CN102268840B - Decorative paper used for floor or furniture - Google Patents
Decorative paper used for floor or furniture Download PDFInfo
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- CN102268840B CN102268840B CN 201110200386 CN201110200386A CN102268840B CN 102268840 B CN102268840 B CN 102268840B CN 201110200386 CN201110200386 CN 201110200386 CN 201110200386 A CN201110200386 A CN 201110200386A CN 102268840 B CN102268840 B CN 102268840B
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- antimildew
- antibacterial
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Abstract
The invention relates to decorative paper used for veneering indoor floor or furniture. According to the decorative paper used for floor or furniture, the back face of raw paper is provided with a mildew-proof antibacterial layer, and the mildew-proof antibacterial layer is formed by drying a mildew-proof antibacterial complex liquid photogravured on the back face of the raw paper. The mildew-proof antibacterial complex liquid comprises the following components by mass percentage: deionized water, alcohol, propylene glycol methyl ether, a thickening agent, an antibacterial agent CMIT(Chloromethylisothiazolinone) or MIT (Methylisothiazolinone), a bacteriacide BIT (Benzisothiazolinone), a mildew-proof agent OIT (Ocyl-isothiazolinone) and a pH regulating agent, and the pH value of the mildew-proof antibacterial complex liquid is 8.0-8.3. The decorative paper used for floor or furniture has the advantage of good mildew-proof and antibacterial effects.
Description
Technical field
The present invention relates to a kind of indoor floor and furniture surfacing facing paper.
Background technology
The facing paper industry is flourishing at present, is rooted in the hearts of the people for the idea of wood with paper.The facing paper that existing floor and furniture surfacing are used is mainly double-layer structure, namely is made of the printing ink on body paper and front, and during use, the body paper back side is pressed together on substrate, and substrate is mainly wood base board or fiberboard.General gravure printing ink all can contain mould inhibitor, but the effect of these mould inhibitors is all in order to extend the holding time of printing ink, not prevent the effect that body paper is mouldy.The deficiency that existing facing paper exists is that facing paper uses easy mouldy breed bacteria after a period of time, and mouldy breed bacteria often all begins from inside to outside, and namely the very easily mouldy breed bacteria in the back side of body paper and baseplate-laminating causes the whole mouldy breed bacteria of facing paper.
Summary of the invention
Order of the present invention is in order to solve existing floor or furniture facing paper above shortcomings, to provide a kind of antimildew and antibacterial effective facing paper.
In order to realize above-mentioned goal of the invention, the present invention has adopted following technical scheme:
A kind of floor or furniture facing paper, the body paper back side are provided with the antimildew and antibacterial layer, and the antimildew and antibacterial layer is formed in the antimildew and antibacterial complex liquid oven dry on the body paper back side by intaglio printing; Described antimildew and antibacterial complex liquid comprises following component by mass percentage: deionized water 85-90%, ethanol 2-4%, propylene glycol monomethyl ether 3-7%, thickener 1.5-5.5%, antiseptic CMIT or antiseptic MIT 0.1-0.4%, bactericide BIT 0.1-0.4%, mould inhibitor OIT 0.1-0.4%, pH value conditioning agent 0.1-0.5%; The pH value of above-mentioned antimildew and antibacterial complex liquid is between 8.0-8.3.
As preferably, the viscosity of described antimildew and antibacterial complex liquid is between 20-24S, and the antimildew and antibacterial complex liquid of above-mentioned viscosity is conducive to be printed on body paper fast most.
As preferably, described antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 85-90%, ethanol 2-4%, propylene glycol monomethyl ether 3-7%, thickener 1.5-5.5%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.1-0.5%.Adopt antiseptic CMIT or the antiseptic MIT of aforementioned proportion, the antimildew and antibacterial film antimildew and antibacterial effect that bactericide BIT and mould inhibitor OIT make is very good.
Further, described antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 87.7%, ethanol 3%, propylene glycol monomethyl ether 5%, thickener 3.5%, antiseptic CMIT or antiseptic MIT0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.The antimildew and antibacterial film antimildew and antibacterial best results of making of said components ratio.
Further, described bactericide BIT is BIT; Mould inhibitor OIT is N-octyl group isothiazolinone; Antiseptic CMIT is CMIT; Antiseptic MIT is MIT; Thickener is ROHM AND HAAS thickener TT-935; The pH value conditioning agent is a kind of in AMP-95, CP-800, ammoniacal liquor, sodium carbonate, sodium bicarbonate.
