CN102605604A - Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation - Google Patents
Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation Download PDFInfo
- Publication number
- CN102605604A CN102605604A CN2012100642663A CN201210064266A CN102605604A CN 102605604 A CN102605604 A CN 102605604A CN 2012100642663 A CN2012100642663 A CN 2012100642663A CN 201210064266 A CN201210064266 A CN 201210064266A CN 102605604 A CN102605604 A CN 102605604A
- Authority
- CN
- China
- Prior art keywords
- dyeing
- polishing
- enzyme preparation
- deoxidizing
- bath process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses an enzyme preparation for a deoxidizing, polishing and dyeing one-bath method and application of the enzyme preparation, and belongs to the technical field of enzyme preparations. The enzyme preparation for the deoxidizing, polishing and dyeing one-bath method comprises the following components in percentage by mass: 5 to 10 percent of catalase, 30 to 50 percent of cellulase, 5 to 10 percent of sorbitol, 0.1 to 0.3 percent of potassium sorbate, and the balance of deionized water. The enzyme preparation for the deoxidizing, polishing and dyeing one-bath method can be applied to dyeing and finishing of cotton fabrics, and fulfills the aim of integrating three procedures of removing residual hydrogen peroxide, polishing and dyeing. Compared with the conventional enzyme preparation, the enzyme preparation for the deoxidizing, polishing and dyeing one-bath method has the advantages of shortening the processing time by over 90 minutes, obviously improving the production efficiency and fulfilling the aims of remarkably reducing water consumption, reducing energy consumption, reducing sewage discharge and reducing cost.
Description
Technical field
A kind of enzyme preparation and application thereof that is used for one-bath process of deoxidizing, polishing and dyeing of the present invention especially relates to a kind of enzyme preparation of removing remaining hydrogen peroxide solution polishing and dyeing single bath process that is used for cotton kind fabric dyeing and finishing processing, belongs to the enzyme preparation technical field.
Background technology
The dyeing and finishing work flow of traditional cotton kind fabric is that oxygen floats, hot water wash deoxygenation, biopolishing, dyeing and back arrangement.Its method of removing remaining hydrogen peroxide solution is to use hot water wash, and this method efficient is low, and energy consumption is high.
Developed biology enzyme in recent years and removed remaining hydrogen peroxide solution technology, work flow is improved to that oxygen floats, biology enzyme removes hydrogen peroxide solution, biopolishing, dyeing and back arrangement.Use biology enzyme to remove hydrogen peroxide solution and saved a large amount of water, electricity, vapour and time.
Because biopolishing is to utilize cellulase that fabric face is carried out polished finish, common polishing enzyme needs under acid condition, to carry out, and reactive dyeing then needs under neutrallty condition, to carry out.Therefore at present deoxygenation, polishing, dyeing need divide for three steps carried out, with duration, energy consumption is big, cost is high.
Summary of the invention
The purpose of this invention is to provide a kind of enzyme preparation that is used for one-bath process of deoxidizing, polishing and dyeing that mainly is applicable to cotton kind fabric dyeing and finishing processing.
Another object of the present invention is the described application that is used for the enzyme preparation of one-bath process of deoxidizing, polishing and dyeing in cotton kind fabric dyeing and finishing processing; To realize that deoxygenation, polishing, three operations of dyeing close three is one, the purpose that reach remarkable minimizing water consumption, cuts down the consumption of energy, reduces sewage discharge, reduces cost and enhance productivity.
The object of the invention is realized by following technical proposals.
A kind of enzyme preparation that is used for one-bath process of deoxidizing, polishing and dyeing, it is formed as follows by mass percentage; Catalase 5%～10%, cellulase 30%～50%, sorbierite 5%～10%, potassium sorbate 0.1%～0.3% surplusly supplies 100% for deionized water.
