CN102584176B - Method for preparing ceramic wall and floor tile by utilizing construction waste - Google Patents

Method for preparing ceramic wall and floor tile by utilizing construction waste Download PDF

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CN102584176B
CN102584176B CN201210031581.6A CN201210031581A CN102584176B CN 102584176 B CN102584176 B CN 102584176B CN 201210031581 A CN201210031581 A CN 201210031581A CN 102584176 B CN102584176 B CN 102584176B
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wall
ceramic
construction waste
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tile
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CN102584176A (en
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税安泽
孙皓
张瑞军
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GUANGZHOU SHIZHENG ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY DEVELOPMENT Co Ltd
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GUANGZHOU SHIZHENG ENVIRONMENTAL PROTECTION SCIENCE AND TECHNOLOGY DEVELOPMENT Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/58Construction or demolition [C&D] waste

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a method for preparing a ceramic wall and floor tile by utilizing construction waste. The wall and floor tile is lower than 3.0 percent in water absorption and is higher than 15MPa in compression strength. According to the method for preparing the ceramic wall and floor tile by utilizing the construction waste, a ceramic glazed tile, a light tile (including a light insulating tile), an ultra-thin tile, a polished tile and the like can be directly prepared by taking the construction waste as a raw material by utilizing a traditional ceramic interior and exterior wall tile or floor tile production line. By adopting the technology provided by the invention, the utilization ratio of the construction waste is high, the water absorption of the wall and floor tile is low, the antifouling property is good, the strength is high and industrialization popularization is easy.

Description

一种利用建筑废弃物制备陶瓷墙地砖的方法A method of using construction waste to prepare ceramic wall and floor tiles

技术领域 technical field

本发明涉及建筑废弃物的资源化利用领域,具体涉及一种利用建筑废弃物即建筑垃圾制备吸水率低、防污性能好、强度高的陶瓷内外墙砖及地板砖的方法。 The invention relates to the field of resource utilization of construction waste, in particular to a method for preparing ceramic interior and exterior wall tiles and floor tiles with low water absorption, good antifouling performance and high strength by using construction waste, that is, construction waste.

背景技术 Background technique

随着经济和城镇化建设的发展,旧楼改造与拆除、新楼兴建、基础设施建设的速度也不断加快。据统计,我国每年拆除4亿平方米旧建筑,产生建筑废弃物即建筑垃圾约5亿吨;每年新建建筑20亿平方米,产生建筑垃圾大于1亿吨;每年装修2000万套新房,产生建筑垃圾4000万吨。目前,我国建筑垃圾的年排放量已经超过6.4亿吨。 With the development of economy and urbanization, the speed of renovation and demolition of old buildings, construction of new buildings and infrastructure construction is also accelerating. According to statistics, my country demolishes 400 million square meters of old buildings every year, generating about 500 million tons of construction waste; 2 billion square meters of new buildings are built every year, generating more than 100 million tons of construction waste; 40 million tons of garbage. At present, the annual discharge of construction waste in my country has exceeded 640 million tons.

如此大量的建筑垃圾如不进行妥善处理而直接填埋,既污染水土资源和空气环境、挤占土地,又浪费我国宝贵的矿产资源、严重阻碍我国工业的可持性发展。因此,建筑垃圾的资源化利用已成为政府及相关行业和科技工作者梦寐以求的目标。 If such a large amount of construction waste is directly buried without proper treatment, it will not only pollute water and soil resources and the air environment, occupy land, but also waste my country's precious mineral resources and seriously hinder the sustainable development of my country's industry. Therefore, the resource utilization of construction waste has become the dream goal of the government and related industries and scientific and technological workers.

