CN102559005A - Waterborne color transparent glass paint and preparation method thereof - Google Patents
Waterborne color transparent glass paint and preparation method thereof Download PDFInfo
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- CN102559005A CN102559005A CN2011104130424A CN201110413042A CN102559005A CN 102559005 A CN102559005 A CN 102559005A CN 2011104130424 A CN2011104130424 A CN 2011104130424A CN 201110413042 A CN201110413042 A CN 201110413042A CN 102559005 A CN102559005 A CN 102559005A
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Abstract
The invention discloses a waterborne color transparent glass paint and a preparation method thereof and relates to the glass paint industrial field. The waterborne color transparent glass paint comprises the following raw materials by weight percent: 60%-68% of waterborne epoxy emulsion, 4%-8% of waterborne amino resin, 2%-4% of cosolvent, 0.3%-0.8% of neutralizer, 15%-20% of deionized water, 5%-10% of waterborne metal complex dye, 0.5%-1.0% of waterborne silane coupling agent and 0.1%-0.4% of waterborne defoaming agent. After the waterborne color transparent glass paint prepared by the preparation method is sprayed on the surface of glass, the glass is roasted at 180-200 DEG C for 10-15min for curing and film-forming; and the paint film has bright color, high glossiness, good transparency, good water boiling resistance, high hardness and high adhesive force to glass.
Description
Technical field
The present invention relates to the glass paint industrial circle, be specifically related to a kind of water colour transparent glass lacquer and preparation method thereof, be mainly used in the coating protection and the decoration of glass and glasswork.
Background technology
As a kind of functional, environment-friendly type aqueous coating; Aqueous glass coats with lacquer particularly the water colour transparent glass lacquer and has that decorative effect is obvious, paint film is lucuriant in design, is easy to advantages such as cleaning, is widely used in glass decoration articles for use such as light fixture, wineglass, vase, storm lantern, candlestick.
Yet; The aqueous glass lacquer is weak because of the perviousness of its solvent (water), water-miscible paint is poor to the wettability of glass, the causes such as smooth finish height on base material (glass) surface; Cause water-miscible paint to be difficult on glass baseplate, produce good adhering to, seriously hindered the development of aqueous glass lacquer.The kind of aqueous glass lacquer mainly contains polyurethane aqueous dispersion body type, water-soluble polypropylene acid resin type, acrylate modified polyurethane-type etc. at present, and the subject matter of existence is poor adhesive force, and chemical-resistant is poor, solvent resistance is bad, and water boiling resistance property is poor.
Summary of the invention
In order to solve the problem that prior art exists, the invention provides a kind of water colour transparent glass lacquer and preparation method thereof, wherein, said water colour transparent glass lacquer is main base-material with aqueous epoxy emulsion, water-compatible amino resin is a linking agent; Film after the film forming have beautiful in colour, sticking power good, transparency is high, water boiling resistance property excellent characteristics;
A kind of water colour transparent glass lacquer; Count by weight percentage, the proportioning raw materials of said water colour transparent glass lacquer is: 60%～68% aqueous epoxy emulsion, 4%～8% water-compatible amino resin, 2%～4% solubility promoter, 0.3%～0.8% neutralizing agent, 15%～20% deionized water, 5%～10% water-based metal complexdyes, 0.5%～1.0% aqueous silane coupling agent and 0.1%～0.4% water-based skimmer.
Further, said water-compatible amino resin is highly methyl etherified melamine resin.
Further, said aqueous silane coupling agent is 4 amino butyl triethoxyl silanes.
A kind of making method of water colour transparent glass lacquer is characterized in that, comprises the steps:
1), aqueous epoxy emulsion, water-compatible amino resin, solubility promoter, neutralizing agent, deionized water are added in the pot of getting the raw materials ready according to said proportioning raw materials successively, stirred 5～10 minutes;
2), the water-based metal complexdyes is joined in the pot of getting the raw materials ready by said proportioning raw materials, stirred 5 minutes;
3), aqueous silane coupling agent, water-based skimmer are joined in the pot of getting the raw materials ready by said proportioning raw materials successively, stirred 3～5 minutes, form the water colour transparent glass lacquer of transparent homogeneous.
