CN102490509A - Wallpaper and production process thereof - Google Patents

Wallpaper and production process thereof Download PDF

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Publication number
CN102490509A
CN102490509A CN2011104077916A CN201110407791A CN102490509A CN 102490509 A CN102490509 A CN 102490509A CN 2011104077916 A CN2011104077916 A CN 2011104077916A CN 201110407791 A CN201110407791 A CN 201110407791A CN 102490509 A CN102490509 A CN 102490509A
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China
Prior art keywords
wallpaper
production technology
foaming
environment
production
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CN2011104077916A
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Chinese (zh)
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CN102490509B (en
Inventor
康仲贤
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上海欣旺壁纸有限公司
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Priority to CN 201110407791 priority Critical patent/CN102490509B/en
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Publication of CN102490509B publication Critical patent/CN102490509B/en

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Abstract

The invention relates to wallpaper and production process thereof. The production process mainly comprises the steps of printing the surface of a base material (pure paper or non-woven fabrics) through water-based ink, drying semi-finished products in a drying oven, coating water-based media on printed and dried semi-finished products, conducting heating foaming to the water-based media to present patterns, then cooling the semi-finished products after foaming, inspecting and conducting edge cutting treatment on the wallpaper, rolling to obtain the wallpaper in various specifications and with fixed lengths and widths, packaging by using a shrink film, and boxing according to the same specification to obtain end product wallpaper. The wallpaper manufactured by using the production process is environmental friendly in using raw material and the production process, colorful, strong in foaming third dimension, simple in the production process, and easy to achieve industrialization scale production.

