CN102687717B - Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination - Google Patents
Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination Download PDFInfo
- Publication number
- CN102687717B CN102687717B CN 201210194268 CN201210194268A CN102687717B CN 102687717 B CN102687717 B CN 102687717B CN 201210194268 CN201210194268 CN 201210194268 CN 201210194268 A CN201210194268 A CN 201210194268A CN 102687717 B CN102687717 B CN 102687717B
- Authority
- CN
- China
- Prior art keywords
- weedicide
- parts
- auxiliary agent
- herbicidal combinations
- weighing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a use method of a weeding composition containing a herbicide adjuvant, especially the use method of the weeding composition. The invention provides the use method of the weeding composition containing the herbicide adjuvant, and solves the problems of low average plant control effect and lower average fresh weight control effect of the prior herbicide. The use method comprises: spraying and using the weeding composition containing the herbicide adjuvant with an amount according to the 200-250mL/Mu. The invention is mainly used for the weeding composition containing the herbicide adjuvant.
Description
Technical field
The present invention relates to a kind of using method of Herbicidal combinations.
Background technology
For a long time, the processing of domestic pesticidal preparations is widely used " triphen " (benzene,toluene,xylene) as solvent, take DMF (DMF) etc. as cosolvent.This class organic solvent is very big to people, animal and environmental hazard, bans use of in developed country.
Benzene is a kind of colourless liquid mixture with aromatic odor, belongs to inflammable, explosive hazardous chemical.Chronic poisoning can occur in Long Term Contact, even causes leukemia.The World Health Organization was defined as carcinogenic substance with it in 1993.
Toluene approximately 48% participates in metabolism after entering human body in vivo, through liver, brain, lung and kidney, excretes at last.In this process, can produce harm to nervous system.
Dimethylbenzene comprises ortho position, a position and three kinds of isomer of contraposition, and is maximum with a position proportion, can reach 60～70%, and the contraposition proportion is minimum.Dimethylbenzene can absorb through respiratory tract, skin and digestive tract, and its steam enters human body through respiratory tract, and a part is discharged through respiratory tract, the dimethylbenzene of absorption distribute in vivo with in adipose tissue and the suprarenal gland at most, after be followed successively by marrow, brain, blood, kidney and liver.It is reported, three workman's inhaled concentrations are 43.1g/m
3Dimethylbenzene, after 18.5 hours, a people is dead, the visible pulmonary venous pleonaemia of postmortem and cerebral hemorrhage, two people lose one's senses and reach 19～24 hours in addition, with the loss of memory and change in renal function.In addition, the dimethylbenzene that sucks high concentration can make loss of appetite, feel sick, vomits and stomachache, sometimes can cause the damage of liver kidney invertibity.Dimethylbenzene also is a kind of anaesthetic simultaneously, and Long Term Contact can make nervous function disorderly.
DMF (DMF) SK can be by sucking, eat, entering human body through approach such as skin absorptions.Acute poisoning performance has eye and upper respiratory tract irritation, headache, anxiety, nauseating, vomiting, stomachache, constipation etc.Generally after a few days of poisoning, jaundice can appear to hepatic lesion in liver enlargement, pain in the hepatic region.Through the skin absorber, bubble, coarse, mono-anesthesia, itch, cusalgia appear in skin.The Chronic Effect main manifestations has skin, mucous membrane irritation, neurasthenia syndrome, and blood pressure is on the low side.Nauseating, vomiting, uncomfortable in chest, poor appetite, stomachache, constipation and changes of liver function etc. are still arranged.DMF all has to a certain degree infringement to the reproductive function of humans and animals.
Summary of the invention
The invention provides a kind of using method that contains the Herbicidal combinations of auxiliary agent of weedicide, solve average strain preventive effect and the low problem of mean fresh preventive effect of existing weed killer herbicide.
Auxiliary agent of weedicide of the present invention is comprised of 10～60 parts organic silicon surfactant, 10～80 parts soybean oil and other auxiliary agent of 10～90 parts by weight, and described other auxiliary agent is the combination of any two or three in styryl phenylol APEO, fatty alcohol-polyoxyethylene ether and the calcium dodecyl benzene sulfonate.
