CN102268493A - Method for preparing rose-fragrance leather - Google Patents
Method for preparing rose-fragrance leather Download PDFInfo
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- CN102268493A CN102268493A CN2011101964320A CN201110196432A CN102268493A CN 102268493 A CN102268493 A CN 102268493A CN 2011101964320 A CN2011101964320 A CN 2011101964320A CN 201110196432 A CN201110196432 A CN 201110196432A CN 102268493 A CN102268493 A CN 102268493A
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Abstract
The invention discloses a method for preparing rose-fragrance leather, which comprises the following steps of: rewetting retanned, dyed and fat-stuffed leather in a mass ratio of leather to water of 1:(7.5-10) at the temperature of between 30 and 40DEG C and a rate of 600-800r/min for 6 to 8 hours; and regulating the pH of a system to be 5-7 by using a solution of sodium bicarbonate, adding rose essence capsules in a mass ratio of essence to leather of (3-8):1, heating the system to the temperature of between 40 and 60DEG C, increasing fragrance for 6 to 9 hours when a rotating speed is 600-1,200r/min, taking the fragrance-increased leather out, and airing naturally to obtain the rose-fragrance leather. The rose-fragrance leather has the essence utilization rate of 34.92 percent, has obvious rose fragrance, still has obvious rose fragrance after 40 days, and has good fragrance sustained-release property.
Description
Technical field
The present invention relates to a kind of rose scent leather and preparation method thereof, specifically relate to the preparation method who adopts wet complete processing to process a kind of rose scent leather.
Background technology
Leather industry and people live closely bound up, and in recent years, fragrant leather has become one of development trend of functional leather.It is the effective means that improves product specification and added value that fragrance is combined with leather, also is the joint demand of human consumer and leather industry.Fragrance leather pleasant aroma, class height can be used on the products such as automobile cushion leather, sofa artificial leather, clothing leather, luggage leather, and extremely vast market is arranged.Rose compound is a kind of important additive, liked by the human consumer, is mainly used at present in the daily necessities such as weaving, leather, and the quality of end product is played crucial effects.The conventional leather perfuming is directly essence to be sprayed at the finished leather surface, but easily causes the surface inhomogeneous, shortcomings such as color spot.
Summary of the invention
The present invention provides a kind of preparation method of rose scent leather in order to solve above-mentioned technical problem, the rose scent leather of this method preparation has feature rose fragrance, and whole pleasant aroma has fragrance slow release effect preferably.
Technical scheme of the present invention
A kind of preparation method of rose scent leather, its preparation process process flow diagram as shown in Figure 1, be about to leather and weigh that to add that a certain amount of water termostat stirs behind the certain hour with lye pH adjustment be 5～7 in the back, add a certain amount of rose essence capsules subsequently, carry out constant temperature again and stir to take out behind the certain hour and dry, promptly get a kind of rose scent leather in natural ventilation place.Its concrete preparation process comprises the steps:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor returning wet treatment in 1:7.5～10, be 30～40 ℃ in temperature, when rotating speed is 600～800 r/min, return wet 6～8h, get system 1;
Described leather is ox-hide, sheepskin or pigskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 5～7 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather, i.e. m
Essence: m
LeatherBe 3～8:1, get system 2, system 2 is warming up to 40～60 ℃, rotating speed is 600～1200 r/min, behind perfuming 6～9h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
Beneficial effect of the present invention
A kind of rose scent leather of the present invention owing to adopt wet complete processing to be prepared, to the leather perfuming, makes essence capsule directly infiltrate collagen inside in the wet workshop section that processes, and can effectively improve the slow release effect of essence.The essence utilization ratio of the rose scent leather of preparation is up to 34.92%, and fragrance is mellow and full pleasant, and rose fragrance is remarkable, can effectively improve the former scent of of leather; After placing in 40 days, the rose fragrance of rose scent leather is still more remarkable, and fragrance does not have considerable change, has good fragrance slow-releasing.
A kind of rose scent leather of the present invention has reduced the leather peculiar smell, makes leather give out light pleasant fragrance for a long time, can significantly improve leather quality and class, has also played certain function of health care.
Description of drawings
Fig. 1, a kind of rose scent leather preparation process synoptic diagram.
Embodiment
Below by embodiment the present invention is described in further detail, but do not limit the present invention.
