CN102719137A - Special jet ink for PVC (polyvinyl chloride) cable - Google Patents
Special jet ink for PVC (polyvinyl chloride) cable Download PDFInfo
- Publication number
- CN102719137A CN102719137A CN2012101803639A CN201210180363A CN102719137A CN 102719137 A CN102719137 A CN 102719137A CN 2012101803639 A CN2012101803639 A CN 2012101803639A CN 201210180363 A CN201210180363 A CN 201210180363A CN 102719137 A CN102719137 A CN 102719137A
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- printing ink
- code
- organic solvent
- spraying printing
- Prior art date
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- 229920000915 polyvinyl chloride Polymers 0.000 title abstract 8
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 8
- 238000007639 printing Methods 0.000 claims abstract description 96
- 229920005989 resin Polymers 0.000 claims abstract description 71
- 239000011347 resin Substances 0.000 claims abstract description 71
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 20
- 239000004094 surface-active agent Substances 0.000 claims abstract 4
- 239000003086 colorant Substances 0.000 claims abstract 2
- 239000000976 ink Substances 0.000 claims description 102
- 238000005507 spraying Methods 0.000 claims description 79
- 239000003960 organic solvent Substances 0.000 claims description 57
- 239000002994 raw material Substances 0.000 claims description 44
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 42
- 229920002554 vinyl polymer Polymers 0.000 claims description 42
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 38
- 239000011259 mixed solution Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 28
- 238000002156 mixing Methods 0.000 claims description 27
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 22
- 239000013543 active substance Substances 0.000 claims description 20
- 239000004840 adhesive resin Substances 0.000 claims description 20
- 229920006223 adhesive resin Polymers 0.000 claims description 20
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 18
- 239000011737 fluorine Substances 0.000 claims description 18
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 17
- WDGKXRCNMKPDSD-UHFFFAOYSA-N lithium;trifluoromethanesulfonic acid Chemical compound [Li].OS(=O)(=O)C(F)(F)F WDGKXRCNMKPDSD-UHFFFAOYSA-N 0.000 claims description 17
- 239000004902 Softening Agent Substances 0.000 claims description 16
- 239000001069 triethyl citrate Substances 0.000 claims description 16
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 16
- 235000013769 triethyl citrate Nutrition 0.000 claims description 16
- 239000006229 carbon black Substances 0.000 claims description 15
- 235000019241 carbon black Nutrition 0.000 claims description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 14
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 14
- 239000001038 titanium pigment Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 8
- 239000000975 dye Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 239000000992 solvent dye Substances 0.000 claims description 5
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- LAVARTIQQDZFNT-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-yl acetate Chemical compound COCC(C)OCC(C)OC(C)=O LAVARTIQQDZFNT-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 2
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 claims description 2
- 108700032487 GAP-43-3 Proteins 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- WUFQLZTXIWKION-UHFFFAOYSA-N deoxypeganine perchlorate Natural products C1C2=CC=CC=C2N=C2N1CCC2 WUFQLZTXIWKION-UHFFFAOYSA-N 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 2
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 2
- 235000019439 ethyl acetate Nutrition 0.000 claims description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 2
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 2
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 2
- ZGHFDIIVVIFNPS-UHFFFAOYSA-N methyl alpha-methylvinyl ketone Natural products CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 claims description 2
- 229940017144 n-butyl lactate Drugs 0.000 claims description 2
- ODYNBECIRXXOGG-UHFFFAOYSA-N n-butylbutan-1-amine;hydron;chloride Chemical compound [Cl-].CCCC[NH2+]CCCC ODYNBECIRXXOGG-UHFFFAOYSA-N 0.000 claims description 2
- MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 claims description 2
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 4
- 239000004408 titanium dioxide Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 8
- 238000003860 storage Methods 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 6
- 239000011230 binding agent Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000003791 organic solvent mixture Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- 238000003756 stirring Methods 0.000 description 12
- DLZPQJDDVWPHNU-UHFFFAOYSA-N C(C)(=O)OC=C.OC=CCl Chemical compound C(C)(=O)OC=C.OC=CCl DLZPQJDDVWPHNU-UHFFFAOYSA-N 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- 238000001035 drying Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000004576 sand Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- -1 fluorine lipid Chemical class 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
Abstract
The invention discloses a special jet ink for PVC (polyvinyl chloride) cables, which consists of the following components by weight portions: 60-90 portions of organic solvent mixture, 5-12 portions of binder resin, 1-10 portions of colorant, 0.1-2.0 portions of plasticizer, 0.1-2.0 portions of adhesion promoter, 0.1-2.0 portions of surfactant, 0.2-5.0 portions of dispersing agent and 0.1-2.0 portions of conductance agent. The special jet ink for PVC cables disclosed by the invention is suitable for PVC substrate printing and has small particle size and good sprayability. The jet ink can quickly dry on the surface of the PVC substrate, having the advantages of stain resistance, scratch resistance, strong adhesion and good printing quality, printing stability, ink dryness and storage stability. The jet ink does not block the nozzle during printing and has good adhesion to PVC cables and good durability.
