CN102504712A - Double-sided pressure sensitive adhesive tape capable of movement in short time, and preparation method thereof - Google Patents

Double-sided pressure sensitive adhesive tape capable of movement in short time, and preparation method thereof Download PDF

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CN102504712A
CN102504712A CN 201110364736 CN201110364736A CN102504712A CN 102504712 A CN102504712 A CN 102504712A CN 201110364736 CN201110364736 CN 201110364736 CN 201110364736 A CN201110364736 A CN 201110364736A CN 102504712 A CN102504712 A CN 102504712A
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adhesive
adhesive layer
sensitive adhesive
adhesive tape
beads
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CN 201110364736
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Chinese (zh)
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CN102504712B (en )
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何利军
李印柏
林新松
王兵
翟海潮
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北京天山新材料技术股份有限公司
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Abstract

The invention discloses a double-sided pressure sensitive adhesive tape capable of free movement in a short time, and a method thereof. The adhesive tape comprises two adhesive layers, wherein the surface of an adhesive layer is covered with 5-10/cm<2> microbeads, and the surface of the adhesive layer is covered with release paper. The adhesive layers are the pressure sensitive adhesive layers. The preparation method for the tape comprises: mixing 2-ethylhexyl acrylate and an acrylic acid monomer, adding a certain monomer weight of azobisisobutylnitrile, and dissolving in ethyl acetate to obtain a mixed solution; in the case of nitrogen introducing, carrying out a reaction for 8 hours at a temperature of 60-65 DEG C to obtain an acrylate polymer; adding a cross-linking agent to the solution, and uniformly mixing; coating the adhesive solution on the silicone treated release paper, and conveying to a baking oven to carry out drying, wherein the temperature is 100 DEG C, and the time is 5 minutes; adhering the adhesive layer to the substrate after completing the drying, wherein the thickness of the adhesive layer after the drying is 70-80 mum; preparing a dried adhesive film by the same method, and uniformly spraying the microbeads with the diameter of 10-30 mum on the adhesive surface after the adhesive film is adhered to the substrate, wherein each square centimeter of the adhesive surface is sprayed with 5-10 of the microbeads, and the release paper is compounded on the adhesive layer after completing the microbead spraying.

Description

一种短时间内可移动的双面压敏粘合带及制备方法 One kind of short movable sided pressure-sensitive adhesive tape and a preparation method

技术领域 FIELD

[0001] 本发明涉及一种压敏胶带,尤其涉及一种短时间内可移动的双面压敏粘合带及制备方法。 [0001] The present invention relates to a pressure sensitive adhesive tape, especially double-sided pressure-sensitive adhesive tape, and relates to a method of preparing a movable short.

背景技术 Background technique

[0002] 目前用于物品固定的双面压敏粘合带主要有泡棉基材双面粘合带、无基材双面粘合带、薄膜基材双面粘合带、纺织或非纺织品基材的双面粘合带。 [0002] It immobilized article for double-sided pressure-sensitive adhesive tape main foam substrate double-sided adhesive tape, double-sided adhesive tape without a substrate, the film substrate double-sided adhesive tape, or a non-woven textiles the double-sided adhesive tape base material. 这些双面粘合带其中一种用于临时性的粘贴固定,使用完成后易于揭除。 The double-sided adhesive tape wherein a temporary fixing adhesive for easy removability after the completion of use. 另一种是用于永久固定型,粘合带粘贴后即无法再揭除,即使能够揭除也会造成粘接件破坏或者粘合带发生破坏,粘合带破坏后残留物清理困难。 Another is a permanently fixed, after the adhesive tape joining no longer strippable, even if the adhesive can be strippable member can also cause damage or destruction occurs the adhesive tape, the adhesive tape after the destruction of the residue cleanup difficult. 双面粘合带所用的压敏胶一般为丙烯酸酯型或橡胶型,压敏胶一般先涂布于离型纸或离型膜上,然后进行干燥或UV照射,再通过复合或转移得到双面压敏粘合带制 The double-sided pressure-sensitive adhesive tape are generally used acrylic type or a rubber type pressure-sensitive adhesive is generally applied to a first release film or release paper, followed by drying or UV irradiation, and then the composite obtained by double transfer or The pressure-sensitive adhesive tape prepared surface