The invention has the beneficial effects as follows:
The method that the present invention adopted, wherein, hydroxyl that contains in the aqueous epoxy resins molecular structure and ehter bond behind the aminoresin curing reaction, further generate new hydroxyl and ehter bond, make paint film have very high force of cohesion and adhesive power; The epoxy resin thermal expansivity is less simultaneously, makes paint film adhesion good; During preparation, add the aqueous silane coupling agent in the system, make paint film further strengthen the sticking power of glass.
Embodiment
For making the object of the invention, technical scheme and advantage clearer, will combine embodiment to do the present invention is done further detailed description below.
Embodiment 1
The water colour transparent glass lacquer that present embodiment 1 is provided is processed by following raw material by weight ratio, is specially:
61% aqueous epoxy emulsion, 7.5% water-compatible amino resin, 3.5% solubility promoter, 0.6% neutralizing agent, 19% deionized water, 7.6% water-based metal complexdyes (Yellow-099), 0.6% aqueous silane coupling agent and 0.2% water-based skimmer.
Wherein, aqueous epoxy emulsion can use sea green good G-935, and water-compatible amino resin uses Ineos R-747 resin;
The making method of above-mentioned water colour transparent glass lacquer specifically comprises the steps:
1), aqueous epoxy emulsion, water-compatible amino resin, solubility promoter, neutralizing agent and deionized water are added in the pot of getting the raw materials ready by the above-mentioned raw materials proportioning successively, stirred 5～10 minutes;
2), the water-based metal complexdyes is joined in the pot of getting the raw materials ready by the above-mentioned raw materials proportioning, stirred 5 minutes;
3), aqueous silane coupling agent and water-based skimmer are joined in the pot of getting the raw materials ready by the above-mentioned raw materials proportioning successively, stirred 3～5 minutes, form the water colour transparent glass lacquer of transparent homogeneous.
The method that present embodiment adopted, wherein, hydroxyl that contains in the aqueous epoxy resins molecular structure and ehter bond behind the aminoresin curing reaction, further generate new hydroxyl and ehter bond, make paint film have very high force of cohesion and adhesive power; The epoxy resin thermal expansivity is less simultaneously, makes paint film adhesion good; During preparation, add the aqueous silane coupling agent in the system, make paint film further strengthen the sticking power of glass.
Embodiment 2
The water colour transparent glass lacquer that present embodiment 2 is provided is processed by following raw material by weight ratio, is specially:
65% aqueous epoxy emulsion, 6% water-compatible amino resin, 3% solubility promoter, 0.5% neutralizing agent, 17% deionized water, 7.4% water-based metal complexdyes (Red-311), 0.8% aqueous silane coupling agent and 0.3% water-based skimmer.
Its making method repeats no more with embodiment 1 here.
The method that present embodiment adopted, wherein, hydroxyl that contains in the aqueous epoxy resins molecular structure and ehter bond behind the aminoresin curing reaction, further generate new hydroxyl and ehter bond, make paint film have very high force of cohesion and adhesive power; The epoxy resin thermal expansivity is less simultaneously, makes paint film adhesion good; During preparation, add the aqueous silane coupling agent in the system, make paint film further strengthen the sticking power of glass.
Embodiment 3
The water colour transparent glass lacquer that present embodiment 3 is provided is processed by following raw material by weight ratio, is specially:
67% aqueous epoxy emulsion, 5% water-compatible amino resin, 2.5% solubility promoter, 0.4% neutralizing agent, 16% deionized water, 7.8% water-based metal complexdyes (Blue-762), 0.9% aqueous silane coupling agent and 0.4% water-based skimmer.
Its making method repeats no more with embodiment 1 here.
The method that present embodiment adopted, wherein, hydroxyl that contains in the aqueous epoxy resins molecular structure and ehter bond behind the aminoresin curing reaction, further generate new hydroxyl and ehter bond, make paint film have very high force of cohesion and adhesive power; The epoxy resin thermal expansivity is less simultaneously, makes paint film adhesion good; During preparation, add the aqueous silane coupling agent in the system, make paint film further strengthen the sticking power of glass.
Above-described embodiment is a more preferably embodiment of the present invention, and common variation that those skilled in the art carries out in technical scheme scope of the present invention and replacement all should be included in protection scope of the present invention.