截止目前为止,有关建筑垃圾资源化利用的报道有:“用建筑废渣制造建材的方法”(CN.02121552.9)、“一种用建筑垃圾生产的墙地砖”(CN. 200410064526.2)、“建筑垃圾砖及其制造方法”(CN.200510011401.8)、“一种免烧多孔保温砖”(CN.200710024410.X)、“利用建筑垃圾生产的建材及其制备方法”(CN.200810216033.4)、“利用磷石膏固化建筑垃圾生产免烧砖的方法”(CN.201010230572.0)、“建筑垃圾再利用生产水泥产品的方法”(CN.201110132550.5)等。但这些技术以水泥或磷石膏等为粘结剂,通过养护(免烧)制备砌块、道路砖、广场砖及砂浆、水泥掺合料等。由于这些砖未经烧成,使用大量的水泥或磷石膏等使其固化,产品吸水率高(防污性能差)、强度低,不能应用于内外墙砖及地板砖(从严格意义上讲它们均非陶瓷),只能用于低附加值的砌块、道路砖、广场砖及砂浆、水泥掺合料等,且建筑垃圾使用率低。 Up to now, the reports on resource utilization of construction waste include: "Method for making building materials with construction waste residue" (CN. 02121552.9), "A wall and floor brick produced from construction waste" (CN. and its manufacturing method" (CN.200510011401.8), "a non-fired porous insulation brick" (CN.200710024410.X), "building materials produced from construction waste and its preparation method" (CN.200810216033.4), "using phosphogypsum A method for solidifying construction waste to produce burn-free bricks" (CN.201010230572.0), a "method for producing cement products by reusing construction waste" (CN.201110132550.5), etc. However, these technologies use cement or phosphogypsum as a binder, and prepare blocks, road bricks, square bricks, mortar, cement admixtures, etc. through curing (burn-free). Because these bricks have not been fired, a large amount of cement or phosphogypsum is used to solidify them, the product has high water absorption (poor antifouling performance) and low strength, so it cannot be applied to interior and exterior wall tiles and floor tiles (in a strict sense, they are None of them are ceramics), and can only be used for low value-added blocks, road bricks, square bricks and mortar, cement admixtures, etc., and the utilization rate of construction waste is low.

此外,以建筑垃圾为原料的一部分,经烧成制砖的报道有:“一种利用建筑垃圾、工业废渣生产新建材的方法”(CN.200310110163.7)、“煤矸石和建筑垃圾空心陶瓷保温板及其制作方法”(CN. 201010507514.8)等,它们虽然经过了烧制,但产品仍然吸水率高(防污性能差)、强度低,也不能应用于内外墙砖及地板砖,且建筑垃圾使用率也低(后者最高可达30%)。 In addition, some reports about using construction waste as raw materials to burn into bricks include: "A method for producing new building materials using construction waste and industrial waste residue" (CN.200310110163.7), "Coal gangue and construction waste hollow ceramic insulation board and its production method” (CN. 201010507514.8), etc. Although they have been fired, the products still have high water absorption (poor antifouling performance) and low strength, and cannot be applied to interior and exterior wall and floor tiles, and construction waste is used rate is also low (the latter can reach up to 30%).

现有技术存在建筑垃圾使用率低,产品吸水率高(防污性能差)、强度低、附加价值低等问题,不适用于陶瓷内外墙砖及地板砖的制备,难以广泛推广,难以满足大量排放的建筑垃圾资源化利用需求。因此,以建筑垃圾为原料,开发一种建筑垃圾使用率高,产品吸水率低、防污性能好、强度高的陶瓷内外墙砖及地板砖制备技术具有非常重要的社会经济意义。 The existing technology has problems such as low utilization rate of construction waste, high water absorption rate of the product (poor antifouling performance), low strength, and low added value. Requirements for resource utilization of discharged construction waste. Therefore, using construction waste as raw material, it is of great social and economic significance to develop a ceramic interior and exterior wall tile and floor tile preparation technology with high construction waste utilization rate, low product water absorption, good antifouling performance, and high strength.

发明内容 Contents of the invention

本发明的目的是为了克服上述现有技术中存在的不足,提供一种建筑垃圾使用率高,产品吸水率低、防污性能好、强度高的陶瓷内外墙砖及地板砖制备技术。 The object of the present invention is to overcome the shortcomings in the above-mentioned prior art and provide a preparation technology for ceramic interior and exterior wall tiles and floor tiles with high utilization rate of construction waste, low water absorption, good antifouling performance and high strength.

本发明的目的通过如下技术方案实现: The purpose of the present invention is achieved through the following technical solutions:

一种利用建筑垃圾制备的陶瓷内外墙砖及地板砖,其吸水率小于3.0%,抗压强度大于15MPa。 The ceramic interior and exterior wall tiles and floor tiles prepared from construction waste have a water absorption rate of less than 3.0% and a compressive strength greater than 15MPa.