Description

A kind of wallpaper and production technology thereof
Technical field
The present invention relates to a kind of wallpaper and production technology thereof of environmental-protecting material, belong to the environment-friendly architecture ornament field of materials.
Background technology
Wallpaper is claimed wall paper, wallpaper again, and current conventional wallpaper is base material with the wood pulp paper, is coating with polyvinyl chloride (PVC) or other petrochemical material; The decorative material for internal wall of processing through printing, embossing or foaming has rich color, and pattern is various; Exquisite in texture; Well arranged, be prone to characteristics such as construction, be widely used in family and inner wall decoration public, commercial location.
Along with improving constantly of domestic resident living level, fitting-up has proposed the renewal requirements at the higher level to interior wall, and the consumer proposes requirements at the higher level to the environmental-protecting performance of house decorative material.Conventional wallpaper carries out high temperature foaming performance figure through PVC (being polyvinyl chloride); Although foaming effect is good; But PVC produces with foaming process and all belongs to the high pollution production technology, and harmful substance contents is high in the raw material, natural degradation process decades-long; The grievous injury health does not meet the environmental protection policy requirement that country is carrying out yet.
Environment-friendly water-based dielectric surface foaming wallhanging uses loopful to protect medium, and through high temperature foaming back performance foamed pattern, production process is harmless pollution-free, and finished product does not contain hazardous substance, and can in six months, accomplish natural degradation under field conditions (factors).But because the viscosity of environment-friendly water-based medium is lower than PVC, domestic present environment-friendly water-based dielectric surface foaming wallpaper ubiquity foaming layer is thin, and is prone to from phenomenons such as printed layers come off.
For overcoming the above problems, be necessary to capture the technical barrier of environment-friendly water-based dielectric surface foaming, produce both environmental protection, can show again that third dimension is strong, the wallpaper of rich color, clear patterns, improve Chinese wallpaper manufacturing technology level.
Summary of the invention
For addressing the above problem, the object of the present invention is to provide that a kind of third dimension is strong, rich color, the novel environment-friendly water-based dielectric surface foaming cylinder of clear patterns, the production technology of intaglio printing wallpaper.
Another object of the present invention is to provide the environment-friendly water-based dielectric surface foaming cylinder, the intaglio printing wallpaper that adopt above-mentioned explained hereafter.
For realizing above-mentioned first purpose, the technical scheme that the present invention takes is: a kind of production technology of wallpaper may further comprise the steps:
Step 1 is printed on substrate surface to the environmental protection ink through printing machine and forms pattern, gets into baking oven and dries;
Step 2 with the wallpaper that step 1 obtains, is coated wallpaper surface with environment-friendly water-based medium through print wheel through printing machine, gets into baking oven and dries foaming;
Step 3, the wallpaper that step 2 is obtained passes through chill roll, utilizes recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing;
Step 4 is with the wallpaper that step 3 the obtains processing of testing, cut edge;
Step 5, the wallpaper that step 4 is obtained is wound into regular length and width and multiple specification product;
Step 6, the wallpaper that step 5 is obtained are carried out the heat shrink films packing, according to the same size carton of packing into, obtain the finished product wallpaper again.
As a kind of preferred version of the present invention, said printing machine is cylinder printing machine or intaglio press.
As a kind of preferred version of the present invention, said base material is nonwoven or pure paper.
As a kind of preferred version of the present invention, the Unit Weight of said nonwoven or pure paper is 100-180g/m2.
As a kind of preferred version of the present invention, in the step 1, said print speed printing speed be 50-80 rice/minute.
As a kind of preferred version of the present invention, in the step 1, said bake out temperature is 110-160 ℃.
As a kind of preferred version of the present invention, in the step 1, said bake out temperature is 80-160 ℃.
As a kind of preferred version of the present invention, in the step 2, said environment-friendly water-based medium is coated the wallpaper surface with cylinder, intaglio process brush wheel, and coating weight is 10-25 g/m2, the printing coating speed be 50-80 rice/minute, the oven dry blowing temperature be 130-200 ℃.
As a kind of preferred version of the present invention; In environment-friendly water-based medium, add the tackifier of research and development voluntarily, the composition of said tackifier is: contain (methyl) alkyl acrylate 60 ~ 65% of epoxy radicals, alkyl acrylate 15 ~ 20%; Vinyl 3 ~ 5%, mylar 1 ~ 2%.Tackifier strengthen the environment-friendly water-based media attachment degree after the foaming, are difficult for coming off from printed layers.