Used rose essence capsules is that median size is 91 nm in the embodiment of the invention, and the size-grade distribution coefficient is 0.034 nano rose essence capsules emulsion, and its preparation method is (referring to patent: 201010147881.1) comprise the steps:
At first, in beaker, add the rose compound of 0.4 parts by weight and the polysorbas20 of 2.0 parts by weight, be blended under the speed of magnetic agitation 1100r/min and fully stir 5min, and in beaker, slowly add deionized water, continue identical speed and stir, until the emulsion homogeneous;
Then, under magnetic agitation, slowly drip the pH value to 2.0 of the hydrochloric acid soln regulation system of 1 mol/L, then slowly add the positive butyl ester of alpha-cyanoacrylate (BCA) of 0.8 parts by weight, stir while dripping, dropwise, seal a bottle, continue to stir, make its abundant polymerization, termination reaction behind the 2h with the pH value to 7.0 of the sodium hydroxide solution regulation system of 1 mol/L, continues to stir 0.5h, promptly getting median size is 91 nm, and the size-grade distribution coefficient is 0.034 nano rose essence capsules emulsion.
Ox-hide behind the used retanning dyeing and fat-liquoring of the present invention, sheepskin available from Hebei Dongming Leather Co., Ltd., pigskin available from the rich leather made in Great Britain of Guangxi province Yulin City company limited.
It is to adopt ultraviolet spectrophotometer (JHT-21 ultraviolet spectrophotometer, UNICO(Shanghai) Instruments Co., Ltd.) to measure that the flavoring essence utilization ratio of a kind of rose scent leather of the present invention is measured, and its calculation formula is as follows:
ω---leather flavoring essence utilization ratio;
C
0---essence concentration in the nano essence dressing liquid before the perfuming;
C
a---residual essence concentration in the dressing liquid behind the perfuming.
Embodiment 1
A kind of preparation method of rose scent leather comprises being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:7.5 returns wet treatment, be 30 ℃ in temperature, when rotating speed is 600 r/min, return wet 6h, get system 1;
Described leather is an ox-hide;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 5 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 3:1, get system 2, system 2 is warming up to 40 ℃, rotating speed is 800 r/min, behind perfuming 9 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
A kind of rose scent leather of above-mentioned gained, the essence utilization ratio is 9% after measured, rose fragrance a little less than, have more leather smell.
Embodiment 2
A kind of preparation method of rose scent leather comprises being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:9 returns wet treatment, be 35 ℃ in temperature, when rotating speed is 800 r/min, return wet 7h, get system 1;
Described leather is an ox-hide;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 6 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 5:1, get system 2, system 2 is warming up to 50 ℃, rotating speed is 1000 r/min, behind perfuming 8 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
A kind of rose scent leather of above-mentioned gained, the essence utilization ratio is 27.50% after measured, slightly has Muscat Hamburg gas, has the leather smell.
Embodiment 3
A kind of preparation method of rose scent leather comprises being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:10 returns wet treatment, be 40 ℃ in temperature, when rotating speed is 700 r/min, return wet 8h, get system 1;
Described leather is a sheepskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 5 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 6:1, get system 2, system 2 is warming up to 60 ℃, rotating speed is 1200 r/min, behind perfuming 6 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
A kind of rose scent leather of above-mentioned gained, the essence utilization ratio is 28.25% after measured, whole fragrance is comparatively comfortable, slightly has Muscat Hamburg gas, slightly carries the leather smell secretly.
Embodiment 4
A kind of preparation method of rose scent leather comprises being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:8 returns wet treatment, be 40 ℃ in temperature, when rotating speed is 800 r/min, return wet 8h, get system 1;
Described leather is a pigskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 7 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 8:1, get system 2, system 2 is warming up to 50 ℃, rotating speed is 900 r/min, behind perfuming 8 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
A kind of rose scent leather of above-mentioned gained, the essence utilization ratio is 31% after measured, whole fragrance is comfortable, has rose fragrance, hardly belt leather leather smell.