The described preparation method who is used for the enzyme preparation of one-bath process of deoxidizing, polishing and dyeing, step is following:
(1) by mass percentage, take by weighing catalase, cellulase, sorbierite, potassium sorbate respectively;
(2) press proportioning with deionized water dissolving potassium sorbate and sorbierite, obtain dilute solution;
(3) dilute solution is added in the reaction vessel, transfer pH4.8-5.5, add cellulase and the catalase that weighs up again, stir, leave standstill, promptly get the enzyme preparation that product is used for one-bath process of deoxidizing, polishing and dyeing.
Catalase enzyme work in the prescription is 200000 μ/mL, and cellulose enzyme activity is 32660 NCAU/g.
The described application that is used for the enzyme preparation of one-bath process of deoxidizing, polishing and dyeing, in cotton kind fabric dyeing and finishing processing, realizing removing remaining hydrogen peroxide solution, polishing, three operations of dyeing, to close three be one application.
Catalase is to be got by fermenting and producing such as bacterium or pluck, available from letter (China) Bioisystech Co., Ltd of Novi.The advantage enzyme activity is high, can in very wide pH and temperature range, work.Cellulase can Bioisystech Co., Ltd of section available from the outstanding person for being got by the microorganism fungus kind fermentation.Advantage: enzyme is lived high, and action pH is wide, and arriving in acidity can both effective function under the neutrallty condition.
Compare with prior art, the present invention has following outstanding advantage and beneficial effect.
Because used cellulase of the present invention and catalatic action pH scope are extremely wide, the caused pH value fluctuation of residual alkali that fiber oozes out after can not floating because of oxygen when in the reactive dyeing bath, using influences the biopolishing effect.Product of the present invention all can be used in the scope of pH value 4.5～8; Be specially adapted to COTTON FABRIC oxygen and float the three-in-one technology of removal hydrogen peroxide solution, polishing, dyeing (being one-bath process of deoxidizing, polishing and dyeing) afterwards, its technological process can shorten to: oxygen floats, one-bath process of deoxidizing, polishing and dyeing is handled and the back arrangement.Compare with existing enzyme preparation; The enzyme preparation of using one-bath process of deoxidizing, polishing and dyeing of the present invention can shorten more than 90min process time; Obviously enhance productivity, and the purpose that can reach remarkable minimizing water consumption, cut down the consumption of energy, reduce sewage discharge and reduce cost.
The specific embodiment
Through embodiment the present invention is further described below, but protection scope of the present invention is not limited thereto.
Embodiment 1
Be used for removing the enzyme preparation of hydrogen peroxide solution polishing and dyeing single bath process, by mass percentage, it consists of:
Catalase 10%
Cellulase 50%
Sorbierite 10%
Potassium sorbate 0.3%
Deionized water supplies 100%
The preparation method is following:
(1) by above-mentioned mass percent, takes by weighing potassium sorbate, sorbierite and deionized water respectively;
(2) obtain dilute solution with deionized water dissolving potassium sorbate, sorbierite;
(3) dilute solution is transferred pH to 5.2 with acetic acid.Add cellulase and the catalase that weighs up again, stir, leave standstill, promptly get product.
Embodiment 2
Be used for removing the enzyme preparation of hydrogen peroxide solution polishing and dyeing single bath process, by mass percentage, it consists of:
Hydrogen peroxide 5%
Cellulase 30%
Sorbierite 10%
Potassium sorbate 0.3%
Deionized water supplies 100%
The preparation method is following:
(1) by above-mentioned mass percent, takes by weighing potassium sorbate, sorbierite and deionized water respectively;
(2) obtain dilute solution with deionized water dissolving potassium sorbate, sorbierite;
(3) dilute solution is transferred pH to 5.0 with acetic acid.Add cellulase and the catalase that weighs up again, stir, leave standstill, promptly get product
Embodiment 3
The application note of enzyme preparation that is used for removing hydrogen peroxide solution polishing and dyeing single bath process is following:
The technological process of one-bath process of deoxidizing, polishing and dyeing is:
(1) oxygen floats, (2) one-bath process of deoxidizing, polishing and dyeing is handled, the arrangement of (3) back.
