CN102683742A - Lithium ion battery cell and preparation method thereof - Google Patents

Lithium ion battery cell and preparation method thereof Download PDF

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CN102683742A
CN102683742A CN2012101919635A CN201210191963A CN102683742A CN 102683742 A CN102683742 A CN 102683742A CN 2012101919635 A CN2012101919635 A CN 2012101919635A CN 201210191963 A CN201210191963 A CN 201210191963A CN 102683742 A CN102683742 A CN 102683742A
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diaphragm
negative electrode
positive electrode
electrode sheet
separator
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汪云龙
李聪
何平
张柏清
方宏新
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Ningde Amperex Technology Ltd
Dongguan Amperex Technology Ltd
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Ningde Amperex Technology Ltd
Dongguan Amperex Technology Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a lithium ion battery cell which comprises a positive plate and a negative plate which are mutually stacked, wherein the number of the positive plate and the negative plate is at least two, the difference between the number of the positive plate and the number of the negative plate is 1, the lithium ion battery cell further comprises a wound first diaphragm and a wound second diaphragm, the positive plate is arranged on the same side of the first diaphragm, the negative plate is arranged on the same side of the second diaphragm, and the first diaphragm and the second diaphragm are alternately spaced between the adjacent positive plate and the adjacent negative plate in the direction from the innermost circle to the outermost circle of the battery cell. Compared with the prior art, the multi-layer pole pieces are connected in parallel, so that the internal impedance of the battery cell is reduced, the polarization is reduced, and the discharge platform is improved; the parallel connection of the pole pieces improves the high-rate charge and discharge capacity of the battery core; the battery cell has the advantages that the pole pieces are stacked together, the internal structure is uniform, and the stress is uniformly distributed, so that the battery cell is not easy to deform. In addition, the invention also discloses a preparation method of the battery cell.

Description

一种锂离子电芯及其制备方法A kind of lithium ion cell and preparation method thereof

技术领域 technical field

本发明属于锂离子电池技术领域,特别涉及一种锂离子电芯及其制备方法。 The invention belongs to the technical field of lithium ion batteries, in particular to a lithium ion battery cell and a preparation method thereof.

背景技术 Background technique

锂离子电池作为新能源领域最具代表性的储能器件,在移动电子、动力电池和储能电站等领域中占据不可取代的位置。尤其在动力电池领域,对电池的大倍率充放电性能有了更高的要求。 As the most representative energy storage device in the field of new energy, lithium-ion batteries occupy an irreplaceable position in the fields of mobile electronics, power batteries and energy storage power stations. Especially in the field of power batteries, there are higher requirements for the high rate charge and discharge performance of batteries.

目前的电芯制备方式主要有两种:卷绕方式和叠片方式。相对而言,卷绕方式效率更高,但是卷绕方式卷出的电芯内部结构不均一,电芯不同位置所受的应力也不同,这就造成了某些厚电芯和容易厚度反弹的电芯在充放电时容易变形。而且卷绕方式制备的电池还存在内阻较大的缺点。而叠片方式的优势是并联的堆叠方式使得电芯内阻更小,放电平台更高,内部受力均匀一致,且采用叠片方式制备的电池的大倍率充放电能力较好,适合于应用在动力电池领域。但是采用叠片方式制备电池的过程中需要制备电极单元来完成堆叠,工艺繁琐复杂,效率不高。 At present, there are two main methods of cell preparation: winding method and lamination method. Relatively speaking, the winding method is more efficient, but the internal structure of the cell rolled out by the winding method is not uniform, and the stress on different positions of the cell is also different, which causes some thick cells and easy thickness rebound. The battery cell is easily deformed during charging and discharging. Moreover, the battery prepared by winding method also has the disadvantage of relatively large internal resistance. The advantage of the lamination method is that the parallel stacking method makes the internal resistance of the battery cells smaller, the discharge platform is higher, and the internal force is uniform, and the battery prepared by the lamination method has a better high-rate charge and discharge capacity, which is suitable for application In the field of power batteries. However, in the process of preparing batteries by stacking, electrode units need to be prepared to complete the stacking, the process is cumbersome and complicated, and the efficiency is not high.

例如,申请专利号为CN200880120848.0的中国专利申请记载了采用二分电池和全电池堆叠卷绕的方式来制备锂离子电芯。具体而言,该方式是将正极片、隔膜和负极片先热合成二分电池和全电池单元,再将每个单元放置在单独一条隔膜上热合,卷绕成电芯组件。该方式工艺较为复杂,需要进行两次热复合,并且要先制备电池单元,效率较低。并且由于采用两次热复合,极片与隔膜、以及极片之间的对齐精度也不容易控制。 For example, the Chinese patent application with the application patent number CN200880120848.0 records that a lithium-ion battery cell is prepared by stacking and winding a two-part battery and a full battery. Specifically, this method is to heat-synthesize the positive electrode sheet, separator, and negative electrode sheet into two sub-batteries and full battery units, and then place each unit on a separate separator and heat-seal it, and wind it into a cell assembly. The process of this method is relatively complicated, and thermal compounding needs to be carried out twice, and the battery unit must be prepared first, so the efficiency is low. Moreover, due to the two-time heat recombination, the alignment accuracy between the pole piece and the diaphragm, and between the pole pieces is not easy to control.

有鉴于此,确有必要提供一种既能减小电芯内阻,又能改善电芯变形,同时还能够保证生产效率及简化工艺的锂离子电芯制备方法,以及采用该方法制备的锂离子电芯。 In view of this, it is necessary to provide a lithium ion battery preparation method that can reduce the internal resistance of the battery cell, improve the deformation of the battery cell, ensure production efficiency and simplify the process, and the lithium ion battery prepared by this method ion cell.

发明内容 Contents of the invention

本发明的目的之一在于:针对现有技术的不足,而提供一种锂离子电芯,该电芯综合了卷绕方式和叠片方式的优势,克服了卷绕方式和叠片方式的不足,具有较小的内阻和较好的大倍率充放电能力,内部受力均匀一致,不易变形。 One of the objectives of the present invention is to provide a lithium-ion battery cell for the deficiencies of the prior art, which combines the advantages of the winding method and the lamination method, and overcomes the shortcomings of the winding method and the lamination method , with small internal resistance and good high rate charge and discharge capacity, uniform internal force, not easy to deform.