Embodiment 5
A kind of preparation method of rose scent leather comprises being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:8.5 returns wet treatment, be 35 ℃ in temperature, when rotating speed is 700 r/min, return wet 7h, get system 1;
Described leather is a sheepskin;
(2), be that the pH of the system 1 of 0.5% sodium bicarbonate regulating step (1) gained is 6 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 7:1, get system 2, system 2 is warming up to 60 ℃, rotating speed is 1200 r/min, behind perfuming 9 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
A kind of rose scent leather of above-mentioned gained, the essence utilization ratio is 34.92% after measured, whole fragrance is comfortable, rose fragrance is remarkable, and no leather smell after placing in 40 days, the rose fragrance of rose scent leather is still more remarkable, and fragrance does not have considerable change, has good fragrance slow-releasing.
Above said content only is the basic explanation of the present invention under conceiving, and according to any equivalent transformation that technical scheme of the present invention is done, all should belong to protection scope of the present invention.
Claims (8)
1. the preparation method of a rose scent leather is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor returning wet treatment in 1:7.5～10, be 30～40 ℃ in temperature, when rotating speed is 600～800 r/min, returns wet 6～8h and get system 1;
(2), be that the pH of 0.5% sodium hydrogen carbonate solution regulating step (1) gained system 1 is 5～7 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather, i.e. m
Essence: m
LeatherBe 3～8:1, get system 2, again system 2 is warming up to 40～60 ℃, rotating speed is 600～1200 r/min, behind perfuming 6～9 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather;
Described rose essence capsules is that median size is 91 nm, and the size-grade distribution coefficient is 0.034 nano rose essence capsules emulsion.
2. the preparation method of rose scent leather as claimed in claim 1 is characterized in that the leather described in the step (1) is ox-hide, sheepskin or pigskin.
3. the preparation method of rose scent leather as claimed in claim 1 is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:7.5 returns wet treatment, be 30 ℃ in temperature, when rotating speed is 600 r/min, return wet 6h, get system 1;
Described leather is an ox-hide;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 5 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 3:1, get system 2, system 2 is warming up to 40 ℃, rotating speed is 800r/min, behind the perfuming 9h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
4. the preparation method of rose scent leather as claimed in claim 1 is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:9 returns wet treatment, be 35 ℃ in temperature, when rotating speed is 800 r/min, return wet 7h, get system 1;
Described leather is an ox-hide;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 6 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 5:1, get system 2, system 2 is warming up to 50 ℃, rotating speed is 1000 r/min, behind perfuming 8 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
5. the preparation method of rose scent leather as claimed in claim 1 is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:10 returns wet treatment, be 40 ℃ in temperature, when rotating speed is 700 r/min, return wet 8h, get system 1;
Described leather is a sheepskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 5 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 6:1, get system 2, system 2 is warming up to 60 ℃, rotating speed is 1200 r/min, behind perfuming 6 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
6. the preparation method of rose scent leather as claimed in claim 1 is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:8 returns wet treatment, be 40 ℃ in temperature, when rotating speed is 800 r/min, return wet 8h, get system 1;
Described leather is a pigskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 7 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 8:1, get system 2, system 2 is warming up to 50 ℃, rotating speed is 900 r/min, behind perfuming 8 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
7. the preparation method of rose scent leather as claimed in claim 1 is characterized in that comprising being prepared as follows step:
(1), with the leather behind the retanning dyeing and fat-liquoring, the mass ratio of control leather and water is m
Leather: m
WaterFor 1:8.5 returns wet treatment, be 35 ℃ in temperature, when rotating speed is 700 r/min, return wet 7h, get system 1;
Described leather is a sheepskin;
(2), be that the pH of the system 1 of 0.5% sodium hydrogen carbonate solution regulating step (1) gained is 6 with massfraction, add rose essence capsules subsequently, the mass ratio of control rose essence capsules and leather is m
Essence: m
LeatherBe 7:1, get system 2, system 2 is warming up to 60 ℃, rotating speed is 1200 r/min, behind perfuming 9 h leather taking-up behind the perfuming is dried in natural ventilation place, promptly gets a kind of rose scent leather.
