CN102660145A - Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof - Google Patents

Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof Download PDF

Info

Publication number
CN102660145A
CN102660145A CN2012101319674A CN201210131967A CN102660145A CN 102660145 A CN102660145 A CN 102660145A CN 2012101319674 A CN2012101319674 A CN 2012101319674A CN 201210131967 A CN201210131967 A CN 201210131967A CN 102660145 A CN102660145 A CN 102660145A
Authority
CN
China
Prior art keywords
general formula
disperse
composition
dye composition
disperse dye
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2012101319674A
Other languages
Chinese (zh)
Other versions
CN102660145B (en
Inventor
俞杏英
姚晨华
谢孔良
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Wanfeng Chemical Co., Ltd
Original Assignee
Zhejiang Wanfeng Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Wanfeng Chemical Co Ltd filed Critical Zhejiang Wanfeng Chemical Co Ltd
Priority to CN201210131967.4A priority Critical patent/CN102660145B/en
Publication of CN102660145A publication Critical patent/CN102660145A/en
Application granted granted Critical
Publication of CN102660145B publication Critical patent/CN102660145B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention relates to a disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof. The disperse dye composition comprises 2-4 of yellow dyes disclosed as a general formula (I), orange dyes disclosed as a general formula (II), blue dyes disclosed as a general formula (III) and red dyes disclosed as a general formula (IV), wherein the number of dyes disclosed as each general formula does not exceed two. The disperse dye composition is used for a disperse/reactive dye combination printing method. The disperse dye composition is suitable for disperse/reactive dye combination printing technique of terylene/cotton and terylene/viscose blend fabrics, and has the advantages of simple technological process, higher production efficiency, lower production cost and less printing wastewater; the printed fabric has the advantages of smooth cloth cover and favorable fabric style; and Compared with the traditional printing, the invention implements disperse/reactive dye one-step printing technology of terylene/cotton and terylene/viscose blend fabrics.