Wherein said organic silicon surfactant is Silwet408, is based on the non-ionic surface active agent of alkoxy-modified poly-trisiloxanes.
The Herbicidal combinations that contains above-mentioned auxiliary agent of weedicide by weight by 20～90 parts Acetochlor, 1～20 part the piperazine humulone, 5～40 parts 2,4-d butyl ester, 10～40 parts auxiliary agent of weedicide and 5～20 parts turpentine-based vegetable oil form.
The preparation method of the above-mentioned Herbicidal combinations that contains auxiliary agent of weedicide, carry out according to the following steps:
One, take by weighing by weight 20～90 parts Acetochlor, 1～20 part the piperazine humulone, 5～40 parts 2,4-d butyl ester, 10～40 parts auxiliary agent of weedicide and 5～20 parts turpentine-based vegetable oil;
Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 30～60min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide.
The application that contains the Herbicidal combinations of auxiliary agent of weedicide of the present invention is that the Herbicidal combinations that will contain auxiliary agent of weedicide is used for Soybean Field sealing weeding.
Auxiliary agent of weedicide of the present invention can obviously improve preventive effect and the safety of Herbicidal combinations, and this auxiliary agent of weedicide is easy to biological degradation, edaphon is had no adverse effects, to people and ecological environment security.Herbicidal combinations of the present invention adopts turpentine-based vegetable oil to make solvent, by the effect of organic silicon surfactant, makes the active ingredient quick humidification crop of weed killer herbicide, improve the penetration of weed killer herbicide, can make medicine reach fast target, thereby significantly improve drug effect, can reduce the weed killer herbicide consumption simultaneously.Herbicidal combinations is suitable for the multiple formulations such as missible oil, microemulsion, aqueous emulsion, suspension emulsion.Because the solvent for use turpentine-based vegetable oil has replaced " triphen " light aromatics kind solvent, waste, preserve the ecological environment significant for reducing non-renewable resources.
Auxiliary agent of weedicide of the present invention and Herbicidal combinations using method are simple, and cost is low, are easy to apply, and for preserving the ecological environment, reduce the non-renewable resources waste significant.
Embodiment
Embodiment one: the auxiliary agent of weedicide of present embodiment is comprised of 10～60 parts organic silicon surfactant, 10～80 parts soybean oil and other auxiliary agent of 10～90 parts by weight, and described other auxiliary agent is the combination of any two or three in styryl phenylol APEO, fatty alcohol-polyoxyethylene ether and the calcium dodecyl benzene sulfonate.
Present embodiment is when the combination of any two or three in styryl phenylol APEO, fatty alcohol-polyoxyethylene ether and the calcium dodecyl benzene sulfonate in other auxiliary agent, by arbitrarily than making up.
The auxiliary agent of weedicide of present embodiment can obviously improve preventive effect and the safety of Herbicidal combinations, and this auxiliary agent of weedicide is easy to biological degradation, edaphon is had no adverse effects, to people and ecological environment security.By the effect of organic silicon surfactant in the auxiliary agent of weedicide, make the active ingredient quick humidification crop of weed killer herbicide, improve the penetration of weed killer herbicide, can make medicine reach fast target, thereby significantly improve drug effect, can reduce the weed killer herbicide consumption simultaneously.
Embodiment two: what present embodiment and embodiment one were different is that described organic silicon surfactant is Silwet408.Other is identical with embodiment one.
Organic silicon surfactant Silwet408 is based on the non-ionic surface active agent of alkoxy-modified poly-trisiloxanes.Be the commercially available prod.
Embodiment three: present embodiment is different from embodiment one or two is that the auxiliary agent of weedicide of present embodiment is comprised of 20～50 parts organic silicon surfactant, 20～60 parts soybean oil and other auxiliary agent of 20～70 parts by weight.Other is identical with embodiment one or two.