P P

ΡΠ ο ΡΠ ο

[0003] 上面所提及的永久固定型双面压敏粘合带在固定应用时一般先提前与一个被粘物表面粘贴成组合件,我们称之为“预组件”。 [0003] The above-mentioned double-sided pressure-sensitive adhesive permanently fixed with the fixed first application typically is advanced with a sticky surface attached to the assembly, which we call "pre-assembly." 在需要与另一个表面粘接时,将粘合带表面的离型纸或离型膜揭除后与另一个被粘物表面粘合,后一个粘合面我们称之为“贴合面”。 Release paper or release film with an adhesive if necessary the other surface, the rear surface of the adhesive tape is bonded to another removability sticky surface, a rear bonding face we call "bonding surface" . 由于普通双面粘合带的粘合层在很短的时间内即与贴合面达到有效的粘合,造成在初期粘贴位置错误需要进行调整时无法对粘合带进行无损的移动,只能以破坏方式进行重新返工, 造成材料浪费及降低生产效率。 Since the adhesive layer of the double-sided adhesive tape in general very short time, i.e. to achieve effective adhesion to the bonding surface, resulting in non-destructive not move the adhesive tape joining position error at the initial adjustment is required, only to destroy the way of rework, wasted material and lower production efficiency.

发明内容 SUMMARY

[0004] 为了克服现有技术的不足,本发明的目的在于提供一种在短时间内可以自由移动的双面压敏粘合带,在初始粘贴后对预组件位置需要进行调整时可方便的将粘合带从贴合面上揭下来,揭下来的带有 [0004] In order to overcome the deficiencies of the prior art, an object of the present invention to provide a double-sided pressure-sensitive adhesive tape which is freely movable in a short time, can be easily pre-assembly position when adjustment is required after the initial paste attached to the adhesive tape peeled off from the bonded surface, peeled off with

双面粘合带的预组件可再次进行粘贴,而不需要更换粘合带或破坏预组件。 Pre-assembly of double-sided adhesive tape can be attached again, without the need to replace adhesive tape or destroy pre-assembly.

[0005] 为了实现上述的目的,本发明采用了如下技术方案:包括两个胶粘层,其特点是所述其中一个胶粘层的表面覆盖有5-10个/cm2微珠,所述胶粘层的表面覆盖离型纸;所述胶粘层为压敏胶层,可制成有基材或者无基材的胶粘层。 [0005] To achieve the above object, the present invention employs the following technical solutions: comprises two adhesive layers, characterized wherein a surface of said adhesive layer is covered with a 5-10 / cm2 beads, the gum surface of the release paper covering the adhesive layer; the adhesive layer is a pressure sensitive adhesive layer, can be made with a substrate or a substrate-adhesive layer.

[0006] 上述微珠为金属微珠、玻璃微珠或陶瓷微珠,所述微珠直径为10_30um,所述微珠是中空或者实心,成圆率大于等于85%。 [0006] The microbeads of metal beads, ceramic beads, or glass beads, the beads having a diameter of 10_30um, the beads are hollow or solid, circularity greater than or equal to 85%.

[0007] 上述基材为PE泡棉、EVA泡棉、PU泡棉、EPDM泡棉、PVC泡棉、无纺布、纺织布或各种塑料薄膜。 [0007] The substrate is a PE foam, EVA foam, PU foam, EPDM foam, PVC foam, nonwoven fabric, woven fabric or plastic film.