Description

Be used to disperse/active disperse dye composition and preparation and application with the slurry stamp
Technical field
The invention belongs to stamp dispersed dye and preparation thereof and Application Areas, particularly one is used to disperse/active disperse dye composition and preparation and application with the slurry stamp.
Background technology
In recent ten years; Energy shortage and problem of environmental pollution are outstanding day by day; The International Textile market competition is fierce more simultaneously; Requirement working (machining) efficiency height and tooling cost are low etc., promoted the research and development of countries in the world to the high-level efficiency dyeing and printing process, and certain expansion is all being arranged aspect used fabric, dyestuff, technology even the auxiliary agent.
Advantage such as native cellulose fibre is comfortable because of taking, aboundresources, utilizability are strong is always in occupation of critical role.Mierocrystalline cellulose BLENDED FABRIC stamp is the developing direction of important stamp, and dispersion/reactive printing product color is bright-coloured, and is soft, and product is high-grade.Polyester piece good has HS, snappiness, and characteristics such as high abrasion are widely used on industrial, civilian and national defence.Wash/cotton, wash/glue the garment material of BLENDED FABRIC, it is wear-resisting, the performance of light weight is higher than common textile garment material.
Cotton and blend polyester or interlacing product have both the advantage of two kinds of fibers simultaneously, and be complementary again not enough, not only has higher elasticity and intensity, and have good wear behavior.Because cotton/dyeing behavior and the physical and chemical performance of washing fabric have nothing in common with each other; A series of problems such as the finishing process in printing and dye-ing technology exists that technical process is long, quality is wayward, printing fastness is poor, especially staining fastness is poor, and aberration is big, uneven dyeing, back arrangement difficulty are big.On printing technique, dyestuff is dispersed dye on the best of terylene, and color fixing condition is acid, but under acidic conditions; Reactive dyestuffs are not painted basically to cotton fibre, and reactive dyestuffs must be in fixation under the alkaline condition, and generally speaking, alkaline condition can produce great effect to the terylene stamp; Under the alkaline condition, the terylene dye uptake is very low, and it is serious that look becomes; Not only influence printing fastness, stamp is stain in vain, influence quality product.Textile printing and dyeing industry is to be the course of processing of main medium with chemical assistant, water, how to reduce water, reduces the discharging of poisonous and harmful chemical, reduces generation of waste, the key that the high-grade stamp product of exploitation weaving is the printing and dyeing industry Sustainable development.The printing technique of cotton/polyester fabric; It is poor that the palpus emphasis solves with the consistency of slurry stamp; Look rate active and dispersed dye is low, look becomes big; Stain in vain with two kinds of fibers on dye the problems such as cloth cover effect that difference causes greatly; Dispersion/the activity that is applicable to stamp is with the disperse dye composition of slurry stamp and the important development direction that the stamp novel process is this series products thereof, improve simultaneously cotton/wash intertexture printing technique level to energy-saving and emission-reduction, improve product specification, and next step product development all has material impact.
Summary of the invention
Technical problem to be solved by this invention provides and a kind ofly is used to disperse/active disperse dye composition and preparation and application with the slurry stamp, and this disperse dye composition has alkaline-resisting stability, dye uptake is high, colouring evenly, redying property is good; Dispersion/activity is with the novel process of slurry stamp; The stamp flow process shortens greatly, and conserve energy is raised the efficiency; Reduce sewage discharge, save production cost.
Of the present inventionly a kind ofly be used to disperse/active disperse dye composition with the slurry stamp; This disperse dye composition comprises: 2~4 kinds of dyestuffs in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), and the dyestuff shown in each general formula is no more than two kinds;
General formula (I), (II) are (III), (IV) as follows:
Wherein, R 1, R 4, R 6, R 8Be hydrogen, methyl or methoxy; R 2Be hydrogen or methyl;
Work as R 2During for hydrogen, R 3Be 2-nitrophenyl or 2, the 4-dinitrophenyl;
Work as R 2During for methyl, ethyl or cyanoethyl, R 3Be benzyl or 2-methyl-benzyl;
R 5, R 7Be hydrogen, nitro, methyl or ethyl.
R 9Be methyl, ethyl, benzyl, 2-methyl-benzyl or 2-nitrophenyl.
Yellow dyes shown in the described general formula (I) is preferably from the compound shown in formula (I-A), (I-B), (I-C), (I-D), (I-E);
Orange dye shown in the described general formula (II) is preferably from the compound shown in formula (II-A), (II-B), (II-C);
Blue dyes shown in the described general formula (III) is preferably from the compound shown in formula (III-A), (III-B), (III-C);