Embodiment four: present embodiment is different from embodiment one or two is that the auxiliary agent of weedicide of present embodiment is comprised of 30 parts organic silicon surfactant, 40 parts soybean oil and other auxiliary agent of 50 parts by weight.Other is identical with embodiment one or two.
Embodiment five: present embodiment is different from embodiment one or two is that the auxiliary agent of weedicide of present embodiment is comprised of 40 parts organic silicon surfactant, 45 parts soybean oil and other auxiliary agent of 45 parts by weight.Other is identical with embodiment one or two.
Embodiment six: the Herbicidal combinations that contains embodiment one described auxiliary agent of weedicide by weight by 20～90 parts Acetochlor, 1～20 part the piperazine humulone, 5～40 parts 2,4-d butyl ester, 10～40 parts embodiment one described auxiliary agent of weedicide and 5～20 parts turpentine-based vegetable oil form.
The described Herbicidal combinations that contains auxiliary agent of weedicide of present embodiment, Herbicidal combinations of the present invention adopts turpentine-based vegetable oil to make solvent, effect by organic silicon surfactant, make the active ingredient quick humidification crop of weed killer herbicide, improve the penetration of weed killer herbicide, can make medicine reach fast target, thereby significantly improve drug effect, can reduce the weed killer herbicide consumption simultaneously.Herbicidal combinations is suitable for the multiple formulations such as missible oil, microemulsion, aqueous emulsion, suspension emulsion, because the solvent for use turpentine-based vegetable oil has replaced " triphen " light aromatics kind solvent, wastes, preserves the ecological environment significant for reducing non-renewable resources.The Herbicidal combinations using method of the auxiliary agent of weedicide of present embodiment is simple, and cost is low, is easy to apply.
Embodiment seven: present embodiment and embodiment six are different be contain auxiliary agent of weedicide Herbicidal combinations by weight by 30～80 parts Acetochlor, 5～15 parts the piperazine humulone, 10～35 parts 2,4-d butyl ester, 15～35 parts embodiment one described auxiliary agent of weedicide and 12～18 parts turpentine-based vegetable oil form.
Embodiment eight: present embodiment and embodiment six are different be contain auxiliary agent of weedicide Herbicidal combinations by weight by 50 parts Acetochlor, 10 parts the piperazine humulone, 20 parts 2,4-d butyl ester, 20 parts embodiment one described auxiliary agent of weedicide and 15 parts turpentine-based vegetable oil form.
Embodiment nine: the embodiment six described preparation methods that contain the Herbicidal combinations of auxiliary agent of weedicide, carry out according to the following steps: one, take by weighing by weight 20～90 parts Acetochlor, 1～20 part the piperazine humulone, 5～40 parts 2,4-d butyl ester, 10～40 parts auxiliary agent of weedicide and 10～20 parts turpentine-based vegetable oil; Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 30～60min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide.
The Herbicidal combinations that contains auxiliary agent of weedicide of present embodiment preparation, adopt turpentine-based vegetable oil to make solvent, effect by organic silicon surfactant, make the active ingredient quick humidification crop of weed killer herbicide, improve the penetration of weed killer herbicide, can make medicine reach fast target, thereby significantly improve drug effect, can reduce the weed killer herbicide consumption simultaneously.Herbicidal combinations is suitable for the multiple formulations such as missible oil, microemulsion, aqueous emulsion, suspension emulsion.Because the solvent for use turpentine-based vegetable oil has replaced " triphen " light aromatics kind solvent, waste, preserve the ecological environment significant for reducing non-renewable resources.The Herbicidal combinations using method that contains auxiliary agent of weedicide of present embodiment is simple, and cost is low, is easy to apply.
Embodiment ten: the embodiment six described application that contain the Herbicidal combinations of auxiliary agent of weedicide are that the Herbicidal combinations that will contain auxiliary agent of weedicide is used for Soybean Field sealing weeding.
With following verification experimental verification beneficial effect of the present invention:
Test one: the auxiliary agent of weedicide of this test one is comprised of 30 parts organic silicon surfactant, 20 parts soybean oil and 10 parts styryl phenylol APEO and 10 parts fatty alcohol-polyoxyethylene ether by weight.