Below above-mentioned technological process is further described.
(1) oxygen floats: undertaken by conventional oxygen bleaching process, and draining after accomplishing, water inlet adds glacial acetic acid and regulates pH to neutral;
(2) one-bath process of deoxidizing, polishing and dyeing is handled: add one-bath process of deoxidizing, polishing and dyeing enzyme preparation (embodiment of the invention 1) product 0.5%～1.0% (is benchmark with pending fabric gross mass), operation 30min adds dyestuff, glauber salt (REACTIVE DYES accelerant); Be warming up to 60 ℃; Insulation 30～60min adds soda ash (dye fixing agent), insulation 30～60min; Draining, washing is to clean;
(3) back arrangement: undertaken by common process.
Effect (is the example explanation with embodiment 1): referring to table 1, table 1 has provided the product that uses embodiment 1 gained and has been applied to one-bath process of deoxidizing, polishing and dyeing technology and traditional handicraft result relatively.
Table 1 single bath process technology and traditional handicraft effect comparison
Method of testing
Reduction rate: sample after former cloth and the processing is put into full-automatic ventilated type fast constant temperature baking oven, dry to constant weight in 105 ℃.Calculate reduction rate according to formula (1):
In reduction rate=［ (Wo-W1)/Wo ］ * 100% (1) formula: w0---sample mass before the polishing; W1---polishing back sample mass.
The anti-fluffing and anti-pilling performance: cut 5 diameters, 12 cm circular specimens, press GB/T 4802.1-1997 (textile fabric pilling testing circle method of loci " test pilling performance on YG501 type pilling instrument.Evaluation classification: 5 grades: not balling-up; 4 grades: a small amount of balling-up is arranged; 3 grades: the moderate quatity balling-up; 2 grades: serious balling-up.
Bursting strength: test on HD026N electronic fabric tensometer with reference to GB 3923.1 1 1997 " the mensuration galley proof method of textile fabric tensile property ultimate strength and elongation at break ", test is preceding in thermostatic constant wet chamber's balance 24 h.
Tinctorial yield: the coloration of textile materials degree of depth characterizes with the K/S value, and PLUS-CT computer color measurement and color match appearance is tested, and is reference sample with the traditional handicraft sample to adopt SF600.
Table 2 single bath process technology and the contrast of traditional handicraft cost
Can know that from table 2 COTTON FABRIC is used and removed hydrogen peroxide solution polishing and dyeing single bath process, technological process is shortened, and working (machining) efficiency improves, and consumption such as water, electricity and steam all reduce than the acid polishing of tradition enzymatic process greatly, and quantity of wastewater effluent reduces, remarkable in economical benefits.
Claims (4)
1. an enzyme preparation that is used for one-bath process of deoxidizing, polishing and dyeing is characterized in that it is formed as follows by mass percentage; Catalase 5%～10%, cellulase 30%～50%, sorbierite 5%～10%, potassium sorbate 0.1%～0.3% surplusly supplies 100% for deionized water.
2. the described preparation method who is used for the enzyme preparation of one-bath process of deoxidizing, polishing and dyeing of claim 1 is characterized in that step is following:
(1) by mass percentage, take by weighing catalase, cellulase, sorbierite, potassium sorbate respectively;
(2) press proportioning with deionized water dissolving potassium sorbate and sorbierite, obtain dilute solution;
(3) dilute solution is added in the reaction vessel, transfer pH4.8-5.5, add cellulase and the catalase that weighs up again, stir, leave standstill, promptly get the enzyme preparation that product is used for one-bath process of deoxidizing, polishing and dyeing.
3. the enzyme preparation that is used for one-bath process of deoxidizing, polishing and dyeing as claimed in claim 2, the catalase enzyme work in it is characterized in that filling a prescription is 200000 μ/mL, cellulose enzyme activity is 32660 NCAU/g.