[0008] 制备所述一种短时间内可移动的双面压敏粘合带的方法,该方法是: [0008] The method of preparing the one movable short sided pressure-sensitive adhesive tape, which is:

将丙烯酸一2 —乙基己酯与丙烯酸单体混和,然后加入单体重量0. 2^0. 5%偶氮二异丁腈溶于乙酸乙酯中,得到混和溶液;在通氮气的情况下于60 - 65°C反应8小时,得到丙烯酸酯类聚合物,然后将交联剂加入上述溶液中并混和均勻;将所得到粘合剂溶液涂布于有机硅处理过的离型纸上并送入烘箱进行干燥,温度设定为100°C,时间为5分钟;干燥完成后胶层厚度为70 - 80微米,干燥后将胶层与基材进行贴合;用同样的方法再完成一张干燥后的胶膜,在与基材贴合后在胶面上按每平米厘米5 - 10个的数量均勻洒上直径为10-30um微米的微珠,完成后再用离型纸复合在胶层上。 The acrylic acid a 2 - ethylhexyl acrylate and acrylic monomer mixture, the monomer is then added 0.2 weight ^ 05% of azobisisobutyronitrile dissolved in ethyl acetate, to give mixed solution; in the case of nitrogen in the 60 - 65 ° C for 8 hours to obtain an acrylic polymer, a crosslinking agent and then added to the solution and mixed uniformly; the resulting solution is applied onto the adhesive to a silicone-treated release paper and sent the drying oven, temperature was set to 100 ° C, for 5 min; after completion of the drying layer thickness of 70--80 microns, adhesive layer and base material after drying bonding; the same way and then completing a after drying the film, and the substrate after bonding in the gum per square meter surface of 5 cm - 10 number of microbeads uniformly sprinkled 10-30um microns in diameter, after the completion of release paper composite in the gum layer.

[0009] 有益效果:本发明其中一个胶粘层面覆盖着一定数量的微珠,这些微珠可以使得在初始粘贴后对预组件位置需要进行调整时可方便的将 [0009] The beneficial effects: the present invention wherein a level of adhesive covering a certain number of beads, the beads may be convenient for such pre-assembly position needs to be adjusted after the initial pasted

带有双面粘合带的预组件从贴合面上揭下来,揭下来的带有双面粘合带的预组件可再次进行粘贴,而不需要更换双面粘合带或造成预组件破坏而更换。 Pre-assembly with a double-sided adhesive tape is peeled off from the bonded surface, peeled off the pre-assembly with the double-sided adhesive tape can be attached again, without the need to replace the double-sided adhesive tape or cause damage preassembly and replacement.

具体实施方式 detailed description

[0010] 为使本发明的目的、技术方案和优点更加清楚明白,以下结合具体实施例,对本发明进一步详细说明。 [0010] To make the objectives, technical solutions, and advantages of the present invention will become more apparent hereinafter with reference to specific embodiments, the present invention is further described in detail.

[0011] 实施例1 [0011] Example 1

本发明所述的压敏粘合剂为丙烯酸酯类压敏粘合剂,丙烯酸酯压敏粘合剂通常以(甲基)丙烯酸烷基酯和具有自由基聚合型不饱和基团并至少一个反应性官能团的单体共聚合而得到。 The pressure-sensitive adhesive of the present invention are acrylate pressure sensitive adhesives, acrylate pressure sensitive adhesives are typically (meth) acrylic acid alkyl ester having a radical polymerizable unsaturated group and at least one monomer reactive functional group obtained by copolymerizing.

