CN102395668A - Surfactant compositions comprising lamellar elements as a visual cue - Google Patents

Surfactant compositions comprising lamellar elements as a visual cue Download PDF

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Publication number
CN102395668A
CN102395668A CN2010800169965A CN201080016996A CN102395668A CN 102395668 A CN102395668 A CN 102395668A CN 2010800169965 A CN2010800169965 A CN 2010800169965A CN 201080016996 A CN201080016996 A CN 201080016996A CN 102395668 A CN102395668 A CN 102395668A
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preferably
element
surfactant
formulation according
weight
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CN2010800169965A
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Chinese (zh)
Inventor
A·E·哈默
A·P·帕克
C·W·琼斯
G·J·P·弗德
S·A·巴内特
S·迪克松
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荷兰联合利华有限公司
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Priority to EP09158030 priority Critical
Priority to EP09158030.8 priority
Priority to PCT/EP2010/054799 priority patent/WO2010119022A1/en
Priority to EPPCT/EP2010/054799 priority
Application filed by 荷兰联合利华有限公司 filed Critical 荷兰联合利华有限公司
Priority to PCT/EP2010/054894 priority patent/WO2010119065A1/en
Publication of CN102395668A publication Critical patent/CN102395668A/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials characterised by their shape or physical properties
    • C11D17/0039Coated compositions or coated components in the compositions, (micro)capsules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials characterised by their shape or physical properties
    • C11D17/04Detergent materials characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/505Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay

Abstract

A packaged, liquid or gel, preferably surfactant-containing formulation, comprising a visual cue, wherein the visual cue comprises a plurality of water-soluble sheet-like elements of dispersed material, preferably formed from modified poly vinyl alcohol.

Description

包含层状元件作为视觉指示物的表面活性剂组合物 Element comprises a layered visual cues as surfactant composition

技术领域 FIELD

[0001] 本发明涉及包含层状元件(element)作为视觉指示物(cue)的液体或凝胶表面活性剂组合物(特别是液体洗衣洗涤剂组合物),制造包括该视觉指示物的元件的方法,元件本身,以及所述元件在洗涤过程中向织物和/或向洗涤或冲洗介质递送有益剂的用途。 [0001] The present invention relates to liquid or gel compositions the surfactant (particularly a liquid laundry detergent composition) comprising a laminar element (element) as a visual indicator (CUE), and producing the visual indicator member comprises a the method of the elements themselves, and the use of the element to the fabric and / or delivery of the washing or rinsing medium, the benefit agent during the washing process.

[0002] 发明背景 [0002] Background of the Invention

[0003] 洗衣处理组合物除了含有表面活性剂和任选的增效剂(builder)外,一般还含有向洗涤的衣物提供益处的成分。 [0003] In addition to laundry treatment composition comprising a surfactant and optionally builders (Builder), in general also contain provide a benefit to the laundry composition. 这些成分的例子包括但不限于香料、酶、漂白剂、调色颜料(shading pigment)和染料及织物调理剂。 Examples of such ingredients include, but are not limited to perfumes, enzymes, bleaching agents, toning pigments (shading pigment) and dyes and fabric conditioner. 这些物质经常也是洗衣组合物中最昂贵的组分, 且被称为“有益剂”。 These substances are laundry compositions are often the most expensive component, and is referred to "a beneficial agent." 由于有益剂与制剂中的其他成分的潜在不相容性,当这些物质被包括在制剂中时,可能有利的是保护(例如,通过包封)这些有益剂。 Due to the potential incompatibility with other components of the formulation of the beneficial agent, when these substances are included in the formulation, it may be advantageous to protect (e.g., by encapsulation) such benefit agents. 这种不相容性可以导致制剂不稳定,或引起有益剂与其他制剂组分的不必要的反应,从而导致有益剂的功效或其他产品性能受到不利影响。 This incompatibility can result in unstable formulations, or cause unwanted reactions with other beneficial agent formulation components, resulting in efficacy or other beneficial agent performance is adversely affected.

[0004] 已经提出:对于粉末,在所谓的“视觉指示物”中引入这些有益剂和/或在有益剂在组合物中稳定的情况下,在制剂中包括视觉指示物以表明有益剂的存在。 [0004] have been proposed: For powder, the introduction of these beneficial agents and / or where the beneficial agent is stable in the composition, in the formulation includes a visual indicator to indicate the presence of beneficial agent in a so-called "visual indicator" in . 包含指示物的元件作为产品剂量的一部分递送,并在洗涤的某些阶段可溶。 An indicator element comprising a product as part of delivery of the dose, and soluble in some stage of washing. 一种这样的视觉指示物是彩色“斑点”,其经常被引入含酶洗衣粉中。 One such indicator is a visual color "spot", which is often incorporated in the enzyme-containing detergent. 这通常是用合适的染料着色的碳酸钠颗粒,且其本身并不含有酶。 This is usually sodium percarbonate particles with a suitable colored dye, and is not itself contain enzyme.

[0005] US 2003/144161 A公开了颗粒洗衣洗涤剂组合物,尤其是高体积密度粉末和片剂,其含有低水平的对皮肤有益的芦荟或另一种草药提取物。 [0005] US 2003/144161 A discloses a granular laundry detergent compositions, in particular high bulk density powders and tablets which contain low levels of skin benefit aloe or other herbal extracts. 草药提取物优选以彩色(优选绿色)斑点的形式存在。 Herbal extract is preferably present in the colored (preferably green) in the form of spots.

[0006] 已经提出或使用的其他视觉指示物包括珠、层状形状(如平面环)和各种“花”形状。 [0006] have been proposed or used for other visual indicator comprises a bead, a layered shape (such as flat rings), and various "flower" shape.

[0007] GB 2358403 A公开了颗粒洗衣洗涤剂组合物,其包含大部分的白色或浅色的颗粒和小部分的在至少一个尺寸上具有比白色或浅色颗粒的平均粒径显著较大的平均粒径的视觉反差体(visually contrasting bodies)。 [0007] GB 2358403 A discloses a granular laundry detergent composition comprising a major proportion of white or light-colored particles and a minor portion having at least one dimension than the average particle diameter of the white or light-colored particles significantly larger the average particle size of visual contrast body (visually contrasting bodies). 优选地,所述反差体具有规则的形状和均勻的大小,且由优选为高度反射的和/或发荧光的亮色材料形成。 Preferably, the contrast has a uniform shape and size rules, and is preferably formed from and / or fluoresced bright highly reflective material. 视觉反差体向例如消费者提供强烈的指示物以表明有益成分的存在(即使存在量非常小)。 Provide a strong visual contrast member indicator to the consumer, for example, to indicate the presence of the beneficial ingredients (even if there is very small).

[0008] GB 2358404 A公开了颗粒洗衣洗涤剂组合物,其包含大部分的白色或浅色颗粒和小部分的由能够在组合物溶于水中时赋予产生的溶液颜色的物质形成的视觉反差颗粒。 [0008] GB 2358404 A discloses a granular laundry detergent composition comprising a major proportion of white or light-colored particles and a small portion of the visual contrast can be imparted to the particulate matter formed color of the solution produced when the composition is dissolved in water . 该视觉反差颗粒可以含有产生荧光洗涤液的荧光物质或可以含有在高PH值时产生彩色溶液但在较低PH值时产生无色或不同颜色的溶液的pH指示剂。 The visual contrast particles may contain a fluorescent substance generates fluorescence washing liquid or solution may contain a color produced at high pH indicator PH value but produces a colorless or a different color of solution at low PH values. 视觉反差颗粒和洗涤液的视觉效果为例如消费者提供提示以表明有益成分的存在或表明应加入更多产品。 Visual contrast particles and washing liquid to provide visual effects such as prompting the consumer to indicate the presence or beneficial ingredients should be added to indicate that more products.

[0009] WO 09/047125 A公开了一种颗粒状洗衣洗涤剂组合物,其包含至少5重量%的表面活性剂、任选的增效剂和任选的另外的清洁成分、香料和0. 01至10重量%的视觉指示物,其中视觉指示物形似具有花瓣的花,经着色以具有自然存在的花瓣颜色,且其中香料本质上是花香。 [0009] WO 09/047125 A discloses a granular laundry detergent composition, which comprises at least 5 wt% of a surfactant, optionally a builder and optionally a further cleaning ingredients, spices and 0. 01 to 10 wt% of visual cues wherein the visual indicator has the shape of flower petals colored to have a naturally occurring petal color and wherein the perfume is floral essence. [0010] WO 09/047126 A公开了一种颗粒状洗涤剂组合物,其包含0. 1至10重量%由可溶性薄膜制成的可溶性彩色层状视觉指示物,各可溶性彩色层状视觉指示物具有为5平方毫米至100平方毫米的平面截面积,薄膜的相对密度为0. 2至0. mcg/l,和薄膜包含10至90 重量%的表面活性剂。 [0010] WO 09/047126 A discloses a granular detergent composition comprising from 0.1 to 10 wt% soluble colored lamellar visual cues made from a soluble film, each soluble colored lamellar visual cues as having a 5 to 100 mm2 cross-sectional area of ​​a plane, the relative density of the film is 0.2 to 0. mcg / l, and the film comprising 10 to 90% by weight of a surfactant.

[0011] 用作指示物的已知层状元件通常是通过将合适材料的平面片切割成一定形状来制造。 [0011] was used as an indicator of the layered element is generally known to be manufactured by a planar sheet material cut to the appropriate shape.

[0012] WO 09/047124 A公开了一种洗衣处理组合物,其包含洗衣处理基质和0. 01至10 重量%的反差彩色凹面层状薄膜颗粒,其具有平面表面和平面边缘,且其中:a)外缘成形以使得至少一条通过平面绘制的直线在超过两个位置与边缘相交;b)凹面层状薄膜颗粒可以平铺;c)凹面层状薄膜颗粒颜色与洗衣处理基质形成反差,由此该凹面层状薄膜颗粒作为视觉指示物发挥功能。 [0012] WO 09/047124 A discloses a laundry treatment composition comprising a laundry treatment substrate and 0.01 to 10 wt% of the colored concave lamellar film particles contrast, having a planar surface and a plane edge, and wherein: a) an outer edge shaped such that a straight line drawn through the plane of the at least one more than two positions at the intersection of the edge; b) the concave lamellar film particles can be tiled; c) the concave lamellar film particle matrix color contrast with the laundry treatment, of this concave lamellar film particles as the visual indicator function. 在此,引用语“凹面”指所述指示物的边缘。 Here, reference term "concave" means that the indicator edge thereof.

[0013] 对于洗衣液,及对于用于个人和家庭护理的其他液体或凝胶产品,引入“敏感,,的有益剂的问题比粉末和颗粒状产品更严重。例如,漂白剂和酶可能相互作用,酶和一些增稠剂或结构化剂也可能相互作用。挥发性的香料可能会损失,并且在其中有益剂(如香料) 被包封并具有聚合物沉积助剂的情况下,沉积助剂可以被其他存在的组分降解。 [0013] For laundry detergent, and used for personal and home care products of other liquid or gel, the introduction of "sensitive ,, the beneficial agent problem is more serious than powders and granular products. For example, bleach and enzymes may be mutually action of some enzymes and thickening or structuring agents may interact. volatile perfume may be lost, and in the case where the beneficial agent (e.g., perfume) is encapsulated and deposition aid having a polymeric deposition aid agents may be degraded by the presence of other components.

发明内容 SUMMARY

[0014] 我们已经确认,水溶性的层状元件可以在液体和凝胶产品中形成有用的视觉指示物,并可以任选地用于保护和/或递送有益剂。 [0014] We have confirmed that the water-soluble elements may be formed in a layered visual indicators useful in liquid and gel products, and may optionally be used to protect and / or delivery of the beneficial agent.

[0015] 因此,本发明提供了包括水溶性视觉指示物的包装的液体或凝胶制剂,其中所述视觉指示物包括多个分散物质的片状元件,且其中所述指示物包含任选的有益剂。 [0015] Accordingly, the present invention provides a liquid or gel formulation comprises a water soluble packaging of a visual indicator, wherein the visual indicator comprises a plurality of sheet-like elements dispersible material, and wherein said indication comprises optionally benefit agent.

[0016] 本发明中的“水溶性”指形成指示物的元件在25摄氏度下溶于软化水中。 [0016] In the present invention, "water-soluble" refers to the formation of the indicator element is dissolved in demineralised water at 25 degrees Celsius.

[0017] 本发明中的“包装的”指液体或凝胶制剂被稳定地封闭在容器内用于销售和/或运输。 The [0017] present invention is "packaged" refers to a liquid or gel formulation is stably enclosed within a container for sale and / or shipping. “包装的”不包括当包含视觉指示物的已知粉状产品被放置在洗涤器中时所形成的临时洗涤液。 "Packaging" does not include the temporary washing solution comprising a visual indicator when the known powdered product is placed in a scrubber formed.

[0018] 优选地,制剂包括可倾倒的液体或凝胶。 [0018] Preferably, the formulation comprises a pourable liquid or a gel.

