CN102343135A - Selenium-containing Chinese medicinal pesticide residue scavenger - Google Patents
Selenium-containing Chinese medicinal pesticide residue scavenger Download PDFInfo
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- CN102343135A CN102343135A CN2011102252639A CN201110225263A CN102343135A CN 102343135 A CN102343135 A CN 102343135A CN 2011102252639 A CN2011102252639 A CN 2011102252639A CN 201110225263 A CN201110225263 A CN 201110225263A CN 102343135 A CN102343135 A CN 102343135A
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- selenium
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- scavenger
- pesticide residue
- chinese medicinal
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- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 15
- 239000011669 selenium Substances 0.000 title claims abstract description 15
- 239000002516 radical scavenger Substances 0.000 title abstract description 24
- 239000000447 pesticide residue Substances 0.000 title abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000007516 Chrysanthemum Nutrition 0.000 claims abstract description 7
- 240000002853 Nelumbo nucifera Species 0.000 claims abstract description 7
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims abstract description 7
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims abstract description 7
- 240000001949 Taraxacum officinale Species 0.000 claims abstract description 7
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 238000000227 grinding Methods 0.000 claims abstract description 7
- 244000189548 Chrysanthemum x morifolium Species 0.000 claims abstract description 3
- 240000007164 Salvia officinalis Species 0.000 claims abstract description 3
- 241000205585 Aquilegia canadensis Species 0.000 claims abstract 2
- 150000003342 selenium Chemical class 0.000 claims description 16
- 241000411851 herbal medicine Species 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 229940091258 selenium supplement Drugs 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 244000157790 Buglossoides arvense Species 0.000 claims description 6
- 235000004256 Buglossoides arvense Nutrition 0.000 claims description 6
- 241001499733 Plantago asiatica Species 0.000 claims description 6
- RNGFNLJMTFPHBS-UHFFFAOYSA-L dipotassium;selenite Chemical group [K+].[K+].[O-][Se]([O-])=O RNGFNLJMTFPHBS-UHFFFAOYSA-L 0.000 claims description 5
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 claims description 3
- 229960001471 sodium selenite Drugs 0.000 claims description 3
- 235000015921 sodium selenite Nutrition 0.000 claims description 3
- 239000011781 sodium selenite Substances 0.000 claims description 3
- 235000005412 red sage Nutrition 0.000 claims description 2
- 239000000047 product Substances 0.000 abstract description 14
- 239000000843 powder Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 4
- 241000130781 Arnebia Species 0.000 abstract 1
- 235000003805 Musa ABB Group Nutrition 0.000 abstract 1
- 240000008790 Musa x paradisiaca Species 0.000 abstract 1
- 235000015266 Plantago major Nutrition 0.000 abstract 1
- 235000017276 Salvia Nutrition 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 description 18
- 239000003905 agrochemical Substances 0.000 description 16
- 241000196324 Embryophyta Species 0.000 description 9
- 235000013305 food Nutrition 0.000 description 5
- 235000021393 food security Nutrition 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- 241000723353 Chrysanthemum Species 0.000 description 4
- 241000245240 Lonicera Species 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 4
- 235000002020 sage Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000005946 Cypermethrin Substances 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- 229960005424 cypermethrin Drugs 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 208000019901 Anxiety disease Diseases 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 230000036506 anxiety Effects 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 231100000957 no side effect Toxicity 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001570521 Lonicera periclymenum Species 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- FJUJRXCRSJWOSA-UHFFFAOYSA-N NC(=O)N.N1=CC=CC=C1.[F] Chemical compound NC(=O)N.N1=CC=CC=C1.[F] FJUJRXCRSJWOSA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 231100000570 acute poisoning Toxicity 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- HKPHPIREJKHECO-UHFFFAOYSA-N butachlor Chemical compound CCCCOCN(C(=O)CCl)C1=C(CC)C=CC=C1CC HKPHPIREJKHECO-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000144 pharmacologic effect Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to pesticide residue scavenger, in particular to a selenium-containing Chinese medicinal pesticide residue scavenger. The selenium-containing Chinese medicinal pesticide residue scavenger is characterized by being prepared by the following steps of: grinding 5-15 parts by weight of lotus leaf, 5-15 parts by weight of root of red-rooted salvia, 40-60 parts of chrysanthemum, 40-60 parts of sinkiang arnebia root, 40-60 parts of honeysuckle flower, 40-60 parts of dandelion and 40-60 parts of plantain herb into powder; putting the powder into hot water of which the temperature is 60-70 DEG C and which is 10-15 times the amount of the powder, and stirring for 14-16 hours; filtering; and adding 0.2-0.5 part of selenium into the filtrate to obtain a finished product. The Chinese medicinal materials for the scavenger are easy to buy; and the scavenger has low cost, is convenient to prepare and use, and is an environmentally-friendly pesticide residue scavenger.
