CN102584438B - Eucalyptus controlled release fertilizer and preparation process thereof - Google Patents

Eucalyptus controlled release fertilizer and preparation process thereof Download PDF

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CN102584438B
CN102584438B CN201210027546.7A CN201210027546A CN102584438B CN 102584438 B CN102584438 B CN 102584438B CN 201210027546 A CN201210027546 A CN 201210027546A CN 102584438 B CN102584438 B CN 102584438B
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fertilizer
rumen
eucalyptus
fertiliser granulates
eucalptus
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叶长东
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Abstract

The invention provides a eucalyptus controlled release (namely slow release) fertilizer. The fertilizer comprises an outer coating layer and inner fertilizer particles in a weight ratio of (0.8-5):(5-12), wherein the fertilizer particles comprise nitrogen, phosphorus, potassium, boron, zinc and copper. In addition, the invention provides a preparation method and application of the eucalyptus fertilizer, and the like.

Description

Eucalyptus controlled release fertilizer and preparation technology thereof
Technical field
The invention belongs to vegetable fertilizer field, particularly, the present invention relates to the release and release control fertilizer for eucalyptus.
Background technology
Eucalyptus is fast, material is excellent, is the short period commodity trees of current Spread in China plantation, and its timber is widely used in the processing of papermaking, fibrous plate.Yet, in the process of growth of eucalyptus, the demand of nutrient is wanted to large compared with other seeds, therefore must the enough fertilizer that imposes, just can make eucalyptus normal growth.
For this reason, someone Eucalptus fertilizer that begins one's study at present.For example, Chinese patent application 03139716 discloses trace element fertilizer, comprises two or more of B, Cu, Zn, Mn, Fe and Mo element, for preventing and treating eucalyptus nutritional deficiency physiological disease.
It is at present more the composite fertilizer that inorganic fertilizer and trace element form.For example, Chinese patent application 03157602 discloses special composite fertilizer for eucalyptus, comprises that the macroelement of nitrogen, phosphorus, potassium etc. is fertile, the trace element fertilizer of iron, manganese, zinc, copper, boron, molybdenum etc., and plant-growth regulator; Chinese patent application 200510078471 also discloses fertilizer dedicated to eucalyptus material, and it is comprised of trace elements such as the macroelement such as nitrogen, phosphorus, potassium and iron, manganese, zinc, copper, boron, molybdenums; Chinese patent 200610125356 discloses fertilizer dedicated to eucalyptus, comprises 5~18% nitrogenous fertilizer, 7~15% phosphate fertilizer, 5~12% potash fertilizer, 0.05~0.3% copper, 0.05~0.4% zinc and 0.05~0.2% boron; Chinese patent application 200910166761 discloses fertilizer dedicated to eucalyptus, and Ta You city domestic sewage treatment plant mud, urea, monoammonium phosphate, Repone K form; Chinese patent application 201010585251 discloses fertilizer dedicated to eucalyptus, comprises the base manure being comprised of nitrogen, phosphorus, potassium, boron and zinc, and topdressing of being comprised of nitrogen, phosphorus, potassium, boron and the zinc of another proportioning.
Except above-mentioned composite fertilizer, the use of microbial inoculum also can increase fertility.For example, Chinese patent application 200410027047 discloses fertilizer dedicated to eucalyptus, comprises enzymatic microorganism, organic matter, humic acid, nitrogen, phosphorus, potash fertilizer etc.; Chinese patent application 200710074909 discloses fertilizer dedicated to eucalyptus, comprises the effectively viable bacteria such as yeast, actinomycetes, photosynthetic bacteria, vinelandii, P and K decomposing bacterium.But these Fertilizer application bacterial classifications are not clear, even cannot know between multiple bacterial classification, whether can produce pick up anti-.Although also there is the technology of using single culture at present, as Penicillium notatum of the bacillus megaterium of the fixed nitrogen stenotrophomonas maltophilia of Chinese patent application 200910114539, Chinese patent application 201010227376, Chinese patent application 201010548966 etc., but result of use is single, be unfavorable for practice popularization.