As a kind of preferred version of the present invention, the temperature of said recirculated water be 3-30 ℃ as a kind of preferred version of the present invention, the rolling width of said step 5 is 530-1100mm, length is 10m.
As a kind of preferred version of the present invention, in the step 6, said wallpaper carries out heat shrink films with automatic packaging machine to be packed, and said heat shrink films is under 110-120 ℃ of temperature, and the speed of service is a packing under 5 meters/minute states.
Adopt above-mentioned explained hereafter wallpaper it comprise substrate layer, patterned layer, foaming layer; Said patterned layer is positioned at the upper epidermis of substrate layer, and said foaming layer is positioned on the patterned layer.
As a kind of preferred version of the present invention,, said substrate layer is nonwoven or pure paper.
Compared with prior art; The all raw material of wallpaper of the present invention comprises that base material, ink, aqueous medium all adopt environment-friendly materials; Advantages such as the green technology index of wallpaper is superior to like product, and simultaneously, wallpaper of the present invention has that third dimension is strong, rich color, clear patterns, viscosity by force, do not contain hazardous substance; Wallpaper production technology of the present invention is easy to industrial-scale production; Streamline speed is 2 times of common wallpaper streamline speed, reduces the energy consumption that manufacture order props up wallpaper, and production process is harmless pollution-free.
Description of drawings
Fig. 1 is the technological process of production figure of this a kind of wallpaper.
Fig. 2 is the structural representation of wallpaper of the present invention.
Reference numeral:
3 foaming layers of 1 substrate layer, 2 patterned layer.
The specific embodiment
Embodiment one:
As shown in Figure 2, described environment-friendly water-based dielectric surface foaming cylinder printing wallpaper comprises: substrate layer 1, patterned layer 2, foaming layer 3, and wherein, substrate layer 1 is a nonwoven, and patterned layer 2 is positioned at the upper epidermis of substrate layer 1, and foaming layer 3 is positioned on the patterned layer 2.
As shown in Figure 1, the step of wallpaper production technology of the present invention is following:
Step 1 through the cylinder printing machine on the cylinder streamline, is printed on non-woven paper surface to the environmental protection ink and forms pattern, print speed printing speed be 50-60 rice/minute, get in the baking oven of cylinder streamline and dry, oven temperature is 130-160 ℃.
Step 2; The wallpaper that will obtain through step 1 through the cylinder printing machine on the cylinder streamline, is coated the wallpaper surface to environment-friendly water-based medium acrylic acid resin through the cylinder print wheel; Spreading area>wall cloth area 60%; The coating weight of environment-friendly water-based medium acrylic acid resin is 20-25 g/m2, and adding Main Ingredients and Appearance in the acrylic acid resin is the tackifier of acrylic acid salt, the printing coating speed be 50-60 rice/minute; Dry foaming in the baking oven of entering cylinder streamline, blowing temperature is 160-200 ℃.
Step 3, the wallpaper that step 2 is obtained passes through the chill roll in the cylinder streamline, utilizes 3-15 ℃ recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing.
Step 4, with the wallpaper that step 3 the obtains processing of testing, cut edge, the defective products that will print and foam is rejected, and product is carried out quality-screening, reduces follow-up finished product fraction defective, and reduces the invalid quality restriction of follow-up generation.
Step 5, it is 530-1100mm that the wallpaper that step 4 is obtained is wound into width, length is the wallpaper of 10m;
Under 110-120 ℃ of temperature, the speed of service is to carry out the heat shrink films packing under 5 meters/minute states with automatic packaging machine for step 6, the wallpaper that step 5 is obtained, and according to the same size carton of packing into, obtains the finished product wallpaper again.
Embodiment two:
As shown in Figure 1, the step of environment-friendly water-based dielectric surface foaming intaglio plate nonwoven wallpaper production technology of the present invention is following:
Step 1 through the intaglio press on the intaglio plate streamline, is printed on non-woven paper surface to the environmental protection ink and forms pattern, print speed printing speed be 70-80 rice/minute, get in the baking oven of intaglio plate streamline and dry, oven temperature is 110-140 ℃.
Step 2, the wallpaper that will obtain through step 1 is through the intaglio press on the intaglio plate streamline; Coat the wallpaper surface to environment-friendly water-based medium PU resin through the intaglio process brush wheel, spreading area wall cloth area 30%, the coating weight of environment-friendly water-based medium PU resin is 10-15 g/m2; Adding Main Ingredients and Appearance in the PU resin is the tackifier of acrylic acid salt; The printing coating speed be 70-80 rice/minute, get in the baking oven of intaglio plate streamline and dry foaming, blowing temperature is 140-160 ℃.
Step 3, the wallpaper that step 2 is obtained passes through the chill roll in the intaglio plate streamline, utilizes 16-30 ℃ recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing.
Step 4, with the wallpaper that step 3 the obtains processing of testing, cut edge, the defective products that will print and foam is rejected, and product is carried out quality-screening, reduces follow-up finished product fraction defective, and reduces the invalid quality restriction of follow-up generation.
