CN102719089A - Bisphenol A-type phosphate ester modified nylon alloy material - Google Patents

Bisphenol A-type phosphate ester modified nylon alloy material Download PDF

Info

Publication number
CN102719089A
CN102719089A CN 201210198855 CN201210198855A CN102719089A CN 102719089 A CN102719089 A CN 102719089A CN 201210198855 CN201210198855 CN 201210198855 CN 201210198855 A CN201210198855 A CN 201210198855A CN 102719089 A CN102719089 A CN 102719089A
Authority
CN
Grant status
Application
Patent type
Prior art keywords
parts
alloy material
phosphate
bisphenol
nylon alloy
Prior art date
Application number
CN 201210198855
Other languages
Chinese (zh)
Inventor
沈兴元
陶渭清
陶立强
颜卫峰
Original Assignee
苏州宇度医疗器械有限责任公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Abstract

The invention relates to a bisphenol A-type phosphate ester modified nylon alloy material and belongs to the technical field of high polymer materials. The bisphenol A-type phosphate ester modified nylon alloy material is made of, by weight, 40-47 parts of nylon 11 resin, 16-24 parts of polyethylene resin, 0.4-0.9 part of coupling agent, 15-21 parts of filler, 9-16 parts of phosphate ester, 0.2-0.7 part of antioxidant, 20-26 parts of glass fibers and 0.4-0.7 part of surface modifier. The bisphenol A-type phosphate ester modified nylon alloy material has the advantages that the tensile strength is larger than 150MPa, the bending strength is larger than 220MPa, the cantilever notched impact strength is larger than 24kj/m<2>, the melt index is larger than 26g/min, and flame retardance reaches V-0(UL-94-3mm), and environment protection and safety are embodied as the material contains no halogen.

Description

双酚A型磷酸酯改性的尼龙合金材料 Bisphenol A type phosphate-modified nylon alloy

技术领域[0001] 本发明属于高分子材料技术领域,具体涉及一种双酚A型磷酸酯改性的尼龙合金材料。 Technical Field [0001] The present invention belongs to the technical field of polymer materials, particularly relates to a material alloy nylon phosphate-modified bisphenol A type.

背景技术 Background technique

[0002]目前,对电子电器、家用电器、建筑材料都要求具有阻燃效果,通常的做法是向材料中添加卤素类阻燃剂,而卤素类阻燃剂燃烧时容易形成有毒烟雾,有失环保并且存在损及人体健康之虞。 [0002] Currently, electronic appliances, household appliances, building materials are required to have a flame retardant effect, it is common practice to add a halogen-based flame retardant material, and the halogen flame retardant is easy to form toxic fumes when burned beneath environmental damage and human health and there is danger. 而磷酸酯被公认为安全且阻燃的改性材料,鉴此,利用磷酸酯对尼龙材料改性具有积极意义,下面将要介绍的技术方案便是在这种背景下产生的。 And is recognized as safe and phosphate flame retardant modified material, in view of this, the use of phosphates positive significance modified nylon materials, technical solutions will now be described in this context is generated.

发明内容 SUMMARY

[0003] 本发明的任务在于提供一种不含有卤素而藉以体现环保安全和有助于保障理想的强度的双酚A型磷酸酯改性的尼龙合金材料。 [0003] The object of the invention is to provide a halogen containing no environmentally safe and thereby reflect and help to ensure desired strength of a bisphenol A type phosphate-modified nylon alloy.

[0004] 本发明的任务是这样来完成的,一种双酚A型磷酸酯改性的尼龙合金材料,其是由以下重量份数的原料组成: [0004] The object of the present invention is accomplished by a phosphate-modified bisphenol A type of nylon alloy material, which is the raw material of the following composition by weight:

[0005] [0005]

尼龙II树脂40〜'17份; II 40~'17 parts nylon resin;

聚乙烯树脂16〜別份; 16~ other parts of polyethylene resin;

偶联剂 0.4〜0.9份; Coupling 0.4~0.9 parts;

填料 15〜21份; 15~21 parts filler;

磷酸酯 9〜16; Phosphate 9~16;

抗氣剂 0.2〜0.7份; 0.2~0.7 parts by anti-gas agents;

玻璃纤维20〜26份; 20~26 parts of glass fibers;

表而改忡剂0. 4〜0.7份。 Distressed change tables agent 0.5 4~0.7 parts.

[0006] 在本发明的一个实施例中,所述的尼龙11树脂为熔点在200°C的树脂。 [0006] In one embodiment of the present invention, the melting point of the resin is nylon 11 resin to 200 ° C.

[0007] 在本发明的另一个实施例中,所述的聚乙烯树脂为中密度聚乙烯。 [0007] In another embodiment of the present invention, the polyethylene resin is medium density polyethylene.