Orchil shown in the described general formula (IV) is preferably from the compound shown in formula (IV-A), (IV-B), (IV-C), (IV-D);
Describedly be used to disperse/active disperse dye composition with the slurry stamp; Comprise: the combination of 2 kinds of dyestuffs shown in any one general formula in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), wherein the quality percentage composition of every kind of dyestuff is 1-99%;
Describedly be used to disperse/active disperse dye composition with the slurry stamp; Comprise: the combination of dyestuff among the 2-4 shown in any two kinds of general formulas in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), and the dyestuff shown in each general formula is no more than two kinds; Wherein the quality percentage composition of dyestuff shown in each general formula is 1-99% in two kinds of general formulas;
Describedly be used to disperse/active disperse dye composition with the slurry stamp; Comprise: the 3-4 kind dye combinations shown in any three kinds of general formulas in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), wherein the ratio of the quality percentage composition of dyestuff shown in each general formula is 1-98%: 1-98%: 1-98% in three kinds of general formulas;
Describedly be used to disperse/active disperse dye composition with the slurry stamp; Comprise: in the orchil shown in a kind of and general formula (IV) in the blue dyes shown in a kind of, the general formula (III) in the orange dye shown in a kind of, the general formula (II) in the yellow dyes shown in the general formula (I); Totally 4 kinds of dyestuffs; The quality percentage composition of the yellow dyes shown in its formula of (I) is 3~60%; The quality percentage composition of the orange dye shown in the general formula (II) is 5~55%, and the quality percentage composition of the blue dyes shown in the general formula (III) is 5~55%, and the quality percentage composition of the orchil shown in the general formula (IV) is 10~55%.
Of the present inventionly a kind ofly be used to disperse/preparation method of active disperse dye composition with the slurry stamp, comprise:
After each component is mixed in the disperse dye composition, at former dyestuffs of chemosynthesis process of preparing blended such as diazotization and couplings, then the former dyestuff of above-mentioned blended is carried out the micronize dispersion processing in the presence of auxiliary agent, commercialization becomes dispersed dye; Wherein the weight ratio of each component sum is 0.8-5 in auxiliary agent and the disperse dye composition: 1;
Or, carry out the broken dispersion processing of wet-milling and become dispersed dye after each component is mixed in the disperse dye composition;
Or each component in the disperse dye composition directly mixed, get final product.
Described auxiliary agent is dispersion agent, help in seal agent, the stablizer one or more; Described dispersion agent is the sodium naphthalene sulfonate verivate; Be dispersing agent NNO, Dispersant MF, modification Dispersant MF; Helping the seal agent is in Dyhard RU 100, urea, nicotinic acid, the nicotinic acid derivates one or more, and stablizer is one or more in sodium dihydrogen citrate, disodium citrate, trisodium citrate, sodium hydrogencarbonate, the yellow soda ash.
Described auxiliary agent is dispersion agent, help two or three in seal agent, the stablizer, and dispersion agent, to help the mass ratio of seal agent and stablizer be 60-90: 5-20: 5-20.
Of the present inventionly a kind ofly be used for disperseing/active application of starching printing method with the disperse dye composition of slurry stamp in dispersions/activity together.
Described dispersion/activity comprises with the slurry printing method:
(1) behind the processing fabric, oven dry, typing;
(2) then above-mentioned disperse dye composition and reactive dyestuffs are added in the entry, stir and make it dispersion, add urea, dissolved good dye composite;
(3) the sodium-alginate thickener is added in the entry while stirring,, get sodium alginate paste after the filtration until no macrobead; With step (2) obtain dissolve good dye composite and filter after; Add in the above-mentioned sodium alginate paste, obtain treating stamp with slurry dispersion/active composition mill base;
(4) adopt above-mentioned same slurry dispersion/active composition mill base to the textile printing that step (1) obtains, evaporate then or bake the dye composite mill base fixation that makes on the fabric; Washing, stentering forming get final product at last.
Contain alkaline agent in the sodium alginate paste described in the step (3), described alkaline agent is yellow soda ash or sodium hydrogencarbonate.
Among the present invention, said disperse dye composition basically by general formula (I), (II), (III) or two kinds of dyestuffs shown in any one structure (IV) form, based on described two kinds of dyestuffs, the quality percentage composition of every kind of dyestuff is 1-99%; Here; " basically " implication is this disperse dye composition by general formula (I), (II), (III) or the dispersed dye shown in any one structure (IV) constitute or mainly by general formula (I), (II), (III) or the dispersed dye shown in any one structure (IV) constitute, but also might contain other component that a part of auxiliary agent or a spot of impurity etc. do not influence its performance.