为了达到上述目的,本发明采用如下技术方案:一种锂离子电芯,包括相互层叠设置的正极片和负极片,所述正极片的片数为至少两片,所述负极片的片数为至少两片,并且所述正极片的片数和所述负极片的片数相差1片,使正负极能够依次堆叠;每一片正极片均设置有正极极耳,每一片负极片均设置有负极极耳,相邻的两片正极极耳焊接连接,相邻的两片负极极耳焊接连接,还包括卷绕的第一隔膜和卷绕的第二隔膜,每一片正极片均设置于所述第一隔膜的同一侧,每一片负极片均设置于所述第二隔膜的同一侧,在从所述电芯的最内圈到最外圈的方向上,所述第一隔膜和所述第二隔膜交替地间隔于相邻的所述正极片和所述负极片之间。 In order to achieve the above object, the present invention adopts the following technical scheme: a lithium-ion battery cell, including a positive electrode sheet and a negative electrode sheet stacked on each other, the number of the positive electrode sheets is at least two, and the number of the negative electrode sheets is At least two pieces, and the number of positive pole pieces and the number of negative pole pieces differ by 1 piece, so that the positive and negative poles can be stacked in sequence; each positive pole piece is provided with a positive pole lug, and each negative pole piece is provided with Negative pole tabs, two adjacent positive pole tabs are welded and connected, two adjacent negative pole tabs are welded and connected, and the wound first diaphragm and the wound second diaphragm are also included. Each positive pole piece is arranged on the On the same side of the first diaphragm, each negative electrode sheet is arranged on the same side of the second diaphragm, in the direction from the innermost ring to the outermost ring of the battery core, the first diaphragm and the The second separators are alternately spaced between the adjacent positive electrode sheets and the negative electrode sheets.

作为本发明锂离子电芯的一种改进,所述第一隔膜的长度和所述第二隔膜的长度均比所述负极片的长度大0.1-2mm,所述第一隔膜的宽度和所述第二隔膜的宽度均比所述负极片的宽度大0.1-2mm;所述负极片的长度比所述正极片的长度大0.1-2mm,所述负极片的宽度比所述正极片的宽度大0.1-2mm,以防止正极片和负极片之间接触,并防止析锂现象的发生,保证电池安全。 As an improvement of the lithium ion battery cell of the present invention, the length of the first diaphragm and the length of the second diaphragm are both 0.1-2mm larger than the length of the negative electrode sheet, and the width of the first diaphragm and the length of the The width of the second separator is 0.1-2mm larger than the width of the negative electrode sheet; the length of the negative electrode sheet is 0.1-2mm larger than the length of the positive electrode sheet, and the width of the negative electrode sheet is larger than the width of the positive electrode sheet 0.1-2mm, to prevent the contact between the positive electrode and the negative electrode, and prevent the occurrence of lithium precipitation, so as to ensure the safety of the battery.

作为本发明锂离子电芯的一种改进,每一片正极片均通过热合固定设置于所述第一隔膜,以保证正极片与第一隔膜之间不发生相互滑动;每一片负极片均通过热合固定设置于所述第二隔膜,以保证负极片与第二隔膜之间不发生相互滑动。同时,还能提高电池的硬度。 As an improvement of the lithium-ion battery cell of the present invention, each positive electrode sheet is fixedly arranged on the first separator by heat sealing to ensure that the positive electrode sheet and the first separator do not slide each other; each negative electrode sheet is heat-sealed. It is fixedly arranged on the second diaphragm to ensure that the negative electrode sheet and the second diaphragm do not slide against each other. At the same time, it can also improve the hardness of the battery.

作为本发明锂离子电芯的一种改进,所述第一隔膜的末端和所述第二隔膜的末端均贴有粘胶。 As an improvement of the lithium-ion battery cell of the present invention, the end of the first diaphragm and the end of the second diaphragm are both pasted with glue.

作为本发明锂离子电芯的一种改进,所述正极极耳和所述负极极耳位于所述电芯前端的两侧。 As an improvement of the lithium ion battery cell of the present invention, the positive electrode tab and the negative electrode tab are located on both sides of the front end of the battery cell.

相对于现有技术,本发明具有以下优点:第一,多层极片并联减小了电芯的内部阻抗,使得极化减小,放电平台提高,更接近材料自身的真实放电平台。 Compared with the prior art, the present invention has the following advantages: First, the parallel connection of multi-layer pole pieces reduces the internal impedance of the cell, reduces the polarization, improves the discharge platform, and is closer to the real discharge platform of the material itself.

第二,极片的并联提高了电芯的大倍率充放电能力。 Second, the parallel connection of pole pieces improves the high rate charge and discharge capability of the battery cell.

第三,本发明的电芯由于极片是堆叠在一起的,内部结构统一,应力均匀分布,所以不容易产生变形。 Thirdly, since the pole pieces of the battery cell of the present invention are stacked together, the internal structure is uniform, and the stress is uniformly distributed, so deformation is not easy to occur.

本发明的另一个目的在于提供一种锂离子电芯的制备方法,包括以下步骤:第一步,将至少两片留有正极极耳的正极片间隔地设置在第一隔膜的一侧,将至少两片留有负极极耳的负极片间隔地设置在第二隔膜的一侧,并且所述正极片的片数和所述负极片的片数相差一片,多出的一片对应空白隔膜,其余正极片与负极片一一对应设置;也就是说,第一隔膜的起始位置不放置极片(正极片或负极片),而第二隔膜的起始位置则放置有极片(正极片或负极片)。 Another object of the present invention is to provide a preparation method of a lithium-ion battery, comprising the following steps: in the first step, at least two positive pole pieces with positive pole tabs are arranged at intervals on one side of the first diaphragm, and At least two negative electrode sheets with negative electrode tabs are arranged at intervals on one side of the second separator, and the number of positive electrode sheets is different from the number of negative electrode sheets by one piece, and the extra piece corresponds to a blank separator, and the rest The positive electrode piece and the negative electrode piece are set in one-to-one correspondence; that is to say, the starting position of the first diaphragm is not placed with the pole piece (positive electrode piece or negative electrode piece), while the starting position of the second diaphragm is placed with the pole piece (positive electrode piece or negative electrode piece). negative plate).