Description
Technical field
The invention belongs to pesticide residue scavenging agent, particularly a kind ofly contain the agent of selenium Farm chemical of Chinese berbs residue removal.
Background technology
Reform and open up to the outside world over 30 years, the protection to environment has been ignored in a lot of areas by China in rapid economic development.The a large amount of blowdowns of industrial and mining enterprises; Automobile pollution sharply increases; Cause the environment such as water source, atmosphere, soil in China town and country to receive pollution in various degree; Developed area particularly, the infringement that the farmland receives is the most serious, and crops are declined to a great extent because of heavy metals exceeding standard and the residual quality that exceeds standard of agricultural chemicals medicine.Environment and food pollution have threatened numerous residents' health.On the one hand, to the undue dependence of agricultural chemicals, the abuse of antibiotic, hormone causes China crops, poultry, fowl, egg, the interior hazard residue material of aquatic products body significantly to increase in the agricultural production.On the other hand, according to the Heilungkiang investigation of 2010.10 months, because global climate warms gradually, the originally non-existent insect pest in grain-producing area, China northeast has also occurred like rice-stem borer unexpectedly.The original no pesticide variety of the cereal crops in motherland silo northeast also must not be out of use in the future.The agricultural chemicals use lack of standardization of various places agricultural sector worry causes seriously reducing quality of agricultural product, influences the healthy of China's sustainable development of agriculture and vast urban and rural residents.
The alarm bell of food security is beaten! The outstanding problem that grain, fruit, the vegetables of selling in the market all exist residues of pesticides, heavy metal and harmful element to exceed standard largely, a succession of food acute poisoning incident, the life that has jeopardized people is with healthy! Caused showing great attention to of society, national top leader is weighed down with anxieties for this reason." bread is the staff of life, and food is with An Weixian ", reducing and eliminating residues of pesticides has become the new trend of China's agricultural sound development, the new expectation of compatriots' food security.After country's " food security method " promulgation; The consciousness of food security is rooted in the hearts of the people, " bread is the staff of life, and food is with An Weixian "; People call " nuisanceless ", " green ", " organic " food can really put on dining table " eat relievedly, afford to eat ".Concerning agricultural production enterprise, residues of pesticides and heavy metal pollution problem are the most important things of food security work in the elimination agricultural product.This is a global problem, and each state has all dropped into great amount of manpower, financial resources and scientific research technical force and attempted to solve this difficult problem.
Summary of the invention
Goal of the invention
The present invention adopts Chinese herbal medicine formula to combine selenium salt, and it is superior that residues of pesticides are removed effect, can effectively solve the difficult problem of residues of pesticides.
Technical scheme
Contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with lotus leaf 5-15 part; Red sage root 5-15 part, chrysanthemum 40-60 part, Asian puccoon 40-60 part, honeysuckle 40-60 part; Dandelion 40-60 part, Asiatic plantain 40-60 part is a powdery with the said herbal medicine crushing grinding, gets it and places hot water of 60-70 ℃ that 10-15 doubly measures to soak and stirred 14-16 hour; After filtering, filtrating adds selenium salt 0.2-0.5 part, finished product.
Described finished product is regulated pH7-8.
Selenium salt is potassium selenite or sodium selenite
Beneficial effect
1,Contain selenium salt among the present invention, the present invention is sprayed on the crop blade face, selenium gets into plant cell rapidly in the photosynthesis of plants process; Special physiological through the irritation cell protease-producing strain is active; Quicken the rejection function of cell, quicken aging, the fracture of agricultural chemicals (high-molecular hydrocarbons) strand simultaneously, make agricultural chemicals change structure in the short period of time and lose toxicity; Resolve into natural basic element carbon and hydrogen, remove the harm of residues of pesticides the mankind.The present invention's residual mechanism of farming of degrading is the process that physiological action after plant cell activates promotes physical and chemical effect.What this process embodied is the stechiology principle.And raw materials used inorganic selenium salt and the natural traditional Chinese medicine of being do not contain any chemical composition, so be not chemical principle, can not produce in " derivative " behind the chemical reaction.See that from practice through repetition test, the present invention mixes with agricultural chemicals under different time, variable concentrations state; Do not produce degradation mutually, thus normally bring into play under the situation of drug effect not influencing agricultural chemicals, through technical finesse of the present invention; Get final product thorough degrading pesticide residues, and do not have the anxiety of secondary pollution.Selenium salt combines Chinese herbal medicine, to vegetables, and cereal crops, tealeaves, it is all effective that fruit is removed residues of pesticides.
