling waste water flocculation sediment treatment unit in the claim 1 to 7 to handle well-drilling waste water comprises following step:
A, well-drilling waste water and coagulating agent are directed in first tank body (101) through admission port (1a) and dosing mouth (1b); The whipping appts (2) that starts on the flocculation reaction jar (1) mixes well-drilling waste water and coagulating agent; The mixed solution of well-drilling waste water and coagulating agent is through in middle siphunculus (7) overflow to the second tank body (102), and through being arranged at the lateral water outlet overflow of second tank body (102) in flocculating settling pond (3);
B, liquid left standstill 12~16 hours in flocculating settling pond (3);
C, unlatching are arranged at the valve between flocculation sedimentation tank and middle pond (4), the liquid in middle pond (4) are pumped in the contraminated zone (10b) of electrofloatation device (10) with second water pump (6);
D, starting impulse power supply, electrolysis also makes the sedimentation of sewage physics;
E, the liquid in the clean water area (10c) is directed in the flocculation reaction jar (1); After in the liquid return in contraminated zone (10b) to flocculating settling pond (3) static 12~16 hours; Unlatching is arranged at the valve between flocculation sedimentation tank (3) and middle pond (4), with pond 4 in the middle of the supernatant liquid importing of flocculation sedimentation tank (3).
9. the method for processing well-drilling waste water according to claim 8 is characterized in that: after the said step e, liquid in middle pond (4) is back to wellbore construction.
10. the method for processing well-drilling waste water according to claim 8; It is characterized in that: in said step a, said coagulating agent comprises the component of following mass ratio: 2~4 parts in 0.01~0.12 part of SEPIGEL 305, calcium hydroxide or 1~3 part in quicklime, ferric sulfate or ferrous sulfate.
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CN104075910A (en) * 2014-06-30 2014-10-01 宣尧杭 Sampling detection device for printing and dyeing wastewater treatment system
CN106032292A (en) * 2015-03-10 2016-10-19 天津翼高腾飞电解技术有限公司 A vertical-electrode electrolysis type waste water treating skid-mounted device
CN104909441A (en) * 2015-06-05 2015-09-16 江苏立业环境科技有限公司 Volute sewage treatment system
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CN109292931A (en) * 2018-11-05 2019-02-01 黑河学院 A kind of solar battery preparation discharge of wastewater processing unit
CN113105097A (en) * 2020-01-13 2021-07-13 中国石油天然气集团有限公司 Harmless treatment method for waste water-based mud
CN111410346A (en) * 2020-02-21 2020-07-14 西南石油大学 Combined treatment device and method for waste drilling fluid
CN111410346B (en) * 2020-02-21 2022-04-22 西南石油大学 Combined treatment device and method for waste drilling fluid
CN111252871A (en) * 2020-02-28 2020-06-09 广东工业大学 Device for removing colloid impurities under action of static field force coupled with multistage partition plates and water power
CN111252871B (en) * 2020-02-28 2022-06-03 广东工业大学 Device for removing colloid impurities under action of static field force coupled with multistage partition plates and water power
CN112843877A (en) * 2021-02-24 2021-05-28 江苏珺瑶环境能源有限公司 Intelligent integrated sewage treatment equipment and sewage treatment method

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