其中,隔膜(第一隔膜和第二隔膜)由具有离子导通能力的聚合物组成,正极片是由正极材料涂覆到正极集流体表面制造而成,负极极片是由负极材料涂覆到负极集流体表面制造而成,隔膜必须有足够长度和宽度包裹所有极片,以防止正极片和负极片直接接触,隔膜的长度及宽度方向要超过负极片0.1-2mm,负极片长度及宽度方向要超出对应的正极片0.1-2mm,以保证电池安全。 Among them, the diaphragm (the first diaphragm and the second diaphragm) is composed of a polymer with ion conductivity, the positive electrode sheet is made by coating the positive electrode material on the surface of the positive electrode current collector, and the negative electrode sheet is made by coating the negative electrode material on the surface of the positive electrode current collector. Manufactured on the surface of the negative electrode collector, the separator must have sufficient length and width to wrap all the pole pieces to prevent direct contact between the positive electrode piece and the negative electrode piece. It should exceed the corresponding positive plate by 0.1-2mm to ensure the safety of the battery.

间隔设置在第一隔膜上的正极片之间的距离从卷绕初始端开始依次增加,间隔设置在第二隔膜上的负极片之间的距离从卷绕初始端开始依次增加,以够保证极片间良好的对齐度)。 The distance between the positive electrode sheets arranged at intervals on the first separator increases sequentially from the initial end of the winding, and the distance between the negative electrode sheets arranged at intervals on the second separator increases sequentially from the initial end of the winding, so as to ensure that the electrode good alignment between slices).

第二步,将设置有正极片的第一隔膜和设置有负极片的第二隔膜对齐放置,并使第一隔膜和第二隔膜分设于正极片或负极片的两侧。 In the second step, the first diaphragm provided with the positive electrode sheet and the second diaphragm provided with the negative electrode sheet are aligned, and the first diaphragm and the second diaphragm are separately arranged on both sides of the positive electrode sheet or the negative electrode sheet.

第三步,从空白隔膜一端开始卷绕,使正极片和负极片依次堆叠,然后将正极极耳焊接连接,负极极耳焊接连接,得到锂离子电芯。其中,极耳并联焊接可以减小内阻,提高电池的放电倍率。 The third step is to start winding from one end of the blank separator, so that the positive electrode sheet and the negative electrode sheet are stacked in sequence, and then the positive electrode tab is welded and connected, and the negative electrode tab is welded and connected to obtain a lithium ion battery. Among them, the parallel welding of the tabs can reduce the internal resistance and increase the discharge rate of the battery.

为了进一步提高正极片、第一隔膜、负极片和第二隔膜之间的稳固性,在将正极片、第一隔膜、负极片和第二隔膜按照一定顺序堆叠后需要在一定温度下进行热合,热合的温度范围胃20—200℃,以保证极片与隔膜不发生相对滑动。 In order to further improve the stability between the positive electrode sheet, the first separator, the negative electrode sheet and the second separator, after stacking the positive electrode sheet, the first separator, the negative electrode sheet and the second separator in a certain order, it is necessary to perform heat sealing at a certain temperature, The temperature range of heat sealing is 20-200°C to ensure that the pole piece and the diaphragm do not slide relative to each other.

其中,卷绕完成后电芯的最上层和最下层的极片既可以是双面涂覆的正极片也可以是双面涂覆的负极片,还可以是单面涂覆的正极集流体或单面涂覆的负极集流体,优选为单面涂覆的正极集流体或单面涂覆的负极集流体,因为这样可以防止活性物质的浪费,提高电池的能量密度。更优选的,电芯的最上层和最下层极片均为单面涂覆的负极集流体,因为这样还可以节约成本。 Among them, after the winding is completed, the uppermost and lowermost pole pieces of the battery can be either double-sided coated positive pole pieces or double-sided coated negative pole pieces, or single-side coated positive electrode current collectors or The negative electrode collector coated on one side is preferably a positive electrode collector coated on one side or a negative electrode collector coated on one side, because this can prevent waste of active materials and increase the energy density of the battery. More preferably, both the uppermost layer and the lowermost electrode sheet of the battery cell are negative electrode collectors coated on one side, because this can also save costs.

作为本发明锂离子电芯的制备方法的一种改进,第一步中,每一片正极片均通过热合固定设置于所述第一隔膜,每一片负极片均通过热合固定设置于所述第二隔膜,防止正极片和第一隔膜之间的滑动,以及防止负极片与第二隔膜之间的滑动,提高了电池的安全性能。 As an improvement of the preparation method of the lithium-ion battery cell of the present invention, in the first step, each positive electrode sheet is fixed on the first separator by heat sealing, and each negative electrode sheet is fixed on the second separator by heat sealing. The separator prevents sliding between the positive electrode sheet and the first separator, and prevents sliding between the negative electrode sheet and the second separator, thereby improving the safety performance of the battery.

作为本发明锂离子电芯的制备方法的一种改进,第一步中,相邻正极片的正极极耳左右交替设置;相邻负极片的负极极耳左右交替设置,以保证同极性极耳的对齐,利于焊接。 As an improvement of the preparation method of the lithium-ion battery cell of the present invention, in the first step, the positive tabs of adjacent positive plates are alternately arranged left and right; the negative tabs of adjacent negative plates are alternately arranged left and right to ensure the same polarity The alignment of the ears is good for welding.

作为本发明锂离子电芯的制备方法的一种改进,第三步卷绕完成后,在所述第一隔膜的末端和所述第二隔膜的末端贴上粘胶,将第一隔膜和第二隔膜固定在电芯上。 As an improvement of the preparation method of the lithium-ion battery cell of the present invention, after the third step of winding is completed, glue is pasted on the end of the first diaphragm and the end of the second diaphragm, and the first diaphragm and the second diaphragm are The two diaphragms are fixed on the electric core.