,This pesticide residue scavenging agent is sprayed directly on the crops in the growth, can remove the persticide residue that remains on the crops fast and efficiently, and the persticide residue after it is removed is lower than the limit standard of national regulation; Simultaneously; This pesticide residue scavenging agent not only can be removed efficiently, fast and be sprayed at the residues of pesticides with the different agricultural chemicals on a kind of crops; And can remove the residues of pesticides that are sprayed at the different agricultural chemicals on the different crops efficiently, fast, prove its removing of residues of pesticides with wide spectrum effect; And find that through range estimation the plant leaf surface that high concentration agricultural chemical sprayed after 3 days is yellow, the blade face of plant returns to the blue look after spraying this pesticide residue scavenging agent, shows that this scavenger to plant safety, has no side effect; In addition, the Chinese herbal medicine material of this scavenger is prone to purchase, and is with low cost, and preparation, easy to use is green, the environmental protection scavenger of crops residues of pesticides.
The specific embodiment
Embodiment 1
Contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with 5 parts on lotus leaf; 5 parts of the reds sage root, 40 parts of chrysanthemums, 40 parts of Asian puccoons, 40 parts of honeysuckles; 40 parts of dandelions, 40 parts of Asiatic plantains are powdery with the said herbal medicine crushing grinding, get its hot water that places 60 ℃ of 10 times of amounts and soak and stirred 14 hours; After filtering, filtrating adds 0.2 part of selenium salt, finished product.Described finished product is regulated pH7.Selenium salt is potassium selenite
Embodiment 2
Contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with 10 parts on lotus leaf; 15 parts of the reds sage root, 60 parts of chrysanthemums, 60 parts of Asian puccoons, 60 parts of honeysuckles; 60 parts of dandelions, 60 parts of Asiatic plantains are powdery with the said herbal medicine crushing grinding, get its hot water that places 70 ℃ of 15 times of amounts and soak and stirred 16 hours; After filtering, filtrating adds 0.5 part of selenium salt, finished product.Described finished product is regulated pH8.Selenium salt is sodium selenite.
Embodiment 3
Contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with 7 parts on lotus leaf; 10 parts of the reds sage root, 50 parts of chrysanthemums, 50 parts of Asian puccoons, 50 parts of honeysuckles; 50 parts of dandelions, 50 parts of Asiatic plantains are powdery with the said herbal medicine crushing grinding, get its hot water that places 65 ℃ of 12 times of amounts and soak and stirred 15 hours; After filtering, filtrating adds 0.4 part of selenium salt, finished product.Described finished product is regulated pH7.2.Selenium salt is potassium selenite.
Embodiment 4
Contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with 12 parts on lotus leaf; 12 parts of the reds sage root, 33 parts of chrysanthemums, 44 parts of Asian puccoons, 53 parts of honeysuckles; 47 parts of dandelions, 45 parts of Asiatic plantains are powdery with the said herbal medicine crushing grinding, get its hot water that places 67 ℃ of 13 times of amounts and soak and stirred 15 hours; After filtering, filtrating adds 0.3 part of selenium salt, finished product.Described finished product is regulated pH7.5.Selenium salt is potassium selenite.
Embodiment 5
Pesticide residue scavenging agent of the present invention; According to the pharmacological function of Chinese herbal medicine, through combination and reasonably collocation, the creationary pesticide residue scavenging agent that is applied on the crops of developing that Chinese herbal medicine is carried out science; Utilize the growth mechanism of crops itself; After it is absorbed, produce and have the function of detoxifcation, toxin expelling, realize the purpose that residues of pesticides are removed.Through testing: on same crops, spray different agricultural chemicals respectively and different meal with wine crops are sprayed different agricultural chemicals; After 3 days, embodiment 1-4 is directly sprayed this pesticide residue scavenging agent by the dosage of 50kg/ mu, gather censorship after 3 days; It removes effect such as following table 1: the Detecting Pesticide method is with reference to national standard (GT/T5009.145-2003; GT/T5009.20-2003, GT/T20769-2006, GB/T5009.12-2003).
