CN102284245A - Method for treating waste gas by biotrickling filter, and special device thereof - Google Patents

Method for treating waste gas by biotrickling filter, and special device thereof Download PDF

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CN102284245A
CN102284245A CN201110159408XA CN201110159408A CN102284245A CN 102284245 A CN102284245 A CN 102284245A CN 201110159408X A CN201110159408X A CN 201110159408XA CN 201110159408 A CN201110159408 A CN 201110159408A CN 102284245 A CN102284245 A CN 102284245A
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nutrient solution
biological
tower
storage tank
biological treatment
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陈建孟
陈东之
房俊逸
钱东升
王家德
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Zhejiang University of Technology
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Abstract

本发明公开了一种以生物滴滤塔处理废气的方法:将废气从生物滴滤塔底部通入,经过生物滴滤塔处理,处理好的废气从顶部排出,所述的生物滴滤塔由设有废气进口的塔底、塔身、安装有尾气出口的塔顶组成,所述的塔身由若干个生物处理单元至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层,所述的液体隔层上布置有供相邻层气连通的通气口,每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的生物填料层、营养液接收池;本发明提高了单位填料处理负荷;改善了填料层堵塞问题,避免了沟流现象的出现,气液接触均匀、充分;填料更换及反冲洗更加方便;该工艺经济,适应复杂的挥发性有机混合污染物的净化处理。The invention discloses a method for treating waste gas with a biological trickling filter tower: the waste gas is passed through the bottom of the biological trickling filter tower, treated by the biological trickling filter tower, and the treated waste gas is discharged from the top, and the biological trickling filter tower is composed of The bottom of the tower with exhaust gas inlet, the tower body, and the top of the tower equipped with exhaust gas outlet are composed. The tower body is composed of several biological treatment units stacked from bottom to top, and the biological treatment units on adjacent layers are arranged There is a liquid interlayer, and the air vents for the adjacent layers are arranged on the liquid interlayer, and each layer of biological treatment units is independently equipped with a nutrient solution spray system and a temperature control device from top to bottom. Biological packing layer and nutrient solution receiving pool; the invention increases the processing load of the unit packing; improves the plugging problem of the packing layer, avoids the occurrence of channeling phenomenon, and has uniform and sufficient gas-liquid contact; packing replacement and backwashing are more convenient; the process Economical, suitable for the purification treatment of complex volatile organic mixed pollutants.

Description

一种以生物滴滤塔处理废气的方法及其专用装置A method for treating waste gas with a biological trickling filter tower and its special device

(一)技术领域(1) Technical field

本发明涉及一种环境工程中废气净化方法及装置,特别涉及一种以生物滴滤塔处理废气的方法及其专用装置。The invention relates to a method and a device for purifying waste gas in environmental engineering, in particular to a method for treating waste gas with a biological trickling filter tower and a special device thereof.

(二)背景技术(2) Background technology

众多工业化生产过程中不可避免地产生大量废气,这些废气不宜回收利用,通常含有多组分有毒有害的有机物和无机物,对人体和环境产生危害,造成大气污染。Many industrial production processes inevitably produce a large amount of waste gas. These waste gases are not suitable for recycling. They usually contain multi-component toxic and harmful organic and inorganic substances, which are harmful to human body and environment, and cause air pollution.

目前用于废气控制的技术较多,常用的几种技术主要有燃烧法、吸附法、化学吸收法和生物法等,其中生物法与其他传统的处理方法相比,具备投资少、运行费用低、无二次污染等优点,尤其在处理低浓度、生物降解性好的气态污染物时更显其经济性。在处理低浓度的有机气体和臭气时,生物法的一次性投资是燃烧法的1/3、吸附法的1/8~1/5、化学吸收法1/3;运行费用是燃烧法的1/20、吸附法的1/10、化学吸收法的1/15。因此该方法正在成为一项在废气污染控制领域迅速推广的高新技术。At present, there are many technologies used for waste gas control. The commonly used technologies mainly include combustion method, adsorption method, chemical absorption method and biological method. Compared with other traditional treatment methods, biological method has less investment and lower operating cost. , No secondary pollution and other advantages, especially in the treatment of gaseous pollutants with low concentration and good biodegradability, it is more economical. When dealing with low-concentration organic gases and odors, the one-time investment of the biological method is 1/3 of the combustion method, 1/8-1/5 of the adsorption method, and 1/3 of the chemical absorption method; the operating cost is that of the combustion method. 1/20, 1/10 of the adsorption method, and 1/15 of the chemical absorption method. Therefore, this method is becoming a high-tech that is rapidly promoted in the field of waste gas pollution control.

生物法处理废气时通常采用固定化微生物过滤废气的工艺,其装置主要使用滤塔的形式。工程实践及研究表明,这些滤塔存在五个方面的缺陷:①由于滤塔内现有用于微生物固定化的载体为有机或无机填料,传质效果较差,容易引起短路,实际运行中需要经常搅动填料或更换填料,处理效果较差且不利于滤塔的设备化生产;②表面负荷、质量负荷较小,因此去除能力和去除率也较小;③生物负荷较小;④抗高浓度有毒污染物性能较差;⑤滤塔的结构设计使空塔停留时间较短,影响去除能力和去除率。通过实践表明,生物滴滤塔在使用过程中存在的主要问题是塔体内布水、布气及pH控制不均,死亡微生物堆积引起填料堵塞。Biological treatment of waste gas usually uses immobilized microorganisms to filter waste gas, and its devices mainly use the form of filter towers. Engineering practice and research show that these filter towers have defects in five aspects: ①Because the existing carrier used for microorganism immobilization in the filter tower is organic or inorganic filler, the mass transfer effect is poor and it is easy to cause short circuit. Agitating the packing or replacing the packing, the treatment effect is poor and it is not conducive to the equipment production of the filter tower; ②The surface load and mass load are small, so the removal capacity and removal rate are also small; ③The biological load is small; ④Resistance to high concentration and poisonous The performance of pollutants is poor; ⑤The structural design of the filter tower makes the empty tower residence time shorter, which affects the removal capacity and removal rate. Practice has shown that the main problems in the use of biological trickling filter towers are uneven water distribution, gas distribution and pH control in the tower, and the accumulation of dead microorganisms causes packing blockage.