作为本发明锂离子电芯的制备方法的一种改进,:第三步卷绕完成后,所述正极极耳均位于所述电芯前端的一侧,所述负极极耳均位于所述电芯前端的另一侧,便于正极极耳和负极极耳的焊接,并且便于外接用电器。 As an improvement of the preparation method of the lithium-ion battery cell of the present invention, after the third step of winding is completed, the positive electrode tabs are all located on one side of the front end of the battery core, and the negative electrode tabs are all located on the front end of the battery cell. The other side of the front end of the core is convenient for welding the positive pole lug and the negative pole lug, and it is convenient for external electrical appliances.

相对于现有技术,本发明的制备方法与现有的叠片方式相比,因为不需要制作大量的电池单元(二分电池或全电池),因此工艺得到简化,效率更高。而且制备的电池兼具卷绕方式与叠片方式制备的电池的优势,既具有较小的内阻,又具有较小的变形。 Compared with the prior art, the preparation method of the present invention is compared with the existing stacking method, because there is no need to manufacture a large number of battery cells (two sub-cells or full cells), so the process is simplified and the efficiency is higher. Moreover, the prepared battery has both the advantages of the battery prepared by the winding method and the laminated method, and has not only small internal resistance, but also small deformation.

附图说明 Description of drawings

下面结合附图和具体实施方式,对本发明及其有益技术效果进行详细说明。 The present invention and its beneficial technical effects will be described in detail below in conjunction with the accompanying drawings and specific embodiments.

图1为本发明实施例1的正极片在第一隔膜上的排布结构示意图。 FIG. 1 is a schematic diagram of the arrangement structure of the positive electrode sheet on the first separator in Example 1 of the present invention.

图2为本发明实施例1的负极片在第二隔膜上的排布结构示意图。 FIG. 2 is a schematic diagram of the arrangement structure of the negative electrode sheet on the second separator in Example 1 of the present invention.

图3为本发明实施例1的电芯在卷绕时的结构示意图。 FIG. 3 is a schematic structural view of the battery cell in Example 1 of the present invention when it is wound.

图4为本发明实施例1的电芯的结构示意图。 FIG. 4 is a schematic structural view of the battery cell according to Embodiment 1 of the present invention.

图5为本发明实施例2的正极片在第一隔膜上的排布结构示意图。 FIG. 5 is a schematic diagram of the arrangement structure of the positive electrode sheet on the first separator according to Example 2 of the present invention.

图6为本发明实施例2的负极片在第二隔膜上的排布结构示意图。 FIG. 6 is a schematic diagram of the arrangement structure of the negative electrode sheet on the second separator according to Example 2 of the present invention.

图7为本发明实施例2的电芯在卷绕时的结构示意图。 FIG. 7 is a schematic structural view of the battery cell according to Example 2 of the present invention when it is wound.

图8为本发明实施例2的电芯的结构示意图。 FIG. 8 is a schematic structural view of a battery cell according to Embodiment 2 of the present invention.

具体实施方式 Detailed ways

以下结合具体实施例详细描述本发明及其有益效果,但是,本发明的实施例并不局限于此。 The present invention and its beneficial effects are described in detail below in conjunction with specific embodiments, however, the embodiments of the present invention are not limited thereto.

实施例1:本发明提供的一种锂离子电芯的制备方法,包括以下步骤:第一步,本实施例中,正极片1的片数比负极片3的片数少一片,且正极片1的片数至少为2片,每一片正极片1上均设置有正极极耳11,每一片负极片3上均设置有负极极耳31。如图1和2所示,将留有正极极耳11的正极片1间隔地通过热合固定在第一隔膜2的一侧,其中,第一隔膜2的起始位置不放置正极片1。将留有负极极耳31的负极片3间隔地通过热合固定在第二隔膜4的一侧,其中,第二隔膜4的起始位置放置有负极片3。其余正极片1与负极片3一一对应设置。在第一隔膜2的长度方向上,从起始位置开始,相邻正极片1之间的间距逐渐增大;在第二隔膜4的长度方向上,从起始位置开始,相邻负极片3之间的间距逐渐增大。相邻正极片1的正极极耳11左右交替设置;相邻负极片3的负极极耳31左右交替设置,即,若一片正极片1的正极极耳11设置在其右侧,则与该正极片1左右相邻的正极片1上的正极极耳11则设置在左侧,同理,负极片3也是如此。而且,对于相对设置的正极片1和负极片3,正极极耳11和负极极耳31交错设置。 Embodiment 1: the preparation method of a kind of lithium ion cell provided by the present invention comprises the following steps: the first step, in the present embodiment, the number of sheets of positive electrode sheet 1 is less than the number of sheets of negative electrode sheet 3, and the number of sheets of positive electrode sheet The number of sheets 1 is at least 2, and each positive electrode sheet 1 is provided with a positive electrode tab 11 , and each negative electrode sheet 3 is provided with a negative electrode tab 31 . As shown in FIGS. 1 and 2 , the positive electrode sheet 1 with positive electrode tabs 11 is fixed on one side of the first separator 2 by heat sealing at intervals, wherein the initial position of the first separator 2 does not place the positive electrode sheet 1 . The negative electrode sheet 3 with the negative electrode tabs 31 left is fixed on one side of the second separator 4 by heat sealing at intervals, wherein the initial position of the second separator 4 is placed with the negative electrode sheet 3 . The rest of the positive electrode sheets 1 and the negative electrode sheets 3 are provided in one-to-one correspondence. In the length direction of the first diaphragm 2, starting from the initial position, the spacing between adjacent positive electrode sheets 1 gradually increases; in the length direction of the second diaphragm 4, starting from the initial position, the adjacent negative electrode sheets 3 The distance between them gradually increases. The positive pole lugs 11 of adjacent positive pole sheets 1 are arranged alternately left and right; The positive electrode lug 11 on the positive electrode sheet 1 adjacent to the left and right of the sheet 1 is arranged on the left side, and the same is true for the negative electrode sheet 3 . Moreover, for the positive electrode sheet 1 and the negative electrode sheet 3 that are oppositely arranged, the positive electrode tabs 11 and the negative electrode tabs 31 are alternately arranged.