8. as the described rose essence capsules of step (2) among the preparation method of the arbitrary described rose scent leather of claim 1～7, it is characterized in that its preparation method comprises the steps:
At first, in beaker, add the rose compound of 0.4 parts by weight and the polysorbas20 of 2.0 parts by weight, be blended under the speed of magnetic agitation 1100r/min and fully stir 5min, and in beaker, slowly add deionized water, continue identical speed and stir, until the emulsion homogeneous;
Then, under magnetic agitation, slowly drip the pH value to 2.0 of the hydrochloric acid soln regulation system of 1 mol/L, then slowly add the positive butyl ester of alpha-cyanoacrylate of 0.8 parts by weight, stir while dripping, dropwise, seal a bottle, continue to stir, make its abundant polymerization, termination reaction behind the 2h, with the pH value to 7.0 of the sodium hydroxide solution regulation system of 1 mol/L, continuing to stir 0.5h, promptly to get median size be 91 nm, and the size-grade distribution coefficient is 0.034 nano rose essence capsules emulsion.
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| CN2011101964320A CN102268493A (en) | 2011-07-14 | 2011-07-14 | Method for preparing rose-fragrance leather |
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| CN2011101964320A CN102268493A (en) | 2011-07-14 | 2011-07-14 | Method for preparing rose-fragrance leather |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605643A (en) * | 2012-02-03 | 2012-07-25 | 常州汉斯化学品有限公司 | Application of disperse dye microcapsules in leather |
| CN102744924A (en) * | 2012-07-27 | 2012-10-24 | 山东泰山金润塑胶制品有限公司 | Odor release type cushion for recreation and manufacturing method of odor release type cushion for recreation |
| CN112858650A (en) * | 2021-01-13 | 2021-05-28 | 上海应用技术大学 | Analysis research method for improving automobile leather smell based on sigma-tau intensity method |
| CN113308582A (en) * | 2021-05-18 | 2021-08-27 | 辽宁富新新材料有限公司 | Light sweet automobile leather with special low odor and production process thereof |
| CN114410851A (en) * | 2022-01-23 | 2022-04-29 | 浙江奥康鞋业股份有限公司 | Novel fragrant cow leather material and preparation process thereof |
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| US5368609A (en) * | 1990-10-30 | 1994-11-29 | Henkel Kommanditgesellschaft Auf Aktien | Softening filler for leather |
| WO2000065100A1 (en) * | 1999-04-26 | 2000-11-02 | Pittards Public Limited Company | Impregnation of leather with micro-encapsulated material |
| CN101816911A (en) * | 2010-04-15 | 2010-09-01 | 上海应用技术学院 | Method for preparing nano rose essence capsules |
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2011
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| DE3921145A1 (en) * | 1989-06-28 | 1991-01-10 | Basf Ag | Rendering leather surface mattee as steroid replacement - by application of compsn. contg. microcapsules |
| US5368609A (en) * | 1990-10-30 | 1994-11-29 | Henkel Kommanditgesellschaft Auf Aktien | Softening filler for leather |
| WO2000065100A1 (en) * | 1999-04-26 | 2000-11-02 | Pittards Public Limited Company | Impregnation of leather with micro-encapsulated material |
| CN101816911A (en) * | 2010-04-15 | 2010-09-01 | 上海应用技术学院 | Method for preparing nano rose essence capsules |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605643A (en) * | 2012-02-03 | 2012-07-25 | 常州汉斯化学品有限公司 | Application of disperse dye microcapsules in leather |
| CN102605643B (en) * | 2012-02-03 | 2014-06-04 | 江苏汉诺斯化学品有限公司 | Application of disperse dye microcapsules in leather |
| CN102744924A (en) * | 2012-07-27 | 2012-10-24 | 山东泰山金润塑胶制品有限公司 | Odor release type cushion for recreation and manufacturing method of odor release type cushion for recreation |
| CN102744924B (en) * | 2012-07-27 | 2015-10-21 | 山东泰山金润塑胶制品有限公司 | A kind of fragrance releasing leisure pad and preparation method thereof |
| CN112858650A (en) * | 2021-01-13 | 2021-05-28 | 上海应用技术大学 | Analysis research method for improving automobile leather smell based on sigma-tau intensity method |
| CN112858650B (en) * | 2021-01-13 | 2023-08-18 | 上海应用技术大学 | Analysis and research method for improving automobile leather smell based on sigma-tau strength method |
| CN113308582A (en) * | 2021-05-18 | 2021-08-27 | 辽宁富新新材料有限公司 | Light sweet automobile leather with special low odor and production process thereof |
| CN114410851A (en) * | 2022-01-23 | 2022-04-29 | 浙江奥康鞋业股份有限公司 | Novel fragrant cow leather material and preparation process thereof |
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Application publication date: 20111207 |