CN102533015A - Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall - Google Patents
Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall Download PDFInfo
- Publication number
- CN102533015A CN102533015A CN2010106174367A CN201010617436A CN102533015A CN 102533015 A CN102533015 A CN 102533015A CN 2010106174367 A CN2010106174367 A CN 2010106174367A CN 201010617436 A CN201010617436 A CN 201010617436A CN 102533015 A CN102533015 A CN 102533015A
- Authority
- CN
- China
- Prior art keywords
- phenolic foam
- flame
- foam board
- pentaerythritol
- melamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 24
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title 1
- 239000006260 foam Substances 0.000 claims abstract description 31
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000839 emulsion Substances 0.000 claims abstract description 14
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 12
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 12
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 12
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 12
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 12
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 16
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- 230000009970 fire resistant effect Effects 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 238000010298 pulverizing process Methods 0.000 abstract description 4
- 239000002893 slag Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 230000009967 tasteless effect Effects 0.000 abstract 1
- 239000012774 insulation material Substances 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920006327 polystyrene foam Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000004794 expanded polystyrene Substances 0.000 description 2
- 239000004795 extruded polystyrene foam Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009422 external insulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- -1 pH 6-7 Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Landscapes
- Building Environments (AREA)
Abstract
本发明公开了一种外墙外保温酚醛泡沫板用防火阻燃界面剂的制备方法，本方法包括原材料配比及生产工艺。它是以乙酸乙烯酯-乙烯共聚乳液为基料，聚磷酸铵为脱水催化剂、季戊四醇为成炭剂和三聚氰胺为发泡剂的阻燃体系，并加入其他助剂配制而成。本发明的酚醛泡沫板用防火阻燃界面剂安全环保，无毒无味，在酚醛泡沫板表面形成一层既具有良好的柔韧性和粘结力，又具有优异的防火阻燃性能界面，增加了表面的韧性，提高了与粘结及抹面材料的粘结强度，起到了防止酚醛泡沫板粉化和掉渣的功能，因而，可明显改善酚醛泡沫板在外墙外保温中的使用效果。The invention discloses a preparation method of a fireproof and flame retardant interface agent for an external wall thermal insulation phenolic foam board. The method includes raw material ratio and production process. It is a flame-retardant system based on vinyl acetate-ethylene copolymer emulsion, ammonium polyphosphate as dehydration catalyst, pentaerythritol as char-forming agent and melamine as foaming agent, and is prepared by adding other additives. The fire-proof and flame-retardant interface agent for phenolic foam boards of the present invention is safe and environmentally friendly, non-toxic and tasteless, and forms a layer on the surface of the phenolic foam boards, which has good flexibility and cohesive force, and has excellent fire-proof and flame-retardant performance interfaces, increasing the The toughness of the surface improves the bonding strength with the bonding and plastering materials, and prevents the pulverization and slag of the phenolic foam board. Therefore, it can significantly improve the use effect of the phenolic foam board in external wall insulation.
Description
技术领域 technical field
本发明涉及到一种建筑界面剂的生产技术范畴，具体地讲，涉及到外墙外保温酚醛泡沫板用防火阻燃界面剂的制备方法。The invention relates to the production technical category of a building interface agent, in particular to a preparation method of a fire-proof and flame-retardant interface agent for an external thermal insulation phenolic foam board.