Description
(1) technical field
The present invention relates to the ink jet printing field, special-purpose code-spraying printing ink of particularly a kind of PVC cable and preparation method.
(2) background technology
After code-spraying printing ink is a kind of electric field action that receives between code jetting device shower nozzle and stock, can be ejected on the stock on request and produces the liquid ink of pictograph.Code-spraying printing ink requires nonchoking nozzle in course of injection, and is moist on nozzle wall, but spray printing can rapid drying and firm attachment to the base material, and anti-contamination can excellence with scoring resistance.
Spout stops up or the related patent U.S. Patent No. of tiltedly spraying problem has U.S. Pat 6726756, US7520926, US6444019, US6231654 or the like for overcoming, usually their solvent of adopting and resin system unusual costliness all.
For PVC cable surface spray printing, owing to contain a large amount of softening agent in the PVC CABLE MATERIALS, in use softening agent can be moved to cable surface gradually, thereby it is bad and not durable to cause printed patterns and PVC base material to adhere to.European patent EP 0314403 has been made relevant report about the problems referred to above that caused by softening agent, and this inkjet compositions has adopted a kind of amino acryloid cement resin of side that contains.Behind the spray printing, packaged finished cable often is in the higher environment of temperature in transportation or storage process, is prone to take place spray printing figure or coding migration between the cable surface that is in contact with one another, and causes press quality to reduce.Therefore, select the suitable binder resin, it is most important to solving this type of problem to give better binding property of ink film and weather resistance.
At present, because technical capacity is limit, domestic code-spraying printing ink all can not solve stifled nozzle simultaneously and well bond and competent problem with the PVC cable, has limited its application aspect the coding of PVC cable.
(3) summary of the invention
The present invention is directed to the problems referred to above special-purpose code-spraying printing ink of a kind of PVC cable and preparation method are provided, the not stifled nozzle of this printing ink, good, the good endurance of sticking power, making method is simple, easy handling.
The technical scheme that the present invention adopts is:
The present invention provides a kind of PVC cable special-purpose code-spraying printing ink; Form based on said code-spraying printing ink total raw material quality, said code-spraying printing ink is made up of following quality proportion raw material: 60 ~ 90 parts of organic solvent mixed solutions, 5 ~ 12 parts of adhesive resins, 1 ~ 10 part of tinting material, 0.1 ~ 2.0 part in softening agent, 0.1 ~ 2.0 part of adhesion promoter, 0.1 ~ 2.0 part in tensio-active agent, 0.2 ~ 5.0 part of dispersion agent and electricity are led 0.1 ~ 2.0 part of agent;
The organic solvent mixed solution adopts 3 types solvent system among the present invention; Wherein contain a kind of ink composite of giving at least and have the high volatile volatile solvent (organic solvent that boiling point is 50～100 ℃ of drying property preferably at substrate surface; Be organic solvent A) and a kind of low voc solvent (boiling point is 100～240 ℃ of organic solvents, i.e. organic solvent B), the rate of volatilization of control organic solvent mixed solution is less than 10s; In addition; Also contain and a kind ofly can produce the organic solvent of swelling and alligatoring effect substrate surface, i.e. organic solvent C, said thus organic solvent mixed solution is the mixing solutions of organic solvent A, organic solvent B and organic solvent C; Said organic solvent A is that boiling point is the mixing of 50～100 ℃ of one or more arbitrary proportions in the organic solvent; Form based on said code-spraying printing ink total raw material quality, said organic solvent A mass fraction is 55 ~ 85 parts, is preferably 60 ~ 80 parts (more preferably 61.5 ~ 75.5 parts); Said organic solvent B is that boiling point is the mixing of 100～240 ℃ of one or more arbitrary proportions in the organic solvent; Form based on said code-spraying printing ink total raw material quality; The mass fraction of said organic solvent B is 3 ~ 20 parts, and the mass fraction of said organic solvent B is preferably 4 ~ 18 parts; Said organic solvent C is a kind of in N-Methyl pyrrolidone, N-ethyl pyrrolidone, gamma-butyrolactone or the γ-Wu Neizhi, and preferred N-Methyl pyrrolidone is formed based on said code-spraying printing ink total raw material quality, and the mass fraction of said organic solvent C is 1 ~ 8 part; The present invention's's said " forming " implication based on said code-spraying printing ink total raw material quality be the mass parts unit mass of each material of the present invention all by total mass, promptly the mass parts unit mass of each material all equates.