As preferably, described antimildew and antibacterial complex liquid is printed on the back side of body paper with the full version of the print speed printing speed of 100-120m/min, can guarantee that the antimildew and antibacterial complex liquid is located on the back side of body paper uniformly, make all position antimildew and antibacterial effects at the back side of body paper good equally.
As preferably, described antimildew and antibacterial complex liquid forms the antimildew and antibacterial film by oven for drying, and oven temperature is between 150-160 ℃, and temperature is poor lower than 150 ℃ of film-formation results, temperature is higher than 160 ℃ of performances that can affect each component, the antimildew and antibacterial effect of the antimildew and antibacterial film of reduction.
As preferably, described body paper is the titanium white fibrous paper.
Adopted a kind of floor or the furniture facing paper of technique scheme, the body paper back side is provided with the antimildew and antibacterial layer, and the antimildew and antibacterial layer is formed in the antimildew and antibacterial complex liquid oven dry on the body paper back side by intaglio printing.Deionized water in the antimildew and antibacterial complex liquid has guaranteed the degree of purity of antimildew and antibacterial complex liquid, ethanol and propylene glycol monomethyl ether help the rapid draing of antimildew and antibacterial complex liquid, especially propylene glycol monomethyl ether is because the little easy volatilization of specific heat, more be conducive to drying, by the PH conditioning agent, pH value is adjusted to and namely be alkalescence between 8.0-8.3, be convenient to the viscosity that thickener is adjusted the antimildew and antibacterial complex liquid.The antimildew and antibacterial effect that has guaranteed the antimildew and antibacterial complex liquid is used in the mixing of antiseptic CMIT or antiseptic MIT, bactericide BIT and mould inhibitor OIT.This floor or furniture have added antimildew and antibacterial characteristic at the back side of body paper with facing paper in the process of producing, not only the antimildew and antibacterial effect is more obvious, and make facing paper all keep the function of antimildew and antibacterial in long-term use procedure, solved the mouldy situation that obtains of breed bacteria that traditional body paper begins from inside to outside.In sum, this floor or furniture are that antimildew and antibacterial is effective with the advantage of facing paper.
The specific embodiment
Embodiment 1
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 87.7%, ethanol 3%, propylene glycol monomethyl ether 5%, thickener 3.5%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.The pH value of antimildew and antibacterial complex liquid is between 8.0-8.3, and the viscosity of antimildew and antibacterial complex liquid is between 20-24S.
Above-mentioned bactericide BIT is BIT; Mould inhibitor OIT is N-octyl group isothiazolinone; Antiseptic CMIT is CMIT; Antiseptic MIT is MIT; The pH value conditioning agent is AMP-95; Thickener is ROHM AND HAAS thickener TT-935.The pH value conditioning agent can be also a kind of in CP-800, ammoniacal liquor, sodium carbonate, sodium bicarbonate.
During production, first deionized water, ethanol, propylene glycol monomethyl ether, thickener, antiseptic CMIT or MIT, bactericide BIT, the mould inhibitor OIT with above-mentioned mass ratio is hybridly prepared into combination solution at normal temperatures, with pH value conditioning agent AMP-95, the PH of above-mentioned combination solution is adjusted between 8.0-8.3 again, because be not that alkaline solution just is not easy to carry out next step thickening.Add association thickener in combination solution, Shanghai ROHM AND HAAS thickener TT-935 specifically, the combination solution viscosity is adjusted between 20-24S, measure by being coated with four glasss of instruments, then be printed on the back side of body paper with the full version of the print speed printing speed of 100-120m/min, dry by drying tunnel at last and form the antimildew and antibacterial layer, temperature is between 150-160 ℃, expire on edition back side that is printed on body paper and can guarantee that the antimildew and antibacterial complex liquid is located on the back side of body paper uniformly, make all position antimildew and antibacterial effects of the back side of body paper good equally, and working (machining) efficiency is also high.Body paper is the titanium white fibrous paper.
The floor that said method is made or furniture draw following microbiological data after testing with the facing paper back side: aspergillus flavus, 0 grade of mildew-resistant grade; Penicillium citrinum, 0 grade of mildew-resistant grade; Chaetomium globosum, 0 grade of mildew-resistant grade; Trichoderma viride, 0 grade of mildew-resistant grade; The short boundary of teething, 0 grade of mildew-resistant grade; La Yeya branch bacterium, 0 grade of mildew-resistant grade; Paecilomyces varioti, 0 grade of mildew-resistant grade.Be that each bacterioid and micro organism quantity do not detect.
Antimildew and antibacterial grade national standard is divided into level Four, and 0 grade is that best surfaces is without bacterium or microorganism.One-level is taken second place, in addition by that analogy.