4. the described application that is used for the enzyme preparation of one-bath process of deoxidizing, polishing and dyeing of claim 1, in cotton kind fabric dyeing and finishing processing, realizing removing remaining hydrogen peroxide solution, polishing, three operations of dyeing, to close three be one application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100642663A CN102605604A (en) | 2012-03-13 | 2012-03-13 | Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012100642663A CN102605604A (en) | 2012-03-13 | 2012-03-13 | Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102605604A true CN102605604A (en) | 2012-07-25 |
Family
ID=46523339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012100642663A Pending CN102605604A (en) | 2012-03-13 | 2012-03-13 | Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102605604A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888755A (en) * | 2012-10-24 | 2013-01-23 | 绍兴中纺院江南分院有限公司 | Enzyme additive for cotton knitted fabric and preparation method and application thereof |
| CN102965982A (en) * | 2012-11-27 | 2013-03-13 | 绍兴市华绅纺织品整理有限公司 | Deoxidizing and polishing one-bath process dyeing of polyester cotton knitted fabric |
| CN103290670A (en) * | 2013-05-16 | 2013-09-11 | 辽宁腾达集团股份有限公司 | Method for removing residual oxygen of pure-cotton knitted fabric by use of heat energy after bleaching |
| CN103643562A (en) * | 2013-12-09 | 2014-03-19 | 上海市纺织科学研究院 | Composite biological enzyme preparation for solvent method bamboo fiber fabric and application thereof |
| CN103741492A (en) * | 2013-12-04 | 2014-04-23 | 江苏双圆袋鼠服饰有限公司 | Cotton knitted fabric deoxygenation polishing dyeing-enzyme bath treatment process |
| CN104213416A (en) * | 2014-08-27 | 2014-12-17 | 东莞泛亚太生物科技有限公司 | Compounded deoxidizing and polishing enzyme preparation and textile printing and dyeing method |
| CN104560933A (en) * | 2014-12-25 | 2015-04-29 | 江南大学 | Liquid proline specific endo protease compound enzyme preparation |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1851110A (en) * | 2006-05-26 | 2006-10-25 | 顾曰田 | Method for after-treating cotton knit vest by biological enzyme |
| CN101434940A (en) * | 2008-12-24 | 2009-05-20 | 中山时进纺织原料有限公司 | Deoxidization/depilation complex enzyme |
| CN101624775A (en) * | 2009-08-14 | 2010-01-13 | 福建省晋江新德美化工有限公司 | Enzyme preparation for one-bath process of deoxidizing, polishing and dyeing |
-
2012
- 2012-03-13 CN CN2012100642663A patent/CN102605604A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1851110A (en) * | 2006-05-26 | 2006-10-25 | 顾曰田 | Method for after-treating cotton knit vest by biological enzyme |
| CN101434940A (en) * | 2008-12-24 | 2009-05-20 | 中山时进纺织原料有限公司 | Deoxidization/depilation complex enzyme |
| CN101624775A (en) * | 2009-08-14 | 2010-01-13 | 福建省晋江新德美化工有限公司 | Enzyme preparation for one-bath process of deoxidizing, polishing and dyeing |
Non-Patent Citations (2)
| Title |
|---|
| 《针织工业》 20091231 郭卫红 "生物酶在纯棉针织物前处理中的应用" 第58-60页 1-3 , 第12期 * |
| 郭卫红: ""生物酶在纯棉针织物前处理中的应用"", 《针织工业》, no. 12, 31 December 2009 (2009-12-31), pages 58 - 60 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888755A (en) * | 2012-10-24 | 2013-01-23 | 绍兴中纺院江南分院有限公司 | Enzyme additive for cotton knitted fabric and preparation method and application thereof |
| CN102888755B (en) * | 2012-10-24 | 2014-08-27 | 绍兴中纺院江南分院有限公司 | Enzyme additive for cotton knitted fabric and preparation method and application thereof |
| CN102965982A (en) * | 2012-11-27 | 2013-03-13 | 绍兴市华绅纺织品整理有限公司 | Deoxidizing and polishing one-bath process dyeing of polyester cotton knitted fabric |
| CN103290670A (en) * | 2013-05-16 | 2013-09-11 | 辽宁腾达集团股份有限公司 | Method for removing residual oxygen of pure-cotton knitted fabric by use of heat energy after bleaching |