Step 5, it is 530-1100mm that the wallpaper that step 4 is obtained is wound into width, length is the wallpaper of 10m.
Under 110-120 ℃ of temperature, the speed of service is to carry out the heat shrink films packing under 5 meters/minute states with automatic packaging machine for step 6, the wallpaper that step 5 is obtained, and according to the same size carton of packing into, obtains the finished product wallpaper again.
Embodiment three:
As shown in Figure 2; Described environment-friendly water-based dielectric surface foaming cylinder printing wallpaper comprises-----substrate layer 1, patterned layer 2, foaming layer 3, and wherein, said substrate layer 1 is specially pure paper; Said patterned layer 2 is positioned at the upper epidermis of substrate layer 1, and said foaming layer 3 is positioned on the patterned layer 2.
As shown in Figure 1, the step of environment-friendly water-based dielectric surface foaming cylinder pure paper wallpaper production technology of the present invention is following:
Step 1 through the cylinder printing machine on the cylinder streamline, is printed on pure paper surface to the environmental protection ink and forms pattern, print speed printing speed be 50-60 rice/minute, get in the baking oven of cylinder streamline and dry, oven temperature is 130-160 ℃.
Step 2, the wallpaper that will obtain through step 1 is through the cylinder printing machine on the cylinder streamline; Coat wallpaper surface, spreading area to environment-friendly water-based medium PU resin through the cylinder print wheel>wall cloth area 60%, the coating weight of environment-friendly water-based medium acrylic acid resin is 20-25 g/m2; Adding Main Ingredients and Appearance in the PU resin is the tackifier of acrylic acid salt; The printing coating speed be 50-60 rice/minute, get in the baking oven of cylinder streamline and dry foaming, blowing temperature is 160-200 ℃.
Step 3, the wallpaper that step 2 is obtained passes through the chill roll in the cylinder streamline, utilizes 3-15 ℃ recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing.
Step 4, with the wallpaper that step 3 the obtains processing of testing, cut edge, the defective products that will print and foam is rejected, and product is carried out quality-screening, reduces follow-up finished product fraction defective, and reduces the invalid quality restriction of follow-up generation.
Step 5, it is 530-1100mm that the wallpaper that step 4 is obtained is wound into width, length is the wallpaper of 10m.
Under 110-120 ℃ of temperature, the speed of service is to carry out the heat shrink films packing under 5 meters/minute states with automatic packaging machine for step 6, the wallpaper that step 5 is obtained, and according to the same size carton of packing into, obtains the finished product wallpaper again.
Embodiment four:
As shown in Figure 2; Described environment-friendly water-based dielectric surface foaming intaglio printing wallpaper comprises-----substrate layer 1, patterned layer 2, foaming layer 3, and wherein, said substrate layer 1 is specially pure paper; Said patterned layer 2 is positioned at the upper epidermis of substrate layer 1, and said foaming layer 3 is positioned on the patterned layer 2.
As shown in Figure 1, the step of environment-friendly water-based dielectric surface foaming intaglio plate pure paper wallpaper production technology of the present invention is following:
Step 1 through the intaglio press on the intaglio plate streamline, is printed on pure paper surface to the environmental protection ink and forms pattern, print speed printing speed be 70-80 rice/minute, get in the baking oven of intaglio plate streamline and dry, oven temperature is 110-140 ℃.
Step 2; The wallpaper that will obtain through step 1 through the intaglio press on the intaglio plate streamline, is coated the wallpaper surface to environment-friendly water-based medium acrylic acid resin through the intaglio process brush wheel; Spreading area < wall cloth area 30%; The coating weight of environment-friendly water-based medium acrylic acid resin is 10-15 g/>m2, and adding Main Ingredients and Appearance in the acrylic acid resin is the tackifier of acrylic acid salt, the printing coating speed be 70-80 rice/minute; Dry foaming in the baking oven of entering intaglio plate streamline, blowing temperature is 140-160 ℃.
Step 3, the wallpaper that step 2 is obtained passes through the chill roll in the intaglio plate streamline, utilizes 16-30 ℃ recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing.
Step 4, with the wallpaper that step 3 the obtains processing of testing, cut edge, the defective products that will print and foam is rejected, and product is carried out quality-screening, reduces follow-up finished product fraction defective, and reduces the invalid quality restriction of follow-up generation.
Step 5, it is 530-1100mm that the wallpaper that step 4 is obtained is wound into width, length is the wallpaper of 10m.
Under 110-120 ℃ of temperature, the speed of service is to carry out the heat shrink films packing under 5 meters/minute states with automatic packaging machine for step 6, the wallpaper that step 5 is obtained, and according to the same size carton of packing into, obtains the finished product wallpaper again.
More than four kinds of specific embodiment be merely preferred embodiment of the present invention, or not all any modifications of within spirit of the present invention and principle, being made, be not equal to replacement, improvement etc. in order to restriction the present invention, all should be included within protection scope of the present invention.