Adhesive resin that adopts among the present invention and stock material surface have very strong magnetism; Can improve the sticking power of ink film to the stock surface; Give ink film certain rub resistance, said adhesive resin is hydroxyl vinyl chloride-vinyl acetate resin and the vinyl resin mixture with the ratio of mass ratio 1:1～7;
Tinting material among the present invention can be single pigment or solvent dye, also can be the compsn of pigment or solvent dye;
Said softening agent is the mixing of one or more arbitrary proportions among triethyl citrate, diethyl phthalate, DOP, softening agent
160 or the softening agent Rit-Cizer 8, the optimization citric acid triethyl;
Said adhesion promoter can be selected the mixing of one or more arbitrary proportions among Silquest A-1100, SilquestA-1200, Silquest A-187 or the Silquest A-186 of Momentive for use, preferred SilquestA-1100;
Said tensio-active agent can be selected the polyester modification YSR 3286 BYK of BYK-Chemicals for use
TM333, BYK
TM378 or BYK
TM388 or the fluorine fat FC of 3M
TM-4430, preferred fluorine lipid tensio-active agent FC
TM-4430;
It is one of following that said dispersion agent can be selected for use: Solsperse
TM24000 (Lubrizol Corp.), Solsperse
TM32500 (Lubrizol Corp.), Solsperse
TM36000 (Lubrizol Corp.), Solsperse
TMThe mixing of one or more arbitrary proportions among 38500 (Lubrizol Corp.), BYKJET-9130 (Bi Ke chemistry), BYKJET-9132 (Bi Ke chemistry) or the BYKJET-9133 (Bi Ke chemistry), preferred Solsperse
TM24000;
Said electricity is led the mixing that agent is one or more arbitrary proportions in trifluoromethanesulfonic acid lithium, acetic acid tetramethyl-ammonium, hydrochloric acid dimethyl amine or the hydrochloric acid dibutylamine, preferred trifluoromethanesulfonic acid lithium.
Softening agent according to the invention can be given ink film snappiness preferably, thereby improves the sticking power of ink film on PVC cable top layer to a certain extent.Said dispersion agent is that a kind of dissolving in maybe can be scattered in dispersant with high efficiency in the solvent, gives the good dispersiveness of pigment, flowability and stability in storage.Said tensio-active agent is polyester modification YSR 3286 or fluorine lipid.
Further, form based on said code-spraying printing ink total raw material quality, the mass fraction of said organic solvent A is preferably 60 ~ 80 parts (more preferably 61.5 ~ 75.5 parts).
Further, said organic solvent A is preferably the mixing of one or more arbitrary proportions in acetone, butanone, MIPK, ETHYLE ACETATE or the Iso Butyl Acetate, more preferably butanone.
Further, form based on said code-spraying printing ink total raw material quality, the mass fraction of said organic solvent B is preferably 4 ~ 18 parts.
Further; Said organic solvent B is preferably the mixing of one or more arbitrary proportions in cyclohexanone, diethylene glycol ether acetic ester, dipropylene glycol methyl ether acetate, 1-Methoxy-2-propyl acetate, propylene glycol monomethyl ether, Diethylene Glycol butyl ether or the n-Butyl lactate, more preferably 1-Methoxy-2-propyl acetate.
Further, form based on said code-spraying printing ink total raw material quality, the mass fraction of said organic solvent C is 2 ~ 5 parts (more preferably 2 ~ 4 parts).
Further, said organic solvent C is a kind of in N-Methyl pyrrolidone, N-ethyl pyrrolidone, gamma-butyrolactone or the γ-Wu Neizhi, more preferably N-Methyl pyrrolidone.