Embodiment 2
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.Except the formula of antimildew and antibacterial complex liquid was different from embodiment 1, other was all identical with embodiment 1.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 85%, ethanol 4%, propylene glycol monomethyl ether 7%, thickener 3.2%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
The floor of making or furniture draw following microbiological data after testing with the facing paper back side: aspergillus flavus, 0 grade of mildew-resistant grade; Penicillium citrinum, 0 grade of mildew-resistant grade; Chaetomium globosum, 0 grade of mildew-resistant grade; Trichoderma viride, 0 grade of mildew-resistant grade; The short boundary of teething, 0 grade of mildew-resistant grade; La Yeya branch bacterium, 0 grade of mildew-resistant grade; Paecilomyces varioti, 0 grade of mildew-resistant grade.Be that each bacterioid and micro organism quantity do not detect.
Embodiment 3
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.Except the formula of antimildew and antibacterial complex liquid was different from embodiment 1, other was all identical with embodiment 1.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 90%, ethanol 3%, propylene glycol monomethyl ether 4%, thickener 2.2%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
The floor of making or furniture draw following microbiological data after testing with the facing paper back side: aspergillus flavus, 0 grade of mildew-resistant grade; Penicillium citrinum, 0 grade of mildew-resistant grade; Chaetomium globosum, 0 grade of mildew-resistant grade; Trichoderma viride, 0 grade of mildew-resistant grade; The short boundary of teething, 0 grade of mildew-resistant grade; La Yeya branch bacterium, 0 grade of mildew-resistant grade; Paecilomyces varioti, 0 grade of mildew-resistant grade.Be that each bacterioid and micro organism quantity do not detect.
Embodiment 4
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.Except the formula of antimildew and antibacterial complex liquid was different from embodiment 1, other was all identical with embodiment 1.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 87.7%, ethanol 3%, propylene glycol monomethyl ether 5%, thickener 3.5%, antiseptic CMIT or antiseptic MIT 0.25%, bactericide BIT 0.1%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
The floor of making or furniture draw following microbiological data after testing with the facing paper back side: aspergillus flavus, 3 grades of mildew-resistant grades; Chaetomium globosum, 2 grades of mildew-resistant grades; Paecilomyces varioti, 1 grade of mildew-resistant grade.Be that the back side has multiple mould.
Embodiment 5
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.Except the formula of antimildew and antibacterial complex liquid was different from embodiment 1, other was all identical with embodiment 1.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 85%, ethanol 4%, propylene glycol monomethyl ether 7%, thickener 3.2%, antiseptic CMIT or antiseptic MIT 0.25%, bactericide BIT 0.1%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
The floor of making or furniture draw following microbiological data after testing with the facing paper back side: aspergillus flavus, 3 grades of mildew-resistant grades; Chaetomium globosum, 2 grades of mildew-resistant grades; Paecilomyces varioti, 1 grade of mildew-resistant grade.Be that the back side has multiple mould.
Embodiment 6
A kind of floor or furniture facing paper, body paper is coated with the antimildew and antibacterial layer on the back side, and the antimildew and antibacterial complex liquid oven dry on the body paper back side forms the antimildew and antibacterial layer by intaglio printing.Except the formula of antimildew and antibacterial complex liquid was different from embodiment 1, other was all identical with embodiment 1.The antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 87.7%, ethanol 3%, propylene glycol monomethyl ether 5%, thickener 3.5%, antiseptic CMIT or antiseptic MIT 0.2%, bactericide BIT 0.15%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
The floor of making or furniture draw following microbiological data after testing with the facing paper back side: Penicillium citrinum, 2 grades of mildew-resistant grades; Trichoderma viride, 2 grades of mildew-resistant grades; The short boundary of teething, 2 grades of mildew-resistant grades.
Draw by experiment, the antimildew and antibacterial effect at the body paper back side of mildew-proof antibacterial decorative paper of the present invention directly and antiseptic CMIT or antiseptic MIT, bactericide BIT is relevant with the usage ratio of mould inhibitor OIT, it adopts antiseptic CMIT or antiseptic MIT in embodiment 1, the usage ratio antimildew and antibacterial best results of bactericide BIT and mould inhibitor OIT.
Claims (7)
1. a floor or furniture facing paper is characterized in that the body paper back side is provided with the antimildew and antibacterial layer, and the antimildew and antibacterial layer is formed in the antimildew and antibacterial complex liquid oven dry on the body paper back side by intaglio printing; Described antimildew and antibacterial complex liquid comprises following component by mass percentage: deionized water 85-90%, ethanol 2-4%, propylene glycol monomethyl ether 3-7%, thickener 1.5-5.5%, antiseptic CMIT or antiseptic MIT 0.1-0.4%, bactericide BIT 0.1-0.4%, mould inhibitor OIT 0.1-0.4%, pH value conditioning agent 0.1-0.5%; The pH value of above-mentioned antimildew and antibacterial complex liquid is between 8.0-8.3; The viscosity of described antimildew and antibacterial complex liquid is between 20-24S.