Among the present invention; Said disperse dye composition be general formula (I), (II), (III) or (IV) in the 2-4 kind dye combinations shown in any two kinds of structures; And the dyestuff of every kind of structure is no more than two kinds, and based on the dyestuff shown in said two kinds of structures, the quality percentage composition of the dyestuff shown in every kind of structure is 1-99%; Here, the implication of " basically " is the same.
Among the present invention; Said disperse dye composition be general formula (I), (II), (III) or (IV) in the 3-4 kind dye combinations shown in any three kinds of structures; Based on the dyestuff shown in said three kinds of structures; The quality percentage composition of the dyestuff shown in every kind of structure is 1-98%, and here, the implication of " basically " is the same.
Among the present invention; Said disperse dye composition is general formula (I), (II), (III) and (IV) combination of 4 kinds of dyestuffs shown in four kinds of structures; Based on the dyestuff shown in said four kinds of structures, the quality percentage composition of the dyestuff shown in the general formula (I) is 3~60%, and the quality percentage composition of the dyestuff shown in the general formula (II) is 5~55%; The quality percentage composition of the dyestuff shown in the general formula (III) is 5~55%; The quality percentage composition of the dyestuff shown in the general formula (IV) is 10~55%, and here, the implication of " basically " is the same.
Prepare the employed general formula of disperse dye composition of the present invention (I), (II), (III) and (IV) shown in dye composition be existing compound in the prior art; Or disclosed dyestuff of some patent or similar these dyestuff, with the method for wherein record or similarly method can make at an easy rate.
The dye preparations of disperse dye composition of the present invention configuration can be the liquid state, emulsifiable paste attitude after the micro-ion dispersion treatment or supply with dyeing with powdery, graininess that spray method etc. is carried out after the drying treatment.Particularly; When mixing colouring agent of the present invention adds assistant composition when being mixed with corresponding solid dye goods; The weight percentage of disperse dye composition is preferably 10-60%, and the weight percentage of assistant composition is 40-90% (summation that refers to three kinds of interpolations).When described mixing colouring agent adding auxiliary agent was mixed with the corresponding liquid dye preparations, the weight percentage of disperse dye composition was preferably 10-30%, and the weight percentage of auxiliary agent is preferably 20-45%, and all the other are water.
The disperse dye composition that the present invention forms can be starched stamp together with reactive dyestuffs; Reactive dyestuffs can use conventional chloro-s-triazine reactive dyestuffs and a vinyl-sulfone reactive dyes, and chloro-s-triazine reactive dyestuffs and vinyl-sulfone reactive dyes mixed active base reactive dyestuffs.The present composition is particularly useful for washing/and cotton, wash/glue the same printing technology of starching of BLENDED FABRIC dispersions/reactive dyestuffs, have the effect that cloth cover is clean and tidy, Fabric Style is good; Simultaneously, realized washing/cotton, washed/glue one step of BLENDED FABRIC dispersion/reactive dyestuffs printing technique, the technical process means, production efficiency improves, and production cost and printing waste water reduce.
Beneficial effect:
(1) disperse dye composition provided by the present invention has alkaline-resisting stability, can be in fixation under the alkaline condition;
(2) the slurry good stability of disperse dye composition provided by the present invention and reactive printing; Disperse dye composition can also with the slurry stamp in the catalytic activity dyestuff to the cellulosic fabric fixation; Therefore in activity slurry together; Can not add new laking agent, the compsn dye uptake of dyestuff is high, colouring is even, redying property is good, can guarantee that the dye uptake of reactive dyestuffs is high, paint evenly;
(3) disperse dye composition provided by the present invention does not require neutralization to the washing effect of fabric pretreatment, but direct printing need not repeatedly wash, can realize washing/cotton, wash/glue the same needs of starching printing technology of BLENDED FABRIC dispersions/reactive dyestuffs;
(4) dispersion provided by the present invention/activity is with the novel process of slurry stamp, and the stamp flow process shortens greatly, and conserve energy is raised the efficiency, and reduces sewage discharge, saves production cost;
(5) fabrics cloth cover behind the disperse dye composition stamp provided by the present invention is clean and tidy, fabric is smooth, Fabric Style and feel are splendid.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Percentage composition described in the following embodiment is the quality percentage composition.
Embodiment 1
With the former dyestuff of dispersed dye shown in 100kg formula (II-B), the 98kg formula (II-C), 250kg Dispersant MF, 50kg Dyhard RU 100,25kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 2