After above Term Fertilization, especially, after southern rain-belt is used, wherein solubility inorganic fertilizer can fast speed dissolve, and has reduced on the one hand the effect of Term Fertilization, causes fertilizer waste, also pollutes in addition periphery water body.For this reason, there is people to prepare slowly-releasing (controlled release) fertilizer by increase the mode of coating on fertilizer surface.For example, Chinese patent 96105688 discloses a kind of coated fertilizer, wherein the composition of soil layer is except 0.1~50 part of gelatin, it is mainly soluble inorganic salt, as 1~180 part of solubilizing agent (its main component is the inorganic salt such as ammonium sulfate, ammonium nitrate) and 0.1~200 part of plant nutrient compound (being mainly the vitriol of iron, zinc), cause like this in the coating of gelatin parcel and have great amount of soluble inorganic salt, after meeting water, rapid dissolving makes fertiliser granulates form vesicular or disintegration, and actual slowly-releasing (controlled release) ability is very limited.And for example, Chinese patent CN202072642U discloses the slow release compound fertilizer special for eucalyptus comprising with organic-capping layer, but the main component of organic-capping layer is polyethylene and paraffin, hard degradation own, cannot effectively discharge inner fertilizer, even cause the white pollution of vinyon.
For this reason, the inventor is through long-term and arduous research, picked out rumen-undegraded fat and carry out Wrapped fertilizer from the existing chemical products as vast as the open sea, and the emission levels in the eucalyptus controlled release fertilizer of formation is moderate, and this material can degrade at occurring in nature, can not form white pollution.Rumen-undegraded fat powder is used to wrap up the feed of animal edible in the prior art, and because it has the fusing point that exceeds envrionment temperature (this is lower than the problem in animal body), and nobody uses it in feed parcel, but the inventor finds can discharge with moderate speed in moisture physical environment.More surprisingly, inventor's discovery, this material only has under the condition of mineral manure at parcel, and encapsulation rate is not high, therefore needs more material to wrap up, and causes cost to increase; And when wrapping up the fertilizer that contains yellow humic acid, only need less material just effectively to seal, reduced cost.
Summary of the invention
The technical problem to be solved in the present invention is the Eucalptus fertilizer that provides new, and it can controlled release (that is, slowly-releasing) fertilizer.The present invention also provides and has prepared the application of Eucalptus fertilizer and method etc. in addition.
Particularly, in first aspect, the invention provides Eucalptus fertilizer, it comprise outer field integument and fertiliser granulates, it is characterized in that, the weight ratio of integument and fertiliser granulates is 0.8~5: 5~12, wherein
Integument is comprised of rumen-undegraded fat; With,
Fertiliser granulates comprises nitrogen, phosphorus, potassium, boron, zinc and copper.
Preferably, in first aspect present invention, the diameter of fertiliser granulates is about 0.3~1.5mm, is preferably 0.4~0.8mm, most preferably is 5mm.
Preferably, in first aspect present invention, the weight ratio of integument and fertiliser granulates is 1~4: 6~9.
Preferably, in first aspect present invention, fertiliser granulates comprises ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol and Salzburg vitriol.More preferably wherein, the weight ratio of ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol and Salzburg vitriol is 20~30: 50~70: 6~10: 0.5~1.5: 0.3~0.8: 0.3~0.8.
Preferably, in first aspect present invention, fertiliser granulates also comprises yellow humic acid.More preferably wherein, the weight ratio of ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol, Salzburg vitriol and yellow humic acid is 20~30: 50~70: 6~10: 0.5~1.5: 0.3~0.8: 0.3~0.8: 15~25.
Preferably in first aspect present invention, the rumen-undegraded fat Shi Bai HTL316 of Canon.
In second aspect, the invention provides the application of rumen-undegraded fat in preparing Eucalptus fertilizer.More preferably wherein, Eucalptus fertilizer is eucalyptus controlled release fertilizer.
Preferably, in second aspect present invention, Eucalptus fertilizer is the Eucalptus fertilizer of first aspect present invention.
In the third aspect, the invention provides the preparation method of the Eucalptus fertilizer of first aspect present invention, it comprises:
(1) fusing rumen-undegraded fat; With
(2) rumen-undegraded fat of fusing is sprayed on fertiliser granulates surface.
Preferably, in third aspect present invention, the diameter of fertiliser granulates is about 0.3~1.5mm, is preferably 0.4~0.8mm, most preferably is 5mm.
The present invention has following advantages and effect: the elements such as the required nitrogen of Eucalyptus, phosphorus, potassium, boron, zinc and copper can be provided, improve the growth rate of eucalyptus; Controlled release/slow release fertilizer, effectively reduces the turnover rate of fertilizer, improves the utilising efficiency of fertilizer; Controlled release/sustained release rate is moderate and stable, further improves the growth rate of eucalyptus; The equal degradable of fertilizer component, can not bring white pollution; While using yellow humic acid, not only can increase nutriment in a fertilizer, and can effectively improve encapsulation rate, reduce the consumption of lapping, save cost.
