CN102634906A - High-intensity high-impact-resistant glass fiber cloth and preparation method thereof - Google Patents
High-intensity high-impact-resistant glass fiber cloth and preparation method thereof Download PDFInfo
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- CN102634906A CN102634906A CN2012101356940A CN201210135694A CN102634906A CN 102634906 A CN102634906 A CN 102634906A CN 2012101356940 A CN2012101356940 A CN 2012101356940A CN 201210135694 A CN201210135694 A CN 201210135694A CN 102634906 A CN102634906 A CN 102634906A
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- glass fabric
- glass fiber
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- 239000004744 fabrics Substances 0.000 title claims abstract description 44
- 239000003365 glass fibers Substances 0.000 title claims abstract description 22
- 238000002360 preparation methods Methods 0.000 title claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- 239000000314 lubricants Substances 0.000 claims abstract description 8
- 229920000728 polyesters Polymers 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 229920002635 polyurethanes Polymers 0.000 claims abstract description 8
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- 239000007822 coupling agents Substances 0.000 claims abstract description 7
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 7
- 239000007787 solids Substances 0.000 claims abstract description 6
- 239000011901 water Substances 0.000 claims abstract description 6
- 238000009941 weaving Methods 0.000 claims abstract description 5
- 239000011521 glasses Substances 0.000 claims description 36
- 238000000034 methods Methods 0.000 claims description 20
- 238000004513 sizing Methods 0.000 claims description 16
- 241000209094 Oryza Species 0.000 claims description 7
- 235000007164 Oryza sativa Nutrition 0.000 claims description 7
- 235000009566 rice Nutrition 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 abstract 3
- 281000026093 RS Technologies companies 0.000 abstract 1
- 229920005989 resins Polymers 0.000 description 7
- 239000000835 fibers Substances 0.000 description 6
- 239000011347 resins Substances 0.000 description 6
- 239000002243 precursors Substances 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004917 carbon fibers Substances 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
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- 229910000272 alkali metal oxides Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering processes Methods 0.000 description 1
- 230000002349 favourable Effects 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
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- BLRPTPMANUNPDV-UHFFFAOYSA-N silane Chemical compound data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
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Abstract
Description
Technical field
The present invention relates to a kind of glass fabric and preparation method thereof, be specifically related to a kind of high-strength high-impact glass fabric and preparation method thereof.
Background technology
Glass fabric is present modal a kind of reinforcing material, but glass fibre is with resin-bonded the time, owing to have the mechanics plane of weakness between glass fibre and the resin, therefore layering easily.And glass fibre can receive the effect of inherent strain in forming process, and in process, can receive the effect of external mechanical force, therefore defective such as a little less than some high-strength high-impact fields will exist intensity difference, impact resistance.
Therefore, at present in high-strength high-impact field (like the helmet, bumper, yacht, fishing boat and sports equipment etc.), often select the carbon fiber of intensity height, good impact resistance for use, but the price of carbon fiber is very expensive.
Summary of the invention
One of the object of the invention is to address the above problem, and provides a kind of and not only can combine well with resin, but also goes for the high-strength high-impact glass fabric in high-strength high-impact field.
Another object of the present invention is to provide the preparation method of above-mentioned high-strength high-impact glass fabric.
The technical scheme that realizes one of the object of the invention is: a kind of high-strength high-impact glass fabric; It is to be interweaved by warp thread and weft yarn to form; Said warp thread and weft yarn all are glass fibres that surfaces coated is covered with sizing agent; Said sizing agent by coupling agent, lubricant, epoxy film forming agent, polyester film forming agent, polyurethane film-forming agent and water according to 0.4: 0.4: 4.5: 1.8: 0.4: 92.5 weight ratio mixes, and the solids content in the sizing agent is 5.0%～7.0%; The moisture content of glass fabric≤0.20%, combustible content are 0.6%～1.0%; The warp-wise intensity of glass fabric is 1600N/25mm～3000N/25mm, and latitudinal strength is 1500N/25mm～1800N/25mm.
The mass area ratio of said glass fabric is 250 ± 20g/m 2, warp-wise intensity is 1600N/25mm～1800N/25mm, latitudinal strength is 1500N/25mm～1600N/25mm.