针对上述问题,本发明所述的生物滴滤塔处理工业废气,分别控制各填料层中营养液pH值及各填料层营养液喷淋量,每个塔体单元中营养液喷淋量可根据污染处理负荷灵活控制,每个塔体单元中营养液pH值可根据污染物处理的种类及去除的先后顺序分层控制,对生物净化的工程实践具有重要意义。In view of the above problems, the biological trickling filter tower of the present invention treats industrial waste gas, respectively controls the pH value of the nutrient solution in each packing layer and the spraying amount of the nutrient solution in each packing layer, and the spraying amount of the nutrient solution in each tower body unit can be according to The pollution treatment load can be flexibly controlled, and the pH value of the nutrient solution in each tower unit can be controlled hierarchically according to the type of pollutant treatment and the sequence of removal, which is of great significance to the engineering practice of biological purification.

(三)发明内容(3) Contents of the invention

本发明目的是提供一种以生物滴滤塔处理废气的方法及其专用装置,该处理方法及装置采用分层喷淋营养液,分层控制pH值,高效,经济。The object of the present invention is to provide a method and a special device for treating waste gas with a biological trickling filter tower. The treatment method and device adopt layered spraying of nutrient solution, layered control of pH value, high efficiency and economy.

本发明采用的技术方案是:The technical scheme adopted in the present invention is:

一种以生物滴滤塔处理废气的方法,所述的方法是将废气从生物滴滤塔底部通入,经过生物滴滤塔处理,处理好的废气从顶部排出,所述的生物滴滤塔由设有废气进口的塔底、塔身、安装有尾气出口的塔顶组成,所述的塔身由若干个生物处理单元至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层,所述的液体隔层上布置有供相邻层气连通的通气口,每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的生物填料层、营养液接收池,所述的生物填料层上喷洒有活性污泥与营养液,所述的营养液喷淋系统由安装在生物处理单元顶部的喷洒器,安装在营养液接收池底部的营养液输出管,设在生物滴塔外部的营养液储罐、电磁计量泵、营养液输入管、喷洒器、pH自动控制系统、蠕动泵、氢氧化钠储液罐连接组成;所述的营养液储罐承接所述的营养液输出管,所述的营养液储罐、电磁计量泵、营养液输入管、喷洒器依次相接,所述的pH自动控制系统通过蠕动泵分别与营养液储罐和氢氧化钠储液罐连接,pH自动控制系统还设有与营养液储罐接通的pH计探头;所述的各生物处理单元的营养液的pH不同,所述的各生物处理单元的pH自动控制系统设定的pH值不同。A method for treating waste gas with a biological trickling filter tower, the method is to pass the waste gas from the bottom of the biological trickling filter tower, and after being treated by the biological trickling filter tower, the treated waste gas is discharged from the top. The biological trickling filter tower It consists of the bottom of the tower with exhaust gas inlet, the tower body, and the top of the tower with exhaust gas outlet. The tower body is composed of several biological treatment units stacked from bottom to top. There is a liquid interlayer, and the air vents for the adjacent layers are arranged on the liquid interlayer. Each layer of biological treatment units is independently equipped with a nutrient solution spray system and a temperature control device from top to bottom. The biological filler layer and the nutrient solution receiving tank, the biological filler layer is sprayed with activated sludge and nutrient solution, and the nutrient solution spray system is installed on the nutrient solution receiving tank by a sprayer installed on the top of the biological treatment unit The nutrient solution output pipe at the bottom of the pool is connected to the nutrient solution storage tank outside the biological drop tower, electromagnetic metering pump, nutrient solution input pipe, sprinkler, pH automatic control system, peristaltic pump, and sodium hydroxide liquid storage tank; The nutrient solution storage tank is connected to the nutrient solution output pipe, the nutrient solution storage tank, the electromagnetic metering pump, the nutrient solution input pipe, and the sprinkler are connected in sequence, and the pH automatic control system is connected with the nutrient solution through the peristaltic pump respectively. The nutrient solution storage tank is connected with the sodium hydroxide storage tank, and the pH automatic control system is also provided with a pH meter probe connected with the nutrient solution storage tank; the pH of the nutrient solution of each of the biological treatment units is different, and each of the described The pH value set by the pH automatic control system of the biological treatment unit is different.

所述的塔身由三个生物处理单元至下而上叠置安装组成,至下而上所述的pH自动控制系统设定的pH值分别是2~3、4~5、6~7。The tower body is composed of three biological treatment units stacked and installed from bottom to top, and the pH values set by the pH automatic control system from bottom to top are 2-3, 4-5, 6-7 respectively.

所述的生物填料层中的填料为聚氨酯小球;所述填料孔隙率大、强度高、易于挂膜,填料尺寸为13~16mm,堆积密度和真密度分别为138.9kg·m-3和1588.2kg·m-3。The filler in the biological filler layer is polyurethane pellets; the filler has large porosity, high strength, and is easy to form a film. The size of the filler is 13-16mm, and the bulk density and true density are 138.9kg·m -3 and 1588.2 kg·m -3 .

所述的生物填料层层厚与塔径比为0.8~2.0∶1,最优选1.4∶1。The ratio of the thickness of the biological filler layer to the tower diameter is 0.8-2.0:1, most preferably 1.4:1.

所述的设有温控装置的生物填料层温度控制在30℃。The temperature of the biological filler layer equipped with a temperature control device is controlled at 30°C.