第二步,如图3所示,将设置有正极片1的第一隔膜2和设置有负极片3的第二隔膜4对齐放置,即除了起始位置外,其余位置的正极片1和负极片3对齐,并使第一隔膜2和第二隔膜4分设于负极片3的两侧,也就是说,第一隔膜2位于正极片1和负极片3之间。 In the second step, as shown in Figure 3, the first diaphragm 2 provided with the positive electrode sheet 1 and the second diaphragm 4 provided with the negative electrode sheet 3 are aligned and placed, that is, the positive electrode sheet 1 and the negative electrode at the rest of the position except the initial position The sheets 3 are aligned, and the first separator 2 and the second separator 4 are separately arranged on both sides of the negative electrode sheet 3 , that is, the first separator 2 is located between the positive electrode sheet 1 and the negative electrode sheet 3 .

第三步,从第一隔膜2的空白端开始卷绕,使位于第二隔膜4起始位置的负极片3堆叠在位于第一隔膜2一侧的正极片1上,按此方向继续卷绕,然后再通过热合的方式将正极片1、第一隔膜2、负极片3和第二隔膜4固定在一起,热合的温度为20-200℃,以防止正极片1、负极片3和第一隔膜2、第二隔膜4之间的相互滑动,保证电池安全,同时还能增强电池的硬度。卷绕完成后,再在第一隔膜2的末端和第二隔膜4的末端贴上粘胶5,此时,正极极耳11为与电芯的一侧,负极极耳31位于电芯另一侧,然后将正极极耳11焊接连接,负极极耳31焊接连接,得到锂离子电芯。 The third step is to start winding from the blank end of the first separator 2, so that the negative electrode sheet 3 at the starting position of the second separator 4 is stacked on the positive electrode sheet 1 on the side of the first separator 2, and continue winding in this direction , and then fix the positive electrode sheet 1, the first separator 2, the negative electrode sheet 3 and the second separator 4 together by means of heat sealing. Mutual sliding between the diaphragm 2 and the second diaphragm 4 ensures the safety of the battery and at the same time enhances the hardness of the battery. After the winding is completed, paste the glue 5 on the end of the first diaphragm 2 and the end of the second diaphragm 4. At this time, the positive pole tab 11 is on one side of the battery core, and the negative pole tab 31 is located on the other side of the battery core. side, and then weld the positive tab 11 and the negative tab 31 to obtain a lithium-ion cell.

采用以上方法得到的锂离子电芯的结构示意图如图4所示,包括相互层叠设置的正极片1和负极片3,并且正极片1的片数比负极片3的片数少一片,正极片1均设置有正极极耳11,负极片3均设置有负极极耳31,正极极耳11焊接连接,负极极耳31焊接连接,还包括卷绕的第一隔膜2和卷绕的第二隔膜4,正极片1均设置于第一隔膜2的同一侧,负极片3均设置于第二隔膜4的同一侧,在从电芯的最内圈到最外圈的方向上,第一隔膜2和第二隔膜4交替地间隔于相邻的正极片1和负极片3之间。正极极耳11和负极极耳31位于电芯前端的两侧。电芯的前端是指极耳伸出的一端。 The schematic diagram of the structure of the lithium-ion cell obtained by the above method is shown in Figure 4, including positive electrode sheets 1 and negative electrode sheets 3 stacked on each other, and the number of positive electrode sheets 1 is one less than the number of negative electrode sheets 3, and the positive electrode sheets 1 are all provided with a positive electrode tab 11, and the negative electrode sheets 3 are all provided with a negative electrode tab 31, the positive electrode tab 11 is welded and connected, and the negative electrode tab 31 is welded and connected, and also includes a wound first diaphragm 2 and a wound second diaphragm 4. The positive electrode sheets 1 are all arranged on the same side of the first separator 2, and the negative electrode sheets 3 are all arranged on the same side of the second separator 4. In the direction from the innermost ring to the outermost ring of the cell, the first separator 2 and the second separator 4 are alternately spaced between adjacent positive electrode sheets 1 and negative electrode sheets 3 . The positive pole tab 11 and the negative pole tab 31 are located on both sides of the front end of the cell. The front end of the cell refers to the end where the tab protrudes.

电芯的最上层和最下层极片均为负极片3,该负极片3可以是双面涂覆有负极材料的负极片3,也可以是单面涂覆有负极材料的负极片3,其未涂覆负极材料的一侧位于最外侧。且正极极耳均11位于电芯的一侧,负极极耳31均位于电芯的另一侧。 The uppermost and lowermost pole pieces of the cell are negative pole pieces 3, which can be negative pole pieces 3 coated with negative material on both sides, or negative pole pieces 3 coated with negative material on one side. The side not coated with the negative electrode material is located on the outermost side. In addition, the positive tabs 11 are located on one side of the cell, and the negative tabs 31 are located on the other side of the cell.

第一隔膜2的末端和第二隔膜4的末端均贴有粘胶5。当然,也可以通过热融合的方式将第一隔膜2和第二隔膜4固定在电芯最外端。 The end of the first diaphragm 2 and the end of the second diaphragm 4 are pasted with glue 5 . Of course, the first separator 2 and the second separator 4 can also be fixed on the outermost end of the cell by thermal fusion.

此外,为了防止析锂和正极片1与负极片3直接接触,第一隔膜2的长度和第二隔膜4的长度均比负极片3的长度大0.1-2mm,第一隔膜2的宽度和第二隔膜4的宽度均比负极片3的宽度大0.1-2mm;负极片3的长度比正极片1的长度大0.1-2mm,负极片3的宽度比正极片1的宽度大0.1-2mm。 In addition, in order to prevent lithium precipitation and the direct contact between the positive electrode sheet 1 and the negative electrode sheet 3, the length of the first diaphragm 2 and the length of the second diaphragm 4 are both 0.1-2 mm larger than the length of the negative electrode sheet 3, and the width of the first diaphragm 2 and the second diaphragm 4 are larger than the length of the negative electrode sheet 3. The width of two separators 4 is 0.1-2mm larger than the width of negative electrode sheet 3; the length of negative electrode sheet 3 is 0.1-2mm larger than the length of positive electrode sheet 1, and the width of negative electrode sheet 3 is larger than the width of positive electrode sheet 1.