[0012] 对于(甲基)丙烯酸烷基酯可以列举的常用的有:(甲基)丙烯酸甲酯、(甲基)丙烯酸乙酯、(甲基)丙烯酸正丁酯、(甲基)丙烯酸异丁酯、(甲基)丙烯酸一2 —乙基己酯、(甲基) 丙烯酸正辛酯、(甲基)丙烯酸异辛酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸十八烷基酯等。 [0012] For the (meth) acrylic acid alkyl ester may be used are exemplified meth) acrylate, ethyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate butyl (meth) acrylate, a 2 - ethylhexyl (meth) acrylate, n-octyl (meth) acrylate, isooctyl (meth) acrylate, lauryl (meth) acrylate, octadecyl ester and the like. 以上单体可以单独也可以两种以上组合使用。 More monomers may be used alone or two or more thereof. 该单体的用量占单体总量的80 - 99%。 80 with the total amount of the monomers of the monomer --99%.

[0013] 作为官能单体可以列举的常用的有:(甲基)丙烯酸、衣康酸、(甲基)丙烯酸羟基乙酯、(甲基)丙烯酸β —羟基乙酯、(甲基)丙烯酸羟基丙酯、(甲基)丙烯酸羟基丁酯、丙烯酰胺、N—羟甲基丙烯酰胺、甲基丙烯酸缩水甘油酯、马来酸酐等。 [0013] Examples of the functional monomer include the commonly used meth) acrylic acid, itaconic acid, (meth) acrylate, hydroxypropyl (meth) acrylate, β - hydroxyethyl (meth) acrylate, hydroxypropyl propyl (meth) acrylate, hydroxybutyl methacrylate, acrylamide, N- methylol acrylamide, glycidyl methacrylate, maleic anhydride and the like. 该单体可以单独也可以两种以上组合使用,用量一般占单体总量的1 一20%。 The monomers may be used alone or two or more may be used in combination, an amount of usually accounts for 20% of the total amount of monomers a.

[0014] 另外可以用于共聚合的其它类型单体还可以包括:乙酸乙烯酯、苯乙烯、甲基苯乙烯、丙烯腈。 [0014] may additionally be used other types of copolymerizable monomers can also include: vinyl acetate, styrene, methyl styrene, acrylonitrile. 其用量一般占单体总量的O — 20%。 O in an amount of usually accounts for the total amount of monomers --20%.

[0015] 根据需要粘合剂可以加入交联剂(如异氰酸酯类交联剂、酰胺类交联剂、乙酰丙酮金属盐类)、增粘树脂(如松香及其衍生物、萜烯或改性萜烯类、油溶性酚醛类)、抗老化剂、 填料、颜料等。 [0015] The adhesive needs a crosslinking agent may be added (e.g., isocyanate crosslinking agents, crosslinking agents amides, acetylacetone metal salts), tackifier resin (such as rosin and its derivatives, terpenes and modified terpenes, oil-soluble phenol-based), anti-aging agents, fillers, pigments and the like.

[0016] 上述的压敏粘合剂在制备时可以采用热聚合引发剂或光聚合引发剂进行固化反应得到。 [0016] The pressure sensitive adhesive may be employed in the preparation of a thermal polymerization initiator or a photopolymerization initiator to obtain a curing reaction.

[0017] 用于热聚合引发剂可以提及的有:偶氮类聚合引发剂(例如,偶氮二异丁腈、偶氮二甲基丁腈、偶氮二异庚腈)。 [0017] A thermal polymerization initiator may be mentioned are: azo-based polymerization initiators (e.g., azobisisobutyronitrile, azobis methylbutyronitrile, azobis iso-heptonitrile). 过氧化物类聚合引发剂(例如,过氧化二苯甲酰、过氧化二苯甲酰叔丁酯、过氧化甲乙酮、过氧化马来酸叔丁酯)。 Peroxide-based polymerization initiators (e.g., dibenzoyl peroxide, t-butyl over dibenzoyl peroxide, methyl ethyl ketone peroxide, tert-butyl maleate). 热聚合引发剂的用量一般为单体总量的0. 2〜0. 5%O The amount of thermal polymerization initiator to total monomers is generally 0. 2~0. 5% O