Further, hydroxyl vinyl chloride-vinyl acetate resin described in the said adhesive resin is vinyl chloride-vinyl acetate resin E22/48A, vinyl chloride-vinyl acetate resin E15/45M or vinyl chloride-vinyl acetate resin E15/45, preferred vinyl chloride-vinyl acetate resin E22/48A, and vinyl resin is vinyl resin Paraloid
TMB60, vinyl resin Paraloid
TMB66, vinyl resin Paraloid
TMB67, vinyl resin Paraloid
TMB66, vinyl resin B-60, vinyl resin B-66, vinyl resin BR-106, vinyl resin BR-73, vinyl resin 64/12N, vinyl resin LP64/11, vinyl resin 66/02 or vinyl resin BR-116, preferred acrylic resins BR-106.
Further; Pigment described in the said tinting material be white titanium pigment R-900, white titanium pigment R-902, carbon black 400R, carbon black M-L, carbon black
Black C-K,, carbon black
Black C-T or carbon black
Black C-A, one or both among preferred white titanium pigment R-900, carbon black 400R or carbon black
the Black C-K; Said solvent dye is solvent-borne type black dyes
Black RLI or solvent-borne type black dyes
Black CN, preferred solvent type black dyes
Black RLI.
Further; According to the invention based on the per 100 parts of code-spraying printing inks of said code-spraying printing ink total raw material quality, preferably be made up of following quality proportion raw material: 70 ~ 85 parts of organic solvent mixed solutions, 5 ~ 10 parts of adhesive resins, 2 ~ 8 parts of tinting materials, 0.5 ~ 1.5 part in softening agent, 0.2 ~ 1.0 part of adhesion promoter, 0.2 ~ 0.5 part in tensio-active agent, 0.5 ~ 3 part of dispersion agent and electricity are led 0.2 ~ 1.0 part of agent.
Preferably, form based on said code-spraying printing ink total raw material quality, the organic solvent mixed solution of said code-spraying printing ink is preferably 71.5 ~ 73.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates and 4 parts of N-Methyl pyrrolidone and forms.
Further; Code-spraying printing ink according to the invention is formed based on said code-spraying printing ink total raw material quality, and more preferably per 100 parts of code-spraying printing inks are made up of following quality proportion raw material: 81 ~ 87 parts of organic solvent mixed solutions, 8 parts of adhesive resins, 3 ~ 7 parts of tinting materials, 1 part in softening agent, 0.3 part of adhesion promoter, 0.2 part in tensio-active agent, 1 part of dispersion agent and electricity are led 1 part of agent.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 71.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 1 part of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 7 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine ester FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 71.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 2 parts of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 6 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 71.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 4 parts of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 4 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 73.5 parts of butanone, 4 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 1 part of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 7 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 69.5 parts of butanone, 8 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 1 part of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 7 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 61.5 parts of butanone, 18 parts of 1-Methoxy-2-propyl acetates, 2 parts of N-Methyl pyrrolidone, 1 part of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 7 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 73.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 2 parts of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 6 parts of vinyl resin BR-106,6 parts of carbon blacks
Black C-K, 1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 71.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 2 parts of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 6 parts of vinyl resin BR-106,7 parts of carbon black 400R, 1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
Further; Form based on said code-spraying printing ink total raw material quality, the special-purpose code-spraying printing ink of described per 100 parts of PVC cables preferably is made up of following quality proportion raw material: 75.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 2 parts of hydroxyl vinyl chloride-vinyl acetate resin E22/48A, 6 parts of vinyl resin BR-106,3 parts of solvent-borne type black dyess
Black RLI, 1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
The present invention also provides the preparation method of the special-purpose code-spraying printing ink of a kind of described PVC cable, and said method is: under the room temperature (20 ℃), the adhesive resin of prescription amount is dissolved with a small amount of organic solvent mixed solution; Process the adhesive resin mixed solution; Tinting material with the prescription amount dissolves with the organic solvent mixed solution that remains the prescription amount again, stirs, disperses, and processes the mixed solution of tinting material; At last the electricity of the dispersion agent of the tensio-active agent of the adhesion promoter of the softening agent of the mixed solution of above-mentioned adhesive resin mixed solution, tinting material and prescription amount, prescription amount, prescription amount, prescription amount and prescription amount being led agent mixes; Stir, the nanometer horizontal sand mill grinds, and filters; Get filtrating, promptly obtain the special-purpose code-spraying printing ink of said PVC cable.
The special-purpose code-spraying printing ink of PVC cable according to the invention is applied to the printing of PVC base material.