背景技术 Background technique
目前，建筑外墙外保温用保温材料主要分为无机和有机两类，无机材料如岩棉、玻璃棉、泡沫玻璃、微孔硅酸钙、憎水珍珠岩等，防火性能好，但导热系数较大，保温效果不理想，难以满足国家建筑节能标准要求，用量小；有机材料如聚苯乙烯泡沫EPS、XPS和聚氨酯硬泡PU等，质量轻，保温、隔热效果好，大量应用于建筑外墙外保温，但其最大的缺陷是防火安全性差，易老化、易燃烧，燃烧时烟雾大、毒性大，使用年限、防火性均不如无机保温材料。特别是EPS泡沫、XPS泡沫，耐火性极差，在80℃就产生熔融变形滴落，给建筑带来很大的安全隐患。就我国目前广泛采用的聚苯乙烯泡沫和聚氨酯硬泡而言，如果大幅度提高其阻燃性指标，从技术角度看尚不具备条件，即使加入大量阻燃剂，因一般阻燃剂的沸点小于300℃，火灾发生时，环境温度可高达1000℃，阻燃剂挥发，根本起不到阻燃效果，所以防火性能仍不理想，且成本大幅度提高。At present, thermal insulation materials used for external thermal insulation of building exterior walls are mainly divided into two types: inorganic and organic. Larger, the thermal insulation effect is not ideal, it is difficult to meet the requirements of the national building energy-saving standards, and the dosage is small; organic materials such as polystyrene foam EPS, XPS and polyurethane rigid foam PU, etc., are light in weight, good thermal insulation and heat insulation effects, and are widely used in buildings External wall insulation, but its biggest disadvantage is poor fire safety, easy aging, easy to burn, large smoke and high toxicity when burning, and its service life and fire resistance are not as good as inorganic insulation materials. Especially EPS foam and XPS foam have extremely poor fire resistance, and they will melt, deform and drip at 80°C, which brings great safety hazards to buildings. As far as polystyrene foam and polyurethane rigid foam are currently widely used in my country, if their flame retardancy index is greatly improved, it is not yet ready from a technical point of view. Even if a large amount of flame retardant is added, due to the boiling point of general flame retardant When the temperature is less than 300°C, when a fire occurs, the ambient temperature can be as high as 1000°C, the flame retardant will volatilize, and the flame retardant effect will not be achieved at all, so the fire resistance performance is still not ideal, and the cost will be greatly increased.
酚醛泡沫板为新一代保温、防火、隔音材料，它兼备了有机和无机保温材料的优点：轻质、保温好、尺寸稳定性好、防火性能优异，与聚苯乙烯泡沫和聚氨酯硬泡等材料相比，最大特点是耐热性好，低温收缩性小，具有独特的阻燃和尺寸稳定性，在2000℃高温下不燃烧、不熔化、不收缩、无毒气、无浓烟、无滴落，只是表面形成炭化层。有较强的环保、节能功效。但是，我国现有的酚醛泡沫板还存在硬脆，易粉化和掉渣等技术缺陷，当酚醛泡沫板作为建筑外墙保温材料时，除要对原料酚醛树脂进行增韧改性外，还要通过在其表面涂刷一道专用防火阻燃界面剂，增加酚醛泡沫板表面的强度，防止粉化和掉渣，提高其与抹面材料的粘结强度，目前国内外尚未有专门用于外墙外保温酚醛泡沫板的防火阻燃界面剂。Phenolic foam board is a new generation of thermal insulation, fireproof and sound insulation materials. It combines the advantages of organic and inorganic thermal insulation materials: light weight, good thermal insulation, good dimensional stability, and excellent fire resistance. It is compatible with polystyrene foam and polyurethane rigid foam. In comparison, the biggest feature is good heat resistance, low shrinkage at low temperature, unique flame retardancy and dimensional stability, no burning, no melting, no shrinkage, no poisonous gas, no dense smoke, no dripping at a high temperature of 2000 °C , only a carbonized layer is formed on the surface. It has strong environmental protection and energy saving effects. However, the existing phenolic foam boards in our country still have technical defects such as hardness and brittleness, easy pulverization and slag drop. It is necessary to brush a special fire-proof and flame-retardant interface agent on the surface to increase the strength of the surface of the phenolic foam board, prevent pulverization and slag, and improve its bonding strength with the plastering material. Fireproof and flame retardant interface agent for external insulation phenolic foam board.
本发明的目的就是要提供一种制备外墙外保温酚醛泡沫板用防火阻燃界面剂的制备方法。The object of the present invention is to provide a method for preparing a fire-resistant and flame-retardant interface agent for external thermal insulation phenolic foam boards.