一种本发明所述的废气处理方法的专用装置,所述的装置为生物滴滤塔,所述的生物滴滤塔由塔底、塔身、塔顶组成,所述的塔底设有废气进口,所述的塔顶安装有尾气出口;所述的塔身由若干个生物处理单元至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层,所述的液体隔层上布置有供相邻层气连通的通气口,每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的可承载活性污泥与营养液的生物填料层、营养液接收池,所述的营养液喷淋系统由安装在生物处理单元顶部的喷洒器,安装在营养液接收池底部的营养液输出管,设在生物滴塔外部的营养液储罐、电磁计量泵、营养液输入管、喷洒器、pH自动控制系统、蠕动泵、氢氧化钠储液罐连接组成;所述的营养液储罐承接所述的营养液输出管,所述的营养液储罐、电磁计量泵、营养液输入管、喷洒器依次相接,所述的pH自动控制系统通过蠕动泵分别与营养液储罐和氢氧化钠储液罐连接,pH自动控制系统还设有与营养液储罐接通的pH计探头,所述的尾气出口设有与氢氧化钠尾气吸收罐的通管。A special device for the waste gas treatment method of the present invention, the device is a biological trickling filter tower, the biological trickling filter tower is composed of a tower bottom, a tower body, and a tower top, and the waste gas filter is provided at the bottom of the tower Inlet, the top of the tower is equipped with a tail gas outlet; the tower body is composed of several biological treatment units stacked from bottom to top, and a liquid interlayer is arranged between the biological treatment units of adjacent layers. The liquid compartment is provided with air vents for adjacent layers to communicate with each other, and each layer of biological treatment units is independently equipped with a nutrient solution spray system from top to bottom, and equipped with a temperature control device that can carry activated sludge and nutrient solution. The biological filler layer and the nutrient solution receiving tank, the nutrient solution spraying system consists of a sprinkler installed on the top of the biological treatment unit, a nutrient solution output pipe installed at the bottom of the nutrient solution receiving tank, and a nutrient solution installed outside the biological drop tower Liquid storage tank, electromagnetic metering pump, nutrient solution input pipe, sprinkler, pH automatic control system, peristaltic pump, sodium hydroxide liquid storage tank connected; the nutrient solution storage tank undertakes the nutrient solution output pipe, the The nutrient solution storage tank, the electromagnetic metering pump, the nutrient solution input pipe, and the sprinkler are connected in sequence, and the pH automatic control system is connected with the nutrient solution storage tank and the sodium hydroxide storage tank respectively through a peristaltic pump, and the pH is automatically controlled. The system is also provided with a pH meter probe connected to the nutrient solution storage tank, and the tail gas outlet is provided with a through pipe connected to the sodium hydroxide tail gas absorption tank.

本发明所述的废气处理方法专用装置中,所述的通气口为布置在液体隔层上的带有顶帽的管状突起,所述的管状突起的顶部连接有底面大于管状突起的顶帽,所述的顶帽与管状突起通过留有空隙的栅栏连接,所述的空隙位于所述营养液接收池预设液面的上方。In the special device for waste gas treatment method according to the present invention, the vent is a tubular protrusion with a top cap arranged on the liquid compartment, and the top of the tubular protrusion is connected with a top cap whose bottom surface is larger than the tubular protrusion, The top cap is connected to the tubular protrusion through a barrier with a gap, and the gap is located above the preset liquid level of the nutrient solution receiving pool.

进一步,所述的专用装置中,所述的顶帽为锥形。Further, in the special device, the top cap is conical.

进一步,所述的带有顶帽的管状突起有若干个,呈放射状均匀布置在液体隔层上。Further, there are several tubular protrusions with a top cap, which are uniformly arranged radially on the liquid compartment.

进一步,所述的专用装置,所述的塔身由三个生物处理单元至下而上叠置安装组成。Further, in the special device, the tower body is composed of three biological treatment units stacked and installed from bottom to top.

本发明所述的以生物滴滤塔处理废气的方法的专用装置由多层生物处理单元构成一个整体,每个生物处理单元可以单独控制pH值和营养液喷淋量,适用于能被微生物降解的污染物,对多组分的混合废气尤其适用。The special device for the method of treating waste gas with a biological trickling filter tower according to the present invention is composed of multi-layer biological treatment units as a whole, and each biological treatment unit can independently control the pH value and the spraying amount of nutrient solution, and is suitable for use in biodegradable It is especially suitable for multi-component mixed exhaust gas.

与现有技术相比,本发明的有益效果主要体现在:(1)本发明以生物滴滤塔处理废气的方法,处理废气的专用装置由若干个生物处理单元至下而上叠置安装组成,每个生物处理单元中营养液强度可依据处理负荷单独控制,提高了单位填料处理负荷;改善了填料层堵塞问题,避免了沟流现象的出现,气液接触均匀、充分;(2)采用单独生物处理单元结构,填料更换及反冲洗更加方便;(3)采用单独的pH自动控制系统能够获得不同pH值条件下的高效降解菌,稳定营养液pH需要投入的碱液量降低,该工艺更为经济,并且能适应复杂的挥发性有机混合污染物的净化处理。Compared with the prior art, the beneficial effects of the present invention are mainly reflected in: (1) The present invention uses a biological trickling filter tower to treat waste gas, and the special device for treating waste gas consists of several biological treatment units stacked and installed from bottom to top , the strength of the nutrient solution in each biological treatment unit can be individually controlled according to the processing load, which increases the processing load of the unit packing; improves the plugging problem of the packing layer, avoids the occurrence of channel flow, and the gas-liquid contact is uniform and sufficient; (2) adopts Separate biological treatment unit structure makes packing replacement and backwashing more convenient; (3) the use of a separate pH automatic control system can obtain highly efficient degrading bacteria under different pH conditions, and the amount of alkali solution required to stabilize the pH of the nutrient solution is reduced. It is more economical and can adapt to the purification treatment of complex volatile organic mixed pollutants.