Compared with prior art; Beneficial effect of the present invention is mainly reflected in: the present invention has adopted a kind of vinyl chloride-vinyl acetate resin and vinyl resin blended adhesive resin that can produce mixed solvent and a kind of hydroxyl of alligatoring, swelling action to base material to prepare the special-purpose code-spraying printing ink of PVC cable; It is applicable to the printing of PVC base material, and granularity is little, has good spray property; In the rapid drying of PVC substrate surface ability; Anti-contamination, scratch resistance wound, strong adhesion in addition, also have good press quality, printing stability, ink setting property and stability in storage; In the coding process not blocking sprayer, good to PVC cable sticking power, weather resistance is good.
(4) embodiment
Below in conjunction with specific embodiment the present invention is described further, but protection scope of the present invention is not limited in this:
The mensuration of viscosity according to the invention adopts the DV-II+ type rotor viscosmeter of Bookfield company; Printing ink particle diameter and distribution are measured with Zetasizer3000 HAS Zeta potential nanometer laser particle size analyzer (Britain Malvern); Specific conductivity adopts the DDS-11A conductivitimeter to measure; Surface tension uses the KRUSS100 surface tension instrument to test.The volatility testing method: adopt the kapillary of 5 microlitres to get an amount of ink solutions sample, place watch-glass under the room temperature, the record sample solvent is the required time t of volatilization all
1Get the diethyl ether solution of equal quality again, test its volatilization required time t equally
0, calculate E=t
1/ t
0The E value is more little, shows that its volatilization time is short more, and quick-drying is good more.
Embodiment 1-3
Press the prescription of table 1, prepare the special-purpose code-spraying printing ink of PVC cable: after earlier butanone, 1-Methoxy-2-propyl acetate and N-Methyl pyrrolidone being pressed the mixing of prescription amount, process the organic solvent mixed solution through following method.Then vinyl chloride-vinyl acetate resin E22/84A of the hydroxyl of prescription amount (Germany watt digest) and vinyl resin BR-106 (Mitsubishi) are joined in the above-mentioned part organic solvent mixed solution; Room temperature (25 ℃) stirs, dissolving, makes the adhesive resin mixing solutions.Secondly, white titanium pigment R-900 (Dupont) is joined in the organic solvent mixed solution of residue prescription amount, room temperature (25 ℃) stirs, disperses, and makes the tinting material mixed solution.At last, above-mentioned adhesive resin mixed solution and tinting material mixed solution are at room temperature mixed, add triethyl citrate, Silquest A-1100 (U.S. steps figure), the Solsperse of prescription amount
TM24000 (U.S. Lu Borun), trifluoromethanesulfonic acid lithium and fluorine fat FC
TM-4430 (U.S. 3M), stirring, nanometer horizontal sand mill grind, filter, and get filtrating, promptly get the special-purpose code-spraying printing ink of PVC cable.And the special-purpose code-spraying printing ink of the PVC cable of above-mentioned preparation carried out performance tests such as surface tension, specific conductivity, viscosity, volatility and size, the result sees shown in the table 2.
Table 1 ink combination composition formula
Table 2 ink performance index
| Performance index | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Surface tension/dyn/cm | 26 | 27 | 29 |
| Specific conductivity/S/m | 0.13 | 0.12 | 0.12 |
| Viscosity/mPa.s (25 ℃) | 2.6 | 3.2 | 4.8 |
| Volatility/s | ＜3 | ＜3 | ＜3 |
| Particle diameter/nm | 100-200 | 100-200 | 100-200 |
Embodiment 4-6
Press the prescription of table 3, prepare the special-purpose code-spraying printing ink of PVC cable: after earlier butanone, 1-Methoxy-2-propyl acetate and N-Methyl pyrrolidone being pressed the mixing of prescription amount, process the organic solvent mixed solution through following method.Vinyl chloride-vinyl acetate resin E22/48A and vinyl resin BR-106 with the hydroxyl of prescription amount joins in the above-mentioned residue prescription amount organic liquid mixture then, and room temperature (25 ℃) stirs, dissolving, makes the adhesive resin mixing solutions.Secondly, white titanium pigment R-900 is joined in the mixed solvent of residue prescription amount, room temperature (25 ℃) stirs, disperses, and makes the tinting material mixed solution.At last, above-mentioned adhesive resin mixing solutions and tinting material mixed solution are at room temperature mixed, add triethyl citrate, Silquest A-1100, the Solsperse of prescription amount
TM24000, trifluoromethanesulfonic acid lithium and fluorine fat FC
TM-4430, stirring, nanometer horizontal sand mill grind, filter, and get filtrating, promptly get the special-purpose code-spraying printing ink of PVC cable.And the special-purpose code-spraying printing ink of the PVC cable of above-mentioned preparation carried out performance tests such as surface tension, specific conductivity, viscosity, volatility and size, the result sees shown in the table 4.