[0019] 本文定义的“可倾倒的液体”指在25°C和20秒―1的剪切速率下粘度小于大约2000mPa. s的液体。 [0019] "pourable liquid" as defined herein refers to at 25 ° C for a shear rate of 20 sec -1 and a viscosity of less than about 2000 mPa. S in the liquid. 在一些实施方式中,在25°C和20秒―1的剪切速率下,可倾倒的液体的粘度可以为大约200至大约IOOOmPa. S。 In some embodiments, at 25 ° C under a shear rate of 20 sec -1 and the viscosity of the liquid may be poured from about 200 to about IOOOmPa. S. 在一些实施方式中,在25°C和20秒―1的剪切速率下,可倾倒液体的粘度可以为大约200至大约500mPa. s。 In some embodiments, and at 25 ° C under a shear rate of 20 sec -1, pourable viscosity of the liquid may be from about 200 to about 500mPa. S.

[0020] 本文定义的“凝胶”指在25°C和20秒―1的剪切速率下粘度大于大约2000mPa. s的透明或半透明的液体。 [0020] as defined herein, "gel" refers to 25 ° C under a shear rate of 20 sec -1 and a viscosity of greater than about 2000 mPa. S transparent or translucent liquid of. 在一些实施方式中,在25°C和20秒-1的剪切速率下,凝胶的粘度可以为大约3000至大约IOOOOmPa. s,和在25°C和0. 1秒―1的剪切速率下,粘度大于大约5000mPa. s。 In some embodiments, and at 25 ° C under a shear rate of 20 sec -1, the viscosity of the gel may be from about 3000 to about IOOOOmPa. S, and a shear at 25 ° C and 0.1 seconds -1 at a rate, a viscosity of greater than about 5000mPa. s.

[0021] 通常,低粘度液体包含结构化剂以帮助保持指示物处于悬浮中。 [0021] Generally, low-viscosity liquid comprising a structuring agent to assist in maintaining in suspension in the indicator. 尤其可用于本发明的组合物中的一种结构化剂类型包括非聚合的(除了常规烷氧基化外)、结晶的羟基官能化材料,当它们在基质中原位结晶时,其可以在整个液体基质中形成线状结构化系统。 In particular, it is used in one type of structuring agent compositions of the present invention comprises non-polymeric (except for conventional completely apart alkoxy), crystalline hydroxy-functional materials, when they are crystallized within the matrix in situ, which may be whole liquid matrix form thread-like structuring system. 这种材料一般可以表征为结晶的、含羟基的脂肪酸、脂肪酯或脂肪蜡。 Such materials can be generally characterized as crystalline, hydroxyl-containing fatty acids, fatty esters or fatty waxes. 优选的结晶的、含羟基的结构剂(structurant)的具体例子包括蓖麻油及其衍生物。 Preferred crystalline, specific examples of the hydroxyl-containing structurants (structurant) include castor oil and its derivatives. 其实例包括氢化蓖麻油及其水解产物(例如羟基硬脂酸)的混合物。 Examples thereof include hydrogenated castor oil and a mixture of hydrolysis products (e.g. hydroxy acid). 尤其优选的是氢化蓖麻油衍生物,例如氢化蓖麻油和氢化蓖麻蜡。 Especially preferred are hydrogenated castor oil derivatives such as hydrogenated castor oil and hydrogenated castor wax. 市售的基于蓖麻油的结晶含羟基结构剂包括来自Mieox,Inc.(现为Elementis)的THMCIN⑧。 Commercially available crystalline castor oil based hydroxyl-containing structurants include from Mieox, Inc. (Now Elementis) of THMCIN⑧. 可选地,可以使用纤维素材料。 Alternatively, the cellulosic material may be used.

[0022] 优选地,包装为至少部分透明的。 [0022] Preferably, the package is at least partially transparent. 本文使用的“透明”指本发明的制剂或包装在光谱的可见光部分(大约410-800nm)优选具有大于25%、更优选大于30%、最优选大于40%、最佳大于50%的透光率。 As used herein, "transparent" refers to a preparation or package of the present invention in the visible part of the spectrum (approximately 410-800nm) preferably greater than 25%, more preferably greater than 30%, most preferably greater than 40%, optimally more than 50% light transmission rate. 本发明可以使用的包装材料包括但不仅限于:聚丙烯(PP)、 聚乙烯(PE)、聚碳酸酯(PC)、聚酰胺类(PA)和/或聚对苯二甲酸乙二醇酯(PETE)、聚氯乙烯(PVC)和聚苯乙烯(PS)或多层组合。 The present invention may be used in packaging materials include, but are not limited to: polypropylene (PP), polyethylene (PE), polycarbonate (PC), polyamides (PA) and / or polyethylene glycol terephthalate ( PETE), polyvinylchloride (PVC) and polystyrene (PS) or multilayer combinations.

[0023] 包装初始可以包含几个剂量的制剂。 [0023] The package may comprise several initial dose of the formulation. 本发明也适用于所谓的“单位剂量”制剂,其优选包括含单剂量的制剂的水溶性袋,但制剂的优选形式是在可重新盖紧的瓶子、多剂量袋或其他类似容器中以多个液体剂量递送的制剂。 The present invention is also applicable to so-called "unit dose" formulation, which preferably comprises a water-soluble bags containing a single dose of the formulation, but preferably the formulation is in the form of reclosable bottles, bags or other similar multi-dose container to multiple a liquid formulation dose delivery.

[0024] 优选地,制剂是透明的。 [0024] Preferably, the formulation is transparent. “透明的”是指该制剂使得能够可以通过1厘米厚度的制剂(在没有指示物的情况下)读出“Arial 12 point”印刷的样本。 "Transparent" means that the preparation (in the absence of the indicator) of the sample read "Arial 12 point" cm Thickness printing formulation can pass. 在透明制剂和至少部分透明的容器中的层状指示物与包括由相同体积的材料构成的球体或其他三维固体的指示物相比具有更高的视觉效应(visual impact)。 Transparent formulations and at least partially transparent container comprises a layered sphere with an indicator or other three-dimensional volume of a solid made of the same material as the indicator has a higher visual effect (visual impact) compared.

[0025] 本发明特别优选的实施方式提供了刚性、至少部分透明的容器,其包含透明的液体洗衣洗涤剂组合物,所述组合物具有分散于其中的多个可溶于水但不溶于该组合物中的元件。 [0025] A particularly preferred embodiment of the present invention provides a rigid, at least partially transparent container, which includes a transparent liquid laundry detergent composition, said composition having dispersed therein a plurality of water-soluble but insoluble in the composition element.

[0026] 该指示物提供的进一步的优势是,这些元件可以被用来携带有用的有益剂(例如,染料),所述有益剂如果没有进行保护以避免组合物的影响,所述有益剂会显著改变其视觉外观。 [0026] A further advantage of this indicator are provided, these elements can be used to carry a useful benefit agent (e.g., dyes), the benefit agent if not protected from the influence of the composition, said benefit agent will significantly altering its visual appearance.

[0027] 优选地,元件的平均直径(平面测量的)与元件的厚度的比率大于5 : 1,优选大于8 : 1。 [0027] The average diameter thickness ratio preferably, the element element (measured in the plane) greater than 5: 1, preferably greater than 8: 1.

[0028] 通常情况下,元件的平均直径为1-lOmm,优选是3_6mm。 The [0028] Typically, the average diameter of the element is 1-lOmm, preferably 3_6mm. 小于Imm的元件具有低的视觉效应,而那些大于IOmm的元件可以导致不规则的计量。 Less than Imm element having a low visual effect, and those elements may be greater than the lead metered IOmm irregular. 通常情况下,元件的平均厚度为100-2000微米,优选200-500微米。 Typically, the average thickness of the element is 100 to 2000 microns, preferably 200-500 microns. 随着元件变得更厚,它们在制剂方面变得更加昂贵且更不容易悬浮。 As the element becomes thicker, they become more expensive and less readily suspended in terms of the formulation. 随着元件变得更薄,它们具有较小的有益剂承载能力且需要更多的量来递送适当水平的有益剂。 As the element becomes thinner, they have a small beneficial agent bearing capacity and requires a larger amount to deliver an appropriate level of benefit agent.

[0029] 优选的表面活性剂组合物是包含阴离子表面活性剂、非离子表面活性剂或其混合物的液体或凝胶洗衣洗涤剂组合物。 [0029] Preferred surfactant compositions comprising an anionic surfactant, a liquid or gel nonionic surfactants, or mixtures thereof laundry detergent compositions. 这些制剂意图用于包括主要清洗步骤和冲洗步骤的多阶段洗衣过程中。 These formulations are intended for the rinsing step includes a primary rinsing step and multi-stage washing process. 根据所提供的有益剂,指示物可以被设计为在洗涤的早期阶段溶解,或可以被携带进入冲洗步骤并随后在冲洗中溶解。 The beneficial agent provided by the indicator may be designed to be dissolved in the early stage of washing, or may be carried into the washing step and then dissolved in flushing. 因此,指示物的进一步优势是它们可以递送否则与制剂的其他组分不相容的有益剂。 Thus, the indicator further advantage is that they can be delivered or incompatible with the other components of the formulation of the beneficial agent. 例如,指示物可以用来递送香料进入冲洗并降低由主要清洗中存在的表面活性剂除去的香料的程度。 For example, the indicator can be used to deliver perfume into the flushing and reduce the degree of perfume surfactant present in the main washing removed.

[0030] 特别优选的是,对于如液体洗衣洗涤剂组合物的实施方式,组合物应用的剂量为使得产生的洗涤液具有小于lg/L、更优选小于0. 5g/L的表面活性剂(皂除外)浓度。 [0030] Particularly preferred are, as for the embodiment of the liquid laundry detergent compositions, dosage of the composition applied is such that the washing liquid is produced having less than lg / L, and more preferably less than 0. 5g / L of a surfactant ( except soap) concentration. 与常规的洗涤液相比,这是低水平的表面活性剂。 Compared with the conventional washing liquid, which is a low level of a surfactant. 还优选的是:含有指示物的液体洗涤剂产品的剂量小于30毫升,优选小于25毫升。 Also preferred are: dose liquid detergent product containing an indication of less than 30 ml, preferably less than 25 milliliters. 与洗衣组合物的常规剂量相比,这是较低的剂量。 Compared with the conventional dose laundry compositions, which is a low dose. 这种低剂量和/或低表面活性剂产品具有环境优势,因为该产品需要运输较少量的材料,并减少了表面活性剂的使用量。 This low dose and / or surfactant products having a low environmental advantages, since the product needs lesser amount of material transport, and reduces the amount of the surface active agent. 但是为了使用户信服该低剂量的产品是有效的,包括含有层状元件的视觉指示物是非常有利的,因为即使在低剂量的产品下,这也具有显著的视觉效应。 But in order to convince the user that a low dose of product to be effective, include a visual indicator comprising laminar element is highly advantageous, because even at a low dose product, which also has a significant visual effect.

[0031] 发明详述 [0031] DETAILED DESCRIPTION

[0032] 除非另外说明,提及的所有量为总组合物的重量%。 [0032] Unless otherwise indicated, all amounts referred to the total composition weight%.

[0033] 除了在工作和比较实施例中,或以其他方式明确表明的情况下,本说明书中表示物质的量或比率或者反应条件、物质的物理性质和/或应用的所有数值可以理解为由词语“大约”修饰。 [0033] In addition to the working and comparative examples, or in the case of the otherwise clear that, in this description indicating amounts or ratios of material or conditions of reaction, physical properties of materials and / or values ​​of all applications will be appreciated by The word "about".

[0034] 形成指示物的元件: [0034] The indicator element is formed of:

[0035] 优选的元件由具有聚合物骨架的材料制成,所述聚合物骨架在疏水改性之前为水溶性的。 [0035] Preferably the element is made of a material having a polymer backbone, said polymer backbone before the hydrophobically modified water-soluble. 或者,指示物的元件可以由不溶于整体制剂(bulk formulation)的表面活性剂材料制成。 Alternatively, the indicator element may be made of the overall formulation is insoluble (bulk formulation) surfactant material.

[0036] 优选地,聚合物应溶于水中,以使得当0. 1克、优选0. 3克、更优选0. 5克的聚合物在室温下被置于IL的软化水中并在旋转振动器上在20摄氏度下以100RPM振摇2小时,然后通过适当大小的筛或滤纸过滤而从溶液中除去并干燥时,此时除去的聚合物的重量小于所添加聚合物的95重量%。 [0036] Preferably, the polymer should be dissolved in water, such as 0.1 g, preferably 0.3 g, more preferably 0.5 g of polymer is placed IL demineralized water at room temperature and rotational vibration on 100RPM is shaken for 2 hours at 20 ° C, and then removed when dried, then remove the weight of the polymer is less than 95% by weight of the added polymer from the solution by an appropriately sized screen or filter paper. 涉及指示物的“水溶性”意思是指示物在洗涤或其他应用的过程中溶解。 Indicator relates to "water-soluble" means that the indicator is dissolved during the washing or other applications.