| CN103741492A (en) * | 2013-12-04 | 2014-04-23 | 江苏双圆袋鼠服饰有限公司 | Cotton knitted fabric deoxygenation polishing dyeing-enzyme bath treatment process |
| CN103643562A (en) * | 2013-12-09 | 2014-03-19 | 上海市纺织科学研究院 | Composite biological enzyme preparation for solvent method bamboo fiber fabric and application thereof |
| CN104213416A (en) * | 2014-08-27 | 2014-12-17 | 东莞泛亚太生物科技有限公司 | Compounded deoxidizing and polishing enzyme preparation and textile printing and dyeing method |
| CN104560933A (en) * | 2014-12-25 | 2015-04-29 | 江南大学 | Liquid proline specific endo protease compound enzyme preparation |
| CN104560933B (en) * | 2014-12-25 | 2019-06-21 | 江南大学 | A kind of liquid proline specific endo protease compounded enzyme preparate |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102605604A (en) | Enzyme preparation for deoxidizing, polishing and dyeing one-bath method and application of enzyme preparation | |
| CN101624775B (en) | Enzyme preparation for one-bath process of deoxidizing, polishing and dyeing | |
| CN104018337B (en) | With the desizing method of the textile yarn-dyed fabric of starch and the starching of PVA mixed slurry | |
| CN102888755B (en) | Enzyme additive for cotton knitted fabric and preparation method and application thereof | |
| CN105386324B (en) | A kind of cotton or the pre-treating method of polyester cotton | |
| CN103306129B (en) | The treatment fluid of scouringing and bleaching for cotton fabrics ultralow temperature and treatment process | |
| CN103821006A (en) | Elastic polyester-cotton fabric dyeing and finishing pretreatment method | |
| CN102965982A (en) | Deoxidizing and polishing one-bath process dyeing of polyester cotton knitted fabric | |
| CN101003952A (en) | Technical method of pigment wash, dye, and general finish for ready-made clothes in pure cotton | |
| CN102704259A (en) | Low-temperature scouring and bleaching agent and application thereof | |
| WO2014161252A1 (en) | Whole-process low-temperature dyeing and finishing process for cotton knitted fabric during scouring and bleaching, dyeing and soaping | |
| CN103469538B (en) | Low-temperature less-alkali pretreatment method for modified polyester/cotton blended knitted fabric | |
| CN102817240A (en) | Non-steaming cold pad-batch process of all-cotton or polyester-cotton fabric | |
| CN102936849B (en) | A kind of enzymatic scouring-efficient cryogenic is scouringed and bleaching treatment process | |
| CN104233826B (en) | A kind of cotton fabrics one bathes low temperature desizing, refine and bleaching pre-treating method | |
| CN102154230B (en) | Neutral low-temperature refining enzyme and use thereof in pretreatment of fabrics | |
| CN105108861A (en) | Bamboo craft dyeing method | |
| CN105155167A (en) | Application of thermophilic Chaetomium cellulose to polishing, dyeing and one-bat technology | |
| CN104404797A (en) | Activated dye low-alkaline dyeing method for black regenerated cellulose fiber cheese | |
| CN103088678A (en) | Method used for textile dyeing and finishing after-treatment | |
| CN102392343A (en) | Pretreatment and bath-treatment method for modifying cotton fabrics | |
| CN106223001A (en) | The enzyme of a kind of containing cellulose fiber yarn fabric quick desizing kiering method continuously | |
| CN106638053A (en) | One-bath dyeing technology for polyester-cotton blended fabric by natural vegetable dye | |
| CN103397531A (en) | Matte finishing method and low-temperature low-alkali production method of cotton fabrics | |
| CN101818451A (en) | Bleaching pre-processing process for pure cotton padding cloth |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120725 |