CN102492541A - Method for extracting rose hip oil by supercritical carbon dioxide - Google Patents
Method for extracting rose hip oil by supercritical carbon dioxide Download PDFInfo
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- CN102492541A CN102492541A CN2011104147764A CN201110414776A CN102492541A CN 102492541 A CN102492541 A CN 102492541A CN 2011104147764 A CN2011104147764 A CN 2011104147764A CN 201110414776 A CN201110414776 A CN 201110414776A CN 102492541 A CN102492541 A CN 102492541A
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- Prior art keywords
- carbon dioxide
- extraction
- oil
- supercritical carbon
- fructus rosae
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 10
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 10
- 239000010667 rosehip oil Substances 0.000 title abstract 5
- 238000000605 extraction Methods 0.000 claims abstract description 26
- 238000001291 vacuum drying Methods 0.000 claims abstract description 6
- 238000003815 supercritical carbon dioxide extraction Methods 0.000 claims description 9
- 238000010298 pulverizing process Methods 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims 1
- 238000011068 loading method Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 18
- 238000001035 drying Methods 0.000 abstract description 5
- 241000220317 Rosa Species 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract 3
- 241000196324 Embryophyta Species 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 238000012856 packing Methods 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 abstract 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 17
- 235000021050 feed intake Nutrition 0.000 description 4
- 241000109365 Rosa arkansana Species 0.000 description 3
- 235000005066 Rosa arkansana Nutrition 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000021022 fresh fruits Nutrition 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- 208000006770 Ascorbic Acid Deficiency Diseases 0.000 description 1
- 208000024172 Cardiovascular disease Diseases 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
- 108090001030 Lipoproteins Proteins 0.000 description 1
- 235000016607 Rosa bella Nutrition 0.000 description 1
- 241000914162 Rosa bella Species 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000220222 Rosaceae Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 206010047623 Vitamin C deficiency Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005906 menstruation Effects 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 208000010233 scurvy Diseases 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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- Fats And Perfumes (AREA)
- Medicines Containing Plant Substances (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
The invention provides a method for extracting rose hip oil by supercritical carbon dioxide. The following percentages all refer to weight percentages. The method for extracting rose hip oil by supercritical carbon dioxide includes the drying step, the smashing step, the feeding step and the extracting step, and specifically, the method includes the following steps: drying rose hips by a vacuum drying oven and controlling moisture within a range from 4% to 10%, smashing the dried rose hips and controlling smashing degree within a range from 30 to 70 meshes, packing the smashed rose hips into an extraction kettle, wherein feeding coefficient ranges from 70% to 90%. Extraction conditions include the extraction temperature ranging from 40 DEG C to 55 DEG C, the pressure ranging from 25MPa to 35MPa, the first separation temperature ranging from 45 DEG C to 65 DEG C, the pressure ranging from 7MPa to 15MPa, the second separation temperature ranging from 30 DEG C to 45 DEG C, the pressure ranging from 4MPa to 6MPa, flow rate of carbon dioxide ranging from 180kg/h to 260kg/h and extraction time ranging from 2.5 hours to 4.5 hours, and rose hip oil is discharged from a first separation outlet. The rose hip oil extracted by the supercritical carbon dioxide is natural plant refined oil having curative effect, contains seventeen kinds of amino acid and a great quantity of advanced unsaturated fatty acid, has effects of strengthening original cells, accelerating the growth of new cells and preventing skin ageing and the like and can be used in food, medicine, healthcare products and cosmetics.
Description
Technical field
The invention belongs to Vegetable oil lipoprotein extractive technique field, be specifically related to a kind of method of supercritical carbon dioxide extraction Fructus Rosae Davuricae oil.
Background technology
Fructus Rosae Davuricae, the formal name used at school Flos rosae multiflorae has another name called rose hip, and Rosa bella fruit belongs to the Rosaceae, is distributed widely in Heilungkiang and ground such as on the south large and small Xing'an Mountains.This fruit is warm in nature, and flavor acid is nutritious, among the peoplely searches for food in a large number or is used to make tea, steeps in wine etc." Chinese medicine voluminous dictionary " called it has that invigorating the spleen is regulated the flow of vital energy, the effect of nourishing blood for regulating menstruation.The 8th, nine editions pharmacopeia of the FSU are also recorded, and are used to treat vitamin C deficiency.Domestic in recent years big quantity research shows that it is anti-ageing in addition, prevents and treats effects such as cardiovascular disorder.