[0037] 本文所用的涉及改性聚合物的“不溶性”指聚合物(和因此由其形成的指示物的元件)应不溶解于制剂中。 [0037] As used herein, relates to a modified polymer "insoluble" refers to a polymer (and thus the indicator element is formed therefrom) should not be dissolved in the formulation. 适当的聚合物为满足以下条件的聚合物:当lg/L的改性聚合物在室温下被放置于水性表面活性剂混合物(直链烷基苯磺酸盐(LAQ与非离子型表面活性剂(其是脂族C12至C15直链伯醇与环氧乙烷(7E0)的反应产物)的混合物)(其中表面活性剂浓度大于5g/l),并在旋转振动器上在下以100RPM振摇2小时,然后通过适当大小的筛或滤纸过滤从溶液除去并干燥时,此时除去的改性聚合物的重量在所添加改性聚合物的95重量%之内。 Suitable polymer is a polymer satisfying the following conditions: when lg / L of modified polymer mixture is placed in an aqueous surfactant (linear alkylbenzene sulphonate (LAQ and nonionic surfactant at room temperature (which is a C12 to C15 linear primary alcohol with ethylene oxide (7E0) reaction products of aliphatic) mixture) (wherein the surfactant concentration is greater than 5g / l), and next to 100RPM shaken on a rotary shaker for 2 hours and then filtered through a sieve or filter paper of appropriate size is removed from the solution, and when dried, the weight of the modified polymer is removed in the case of the modified polymer is 95% by weight of added.

[0038] 优选地,指示物不溶于水性表面活性剂混合物(直链烷基苯磺酸盐(LAQ与非离子型表面活性剂(其是脂族C12至C15直链伯醇与环氧乙烷(7E0)的反应产物)的混合物) 中,其中表面活性剂浓度为5至800g/l,更优选5至500g/l,例如50至500g/l。 [0038] Preferably, the indicator is insoluble in aqueous surfactant mixture (linear alkylbenzene sulphonate (LAQ with a nonionic surfactant (which is an aliphatic C12 to C15 linear primary alcohol with ethylene oxide the mixture (7E0) reaction product)), wherein the surfactant concentration is 5 to 800g / l, more preferably 5 to 500g / l, for example 50 to 500g / l.

[0039] 下临界溶液温度(LCST)是在低温下水性溶液中表现出良好溶解性,但是当温度升高至高于LCST时从溶液中析出的材料的特性(参见!^eil等人,Macromolecules 1993, 26,2496-2500)。 [0039] The critical solution temperature (LCST) is the performance under the low-temperature water solution in a good solubility, but when the temperature is raised to above the LCST material precipitated from solution properties (see! ^ Eil et al., Macromolecules 1993 , 26,2496-2500). 对于本发明的聚合物显示出所指的LCST效应的“水性溶液”包括水和水性表面活性剂溶液(包括水性表面活性剂混合物)。 For the polymers of the present invention exhibit an LCST effect within the meaning of "aqueous solution" includes water and an aqueous surfactant solution (an aqueous mixture comprising a surfactant).

[0040] 改性聚合物的优选LCST范围是5至55°C,更优选5至50°C。 LCST range is preferably [0040] of the modified polymer 5 to 55 ° C, more preferably 5 to 50 ° C. 在本发明的优选实施方式中,改性聚合物在水中的LCST大于20°C,更优选大于30°C。 In a preferred embodiment of the present invention, the modified polymer LCST in water of greater than 20 ° C, more preferably greater than 30 ° C.

[0041] 通常情况下,元件包括例如具有多个嵌入基质中的离散有益剂实体的聚合物的基质。 [0041] Typically, for example, a matrix having a plurality of elements comprising a polymer benefit agent embedded discrete entities in a matrix. 嵌入基质中的离散有益剂实体可以为相同或不同的有益剂。 Benefit agent embedded discrete entities in the matrix may be the same or different beneficial agents. 离散有益实体指,例如,包含包封香料的颗粒或软化油(softening oil)的液滴。 Advantageous refers discrete entities, e.g., comprising encapsulated perfume particles or softening oil (softening oil) droplets.

[0042] 元件优选包含基质材料(优选疏水改性聚合物(i))和织物有益剂(ii),其比率为1 : 50至99 : 1重量份,更优选为1 : 40至95 : 1重量份。 [0042] The element preferably comprises a matrix material (preferably hydrophobically modified polymer (i)) and a fabric benefit agent (II), a ratio of 1: 50 to 99: 1 parts by weight, more preferably from 1: 40 to 95: 1 parts by weight.

[0043] 适合用作疏水改性聚合物的全部或部分骨架的聚合物优选选自聚乙烯醇、聚乙酸乙烯酯、纤维素醚类、聚环氧乙烷、淀粉、聚乙烯吡咯烷酮、聚丙烯酰胺、聚乙烯甲基醚-马来酸酐、聚马来酸酐、苯乙烯马来酸酐、羟乙基纤维素、甲基纤维素、聚乙二醇类、羧甲基纤维素、聚丙烯酸盐类、藻酸盐类、丙烯酰胺共聚物类、瓜尔胶、酪蛋白、乙烯-马来酸酐树脂系列、聚乙烯亚胺、乙基羟乙基纤维素、乙基甲基纤维素和羟乙基甲基纤维素。 [0043] Suitable polymers are preferably selected from hydrophobically modified polyvinyl alcohols used as all or part of the polymer backbone, polyvinyl acetate, cellulose ethers, polyethylene oxide, starch, polyvinyl pyrrolidone, polyacrylic amides, polyvinyl methyl ether - maleic anhydride, polymaleic anhydride, styrene maleic anhydride, hydroxyethylcellulose, methylcellulose, polyethylene glycols, carboxymethylcellulose, polyacrylic acid salts , alginates, acrylamide copolymers, guar gum, casein, ethylene - maleic anhydride resin series, polyethyleneimine, ethyl hydroxyethylcellulose, ethyl cellulose and hydroxyethyl Methylcellulose. 源自上述骨架的聚合物的共聚混合物也是合适的。 The skeleton is a polymer derived from the copolymerization mixture are also suitable. 优选地,聚合物具有骨架和包含羟基的侧链。 Preferably, the polymer having a backbone and a side chain containing a hydroxyl group.

[0044] 对于聚合物最优选的骨架包括聚乙烯醇,且优选聚合物的平均分子量为1000至300,000道尔顿,优选2,000至100,000道尔顿。 [0044] The most preferred backbone of the polymer include polyvinyl alcohol, and an average molecular weight of the polymer is preferably 1000 to 300,000 Daltons, preferably from 2,000 to 100,000 Daltons.

[0045] 聚乙烯醇(PVOH)可以以包含一定量的聚乙酸乙烯酯(PVAc)的形式提供,其中PVOH材料的一定水平的羟基(OH)被乙酸根基团(OCOCH3)取代。 [0045] The polyvinyl alcohol (PVOH) may be provided in the form comprising an amount of polyvinyl acetate (of PVAc), wherein a certain level of material PVOH hydroxyl (OH) radicals are acetate (OCOCH3) substituted. PVAc的水解是一种常见的制备PVOH的方式。 Hydrolysis of PVAc prepared PVOH is a common way. 因此,本文使用的PVOH—般包含一些PVAc。 Therefore, PVOH- as used herein includes some PVAc. 基于构成聚合物的单体的总数的%,PVOH材料(疏水改性之前或之后)可以包含0. 01至40%的PVAc,优选0. 01 至20 %,更优选0. 1至15 %,最优选0. 5至10 %。 % Based on the total monomers constituting the polymer, of PVOH material (hydrophobically modified before or after) may comprise of from 0.01 to 40% of PVAc, preferably from 0.01 to 20%, more preferably from 0.1 to 15%, most preferably from 0.5 to 10%. 如本文使用的,术语PVOH包括具有如前定义的PVAc水平的PVOH化合物。 As used herein, the term PVOH PVOH comprising a compound as previously defined levels of PVAc. 特别优选的材料具有85%至99%的“水解度”。 Particularly preferred materials have a 85 to 99% of the "degree of hydrolysis."

[0046] 优选的聚合物被改性以包含疏水取代基。 [0046] Preferred polymers are modified to include hydrophobic substituent. 一种优选的改性方法在实施例1中详细描述。 A preferred modification method is described in detail in Example 1.

[0047] 优选的疏水衍生基团包括那些基于选自缩醛类、缩酮类、酯类、氟化有机化合物、 醚类、烷烃类、烯烃类和芳香化合物的母体基团。 [0047] Preferred hydrophobic derivative groups include those based on parent groups selected from acetals, ketals, esters, fluorinated organic compounds, ethers, alkanes, olefins and aromatic compounds.

[0048] 非常优选的疏水取代基是C4至C22碳链长度的烃基。 [0048] Highly preferred hydrophobic substituent is a hydrocarbon group C4 to C22 carbon chain length. 这些烃基可以是基于烷基或烯基的,其可以是直链、支链或包含环的;它可以还或者替代地引入芳香基团。 These hydrocarbon groups may be based on alkyl or alkenyl group which may be linear, branched, or ring-containing; or alternatively it can also be introduced into the aromatic group.

[0049] 更优选地,烃基的碳链长度为C4至C2tl,甚至更优选C4至C15,最优选C4至Cltl,例如, C4 .半:Cg O [0049] More preferably, the hydrocarbon carbon chain length of C4 to C2tl, and even more preferably C4 to C15, most preferably C4 to Cltl, e.g., semi-C4:. Cg O

[0050] 大于22的烃基链长度是不合需要的,因为由其获得衍生基团的母体材料与聚合物骨架反应性差或完全不反应。 [0050] hydrocarbon chain length greater than 22 are undesirable because the reaction is obtained by completely or parent material derivative group reactive with the polymer backbone difference. 小于4的烃基提供可以忽略不计的附加的疏水性。 Hydrocarbon group of less than 4 may provide negligible additional hydrophobicity of excluding.

[0051] 适用于向聚合物上引入疏水性衍生基团的特别优选的物质是醛类,例如丁醛、辛醛、十二醛、2-乙基己醛、环己烷甲醛(cyclohexane carboxy-aldehyde)、柠檬醛和4_氨基丁醛二甲缩醛。 [0051] particularly suitable for the introduction of hydrophobic material preferably derived group to the polymer aldehydes, such as butyraldehyde, octyl aldehyde, dodecyl aldehyde, 2-ethyl hexanal, cyclohexane-carbaldehyde (cyclohexane carboxy- aldehyde), and citral dimethyl acetal 4_ ammonia.

[0052] 疏水性物质优选存在于聚合物中的水平为基于聚合物总重量的0. 1至40重量%, 更优选2 %至30 %,最优选4%至15 %。 [0052] The hydrophobic material is preferably present in the polymer based on the level of 0.1 to 40 wt% of the total weight of the polymer, more preferably from 2% to 30%, most preferably 4% to 15%. 实际上,对于具有相对高水解度的PVOH物质,这意味着优选的物质使得聚合物的5-15%的-OH基团被疏水体取代。 In fact, for a substance having a relatively high degree of hydrolysis of PVOH, which means that a substance is preferably 5-15% of polymer -OH groups is substituted with a hydrophobic material.

[0053] 在聚合物骨架基于聚乙烯醇(PVOH)的情况中,疏水性衍生物质优选以使得骨架上的疏水基团与游离羟基对的数目比为1 : 3至1 : 30,更优选1 : 4至1 : 20,最优选1 : 7至1 : 15的水平存在。 [0053] In the case where the polymer backbone of polyvinyl alcohol (PVOH) based, hydrophobic derivatized hydrophobic substance is preferably such that the number of free hydroxyl groups on the backbone ratio is 1: 3 to 1: 30, more preferably 1 : 4 to 1: 20, most preferably 1: present at a level of 15: 7-1.

[0054] 另外的改性基团可以存在于聚合物骨架上。 [0054] Additional modifying groups may be present on the polymer backbone. 例如,胺类可以优选被包括作为改性基团,因为这使得聚合物响应于例如从洗涤到冲洗液体的PH和/或离子强度的变化而更易溶解。 For example, amines may preferably be included as a modifying group since this makes the polymer from the wash, for example, in response to a change in the PH rinse liquid and / or more soluble ionic strength.

[0055] 特别优选的聚合物颗粒包含下式的疏水改性聚合物: [0055] Particularly preferred polymeric particles comprise hydrophobically modified polymers of the formula:

[0056] [0056]

Figure CN102395668AD00091

[0057] 其中,ζ与χ的平均数目比为1 : 200至1 : 6,y基于构成聚合物的单体总数(x+y+z)的%为0. 01至20%,且R是疏水基团,其为具有3至21个碳原子、优选3至6个碳原子的烷基或链烯基。 [0057] wherein the average number ratio ζ and χ 1: 200 to 1: 6, y% based on the total number of monomers constituting the polymer (x + y + z) is from 0.01 to 20%, and R is hydrophobic group, which having 3 to 21 carbon atoms, preferably 3 to 6 carbon atoms or an alkenyl group. 最优选1?是(:3!17。 ? 1 is the most preferred (:! 317.

[0058] 有益剂 [0058] The beneficial agent

[0059] 虽然有益剂是构成指示物的元件的任选特征,它们至少在某些元件中的存在是非常优选的。 [0059] Although the beneficial agent is an optional feature element constituting the indicator, which are present in at least some of the elements are highly preferred. 各种有益剂可以被引入元件中。 Various beneficial agent may be introduced into the element. 可以使用任何可以为用制剂处理的基质提供益处的相容性有益剂。 May be used any compatible beneficial agents may provide benefit to the treated substrate with the formulation. 在洗衣领域中,优选的有益剂为例如织物有益剂,以及为洗衣洗涤和/ 或冲洗介质提供益处的有益剂。 In the field of laundry, preferably the benefit agent is a fabric benefit agent, for example, as well as providing benefit to the laundry washing and / or rinsing media beneficial agent.