(四)附图说明(4) Description of drawings

图1生物滴滤塔废气净化系统:1、废气进口,2、塔体,3、排气口,4、填料取样口,5、气体采样口,6、电磁计量泵,7、pH计探头,8、营养液接收池,9、pH自动控制系统,10、蠕动泵,11、氢氧化钠储液罐,12、氢氧化钠尾气吸收罐,13、尾气排放口14、液体隔层,15、挡板结构,16、生物填料层,17、喷洒器,18、营养液输入管,19、营养液输出管,20、通管,21、生物处理单元;Figure 1 The exhaust gas purification system of the biological trickling filter tower: 1. Waste gas inlet, 2. Tower body, 3. Exhaust port, 4. Packing sampling port, 5. Gas sampling port, 6. Electromagnetic metering pump, 7. pH meter probe, 8. Nutrient solution receiving pool, 9. pH automatic control system, 10. Peristaltic pump, 11. Sodium hydroxide liquid storage tank, 12. Sodium hydroxide tail gas absorption tank, 13. Tail gas discharge port 14. Liquid compartment, 15. Baffle structure, 16, biological filler layer, 17, sprinkler, 18, nutrient solution input pipe, 19, nutrient solution output pipe, 20, through pipe, 21, biological treatment unit;

图2挡板结构图:22、管状突起,23、通气口,24、顶帽,25、栅栏;Fig. 2 baffle structure diagram: 22, tubular protrusion, 23, air vent, 24, top cap, 25, fence;

图3生物滴滤塔废气净化系统净化硫化氢的性能考察;Fig. 3 Investigation of the performance of hydrogen sulfide purification by the exhaust gas purification system of the biological trickling filter;

图4生物滴滤塔废气净化系统长期净化硫化氢时各层去除负荷变化情况;Fig. 4 The change of the removal load of each layer when the exhaust gas purification system of the biological trickling filter purifies hydrogen sulfide for a long time;

图5生物滴滤塔废气净化系统净化甲硫醚的性能考察;Fig. 5 The performance investigation of purifying dimethyl sulfide by the exhaust gas purification system of the biological trickling filter;

图6生物滴滤塔废气净化系统净化四氢呋喃的性能考察;Fig. 6 Performance investigation of purifying tetrahydrofuran by the exhaust gas purification system of the biological trickling filter;

(五)具体实施方法(5) Specific implementation methods

下面结合具体实施例对本发明进行进一步描述,但本发明的保护范围并不仅限于此:The present invention is further described below in conjunction with specific embodiment, but protection scope of the present invention is not limited thereto:

实施例1Example 1

以含有硫化氢、甲硫醚、四氢呋喃的混合废气来模拟要处理的废气,以本发明所述的生物滴滤塔处理废气,所述的生物滴滤塔塔体2由塔底、塔身、塔顶组成,所述的塔底设有废气进口1,所述的塔顶安装有尾气排气口3;所述的塔身由若干个生物处理单元21至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层14,所述的液体隔层上布置有供相邻层气连通的通气口23,所述的通气口为布置在液体隔层上的带有锥形顶帽的管状突起22,所述的管状突起的顶部连接有底面大于管状突起的锥形顶帽24,所述的顶帽与管状突起通过留有空隙的栅栏25连接,所述的空隙位于所述营养液接收池预设液面的上方,所述的带有顶帽的管状突起有15个,均匀布置在液体隔层上。每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的可承载活性污泥与营养液的生物填料层16、营养液接收池8,所述的营养液喷淋系统由安装在生物处理单元顶部的喷洒器17,安装在营养液接收池底部的营养液输出管19,设在生物滴塔外部的电磁计量泵6、营养液输入管18、pH自动控制系统9、蠕动泵10、氢氧化钠储液罐11连接组成;所述的营养液接收池8承接所述的营养液输出管19,所述的营养液接收池8、电磁计量泵6、营养液输入管18、喷洒器17依次相接,所述的pH自动控制系统9通过蠕动泵10分别与营养液接收池8和氢氧化钠储液罐11连接,pH自动控制系统9还设有与营养液接收池8接通的pH计探头7,所述的尾气排气口3设有与氢氧化钠尾气吸收罐12的通管20,氢氧化钠尾气吸收罐12设有尾气排放口13,如图1和图2所示。The waste gas to be treated is simulated with the mixed waste gas containing hydrogen sulfide, methyl sulfide, and tetrahydrofuran, and the waste gas is treated with the biological trickling filter tower according to the present invention. The tower body 2 of the biological trickling filter tower consists of a tower bottom, a tower body, The tower top is composed of a waste gas inlet 1 at the bottom of the tower, and an exhaust gas outlet 3 is installed at the top of the tower; the tower body is composed of a plurality of biological treatment units 21 stacked from bottom to top. A liquid interlayer 14 is arranged between the biological treatment units of adjacent layers, and a vent 23 for adjacent layers to communicate with each other is arranged on the liquid interlayer, and the vent is arranged on the liquid interlayer with a The tubular protrusion 22 of the conical top cap, the top of the tubular protrusion is connected with the conical top cap 24 whose bottom surface is larger than the tubular protrusion, and the top cap and the tubular protrusion are connected by a barrier 25 with a gap, the gap Located above the preset liquid level of the nutrient solution receiving pool, there are 15 tubular protrusions with top caps, which are evenly arranged on the liquid compartment. Each layer of biological treatment unit is independently provided with a nutrient solution spray system from top to bottom, a biological filler layer 16 that can carry activated sludge and nutrient solution with a temperature control device, and a nutrient solution receiving pool 8. The liquid spray system consists of a sprinkler 17 installed on the top of the biological treatment unit, a nutrient solution output pipe 19 installed at the bottom of the nutrient solution receiving tank, an electromagnetic metering pump 6 outside the biological drop tower, a nutrient solution input pipe 18, and a pH automatic The control system 9, the peristaltic pump 10, and the sodium hydroxide liquid storage tank 11 are connected to form; the nutrient solution receiving pool 8 is connected to the nutrient solution output pipe 19, and the nutrient solution receiving pool 8, the electromagnetic metering pump 6, Nutrient solution input pipe 18 and sprinkler 17 are connected successively, and described pH automatic control system 9 is respectively connected with nutrient solution receiving pool 8 and sodium hydroxide liquid storage tank 11 by peristaltic pump 10, and pH automatic control system 9 is also provided with The pH meter probe 7 that is connected with the nutrient solution receiving pool 8, the tail gas exhaust port 3 is provided with the through pipe 20 with the sodium hydroxide tail gas absorption tank 12, and the sodium hydroxide tail gas absorption tank 12 is provided with the tail gas discharge port 13 , as shown in Figure 1 and Figure 2.