Table 1 testing result
| Studied thing | The name of spraying insecticide | Spray agricultural chemicals embodiment 1-4 of the present invention (mg/kg) | Do not spray pesticide residue scavenging agent of the present invention (mg/kg) |
| Paddy rice | Cypermethrin | Do not detect | 1.3 |
| ? | 666 powder | Do not detect | 0.15 |
| ? | Acetochlor | Do not detect | 0.17 |
| ? | Acephatemet | Do not detect | 0.37 |
| Mango | Carbendazim | Do not detect | 2.1 |
| ? | 666 powder | Do not detect | 0.15 |
| ? | Butachlor | Do not detect | 0.16 |
| ? | Acephatemet | Do not detect | 0.31 |
| Tea | Cypermethrin | Do not detect | 1.5 |
| ? | 666 powder | Do not detect | 0.57 |
| ? | Fluorine pyridine urea | Do not detect | 0.49 |
| ? | Acephatemet | Do not detect | 1.7 |
| Chinese cabbage | Cypermethrin | Do not detect | 0.67 |
| ? | Doractin | Do not detect | 0.57 |
| ? | 666 powder | Do not detect | 0.25 |
| ? | Acephatemet | Do not detect | 0.47 |
Above-mentioned test data shows: this pesticide residue scavenging agent is sprayed directly on the crops in the growth, can remove the persticide residue that remains on the crops fast and efficiently, and the persticide residue after it is removed is lower than the limit standard of national regulation; Simultaneously; This pesticide residue scavenging agent not only can be removed efficiently, fast and be sprayed at the residues of pesticides with the different agricultural chemicals on a kind of crops; And can remove the residues of pesticides that are sprayed at the different agricultural chemicals on the different crops efficiently, fast, prove its removing of residues of pesticides with wide spectrum effect; And find that through range estimation the plant leaf surface that high concentration agricultural chemical sprayed after 3 days is yellow, the blade face of plant returns to the blue look after spraying this pesticide residue scavenging agent, shows that this scavenger to plant safety, has no side effect; In addition, the Chinese herbal medicine material of this scavenger is prone to purchase, and is with low cost, and preparation, easy to use is green, the environmental protection scavenger of crops residues of pesticides.
Claims (3)
1. contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that being prepared from following steps, by weight, with lotus leaf 5-15 part; Red sage root 5-15 part, chrysanthemum 40-60 part, Asian puccoon 40-60 part, honeysuckle 40-60 part; Dandelion 40-60 part, Asiatic plantain 40-60 part is a powdery with the said herbal medicine crushing grinding, gets it and places hot water of 60-70 ℃ that 10-15 doubly measures to soak and stirred 14-16 hour; After filtering, filtrating adds selenium salt 0.2-0.5 part, finished product.
2. according to claim 1ly contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that described finished product regulates pH7-8.
3. according to claim 1ly contain the agent of selenium Farm chemical of Chinese berbs residue removal, it is characterized in that selenium salt is potassium selenite or sodium selenite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110225263 CN102343135B (en) | 2011-08-08 | 2011-08-08 | Selenium-containing Chinese medicinal pesticide residue scavenger |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110225263 CN102343135B (en) | 2011-08-08 | 2011-08-08 | Selenium-containing Chinese medicinal pesticide residue scavenger |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102343135A true CN102343135A (en) | 2012-02-08 |
| CN102343135B CN102343135B (en) | 2013-05-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110225263 Expired - Fee Related CN102343135B (en) | 2011-08-08 | 2011-08-08 | Selenium-containing Chinese medicinal pesticide residue scavenger |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102343135B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103650817A (en) * | 2012-09-24 | 2014-03-26 | 江苏浩波农业科技开发有限公司 | Method for removing pesticide residues and decreasing heavy metal content in agricultural products |
| CN106190611A (en) * | 2016-07-16 | 2016-12-07 | 襄汾县科农种植专业合作社 | A kind of pesticide residue scavenging agent |
| CN110465040A (en) * | 2019-09-05 | 2019-11-19 | 刘长美 | A kind of degradation agent and its preparation and application of farm-forestry crop pesticide residue of degrading |
| CN111264521A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN111264522A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101229419A (en) * | 2008-02-27 | 2008-07-30 | 武兴战 | Chinese medicinal herb peiticide residue degradant and preparing method thereof |
| CN101597191A (en) * | 2008-06-06 | 2009-12-09 | 孔宪中 | The compound selenium fertilizer of a kind of energy deteriorating pesticide residue and heavy metal |
-
2011
- 2011-08-08 CN CN 201110225263 patent/CN102343135B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101229419A (en) * | 2008-02-27 | 2008-07-30 | 武兴战 | Chinese medicinal herb peiticide residue degradant and preparing method thereof |
| CN101597191A (en) * | 2008-06-06 | 2009-12-09 | 孔宪中 | The compound selenium fertilizer of a kind of energy deteriorating pesticide residue and heavy metal |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103650817A (en) * | 2012-09-24 | 2014-03-26 | 江苏浩波农业科技开发有限公司 | Method for removing pesticide residues and decreasing heavy metal content in agricultural products |
| CN106190611A (en) * | 2016-07-16 | 2016-12-07 | 襄汾县科农种植专业合作社 | A kind of pesticide residue scavenging agent |
| CN111264521A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN111264522A (en) * | 2018-12-05 | 2020-06-12 | 北京康为天生物科技有限公司 | Pesticide residue remover and preparation method and application thereof |
| CN110465040A (en) * | 2019-09-05 | 2019-11-19 | 刘长美 | A kind of degradation agent and its preparation and application of farm-forestry crop pesticide residue of degrading |
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| Publication number | Publication date |
|---|---|
| CN102343135B (en) | 2013-05-08 |
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