本发明陶瓷墙地砖的制备方法,包括以下步骤: The preparation method of ceramic wall and floor tile of the present invention comprises the following steps:

(1)按质量份数计,称取建筑垃圾粉体10-100份、陶瓷粘土0-90份,石英0-10份,长石0-15份,陶瓷废料0-90份;将上述原料混合,经球磨或搅拌或喷雾造粒后制得均匀粉料。 (1) In terms of parts by mass, weigh 10-100 parts of construction waste powder, 0-90 parts of ceramic clay, 0-10 parts of quartz, 0-15 parts of feldspar, and 0-90 parts of ceramic waste; Mixing, making uniform powder after ball milling or stirring or spray granulation.

(2)将上述粉料成型为墙地砖坯体。 (2) Form the above powder into a body of wall and floor tiles.

(3)将上述坯体在900-1260℃下烧制3-420分钟,即可制得吸水率低(防污性能好)、强度高的陶瓷墙地砖。 (3) Fire the above green body at 900-1260°C for 3-420 minutes to produce ceramic wall and floor tiles with low water absorption (good antifouling performance) and high strength.

与现有技术相比,本发明具有的优点和有益效果包括:建筑垃圾使用率高,产品吸水率低(防污性能好)、强度高,各项性能指标均满足相关的陶瓷墙地砖标准,且可以直接利用现有的陶瓷墙地砖生产线生产,易于产业化推广。 Compared with the prior art, the advantages and beneficial effects of the present invention include: high utilization rate of construction waste, low water absorption (good antifouling performance), high strength, and all performance indicators meet the relevant standards for ceramic wall and floor tiles, Moreover, the existing ceramic wall and floor tile production lines can be directly used for production, which is easy for industrialization promotion.

具体实施方式 Detailed ways

下面结合实施例,对本发明做进一步的详细说明: Below in conjunction with embodiment, the present invention is described in further detail:

实施例1 Example 1

(1)按质量份数计,称取建筑垃圾粉体10份、陶瓷粘土90份,石英2份,长石5份;将上述原料混合,加水100份,经球磨、喷雾造粒后,过30目筛,制得均匀粉料。 (1) In terms of parts by mass, weigh 10 parts of construction waste powder, 90 parts of ceramic clay, 2 parts of quartz, and 5 parts of feldspar; mix the above raw materials, add 100 parts of water, and after ball milling and spray granulation, pass 30 mesh sieve to obtain uniform powder.

(2)将上述粉料在100MPa下压制成地板砖坯体。 (2) Press the above powder under 100MPa to make a floor tile body.

(3)将上述坯体在1080℃下烧成30分钟。 (3) The above green body was fired at 1080° C. for 30 minutes.

烧成后样品吸水率0.5%,抗压强度53MPa,容重2420kg/m3,适用于建筑物的陶瓷地板砖。 After firing, the water absorption rate of the sample is 0.5%, the compressive strength is 53MPa, and the bulk density is 2420kg/m 3 , which is suitable for ceramic floor tiles of buildings.

实施例2 Example 2

(1)按质量份数计,称取建筑垃圾粉体100份、石英10份,陶瓷废料90份;将上述原料混合,经搅拌后,过80目筛,制得均匀粉料。 (1) In terms of parts by mass, weigh 100 parts of construction waste powder, 10 parts of quartz, and 90 parts of ceramic waste; mix the above raw materials, and pass through an 80-mesh sieve after stirring to obtain a uniform powder.

(2)将上述粉料在10MPa下压制成外墙砖坯体。 (2) The above-mentioned powder is pressed under 10MPa to form an exterior wall brick body.

(3)将上述坯体在1260℃下烧成3分钟。 (3) The above green body was fired at 1260° C. for 3 minutes.

烧成后样品吸水率0.9%,抗压强度36MPa,容重870kg/m3,导热系数0.24w/m.k,适用于建筑节能(轻质隔热保温)的陶瓷外墙砖。 After firing, the water absorption rate of the sample is 0.9%, the compressive strength is 36MPa, the bulk density is 870kg/m 3 , and the thermal conductivity is 0.24w/mk. It is suitable for building energy-saving (light-weight heat insulation) ceramic exterior wall bricks.

实施例3 Example 3

(1)按质量份数计,称取建筑垃圾粉体50份、陶瓷粘土50份,长石15份;将上述原料混合,加水50份,经球磨、喷雾造粒后,过30目筛,制得均匀粉料。 (1) In terms of parts by mass, weigh 50 parts of construction waste powder, 50 parts of ceramic clay, and 15 parts of feldspar; mix the above raw materials, add 50 parts of water, and pass through a 30-mesh sieve after ball milling and spray granulation. A homogeneous powder was obtained.