The mass area ratio of said glass fabric is 300 ± 24g/m 2, warp-wise intensity is 2000N/25mm～2200N/25mm, latitudinal strength is 1700N/25mm～1800N/25mm.
The mass area ratio of said glass fabric is 400 ± 32g/m 2, warp-wise intensity is 2500N/25mm～2700N/25mm, latitudinal strength is 1450N/25mm～1550N/25mm.
The mass area ratio of said glass fabric is 500 ± 40g/m 2, warp-wise intensity is 2800N/25mm～3000N/25mm, latitudinal strength is 1600N/25mm～1700N/25mm.
The technical scheme that realizes another purpose of the present invention is: a kind of preparation method of high-strength high-impact glass fabric comprises drawing process, twisting process and weaving process; The temperature of said drawing process is 1250 ± 10 ℃, and drawing process also is included in filament surfaces and applies sizing agent; Said sizing agent by coupling agent, lubricant, epoxy film forming agent, polyester film forming agent, polyurethane film-forming agent and water according to 0.4: 0.4: 4.5: 1.8: 0.4: 92.5 weight ratio mixes, and the solids content in the sizing agent is 5.0%～7.0%.
The twist of said twisting process is 35 ± 3 sth. made by twisting/rice, twists with the fingers to twisting with the fingers for Z.
The good effect that the present invention has: (1) high-strength high-impact glass fabric of the present invention can combine with different resin system, comprises thermosetting resin and thermoplastic resin, and can layering when combining.(2) high-strength high-impact glass fabric of the present invention has higher intensity and favorable shock resistance; Go for high-strength high-impact fields such as the helmet, bumper, yacht, fishing boat and sports equipment, greatly reduce cost than carbon fiber.(3) the present invention passes through at the special sizing agent of glass fiber precursor surface-coated; Glass fibre is soaked into fast; Thereby improved the textile performance of glass fibre; Effectively avoid the loss of strength of glass fibre in fabrication processes, improved the binding ability of glass fibre and resin, and then improved the intensity of glass fabric.(4) institutional framework of glass fabric of the present invention is twill or satin weave; Can reduce the flexing degree and the intertwined point of fiber like this; Keep the straight of warp thread and weft yarn; Softness is abundant again, is convenient to when being impacted, can instantaneous impact stress be disperseed to all directions, improves anti-secondary pulse intensity.(5) the present invention is through carrying out preferably the temperature of drawing process and the single fiber diameter of precursor, thereby can further improve the intensity of glass fibre.
The specific embodiment
(embodiment 1)
The high-strength high-impact glass fabric of present embodiment is to be interweaved by warp thread and weft yarn to form.
The preparation method of the high-strength high-impact glass fabric of present embodiment is following:
Drawing process: e-glass marble (alkali metal oxide content≤0.8%) is melted down at 1250 ± 10 ℃, is that the platinum-rhodium alloy bushing of 2.0mm is drawn into precursor through 400 holes, aperture then.In pulling process, filament surfaces applies one deck sizing agent.This sizing agent by coupling agent, lubricant, epoxy film forming agent, polyester film forming agent, polyurethane film-forming agent and water according to 0.4: 0.4: 4.5: 1.8: 0.4: 92.5 weight ratio mixes; Solids content is 5.0%～7.0% in the sizing agent, and combustible content is 0.6%～1.0%.Said coupling agent adopts is that the trade mark that the Nanjing Xiang flies chemistry institute production is the silane coupler of KH-570; Said lubricant adopts is that the trade mark that Yixing gold ancient cooking vessel experimental assembly Co., Ltd produces is 3018 lubricant; What said epoxy film forming agent adopted is the APR resin that Yixing gold ancient cooking vessel experimental assembly Co., Ltd produces; What said polyester film forming agent adopted is that the trade mark that Yixing gold ancient cooking vessel experimental assembly Co., Ltd produces is the polyester film forming agent of SR-1, and said polyurethane film-forming agent is adopted is that the trade mark of Nanjing Glass Fibre Research and Design Institute production is the polyurethane film-forming agent of NBS-430.
Twisting process: precursor is twisted resultant yarn on twisting equipment, twist with the fingers to being the Z sth. made by twisting, the twist is 35 sth. made by twisting/rice.