For the ease of understanding, below will to the present invention, be described in detail by specific embodiment.It needs to be noted, specific examples is only in order to illustrate, does not form limitation of the scope of the invention.Obviously those of ordinary skill in the art can make various corrections and change to the present invention within the scope of the invention according to explanation herein, and these corrections and change are also included in scope of the present invention.In addition, the present invention has quoted open source literature, and these documents are also in order more clearly to describe the present invention, and their full text content is all included the present invention in and carried out reference, just look like they full text in specification sheets of the present invention repeated description excessively the same.
Embodiment
Below will invention be described by specific embodiment herein.As do not specialize part, can implement according to listed method in the familiar agronomy of those skilled in the art and fertilizer science handbook and the reference of quoting herein.In addition, the material and facility using in embodiment all can be bought from the market.
The parcel of embodiment 1 mineral manure
Get 25 kilograms of ammonium chlorides, 60 kilograms of diammonium phosphate, 8 kilograms, Repone K, 1 kilogram of borax, 0.5 kilogram of Zinc vitriol, 0.5 kilogram of Salzburg vitriol, after mixing, then add 2 kilograms of urea and 3 kg of water, after mixing, pulverize and sieve granulation, make the particle that diameter is about 0.5mm, be without Wrapped fertilizer.
Get the HTL316 of 1 kilogram of hundred Canon (BergaFat) (can purchased from Nanning converge new peak herding company limited) melts in 60 ℃ of baking ovens, then with fluidized granulation seed-coating machine, it is all evenly sprayed on the surface of particle of 9 kilograms of above-mentioned preparations and forms integument, obtain mineral manure 1; Separately get the HTL316 of 4 kilogram of hundred Canon (BergaFat) (can purchased from Nanning converge new peak herding company limited) melts in 60 ℃ of baking ovens, then with fluidized granulation seed-coating machine, it is all evenly sprayed on the surface of particle of 6 kilograms of above-mentioned preparations and forms integument, obtain mineral manure 2.
Embodiment 2 is containing the parcel of the fertilizer of yellow humic acid
Get 20 kilograms of ammonium chlorides, 48 kilograms of diammonium phosphate, 6.4 kilograms, Repone K, 0.8 kilogram of borax, 0.4 kilogram of Zinc vitriol, 0.4 kilogram of Salzburg vitriol, after mixing, then add 21 kilograms of yellow humic acids, 1 kilogram of urea and 2 kg of water, after mixing, pulverize and sieve granulation, make the particle that diameter is about 0.5mm.
Get the HTL316 of 1 kilogram of hundred Canon (BergaFat) (can purchased from Nanning converge new peak herding company limited) melts in 60 ℃ of baking ovens, then with fluidized granulation seed-coating machine, it is all evenly sprayed on the surface of particle of 9 kilograms of above-mentioned preparations and forms integument, obtain the fertilizer containing yellow humic acid.
The dissolution rate test of embodiment 3 Wrapped fertilizers
Get the mineral manure 1, mineral manure 2 of embodiment 1 and 2 preparations and containing the fertilizer of yellow humic acid, and get embodiment 1 preparation without Wrapped fertilizer and with the fertilizer of polyethylene parcel in contrast, be immersed in clear water, at different time water sampling, detect fertilizer solubility rate wherein, result is as shown in the table:
Figure GDA0000145304000000051
Without Wrapped fertilizer, almost all dissolve at once, show to there is slow releasing function; With the fertilizer of polyethylene parcel, except there is no the fertiliser granulates of environmental sealing (sealing) in initial dissolving, almost no longer disengage thereafter fertilizer; Sealing of mineral manure 1 is lower, causes a large amount of fertilizer just dissolving at first, but can continue thereafter to disengage the fertilizer of sealing; Mineral manure 2 and higher containing the encapsulation rate of the fertilizer of yellow humic acid, the fertilizer that major part is sealed continues to disengage in the back.
Embodiment 4 eucalyptus fertilization effects
The inventor entrusts Guangxi province forest-science institute, with the fertilizer containing yellow humic acid of embodiment 2 preparations, Eucalyptus Seedlings is carried out to manurial experiment, only use once every year, what take embodiment 1 preparation simultaneously is contrast without Wrapped fertilizer, plant after 1 year, experimental group, than the high 2.72m of the mean stand height of control group, increases 121%.