[0018] 光聚合型引发剂可以提及的有:苯偶姻类及其衍生物、苯偶酰类及其衍生物、苯乙酮类、羟烷基苯酮类、胺烷基苯酮类、酰基磷氧化物、二苯甲酮类、硫杂蒽酮类。 [0018] The photopolymerization initiators may be mentioned are: benzoin and derivatives thereof, benzil and derivatives thereof, acetophenones, hydroxy alkyl ketones, alkyl ketones amine , acyl phosphorus oxide, benzophenones, thioxanthone. 以上引发剂可以单独也可以两种以上组合使用。 Or more initiators may be used alone or two or more thereof. 用量占单体总量的0. 0广5%。 Guangzhou accounts for 5% of the total amount of monomer 0.0.

[0019] 具体实施方法:将92重量份的丙烯酸一2 -乙基己酯与8重量份的丙烯酸单体混和,然后加入单体重量0. 05%的偶氮二异丁腈溶于乙酸乙酯中,得到混和溶液。 [0019] DETAILED DESCRIPTION Methods: a 92 parts by weight of acrylic acid 2 - ethylhexyl acrylate and 8 parts by weight of an acrylic monomer mixture, followed by addition of 0.05% by weight of the monomers of azobisisobutyronitrile dissolved in ethyl acetate to give a mixed solution. 在通氮气的情况下于60 - 65°C反应8小时,得到分子量为100 - 150万的丙烯酸酯类聚合物,聚合物的固体含量为30%。 8 hours 65 ° C, a molecular weight of 100 - - 60 in the case of nitrogen 1,500,000 acrylic polymer, the solid content of the polymer was 30%. 然后将1重量份的交联剂(Cytec cymel 325美国氰特公司产品)加入上述压敏粘合剂溶液中并混和均勻。 Then 1 part by weight of a crosslinker (Cytec cymel 325 US Cytec Company) was added to the pressure-sensitive adhesive solution and mixed uniformly. 将所得到粘合剂溶液涂布于有机硅处理过的离型纸上并送入烘箱进行干燥,温度设定为10(TC,时间为5分钟。干燥完成后胶层厚度为70 - 80 微米,干燥后将胶层与PE泡棉进行贴合。用同样的方法再完成一张干燥后的胶膜,不同的是在胶膜与PE泡棉贴合后在胶面上按每平米厘米5 - 10个的数量均勻洒上直径为10 -30微米的微珠,完成后再用离型纸复合在胶层上。 The resulting adhesive solution was applied to a silicone-treated release paper and fed into the drying oven, temperature was set to 10 (TC, time of 5 minutes after completion of the drying layer thickness of 70 - 80 microns , after drying for PE foam adhesive layer and bonded. the same way again after completion of a dried film, except that the PE foam film after bonding surface of the plastic per square meter at 5 cm - 10 number of uniformly sprinkled diameter of 10 to 30 microns in the microbeads, on the subbing layer before the completion of release paper composite.

[0020] 对比例1 [0020] Comparative Example 1

按照实例1的方法所制得的相同的压敏胶,所不同的是微珠的数量为每平米厘米为2 — 5个。 The method of Example 1 prepared in the same pressure-sensitive adhesive, except that the number of beads per square centimeter of 2 - 5.

[0021] 对比例2 [0021] Comparative Example 2

按照实例1的方法所制得的相同的压敏胶,所不同的是微珠的数量为每平米厘米为15 - 20 个。 In the same manner as in Example 1 of pressure-sensitive adhesive prepared, except that the number of beads per square centimeter is within 15 - 20.

[0022] 对比例3 [0022] Comparative Example 3

按照实例1的方法所制得的相同的压敏胶,所不同的是微珠的直径为50 - 100微米。 The method of Example 1 prepared in the same pressure-sensitive adhesive, except that the microbeads having a diameter of 50--100 microns.