With the former dyestuff of dispersed dye shown in 98kg formula (II-B), the 100kg formula (II-C), 200kg Dispersant MF, 25kg Dyhard RU 100,30kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 3
With the former dyestuff of dispersed dye shown in 50kg formula (II-B), the 150kg formula (II-C), 200kg Dispersant MF, 25kg nicotinic acid, 30kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 4
With the former dyestuff of dispersed dye shown in 100kg formula (II-B), the 98kg formula (II-C), 200kg Dispersant MF, 25kg nicotinic acid, 30kg yellow soda ash grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 5
With the former dyestuff of dispersed dye shown in 98kg formula (II-B), the 100kg formula (II-C), 200kg Dispersant MF, 59kg nicotinic acid, 30kg trisodium citrate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 6
With the former dyestuff of dispersed dye shown in 100kg formula (II-B), the 98kg formula (II-C), 200kg Dispersant MF, 59kg nicotinic acid, 20kg urea, 25kg trisodium citrate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good hues of orange of fabric each item fastness ability.
Embodiment 7
With the former dyestuff of dispersed dye shown in 100kg formula (III-A), the 60kg formula (IV-C), 450kg modification Dispersant MF, 50kg Dyhard RU 100,25kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good blue color of fabric each item fastness ability.
Embodiment 8
With the former dyestuff of dispersed dye shown in 60kg formula (III-A), the 100kg formula (IV-C), 450kg modification Dispersant MF, 25kg Dyhard RU 100,30kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good blue color of fabric each item fastness ability.
Embodiment 9
With the former dyestuff of dispersed dye shown in 90kg formula (III-A), the 70kg formula (IV-C), 450kg modification Dispersant MF, 25kg nicotinic acid, 30kg sodium hydrogencarbonate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good blue color of fabric each item fastness ability.
Embodiment 10
With the former dyestuff of dispersed dye shown in 80kg formula (III-A), the 80kg formula (IV-C), 450kg modification Dispersant MF, 59kg nicotinic acid, 30kg trisodium citrate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good blue color of fabric each item fastness ability.
Embodiment 11
With the former dyestuff of dispersed dye shown in 100kg formula (III-A), the 60kg formula (IV-C), 450kg modification Dispersant MF, 59kg nicotinic acid, 20kg urea, 25kg trisodium citrate grind dispersion with shredder after adding water making beating mixing, and spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good blue color of fabric each item fastness ability.
Embodiment 12
With the former dyestuff of dispersed dye shown in 100kg formula (III-A), 60kg formula (IV-C), the 50kg formula (II-C), 450kg modification Dispersant MF, 59kg nicotinic acid; 20kg urea, 25kg trisodium citrate grind dispersion with shredder after adding water making beating mixing; Spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good bluish voilet tone of fabric each item fastness ability.
Embodiment 13
With the former dyestuff of dispersed dye shown in 50kg formula (II-C), 100kg formula (III-A), 60kg formula (IV-C), the 30kg (I-E), 450kg modification Dispersant MF, 59kg nicotinic acid; 20kg urea, 25kg trisodium citrate grind dispersion with shredder after adding water making beating mixing; Spraying drying gets product.This dyestuff is suitable for the novel process of dispersion/activity with the slurry stamp, can offer the good purple tone of fabric each item fastness ability.。
Embodiment 14
Polyester/cotton blended fabric dispersion/reactive dyestuffs are with the slurry printing technology.
Stamp prescription and technology
By this step stamp, obtain bright-coloured orange fabric, fabrics cloth cover is clean and tidy, and Dry Sack is even, the smooth softness of feel.Fastness detected result such as table 1:
Table 1
Embodiment 15
Wash/glue BLENDED FABRIC
Stamp prescription and technology
By this step stamp, obtain bright-coloured hyacinthine fabric, fabrics cloth cover is clean and tidy, and Dry Sack is even, the smooth softness of feel.Fastness detected result such as table 2:
Table 2
Comparative example 1
With slurry fabric is carried out stamp with made disperse dye composition and reactive dyestuffs in the commercially available DISPERSE ORANGE 30 200 5R alternate embodiment 1, fabric is painted hardly, and dyestuff decomposes fully.And bright-coloured through the fabric color of embodiment 1 stamp, fabrics cloth cover is clean and tidy, and Dry Sack is even, the smooth softness of feel.
Comparative example 2
The disperse dye composition and the reactive dyestuffs that substitute among the dyeing embodiment 2 with commercially available DISPERSE BLUE 2BLN carry out stamp with slurry to fabric, and fabric is painted hardly, and dyestuff decomposes serious.And bright-coloured through embodiment 2 painted fabric colors, fabrics cloth cover is clean and tidy, and Dry Sack is even, the smooth softness of feel.
In the time of from comparative example 1 and 2, can seeing single use dispersed dye of the prior art and reactive dyestuffs with the slurry stamp, fabric is painted hardly, and dyestuff decomposes serious.And the fabric color of using disperse dye composition provided by the present invention and the same slurry of reactive dyestuffs stamp is bright-coloured, and fabrics cloth cover is smooth, and Dry Sack is even, the smooth softness of feel.