发明内容 Contents of the invention
实现本发明外墙外保温酚醛泡沫板用防火阻燃界面剂的具体方法是：The specific method for realizing the fireproof and flame retardant interface agent for the external wall insulation phenolic foam board of the present invention is:
本发明的外墙外保温酚醛泡沫板用防火阻燃界面剂的原料为：乙酸乙烯酯-乙烯共聚乳液VAE-707，其外观为白色均匀乳状液，不挥发物含量≥54.5％，在25℃条件下粘度为500-1000mPa.S；聚磷酸铵为白色结晶或无定形微细粉末，聚合度n＝50，磷含量31.0-32.0％，氮含量14.0-15.0％；季戊四醇为白色结晶或粉末，单季戊四醇含量≥95％、熔点260℃；三聚氰胺为白色结晶粉末，密度1570kg/m3，分解温度为354℃；乳化剂OP-10主要成分为烷基酚与环氧乙烷的缩合物，外观为白色及乳白色糊状物，易溶于水，pH值为6-7，浊点61-67℃；有机硅消泡剂，其外观为白色乳液，有效物质含量23％，pH值为6-10。The raw material of the fire-resistant and flame-retardant interface agent for the external wall insulation phenolic foam board of the present invention is: vinyl acetate-ethylene copolymer emulsion VAE-707, whose appearance is a white uniform emulsion with a non-volatile content of ≥ 54.5%. The viscosity under the condition is 500-1000mPa.S; ammonium polyphosphate is white crystal or amorphous fine powder, polymerization degree n=50, phosphorus content 31.0-32.0%, nitrogen content 14.0-15.0%; pentaerythritol is white crystal or powder, single Pentaerythritol content ≥ 95%, melting point 260°C; melamine is white crystalline powder, density 1570kg/m 3 , decomposition temperature 354°C; emulsifier OP-10 is mainly composed of alkylphenol and ethylene oxide condensation product, appearance is White and milky white paste, soluble in water, pH 6-7, cloud point 61-67°C; silicone defoamer, its appearance is white emulsion, active substance content 23%, pH 6-10 .
原料选定后并按下列重量(％)配制：Raw materials are selected and formulated according to the following weight (%):
聚磷酸铵 30-35；Ammonium polyphosphate 30-35;
三聚氰胺 15-20；Melamine 15-20;
季戊四醇 10-15；Pentaerythritol 10-15;
乙酸乙烯酯-乙烯共聚乳液VAE-707 7.5-10；Vinyl acetate-ethylene copolymer emulsion VAE-707 7.5-10;
乳化剂OP-10 0.1-0.3；Emulsifier OP-10 0.1-0.3;
有机硅消泡剂 0.1-0.3；Silicone defoamer 0.1-0.3;
水 25-30。Water 25-30.
原料配比选定后，其生产工艺是：After the ratio of raw materials is selected, its production process is:
首先将水和乳化剂OP-10加入到分散罐中，开动搅拌机，并搅拌5分钟，然后依次将聚磷酸铵、三聚氰胺和季戊四醇加入分散罐中，调节搅拌机转速至每分钟500转至800转，搅拌30分钟至1小时，然后将搅拌机转速调至每分钟100转至200转，再将乙酸乙烯酯-乙烯共聚乳液VAE-707和有机硅消泡剂加入分散罐中进行搅拌，搅拌时间为10-20分钟，粘度在2,000-3,000mPa.S，之后过80目筛网出料，即制备出本发明的外墙外保温酚醛泡沫板用防火阻燃界面剂。First add water and emulsifier OP-10 into the dispersion tank, start the mixer, and stir for 5 minutes, then add ammonium polyphosphate, melamine and pentaerythritol into the dispersion tank in turn, adjust the speed of the mixer to 500 to 800 revolutions per minute, Stir for 30 minutes to 1 hour, then adjust the speed of the mixer to 100 to 200 rpm, then add vinyl acetate-ethylene copolymer emulsion VAE-707 and silicone defoamer into the dispersion tank for stirring, and the stirring time is 10 -20 minutes, the viscosity is 2,000-3,000mPa.S, and then pass through an 80-mesh sieve and discharge, that is, the fire-resistant and flame-retardant interface agent for external wall insulation phenolic foam boards of the present invention is prepared.
本发明的外墙外保温酚醛泡沫板用防火阻燃界面剂的特点是：The characteristics of the fireproof and flame retardant interface agent for external wall insulation phenolic foam board of the present invention are:
1、优异的粘结性，提高了酚醛泡沫板与胶粘剂和抹面胶浆的粘结强度，与水泥砂浆拉伸粘结强度为0.86MPa，与酚醛泡沫板拉伸粘结强度为0.18MPa，破坏界面在酚醛泡沫板上。1. Excellent cohesiveness, which improves the bonding strength between phenolic foam board and adhesive and plastering mortar. The tensile bonding strength with cement mortar is 0.86MPa, and the tensile bonding strength with phenolic foam board is 0.18MPa. Interface on phenolic foam board.
2、良好的防火阻燃性，其各项指标均达到了GB12441-2005饰面型防火涂料》标准要求。2. Good fire resistance and flame retardancy, and its various indicators have reached the standard requirements of GB12441-2005 Decorative Fireproof Coatings.