所述生物滴滤塔系统启动时,先对填料浸泡24h后装入塔内,对其进行气液循环以获得生物填料。生物滴滤塔由上、中、下三层生物处理单元组成,塔体内径为140mm,每层生物处理单元中生物填料层厚度为200mm,营养液与硫化氢、甲硫醚、四氢呋喃混合废气呈错流式接触,营养液喷淋量控制一样,即喷淋量为100mL·min-1,上、中、下三层生物处理单元pH分别控制为6.5、4.5、2.5;上层生物处理单元生物填料层中微生物优势菌为杆菌,中层微生物优势菌为杆菌兼丝状菌,下层微生物优势菌为丝状菌;所述的空床气速为0.02~0.004m3·s-1、空床停留时间为14~28s、营养液温度为30℃的条件下,废气由废气进口通入生物滴滤塔内,处理后的清洁气体有尾气排放口排出。When the biotrickling filter tower system is started, the filler is soaked for 24 hours before being loaded into the tower, and the gas-liquid circulation is carried out on it to obtain the biological filler. The biological trickling filter tower is composed of upper, middle and lower biological treatment units. The inner diameter of the tower is 140mm. The thickness of the biological filler layer in each biological treatment unit is 200mm. For cross-flow contact, the nutrient solution spray volume is controlled the same, that is, the spray volume is 100mL·min -1 , and the pH of the upper, middle, and lower biological treatment units is controlled to 6.5, 4.5, and 2.5 respectively; the biological filler of the upper biological treatment unit The dominant microorganisms in the layer are bacilli, the dominant microorganisms in the middle layer are bacilli and filamentous bacteria, and the dominant microorganisms in the lower layer are filamentous bacteria; the air velocity in the empty bed is 0.02~0.004m 3 ·s -1 Under the conditions of 14-28s and nutrient solution temperature of 30°C, the waste gas is passed into the biological trickling filter tower from the waste gas inlet, and the treated clean gas is discharged from the tail gas discharge port.

生物滴滤塔对硫化氢去除率的变化情况如图3所示。挂膜启动初期(进口硫化氢浓度维持在50mg·m-3),生物滴滤塔对硫化氢没有显著的净化效果。第5d,硫化氢去除率逐渐升高,第8d的去除率达到92.3%。此后尽管提高进口硫化氢浓度,而生物滴滤塔系统仍能维持较高的净化性能。第14d,当硫化氢浓度为94.3mg·m-3、停留时间(EBRT)为28s时,生物滴滤塔对硫化氢的去除率达到100%。这说明填料上已附着较多的硫化氢降解菌,生物滴滤塔系统的挂膜启动已经基本完成。此后虽然逐步提高硫化氢浓度至250mg·m-3并缩短EBRT为17s,但去除率一直稳定在100%。The change of the hydrogen sulfide removal rate of the biological trickling filter tower is shown in Figure 3. In the initial stage of membrane-hanging start-up (imported hydrogen sulfide concentration is maintained at 50mg·m -3 ), the biological trickling filter has no significant purification effect on hydrogen sulfide. On the 5th day, the removal rate of hydrogen sulfide gradually increased, and the removal rate reached 92.3% on the 8th day. Since then, despite the increase in the concentration of imported hydrogen sulfide, the biotrickling filter system can still maintain a high purification performance. On the 14th day, when the concentration of hydrogen sulfide was 94.3mg·m -3 and the residence time (EBRT) was 28s, the removal rate of hydrogen sulfide by the biological trickling filter reached 100%. This shows that more hydrogen sulfide-degrading bacteria have been attached to the filler, and the film-hanging start-up of the biological trickling filter system has been basically completed. Since then, although the hydrogen sulfide concentration was gradually increased to 250mg·m -3 and the EBRT was shortened to 17s, the removal rate remained stable at 100%.