The Herbicidal combinations that contains above-mentioned auxiliary agent of weedicide by weight by 40 parts Acetochlor, 5 parts the piperazine humulone, 15 parts 2,4-d butyl ester, 35 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil form.
The preparation method of the above-mentioned Herbicidal combinations that contains auxiliary agent of weedicide, carry out according to the following steps:
One, take by weighing by weight 40 parts Acetochlor, 5 parts the piperazine humulone, 15 parts 2,4-d butyl ester, 35 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil;
Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 40min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide.
According to " liquid preparation sampling " sampling among the GB/T1605-2003 " the commercially available agricultural chemical method of sampling ", according to Q/HLN006-2009 " 60% ethysine d butyl ester company standard " emulsion stability, moisture, pH value, heat storage stability, the low-temperature stability of the Herbicidal combinations that contains auxiliary agent of weedicide of this test preparation are tested.Assay sees Table 1.
The project examination table of the Herbicidal combinations that contains auxiliary agent of weedicide of this test of table 1 preparation
The field control effectiveness test method of the Herbicidal combinations that contains auxiliary agent of weedicide of this test preparation is field trial residential quarter pairing method.Randomised block design is adopted in test, establishes 5 processing, repeats for 4 times.Supplying to test crop is corn.Stubble is soybean experimental field, belongs to brunisolic soil, and soil pH value is 7.1, and the content of organic matter is 2.3%.Dispenser in 7 days behind corn seeding.Adopt artificial knapsack sprayer, weed killer herbicide is watered 30 kilograms by different formulation rates, and with the weed killer herbicide of usual vehicle methyl alcohol and blank as contrast, 30 days investigation preventive effects after the medication.Its preventive effect is the results detailed in Table 2.The used data acquisition of table 2 is from agriculture chemical registration try net member unit of the national Ministry of Agriculture---Heilongjiang Province's agricultural chemicals management calibrating station.
The weed killer herbicide field efficacy application form of table 2 test one preparation
Can find out from table 2 result of the test, the weed killer herbicide of this test sprays use by the consumption of 200-250mL/ mu, and its preventive effect is apparently higher than the weed killer herbicide that contains usual vehicle methyl alcohol.
The auxiliary agent of weedicide of this test one preparation and the Herbicidal combinations that contains this auxiliary agent of weedicide have not only increased the safety to crop, people and animals and environment, and have improved the performance of weed killer herbicide, thereby improved herbicidal effect.
Test two: the auxiliary agent of weedicide of this test two is comprised of 40 parts organic silicon surfactant, 40 parts soybean oil and 20 parts styryl phenylol APEO and 20 parts calcium dodecyl benzene sulfonate by weight.
The Herbicidal combinations that contains above-mentioned auxiliary agent of weedicide by weight by 43 parts Acetochlor, 5 parts the piperazine humulone, 17 parts 2,4-d butyl ester, 30 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil form.
The preparation method of the above-mentioned Herbicidal combinations that contains auxiliary agent of weedicide, carry out according to the following steps:
One, take by weighing by weight 43 parts Acetochlor, 5 parts the piperazine humulone, 17 parts 2,4-d butyl ester, 30 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil;
Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 50min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide.
According to " liquid preparation sampling " sampling among the GB/T1605-2003 " the commercially available agricultural chemical method of sampling ", according to Q/HLN006-2009 " 60% ethysine d butyl ester company standard " emulsion stability, moisture, pH value, heat storage stability, the low-temperature stability of the Herbicidal combinations that contains auxiliary agent of weedicide of this test preparation are tested.Assay sees Table 3.