实施例2:本发明提供的一种锂离子电芯的制备方法,包括以下步骤:第一步,本实施例中,正极片1的片数比负极片3的片数多一片,且负极片3的片数至少为2片,每一片正极片1上均设置有正极极耳11,每一片负极片3上均设置有负极极耳31。如图5和6所示,将留有正极极耳11的正极片1间隔地通过热合固定在第一隔膜2的一侧,其中,第一隔膜2的起始位置放置有正极片1。将留有负极极耳31的负极片3间隔地通过热合固定在第二隔膜4的一侧,其中,第二隔膜4的起始位置不放置负极片3。其余正极片1与负极片3一一对应设置。在第一隔膜2的长度方向上,从起始位置开始,相邻正极片1之间的间距逐渐增大;在第二隔膜4的长度方向上,从起始位置开始,相邻负极片3之间的间距逐渐增大。相邻正极片1的正极极耳11左右交替设置;相邻负极片3的负极极耳31左右交替设置,即,若一片正极片1的正极极耳11设置在其右侧,则与该正极片1左右相邻的正极片1上的正极极耳11则设置在左侧,同理,负极片3也是如此。而且,对于相对设置的正极片1和负极片3,正极极耳11和负极极耳31交错设置。 Embodiment 2: the preparation method of a kind of lithium-ion cell provided by the present invention comprises the following steps: the first step, in the present embodiment, the number of sheets of positive electrode sheet 1 is one more than the sheet number of negative electrode sheet 3, and negative electrode sheet The number of sheets 3 is at least two, each positive electrode sheet 1 is provided with a positive electrode tab 11 , and each negative electrode sheet 3 is provided with a negative electrode tab 31 . As shown in FIGS. 5 and 6 , the positive electrode sheet 1 with positive electrode tabs 11 is fixed on one side of the first separator 2 by heat sealing at intervals, wherein the positive electrode sheet 1 is placed at the initial position of the first separator 2 . The negative electrode sheet 3 with the negative electrode tabs 31 left is fixed on one side of the second separator 4 by heat sealing at intervals, wherein the initial position of the second separator 4 does not place the negative electrode sheet 3 . The rest of the positive electrode sheets 1 and the negative electrode sheets 3 are provided in one-to-one correspondence. In the length direction of the first diaphragm 2, starting from the initial position, the spacing between adjacent positive electrode sheets 1 gradually increases; in the length direction of the second diaphragm 4, starting from the initial position, the adjacent negative electrode sheets 3 The distance between them gradually increases. The positive pole lugs 11 of adjacent positive pole sheets 1 are arranged alternately left and right; The positive electrode lug 11 on the positive electrode sheet 1 adjacent to the left and right of the sheet 1 is arranged on the left side, and the same is true for the negative electrode sheet 3 . Moreover, for the positive electrode sheet 1 and the negative electrode sheet 3 that are oppositely arranged, the positive electrode tabs 11 and the negative electrode tabs 31 are alternately arranged.

第二步,如图7所示,将设置有正极片1的第一隔膜2和设置有负极片3的第二隔膜4对齐放置,即除了起始位置外,其余位置的正极片1和负极片3对齐,并使第一隔膜2和第二隔膜4分设于正极片1的两侧,也就是说,第二隔膜4位于正极片1和负极片3之间。 In the second step, as shown in Figure 7, the first diaphragm 2 provided with the positive electrode sheet 1 and the second diaphragm 4 provided with the negative electrode sheet 3 are aligned and placed, that is, except the initial position, the positive electrode sheet 1 and the negative electrode at the remaining positions The sheets 3 are aligned, and the first separator 2 and the second separator 4 are separately arranged on both sides of the positive electrode sheet 1 , that is, the second separator 4 is located between the positive electrode sheet 1 and the negative electrode sheet 3 .

第三步,从第二隔膜4的空白端开始卷绕,使位于第一隔膜2起始位置的正极片1堆叠在位于第二隔膜4一侧的负极片3上,按此方向继续卷绕,然后再通过热合的方式将正极片1、第一隔膜2、负极片3和第二隔膜4固定在一起,热合的温度为20-200℃,以防止正极片1、负极片3和第一隔膜2、第二隔膜4之间的相互滑动,保证电池安全,同时还能增强电池的硬度。卷绕完成后,再在第一隔膜2的末端和第二隔膜4的末端贴上粘胶5,此时,正极极耳11为与电芯的一侧,负极极耳31位于电芯另一侧,然后将正极极耳11焊接连接,负极极耳31焊接连接,得到锂离子电芯。 The third step is to start winding from the blank end of the second separator 4, so that the positive electrode sheet 1 at the starting position of the first separator 2 is stacked on the negative electrode sheet 3 on the side of the second separator 4, and continue winding in this direction , and then fix the positive electrode sheet 1, the first separator 2, the negative electrode sheet 3 and the second separator 4 together by means of heat sealing. Mutual sliding between the diaphragm 2 and the second diaphragm 4 ensures the safety of the battery and at the same time enhances the hardness of the battery. After the winding is completed, paste the glue 5 on the end of the first diaphragm 2 and the end of the second diaphragm 4. At this time, the positive pole tab 11 is on one side of the battery core, and the negative pole tab 31 is located on the other side of the battery core. side, and then weld the positive tab 11 and the negative tab 31 to obtain a lithium-ion cell.