3、该产品为水性，对环境和人体无害，属环保型材料。3. The product is water-based, harmless to the environment and human body, and is an environmentally friendly material.
4、显著提高酚醛泡沫板表面的韧性和强度，防止粉化和掉渣，其柔韧性开裂应变为2.8％。4. Significantly improve the toughness and strength of the surface of phenolic foam board, prevent pulverization and slag falling, and its flexibility cracking strain is 2.8%.
具体实施方式 Detailed ways
实现本发明的外墙外保温酚醛泡沫板用界面剂的具体实施方式是：The specific embodiment that realizes the interface agent for external wall insulation phenolic foam board of the present invention is:
首先选定本发明外墙外保温酚醛泡沫板用界面剂的原料并按下列重量(％)配制：First select the raw material of the interface agent for the external wall insulation phenolic foam board of the present invention and prepare by the following weight (%):
聚磷酸铵 32.6；Ammonium polyphosphate 32.6;
三聚氰胺 18.0；Melamine 18.0;
季戊四醇 12.0；Pentaerythritol 12.0;
乙酸乙烯酯-乙烯共聚乳液VAE-707 8.5；Vinyl acetate-ethylene copolymer emulsion VAE-707 8.5;
乳化剂OP-10 0.2；Emulsifier OP-10 0.2;
有机硅消泡剂 0.2；Silicone defoamer 0.2;
水 28.5。Water 28.5.
原料配比选定后，进行具体的生产工艺：After the ratio of raw materials is selected, the specific production process is carried out:
首先将水和乳化剂OP-10加入到分散罐中，开动搅拌机，并搅拌5分钟，然后依次将聚磷酸铵、三聚氰胺和季戊四醇加入分散罐中，调节搅拌机转速至每分钟650转，搅拌45分钟，然后将搅拌机转速调至每分钟120转，再将乙酸乙烯酯-乙烯共聚乳液VAE-707和有机硅消泡剂加入分散罐中进行搅拌，搅拌时间15分钟，粘度在2500mPa.S，之后过80目筛网出料，即制备出本发明的外墙外保温酚醛泡沫板用防火阻燃界面剂。First add water and emulsifier OP-10 into the dispersion tank, start the mixer, and stir for 5 minutes, then add ammonium polyphosphate, melamine and pentaerythritol into the dispersion tank in turn, adjust the speed of the mixer to 650 rpm, and stir for 45 minutes , then adjust the speed of the mixer to 120 revolutions per minute, then add vinyl acetate-ethylene copolymer emulsion VAE-707 and silicone defoamer into the dispersion tank for stirring, the stirring time is 15 minutes, the viscosity is 2500mPa.S, and then pass The 80-mesh sieve is discharged, that is, the fire-resistant and flame-retardant interface agent for the external wall insulation phenolic foam board of the present invention is prepared.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106174367A CN102533015A (en) | 2010-12-22 | 2010-12-22 | Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106174367A CN102533015A (en) | 2010-12-22 | 2010-12-22 | Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102533015A true CN102533015A (en) | 2012-07-04 |
Family
ID=46341107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106174367A Pending CN102533015A (en) | 2010-12-22 | 2010-12-22 | Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102533015A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861792A (en) * | 2015-05-22 | 2015-08-26 | 营口象圆新材料工程技术有限公司 | Special alkali-resisting interfacial agent for phenolic foam insulation board |
| CN110903689A (en) * | 2019-10-24 | 2020-03-24 | 江苏兰陵高分子材料有限公司 | Hydrophobic modified ternary intumescent flame retardant, preparation method thereof and water-based intumescent fire retardant coating |
| CN111331969A (en) * | 2020-02-26 | 2020-06-26 | 北京建筑材料科学研究总院有限公司 | A kind of polyurethane foam porous glass wool composite insulation board and preparation method thereof |
| CN113956014A (en) * | 2021-11-18 | 2022-01-21 | 天元建设集团有限公司 | Fireproof interface agent and preparation method thereof |
| CN115902178A (en) * | 2022-10-14 | 2023-04-04 | 北京建筑材料检验研究院股份有限公司 | Method for detecting acidity value and adhesive property of phenolic foam material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117510A (en) * | 2007-09-14 | 2008-02-06 | 东北林业大学 | A Modified Amino Resin-Based Intumescent Waterborne Flame-Retardant Coating |
-
2010
- 2010-12-22 CN CN2010106174367A patent/CN102533015A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117510A (en) * | 2007-09-14 | 2008-02-06 | 东北林业大学 | A Modified Amino Resin-Based Intumescent Waterborne Flame-Retardant Coating |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861792A (en) * | 2015-05-22 | 2015-08-26 | 营口象圆新材料工程技术有限公司 | Special alkali-resisting interfacial agent for phenolic foam insulation board |