[0023] 对比例4 [0023] Comparative Example 4

按照实例1的方法所制得的相同的压敏胶,所不同的是两个胶面均未施洒微珠。 In the same manner as in Example 1 of pressure-sensitive adhesive prepared, except that the two adhesive surfaces were not administered sprinkling beads.

[0024] 1、微珠直径测量 [0024] 1, bead diameter measurement

使用数显示式千分尺进行或测量显微镜测量2、洒珠数量测定 Using several display type micrometer or measurement 2 measurement microscope, measuring the number of beads sprinkled

采用直尺划线结合10倍放大镜目测计算IcmX Icm方格内的微珠数量,最少测量10个格。 Binding scribing using 10x magnification ruler visually count the number of beads in the IcmX Icm squares, measuring a minimum of 10 cells.

[0025] [0025]

表1 Table 1

Figure CN102504712AD00051

3、施工性评价测试 3, construction evaluation test

Figure CN102504712AD00061

Claims (4)

  1. 1. 一种短时间内可移动的双面压敏粘合带,包括两个胶粘层,其特征在于:所述其中一个胶粘层的表面覆盖有5-10个/cm2微珠,胶粘层的表面覆盖离型纸;所述胶粘层为压敏胶层,可制成有基材或者无基材的胶粘层。 A movable short double-sided pressure-sensitive adhesive tape, comprising two adhesive layers, characterized in that: a surface wherein said adhesive layer is covered with a 5-10 / cm2 beads, plastic surface of the release paper covering the adhesive layer; the adhesive layer is a pressure sensitive adhesive layer, can be made with a substrate or a substrate-adhesive layer.
  2. 2.根据权利要求1所述的一种短时间内可移动的双面压敏粘合带,其特征在于:所述微珠为金属微珠、玻璃微珠或陶瓷微珠,所述微珠直径为10-30um,所述微珠是中空或者实心,成圆率大于等于85%。 The double-sided pressure-sensitive adhesive tape according to one kind of short movable to claim 1, wherein: the beads metal beads, ceramic beads, or glass beads, the beads having a diameter of 10-30um, the beads are hollow or solid, circularity greater than or equal to 85%.
  3. 3.根据权利要求1所述的一种短时间内可移动的双面压敏粘合带,其特征在于:所述基材为PE泡棉、EVA泡棉、PU泡棉、EPDM泡棉、PVC泡棉、无纺布、纺织布或各种塑料薄膜。 The double-sided pressure-sensitive adhesive tape according to one kind of short movable to claim 1, wherein: said substrate is a PE foam, EVA foam, PU foam, EPDM foam, PVC foam, nonwoven fabric, woven fabric or plastic film.
  4. 4.制备权利要求1所述一种短时间内可移动的双面压敏粘合带的方法,该方法是: 将丙烯酸一2 —乙基己酯与丙烯酸单体混和,然后加入单体重量0. 2^0. 5%偶氮二异丁腈溶于乙酸乙酯中,得到混和溶液;在通氮气的情况下于60 - 65°C反应8小时,得到丙烯酸酯类聚合物,然后将交联剂加入上述溶液中并混和均勻;将所得到粘合剂溶液涂布于有机硅处理过的离型纸上并送入烘箱进行干燥,温度设定为100°C,时间为5分钟;干燥完成后胶层厚度为70 - 80微米,干燥后将胶层与基材进行贴合;用同样的方法再完成一张干燥后的胶膜,在与基材贴合后在胶面上按每平米厘米5 — 10个的数量均勻洒上直径为10-30um微米的微珠,完成后再用离型纸复合在胶层上。 A method of short movable sided pressure-sensitive adhesive tape as claimed in claim 4. Preparation of 1, which is: an acrylic one 2 - ethyl hexyl acrylate and the acrylic monomer mixture, followed by addition of the monomers by weight . ^ 0 0.2 5% azobisisobutyronitrile dissolved in ethyl acetate, to give mixed solution; 60 in the case of nitrogen - 8 hours 65 ° C, to give an acrylic polymer, and then cross-linked agent added to the solution and mixed uniformly; binder solution thus obtained was coated on a silicone-treated release paper and dried into an oven, set at a temperature of 100 ° C, for 5 min; complete drying after the layer thickness of 70--80 microns, adhesive layer and substrate are bonded together after drying; the same way again after completion of a dried film, and the substrate after bonding the surface of the plastic per square meter cm 5 - 10 number of microbeads uniformly sprinkled 10-30um microns in diameter, the composite after the completion of release paper on the adhesive layer.
CN 201110364736 2011-11-17 2011-11-17 Double-sided pressure sensitive adhesive tape capable of movement in short time, and preparation method thereof CN102504712B (en)