生物滴滤塔对甲硫醚去除率的变化情况如图5所示,挂膜启动初期(进口甲硫醚浓度维持在10mg·m-3),生物滴滤塔对甲硫醚没有显著的净化效果,第6d,甲硫醚去除率逐渐升高,第8d的去除率达到66.7%。此后逐步提高进口甲硫醚浓度,生物滴滤塔的去除率也逐渐升高。第17d,当甲硫醚浓度为25.9mg·m-3、EBRT为28s时,生物滴滤塔对甲硫醚的去除率达到100%。这说明填料上已附着较多的甲硫醚降解菌,生物滴滤塔的挂膜启动已经基本完成。此后逐步提高甲硫醚浓度至50mg·m-3并缩短EBRT为17s,虽然去除率有所下降,但去除率基本稳定在90%。The change of the removal rate of dimethyl sulfide by the biological trickling filter is shown in Figure 5. At the initial stage of film formation (the concentration of imported dimethyl sulfide is maintained at 10 mg·m -3 ), the biological trickling filter has no significant purification of dimethyl sulfide Effect, on the 6th day, the removal rate of methyl sulfide gradually increased, and the removal rate reached 66.7% on the 8th day. Since then, the concentration of imported methyl sulfide has been gradually increased, and the removal rate of the biological trickling filter has also gradually increased. On the 17th day, when the concentration of dimethyl sulfide was 25.9mg·m -3 and the EBRT was 28s, the removal rate of dimethyl sulfide in the biological trickling filter reached 100%. This shows that there are more methyl sulfide degrading bacteria attached to the filler, and the start-up of the biotrickling filter tower has been basically completed. After that, the concentration of dimethyl sulfide was gradually increased to 50mg·m -3 and the EBRT was shortened to 17s. Although the removal rate decreased, the removal rate was basically stable at 90%.

生物滴滤塔对四氢呋喃去除率的变化情况如图6所示,挂膜启动初期(进口四氢呋喃浓度维持在10mg·m-3左右),去除率变化不明显。生物滴滤塔从第7天开始去除率明显升高,第11天达到100%,这表明填料内四氢呋喃降解菌数量增多,生物膜逐渐形成。为了确定生物膜生长是否成熟,分别在第13天提高生物滴滤塔进口浓度至20mg·m-3,其去除率逐渐升高并稳定在80%左右,;当浓度再提高到50mg·m-3左右时,去除率也一直维持在81%左右(去除负荷维持不变),这说明生物滴滤塔的挂膜启动基本完成。The change of the removal rate of THF by the biological trickling filter is shown in Figure 6. In the initial stage of film formation (the concentration of imported THF was maintained at about 10 mg·m -3 ), the removal rate did not change significantly. The removal rate of the bio-trickling filter increased significantly from the 7th day, and reached 100% on the 11th day, which indicated that the number of THF-degrading bacteria in the filler increased and the biofilm gradually formed. In order to determine whether the biofilm growth is mature, the concentration at the inlet of the biotrickling filter was increased to 20mg·m -3 on the 13th day, and the removal rate gradually increased and stabilized at about 80%; when the concentration was increased to 50mg·m -3 At about 3 , the removal rate has been maintained at about 81% (removal load remains unchanged), which shows that the start-up of the biotrickling filter is basically completed.

实施例2Example 2

生物滴滤塔结构及实验操作同实施例1,反应器挂膜完成后,进气口硫化氢浓度250~300mg·m-3、EBRT为14s的条件下,考察生物滴滤塔废气净化系统对硫化氢气体的净化情况,结果如图3所示,可以看出硫化氢浓度250mg·m-3、EBRT为14s时硫化氢去除率始终维持在100%;当突然提高硫化氢浓度至300mg·m-3时,硫化氢去除率稳定在99.9%以上,表明生物滴滤塔系统对硫化氢有较好且稳定的去除效果。The structure and experimental operation of the biological trickling filter tower are the same as those in Example 1. After the film coating in the reactor is completed, the hydrogen sulfide concentration at the inlet is 250-300 mg·m -3 , and the EBRT is 14s. The results of hydrogen sulfide gas purification are shown in Figure 3. It can be seen that when the hydrogen sulfide concentration is 250mg·m -3 and the EBRT is 14s, the hydrogen sulfide removal rate is always maintained at 100%; when the hydrogen sulfide concentration is suddenly increased to 300mg·m When -3 , the hydrogen sulfide removal rate is stable above 99.9%, indicating that the biological trickling filter system has a good and stable removal effect on hydrogen sulfide.

由图4可见,当EBRT为14s时,进入生物滴滤塔系统中的硫化氢主要在下层和中层填料层被去除,上层填料层的去除负荷较小。上层填料层对硫化氢去除负荷的贡献逐渐增加;随着反应器的持续运行,下层和中层填料层的去除负荷逐步提高,两填料层对硫化氢的净化贡献占90%以上。在进口浓度相当的条件下,EBRT直接决定了硫化氢的进气负荷。综上所述,各层填料层对硫化氢的去除贡献随着进气负荷的波动而变化。It can be seen from Figure 4 that when the EBRT is 14s, the hydrogen sulfide entering the biotrickling filter system is mainly removed in the lower and middle packing layers, and the removal load of the upper packing layer is small. The contribution of the upper packing layer to the hydrogen sulfide removal load gradually increased; with the continuous operation of the reactor, the removal load of the lower and middle packing layers gradually increased, and the two packing layers accounted for more than 90% of the hydrogen sulfide purification contribution. Under the condition of equal inlet concentration, EBRT directly determines the intake load of hydrogen sulfide. To sum up, the contribution of each packing layer to the removal of hydrogen sulfide varies with the fluctuation of the intake load.

反应器挂膜完成后,考察生物滴滤塔系统在进口甲硫醚浓度10~100mg·m-3依次提高、EBRT为14s的条件下的运行情况,结果如图5所示。当进口浓度为60mg·m-3左右、EBRT为14s时,甲硫醚去除率始终维持在90%;当突然提高浓度至70mg·m-3以上时,甲硫醚去除率稳定在90%以上。对于甲硫醚的去除,中层填料层的贡献较大,能达到60%左右,下层及上层填料层的贡献相当。随着进气负荷的变化,各层对去除率的贡献也有相应的变化。After the film coating in the reactor was completed, the operation of the biotrickling filter system was investigated under the condition that the concentration of dimethyl sulfide at the inlet was increased sequentially from 10 to 100 mg·m -3 and the EBRT was 14s. The results are shown in Figure 5. When the inlet concentration is about 60mg·m -3 and the EBRT is 14s, the removal rate of dimethyl sulfide is always maintained at 90%; when the concentration is suddenly increased to above 70mg·m -3 , the removal rate of dimethyl sulfide is stable above 90% . For the removal of dimethyl sulfide, the contribution of the middle packing layer is relatively large, which can reach about 60%, and the contribution of the lower packing layer and the upper packing layer is equal. As the intake load changes, the contribution of each layer to the removal rate also changes accordingly.