[0060] 优选的有益剂包括香料(游离的和包封的)、酶、消泡剂、调色染料和/或颜料、 清洁增效剂、织物调理剂(例如水不溶性的季铵物质和/或聚硅氧烷)、遮光剂、抗氧化剂、还原剂、螯合剂、色彩护理添加剂(color care additive)、密度匹配聚合物(density matching polymer)、光漂白剂、不饱和油、润肤剂和抗微生物剂。 [0060] Preferred benefit agents include perfumes (free and encapsulated), enzymes, antifoaming agents, toning dyes and / or pigments, synergists cleaning, fabric conditioners (e.g. quaternary ammonium water-insoluble substance and / or silicone), opacifiers, anti-oxidants, reducing agents, chelating agents, color care additives (color care additive), the polymer density matching (density matching polymer), optical bleaches, unsaturated oils, emollients, and antimicrobial agents.

[0061] 本发明的优选实施方式除了有益剂外在元件中还包括崩解剂。 [0061] Preferred embodiments of the present invention, in addition to benefit agents external element further comprises a disintegrant.

[0062] 元件尤其适于与颗粒有益剂(例如包封的香料)或水溶性的/可分散的有益剂一起使用。 [0062] The element is particularly suitable for the particulate benefit agent (e.g., encapsulated perfumes) or the use of water-soluble / dispersible beneficial agent together.

[0063]增塑剂和 / 或结晶干扰剂(crystallinity disruptor) [0063] The plasticizer and / or crystallization interfering agents (crystallinity disruptor)

[0064] 在指示物的元件是由聚合物形成的情况中,聚合物优选引入增塑剂和/或结晶干扰剂。 [0064] In the case where the indicator element is formed from a polymer, the polymer is preferably introduced into the plasticizer and / or crystallization interfering agent.

[0065] 可以理解,术语“增塑剂”和短语“结晶干扰剂”可以互换,因此提到一个即隐含地提到另一个。 [0065] It will be appreciated, the term "plasticizer" and the phrase "crystalline interfering agent" are used interchangeably, i.e. a so mentioned mentioned other implicitly.

[0066] 增塑剂通过控制由于外部因素侵入及其恢复原状态的倾向而导致的链扭曲/重排的方式影响聚合物链对于外部因素(如压缩和伸展力、温度和机械冲击)的反应。 [0066] Plasticizer rearrangement patterns on the control chain and intrusion of external factors distorting tendency to restore the original state caused / polymer chains react to external factors (such as compression and stretching force, temperature and mechanical impact) of . 增塑剂的关键特点是:它们与聚合物指示物高度相容,并且本质上通常是亲水性的。 Plasticizers are key features: they are highly compatible with the polymer indicator, nature and are generally hydrophilic. 增塑剂取决于构成指示物的元件的聚合物的性质。 Constituting the polymer plasticizer depending on the nature of the indicator element.

[0067] 一般来说,适合与PVOH基聚合物指示物一起使用的增塑剂具有-OH基团,与聚合物颗粒的-CH2-CH (OH) -CH2-CH (OH)-聚合物链相同。 [0067] In general, plasticizers suitable for use with PVOH-based polymer having -OH groups indicated, the polymer particles -CH2-CH (OH) -CH2-CH (OH) - polymer chain the same.

[0068] 它们的功能性模式是在羟基内引入短链氢键结合,这削弱了相邻链的相互作用, 其抑制聚集聚合物团的溶胀——聚合物溶解的第一阶段。 [0068] Their mode of functionality is to introduce short chain hydrogen bonding with the hydroxyl groups, which weakens adjacent chain interactions which inhibits swelling of the aggregate polymer group - a first stage polymer dissolved.

[0069] 水本身是对于PVOH聚合物颗粒的合适的增塑剂,而其他常见的增塑剂包括:多羟基化合物,例如,甘油、三羟甲基丙烷、二甘醇、三甘醇、山梨糖醇、二丙二醇、聚乙二醇;淀粉类,例如,淀粉醚、酯化淀粉、氧化淀粉和来自马铃薯、木薯和小麦的淀粉;纤维素类/碳水化合物类,例如,支链淀粉、糊精、羧甲基纤维素和果胶。 [0069] Water itself is a suitable plasticizer for PVOH polymer particles, and other common plasticisers include: polyhydroxy compounds, e.g., glycerol, trimethylolpropane, diethylene glycol, triethylene glycol, sorbitol sugar alcohol, dipropylene glycol, polyethylene glycol; starches, e.g., starch ethers, esterified starch, oxidized starch and starches from potato, tapioca and wheat; cellulosic / carbohydrates, e.g., pullulan, paste fine, carboxymethyl cellulose and pectin. 胺类是特别优选的增塑剂。 Amines are particularly preferred plasticizers.

[0070] 表面活性剂组合物[0071] 下面列出可以用于本发明的制剂中的各种优选的表面活性剂。 [0070] Surface active agent composition [0071] The various formulations listed below may be used in the present invention is preferably a surfactant. 特别优选的含有表面活性剂的制剂是那些在家庭和个人护理领域、特别是洗衣、头发和口腔护理领域中的制剂。 Particularly preferred formulations contain surfactants are those in the field of household and personal care, in particular laundry, hair and oral care formulation art. 完全配制的产品优选包含0. 05至10重量%的上述构成指示物的元件,和2至70重量%、更优选10至30重量%的选自阴离子表面活性剂、非离子表面活性剂、阳离子表面活性剂或其混合物的表面活性剂。 The above-described elements constituting the indicator of the fully formulated product preferably comprise from 0.05 to 10% by weight, and from 2 to 70% by weight, more preferably 10 to 30% by weight of the selected anionic surfactants, nonionic surfactants, cationic surfactant or surfactant mixture. 形成指示物的元件更优选以0. 2至10重量%,最优选0. 2 至5重量%的水平存在于表面活性剂组合物中。 Indicator element is formed more preferably from 0.2 to 10 wt%, most preferably from 0.2 to 5% by weight of a surfactant level present in the composition.

[0072] 洗衣处理组合物 [0072] The laundry treatment composition

[0073] 指示物优选被引入意图和适合用作洗衣处理组合物的制剂中。 [0073] Preferably the indicator is intended to be introduced into the formulation and suitable for use as laundry treatment compositions. 这种制剂以表明它意图用于这种用途的形式进行包装。 Such formulations to indicate that it is intended to use this form for packaging.

[0074] 洗衣处理组合物例如可以采用各向同性液体或表面活性剂结构化液体的形式。 [0074] The laundry treatment composition in the form of, for example, an isotropic liquid or a structured liquid surfactant may be employed.

[0075] 洗衣处理组合物可以是用于主要洗涤的洗涤剂组合物;或者它可以是用于添加到冲洗周期的组合物,例如织物调理剂。 [0075] The laundry treatment composition may be a detergent composition for the main wash; or it may be added to the rinse cycle of a composition, such as fabric conditioning agents.

[0076] 洗衣机的内筒包含相对小的孔,其让水通过但保留被清洗的物品在筒内。 [0076] the washing machine drum containing relatively small pores, which allow water to pass but to retain the items to be cleaned in the barrel. 指示物的层状性质赋予以下优势:即当产品在周期开始之前被直接引入机器筒内且指示物不溶于主要洗涤的洗涤液时,指示物将在洗涤结束时至少部分地被筒过滤并保留进入冲洗步骤。 Laminar property indicator impart the following advantages: that is, when the product is introduced directly into the cartridge machine and before the start of the cycle indicates the main wash solution was washed with insoluble, the indicator is at least partially cylindrical filter and retained at the end of the washing into the rinsing step. 由于在这种作用模式下的指示物需要被引入筒中,它们可以有利地作为适当的水溶性包装中的单位剂量递送或通过所谓的“往复移送装置(shuttle)”递送。 Since in this mode of action need to be introduced indicator barrel, they can advantageously be used as the water-soluble unit dose packages suitable delivery or by so-called "shuttle transferring means (Shuttle)" delivery. 因此对于多剂量容器, 有利的是:销售的产品包括包含将放置在筒中的往复移送装置的套装,或带有可以怎样获得往复移送装置的信息。 Thus for a multi-dose containers, it is advantageously: sales of products including packages comprising placing in the cartridge reciprocating transfer device, or how the information may be obtained with a reciprocating transfer device.

[0077] 制备方法 [0077] Preparation

[0078] 在一个实施方式中,本发明提供了一种制造本发明的指示物的元件的方法,所述方法包括以下步骤: [0078] In one embodiment, the present invention provides a method of manufacturing a device indicator of the present invention, the method comprising the steps of:

[0079] (a)提供本文定义的疏水改性聚合物和任选的织物有益剂的水性混合物; [0079] (a) providing a hydrophobically modified polymer as defined herein and optionally an aqueous mixture of a fabric benefit agent;

[0080] (b)干燥水性混合物以从水性混合物除去全部或部分的水,以形成片材; [0080] (b) drying the aqueous mixture to the aqueous mixture to remove all or part of the water, to form a sheet;

[0081] (c)由片材以需要的形状和/或大小形成元件;和 [0081] (c) a shape and / or size of a sheet to form a desired member; and

[0082] (d)任选地,进一步干燥元件; [0082] (d) optionally, further dried element;

[0083] (e)将元件分散在液体或凝胶的含表面活性剂的组合物中;和 [0083] (e) an element dispersed in the composition containing a surfactant in a liquid or gel; and

[0084] (f)包装所述分散体系。 [0084] (f) packaging the dispersion.

[0085] 可以使用将有益剂引入到指示物中的替代方法。 [0085] The beneficial agent can be incorporated into the alternative indicator. 例如,尽管薄膜制造商可能能够利用香料生产,但他们不太可能具有将材料(如酶)放入薄膜中所需要的设备。 For example, although the film manufacturers may be able to use spices production, but they are unlikely to have a material (e.g., enzyme) into the device in the desired film. 因此,对于通过浇铸将有益剂引入薄膜中的替代方法是将有益剂置于随后压制在一起的两层预制的薄膜之间。 Therefore, by casting a beneficial agent for introducing an alternative method the film is interposed between the beneficial agent film layers then compressed together prefabricated.

[0086] 表面活性剂 [0086] Surfactant

[0087] 一般地,表面活性剂系统的非离子和阴离子表面活性剂可以选自"Surface Active Agents “ 第1 卷,Schwartz & Perry 编著,Interscience 1949,第2 卷Schwartz, Perry & Berch 编著,Interscience 1958, Manufacturing Confectioners Company 出片反白勺''McCutcheon ' s Emulsifiers and Detergents ''白勺$ Itf 片反* 或〃 Tenside-Taschenbuch",H. Mache,第2 版,Carl Hauser Verlag,1981 中所述的表面活性剂。[0088] 优选使用的表面活性剂是饱和的。 [0087] Generally, the surfactant system of nonionic and anionic surfactants can be selected from "Surface Active Agents" Vol. 1, Schwartz & Perry, ed., Interscience 1949, Volume 2 Schwartz, Perry & Berch, eds., Interscience 1958 , Manufacturing Confectioners Company reverse the sheet spoon '' McCutcheon 's Emulsifiers and Detergents'' white spoon $ * anti sheet or the Itf 〃 Tenside-Taschenbuch ", H. Mache, 2nd Ed., Carl Hauser Verlag, 1981 in the surfactant. [0088] the surfactant is preferably used are saturated.

[0089] 可以使用的合适的非离子型洗涤剂化合物特别地包括,具有疏水基团和反应性氢原子的化合物(例如,脂族醇类、酸类、酰胺类或烷基酚类)与烯化氧类(特别是环氧乙烷单独或与环氧丙烷一起)的反应产物。 [0089] Suitable nonionic detergent compounds which may be used include, in particular, compounds having a hydrophobic group and a reactive hydrogen atoms (e.g., aliphatic alcohols, acids, amides or alkyl phenols) with alkylene having the reaction product of alkylene oxides (especially ethylene oxide alone or with propylene oxide).

[0090] 非离子型洗涤剂化合物的非限制性的例子包括:C12-Cw烷基乙氧基化物,例如, 来自Shell的NEODOL⑧非离子表面活性剂及来自BASF的LUTENSOL XL和LUTENSOL XP ; C10-C12烷基酚烷氧基化物,其中,烷氧基单元是乙氧基和丙氧基单元的混合物;与环氧乙烷/环氧丙烷嵌段烷基多胺乙氧基化物的C12-C18醇和C6-C12烷基酚缩合物,如来自BASF的PLUR0NIC ®; US 6,150,322 中讨论的C14-C22 中链支化醇;US 6,153,577、US 6,020,303 和US 6,093,856中讨论的C14-C22中链支化的烷基烷氧基化物BAEx,其中χ为1_30。 [0090] Non-limiting examples of nonionic detergent compounds include: C12-Cw alkyl ethoxylates, e.g., NEODOL⑧ nonionic surfactant and from Shell and LUTENSOL XL from BASF LUTENSOL XP; C10- C12 alkyl phenol alkoxylates wherein the alkoxy unit is a mixture of ethoxy and propoxy units; with ethylene oxide / propylene oxide block alkyl polyamine ethoxylates of C12-C18 alcohols and C6-C12 alkyl phenol condensates, such as PLUR0NIC ® from BASF; C14-C22 mid-chain branched alcohols discussed in US 6,150,322; US 6,153,577, US 6,020,303 and US C14-C22 6,093,856 discussed mid-chain branched alkyl alkoxylates, BAEx, wherein χ is 1_30.