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
CN103254824A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Heat-conductive electric appliance insulated foam adhesive tape for high temperature and preparation method thereof
CN103254823A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Foam adhesive tape and preparation method thereof
CN103254825A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Non-base material adhesive tape and preparation method thereof
CN104152072A (en) * 2012-12-18 2014-11-19 苏州斯迪克新材料科技股份有限公司 Preparation process of high-reliability heat-conducting adhesive tape
CN104152071A (en) * 2012-12-18 2014-11-19 苏州斯迪克新材料科技股份有限公司 Preparation method of high-viscosity adhesive tape

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EP0315072A2 (en) * 1987-10-31 1989-05-10 Nippon Carbide Kogyo Kabushiki Kaisha Pressure-sensitive adhesive layer
WO2002034855A1 (en) * 2000-10-25 2002-05-02 3M Innovative Properties Company Fluid-activatable adhesive articles and methods
CN101275059A (en) * 2007-03-28 2008-10-01 萍 刘 Heat-resistant strippable micro-viscous pressure-sensitive adhesive film and preparation thereof

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US3331729A (en) * 1963-02-14 1967-07-18 Minnesota Mining & Mfg Adhesive bonding method and product
EP0315072A2 (en) * 1987-10-31 1989-05-10 Nippon Carbide Kogyo Kabushiki Kaisha Pressure-sensitive adhesive layer
WO2002034855A1 (en) * 2000-10-25 2002-05-02 3M Innovative Properties Company Fluid-activatable adhesive articles and methods
CN101275059A (en) * 2007-03-28 2008-10-01 萍 刘 Heat-resistant strippable micro-viscous pressure-sensitive adhesive film and preparation thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254824A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Heat-conductive electric appliance insulated foam adhesive tape for high temperature and preparation method thereof
CN103254823A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Foam adhesive tape and preparation method thereof
CN103254825A (en) * 2012-07-10 2013-08-21 东莞市富印胶粘科技有限公司 Non-base material adhesive tape and preparation method thereof
CN103254824B (en) 2012-07-10 2014-10-08 东莞市富印胶粘科技有限公司 High temperature electrical conductivity, thermal insulating foam tape and its manufacturing method
CN103254823B (en) 2012-07-10 2014-10-29 东莞市富印胶粘科技有限公司 One kind of acrylic foam tape and preparation method
CN103254825B (en) 2012-07-10 2014-10-29 东莞市富印胶粘科技有限公司 A high-temperature adhesive tape and the substrate for producing acrylic acid
CN104152072A (en) * 2012-12-18 2014-11-19 苏州斯迪克新材料科技股份有限公司 Preparation process of high-reliability heat-conducting adhesive tape
CN104152071A (en) * 2012-12-18 2014-11-19 苏州斯迪克新材料科技股份有限公司 Preparation method of high-viscosity adhesive tape
CN104152071B (en) * 2012-12-18 2016-04-27 苏州斯迪克新材料科技股份有限公司 A method for preparing a high adhesive tape
CN104152072B (en) * 2012-12-18 2016-07-06 苏州斯迪克新材料科技股份有限公司 Preparation of thermally conductive adhesive tape with high reliability

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