Table 3 ink combination composition formula
Table 4 ink performance index
| Performance index | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Surface tension/dyn/cm | 27 | 27 | 28 |
| Specific conductivity/μ S/cm | 0.11 | 0.11 | 0.12 |
| Viscosity/mPa.s (25 ℃) | 2.9 | 2.9 | 4.7 |
| Volatility/s | ＜3 | ＜6 | 10～50 |
| Particle diameter/nm | 100-200 | 100-200 | 100-200 |
Embodiment 7-9
Press the prescription of table 5, prepare the special-purpose code-spraying printing ink of PVC cable: after earlier butanone, 1-Methoxy-2-propyl acetate and N-Methyl pyrrolidone being pressed the mixing of prescription amount, process mixed solvent through following method.Vinyl chloride-vinyl acetate resin E22/48A and vinyl resin BR-106 with the hydroxyl of prescription amount adds in the above-mentioned part organic solvent mixed solution then, and stirring at room, dissolving make the adhesive resin mixing solutions.Secondly; Carbon black
Black C-K (German BASF-vapour crust) and/or carbon black 400R (U.S.'s Cabot chemical industry) and/or solvent-borne type black dyes
Black RLI (German BASF-vapour crust) are joined residue prescription amount organic solvent mixed solution; Stirring at room, dispersion make the tinting material mixed solution.At last, adhesive resin mixing solutions and tinting material mixed solution are mixed, add triethyl citrate, Silquest A-1100, Solsperse
TM24000, trifluoromethanesulfonic acid lithium and fluorine fat FC
TM-4430 auxiliary agents, wherein carbon black 400R needs the nanometer horizontal sand mill to be ground to required particle diameter (shown in the table 4), and carbon black
Black C-K and solvent-borne type black dyes
Black RLI only needs to stir fast and gets final product, and stirs, and through filtering, gets filtrating and promptly gets the special-purpose black code-spraying printing ink of PVC cable.And the special-purpose code-spraying printing ink of the PVC cable of above-mentioned preparation carried out performance tests such as surface tension, specific conductivity, viscosity, volatility and size, the result sees shown in the table 4.
Table 5 ink combination composition formula
Annotate: "-" expression does not have this component.
Table 6 ink performance index
| Performance index | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Surface tension/dyn/cm | 26 | 26 | 27 |
| Specific conductivity/μ S/cm | 0.11 | 0.11 | 0.13 |
| Viscosity/mPa.s (25 ℃) | 2.9 | 2.9 | 3.1 |
| Volatility/s | ＜3 | ＜3 | ＜4 |
| Particle diameter/nm | 200-230 | 100-200 | × |
Annotate: " * " expression particle diameter is not surveyed.
The special-purpose code-spraying printing ink compsn of the PVC cable of embodiment 1～9 preparation tested on Videojet 1710 code jetting devices (envrionment temperature: 25 ℃, humidity: 30～90%), the PVC base material is as stock, and testing method is a techniques well known.
Test result:
The special-purpose spray printing sizes of ink dots of the PVC cable of (1) press quality: embodiment 1～9 preparation is even, and writing is clear, color is true to nature, sticking power is excellent, scratch resistance wound, wear resistance are better.
(2) stability in storage: get the PVC cable ink special compsn of a certain amount of embodiment 1～9 preparation, be stored in the airtight vial, under 50 ℃, deposited for 12 weeks, measure ink composite and deposit front and back viscosity variation.Viscosity changed all less than 5 parts before and after embodiment 1～9 placed.
(3) printing stability: during spray printing was tested in continuous 12 hours, the PVC cable ink special that embodiment 1～9 prepares disconnected China ink occurred, assists the number of times that sprays, flies black phenomenon less than 3 times.
Through the special-purpose code-spraying printing ink of the foregoing description gained PVC cable, be applicable to the printing of PVC base material, granularity is little, has good spray property, at the rapid drying of PVC substrate surface ability, anti-contamination, scratch resistance wound, strong adhesion.In addition, also have good press quality, printing stability, ink setting property and stability in storage.