| CN104861792B (en) * | 2015-05-22 | 2018-04-03 | 营口象圆新材料工程技术有限公司 | A kind of special alkaline-resisting interfacial agents of phenolic foam heat insulation plate |
| CN110903689A (en) * | 2019-10-24 | 2020-03-24 | 江苏兰陵高分子材料有限公司 | Hydrophobic modified ternary intumescent flame retardant, preparation method thereof and water-based intumescent fire retardant coating |
| CN110903689B (en) * | 2019-10-24 | 2021-11-16 | 江苏兰陵高分子材料有限公司 | Hydrophobic modified ternary intumescent flame retardant, preparation method thereof and water-based intumescent fire retardant coating |
| CN111331969A (en) * | 2020-02-26 | 2020-06-26 | 北京建筑材料科学研究总院有限公司 | A kind of polyurethane foam porous glass wool composite insulation board and preparation method thereof |
| CN111331969B (en) * | 2020-02-26 | 2021-04-13 | 北京建筑材料科学研究总院有限公司 | Polyurethane foam porous glass wool composite insulation board and preparation method thereof |
| CN113956014A (en) * | 2021-11-18 | 2022-01-21 | 天元建设集团有限公司 | Fireproof interface agent and preparation method thereof |
| CN115902178A (en) * | 2022-10-14 | 2023-04-04 | 北京建筑材料检验研究院股份有限公司 | Method for detecting acidity value and adhesive property of phenolic foam material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101914333B (en) | Aqueous nano ultra-thin steel structure fireproof coating and preparation method thereof | |
| WO2014090105A1 (en) | Water-based expandable fireproof coating for steel structure and preparation method therefor | |
| CN105694648B (en) | The resistance to fire-proof and explosion-proof coating of hydro carbons | |
| CN101323727A (en) | A kind of water-based environment-friendly intumescent fireproof coating and preparation method thereof | |
| CN103740231A (en) | Water-based expansive type nano fireproof coating for cable and preparation method thereof | |
| CN103771802B (en) | A kind of environmental protection and energy saving pattern bubble A level fireproof heat insulating strong board and preparation method thereof | |
| CN105885488A (en) | Preparation method of novel inorganic ultra-thin expansion steel structure fire retardant coating | |
| TWI477552B (en) | Fireproof polyurethane material and fireproof structure | |
| CN104692758A (en) | Smoke-suppressing type outdoor flame retardant steel structure fireproof coating | |
| CN102533015A (en) | Preparation method of fireproof flame-retardant interfacial agent for exterior insulation phenol formaldehyde foam board of outer wall | |
| CN104830137A (en) | Sound-absorbing and moisture-resistant tunnel fireproof coating and preparation method thereof | |
| CN102020910A (en) | Hydrocarbon fire resistant ultrathin expanded fireproof coating and preparation method thereof | |
| CN102276974B (en) | High-fire-resistance rigid polyurethane foam plastic and preparation method thereof | |
| CN101786829A (en) | Fireproof interface mortar, preparation method and application thereof | |
| CN103911025B (en) | A kind of aqueous fire-proof coating | |
| CN102964887B (en) | Production process of fireproofing anti-flaming adhesion agent for exterior wall external insulation phenolic foam board | |
| CN102423940B (en) | Non-combustible compact plate and preparation method thereof | |
| CN106084632A (en) | A kind of organic/inorganic compound insulating material and preparation method | |
| CN102976678A (en) | Partition board material | |
| CN106833208B (en) | A kind of smoke-inhibiting type indoor ultrathin steel structure fireproof coating and its preparation process | |
| CN102261137B (en) | Ultrathin stone polyurethane composite board and preparation method thereof | |
| CN103333424B (en) | Halogen-free environment-friendly polystyrene flame retardant and preparation method thereof | |
| CN111116138A (en) | Fireproof heat-insulation polymer cement-based waterproof slurry and preparation method thereof | |
| CN105131745A (en) | Water-based fire-resistant coating for high-expansion steel structure and preparation method and application thereof | |
| EP4177230A1 (en) | Composition for thermal insulation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120704 |