反应器挂膜完成后,考察生物滴滤塔系统中四氢呋喃去除负荷、去除率随进口浓度的变化情况,四氢呋喃进口浓度为10~80mg·m-3依次提高,如图6所示。当进口浓度较低(40mg·m-3以下)时,生物滴滤塔系统对四氢呋喃的去除效率可以达到95%,去除负荷随着进口浓度的增大而增大。进口浓度进一步提高至50mg·m-3后,去除率逐渐变小,生物滴滤塔系统对四氢呋喃的去除能力不再增加,而是维持在一个固定值(60%左右),此时生物滴滤塔系统的降解性能达到最大值。对于四氢呋喃的去除,下层填料层的去除效果不理想,四氢呋喃主要在上层填料层被去除,中层填料层也体现了一定的去除效果(10~20%)。After the completion of film coating in the reactor, the change of THF removal load and removal rate with the inlet concentration in the biotrickling filter system was investigated. The inlet concentration of THF increased sequentially from 10 to 80 mg·m -3 , as shown in Figure 6. When the inlet concentration is low (below 40mg·m -3 ), the removal efficiency of THF in the biotrickling filter system can reach 95%, and the removal load increases with the increase of the inlet concentration. After the inlet concentration was further increased to 50 mg·m -3 , the removal rate gradually decreased, and the removal capacity of the biotrickling filter tower system for THF no longer increased, but remained at a fixed value (about 60%). At this time, the biotrickling filter The degradation performance of the tower system reaches a maximum. For the removal of THF, the removal effect of the lower packing layer is not ideal, THF is mainly removed in the upper packing layer, and the middle packing layer also shows a certain removal effect (10-20%).

生物滴滤塔系统启动时,微生物处于挂膜阶段,生物滴滤塔中总体压降很小,随着挂膜过程的完成以及进入稳定运行状态后总压降慢慢增加后也趋于稳定。由于各层填料层对于废气去除率的贡献不同,微生物生长情况也不同,导致各层的压降也不相同,可以看出下层填料层的压降最大,中层填料层次之,上层填料层最小。When the bio-trickling filter system is started, the microorganisms are in the film-hanging stage, and the overall pressure drop in the bio-trickling filter tower is very small. After the completion of the film-hanging process and entering a stable operating state, the total pressure drop gradually increases and then tends to be stable. Due to the different contributions of each layer of packing layer to the exhaust gas removal rate, the growth of microorganisms is also different, resulting in different pressure drops in each layer. It can be seen that the pressure drop of the lower packing layer is the largest, the middle packing layer is the smallest, and the upper packing layer is the smallest.

Claims (10)