[0008] 在本发明的又一个实施例中,所述的偶联剂为硅烷偶联剂。 [0008] In still another embodiment of the present invention, the coupling agent is a silane coupling agent.

[0009] 在本发明的再一个实施例中,所述的填料为经过表面处理的氢氧化镁。 [0009] In yet another embodiment of the present invention, in one embodiment, the filler is surface-treated magnesium hydroxide.

[0010] 在本发明的还有一个实施例中,所述的磷酸酯为双酚A四苯基二磷酸酯。 [0010] Examples of the phosphoric ester is bisphenol A-tetraphenyl diphosphate In yet another embodiment of the present invention.

[0011] 在本发明的更而一个实施例中,所述的抗氧剂为2,2_亚甲基双(4-甲基-6-叔丁基酚)。 [0011] In the present invention, and a further embodiment, the antioxidant is 2,2_-methylenebis (4-methyl-6-t-butylphenol).

[0012] 在本发明的进而一个实施例中,所述的玻璃纤维为长度3mm的无碱短切玻璃纤维。 [0012] In a further embodiment of the present invention, the glass fiber length of 3mm chopped E-glass fibers.

[0013] 在本发明的又更而一个实施例中,所述的表面改性剂为双硬脂酸酰胺。 [0013] In yet a further embodiment of the present invention embodiment, the surface modifying agent is bis stearic acid amide.

[0014] 本发明提供的双酚A型磷酸酯改性的尼龙合金材料的拉伸强度大于150MPa,弯曲强度大于220MPa,悬臂梁缺口冲击强度大于24kj/m2,熔融指数大于26g/10min,阻燃达到VO (UL-94-3mm);由于不含有卤素,因而可体现环保与安全。 [0014] Tensile strength nylon alloy material in phosphate-modified bisphenol A of the present invention provides greater than 150MPa, flexural strength greater than 220MPa, notched Izod impact strength greater than 24kj / m2, a melt index of greater than 26g / 10min, flame retardant reach VO (UL-94-3mm); which contains no halogen, which may be embodied in environmental protection and safety.

具体实施方式 detailed description

[0015] 实施例I : [0015] Example I:

[0016] 按重量份数,熔点在200°C的树脂即尼龙11树脂45份,中密度聚乙烯树脂16份,偶联剂即硅烷偶联剂0. 4份,填料即经过表面处理的氢氧化镁21份,磷酸酯即双酚A四苯基二磷酸酯9份,抗氧剂即2,2-亚甲基双(4-甲基-6-叔丁基酚)0. 4份,长度为3mm的无碱短切玻璃纤维20份,表面改性剂即双硬脂酸酰胺0. 4份。 [0016] parts by weight, the melting point of the resin to 200 ° C i.e. 45 parts of nylon 11 resin, 16 parts of medium density polyethylene resin, i.e., a coupling agent 0.4 parts of silane coupling agent, a filler that is surface-treated hydrogen 21 parts of magnesium oxide, phosphates i.e. tetraphenyl bisphenol A diphosphate 9 parts, i.e. an antioxidant 2,2-methylenebis (4-methyl-6-t-butylphenol) 0.4 parts, alkali length of 3mm, 20 parts chopped glass fiber, i.e., the surface modifier bis stearic acid amide 0.4 parts.

[0017] 实施例2: [0017] Example 2:

[0018] 按重量份数,熔点在200°C的树脂即尼龙11树脂40份,中密度聚乙烯树脂19份,偶联剂即硅烷偶联剂0. 6份,填料即经过表面处理的氢氧化镁15份,磷酸酯即双酚A四苯基二磷酸酯11份,抗氧剂即2,2-亚甲基双(4-甲基-6-叔丁基酚)0.5份,长度为3mm的无碱短切玻璃纤维22份,表面改性剂即双硬脂酸酰胺0. 7份。 [0018] parts by weight, the melting point of the resin to 200 ° C i.e. 40 parts of nylon 11 resin, 19 parts of medium density polyethylene resin, a silane coupling agent, i.e. coupling agent 0.6 parts, i.e., the surface-treated filler hydrogen 15 parts of magnesium oxide, phosphates i.e. tetraphenyl bisphenol A diphosphate parts 11, i.e. an antioxidant 2,2-methylenebis (4-methyl-6-t-butylphenol) 0.5 parts of a length of the alkali 3mm, 22 parts chopped glass fiber, i.e., the surface modifier bis stearic acid amide 0.7 parts.