2. a kind of floor according to claim 1 or furniture facing paper, it is characterized in that described antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 85-90%, ethanol 2-4%, propylene glycol monomethyl ether 3-7%, thickener 1.5-5.5%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.1-0.5%.
3. a kind of floor according to claim 1 or furniture facing paper, it is characterized in that described antimildew and antibacterial complex liquid is made of following component by mass percentage: deionized water 87.7%, ethanol 3%, propylene glycol monomethyl ether 5%, thickener 3.5%, antiseptic CMIT or antiseptic MIT 0.15%, bactericide BIT 0.2%, mould inhibitor OIT 0.3%, pH value conditioning agent 0.15%.
4. according to claim 1 and 2 or 3 described a kind of floor or furniture facing papers, is characterized in that described bactericide BIT is BIT; Mould inhibitor OIT is N-octyl group isothiazolinone; Antiseptic CMIT is CMIT; Antiseptic MIT is MIT; Thickener is ROHM AND HAAS thickener TT-935; The pH value conditioning agent is a kind of in AMP-95, ammoniacal liquor, sodium carbonate, sodium bicarbonate.
5. a kind of floor according to claim 1 or furniture facing paper, is characterized in that described antimildew and antibacterial complex liquid is printed on the back side of body paper with the full version of the print speed printing speed of 100-120m/min.
6. a kind of floor according to claim 1 or furniture facing paper, is characterized in that described antimildew and antibacterial complex liquid oven dry forms the antimildew and antibacterial layer, and temperature is between 150-160 ℃.
7. a kind of floor according to claim 1 or furniture facing paper, is characterized in that described body paper is the titanium white fibrous paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110200386 CN102268840B (en) | 2011-07-15 | 2011-07-15 | Decorative paper used for floor or furniture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110200386 CN102268840B (en) | 2011-07-15 | 2011-07-15 | Decorative paper used for floor or furniture |
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| Publication Number | Publication Date |
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| CN102268840A CN102268840A (en) | 2011-12-07 |
| CN102268840B true CN102268840B (en) | 2013-06-19 |
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| CN 201110200386 Active CN102268840B (en) | 2011-07-15 | 2011-07-15 | Decorative paper used for floor or furniture |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102608113B (en) * | 2012-03-30 | 2014-08-13 | 上海三爱思试剂有限公司 | Mildew-proof pH test paper and preparation method thereof |
| CN109068639A (en) * | 2016-04-05 | 2018-12-21 | 托尔有限公司 | Synergistic biocide composition containing 5- chloro-2-methyl isothiazoline -3- ketone |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4863180B2 (en) * | 2000-12-27 | 2012-01-25 | 大塚化学株式会社 | Water-based paint and wallpaper for wallpaper |
| DE10135667A1 (en) * | 2001-07-21 | 2003-02-06 | Creavis Tech & Innovation Gmbh | Microbicidal wallpaper |
| CN2707884Y (en) * | 2004-06-07 | 2005-07-06 | 杨圣兵 | Negative ion sterilization moldproof floor board |
| CN2850907Y (en) * | 2005-11-28 | 2006-12-27 | 云南大学 | Antibiotic composite board |
| CN101608078B (en) * | 2009-07-23 | 2012-09-19 | 天津市海山化工科技开发有限公司 | Decorative paper water-based gravure printing ink composition |
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Address after: Ring road Hangzhou city Zhejiang province 311300 Ling'an Linglong Street Linglong Industrial Zone No. 1958 Patentee after: Zhejiang dilon cultural development Limited by Share Ltd Address before: Ring Road Linglong industrial zone of Ling'an city Hangzhou city Zhejiang province 311301 No. 1958 Patentee before: Zhejiang Dilong New Material Co., Ltd. |
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Effective date of registration: 20161202 Address after: Ring road Hangzhou city Zhejiang province 311300 Ling'an Linglong Street Linglong Industrial Zone No. 1958 Patentee after: Zhejiang Dilong New Material Co. Ltd. Address before: Ring road Hangzhou city Zhejiang province 311300 Ling'an Linglong Street Linglong Industrial Zone No. 1958 Patentee before: Zhejiang dilon cultural development Limited by Share Ltd |