1.一种以生物滴滤塔处理废气的方法,其特征在于所述的方法是将废气从生物滴滤塔底部通入,经过生物滴滤塔处理,处理好的废气从顶部排出,所述的生物滴滤塔由设有废气进口的塔底、塔身、安装有尾气出口的塔顶组成,所述的塔身由若干个生物处理单元至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层,所述的液体隔层上布置有供相邻层气连通的通气口,每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的生物填料层、营养液接收池,所述的生物填料层上喷洒有活性污泥与营养液,所述的营养液喷淋系统由安装在生物处理单元顶部的喷洒器,安装在营养液接收池底部的营养液输出管,设在生物滴塔外部的营养液储罐、电磁计量泵、营养液输入管、pH自动控制系统、蠕动泵、氢氧化钠储液罐连接组成;所述的营养液储罐承接所述的营养液输出管,所述的营养液储罐、电磁计量泵、营养液输入管、喷洒器依次相接,所述的pH自动控制系统通过蠕动泵分别与营养液储罐和氢氧化钠储液罐连接,pH自动控制系统还设有与营养液储罐接通的pH计探头;所述的各生物处理单元的营养液的pH不同,所述的各生物处理单元的pH自动控制系统设定的pH值不同。1. A method for treating waste gas with a biological trickling filter, characterized in that the method is that the waste gas is passed into from the bottom of the biological trickling filter, and through the treatment of the biological trickling filter, the treated waste gas is discharged from the top. The biological trickling filter tower consists of a tower bottom with a waste gas inlet, a tower body, and a tower top with an exhaust gas outlet. The tower body is composed of several biological treatment units stacked from bottom to top. A liquid interlayer is arranged between the biological treatment units, and the air vents for adjacent layers are arranged on the liquid interlayer, and each layer of biological treatment units is independently provided with a nutrient solution spray system from top to bottom, A biological filler layer and a nutrient solution receiving pool provided with a temperature control device, activated sludge and nutrient solution are sprayed on the biological filler layer, and the nutrient solution spray system consists of a sprinkler installed on the top of the biological treatment unit, The nutrient solution output pipe installed at the bottom of the nutrient solution receiving tank, the nutrient solution storage tank located outside the biological drop tower, the electromagnetic metering pump, the nutrient solution input pipe, the pH automatic control system, the peristaltic pump, and the sodium hydroxide liquid storage tank are connected. The nutrient solution storage tank is connected to the nutrient solution output pipe, the nutrient solution storage tank, the electromagnetic metering pump, the nutrient solution input pipe, and the sprinkler are connected successively, and the pH automatic control system is connected by a peristaltic pump Connect with the nutrient solution storage tank and the sodium hydroxide storage tank respectively, the pH automatic control system is also provided with the pH meter probe that is connected with the nutrient solution storage tank; The pH of the nutrient solution of each described biological treatment unit is different, the described The pH values set by the pH automatic control system of each biological treatment unit are different. 2.如权利要求1所述的方法,其特征在于所述的塔身由三个生物处理单元至下而上叠置安装组成,至下而上所述的pH自动控制系统设定的pH值分别是2~3、4~5、6~7。2. The method according to claim 1, characterized in that the tower body is composed of three biological treatment units stacked from bottom to top, and the pH value set by the pH automatic control system from bottom to top They are 2~3, 4~5, 6~7 respectively. 3.如权利要求1所述的方法,其特征在于所述的生物填料层中的填料为聚氨酯小球;填料直径为13~16mm,堆积密度和真密度分别为138.9kg·m-3和1588.2kg·m-3。3. The method according to claim 1, characterized in that the filler in the biological filler layer is polyurethane pellets; the diameter of the filler is 13-16mm, and the bulk density and true density are respectively 138.9kg·m -3 and 1588.2 kg·m -3 . 4.如权利要求1所述的方法,其特征在于所述的生物填料层层厚与塔径比为0.8~2.0∶1。4. The method according to claim 1, characterized in that the ratio of the thickness of the biological filler layer to the tower diameter is 0.8 to 2.0:1. 5.如权利要求1所述的方法,所述的设有温控装置的生物填料层温度控制在30℃。5. The method according to claim 1, wherein the temperature of the biological filler layer provided with a temperature control device is controlled at 30°C. 6.一种如权利要求1所述的废气处理方法的专用装置,其特征在于所述的装置为生物滴滤塔,所述的生物滴滤塔由塔底、塔身、塔顶组成,所述的塔底设有废气进口,所述的塔顶安装有尾气出口;所述的塔身由若干个生物处理单元至下而上叠置安装组成,相邻层的生物处理单元之间设有液体隔层,所述的液体隔层上布置有供相邻层气连通的通气口,每层生物处理单元都各自独立地至上而下设有营养液喷淋系统、设有温控装置的可承载活性污泥与营养液的生物填料层、营养液接收池,所述的营养液喷淋系统由安装在生物处理单元顶部的喷洒器,安装在营养液接收池底部的营养液输出管,设在生物滴塔外部的营养液储罐、电磁计量泵、营养液输入管、pH自动控制系统、蠕动泵、氢氧化钠储液罐连接组成;所述的营养液储罐承接所述的营养液输出管,所述的营养液储罐、电磁计量泵、营养液输入管、喷洒器依次相接,所述的pH自动控制系统通过蠕动泵分别与营养液储罐和氢氧化钠储液罐连接,pH自动控制系统还设有与营养液储罐接通的pH计探头,所述的尾气出口设有与氢氧化钠尾气吸收罐的通管。6. A special device for waste gas treatment method as claimed in claim 1, characterized in that said device is a biological trickling filter tower, and said biological trickling filter tower is composed of a tower bottom, a tower body and a tower top, and said The bottom of the tower is provided with an exhaust gas inlet, and the top of the tower is equipped with an exhaust gas outlet; the tower body is composed of several biological treatment units stacked from bottom to top, and the biological treatment units of adjacent layers are provided with Liquid interlayer, the liquid interlayer is provided with air vents for adjacent layers to communicate with each other, and each layer of biological treatment units is independently equipped with a nutrient solution spray system from top to bottom, and a temperature control device that can The biological packing layer and the nutrient solution receiving tank carrying activated sludge and nutrient solution, the nutrient solution spraying system is composed of a sprinkler installed on the top of the biological treatment unit, and a nutrient solution output pipe installed at the bottom of the nutrient solution receiving tank. The nutrient solution storage tank, electromagnetic metering pump, nutrient solution input pipe, pH automatic control system, peristaltic pump, and sodium hydroxide storage tank connected outside the biological drop tower are composed; the nutrient solution storage tank undertakes the described nutrient solution The output pipe, the nutrient solution storage tank, the electromagnetic metering pump, the nutrient solution input pipe, and the sprayer are connected successively, and the described pH automatic control system is respectively connected with the nutrient solution storage tank and the sodium hydroxide storage tank through a peristaltic pump , the pH automatic control system is also provided with a pH meter probe connected with the nutrient solution storage tank, and the exhaust gas outlet is provided with a through pipe connected with the sodium hydroxide tail gas absorption tank. 7.如权利要求6所述的专用装置,其特征在于所述的通气口为布置在液体隔层上的带有顶帽的管状突起,所述的管状突起的顶部连接有底面大于管状突起的顶帽,所述的顶帽与管状突起通过留有空隙的栅栏连接,所述的空隙位于所述营养液接收池预设液面的上方。7. The special device according to claim 6, characterized in that the vent is a tubular protrusion with a top cap arranged on the liquid barrier, and the top of the tubular protrusion is connected with a bottom surface larger than the tubular protrusion. A top cap, the top cap is connected to the tubular protrusion through a barrier with a gap, and the gap is located above the preset liquid level of the nutrient solution receiving pool. 8.如权利要求7所述的专用装置,其特征在于所述的顶帽为锥形。8. The special device according to claim 7, characterized in that said top cap is conical. 9.如权利要求7所述的专用装置,其特征在于所述的带有顶帽的管状突起有若干个,呈均匀布置在液体隔层上。9. The special device according to claim 7, characterized in that there are several tubular protrusions with top caps, which are evenly arranged on the liquid barrier. 10.如权利要求6所述的专用装置,其特征在于所述的塔身由三个生物处理单元至下而上叠置安装组成。10. The special device according to claim 6, characterized in that the tower body is composed of three biological treatment units stacked and installed from bottom to top.
CN201110159408XA 2011-06-14 2011-06-14 Method for treating waste gas by biotrickling filter, and special device thereof Pending CN102284245A (en)

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