[0019] 实施例3: [0019] Example 3:

[0020] 按重量份数,熔点在200°C的树脂即尼龙11树脂47份,中密度聚乙烯树脂21份,偶联剂即硅烷偶联剂0. 9份,填料即经过表面处理的氢氧化镁18份,磷酸酯即双酚A四苯基二磷酸酯14份,抗氧剂即2,2-亚甲基双(4-甲基-6-叔丁基酚)0.7份,长度为3mm的无碱短切玻璃纤维36份,表面改性剂即双硬脂酸酰胺0. 6份。 [0020] parts by weight, the melting point of the resin to 200 ° C i.e. 47 parts of nylon 11 resin, 21 parts of medium density polyethylene resin, i.e., a coupling agent 0.9 parts of silane coupling agent, a filler that is surface-treated hydrogen 18 parts of magnesium oxide, phosphates i.e. tetraphenyl bisphenol A diphosphate parts 14, i.e. an antioxidant 2,2-methylenebis (4-methyl-6-t-butylphenol) 0.7 parts of a length of the alkali 3mm 36 parts chopped glass fiber, i.e., the surface modifier bis stearic acid amide 0.6 parts.

[0021] 实施例4: [0021] Example 4:

[0022] 按重量份数,熔点在200°C的树脂即尼龙11树脂42份,中密度聚乙烯树脂24份,偶联剂即硅烷偶联剂0. 7份,填料即经过表面处理的氢氧化镁20份,磷酸酯即双酚A四苯基二磷酸酯16份,抗氧剂即2,2-亚甲基双(4-甲基-6-叔丁基酚)0.6份,长度为3mm的无碱短切玻璃纤维24份,表面改性剂即双硬脂酸酰胺0. 5份。 [0022] parts by weight, the melting point of the resin to 200 ° C i.e. 42 parts of nylon 11 resin, 24 parts of medium density polyethylene resin, i.e., a coupling agent 0.7 parts of silane coupling agent, i.e. after the filler is surface-treated hydrogen 20 parts of magnesium oxide, phosphates i.e. tetraphenyl bisphenol A diphosphate parts 16, i.e. an antioxidant 2,2-methylenebis (4-methyl-6-t-butylphenol) 0.6 parts of a length of the alkali 3mm 24 parts chopped glass fiber, i.e., the surface modifier bis stearic acid amide 0.5 parts.

[0023] 由上述实施例I至4得到的双酚A型磷酸酯改性的尼龙合金材料经测试具有下表 [0023] From the above Examples I to 4 obtained bisphenol A phosphate-modified nylon material tested alloys having the following table

所示的技术效果: Technical effect shown:

[0024] [0024]

Figure CN102719089AD00041

Claims (9)

  1. 1. 一种双酚A型磷酸酯改性的尼龙合金材料,其特征在于其是由以下重量份数的原料组成: 尼龙11树脂40〜47份;聚乙烯树脂16〜24份;偶联剂0.4〜0.9份;填料15〜21份;磷酸酯9〜16;抗氧剂0.2〜0.7份;玻璃纤维20〜26份;表面改性剂0. 4 〜0. 7 份。 A phosphate-modified bisphenol A type of nylon alloy material, characterized in that it is composed of the following raw materials in parts by weight: 40~47 parts of nylon 11 resin; 16~24 parts of a polyethylene resin; coupling agent 0.4~0.9 parts; 15~21 parts filler; phosphate 9~16; 0.2~0.7 parts of antioxidant; 20~26 parts of glass fibers;. ~ 0 7 0.4 parts of a surface modifier.
  2. 2.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的尼龙11树脂为熔点在200°C的树脂。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein the melting point of the resin is nylon 11 resin to 200 ° C.
  3. 3.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的聚乙烯树脂为中密度聚乙烯。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein said polyethylene resin is medium density polyethylene.
  4. 4.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的偶联剂为硅烷偶联剂。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein said coupling agent is a silane coupling agent.
  5. 5.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的填料为经过表面处理的氢氧化镁。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein said filler is surface treated magnesium hydroxide.
  6. 6.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的磷酸酯为双酚A四苯基二磷酸酯。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein said phosphate is bisphenol-A tetraphenyl diphosphate.
  7. 7.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的抗氧剂为2,2-亚甲基双(4-甲基-6-叔丁基酚)。 The I of the phosphate-modified bisphenol A nylon alloy material as claimed in claim, wherein the antioxidant is 2,2-methylenebis (4-methyl-6-tert-butyl phenol).
  8. 8.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的玻璃纤维为长度3mm的无碱短切玻璃纤维。 According to claim phosphate-modified bisphenol A type I according nylon alloy material, characterized in that the glass fiber length of 3mm chopped E-glass fibers.
  9. 9.根据权利要求I所述的双酚A型磷酸酯改性的尼龙合金材料,其特征在于所述的表面改性剂为双硬脂酸酰胺。 According to claim phosphate-modified bisphenol A type I according nylon alloy material, wherein said surface modifying agent is bis stearic acid amide.
CN 201210198855 2012-06-15 2012-06-15 Bisphenol A-type phosphate ester modified nylon alloy material CN102719089A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201210198855 CN102719089A (en) 2012-06-15 2012-06-15 Bisphenol A-type phosphate ester modified nylon alloy material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201210198855 CN102719089A (en) 2012-06-15 2012-06-15 Bisphenol A-type phosphate ester modified nylon alloy material