Claims (4)
1. a water colour transparent glass coats with lacquer; It is characterized in that; Count by weight percentage, the proportioning raw materials of said water colour transparent glass lacquer is: 60%～68% aqueous epoxy emulsion, 4%～8% water-compatible amino resin, 2%～4% solubility promoter, 0.3%～0.8% neutralizing agent, 15%～20% deionized water, 5%～10% water-based metal complexdyes, 0.5%～1.0% aqueous silane coupling agent and 0.1%～0.4% water-based skimmer.
2. water colour transparent glass lacquer according to claim 1 is characterized in that said water-compatible amino resin is highly methyl etherified melamine resin.
3. water colour transparent glass lacquer according to claim 1 is characterized in that said aqueous silane coupling agent is 4 amino butyl triethoxyl silanes.
4. the making method of a water colour transparent glass lacquer is characterized in that, comprising:
1), aqueous epoxy emulsion, water-compatible amino resin, solubility promoter, neutralizing agent and deionized water are added in the pot of getting the raw materials ready according to said proportioning raw materials successively, stirred 5～10 minutes;
2), the water-based metal complexdyes is joined in the pot of getting the raw materials ready by said proportioning raw materials, stirred 5 minutes;
3), aqueous silane coupling agent and water-based skimmer are joined in the pot of getting the raw materials ready by said proportioning raw materials successively, stirred 3～5 minutes, form the water colour transparent glass lacquer of transparent homogeneous.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104130424A CN102559005A (en) | 2011-12-13 | 2011-12-13 | Waterborne color transparent glass paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104130424A CN102559005A (en) | 2011-12-13 | 2011-12-13 | Waterborne color transparent glass paint and preparation method thereof |
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| CN102559005A true CN102559005A (en) | 2012-07-11 |
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| CN2011104130424A Pending CN102559005A (en) | 2011-12-13 | 2011-12-13 | Waterborne color transparent glass paint and preparation method thereof |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746768A (en) * | 2012-08-02 | 2012-10-24 | 西北永新化工股份有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN103059691A (en) * | 2012-12-19 | 2013-04-24 | 陈名海 | Graphene-modified anti-wear water-based glass coating as well as preparation method and application thereof |
| CN103102764A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | High-wear-resistant water-based glass paint and preparation method thereof |
| CN103102766A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | High adhesive force water-based glass paint and preparation method thereof |
| CN104058600A (en) * | 2014-06-13 | 2014-09-24 | 陈湛玲 | Glass ware gold-plating technology |
| CN104559555A (en) * | 2014-11-29 | 2015-04-29 | 上海国谷化工科技有限公司 | Method for preparing boiling-resistant waterborne acrylic paint |
| CN105153871A (en) * | 2015-07-10 | 2015-12-16 | 刘善江 | Aqueous paint for glass, and preparation method thereof |
| CN105273630A (en) * | 2014-07-16 | 2016-01-27 | 开平市开物化工建材有限公司 | ECS-1002 resin-based glass paint and production process |
| CN103436118B (en) * | 2013-07-29 | 2016-04-06 | 重庆恒美涂料有限公司 | Vacuum plating water-borne coatings |
| CN105838198A (en) * | 2016-06-15 | 2016-08-10 | 青岛源之林农业科技开发有限公司 | Anti-corrosion coating and preparation method thereof |
| CN105925148A (en) * | 2016-06-15 | 2016-09-07 | 青岛源之林农业科技开发有限公司 | Anti-corrosion sampler and manufacturing method thereof |
| CN105969098A (en) * | 2016-06-15 | 2016-09-28 | 青岛源之林农业科技开发有限公司 | Anti-corrosion fishing barrel and preparation method thereof |
| CN105985708A (en) * | 2016-06-27 | 2016-10-05 | 青岛帅洋防锈科技有限公司 | Waterborne high temperature-resistant anti-corrosive paint and preparation method thereof |
| CN106317888A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Blue fluorescent colored glaze and making method thereof |