[0091] 具体的非离子型洗涤剂化合物是C6至C22烷基酚-环氧乙烷缩合物(一般为5至25Ε0,即每分子5至25个环氧乙烷单元)和脂族C8至C18直链或支链伯或仲醇与环氧乙烷(一般为5至40Ε0)的缩合产物。 [0091] Specific nonionic detergent compounds are C6 to C22 alkyl phenols - ethylene oxide condensates (typically 5 to 25Ε0, per molecule, i.e. 5-25 units of ethylene oxide) and an aliphatic C8 to C18 straight or branched chain primary or secondary alcohols with ethylene oxide (typically 5 to 40Ε0) condensation products.

[0092] 可以使用的合适的阴离子洗涤剂化合物通常是具有含大约8至大约22个碳原子的烷基的有机羧酸、硫酸和磺酸的水溶性碱金属盐,术语烷基用来包括高级酰基的烷基部分。 [0092] Suitable anionic detergent compounds which may be used is usually an alkyl group having from about 8 to about 22 carbon atoms in the organic carboxylic acid, water-soluble alkali metal salts of sulfonic acid and sulfuric acid, the term alkyl is intended to include Advanced the alkyl moiety of acyl radicals. 本文有用的阴离子表面活性剂的非限制性的例子包括=C9-C18烷基苯磺酸盐(LAS); Cltl-C^1伯、支化的链和随机的烷基硫酸盐(AS) ;C10-C18 # (2,3)烷基硫酸盐;Cltl-Cw烷基烷氧基硫酸盐(AExS),其中优选1为1-30 ;Cltl-Cw烷基烷氧基羧酸盐,优选包含1-5个乙氧基单元;US 6,020, 303和US 6,060, 443中讨论的中链支化烷基硫酸盐;US 6,008, 181 和US 6,020, 303中讨论的中链支化烷基烷氧基硫酸盐;WO 99/05243, WO 99/05242和WO 99/05244中讨论的改性烷基苯磺酸盐;甲酯磺酸盐(MEQ ;和α -烯烃磺酸盐(AOS)。 Useful herein are non-limiting examples of anionic surfactants include = C9-C18 alkyl benzene sulfonates (LAS); Cltl-C ^ 1 primary, branched-chain and random alkyl sulfates (the AS); C10-C18 # (2,3) alkyl sulfates; Cltl-Cw alkyl alkoxy sulfates (AExS), where 1 is preferably 1-30; Cltl-Cw alkyl alkoxy carboxylates, preferably comprising 1-5 ethoxy units; US 6,020, 303 and US 6,060, 443 discussed in chain branched alkyl sulfates; discussion 6,020, 303 US 6,008, 181 and in US mid-chain branched alkyl alkoxy sulfates; WO 99/05243, WO 99/05242 and modified alkylbenzene discussed in WO 99/05244 sulfonates; methyl ester sulphonates (MEQ; and α - olefins sulfonate (AOS).

[0093] 优选的阴离子洗涤剂化合物是C11至C15烷基苯磺酸钠和C12至C18烷基硫酸钠。 [0093] The preferred anionic detergent compounds are sodium C11 to C15 alkyl and C12 to C18 alkyl sulphates. 以下表面活性剂也是适用的,如EP-A-3^ 177(联合利华)中描述的那些(其显示抗盐析性)、EP-A-070 074中描述的烷基多糖苷表面活性剂,和烷基单糖苷类。 The following surfactants are also suitable, such as EP-A-3 ^ 177 who (which show resistance to salting), alkyl EP-A-070 074 described polyglycoside surfactant (Unilever) described , and alkyl monoglycosides class.

[0094] 优选的表面活性剂系统是阴离子与非离子洗涤剂活性物质的混合物,特别是EP-A-346 995(联合利华)中指出的阴离子和非离子表面活性剂的组和例子。 [0094] Preferred surfactant systems are nonionic and anionic detergent active material mixture, the groups and examples of anionic and nonionic surfactants are especially EP-A-346 995 (Unilever) indicated. 特别优选的表面活性剂系统是C16至C18伯醇硫酸酯的碱金属盐与C12至C15伯醇3-7E0乙氧基化物的混合物。 A particularly preferred surfactant system is a mixture of alkali metal salts of C16 to C18 primary alcohol sulphate and 3-7E0 ethoxylate C12 to C15 primary alcohol.

[0095] 非离子型洗涤剂的存在量优选大于表面活性剂系统的10%,例如,25至90重量%。 [0095] The nonionic detergent is present in an amount of preferably greater than 10% surfactant system, e.g., 25 to 90 wt%. 阴离子表面活性剂的存在量例如可以为表面活性剂系统的大约5重量%至大约40 Anionic surfactants can be present in an amount of, for example, a surfactant system, from about 5% to about 40 wt.

重量%。 weight%.

[0096] 基于甲基醚的表面活性剂可以用来代替上述的基于简单烷基的表面活性剂。 [0096] Surfactants may be used ether-based surfactant in place of the simple-based group.

[0097] 如上所述,形成指示物的元件可以简单地通过降低制剂中的水浓度至指示物变得不溶的程度的表面活性剂的存在而成为不溶性的,或者更优选地,表面活性剂可以与指示物相互作用以防止元件溶解。 [0097] As described above, the indicator element may be formed simply by decreasing the water concentration in the formulation to become insoluble in the presence of an indicator of the extent of the surfactant becomes insoluble, or more preferably, a surface active agent may be interacts with indicating element to prevent dissolution.

[0098] 阳离子织物软化化合物 [0098] cationic fabric softening compound

[0099] 阳离子表面活性剂可以是阳离子织物软化化合物。 [0099] Cationic surfactants may be cationic fabric softening compound. 优选的阳离子织物软化化合物是水不溶性的季铵物质,其包括具有通过至少一个酯键连接到氮头基团(nitrogen head group)上的两个C12_18烷基或链烯基的化合物。 Preferred cationic fabric softening compound is a water insoluble quaternary ammonium material comprising a compound connected to two C12_18 alkyl or alkenyl group on the nitrogen head group (nitrogen head group) by at least one ester bond with. 更优选的是季铵物质具有两个或多个酯键。 More preferred are quaternary ammonium material having two or more ester bonds.

1[0100] 增效剂或络合剂 1 [0100] builder or complexing agent

[0101] 组合物可以任选地包含0至50重量%的洗涤增效剂。 [0101] The composition may optionally comprise from 0 to 50 wt% of detergency builders. 优选增效剂的存在水平为1至40重量%。 Synergist preferably present at a level of 1 to 40 wt%.

[0102] 增效剂物质可以选自:1)钙螯合剂物质,幻沉淀物质,幻钙离子交换物质和4)其混合物。 [0102] builder material may be selected from: 1) calcium sequestrant materials, phantom precipitated material, phantom calcium ion exchange materials and 4) mixtures thereof.

[0103] 当使用一种不溶性的无机增效剂(例如,沸石)时,优选的是其大小为0. 1至10 微米(使用来自Malvern™的激光衍射通过Mastersizer 2000粒度分析仪测量)。 [0103] When an insoluble inorganic builders (e.g., zeolites), it is preferable that a size of 0.1 to 10 microns (using a laser diffraction from a Malvern ™ 2000 particle size analyzer measured by Mastersizer).

[0104] 钙螯合剂增效剂物质的例子包括多聚磷酸碱金属盐类(例如三聚磷酸钠)和有机螯合剂(例如乙二胺四乙酸)。 Examples of calcium sequestrant builder materials [0104] include a polyphosphoric acid alkali metal salts (e.g. sodium tripolyphosphate) and an organic chelating agent (e.g., ethylenediaminetetraacetic acid).

[0105] 沉淀增效剂物质的例子包括正磷酸钠和碳酸钠。 [0105] Examples of precipitating builder materials include sodium orthophosphate and sodium carbonate.

[0106] 钙离子交换增效剂物质的例子包括各种类型的水不溶性晶体或无定形铝硅酸盐, 其中沸石是最为人所知的典型代表物,例如,沸石A、沸石B (又称沸石P)、沸石C、沸石X、沸石Y以及ΕΡ-Α-0,384,070所述的P型沸石。 [0106] Examples of calcium ion-exchange builder materials include the various types of water-insoluble crystalline or amorphous alumino silicates, of which zeolites is the best known representative of typical, for example, zeolite A, zeolite B (also known as zeolite P), zeolite C, zeolite X, zeolite Y and zeolite P ΕΡ-Α-0,384,070 claim.

[0107] 组合物也可以包含0-50重量%的增效剂或络合剂,如乙二胺四乙酸、二亚乙基三胺五乙酸、烷基-或链烯基丁二酸、氨三乙酸或下面提到的其他增效剂。 [0107] The composition may also contain 0-50 wt% of builder or complexing agent such as ethylenediaminetetraacetic acid, diethylenetriamine pentaacetic acid, alkyl - or alkenyl succinic acids, ammonia triacetate or other synergists mentioned below. 许多增效剂由于其络合金属离子的能力也是漂白稳定剂。 Many builders due to their ability to complex metal ions are also bleach-stabilizing agents.

[0108] 沸石和碳酸盐(碳酸盐包括碳酸氢盐和倍半碳酸盐)是优选的增效剂。 [0108] Zeolite and carbonate (including bicarbonate and carbonate sesquicarbonate) are preferred builders.

[0109] 组合物可以包含作为增效剂的结晶铝硅酸盐,优选碱金属铝硅酸盐,更优选铝硅酸钠。 [0109] The composition may contain as builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate. 其通常以低于15重量%的水平存在。 Which is generally present at a level of less than 15% by weight. 铝硅酸盐类是具有以下通式的物质: Aluminum silicate is a substance having the general formula:

[0110] 0. 8-1. 5Μ20· Al2O3. 0. 8-6Si02 [0110] 0. 8-1. 5Μ20 · Al2O3. 0. 8-6Si02

[0111] 其中M是一价阳离子,优选钠。 [0111] where M is a monovalent cation, preferably sodium. 这些物质包含一些结合水,并需要具有至少50mg CaO/g的钙离子交换容量。 These materials contain some bound water and to have at least 50mg CaO / g calcium ion exchange capacity. 在上式中优选的铝硅酸钠含有1.5-3. 5Si02单元。 Sodium aluminosilicate in the above formula preferably contains 1.5-3. 5Si02 unit. 如文献中广泛描述的,通过硅酸钠和铝酸钠之间的反应可以容易地制备它们。 As widely described in the literature, they can be prepared readily by reaction between sodium silicate and sodium aluminate. 表面活性剂与铝硅酸盐(如果存在)的比率优选大于5 : 2,更优选大于3 : 1。 The ratio of aluminosilicate and the surfactant (if present) is preferably greater than 5: 2, more preferably greater than 3: 1.

[0112] 替代铝硅酸盐增效剂或另外地,也可以使用磷酸盐增效剂。 [0112] Alternatively or additionally, the aluminosilicate builders, phosphate builders may be used. 在本领域中,术语“磷酸盐”包括二磷酸盐、三磷酸盐和膦酸盐物质。 In the present art, the term "phosphate" embraces diphosphate, triphosphate, and phosphonate species. 其他形式的增效剂包括硅酸盐,例如可溶性硅酸盐、偏硅酸盐、层状硅酸盐(例如,来自Hoechst的SKS-6)。 Other forms of builder include silicates, such as soluble silicates, metasilicates, layered silicates (e.g., from Hoechst SKS-6).

[0113] 优选地,洗衣洗涤剂制剂是无磷酸盐制备或很大程度上无磷酸盐制备的洗衣洗涤剂制剂,即包含小于1重量%的磷酸盐。 [0113] Preferably, the laundry detergent formulation is a non-phosphate laundry detergent formulation was prepared without phosphate salts or largely, i.e. comprising less than 1 wt% of phosphate.

[0114] 对于透明的液体或凝胶组合物,优选的是非颗粒的、水溶性的增效剂。 [0114] For the transparent liquid or gel compositions, preferred are particles, water-soluble builders. 虽然可以使用一些不溶性的增效剂,过度使用增效剂会导致制剂浑浊或甚至不透明。 Although using some insoluble builders, builders cause excessive use of formulation cloudy or even opaque.

[0115] 调色剂 [0115] Toner

[0116] 制剂优选包含0. 0001至0. 01重量%的蓝色或紫色调色剂。 [0116] formulations preferably comprise from 0.0001 to 0.01% by weight of blue or violet toner. 调色剂减少对于许多着色服装损害的感觉和提高白色服装的白度感受。 Reduce the feeling of the toner for many colored garments and increase whiteness of damage feeling of white garments.

[0117]调色剂优选选自《染料索引》(colour index) (Society of Dyers and Colourists and American Association of Textile Chemists and Colorists 2002) 43^¾ 散碱性、直接和酸性类型的蓝色和紫色染料。 [0117] The toner is preferably selected from the "Color Index" (colour index) (Society of Dyers and Colourists and American Association of Textile Chemists and Colorists 2002) 43 ^ ¾ scattered alkaline and acidic type of direct blue and violet dyes .