Claims (15)

1. the production technology of a wallpaper comprises the steps:
Step 1 is printed on substrate surface to the environmental protection ink through printing machine and forms pattern, gets into baking oven and dries;
Step 2, the wallpaper that will obtain through step 1 is coated wallpaper surface with environment-friendly water-based medium through print wheel through printing machine, gets into baking oven and dries foaming;
Step 3, the wallpaper that step 2 is obtained passes through chill roll, utilizes recirculated water to cool off, and returns to the normal temperature state, makes foamed pattern obtain cooling curing;
Step 4 is with the wallpaper that step 3 the obtains processing of testing, cut edge;
Step 5, the wallpaper that step 4 is obtained is wound into the product of regular length and width;
Step 6, the wallpaper that step 5 is obtained are carried out the heat shrink films packing, according to the same size carton of packing into, obtain the finished product wallpaper again.
2. the production technology of wallpaper as claimed in claim 1, it is characterized in that: said printing machine is cylinder printing machine or intaglio press.
3. the production technology of wallpaper as claimed in claim 1, it is characterized in that: described base material is nonwoven or pure paper.
4. the production technology of wallpaper as claimed in claim 3, it is characterized in that: the Unit Weight of said nonwoven or pure paper is 100-180g/m2.
5. the production technology of wallpaper as claimed in claim 1 is characterized in that: in the step 1, said print speed printing speed be 50-80 rice/minute.
6. the production technology of wallpaper as claimed in claim 1, it is characterized in that: in the step 1, said bake out temperature is 110-160 ℃.
7. the production technology of wallpaper as claimed in claim 5, it is characterized in that: said bake out temperature is 80-160 ℃.
8. the production technology of wallpaper as claimed in claim 1; It is characterized in that: in the step 2, said environment-friendly water-based medium is coated the wallpaper surface with cylinder, intaglio process brush wheel, and coating weight is 10-25 g/m2; The printing coating speed be 50-80 rice/minute, the oven dry blowing temperature be 130-200 ℃.
9. the production technology of wallpaper as claimed in claim 7; It is characterized in that: in said environment-friendly water-based medium, add tackifier, the composition of said tackifier is: contain (methyl) alkyl acrylate 60 ~ 65% of epoxy radicals, alkyl acrylate 15 ~ 20%; Vinyl 3 ~ 5%, mylar 1 ~ 2%.
10. the production technology of wallpaper as claimed in claim 1; It is characterized in that: in said environment-friendly water-based medium, add tackifier, the composition of said tackifier is: contain (methyl) alkyl acrylate 60 ~ 65% of epoxy radicals, alkyl acrylate 15 ~ 20%; Vinyl 3 ~ 5%, mylar 1 ~ 2%.
11. the production technology of wallpaper as claimed in claim 1 is characterized in that: in the step 3, the temperature of said recirculated water is 3-30 ℃.
12. the production technology of wallpaper as claimed in claim 1 is characterized in that: the rolling width of said step 5 is 530-1100mm, and length is 10m.
13. the production technology of wallpaper as claimed in claim 1 is characterized in that: in the step 6, said wallpaper carries out heat shrink films with automatic packaging machine to be packed, and said heat shrink films is under 110-120 ℃ of temperature, and the speed of service is a packing under 5 meters/minute states.
14. adopt the wallpaper of arbitrary explained hereafter in the claim 1 to 12, it is characterized in that: comprise substrate layer, patterned layer, foaming layer; Said patterned layer is positioned at the upper epidermis of substrate layer, and said foaming layer is positioned on the patterned layer.
15. wallpaper as claimed in claim 13 is characterized in that: said substrate layer is nonwoven or pure paper.
CN 201110407791 2011-12-09 2011-12-09 Wallpaper and production process thereof CN102490509B (en)

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Cited By (18)

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CN102839574A (en) * 2012-08-30 2012-12-26 上海欣旺壁纸有限公司 Light-storing wallpaper and preparation method thereof
CN103174063A (en) * 2013-04-09 2013-06-26 上海欣旺壁纸有限公司 Environment-friendly pure paper wallpaper and preparation method thereof
CN103215859A (en) * 2013-05-06 2013-07-24 淮北诺菲雅新材壁纸有限公司 Non-woven embossed wallpaper
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103753989A (en) * 2013-12-20 2014-04-30 深圳市裕同包装科技股份有限公司 Silk screening printing method
CN103938498A (en) * 2014-04-22 2014-07-23 江苏德泰墙纸有限公司 Production process of wall paper
CN104404832A (en) * 2014-10-10 2015-03-11 桂林威迈壁纸有限公司 Producing method of wallpaper
CN104928990A (en) * 2015-07-07 2015-09-23 季丽霞 PVC printing foaming kraft paper and production method thereof
CN104929339A (en) * 2015-06-25 2015-09-23 佛山市南海区欧塑光电有限公司 Home decoration plastic film and manufacturing method thereof
CN105064125A (en) * 2015-08-31 2015-11-18 刘惠强 Plant wallpaper printing technology
CN105178113A (en) * 2015-08-14 2015-12-23 桂林威迈壁纸有限公司 Production technology for wallpaper
CN105563978A (en) * 2015-12-18 2016-05-11 昆山华富新材料股份有限公司 Waterborne polyurethane wall cloth with printable water-based ink and production method of waterborne polyurethane wall cloth
CN105966100A (en) * 2016-05-16 2016-09-28 浙江维涅斯装饰材料股份有限公司 Local embossing technique for non-woven fabric wallpaper
CN106111468A (en) * 2016-08-16 2016-11-16 广东玉兰集团股份有限公司 The wet device of a kind of painting and wallpaper typography
CN106544928A (en) * 2016-10-20 2017-03-29 徐州得铸生物科技有限公司 For the processing technology of the noctilucence silk ornament materials of business club building interior trim
CN106758548A (en) * 2017-01-05 2017-05-31 汪良 A kind of novel environment friendly facing paper and preparation method thereof
CN107190576A (en) * 2017-05-25 2017-09-22 江苏郁金香装饰材料有限公司 A kind of wallpaper production technology
CN107618281A (en) * 2017-10-14 2018-01-23 海宁市天祥包装机械厂 A kind of 3D plastic reliefs product packaging and its manufacture method