| CN106366854A (en) * | 2016-08-31 | 2017-02-01 | 中国科学院兰州化学物理研究所 | High-water-resistance self-emulsified double-component water-borne epoxy glass baking lacquer as well as preparation method and application thereof |
| CN108948927A (en) * | 2018-05-03 | 2018-12-07 | 阜南县铭钰柳木工艺品有限公司 | A kind of preparation method of the bamboo woven flower vase of blooming period prolonging |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040604A (en) * | 1988-09-02 | 1990-03-21 | 吴正永 | Functional glass coating for color filtering |
| CN1948200A (en) * | 2006-11-10 | 2007-04-18 | 华南理工大学 | Water colour transparent glass paint and its preparation method and application |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
-
2011
- 2011-12-13 CN CN2011104130424A patent/CN102559005A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040604A (en) * | 1988-09-02 | 1990-03-21 | 吴正永 | Functional glass coating for color filtering |
| CN1948200A (en) * | 2006-11-10 | 2007-04-18 | 华南理工大学 | Water colour transparent glass paint and its preparation method and application |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746768B (en) * | 2012-08-02 | 2014-12-10 | 西北永新涂料有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN102746768A (en) * | 2012-08-02 | 2012-10-24 | 西北永新化工股份有限公司 | Water-borne colorful glass paint and preparation method and application thereof |
| CN103102764B (en) * | 2012-11-13 | 2015-12-09 | 合肥市科睦佰水性材料有限公司 | A kind of high abrasion waterborne glass coatings and preparation method thereof |
| CN103102764A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | High-wear-resistant water-based glass paint and preparation method thereof |
| CN103102766A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | High adhesive force water-based glass paint and preparation method thereof |
| CN103102766B (en) * | 2012-11-13 | 2016-05-04 | 合肥市科睦佰水性材料有限公司 | A kind of high adhesion force aqueous glass paint and preparation method thereof |
| CN103059691A (en) * | 2012-12-19 | 2013-04-24 | 陈名海 | Graphene-modified anti-wear water-based glass coating as well as preparation method and application thereof |
| CN103436118B (en) * | 2013-07-29 | 2016-04-06 | 重庆恒美涂料有限公司 | Vacuum plating water-borne coatings |
| CN104058600A (en) * | 2014-06-13 | 2014-09-24 | 陈湛玲 | Glass ware gold-plating technology |
| CN105273630A (en) * | 2014-07-16 | 2016-01-27 | 开平市开物化工建材有限公司 | ECS-1002 resin-based glass paint and production process |
| CN104559555A (en) * | 2014-11-29 | 2015-04-29 | 上海国谷化工科技有限公司 | Method for preparing boiling-resistant waterborne acrylic paint |
| CN105153871A (en) * | 2015-07-10 | 2015-12-16 | 刘善江 | Aqueous paint for glass, and preparation method thereof |
| CN105153871B (en) * | 2015-07-10 | 2017-12-08 | 河北晨阳工贸集团有限公司 | A kind of glass sealing wax and preparation method thereof |
| CN105838198A (en) * | 2016-06-15 | 2016-08-10 | 青岛源之林农业科技开发有限公司 | Anti-corrosion coating and preparation method thereof |
| CN105925148A (en) * | 2016-06-15 | 2016-09-07 | 青岛源之林农业科技开发有限公司 | Anti-corrosion sampler and manufacturing method thereof |
| CN105969098A (en) * | 2016-06-15 | 2016-09-28 | 青岛源之林农业科技开发有限公司 | Anti-corrosion fishing barrel and preparation method thereof |
| CN105985708A (en) * | 2016-06-27 | 2016-10-05 | 青岛帅洋防锈科技有限公司 | Waterborne high temperature-resistant anti-corrosive paint and preparation method thereof |
| CN106317888A (en) * | 2016-08-23 | 2017-01-11 | 太仓市双凤镇薄彩工艺品厂 | Blue fluorescent colored glaze and making method thereof |
| CN106366854A (en) * | 2016-08-31 | 2017-02-01 | 中国科学院兰州化学物理研究所 | High-water-resistance self-emulsified double-component water-borne epoxy glass baking lacquer as well as preparation method and application thereof |
| CN108948927A (en) * | 2018-05-03 | 2018-12-07 | 阜南县铭钰柳木工艺品有限公司 | A kind of preparation method of the bamboo woven flower vase of blooming period prolonging |
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Application publication date: 20120711 |