Claims (10)
1. the special-purpose code-spraying printing ink of a PVC cable; It is characterized in that forming based on said code-spraying printing ink total raw material quality, described code-spraying printing ink is made up of following quality proportion raw material: 60 ~ 90 parts of organic solvent mixed solutions, 5 ~ 12 parts of adhesive resins, 1 ~ 10 part of tinting material, 0.1 ~ 2.0 part in softening agent, 0.1 ~ 2.0 part of adhesion promoter, 0.1 ~ 2.0 part in tensio-active agent, 0.2 ~ 5.0 part of dispersion agent and electricity are led 0.1 ~ 2.0 part of agent;
Said organic solvent mixed solution is the mixing solutions of organic solvent A, organic solvent B and organic solvent C; Said organic solvent A is that boiling point is the mixing of 50～100 ℃ of one or more arbitrary proportions in the organic solvent; Form based on said code-spraying printing ink total raw material quality, the mass fraction of said organic solvent A is 55 ~ 85 parts; Said organic solvent B is that boiling point is the mixing of 100～240 ℃ of one or more arbitrary proportions in the organic solvent, forms based on said code-spraying printing ink total raw material quality, and the mass fraction of said organic solvent B is 3 ~ 20 parts; Said organic solvent C is the mixing of one or both arbitrary proportions in N-Methyl pyrrolidone, N-ethyl pyrrolidone, gamma-butyrolactone or the γ-Wu Neizhi, forms based on said code-spraying printing ink total raw material quality, and the mass fraction of said organic solvent C is 1 ~ 8 part;
Said adhesive resin is vinyl chloride-vinyl acetate resin and the vinyl resin of the hydroxyl mixture with mass ratio 1:1～7;
Said tinting material is pigment or solvent dye;
Said softening agent is the mixing of one or more arbitrary proportions among triethyl citrate, diethyl phthalate, DOP, softening agent
160 or the softening agent Rit-Cizer8;
Said adhesion promoter is the mixing of one or more arbitrary proportions among Silquest A-1100, Silquest A-1200, Silquest A-187 or the Silquest A-186;
Said tensio-active agent is fluorine fat FC
TM-4430, surfactant B YK
TM333, surfactant B YK
TM378 or surfactant B YK
TM388;
Said dispersion agent is Solsperse
TM24000, Solsperse
TM32500, Solsperse
TM36000, Solsperse
TM38500, the mixing of one or more arbitrary proportions among BYKJET-9130, BYKJET-9132 or the BYKJET-9133;
Said electricity is led the mixing that agent is one or more arbitrary proportions in trifluoromethanesulfonic acid lithium, acetic acid tetramethyl-ammonium, hydrochloric acid dimethyl amine or the hydrochloric acid dibutylamine.
2. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1 is characterized in that said organic solvent A is the mixing of one or more arbitrary proportions in acetone, butanone, MIPK, ETHYLE ACETATE or the Iso Butyl Acetate.
3. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1 is characterized in that said organic solvent B is the mixing of one or more arbitrary proportions in cyclohexanone, diethylene glycol ether acetic ester, dipropylene glycol methyl ether acetate, 1-Methoxy-2-propyl acetate, propylene glycol monomethyl ether, Diethylene Glycol butyl ether or the n-Butyl lactate.
4. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1 is characterized in that said organic solvent C is a kind of in N-Methyl pyrrolidone, N-ethyl pyrrolidone, gamma-butyrolactone or the γ-Wu Neizhi.
5. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1, the vinyl chloride-vinyl acetate resin that it is characterized in that hydroxyl described in the said adhesive resin is vinyl chloride-vinyl acetate resin E22/48A or vinyl chloride-vinyl acetate resin E15/45M, said vinyl resin is vinyl resin Paraloid
TMB60, vinyl resin Paraloid
TMB66, vinyl resin Paraloid
TMB67, vinyl resin B-60, vinyl resin B-66, vinyl resin BR-106, vinyl resin BR-73, vinyl resin 64/12N, vinyl resin LP64/11, vinyl resin 66/02 or vinyl resin BR-116.
As claimed in claim 1, wherein the PVC cable dedicated inkjet ink, wherein the colorant is a pigment of titanium dioxide R-900, titanium dioxide R-902, carbon 400R, black ML, black
Black? CK, black
Black? CT or carbon black
BlackC-A; said solvent is a solvent dye based black dye
Black? RLI or Solvent-based black dye
Black? CN.
7. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1; It is characterized in that forming based on said code-spraying printing ink total raw material quality, said code-spraying printing ink is made up of following quality proportion raw material: 70 ~ 85 parts of organic solvent mixed solutions, 5 ~ 10 parts of adhesive resins, 2 ~ 8 parts of tinting materials, 0.5 ~ 1.5 part in softening agent, 0.2 ~ 1.0 part of adhesion promoter, 0.2 ~ 0.5 part in tensio-active agent, 0.5 ~ 3 part of dispersion agent and electricity are led 0.2 ~ 1.0 part of agent.
8. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1; It is characterized in that forming based on said code-spraying printing ink total raw material quality, the organic solvent mixed solution of said code-spraying printing ink is 71.5 ~ 73.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates and 4 parts of N-Methyl pyrrolidone.
9. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1; It is characterized in that saidly based on said code-spraying printing ink total raw material quality, per 100 parts of code-spraying printing inks are made up of following quality proportion raw material: 71.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 1 part of vinyl chloride-vinyl acetate resin E22/48A, 7 parts of vinyl resin BR-106,7 parts of white titanium pigment R-900,1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of dispersion agent Solsperse
TM24000,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of tensio-active agent fluorine fat FC
TM-4430.
10. the special-purpose code-spraying printing ink of PVC cable as claimed in claim 1; It is characterized in that saidly based on said code-spraying printing ink total raw material quality, per 100 parts of code-spraying printing inks are made up of following quality proportion raw material: 73.5 parts of butanone, 6 parts of 1-Methoxy-2-propyl acetates, 4 parts of N-Methyl pyrrolidone, 2 parts of vinyl chloride-vinyl acetate resin E22/48A, 6 parts of vinyl resin BR-106,6 parts of carbon blacks
Black C-K, 1 part of triethyl citrate, 0.3 part of adhesion promoter Silquest A-1100,1 part of trifluoromethanesulfonic acid lithium and 0.2 part of fluorine fat FC
TM-4430.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103756411A (en) * | 2013-12-30 | 2014-04-30 | 杭州浙大海维特化工科技有限公司 | Special ink-jet printing ink for PVC (polyvinyl chloride) cable and preparation method |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN105348908A (en) * | 2015-12-02 | 2016-02-24 | 佛山市高明绿色德化工有限公司 | Metal color glass printing ink |
| CN105482554A (en) * | 2014-09-30 | 2016-04-13 | 广州光宝移动电子部件有限公司 | Conductive printing ink |
| CN113928034A (en) * | 2021-10-13 | 2022-01-14 | 石家庄沃佳玛智能科技有限公司 | Method for manufacturing scratch-resistant thermal transfer printing ribbon |
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| US6322620B1 (en) * | 2000-11-16 | 2001-11-27 | National Starch And Chemical Investment Holding Corporation | Conductive ink composition |
| CN1534069A (en) * | 2003-03-31 | 2004-10-06 | 上海乐丽喷印技术有限公司 | Formula of acrylic resin code spray ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6322620B1 (en) * | 2000-11-16 | 2001-11-27 | National Starch And Chemical Investment Holding Corporation | Conductive ink composition |
| CN1534069A (en) * | 2003-03-31 | 2004-10-06 | 上海乐丽喷印技术有限公司 | Formula of acrylic resin code spray ink |
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| CN103756411A (en) * | 2013-12-30 | 2014-04-30 | 杭州浙大海维特化工科技有限公司 | Special ink-jet printing ink for PVC (polyvinyl chloride) cable and preparation method |
| CN103756411B (en) * | 2013-12-30 | 2016-01-06 | 杭州海维特化工科技有限公司 | A kind of special code jetting device ink of PVC cable and preparation method |
| CN104151937A (en) * | 2014-07-07 | 2014-11-19 | 杭州海维特化工科技有限公司 | Special ink jet printing machine ink for PE optical cables and cables and preparation method of special ink jet printing machine ink for PE optical cables and cables |
| CN104151937B (en) * | 2014-07-07 | 2016-08-17 | 杭州海维特化工科技有限公司 | A kind of PE optical cable and cable special ink jet numbering machine ink and preparation method |
| CN105482554A (en) * | 2014-09-30 | 2016-04-13 | 广州光宝移动电子部件有限公司 | Conductive printing ink |
| CN105482554B (en) * | 2014-09-30 | 2018-12-28 | 广州光宝移动电子部件有限公司 | Electrically conductive ink |
| CN105348908A (en) * | 2015-12-02 | 2016-02-24 | 佛山市高明绿色德化工有限公司 | Metal color glass printing ink |
| CN113928034A (en) * | 2021-10-13 | 2022-01-14 | 石家庄沃佳玛智能科技有限公司 | Method for manufacturing scratch-resistant thermal transfer printing ribbon |
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