[0118] 优选存在直接紫色或直接蓝色染料。 [0118] Preferably a direct violet or direct blue dye. 优选染料是双偶氮、三偶氮染料或三苯二噁嗪(triphendioxazine)染料。 Preferred dyes are bis-azo, tris-azo dyes or triphenodioxazine (triphendioxazine) dye. 致癌的联苯胺基染料不是优选的。 Biphenyl amine carcinogenic dyes are not preferred.

12[0119] 可以使用双偶氮含铜染料,如直接紫66。 12 [0119] bis-azo copper containing dyes may be used, such as direct violet 66.

[0120] 最优选的双偶氮染料的结构如下: [0120] The most preferred structures disazo follows:

[0121] [0121]

Figure CN102395668AD00131

[0122]其中: [0122] wherein:

[0123] 环D和E可以独立地为如图所示的萘基或苯基; [0123] ring D and E may be independently naphthyl or phenyl as shown;

[0124] R1选自氢和C1-C4烷基,优选氢; [0124] R1 is selected from hydrogen and C1-C4 alkyl, preferably hydrogen;

[0125] &选自氢、C1-C4烷基、取代或未取代的苯基和取代或未取代的萘基,优选苯基; [0125] & selected from hydrogen, C1-C4 alkyl group, a substituted or unsubstituted phenyl and substituted or unsubstituted naphthyl, preferably phenyl;

[0126] R3和R4独立地选自氢和C1-C4烷基,优选氢或甲基; [0126] R3 and R4 are independently selected from hydrogen and C1-C4 alkyl, preferably hydrogen or methyl;

[0127] X和Y独立地选自氢、C1-C4烷基和C1-C4烷氧基;优选染料具有X =甲基,Y =甲氧基且η为0、1或2,优选1或2。 [0127] X and Y are independently selected from hydrogen, C1-C4 alkyl and C1-C4 alkoxy; preferably dye has X = methyl, Y = methoxy and η is 0, 1 or 2, preferably 1 or 2.

[0128] 优选的双偶氮染料是直接紫7、直接紫9、直接紫11、直接紫沈、直接紫31、直接紫35、直接紫40、直接紫41、直接紫51和直接紫99。 [0128] Preferred are bis azo direct violet 7, direct violet 9, direct violet 11, direct violet Shen, direct violet 31, direct violet 35, direct violet 40, direct violet 41, direct violet 51 and direct violet 99.

[0129] 优选的溶剂和分散染料选自单偶氮或蒽醌染料,最优选溶剂紫13、分散紫27、分散紫沈、分散紫观、分散紫63和分散紫77。 [0129] Preferred solvent and disperse dyes are selected from mono-azo or anthraquinone dyes, most preferably solvent violet 13, disperse violet 27, disperse violet Shen, Disperse Violet concept, disperse violet 63 and disperse violet 77.

[0130] 优选的颜料是颜料紫23。 [0130] Preferred pigments are Pigment Violet 23.

[0131] W02008/017570中公开了合适的有机染料的例子。 [0131] In W02008 / 017570 discloses examples of suitable organic dyes. 优选的染料还包括酸性紫50和酸性蓝98。 Preferred dyes further include acid violet 50 and acid blue 98. 聚合的调色剂/着色剂也是优选的。 Polymerized toner / colorant is also preferred.

[0132] 如上所述,在指示物中引入调色剂或着色剂可以用于防止试剂向产品的整体赋予不必要的颜色,和/或防止调色剂与其他制剂组分不必要的相互作用,和/或确保试剂被携带进入冲洗以提高沉积。 Interaction [0132] As described above, the toner or colorant incorporated in the indicator reagent can be used to prevent unnecessary color imparting to the entire product, and / or prevent toner from other components of the formulation unnecessary and / or to ensure the flushing agent is carried into the deposition to increase.

[0133] 酶类 [0133] Enzymes

[0134] 组合物优选包含一种或多种酶,其提供清洁性能和/或织物护理益处。 [0134] The composition preferably comprises one or more enzymes, which provide cleaning performance and / or fabric care benefits. 合适的酶的例子包括但不限于:半纤维素酶、过氧化物酶、蛋白酶、纤维素酶、木聚糖酶、脂酶、磷脂酶、酯酶、角质酶、果胶酶、甘露聚糖酶、果胶裂解酶、角蛋白酶、还原酶、氧化酶、酚氧化酶、 脂肪氧合酶、木质酶、支链淀粉酶、鞣酸酶、戊聚糖酶、malanases、阿拉伯糖苷酶、透明质酸酶、软骨素酶、漆酶和淀粉酶或其混合物。 Examples of suitable enzymes include, but are not limited to: hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, mannanases , pectin lyases, keratinase, reductase, oxidase, phenoloxidase, lipoxygenase, ligninase, pullulanase, tannase, pentosanase, malanases, arabinosidase, hyaluronan acid enzyme, chondroitinase, laccase, and amylases, or mixtures thereof.

[0135] 典型的组合是可以包含,例如,蛋白酶和脂酶与淀粉酶和/或纤维素酶结合的酶混合物。 [0135] A typical composition can contain, e.g., protease and lipase and amylase and / or cellulase in conjunction with the enzyme mixture. 当存在于清洁组合物中时,上述酶可以以组合物重量的大约0.00001重量%至大约2重量%、大约0. 0001重量%至大约1重量%或甚至大约0. 001重量%至大约0. 5重量%的酶蛋白的水平而存在。 When present in the cleaning composition, the aforementioned enzymes may be from about 0.00001% by weight of the composition to about 2% by weight, from about 0.0001 wt% to about 1 wt% or even from about 0.001% to about 0 wt. 5 wt% of enzyme protein levels exist.

[0136] 优选酶是纤维素酶、脂肪酶、蛋白酶和包括这些中的一种或多种的混合物。 [0136] Preferred enzymes are cellulases, lipases, proteases comprising a mixture of one or more of these.

[0137] 如上所述,可以在指示物的层状元件中引入酶,以防止酶与其他制剂组分(如增稠或结构化系统)的不必要的相互作用。 [0137] As described above, the enzyme can be introduced in a laminar element of the indicator, to prevent unwanted interaction of the enzyme preparation with other components (e.g., thickened or structured system). 基于纤维素的结构化系统通常与纤维素酶产生不利的相互作用,而基于蓖麻油的结构化系统对于脂酶是敏感的。 Cellulose structuring system typically adversely interact with cellulase, based on the castor oil-based structuring system are sensitive to lipase. 漂白剂一般不利于酶的稳定性,且蛋白酶可以显示与其他酶的负面相互作用。 Bleaching agents are generally not conducive to the stability of the enzymes, and protease may show a negative interaction with other enzymes.

[0138] 荧光增白剂 [0138] Fluorescent Brightener

[0139] 组合物优选包含荧光增白剂(光学增白剂)。 [0139] The composition preferably comprises a fluorescent agent (optical brightener). 荧光增白剂是公知的,且许多这样的荧光增白剂是可市售获得的。 Fluorescent agents are well known and many such fluorescent whitening agents are commercially available. 通常情况下,这些荧光增白剂以其碱金属盐的形式(例如, 钠盐)供应和使用。 Usually, these fluorescent agents in the form of their alkali metal salts (e.g., sodium salt) supply and use. 用于组合物中的一种或多种荧光增白剂的总量一般为0.005至2重量%,更优选0.01至0. 1重量%。 The total amount used in the composition of one or more fluorescent whitening agents is generally from 0.005 to 2% by weight, more preferably from 0.01 to 0.1 wt%. 优选的荧光增白剂种类为:二苯乙烯基联苯化合物,例如Tinopal (商标)CBS-X ;二胺均二苯乙烯二磺酸化合物,例如,Tinopal DMS纯Xtra和Blankophor (商标)HRH ;和吡唑啉化合物,例如,Blankophor SN0优选的荧光增白剂是: 2-(4-苯乙烯基-3-磺苯基)-2H-萘酚[1,2-d]三唑钠、4,4' -二{[ (4-苯胺基-6-(N-甲基-N-2-羟乙基)氨基-1,3,5-三嗪-2-基)]氨基}均二苯乙烯-2-2' - 二磺酸二钠、4, 4' -二{[(4-苯胺基-6-吗啉代-1,3,5-三嗪-2-基)]氨基}均二苯乙烯-2-2' -二磺酸二钠和4,4'-双(2_ 磺苯乙烯基)联苯二钠(disodium 4,4' -bis (2-sulfoslyryl) biphenyl)。 Preferred optical brightener species is: distyryl-biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X; diamine-stilbene disulfonic acid compound, e.g., Tinopal DMS pure Xtra and Blankophor (trademark) HRH; and pyrazoline compounds, e.g., Blankophor SN0 preferred fluorescers are: 2- (4-styryl-3-sulfophenyl) -2H- naphthol [1,2-d] triazole sodium, 4 , 4 '- bis {[(4-anilino--6- (N- methyl -N-2- hydroxyethyl) amino-1,3,5-triazin-2-yl)] amino} stilbene '- disulphonate, disodium 4, 4' - ethylene -2-2-bis {[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)] amino} stilbene-2-2 '- disulfonate, disodium 4,4'-bis (2_ sulfo styryl) biphenyl disodium (disodium 4,4' -bis (2-sulfoslyryl) biphenyl).

[0140] 如同使用调色剂,将荧光增白剂引入到指示物中可以用于保护荧光增白剂免于与其他组分的不必要的相互作用,和/或确保试剂被携带进入冲洗以提高沉积。 [0140] As the toner used, the fluorescent brightening agent is introduced into the indicator may be used to protect the fluorescent whitening agent from unnecessary interactions with other components, and / or to ensure that the reagent to be carried into the rinse improve the deposition.

[0141] 香料 [0141] spices

[0142] 优选组合物包含香料。 [0142] Preferably the composition comprises a perfume. 优选产品上的香料(排除任何包封物质或载体)的范围为0.001 至3 重量%,最优选0. 1 至2.5 重量%。 Preferably the range of perfume products (excluding any carrier or encapsulating material) is from 0.001 to 3 wt%, most preferably 0.1 to 2.5 wt%. CFTA Publications 出版的CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide 禾口Schnell Publishing Co.出版的OPD 1993 Chemicals Buyers Directory 80th Annual Edition提供了许多合适的香料的例子。 CFTA Publications published by CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide Hekou Schnell Publishing Co. published OPD 1993 Chemicals Buyers Directory 80th Annual Edition provides many examples of suitable spices.

[0143] 多种香料组分存在于制剂中是普遍的。 [0143] more perfume ingredients are generally present in the formulation. 在本发明的组合物中,设想会有4种或更多、优选5种或更多、优选6种或更多或者甚至7种或更多的不同的香料组分。 In the compositions of the present invention, it is envisaged there will be four or more, preferably 5 or more, preferably six or more or even seven kinds or more different perfume components.

[0144] 在香料混合物中,优选15至25重量%为头香(top note)。 [0144] In perfume mixtures preferably 15 to 25% by weight of top notes (top note). 头香由Poucher(Journal of the Society of Cosmetic Chemists 6(2) :80[1955])定义。 Top notes (of Cosmetic Chemists 6 (2) Journal of the Society: 80 [1955]) defined by Poucher. 优选的头香选自柑桔油、里哪醇、乙酸里哪醇酯、薰衣草、二氢月桂烯醇、玫瑰醚和顺式3-己醇。 Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.

[0145] 香料和尤其是头香可以用于提示织物护理益处。 [0145] In particular spices and fragrant head it can be used to prompt the fabric care benefits.

[0146] 如同其他有益剂一样,将香料引入到指示物中可以用于保护香料免于与其他组分不必要的相互作用和/或蒸发导致的损失,和/或确保试剂被携带进入冲洗以提高沉积。 [0146] As with other beneficial agents, like fragrance introduced into the indicator may be used to protect perfume from unnecessary interactions with other components and / or loss due to evaporation and / or to ensure that the reagent to be carried into the rinse improve the deposition.

[0147] 指示物是特别有效的递送包封的香料的方式,因为通过将香料引入指示物内来防止包封香料的分离(无论通过沉降或漂浮)。 [0147] indicator is encapsulated fragrance particularly effective way of delivery, as indicated by the perfume was introduced into the encapsulated perfume to prevent separation (either by sedimentation or flotation). 此外,对于易发生泄漏的包封物(或其他载体),引入指示物的元件内有助于保留香料(或其他有益剂)在包封物或其他载体中。 In addition, encapsulation is prone to leakage (or other vector), is introduced into the indicator element helps preserve flavor (or other benefit agent) in the encapsulating or other carrier. [0148] 在用于制造指示物的元件的薄膜中的包封香料的优选水平为薄膜与包封物的重量比使得大于10重量%,优选大于25重量%的指示物是香料包封物。 [0148] Preferred levels of perfume encapsulated in a thin film for producing an indicator element of a film in the encapsulation so that the weight ratio of greater than 10 wt%, preferably greater than 25 wt% of perfume encapsulates indicator.