Claims (10)

1. one kind is used to disperse/active disperse dye composition with the slurry stamp; This disperse dye composition comprises: 2~4 kinds of dyestuffs in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), and the dyestuff shown in each general formula is no more than two kinds;
General formula (I), (II) are (III), (IV) as follows:
Wherein, R 1, R 4, R 6, R 8Be hydrogen, methyl or methoxy; R 2Be hydrogen or methyl;
Work as R 2During for hydrogen, R 3Be 2-nitrophenyl or 2, the 4-dinitrophenyl;
Work as R 2During for methyl, ethyl or cyanoethyl, R 3Be benzyl or 2-methyl-benzyl;
R 5, R 7Be hydrogen, nitro, methyl or ethyl.
R 9Be methyl, ethyl, benzyl, 2-methyl-benzyl or 2-nitrophenyl.
2. according to claim 1ly a kind ofly be used to disperse/active disperse dye composition with the slurry stamp, it is characterized in that: the yellow dyes shown in the described general formula (I) is selected from the compound shown in formula (I-A), (I-B), (I-C), (I-D), (I-E);
Orange dye shown in the described general formula (II) is selected from the compound shown in formula (II-A), (II-B), (II-C);
Blue dyes shown in the described general formula (III) is selected from the compound shown in formula (III-A), (III-B), (III-C);
Orchil shown in the described general formula (IV) is selected from the compound shown in formula (IV-A), (IV-B), (IV-C), (IV-D);
3. according to claim 1ly a kind ofly be used to disperse/active disperse dye composition with the slurry stamp; It is characterized in that: described disperse dye composition; Comprise: the combination of 2 kinds of dyestuffs shown in any one general formula in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), wherein the quality percentage composition of every kind of dyestuff is 1-99%;
Or described disperse dye composition; Comprise: the combination of dyestuff among the 2-4 shown in any two kinds of general formulas in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), and the dyestuff shown in each general formula is no more than two kinds; Wherein the quality percentage composition of dyestuff shown in each general formula is 1-99% in two kinds of general formulas;
Or described disperse dye composition; Comprise: the 3-4 kind dye combinations shown in any three kinds of general formulas in the orchil shown in the blue dyes shown in the orange dye shown in the yellow dyes shown in the general formula (I), the general formula (II), the general formula (III), the general formula (IV), wherein the ratio of the quality percentage composition of dyestuff shown in each general formula is 1-98%: 1-98%: 1-98% in three kinds of general formulas;
Or described disperse dye composition; Comprise: in the orchil shown in a kind of and general formula (IV) in the blue dyes shown in a kind of, the general formula (III) in the orange dye shown in a kind of, the general formula (II) in the yellow dyes shown in the general formula (I); Totally 4 kinds of dyestuffs; The quality percentage composition of the yellow dyes shown in its formula of (I) is 3~60%; The quality percentage composition of the orange dye shown in the general formula (II) is 5~55%, and the quality percentage composition of the blue dyes shown in the general formula (III) is 5~55%, and the quality percentage composition of the orchil shown in the general formula (IV) is 10~55%.
4. describedly a kind ofly be used to disperse/preparation method of active disperse dye composition with the slurry stamp like claim 1,2 or 3, comprise:
After each component was mixed in the disperse dye composition, the former dyestuff of preparation blended carried out the micronize dispersion processing with the former dyestuff of above-mentioned blended then in the presence of auxiliary agent in diazotization and coupling, and commercialization becomes dispersed dye; Wherein the weight ratio of each component sum is 0.8-5 in auxiliary agent and the disperse dye composition: 1;
Or, carry out the broken dispersion processing of wet-milling and become dispersed dye after each component is mixed in the disperse dye composition;
Or each component in the disperse dye composition directly mixed, get final product.
5. according to claim 4ly a kind ofly be used to disperse/preparation method of active disperse dye composition with the slurry stamp, it is characterized in that: described auxiliary agent is dispersion agent, help in seal agent, the stablizer one or more.
6. according to claim 5ly a kind ofly be used to disperse/preparation method of active disperse dye composition with the slurry stamp; It is characterized in that: described auxiliary agent is dispersion agent, help two or three in seal agent, the stablizer, and dispersion agent, to help the mass ratio of seal agent and stablizer be 60-90: 5-20: 5-20.
7. describedly a kind ofly be used to disperse/preparation method of active disperse dye composition with the slurry stamp according to claim 5 or 6; It is characterized in that: described dispersion agent is the sodium naphthalene sulfonate verivate; Be dispersing agent NNO, Dispersant MF, modification Dispersant MF; Helping the seal agent is in Dyhard RU 100, urea, nicotinic acid, the nicotinic acid derivates one or more, and stablizer is one or more in sodium dihydrogen citrate, disodium citrate, trisodium citrate, sodium hydrogencarbonate, the yellow soda ash.
8. describedly a kind ofly be used for disperseing/active application of starching printing method with the disperse dye composition of slurry stamp in dispersions/activity together like claim 1,2 or 3.
9. according to claim 8ly a kind ofly be used for disperseing/active disperse dye composition with the slurry stamp is in the application of dispersions/activity with the slurry printing method, and it is characterized in that: described dispersion/activity is starched printing method together, comprising:
(1) behind the processing fabric, oven dry, typing;
(2) then disperse dye composition and reactive dyestuffs are added in the entry, stir and make it dispersion, add urea, dissolved good dye composite;
(3) the sodium-alginate thickener is added in the entry while stirring, after the filtration sodium alginate paste, with step (2) obtain dissolve good dye composite and filter after, add in the above-mentioned sodium alginate paste, obtain with slurry dispersion/active composition mill base;
(4) adopt above-mentioned same slurry dispersions/active composition mill base to the textile printing that step (1) obtains, evaporate then or bake, wash at last, stentering forming gets final product.
10. according to claim 9ly a kind ofly be used for disperseing/active application of starching printing method with the disperse dye composition of slurry stamp in dispersions/activity together; It is characterized in that: contain alkaline agent in the sodium alginate paste described in the step (3), described alkaline agent is yellow soda ash or sodium hydrogencarbonate.
CN201210131967.4A 2012-04-28 2012-04-28 Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof Active CN102660145B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210131967.4A CN102660145B (en) 2012-04-28 2012-04-28 Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210131967.4A CN102660145B (en) 2012-04-28 2012-04-28 Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof

Publications (2)

Publication Number Publication Date
CN102660145A true CN102660145A (en) 2012-09-12
CN102660145B CN102660145B (en) 2014-06-25

Family

ID=46769735

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210131967.4A Active CN102660145B (en) 2012-04-28 2012-04-28 Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof

Country Status (1)

Country Link
CN (1) CN102660145B (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660146A (en) * 2012-04-28 2012-09-12 浙江万丰化工有限公司 Oxidation-resistant disperse dye composition and preparation and application thereof
CN103450706A (en) * 2013-09-07 2013-12-18 张家港市杨舍丝印工艺厂 Dye composition (red brown) and preparation method thereof
CN103509372A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Yellow dye composition and preparation method thereof
CN103509373A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Blue dye composition and preparation method thereof
CN103509374A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Red dye composition and preparation method thereof
CN104151866A (en) * 2014-07-22 2014-11-19 俞杏英 Alkali-resistant disperse dye composition based on thiazole heterocycle red dye containing benzoyloxy group and application of alkali-resistant disperse dye composition
CN104263007A (en) * 2014-08-20 2015-01-07 张家港市振新印染有限公司 High-fastness reactive dye
CN104327548A (en) * 2014-10-08 2015-02-04 浙江龙盛集团股份有限公司 Disperse yellow and disperse orange dye composition
CN104389196A (en) * 2014-11-04 2015-03-04 常熟市威廉蒙森服装有限公司 Preparation method of novel organic color paste used for printing and dyeing menswear
CN104710809A (en) * 2013-12-16 2015-06-17 上海安诺其集团股份有限公司 Bright yellow disperse dye
CN104711868A (en) * 2013-12-16 2015-06-17 上海安诺其集团股份有限公司 Application of bright yellow disperse dye
CN105385192A (en) * 2015-11-30 2016-03-09 无锡新德印染制品有限公司 Green and environment-friendly red reactive dye composite
CN105623298A (en) * 2016-02-25 2016-06-01 浙江龙盛集团股份有限公司 Orange disperse dye compound and application thereof
CN106700653A (en) * 2015-11-17 2017-05-24 浙江迪邦化工有限公司 Disperse dye paste capable of effectively retarding precipitation and preparation method
CN107090192A (en) * 2017-05-24 2017-08-25 上海贝通色彩科技有限公司 A kind of alkali resistance disperse dye composition
CN108867104A (en) * 2017-05-10 2018-11-23 兰溪市漫真服饰有限公司 A kind of same slurry method for transfer printing of cotton-polyester blend fabric
CN112480711A (en) * 2020-12-11 2021-03-12 九江富达实业有限公司 Preparation method and application of high-strength disperse brilliant blue dye

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08217987A (en) * 1995-02-16 1996-08-27 Kiwa Kagaku Kogyo Kk Black disperse dye composition
US5744588A (en) * 1995-10-18 1998-04-28 Dystar Japan Ltd. Blue type disperse dye mixture and process for its preparation
US5868802A (en) * 1996-04-19 1999-02-09 Nippon Kayaku Co., Ltd. Disperse dye composition and method for dyeing hydrophobic fiber materials with the composition
GB2346150A (en) * 1999-02-01 2000-08-02 Ciba Sc Holding Ag Dye mixtures and their use for dyeing or printing cellulose acetate-containing fibre materials
KR100581542B1 (en) * 2005-09-01 2006-05-22 공명도 Black and navy blue disperse dye composition having excellent moisture resistance
CN1927947A (en) * 2006-04-11 2007-03-14 杭州吉华化工有限公司 Red dispersion dyes mixture
CN101974254A (en) * 2010-10-26 2011-02-16 浙江闰土股份有限公司 Black and blue series disperse dye composition
CN102618078A (en) * 2012-03-07 2012-08-01 浙江万丰化工有限公司 Disperse dye composition, dyeing method and preparation method of disperse dye composition
CN102660146A (en) * 2012-04-28 2012-09-12 浙江万丰化工有限公司 Oxidation-resistant disperse dye composition and preparation and application thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08217987A (en) * 1995-02-16 1996-08-27 Kiwa Kagaku Kogyo Kk Black disperse dye composition
US5744588A (en) * 1995-10-18 1998-04-28 Dystar Japan Ltd. Blue type disperse dye mixture and process for its preparation
US5868802A (en) * 1996-04-19 1999-02-09 Nippon Kayaku Co., Ltd. Disperse dye composition and method for dyeing hydrophobic fiber materials with the composition
GB2346150A (en) * 1999-02-01 2000-08-02 Ciba Sc Holding Ag Dye mixtures and their use for dyeing or printing cellulose acetate-containing fibre materials
KR100581542B1 (en) * 2005-09-01 2006-05-22 공명도 Black and navy blue disperse dye composition having excellent moisture resistance
CN1927947A (en) * 2006-04-11 2007-03-14 杭州吉华化工有限公司 Red dispersion dyes mixture
CN101974254A (en) * 2010-10-26 2011-02-16 浙江闰土股份有限公司 Black and blue series disperse dye composition
CN102618078A (en) * 2012-03-07 2012-08-01 浙江万丰化工有限公司 Disperse dye composition, dyeing method and preparation method of disperse dye composition
CN102660146A (en) * 2012-04-28 2012-09-12 浙江万丰化工有限公司 Oxidation-resistant disperse dye composition and preparation and application thereof