Claims (2)

1. Eucalptus fertilizer, it comprise outer field integument and fertiliser granulates, it is characterized in that, the weight ratio of integument and fertiliser granulates is 0.8 ~ 5:5 ~ 12, wherein
Integument is comprised of rumen-undegraded fat, wherein the HTL316 of rumen-undegraded fat Shi Bai Canon; With,
Fertiliser granulates comprises ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol and Salzburg vitriol, and wherein the weight ratio of ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol and Salzburg vitriol is 20 ~ 30:50 ~ 70:6 ~ 10:0.5 ~ 1.5:0.3 ~ 0.8:0.3 ~ 0.8.
2. Eucalptus fertilizer claimed in claim 1, is characterized in that, the weight ratio of integument and fertiliser granulates is 1 ~ 4:6 ~ 9.
3, Eucalptus fertilizer claimed in claim 1, is characterized in that, fertiliser granulates also comprises yellow humic acid.
4, Eucalptus fertilizer claimed in claim 3, it is characterized in that, the weight ratio of ammonium chloride, diammonium phosphate, Repone K, borax, Zinc vitriol, Salzburg vitriol and yellow humic acid is 20 ~ 30:50 ~ 70:6 ~ 10:0.5 ~ 1.5:0.3 ~ 0.8:0.3 ~ 0.8:15 ~ 25.
5, the application of rumen-undegraded fat in preparing Eucalptus fertilizer, wherein Eucalptus fertilizer is arbitrary described Eucalptus fertilizer of claim 1 ~ 4, the wherein HTL316 of rumen-undegraded fat Shi Bai Canon.
6, the preparation method of arbitrary described Eucalptus fertilizer of claim 1 ~ 4, it comprises:
(1) fusing rumen-undegraded fat, the wherein HTL316 of rumen-undegraded fat Shi Bai Canon; With
(2) rumen-undegraded fat of fusing is sprayed on fertiliser granulates surface.
CN201210027546.7A 2012-02-08 2012-02-08 Eucalyptus controlled release fertilizer and preparation process thereof Active CN102584438B (en)

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CN102775216A (en) * 2012-08-10 2012-11-14 九禾股份有限公司 Fertilizer special for eucalyptus and preparation method thereof
CN104045408B (en) * 2013-03-11 2016-08-10 叶长东 Maninot esculenta crantz. Controlled Release Fertilizer and preparation technology thereof
CN103224430A (en) * 2013-05-17 2013-07-31 李志辉 Special ecological fertilizer formula for eucalyptus and preparation method thereof
CN103641647B (en) * 2013-12-09 2014-12-03 广西壮族自治区林业科学研究院 Tea-saponin-containing fertilizer special for eucalyptus
CN104016790A (en) * 2014-05-23 2014-09-03 广西地源之本肥业有限公司 Eucalyptus fertilizer additive
CN104016789A (en) * 2014-05-23 2014-09-03 广西地源之本肥业有限公司 Fertilizer special for eucalyptus
CN105085043A (en) * 2015-08-17 2015-11-25 李志山 Eucalyptus controlled-release fertilizer and preparation method thereof
CN105085053A (en) * 2015-08-21 2015-11-25 李志山 Eucalyptus controlled-release fertilizer and preparation method thereof
CN105198589A (en) * 2015-09-25 2015-12-30 广西百润源农业有限公司 Eucalyptus controlled-release fertilizer and preparation method thereof

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CN101348398B (en) * 2008-08-26 2013-01-30 华南农业大学 Long-acting coated compound fertilizer and preparation thereof
CN102070366A (en) * 2010-12-13 2011-05-25 云南云景林纸股份有限公司 Fertilizer special for eucalyptus and fertilizer application method
CN202072642U (en) * 2011-03-16 2011-12-14 安徽省司尔特肥业股份有限公司 Slow release compound fertilizer special for eucalyptus

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