[0149] 聚合物 [0149] Polymer

[0150] 除了作为形成指示物的元件的基质存在的任何聚合物外,组合物还可以包含一种或多种聚合物。 [0150] In addition, as the polymer matrix is ​​formed of any of the indicator element is present, the compositions may further comprise one or more polymers. 例子为羧甲基纤维素、聚(乙二醇)、聚(乙烯醇)、聚羧酸酯(例如,聚丙烯酸酯)、马来酸/丙烯酸共聚物和甲基丙烯酸十二烷基酯/丙烯酸共聚物。 Examples are carboxymethylcellulose, poly (ethylene glycol), poly (vinyl alcohol), polycarboxylates (e.g., polyacrylate), maleic acid / methacrylic acid copolymers and lauryl methacrylate / acrylic acid copolymer.

[0151] 当调色染料存在时,其存在防止染料沉积的聚合物(例如聚(乙烯基吡咯烷酮)、 聚(乙烯基吡啶-N-氧化物)和聚(乙烯基咪唑))优选不存在于制剂中。 [0151] When the hueing dye is present, it is present to prevent dye deposition polymers (e.g., poly (vinyl pyrrolidone), poly (vinyl pyridine -N--oxide) and poly (vinyl imidazole)) is preferably not present in formulation.

[0152] 水溶助长剂 [0152] Hydrotropes

[0153] 对于液体形式的组合物,有用的是包括防止液晶形成的水溶助长剂。 [0153] For the liquid form of the composition, it is useful to include a hydrotrope to prevent liquid crystal formation. 因而添加水溶助长剂改善组合物的清澈/透明度,并有助于指示物的感知。 Thus adding the hydrotrope to improve the clarity / transparency of the composition and contribute to the perception indicator.

[0154] 合适的水溶助长剂包括但不限于:丙二醇、乙醇、尿素、苯磺酸盐类、甲苯磺酸盐、 二甲苯磺酸盐或异丙苯磺酸盐。 [0154] Suitable hydrotropes include but are not limited to: propylene glycol, ethanol, urea, salts of benzene, toluene sulfonate, xylene sulfonate or cumene sulfonate. 合适的盐类包括但不仅限于:钠、钾、铵、单乙醇胺、三乙醇胺。 Suitable salts include, but are not limited to: sodium, potassium, ammonium, monoethanolamine, triethanolamine. 优选地,水溶助长剂选自丙二醇、二甲苯磺酸盐、乙醇和尿素,以提供最佳的性能。 Preferably, the hydrotrope selected from propylene glycol, xylene sulfonate, ethanol, and urea to provide optimum performance. 水溶助长剂的量一般为0至30 %,优选0. 5 %至30 %,更优选0. 5至30 %,最优选1至15 %。 The amount of the hydrotrope is generally 0 to 30%, preferably from 0.5 to 30%, more preferably from 0.5 to 30%, most preferably 1 to 15%.

[0155] 漂白剂前体 [0155] bleach precursor

[0156] 漂白剂前体(例如,四乙炔二胺(tetra-acetylene diamine)和过碳酸钠)不能直接加入到液体制剂中,因为产生的过酸物质不稳定。 [0156] bleach precursor (e.g., four acetylene diamine (tetra-acetylene diamine) and sodium percarbonate) can not be added directly to the liquid formulations, because the peracid species generated labile. 如果洗衣处理组合物采取液体形式, 那么一般优选的是组合物不包含过氧化漂白剂,例如,过碳酸钠、过硼酸钠和过酸。 If the laundry treatment composition is in the liquid form, it is generally preferred that the composition does not contain a peroxide bleaching agent, e.g., sodium percarbonate, sodium perborate, and peracid.

[0157] 通过在形成指示物的元件中包封前体,可以防止生成过酸,直到组合物被引入主要清洗步骤中。 [0157] precursor by encapsulation indicator element is formed, it is possible to prevent generation of peracid, until the composition is introduced into the main washing step.

[0158] 其他有益剂: [0158] Other beneficial agent:

[0159] 用于引入指示物中的优选的有益剂为香料(游离的和/或包封的)、香料前体(pro-fragrance)、酶、消泡剂、荧光增白剂、漂白剂及其前体(包括光漂白剂)、调色染料和/或颜料、织物调理剂(例如水不溶性的季铵盐物质和/或聚硅氧烷)、润滑剂、去污聚合物(soil-release polymer)、遮光剂、抗氧化剂、还原剂、螯合剂、色彩护理添加剂(color care additive)、不饱和油、润肤剂和抗微生物剂。 Beneficial agent [0159] Preferably for introduction of the indicator in the perfume (free and / or encapsulated), flavor precursors (pro-fragrance), enzymes, antifoaming agents, optical brighteners, bleach and precursors thereof (including optical bleaches), toning dyes and / or pigments, fabric conditioners (e.g. quaternary ammonium salt of the water-insoluble substance and / or silicone), lubricants, soil release polymers (soil-release Polymer), opacifiers, anti-oxidants, reducing agents, chelating agents, color care additives (color care additive), unsaturated oils, emollients and antimicrobial agents. 可以采用这些有益剂中的两种或多种的混合物。 Mixtures of two or more of these beneficial agents may be employed.

[0160] 有益剂在被引入指示物的元件中之前可以被包封或吸附在载体上。 [0160] benefit agent may be encapsulated or adsorbed on the carrier element is introduced prior to the indicator. 合适和优选包封剂包括通过加成或缩聚形成的聚合物及其混合物。 Suitable encapsulating agents include, and preferably is formed by addition or condensation polymers, and mixtures thereof. 特别优选核-壳包封物。 Particularly preferred core - shell encapsulant.

[0161] 也优选有益剂与相关递送助剂结合。 [0161] Also preferably in combination with the relevant benefit agent delivery aid. 合适的递送助剂包括织物直染聚合物(fabric substantive polymer),包括结合到包含有益剂的颗粒上的多糖类、聚酯类和聚酰胺类。 Suitable delivery aids include fabric dyeing linear polymer (fabric substantive polymer), comprising a polysaccharide bound to the particles comprising benefit agent, polyesters and polyamides. 利用指示物的元件引入这种颗粒可以保护沉积助剂免受例如酶类、漂白剂和其他可能会负面影响沉积助剂的物质的作用。 Such particles may be introduced into the deposition aid is protected against e.g. enzymes, bleaching agents and other possible substances adversely affects the deposition aid by the indicator element.

[0162] 正如上文关于香料所提及的,将有益剂引入在包装产品中保持不溶的层状指示物中可以防止有益剂不必要的释放和/或活化,这可以降低制剂成本并改善有益剂的递送/ 或效果。 [0162] As mentioned above for the perfume, the beneficial agent is introduced into the indicator layer remains insoluble in the packaged product can be prevented the unnecessary release of beneficial agent and / or activation which can be beneficial to reduce costs and improve the formulation delivery / or effect agents. 当有益剂被承载在载体上或被包封时,尤其如此。 When the benefit agent is encapsulated in or carried on a support, in particular.

[0163] 特别优选的是包括选自香料和/或香料前体(特别是包封的或载体吸附的香料和/或香料前体)、漂白剂及其前体(包括光漂白剂)、酶、荧光增白剂、抗微生物剂及其两种或多种的任意组合的有益剂。 [0163] Particularly preferred are selected from the group comprising a perfume and / or flavor precursors (in particular encapsulated or adsorbed perfume carrier and / or flavor precursors), and bleach precursors (including photobleach), the enzyme , optical brighteners, antimicrobial agents, and any combination of two or more beneficial agents.

[0164] 完全配制的产品: [0164] fully formulated product:

[0165] 本发明的特别优选的实施方式包括包装的含表面活性剂的制剂,其含有水溶性的视觉指示物,其中: [0165] A particularly preferred embodiment of the present invention comprises a formulation containing a surfactant package, comprising a water soluble visual indicator, wherein:

[0166] a)含有表面活性剂的组合物是可倾倒的液体洗涤剂组合物,包含: [0166] a) a composition comprising a surface active agent is a pourable liquid detergent composition comprising:

[0167] i)0. 05至10重量%的形成视觉指示物的元件,和 [0167] i) 0. 05 to 10 weight percent of the element forming a visual indicator, and

[0168] ii)2至70重量%、优选10至30重量%的选自阴离子表面活性剂、非离子表面活性剂、阳离子表面活性剂或其混合物的表面活性剂; [0168] ii) 2 to 70 wt%, preferably 10 to 30% by weight of the selected anionic surfactant, a nonionic surfactant, a cationic surfactant or mixture of surfactants;

[0169] b)包装是至少部分透明的; [0169] b) the package is at least partially transparent;

[0170] c)视觉指示物包括多个分散物质的片状元件,其中: [0170] c) a visual indicator member comprises a plurality of sheet-dispersible material, wherein:

[0171] i)元件的平均直径(平面测量的)与元件的厚度的比率大于5 : 1,优选大于8:1; The average diameter of [0171] i) element (measured in the plane ratio) is greater than the thickness of the element 5: 1, preferably greater than 8: 1;

[0172] ii)元件的平均直径为1-lOmm,优选3_6mm ; The average diameter of the [0172] ii) component is 1-lOmm, preferably 3_6mm;

[0173] iii)元件的平均厚度为100-2000微米,优选200-500微米;和 The average thickness of the [0173] iii) element 100 to 2000 microns, preferably 200-500 microns; and

[0174] iv)任选地,视觉指示物的元件包含有益剂,更优选包含选自香料和/或香料前体的有益剂,最优选包含包封的或载体吸附的香料和/或香料前体。 [0174] before iv) optionally element, the visual indicator comprises a beneficial agent, more preferably selected from a perfume benefit agent and / or perfume precursors, most preferably encapsulated or adsorbed perfume carrier and / or perfume body.

[0175] 优选的元件具有均勻外观,而不是由较大的片材随机形成。 [0175] Preferably the element has a uniform appearance, rather than randomly formed by the larger sheet. 然而,几个元件群体可以具有不同的外观特征,如形状和/或颜色。 However, several groups of elements may have a different appearance characteristics, such as shape and / or color. 优选存在少于10个、更优选少于5个这样的元件群体。 Preferably there is less than 10, more preferably less than 5 groups of such elements.

[0176] 元件的优选形状为:通过绕沿着指示物的细薄维度的轴在至少十二分之一圈内旋转对称的形状。 The preferred shape of [0176] elements are: at least one twelfth of the circle shape rotationally symmetrical about by thin dimension along the axis of the indicator. 对称优选使得指示物在六分之一或五分之一圈的旋转后是对称的。 Such that the indicator is preferably symmetrical symmetrical after rotation of one sixth revolution or fifths. 特别优选的形状包括花样的形状和具有四、五、六个角的星形。 Particularly preferred shapes include a shape pattern having four, five, six corners of the star. 这些优选的形状有助于改善指示物的可见性和/或过滤。 The preferred shape helps to improve the visibility of the indicator and / or filtration. 一种替代方式是:指示物是由盘或环形成,或是四边形(如菱形)。 An alternative is: indicator is formed by a disc or a ring, or a quadrangle (e.g., rhombus). 指示物可以由具有双边对称(如心型及类似形状)的元件形成。 Indicator may be formed of elements having bilateral symmetry (e.g., heart-shaped and the like shape). 规则形状而不是随机形状的特定群体是表明指示物意图具有某些特定功能的更肯定的指标。 Regular shape specific groups rather than random shapes shown that indicator is intended to have a more positive indicators of certain functions.

[0177] 特别优选的是:选择指示物以使得元件也是在旗帜上找到的标记(如叶、星或新月形),且可以选择指示物和整体制剂的颜色以反映这一点。 [0177] Particularly preferred are: selecting an indicator so that the marking element is found on banner (e.g., leaves, star or crescent), and can choose the color indicator and the overall formulation to reflect this. 因此指示物可以是在蓝色产品中的白色或黄色的星形。 Thus the indicator may be a white or yellow star blue product.

[0178] 令人惊讶的是,当层状元件存在于包含可见颜色染料的产品中时,它会产生视错觉:与指示物不存在时感觉到的相比该产品色彩具有较不强烈。 [0178] Surprisingly, when the layered product is present in the element comprising a dye in a visible color, it will produce a visual illusion: felt the absence of the product as compared with the indicator having a color less intense. 这是无法解释的和未预计到的效果,但具有以下优势:通常存在于包含表面活性剂的产品中以掩盖基础制剂的任何变色的染料或作为织物调色剂存在的染料看起来较不强烈。 This can not be explained and unanticipated effects, but with the following advantages: normally present in products comprising a surfactant to mask any color change of the dye base formulation or present as a fabric dye toner looks less strongly .

[0179] 为了可以进一步和更好地理解本发明,如下参照特别的实施例进行说明。 [0179] In order to further and better understanding of the present invention, particular embodiments will be described below with reference to Examples.

实施例 Example

[0180] 实施例la :疏水改性聚合物材料的制备 Preparation of hydrophobically modified polymeric material: Example la [0180] Embodiment

[0181] 通过将100克聚乙烯醇(PVOH) (Mowiol 20-98 (商品名),来自Kuraray Specialities)和900克软化水放入烧瓶中并加热到70°C来制备PVOH在水中的10重量% 溶液。 [0181] PVOH 10 was prepared by weight in water 100 g of polyvinyl alcohol (PVOH) (Mowiol 20-98 (trade name), available from Kuraray Specialities) and 900 g demineralized water in a flask and heated to 70 ° C % solution. 向其加入10毫升盐酸(36%的水溶液)以催化反应,然后加入丁醛。 Thereto was added 10 ml of hydrochloric acid (36% aqueous solution) to catalyze the reaction, and then butyryl aldehyde. 然后在惰性气氛、70°C下搅拌混合物5小时,之后停止加热,并在室温下继续搅拌另外20小时。 Then stirred under an inert atmosphere, 70 ° C the mixture for 5 hours after which heating was stopped and stirring continued for a further 20 hours at room temperature. 然后使用氢氧化钠溶液调节反应混合物至PH 7。 Sodium hydroxide solution and then the reaction mixture was adjusted to PH 7.