采用以上方法得到的锂离子电芯的结构示意图如图8所示,包括相互层叠设置的正极片1和负极片3,正极片1的片数比负极片3的片数多一片,正极片1均设置有正极极耳11,负极片3均设置有负极极耳31,正极极耳11焊接连接,负极极耳31焊接连接,还包括卷绕的第一隔膜2和卷绕的第二隔膜4,正极片1均设置于第一隔膜2的同一侧,负极片3均设置于第二隔膜4的同一侧,在从电芯的最内圈到最外圈的方向上,第一隔膜2和第二隔膜4交替地间隔于相邻的正极片1和负极片3之间,正极极耳11和负极极耳31位于电芯前端的两侧。电芯的前端是指极耳伸出的一端。 The schematic diagram of the structure of the lithium-ion cell obtained by the above method is shown in Figure 8, including positive electrode sheets 1 and negative electrode sheets 3 stacked on each other, the number of positive electrode sheets 1 is one more than the number of negative electrode sheets 3, and the number of positive electrode sheets 1 Both are provided with positive pole tabs 11, and the negative pole sheets 3 are all provided with negative pole tabs 31, the positive pole tabs 11 are welded and connected, the negative pole tabs 31 are welded and connected, and also include the wound first diaphragm 2 and the wound second diaphragm 4 , the positive electrode sheets 1 are all arranged on the same side of the first separator 2, and the negative electrode sheets 3 are all arranged on the same side of the second separator 4. In the direction from the innermost ring to the outermost ring of the cell, the first separator 2 and the The second separator 4 is alternately spaced between the adjacent positive electrode sheets 1 and negative electrode sheets 3 , and the positive electrode tabs 11 and the negative electrode tabs 31 are located on both sides of the front end of the cell. The front end of the cell refers to the end where the tab protrudes.

电芯的最上层和最下层的极片均为正极片1,该正极片1可以是双面涂覆有正极材料的正极片1,也可以是单面涂覆有正极材料的正极片1,其未涂覆正极材料的一侧位于最外侧。且正极极耳均11位于电芯的一侧,负极极耳31均位于电芯的另一侧。 Both the uppermost and the lowermost pole pieces of the cell are positive pole pieces 1, and the positive pole piece 1 can be a positive pole piece 1 coated with a positive electrode material on both sides, or a positive pole piece 1 coated with a positive pole material on one side. Its side that is not coated with the positive electrode material is located on the outermost side. In addition, the positive tabs 11 are located on one side of the cell, and the negative tabs 31 are located on the other side of the cell.

第一隔膜2的末端和第二隔膜4的末端均贴有粘胶5。当然,也可以通过热融合的方式将第一隔膜2和第二隔膜4固定在电芯最外端。 The end of the first diaphragm 2 and the end of the second diaphragm 4 are pasted with glue 5 . Of course, the first separator 2 and the second separator 4 can also be fixed on the outermost end of the cell by thermal fusion.

此外,为了防止析锂和正极片1与负极片3直接接触,第一隔膜2的长度和第二隔膜4的长度均比负极片3的长度大0.1-2mm,第一隔膜2的宽度和第二隔膜4的宽度均比负极片3的宽度大0.1-2mm;负极片3的长度比正极片1的长度大0.1-2mm,负极片3的宽度比正极片1的宽度大0.1-2mm。 In addition, in order to prevent lithium precipitation and the direct contact between the positive electrode sheet 1 and the negative electrode sheet 3, the length of the first diaphragm 2 and the length of the second diaphragm 4 are both 0.1-2 mm larger than the length of the negative electrode sheet 3, and the width of the first diaphragm 2 and the second diaphragm 4 are larger than the length of the negative electrode sheet 3. The width of two separators 4 is 0.1-2mm larger than the width of negative electrode sheet 3; the length of negative electrode sheet 3 is 0.1-2mm larger than the length of positive electrode sheet 1, and the width of negative electrode sheet 3 is larger than the width of positive electrode sheet 1.

根据上述说明书的揭示和教导,本发明所属领域的技术人员还可以对上述实施方式进行适当的变更和修改。因此,本发明并不局限于上面揭示和描述的具体实施方式,对本发明的一些修改和变更也应当落入本发明的权利要求的保护范围内。此外,尽管本说明书中使用了一些特定的术语,但这些术语只是为了方便说明,并不对本发明构成任何限制。 According to the disclosure and teaching of the above specification, those skilled in the art to which the present invention pertains can also make appropriate changes and modifications to the above embodiment. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and changes to the present invention should also fall within the protection scope of the claims of the present invention. In addition, although some specific terms are used in this specification, these terms are only for convenience of description and do not constitute any limitation to the present invention.

Claims (10)