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660146A (en) * 2012-04-28 2012-09-12 浙江万丰化工有限公司 Oxidation-resistant disperse dye composition and preparation and application thereof
CN103450706A (en) * 2013-09-07 2013-12-18 张家港市杨舍丝印工艺厂 Dye composition (red brown) and preparation method thereof
CN103509372A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Yellow dye composition and preparation method thereof
CN103509373A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Blue dye composition and preparation method thereof
CN103509374A (en) * 2013-09-07 2014-01-15 张家港市杨舍丝印工艺厂 Red dye composition and preparation method thereof
CN104711868B (en) * 2013-12-16 2018-10-16 上海安诺其集团股份有限公司 A kind of application of bright yellow disperse dyes
CN104710809B (en) * 2013-12-16 2017-07-18 上海安诺其集团股份有限公司 A kind of bright yellow disperse dyes
CN104710809A (en) * 2013-12-16 2015-06-17 上海安诺其集团股份有限公司 Bright yellow disperse dye
CN104711868A (en) * 2013-12-16 2015-06-17 上海安诺其集团股份有限公司 Application of bright yellow disperse dye
CN104151866A (en) * 2014-07-22 2014-11-19 俞杏英 Alkali-resistant disperse dye composition based on thiazole heterocycle red dye containing benzoyloxy group and application of alkali-resistant disperse dye composition
CN104151866B (en) * 2014-07-22 2016-06-08 俞杏英 A kind of alkaline-proof disperse dyes compositions based on the thiazole heterocycle orchil containing benzoyloxy and application thereof
CN104263007A (en) * 2014-08-20 2015-01-07 张家港市振新印染有限公司 High-fastness reactive dye
CN104263007B (en) * 2014-08-20 2016-04-06 张家港市振新印染有限公司 A kind of high light fastness reactive dyestuffs
CN104327548A (en) * 2014-10-08 2015-02-04 浙江龙盛集团股份有限公司 Disperse yellow and disperse orange dye composition
CN104327548B (en) * 2014-10-08 2016-08-10 浙江龙盛集团股份有限公司 A kind of disperse yellow is to orange compositions
CN104389196A (en) * 2014-11-04 2015-03-04 常熟市威廉蒙森服装有限公司 Preparation method of novel organic color paste used for printing and dyeing menswear
CN106700653A (en) * 2015-11-17 2017-05-24 浙江迪邦化工有限公司 Disperse dye paste capable of effectively retarding precipitation and preparation method
CN106700653B (en) * 2015-11-17 2018-12-11 浙江迪邦化工有限公司 A kind of disperse dyes slurry and preparation method effectively slowing down precipitating
CN105385192A (en) * 2015-11-30 2016-03-09 无锡新德印染制品有限公司 Green and environment-friendly red reactive dye composite
CN105623298A (en) * 2016-02-25 2016-06-01 浙江龙盛集团股份有限公司 Orange disperse dye compound and application thereof
CN108867104A (en) * 2017-05-10 2018-11-23 兰溪市漫真服饰有限公司 A kind of same slurry method for transfer printing of cotton-polyester blend fabric
CN107090192A (en) * 2017-05-24 2017-08-25 上海贝通色彩科技有限公司 A kind of alkali resistance disperse dye composition
CN107090192B (en) * 2017-05-24 2018-08-03 上海贝通色彩科技有限公司 A kind of alkali resistance disperse dye composition
CN112480711A (en) * 2020-12-11 2021-03-12 九江富达实业有限公司 Preparation method and application of high-strength disperse brilliant blue dye

Also Published As

Publication number Publication date
CN102660145B (en) 2014-06-25

Similar Documents

Publication Publication Date Title
CN102660145B (en) Disperse dye composition for disperse/reactive dye combination printing, and preparation and application thereof
CN102660146B (en) Oxidation-resistant disperse dye composition and preparation and application thereof
CN101265369B (en) Azo dye composition and application thereof
CN102634998B (en) Printing gum for polyester fabrics and novel low-gum printing method
CN102031017A (en) Disperse dye composition and application thereof
CN102746712A (en) Disperse dye composition, dye product and application
CN101735663A (en) Composite black disperse dye
CN101806002A (en) Accelerating agent for reactive dyeing, and preparation method and applications thereof
CN101671492B (en) Composition of cobaly blue dispersed dye
CN102702790B (en) Disperse black azo dye mixture
CN101935465A (en) Disperse yellow brown dye composition
CN101735664A (en) Disperse scarlet dye composition
CN104292881A (en) Active red dye composition and dye product
CN106977976A (en) Yellow disperse dye compound and its synthetic method and tint applications
CN104710841A (en) Red reactive dye composition
CN102127315A (en) Blue disperse dye composition with high light fastness and application thereof
CN105647238B (en) A kind of grey reactive dye compound and its production and use
CN102584794A (en) Active light yellow LA and preparation process thereof
CN101760046A (en) Dispersive black dye composition
CN1995153A (en) Composite active dye
CN102702788A (en) Dispersed azo dye mixture
CN102504595A (en) Azo dye composition, preparation method thereof and use method thereof
CN102888129B (en) Disperse dye composition and applications thereof
CN102372932A (en) Disperse red dye composition
CN105111785A (en) Dark disperse dye composition and applications

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 312073 new second village, Ma On Zhen, Keqiao District, Shaoxing, Zhejiang

Patentee after: Zhejiang Wanfeng Chemical Co., Ltd

Address before: 312073 new village, Ma on Town, Shaoxing, Zhejiang

Patentee before: Zhejiang Wanfeng Chemical Co., Ltd.