[0182] 产生的溶液在丙酮中沉淀以产生缩醛化的PVOH聚合物,并用丙酮(500毫升)然后用水(50毫升)重复洗涤。 [0182] The resulting solution was precipitated in acetone to produce the acetal of PVOH polymer and washed with acetone (500 mL) and washed with water (50 ml), washed repeatedly. 然后在真空条件下、在70°C下干燥过夜以产生白色聚合物。 Then under vacuum, dried at 70 ° C for overnight to yield a white polymer.

[0183] 实施例2 :指示物元件的制备: Preparation of the indicator element:: two cases of [0183] Embodiment

[0184] 包含3份根据实施例1制备的疏水改性PVOH的溶液,在溶液(15%活性)中与7 份包含包封的香料的浆(31%的香料负载)混合。 [0184] The mixture containing 3 parts of hydrophobically modified PVOH solution was prepared in Example 1, a solution (15% active) with 7 parts of encapsulated fragrance slurry (31% perfume loading) comprising. 通过将其倒入Teflon ™薄膜作为内衬的聚苯乙烯生物分析盘,溶液用于形成薄膜。 By being poured into a Teflon ™ film as the inner liner polystyrene bioassay plate, a solution for forming a thin film. 干燥产生的薄膜。 Resulting dried film. 使用手动冲压机由薄膜切割五角星(Five pointed, star)形的元件。 A film using a hand punch cutting pentagram (Five pointed, star) shaped element.

[0185] 实施例3:产品的制备: Product Preparation:: 3 cases of [0185] Embodiment

[0186] 通过混合液体基质与110-120个指示物来制备由12X35克剂量构成的制剂。 [0186] g dose formulation constituted by a 12X35 prepared by mixing with a liquid matrix dictates 110-120. 这将向各剂量递送2%的香料。 This is to provide the dose delivered 2% of spices. 合适的基础液体制剂包含32%的水、36%的表面活性剂(6. 87% NI 7E0U3. 11% LAS、10. 23% SLES 3E0、5. 78% FA)。 Suitable water based liquid formulation containing 32%, 36% surfactant (6. 87% NI 7E0U3. 11% LAS, 10. 23% SLES 3E0,5. 78% FA).

[0187] 实施例4:香料的沉积: [0187] Example 4: Deposition of perfume:

[0188] 用35克剂量的制剂对棉织品样品进行洗涤研究(40°C,棉织品程序,Miele 1714FLA),所述制剂包含原样的包封香料(在产品上为2重量% )或包含含有包封物的指示物。 [0188] Study washing (40 ° C, cotton program, Miele 1714FLA) with a sample of cotton 35 g dose of the formulation, said formulation comprising as-encapsulated fragrance (the product of 2 wt%) containing or comprising encapsulated indicator thereof. 机器的内容物为3千克洗清洁压载负荷和16个毛巾布棉织监测物。 The contents of the machine to wash 3 kg clean ballast load of terry cotton and 16 was monitored. 基础液体制剂包括〃 Surf Small and Mighty" ™。 Base liquid formulations include 〃 Surf Small and Mighty "™.

[0189] “包封物Α”为基于三聚氰胺的“扩散性”包封物,其相当差地保留香料。 [0189] "[alpha] encapsulation" as melamine-based "diffusion" of encapsulation, which is rather poor flavor retained. 包封物B 为基于三聚氰胺的“密封的”包封物,其良好地保留香料。 B is a melamine-based encapsulation of the "sealed" encapsulation, which retain good flavor.

[0190] 下表显示由经过培训的香料评审员小组在揉搓经洗涤的织物样品之前和之后获得的平均分数。 [0190] The following table shows the average scores by trained perfume assessors Panel fabric samples before and after rubbing washed obtained. 这是在衣物在储存后穿戴时释放香料的模式。 This is the release of the perfume in the laundry after storage worn mode. 较高的分数代表较强的香料感觉。 Higher scores represent a strong spice feeling.

[0191] [0191]

Figure CN102395668AD00171

[0192] 由此可以看出,在两种情况下已经引入星形物中的有益剂在揉搓后显示出更好的性能。 [0192] It can be seen, in both cases has been introduced into the star was beneficial agents exhibit better properties after kneading.

Claims (16)

1. 一种包括水溶性的视觉指示物的包装的液体或凝胶制剂,其中,所述视觉指示物包括多个分散物质的片状元件,且其中,所述指示物包括任选的有益剂。 CLAIMS 1. A package comprising a liquid or gel formulation of a water-soluble visual indicator, wherein the visual indicator comprises a plurality of sheet-like elements dispersible material, and wherein said indicator comprises an optional benefit agent .
2.根据权利要求1所述的包装制剂,其包括可倾倒的液体。 2. Packaging of the formulation according to claim 1, which comprises a pourable liquid.
3.根据权利要求2所述的包装制剂,其20秒―1的下粘度为IOOmPa. s至2000mPa. s。 3. The packaged formulation according to claim 2, which is a viscosity of 20 seconds -1 IOOmPa. S to 2000mPa. S.
4.根据任一项前述权利要求所述的包装制剂,其中,所述包装是至少部分透明的。 The packaged formulation according to any one of the preceding claims, wherein the package is at least partially transparent.
5.根据任一项前述权利要求所述的包装制剂,其中,所述元件的平面测量的平均直径与元件厚度的比率大于5 : 1,优选大于8 : 1。 The packaged formulation according to any one of the preceding claims, wherein the ratio of the average diameter and thickness of the element measured in the plane of the element is greater than 5: 1, preferably greater than 8: 1.
6.根据任一项前述权利要求所述的包装制剂,其中,所述元件的平均直径为1-lOmm, 优选3-6mm0 6. Packaging of the formulation according to any preceding claim, wherein the average diameter of the element is 1-lOmm, preferably from 3-6mm0
7.根据任一项前述权利要求所述的包装制剂,其中,所述元件的平均厚度为100-2000 微米,优选200-500微米。 7. Packaging of the formulation according to any preceding claim, wherein the average thickness of the element 100 to 2000 microns, preferably 200-500 microns.
8.根据任一项前述权利要求所述的包装制剂,其中,所述元件为“星”形或“花”形。 8. A package according to any preceding claim formulation according to claim, wherein the element is a "star" shaped or "flower" shape.
9.根据任一项前述权利要求所述的包装制剂,其中,所述元件包含疏水改性的聚合物。 9. A package according to any preceding claim formulation according to claim, wherein said element comprises a hydrophobically modified polymer.
10.根据权利要求9所述的包装制剂,其中,所述元件包含疏水改性聚合物(i)和织物有益剂(ii),其比率为1 : 50至99 : 1重量份,优选为1 : 40至95 : 1重量份。 10. The packaged formulation according to claim 9, wherein said element comprises a hydrophobically modified polymer (i) and a fabric benefit agent (II), a ratio of 1: 50 to 99: 1 parts by weight, preferably 1 : 40 to 95: 1 parts by weight.
11.根据权利要求9-10中的任一项所述的包装制剂,其中,所述元件包含具有选自以下的骨架的疏水改性聚合物:聚乙烯醇、聚乙酸乙烯酯、纤维素醚类、聚环氧乙烷、淀粉、聚乙烯吡咯烷酮、聚丙烯酰胺、聚乙烯甲基醚-马来酸酐、聚马来酸酐、苯乙烯马来酸酐、羟乙基纤维素、甲基纤维素、聚乙二醇类、羧甲基纤维素、聚丙烯酸盐类、藻酸盐类、丙烯酰胺共聚物类、瓜尔胶、酪蛋白、乙烯-马来酸酐树脂系列、聚乙烯亚胺、乙基羟乙基纤维素、乙基甲基纤维素、羟乙基甲基纤维素及其单体的共聚物。 Packaging of the formulation according to any one of 9-10 claims, wherein said element comprises a hydrophobically modified polymer having a backbone selected from: polyvinyl alcohol, polyvinyl acetate, cellulose ethers , polyethylene oxide, starch, polyvinylpyrrolidone, polyacrylamide, polyvinyl methyl ether - maleic anhydride, polymaleic anhydride, styrene maleic anhydride, hydroxyethylcellulose, methylcellulose, polyethylene glycols, carboxymethylcellulose, polyacrylic acid salts, alginates, acrylamide copolymers, guar gum, casein, ethylene - maleic anhydride resin series, polyethyleneimine, ethyl hydroxyethyl cellulose, methyl ethyl cellulose, hydroxyethyl cellulose and a copolymer of monomer.
12.根据任一项前述权利要求所述的包装制剂,其中,所述元件包含基质材料(i)和织物有益剂(ii),其比率为1 : 50至99 : 1重量份,优选为1 : 40至95 : 1重量份。 12. The packaged formulation according to any preceding claim, wherein said element comprises a matrix material (i) and a fabric benefit agent (II), a ratio of 1: 50 to 99: 1 parts by weight, preferably 1 : 40 to 95: 1 parts by weight.
13.根据任一项前述权利要求所述的包装制剂,其包含0. 05至10重量%的所述元件和2至70重量%、优选10至30重量%的表面活性剂。 13. A packaged formulation according to any preceding claim, comprising from 0.05 to 10% by weight of the element and from 2 to 70% by weight, preferably 10 to 30% by weight of a surfactant.
14.根据任一项前述权利要求所述的包装制剂,其中,所述元件包含选自游离的香料、 包封的香料、香料前体、漂白剂及其前体、酶、荧光增白剂、抗微生物剂及其两种或多种的任意组合的有益剂。 14. A packaged formulation according to any one of the preceding claims, wherein the element is selected from the group comprising free perfume, encapsulated perfumes, flavor precursors, and bleach precursors, enzymes, optical brighteners, antimicrobial agents, and beneficial combination of two or more of any.
15. 一种制造权利要求1-14中的任一项所述的包含水溶性的视觉指示物和表面活性剂的包装制剂的方法,所述方法包括以下步骤:(a)提供本文定义的疏水改性聚合物和织物有益剂的水性混合物;(b)干燥水性混合物以从水性混合物除去全部或部分的水,以形成片材;(c)由片材以需要的形状和/或大小形成元件;和(d)任选地,进一步干燥元件;(e)将元件分散在液体或凝胶的包含表面活性剂的组合物中;和(f)包装所述分散体系。 The method of packaging of the formulation and the visual indicator comprises a water soluble surface active agent 15. A manufacture according to any of 1-14 claims, the method comprising the steps of: (a) providing a hydrophobic defined herein the aqueous mixture of modified polymer and a fabric benefit agent; (b) drying the aqueous mixture to the aqueous mixture to remove all or part of the water, to form a sheet; shape and / or size of a sheet to desired (c) forming element ; and (d) optionally, further dried component; (e) an element dispersed in a liquid or gel composition comprising a surface active agent; and (f) packaging the dispersion.
16.根据权利要求1所述的包含表面活性剂的包装制剂,其包含水溶性的视觉指示物, 其中:a)含有表面活性剂的制剂是可倾倒的液体洗涤剂组合物,包含:i)0. 05至10重量%的形成视觉指示物的元件,和ii) 2至70重量%、优选10至30重量%的选自阴离子表面活性剂、非离子表面活性剂、 阳离子表面活性剂或其混合物的表面活性剂;b)所述包装是至少部分透明的;c)所述视觉指示物包括多个分散物质的片状元件,其中:i)所述元件的平面测量的平均直径与元件的厚度比率大于5 : 1,优选大于8 : 1 ;ii)所述元件的平均直径为1-lOmm,优选3-6mm ;iii)所述元件的平均厚度为100-2000微米,优选200-500微米;和iv)任选地,所述视觉指示物的元件包含有益剂,更优选包含选自香料和/或香料前体的有益剂,最优选包含包封的或载体吸附的香料和/或香料前体。 16. The package comprises a surfactant formulation according to claim 1, comprising a water soluble visual indicator, wherein: a) a surfactant formulation containing pourable liquid detergent composition comprising: i) element is 0.05 to 10 wt% is formed of a visual indicator, and ii) 2 to 70 wt%, preferably 10 to 30% by weight of the selected anionic surfactant, a nonionic surfactant, a cationic surfactant or surfactant mixture; b) the package is at least partially transparent; c) the visual indication comprises a plurality of sheet-like elements dispersible material, wherein: i) the mean diameter of the element measured in the plane of the element the thickness ratio is greater than 5: 1, preferably greater than 8: 1; average diameter ii) the element is a 1-lOmm, preferably 3-6mm; average thickness iii) the element 100 to 2000 microns, preferably 200-500 microns ; and iv) optionally, said visual indicator member comprises a beneficial agent, more preferably selected from a perfume benefit agent and / or perfume precursors, most preferably encapsulated or adsorbed perfume carrier and / or perfume precursors.
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