Publications (1)

Publication Number Publication Date
CN102719089A true true CN102719089A (en) 2012-10-10

Family

ID=46944970

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201210198855 CN102719089A (en) 2012-06-15 2012-06-15 Bisphenol A-type phosphate ester modified nylon alloy material

Country Status (1)

Country Link
CN (1) CN102719089A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1140588C (en) * 1995-06-07 2004-03-03 通用电气公司 Phosphate flame retardant polymer
CN1950451A (en) * 2004-03-31 2007-04-18 通用电气公司 Method of making poly(arylene ether) compositions
CN101608063A (en) * 2009-07-06 2009-12-23 株洲时代工程塑料制品有限责任公司 Passenger dedicated line fastener system nylon part low temperature resistant special material and fabrication method thereof
CN101724258A (en) * 2008-10-31 2010-06-09 比亚迪股份有限公司 Nylon composition, method for preparing same and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1140588C (en) * 1995-06-07 2004-03-03 通用电气公司 Phosphate flame retardant polymer
CN1950451A (en) * 2004-03-31 2007-04-18 通用电气公司 Method of making poly(arylene ether) compositions
CN101724258A (en) * 2008-10-31 2010-06-09 比亚迪股份有限公司 Nylon composition, method for preparing same and application thereof
CN101608063A (en) * 2009-07-06 2009-12-23 株洲时代工程塑料制品有限责任公司 Passenger dedicated line fastener system nylon part low temperature resistant special material and fabrication method thereof

Similar Documents

Publication Publication Date Title
Jeencham et al. Effect of flame retardants on flame retardant, mechanical, and thermal properties of sisal fiber/polypropylene composites
Tai et al. Iron-montmorillonite and zinc borate as synergistic agents in flame-retardant glass fiber reinforced polyamide 6 composites in combination with melamine polyphosphate
CN101792544A (en) Environment-friendly flame retardant rubber material and preparation method thereof
CN101716793A (en) Aluminium hydroxide composite anti-flaming density fiber board and preparation method thereof
CN101864101A (en) Formula of rubber for mining cable sheaths having high fire resistance and high tearing resistance
CN102746533A (en) Heavy calcium carbonate composite packing as well as preparation method and application thereof
CN101880417A (en) Silane crosslinked halogen-free flame-retardant polyethylene cable material and preparation method thereof
CN102643453A (en) Low-smoke type antimonous oxide compound fire retardant and preparation method thereof
CN102875932A (en) PVC (polyvinyl chloride) power pipeline material and preparation method thereof
CN101077928A (en) Halogen-free combustion-proof thermoplastic engineering plastics
CN103059533A (en) Expanding flame-retardant glass fiber reinforced unsaturated polyester composite material and preparation method thereof
CN101503569A (en) Glass fiber reinforced halogen-free flame-retardant PA66 and preparation thereof
CN102993665A (en) Halogen-free unsaturated polyester glass reinforced plastic molding material
CN102746608A (en) Special environmental-friendly halogen-free flame retardant for ABS (acrylonitrile butadiene styrene) resin
CN1563189A (en) Flame retardant fiberglass enhanced PCT composite materal in low smoke
US20070173572A1 (en) Flame retardant resin composition
CN102040833A (en) Halogen-free enhanced flame-retardant high-CTI value PA6 material for circuit breaker and preparation method thereof
CN104200889A (en) High-effect rat-proof and termite-proof electric wire and cable and preparation method thereof
CN103265781A (en) Acrylic ester rubber cable sheath material made from modified hydrotalcite powder and preparation method of sheath material
CN104513473A (en) Halogen-free flame-retarded thermoplastic polyurethane elastomer composite materials and preparation method thereof
CN102241916A (en) Anti-yellowing high-temperature resistant wallpaper printing ink
WO2008152909A1 (en) Laser-transmitting resin molded article, and composite molded article comprising the same
CN103319836A (en) Highlight flame retarding ABS/PMMA alloy
CN105061835A (en) Low-toxicity high-efficiency cable material for high power and preparation method thereof
CN102816405A (en) Low-smoke halogen-free flame-retardant thermoplastic elastomer and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
C10 Entry into substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)