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CN102839574A (en) * 2012-08-30 2012-12-26 上海欣旺壁纸有限公司 Light-storing wallpaper and preparation method thereof
CN103174063A (en) * 2013-04-09 2013-06-26 上海欣旺壁纸有限公司 Environment-friendly pure paper wallpaper and preparation method thereof
CN103215859A (en) * 2013-05-06 2013-07-24 淮北诺菲雅新材壁纸有限公司 Non-woven embossed wallpaper
CN103215859B (en) * 2013-05-06 2014-03-12 淮北诺菲雅新材壁纸有限公司 Non-woven embossed wallpaper
CN103334563A (en) * 2013-07-10 2013-10-02 广东玉兰装饰材料有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103334563B (en) * 2013-07-10 2015-07-15 广东玉兰集团股份有限公司 Wallpaper with surface patterns having accumulation effect and manufacturing method thereof
CN103753989A (en) * 2013-12-20 2014-04-30 深圳市裕同包装科技股份有限公司 Silk screening printing method
CN103753989B (en) * 2013-12-20 2016-08-24 深圳市裕同包装科技股份有限公司 A kind of method for printing screen
CN103938498A (en) * 2014-04-22 2014-07-23 江苏德泰墙纸有限公司 Production process of wall paper
CN104404832A (en) * 2014-10-10 2015-03-11 桂林威迈壁纸有限公司 Producing method of wallpaper
CN104404832B (en) * 2014-10-10 2016-08-17 桂林威迈壁纸有限公司 A kind of production method of wallpaper
CN104929339A (en) * 2015-06-25 2015-09-23 佛山市南海区欧塑光电有限公司 Home decoration plastic film and manufacturing method thereof
CN104928990A (en) * 2015-07-07 2015-09-23 季丽霞 PVC printing foaming kraft paper and production method thereof
CN105178113A (en) * 2015-08-14 2015-12-23 桂林威迈壁纸有限公司 Production technology for wallpaper
CN105064125A (en) * 2015-08-31 2015-11-18 刘惠强 Plant wallpaper printing technology
CN105563978A (en) * 2015-12-18 2016-05-11 昆山华富新材料股份有限公司 Waterborne polyurethane wall cloth with printable water-based ink and production method of waterborne polyurethane wall cloth
CN105966100A (en) * 2016-05-16 2016-09-28 浙江维涅斯装饰材料股份有限公司 Local embossing technique for non-woven fabric wallpaper
CN106111468A (en) * 2016-08-16 2016-11-16 广东玉兰集团股份有限公司 The wet device of a kind of painting and wallpaper typography
CN106111468B (en) * 2016-08-16 2018-09-14 广东玉兰集团股份有限公司 It is a kind of to apply wet device and wallpaper printing technology
CN106544928A (en) * 2016-10-20 2017-03-29 徐州得铸生物科技有限公司 For the processing technology of the noctilucence silk ornament materials of business club building interior trim
CN106758548A (en) * 2017-01-05 2017-05-31 汪良 A kind of novel environment friendly facing paper and preparation method thereof
CN107190576A (en) * 2017-05-25 2017-09-22 江苏郁金香装饰材料有限公司 A kind of wallpaper production technology
CN107190576B (en) * 2017-05-25 2019-03-08 江苏郁金香装饰材料有限公司 A kind of wallpaper production technology
CN107618281A (en) * 2017-10-14 2018-01-23 海宁市天祥包装机械厂 A kind of 3D plastic reliefs product packaging and its manufacture method

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