The project examination table of the Herbicidal combinations that contains auxiliary agent of weedicide of this test of table 3 preparation
The field control effectiveness test method of the Herbicidal combinations that contains auxiliary agent of weedicide of this test preparation is field trial residential quarter pairing method.Randomised block design is adopted in test, establishes 5 processing, repeats for 4 times.Supplying to test crop is corn.Stubble is soybean experimental field, belongs to brunisolic soil, and soil pH value is 7.1, and the content of organic matter is 2.3%.Dispenser in 7 days behind corn seeding.Adopt artificial knapsack sprayer, weed killer herbicide is watered 30 kilograms by different formulation rates, and with the weed killer herbicide of usual vehicle methyl alcohol and blank as contrast, 30 days investigation preventive effects after the medication.Its preventive effect is the results detailed in Table 4.The used data acquisition of table 4 is from agriculture chemical registration try net member unit of the national Ministry of Agriculture---Heilongjiang Province's agricultural chemicals management calibrating station.
The weed killer herbicide field efficacy application form of table 4 test two preparations
Claims (4)
1. using method that contains the Herbicidal combinations of auxiliary agent of weedicide, the using method that it is characterized in that containing the Herbicidal combinations of auxiliary agent of weedicide is to finish according to the following steps; The Herbicidal combinations of auxiliary agent of weedicide sprays use by the consumption of 200-250mL/ mu; The Herbicidal combinations of described auxiliary agent of weedicide prepares by following operation: one, take by weighing by weight 40 parts Acetochlor, 5 parts the piperazine humulone, 15 parts 2,4-d butyl ester, 35 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil; Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 40min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide; Wherein said auxiliary agent of weedicide is comprised of 30 parts organic silicon surfactant, 20 parts soybean oil and 10 parts styryl phenylol APEO and 10 parts fatty alcohol-polyoxyethylene ether by weight.
2. a kind of using method that contains the Herbicidal combinations of auxiliary agent of weedicide according to claim 1 is characterized in that described organic silicon surfactant is Silwet408.
3. using method that contains the Herbicidal combinations of auxiliary agent of weedicide, the using method that it is characterized in that containing the Herbicidal combinations of auxiliary agent of weedicide is to finish according to the following steps; The Herbicidal combinations of auxiliary agent of weedicide sprays use by the consumption of 200-250mL/ mu; The Herbicidal combinations of described auxiliary agent of weedicide prepares by following operation: one, take by weighing by weight 43 parts Acetochlor, 5 parts the piperazine humulone, 17 parts 2,4-d butyl ester, 30 parts auxiliary agent of weedicide and 5 parts turpentine-based vegetable oil; Two, the Acetochlor that step 1 is taken by weighing, piperazine humulone, 2,4-d butyl ester and turpentine-based vegetable oil join in the reactor, after stirring, again under stirring, add the auxiliary agent of weedicide that step 1 takes by weighing, continue to stir 50min, obtain containing the Herbicidal combinations of auxiliary agent of weedicide; Wherein said auxiliary agent of weedicide is comprised of 40 parts organic silicon surfactant, 40 parts soybean oil and 20 parts styryl phenylol APEO and 20 parts fatty alcohol-polyoxyethylene ether by weight.