At present Fructus Rosae Davuricae just as a kind of natural health medicine by pay attention to day by day and extensive exploitation.Having occurred on the market by this fruit juice is the protective foods and the nourishing drink of main development, and clinical having developed with the Fructus Rosae Davuricae is the injection liquid and the oral liquid of raw material.Fructus Rosae Davuricae oil is comparatively rare on the market at present, and common Fructus Rosae Davuricae oil utilizes squeezing or solvent extraction technology to make.
Summary of the invention
At present common Fructus Rosae Davuricae oil utilizes squeezing or solvent extraction technology to make; The objective of the invention is to utilize supercritical carbon dioxide extraction method; A kind of method of supercritical carbon dioxide extraction Fructus Rosae Davuricae oil is provided; It is many that the Fructus Rosae Davuricae oil of extraction has overcome pressed oil impurity, contains shortcomings such as dissolvent residual after the SX.The Fructus Rosae Davuricae oil yield that extracts is high, and impurity is low, does not have advantages such as dissolvent residual,
The technical scheme that the present invention adopts is summarized as follows:
Fructus Rosae Davuricae is adopted the vacuum drying oven oven dry, and moisture controlled is dried the back raw material pulverizing 4～10%; Degree of grinding installs to the raw material after pulverizing in the extraction kettle at 30～70 orders, and batch charging coefficient is 70～90%; Extraction conditions is: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, 2.5～4.5 hours extraction time, separates an outlet and is Fructus Rosae Davuricae oil.
The present invention provides the method for a kind of supercritical carbon dioxide extraction Fructus Rosae Davuricae oil, is characterised in that to comprise oven dry, pulverize, feed intake, extract four steps:
(1). oven dry: the wild rose fresh fruit is put into vacuum drying oven, 45～60 ℃ of bake out temperatures, open vacuum, moisture controlled is 4～10%.
(2). pulverize: the Fructus Rosae Davuricae after will drying is pulverized, and degree of grinding is at 30～70 orders.
(3). feed intake: the material after will pulverizing drops in the extraction kettle, and batch charging coefficient is 70～90%.
(4). extraction: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, 2.5～4.5 hours extraction time, separates an outlet and is Fructus Rosae Davuricae oil.
Embodiment
Below in conjunction with specific embodiment the present invention is further described.
Embodiment 1
The method of present embodiment supercritical carbon dioxide extraction Fructus Rosae Davuricae oil comprises the steps:
(1). oven dry: 10kg puts into vacuum drying oven with the wild rose fresh fruit, 60 ℃ of bake out temperatures, open vacuum, moisture controlled finishes oven dry in 6% o'clock.
(2). pulverize: the Fructus Rosae Davuricae after will drying is pulverized, and degree of grinding is at 40 orders.
(3). feed intake: the material after will pulverizing drops in the extraction kettle, and batch charging coefficient is 90%.
(4). extraction: 50 ℃ of extraction temperature, pressure 28MPa; Separate 55 ℃ of temperature, pressure 9MPa; Separate 35 ℃ of two temperature, pressure 5MPa; Carbon dioxide flow is 180kg/h, 3 hours extraction time, separates an outlet and is Fructus Rosae Davuricae oil.Extract Fructus Rosae Davuricae oil 300g.
Embodiment 2
The method of manufacture of present embodiment soybean phospholipid pressed candy comprises the steps:
(1). oven dry: 8.6kg puts into vacuum drying oven with the wild rose fresh fruit, 60 ℃ of bake out temperatures, open vacuum, moisture controlled is 8%.
(2). pulverize: the Fructus Rosae Davuricae after will drying is pulverized, and degree of grinding is at 50 orders.
(3). feed intake: the material after will pulverizing drops in the extraction kettle, and batch charging coefficient is 85%.
(4). extraction: 45 ℃ of extraction temperature, pressure 30MPa; Separate 60 ℃ of temperature, pressure 12MPa; Separate 45 ℃ of two temperature, pressure 6MPa; Carbon dioxide flow is 200kg/h, 3.5 hours extraction time, separates an outlet and is Fructus Rosae Davuricae oil.Extract Fructus Rosae Davuricae oil 280.5g.
Claims (2)
1. the method for supercritical carbon dioxide extraction Fructus Rosae Davuricae oil, following per-cent all is weight percentage, and it is characterized in that supercritical carbon dioxide extraction Fructus Rosae Davuricae oil step comprises oven dry, pulverizes, feeds intake, extracts four steps; Be specially: Fructus Rosae Davuricae is adopted the vacuum drying oven oven dry; Moisture controlled is dried the back raw material pulverizing 4～10%, and degree of grinding is at 30～70 orders; Raw material after pulverizing is installed in the extraction kettle; Batch charging coefficient is 70～90%, and extraction conditions is: 40～55 ℃ of extraction temperature, pressure 25～35MPa; Separate 45～65 ℃ of temperature, pressure 7～15MPa; Separate 30～45 ℃ of two temperature, pressure 4～6MPa; Carbon dioxide flow is 180～260kg/h, 2.5～4.5 hours extraction time, separates an outlet and is Fructus Rosae Davuricae oil.