(2)将上述粉料在200MPa下压制成内墙砖坯体。 (2) Press the above-mentioned powder under 200MPa to make an interior wall brick body.

(3)将上述坯体在900℃下烧成420分钟。 (3) The above green body was fired at 900° C. for 420 minutes.

烧成后样品吸水率3.0%,抗压强度15MPa,容重1580kg/m3,导热系数0.76w/m.k,适用于建筑物的陶瓷内墙砖。 After firing, the water absorption rate of the sample is 3.0%, the compressive strength is 15MPa, the bulk density is 1580kg/m 3 , and the thermal conductivity is 0.76w/mk. It is suitable for ceramic interior wall tiles of buildings.

上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受上述实施例的限制,其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本发明的保护范围之内。 The above-mentioned embodiment is a preferred embodiment of the present invention, but the embodiment of the present invention is not limited by the above-mentioned embodiment, and any other changes, modifications, substitutions, combinations, Simplifications should be equivalent replacement methods, and all are included in the protection scope of the present invention.

Claims (5)

1.一种利用建筑垃圾制备的陶瓷墙地砖,其特征在于,所述墙地砖的吸水率为0.5%-3.0%,抗压强度为15-36MPa,并通过以下方法获得:1. A ceramic wall and floor tile utilizing construction waste to prepare, characterized in that, the water absorption rate of said wall and floor tile is 0.5%-3.0%, and the compressive strength is 15-36MPa, and is obtained by the following method: (1)按质量份数计,称取建筑垃圾粉体10-50份、陶瓷粘土50-90份,石英0-2份,长石5-15份,将上述原料混合,经球磨或搅拌或喷雾造粒后制得均匀粉料;(1) In terms of parts by mass, weigh 10-50 parts of construction waste powder, 50-90 parts of ceramic clay, 0-2 parts of quartz, and 5-15 parts of feldspar, mix the above raw materials, and ball mill or stir or Uniform powder is obtained after spray granulation; (2)将上述粉料成型为墙地砖坯体;(2) Form the above powder into a body of wall and floor tiles; (3)将上述坯体在900-1260℃下烧制30-420分钟,即可制得吸水率低、强度高的陶瓷墙地砖。(3) Fire the above body at 900-1260°C for 30-420 minutes to produce ceramic wall and floor tiles with low water absorption and high strength. 2.权利要求1所述墙地砖的制备方法,其特征在于,包括以下步骤:2. the preparation method of wall and floor tile described in claim 1, is characterized in that, comprises the following steps: (1)将建筑垃圾粉体、陶瓷粘土,石英,长石,混合,经球磨或搅拌或喷雾造粒后制得均匀粉料;(1) Mix construction waste powder, ceramic clay, quartz, feldspar, and make uniform powder after ball milling, stirring or spray granulation; (2)将上述粉料成型为墙地砖坯体;(2) Form the above powder into a body of wall and floor tiles; (3)将上述坯体在900-1260℃下烧制30-420分钟,即可制得吸水率低、强度高的陶瓷墙地砖。(3) Fire the above body at 900-1260°C for 30-420 minutes to produce ceramic wall and floor tiles with low water absorption and high strength. 3.根据权利要求2所述的制备方法,其特征在于,所述球磨为干法球磨或湿法球磨;所述搅拌为干法搅拌或湿法搅拌;所述湿法球磨或湿法搅拌的加水量为10-100份。3. preparation method according to claim 2 is characterized in that, described ball mill is dry method ball mill or wet method ball mill; Described stirring is dry method agitation or wet method agitation; Described wet method ball mill or wet method agitation The amount of water added is 10-100 parts. 4.根据权利要求2所述的制备方法,其特征在于,所述成型为粉压成型或挤出成型、注浆成型、注模成型。4. The preparation method according to claim 2, characterized in that, the molding is powder compression molding or extrusion molding, grouting molding, or injection molding. 5.根据权利要求2所述的制备方法,其特征在于,所述陶瓷墙地砖为陶瓷内墙砖、陶瓷外墙砖及陶瓷地板砖。5. The preparation method according to claim 2, wherein the ceramic wall and floor tiles are ceramic interior wall tiles, ceramic exterior wall tiles and ceramic floor tiles.
CN201210031581.6A 2012-02-13 2012-02-13 Method for preparing ceramic wall and floor tile by utilizing construction waste Expired - Fee Related CN102584176B (en)

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