1.一种锂离子电芯,包括相互层叠设置的正极片和负极片,所述正极片的片数为至少两片,所述负极片的片数为至少两片,并且所述正极片的片数和所述负极片的片数相差1片,每一片正极片均设置有正极极耳,每一片负极片均设置有负极极耳,相邻的两片正极极耳焊接连接,相邻的两片负极极耳焊接连接,其特征在于:还包括卷绕的第一隔膜和卷绕的第二隔膜,每一片正极片均设置于所述第一隔膜的同一侧,每一片负极片均设置于所述第二隔膜的同一侧,在从所述电芯的最内圈到最外圈的方向上,所述第一隔膜和所述第二隔膜交替地设置于相邻的所述正极片和所述负极片之间。 1. A lithium-ion cell, comprising a positive electrode sheet and a negative electrode sheet which are stacked with each other, the number of the positive electrode sheets is at least two, the number of the negative electrode sheets is at least two, and the number of the positive electrode sheets is at least two. The difference between the number of sheets and the number of the negative electrode sheets is 1 sheet, each positive electrode sheet is provided with a positive electrode tab, and each negative electrode sheet is provided with a negative electrode tab, and the adjacent two positive electrode tabs are welded and connected, and the adjacent Two pieces of negative electrode lugs are welded and connected, and it is characterized in that: it also includes a wound first diaphragm and a wound second diaphragm, each positive electrode sheet is arranged on the same side of the first diaphragm, and each negative electrode sheet is arranged on the same side of the first diaphragm. On the same side of the second diaphragm, in the direction from the innermost circle to the outermost circle of the battery core, the first diaphragm and the second diaphragm are alternately arranged on the adjacent positive electrode sheets and between the negative electrode sheet. 2.根据权利要求1所述的锂离子电芯,其特征在于:所述第一隔膜的长度和所述第二隔膜的长度均比所述负极片的长度大0.1-2mm,所述第一隔膜的宽度和所述第二隔膜的宽度均比所述负极片的宽度大0.1-2mm;所述负极片的长度比所述正极片的长度大0.1-2mm,所述负极片的宽度比所述正极片的宽度大0.1-2mm。 2. The lithium ion battery cell according to claim 1, characterized in that: the length of the first diaphragm and the length of the second diaphragm are both 0.1-2mm larger than the length of the negative electrode sheet, and the first Both the width of the separator and the width of the second separator are 0.1-2mm larger than the width of the negative electrode sheet; The width of the positive plate is 0.1-2mm larger. 3.根据权利要求1所述的锂离子电芯,其特征在于:每一片正极片均通过热合固定设置于所述第一隔膜;每一片负极片均通过热合固定设置于所述第二隔膜。 3 . The lithium-ion battery cell according to claim 1 , wherein each positive electrode sheet is fixed to the first separator by heat sealing; each negative electrode sheet is fixed to the second separator by heat sealing. 4 . 4.根据权利要求1所述的锂离子电芯,其特征在于:所述第一隔膜的末端和所述第二隔膜的末端均贴有粘胶。 4. The lithium-ion battery cell according to claim 1, characterized in that: the ends of the first separator and the second separator are both pasted with glue. 5.根据权利要求1所述的锂离子电芯,其特征在于:所述正极极耳和所述负极极耳位于所述电芯前端的两侧。 5 . The lithium ion battery cell according to claim 1 , wherein the positive electrode tab and the negative electrode tab are located on both sides of the front end of the battery cell. 6.一种锂离子电芯的制备方法,其特征在于,包括以下步骤: 6. A preparation method for a lithium ion battery cell, comprising the following steps: 第一步,将至少两片留有正极极耳的正极片间隔地设置在第一隔膜的一侧,将至少两片留有负极极耳的负极片间隔地设置在第二隔膜的一侧,并且所述正极片的片数和所述负极片的片数相差一片,多出的一片对应空白隔膜,其余正极片与负极片一一对应设置; In the first step, at least two positive electrode sheets with positive electrode tabs are arranged at intervals on one side of the first diaphragm, and at least two negative electrode sheets with negative electrode tabs are arranged at intervals on one side of the second diaphragm, And the number of the positive electrode sheets is different from the number of the negative electrode sheets by one sheet, the extra sheet corresponds to a blank diaphragm, and the remaining positive electrode sheets and the negative electrode sheets are set in one-to-one correspondence; 第二步,将设置有正极片的第一隔膜和设置有负极片的第二隔膜对齐放置,并使第一隔膜和第二隔膜分设于正极片或负极片的两侧; In the second step, the first diaphragm provided with the positive electrode sheet and the second diaphragm provided with the negative electrode sheet are aligned and placed, and the first diaphragm and the second diaphragm are separately arranged on both sides of the positive electrode sheet or the negative electrode sheet; 第三步,从空白隔膜一端开始卷绕,使正极片和负极片依次堆叠,然后将正极极耳焊接连接,负极极耳焊接连接,得到锂离子电芯。 The third step is to start winding from one end of the blank separator, so that the positive electrode sheet and the negative electrode sheet are stacked in sequence, and then the positive electrode tab is welded and connected, and the negative electrode tab is welded and connected to obtain a lithium ion battery. 7.根据权利要求6所述的锂离子电芯的制备方法,其特征在于:第一步中每一片正极片均通过热合固定于所述第一隔膜,每一片负极片均通过热合固定于所述第二隔膜。 7. The preparation method of the lithium-ion cell according to claim 6, characterized in that: in the first step, each positive electrode sheet is fixed to the first separator by heat sealing, and each negative electrode sheet is fixed to the first diaphragm by heat sealing. the second diaphragm. 8.根据权利要求6所述的锂离子电芯的制备方法,其特征在于:第一步中,相邻正极片的正极极耳左右交替设置;相邻负极片的负极极耳左右交替设置。 8. The method for preparing a lithium-ion cell according to claim 6, characterized in that: in the first step, the positive tabs of adjacent positive plates are arranged alternately left and right; the negative tabs of adjacent negative plates are alternately arranged left and right. 9.根据权利要求6所述的锂离子电芯的制备方法,其特征在于:第三步卷绕完成后,在所述第一隔膜的末端和所述第二隔膜的末端贴上粘胶。 9 . The method for preparing a lithium ion battery cell according to claim 6 , characterized in that: after the third step of winding is completed, glue is pasted on the end of the first separator and the end of the second separator. 10 . 10.根据权利要求6所述的锂离子电芯的制备方法,其特征在于:第三步卷绕完成后,每一片正极极耳均位于所述电芯前端的一侧,每一片负极极耳均位于所述电芯前端的另一侧。 10. The preparation method of lithium-ion batteries according to claim 6, characterized in that: after the third step of winding is completed, each piece of positive pole tab is located on one side of the front end of the battery core, and each piece of negative pole tab is They are all located on the other side of the front end of the battery core.
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CN103199305A (en) * 2013-03-18 2013-07-10 东莞新能源科技有限公司 Lithium ion battery cell and preparation method thereof
CN104157914A (en) * 2014-09-02 2014-11-19 山东齐星新能源科技有限责任公司 High-power flexible packaged lithium ion battery and processing process thereof
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CN105489942A (en) * 2014-10-07 2016-04-13 株式会社Lg化学 Bidirectionally wound electrode assembly and lithium secondary battery including the electrode assembly
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CN105489942B (en) * 2014-10-07 2018-01-16 株式会社Lg化学 Bidirectionally wound electrode assembly and lithium secondary battery including the electrode assembly
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CN107863552A (en) * 2017-12-05 2018-03-30 中航锂电技术研究院有限公司 A kind of core strueture and the battery using the core strueture
CN109004260A (en) * 2018-07-02 2018-12-14 浙江衡远新能源科技有限公司 A kind of preparation method for cutting lamination winding type soft package lithium ion battery battery core
CN109301339A (en) * 2018-10-08 2019-02-01 东莞阿李自动化股份有限公司 Battery cell winding process
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