Weaving process: will twist good yarn according to counting 96tex, single fiber diameter 11.0 μ m through yarn number, being placed on the creel through close 13.6/cm; Wear palm fibre then; Then count 96tex, single fiber diameter 11.0 μ m, 11.2/cm of filling density, the long 50m/ volume of volume looming weaving according to the latitude yarn number again; Drying and shaping 2h under 80 ± 5 ℃ temperature at last obtains the high-strength high-impact glass fabric of moisture content≤0.20%.
The warp-wise intensity of the glass fabric that present embodiment makes is 1600N/25mm～1800N/25mm, and latitudinal strength is 1500N/25mm～1600N/25mm.
(embodiment 2～embodiment 4)
Each embodiment and embodiment 1 are basic identical, and difference is seen table 1.
Table 1
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210135694.0A CN102634906B (en) | 2012-05-04 | 2012-05-04 | High-intensity high-impact-resistant glass fiber cloth and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210135694.0A CN102634906B (en) | 2012-05-04 | 2012-05-04 | High-intensity high-impact-resistant glass fiber cloth and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102634906A true CN102634906A (en) | 2012-08-15 |
| CN102634906B CN102634906B (en) | 2014-02-05 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102926100A (en) * | 2012-11-16 | 2013-02-13 | 江苏九鼎新材料股份有限公司 | Weaving technology of high-strength glass fiber reinforcing cloth |
| CN103388215A (en) * | 2013-07-31 | 2013-11-13 | 吴江市欧冠纺织有限公司 | Difficult-to-scratch lace fabric |
| CN104233587A (en) * | 2014-09-19 | 2014-12-24 | 南京春辉科技实业有限公司 | Enhanced optical fiber cloth liner for artificial transparent stone and preparation method of enhanced optical fiber cloth liner |
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| CN109881299A (en) * | 2019-03-01 | 2019-06-14 | 杭州鹏图化纤有限公司 | A kind of Wear-proof non-woven fabric and preparation method thereof |
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| CN102926100A (en) * | 2012-11-16 | 2013-02-13 | 江苏九鼎新材料股份有限公司 | Weaving technology of high-strength glass fiber reinforcing cloth |
| CN103388215A (en) * | 2013-07-31 | 2013-11-13 | 吴江市欧冠纺织有限公司 | Difficult-to-scratch lace fabric |
| CN105369437B (en) * | 2014-09-10 | 2017-04-12 | 江苏理工学院 | Method for preparing polyurethane glass fiber composite fiber cloth |
| CN104264326A (en) * | 2014-09-10 | 2015-01-07 | 江苏理工学院 | Method for preparing polyurethane glass fiber composite fiber cloth |
| CN104264326B (en) * | 2014-09-10 | 2016-01-06 | 江苏理工学院 | The preparation method of polyurethane glass fiber composite cloth |
| CN105369437A (en) * | 2014-09-10 | 2016-03-02 | 江苏理工学院 | Method for preparing polyurethane glass fiber composite fiber cloth |
| CN105274706B (en) * | 2014-09-10 | 2017-01-04 | 江苏理工学院 | A kind of preparation method of polyurethane glass fiber composite fiber cloth |
| CN104233587B (en) * | 2014-09-19 | 2016-01-20 | 南京春辉科技实业有限公司 | A kind of artificial transparent stone enhanced fiber shield and preparation method thereof |
| CN104233587A (en) * | 2014-09-19 | 2014-12-24 | 南京春辉科技实业有限公司 | Enhanced optical fiber cloth liner for artificial transparent stone and preparation method of enhanced optical fiber cloth liner |
| CN106676698A (en) * | 2017-03-10 | 2017-05-17 | 海宁市德昌纺织有限责任公司 | Processing method of high-elasticity light and thin composite yarns |
| CN109355776A (en) * | 2018-11-02 | 2019-02-19 | 山东谦津电子科技有限公司 | The overweight weaving process method for thickening electronic-grade glass fiber cloth |
| CN109881299A (en) * | 2019-03-01 | 2019-06-14 | 杭州鹏图化纤有限公司 | A kind of Wear-proof non-woven fabric and preparation method thereof |
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