2. according to the method for the described supercritical carbon dioxide extraction Fructus Rosae Davuricae oil of claim 1, it is characterized in that described batch charging coefficient is actual weight of loading of extraction kettle and the ratio of all filling weight of material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110414776 CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110414776 CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102492541A true CN102492541A (en) | 2012-06-13 |
| CN102492541B CN102492541B (en) | 2013-05-15 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110414776 Active CN102492541B (en) | 2011-12-13 | 2011-12-13 | Method for extracting rose hip oil by supercritical carbon dioxide |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888280A (en) * | 2012-10-16 | 2013-01-23 | 九三粮油工业集团有限公司 | Method for extracting lilac essential oil |
| CN104982933A (en) * | 2015-07-06 | 2015-10-21 | 中国农业大学 | Method for preparing rose hip seed oil microcapsules |
| CN105273842A (en) * | 2015-11-17 | 2016-01-27 | 鹰潭中投科技有限公司 | Preparation method of rose perfume |
| CN109010133A (en) * | 2018-09-10 | 2018-12-18 | 深圳市仙迪化妆品有限公司 | A kind of molten rose berry extract of oil and application |
| CN110042001A (en) * | 2019-05-05 | 2019-07-23 | 黑龙江省睿墨笛科技有限责任公司 | A kind of post-processing approach of wild rose fruit seed oil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353177A (en) * | 2001-11-16 | 2002-06-12 | 苏珣 | Application of CO2 supercritical extraction technique to extract rose oil |
| CN1557521A (en) * | 2004-01-19 | 2004-12-29 | 中 孟 | Extraction method of wild rose under supercritical CO2 condition |
| CN101343594A (en) * | 2007-07-14 | 2009-01-14 | 周志忠 | Preparation method for rose hip or seed oil |
| CN102234587A (en) * | 2010-04-21 | 2011-11-09 | 龚之森 | Rose essential oil and preparation process thereof |
-
2011
- 2011-12-13 CN CN 201110414776 patent/CN102492541B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1353177A (en) * | 2001-11-16 | 2002-06-12 | 苏珣 | Application of CO2 supercritical extraction technique to extract rose oil |
| CN1557521A (en) * | 2004-01-19 | 2004-12-29 | 中 孟 | Extraction method of wild rose under supercritical CO2 condition |
| CN101343594A (en) * | 2007-07-14 | 2009-01-14 | 周志忠 | Preparation method for rose hip or seed oil |
| CN102234587A (en) * | 2010-04-21 | 2011-11-09 | 龚之森 | Rose essential oil and preparation process thereof |
Non-Patent Citations (5)
| Title |
|---|
| E. REVERCHON ETAL.: "Supercritical CO2 extraction of hiprose seed oil：experiments and mathematical modelling", 《CHEMICAL ENGINEERING SCIENCE》 * |
| OSÉ M. DEL VALLE ETAL.: "Supercritical CO2 processing of pretreated rosehip seeds: effect of process scale on oil extraction kinetics", 《THE JOURNAL OF SUPERCRITICAL FLUIDS》 * |
| 方向 等: "玫瑰精油超临界二氧化碳萃取的试验研究", 《林产化学与工业》 * |
| 蔡宝昌 等: "《中药制剂新技术应用》", 31 December 2006, 人民卫生出版社 * |
| 薛晓丽 等: "超临界CO_2萃取玫瑰精油的优化工艺研究", 《江苏农业科学》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102888280A (en) * | 2012-10-16 | 2013-01-23 | 九三粮油工业集团有限公司 | Method for extracting lilac essential oil |
| CN104982933A (en) * | 2015-07-06 | 2015-10-21 | 中国农业大学 | Method for preparing rose hip seed oil microcapsules |
| CN105273842A (en) * | 2015-11-17 | 2016-01-27 | 鹰潭中投科技有限公司 | Preparation method of rose perfume |
| CN109010133A (en) * | 2018-09-10 | 2018-12-18 | 深圳市仙迪化妆品有限公司 | A kind of molten rose berry extract of oil and application |
| CN110042001A (en) * | 2019-05-05 | 2019-07-23 | 黑龙江省睿墨笛科技有限责任公司 | A kind of post-processing approach of wild rose fruit seed oil |
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| Publication number | Publication date |
|---|---|
| CN102492541B (en) | 2013-05-15 |
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