4. a kind of using method that contains the Herbicidal combinations of auxiliary agent of weedicide according to claim 3 is characterized in that described organic silicon surfactant is Silwet408.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210194268 CN102687717B (en) | 2012-06-13 | 2012-06-13 | Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210194268 CN102687717B (en) | 2012-06-13 | 2012-06-13 | Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102687717A CN102687717A (en) | 2012-09-26 |
| CN102687717B true CN102687717B (en) | 2013-10-23 |
Family
ID=46853603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210194268 Active CN102687717B (en) | 2012-06-13 | 2012-06-13 | Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102687717B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102885042A (en) * | 2012-10-30 | 2013-01-23 | 哈尔滨利民农化技术有限公司 | Environment-friendly potato field weeding combination |
| CN104970026B (en) * | 2015-06-08 | 2016-05-18 | 河北中天邦正生物科技股份公司 | A kind of herbicidal composition and uses thereof |
| CN105076132B (en) * | 2015-06-11 | 2017-07-18 | 中国农业大学 | A kind of oil type agricultural chemicals synergist and preparation method thereof |
| CN112075450A (en) * | 2020-09-25 | 2020-12-15 | 河南豫松环保科技有限公司 | Novel herbicide and preparation method thereof |
| CN113951282A (en) * | 2021-08-26 | 2022-01-21 | 黑龙江八一农垦大学 | Environment-friendly herbicide containing plant components and preparation method and application thereof |
| CN114467961A (en) * | 2021-12-22 | 2022-05-13 | 张家口市农业科学院(河北省高寒作物研究所) | Synergistic herbicide rich in organic silicon and vegetable oil auxiliary agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101589714A (en) * | 2009-06-18 | 2009-12-02 | 浙江省农业科学院 | A kind of pesticide synergistic agent and preparation method thereof |
| CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
| CN101984807A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Missible oil preparation using turpentine-based vegetable oil as solvent and preparation method thereof |
-
2012
- 2012-06-13 CN CN 201210194268 patent/CN102687717B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101589714A (en) * | 2009-06-18 | 2009-12-02 | 浙江省农业科学院 | A kind of pesticide synergistic agent and preparation method thereof |
| CN101984809A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Oil suspension preparation using resin-based vegetable oil as carrier and preparation method thereof |
| CN101984807A (en) * | 2010-07-22 | 2011-03-16 | 福建诺德生物科技有限责任公司 | Missible oil preparation using turpentine-based vegetable oil as solvent and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 有机硅表面活性剂和甲基化植物油的复配及在除草剂上应用的研究;赵培侠;《河南省化学会2010年学术年会论文摘要集》;20101231;第1-2段 * |
| 王金信等.除草剂助剂的研究进展.《世界农药》.2008,第30卷(第1期),34-39. |
| 赵培侠.有机硅表面活性剂和甲基化植物油的复配及在除草剂上应用的研究.《河南省化学会2010年学术年会论文摘要集》.2010, |
| 除草剂助剂的研究进展;王金信等;《世界农药》;20080228;第30卷(第1期);34-39 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102687717A (en) | 2012-09-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102687717B (en) | Herbicide adjuvant, weeding combination containing same, as well as preparation method and application of weeding combination | |
| CN102805100B (en) | Herbicide capable of reducing resistance of glyphosate | |
| CN103210916B (en) | Agricultural thickening synergistic agent and glufosinate solution prepared from same | |
| CN102326551B (en) | Weeding composition containing diflufenican | |
| CN101856029A (en) | Pesticide combination containing etoxazole and abamectin | |
| CN106550951A (en) | A kind of Herbicidal combinations and application containing diquat dibromide and trichlopyr | |
| CN104186514A (en) | Pesticide composition containing cyhalodiamide | |
| CN104365658B (en) | A kind of compound synergic herbicide and preparation technology thereof | |
| CN101849556B (en) | Plant source synergistic complex acaricide and preparation method thereof | |
| CN102224830A (en) | Plant source synergistic complex acaricide and preparation method thereof | |
| CN107582943A (en) | A kind of herbal mixture transdermal spray agent for preventing and treating animal psoroptic mange and preparation method | |
| CN102217633B (en) | Pesticide composition containing sulfoxaflor | |
| CN101843268A (en) | Botanical synergistic compound aphicide and preparation method thereof | |
| CN107361069A (en) | A kind of Synergistic herbicide compositions | |
| CN109833296A (en) | Can the new merit chigger disease of prevention and control plants essential oil microemulsion formulation and preparation method thereof | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN102283231B (en) | Oil suspending agent composition containing nicosulfuron and fluroxypyr | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN103548884B (en) | Chinese pistache kills Tetranychus cinnabarinus agent and preparation method thereof | |
| CN104920396A (en) | Weeding composition containing pinoxaden and pyraflufen-ethyl | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN101856034A (en) | Pesticide composition containing etoxazole and fenpropathrin | |
| CN106818794A (en) | A kind of miticide composition containing doractin and fenazaquin | |
| CN101049104B (en) | Composite composition of 0.1 % micellar emulsion of cantharidin | |
| CN106342813A (en) | Mixture herbicide containing imazapic and lactofen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |