CN102241458A - Xanthan waste water treatment process - Google Patents

Xanthan waste water treatment process Download PDF

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Publication number
CN102241458A
CN102241458A CN2010101714176A CN201010171417A CN102241458A CN 102241458 A CN102241458 A CN 102241458A CN 2010101714176 A CN2010101714176 A CN 2010101714176A CN 201010171417 A CN201010171417 A CN 201010171417A CN 102241458 A CN102241458 A CN 102241458A
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waste water
xanthan gum
gum waste
treatment process
water treatment
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李岐山
王志友
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ZIBO DEOSEN BIOCHEMICAL Ltd
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ZIBO DEOSEN BIOCHEMICAL Ltd
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Abstract

The invention discloses a xanthan waste water treatment process. The treatment process is characterized by: carrying out a cooling treatment for xanthan waste water; adjusting specific gravity of sludge granules; carrying out acidification; adjusting pH value; carrying out an anaerobic biological treatment to enable the xanthan waste water to be changed into process water. Compared to the prior art, the xanthan waste water treatment process provided by the present invention has advantages of high efficiency, simple process, easy operation, no mud leaking, stable effluent index, high shock loading resistance, quick granular sludge forming, large biogas production and the like.

Description

Xanthan gum waste water treatment process
Invention field
The invention of this reality belongs to the biological fermentation technical field of waste water processing, relates to a kind of Xanthan gum waste water treatment process.
Background technology
Since the sixties in 20th century, U.S. Kelco company dropped into suitability for industrialized production with xanthan gum, xanthan gum was used very extensive in fields such as food, oil, agricultural chemicals, feed, daily use chemicals, environmental protection, weaving, makeup.Along with the fast development of oil production industry in recent years, to the demand surge of xanthan gum, China has become the maximum xanthan gum producing country in the whole world.Because xanthan gum is the biological fermentation polysaccharide, will inevitably bring the fermented waste fluid pollution problems, in the xanthan gum waste water, contain a large amount of fermentation pollutents, mainly contain inorganic salt such as part sodium-chlor, SODIUMNITRATE, calcium chloride and a large amount of carbohydrate and organic molecule material such as residual sugar, acetate, pyruvic acid etc., CODcr is more than 4000mg/L.If handle badly, not only pollute the environment, also can waste biological substance wherein, the water resources to China constitutes a threat to simultaneously, will seriously restrict the development of enterprise.
Xanthan gum is the product innovation that begins suitability for industrialized production recent years, because technology is blocked mutually, domestic and international research to the comprehensive utilization of xanthan gum waste water is less, to the comprehensive utilization of xanthan gum waste water, does not up to the present have proven technique.
Summary of the invention
Purpose of the present invention, be in order to overcome the deficiencies in the prior art, and provide a kind of Xanthan gum waste water treatment process, this technical scheme efficient height, have do not run stable, the anti-high loading of mud, effluent index impact, form granule sludge fast, produce advantages such as the natural pond is large-minded, and realized recovery of resources.
In order to address the above problem, technical scheme of the present invention is: xanthan gum waste water is handled through cooling, adjusting mud granule proportion and intensity, acidifying, adjusting pH value, anaerobic biological.Its concrete steps are:
(1) cooling with the dry in the air water tower cooling of xanthan gum waste water through plural serial stage, is cooled to 38 and spends between 43 degree, and winter temperature is lower, and cooling is relatively easy, advances a jar water temperature and is controlled between 38-40 degree; Summer temperature is higher, and the water relative difficult of drying in the air is advanced a jar water temperature and is controlled at 41-43 degree;
(2) regulate mud granule proportion and intensity, warm equalizing tank during the xanthan gum waste water after the cooling is imported, described middle temperature is 38-43 ℃, adds liquid lime to regulate mud granule proportion 1.05-1.2;
(3) acidifying joins in the acidification pool in the xanthan gum waste water, is converted into small molecular organic acid class material through acidication, and the time in the acidization is 5-8 hour; Xanthan gum waste water belongs to food wastewater, is subjected to self very easily acidifying of water quality reason, does not need additionally to add the acidifying bacterium in the water, and there are a large amount of acidifying bacterium in equalizing tank and acidification pool, anaerobic jar bottom section.The soluble large molecule organism is converted into lipid acid, alcohols, lactic acid, ammonia, hydrogen sulfide etc., and the pH value just can reduce to 4.5 from 6.0.
(4) regulate the pH value, the basicity employing adding liquid caustic soda of the xanthan gum waste water after the acidifying, the method for liquid lime are adjusted, reach the required pH value of anaerobic biological processing and be 6.0-6.5;
(5) the xanthan gum waste water in the step (4) is imported anaerobic reactor and carry out the anaerobic biological processing, the temperature in the anaerobic jar is 35-38 ℃, and duration of the reaction is 11-13 hour, and pH value is 6.5-7.5.
Anaerobic biological treatment is the chemistry of micro-organisms process of a complexity, relies on the bacterium of three big main monoids, i.e. the combined action of acidication bacterium, product hydrogen acetogen and methanogen is finished.
Required bacterium is promptly in content of the present invention: the acidication bacterium, produce that hydrogen acetogen rate of propagation is fast, the domestication time is short, and do not need other interpolation.Methanogen (being anaerobic grain sludge) rate of propagation is slow, the domestication time is long, needs extra the interpolation during startup, generally starts addition at the 30%(volumetric quantity) more than.
(1), the three phases of anaerobic digestion
Studies show that methanogen can only utilize some simple organics such as formic acid, acetate, methyl alcohol, methyl amine and H 2 / CO 2 Deng, contain above lipid acid of two carbon and the alcohols beyond the methyl alcohol and can not utilize.Therefore, the anaerobic process must be passed through with the next stage:
Fs: hydrolysis, souring stage
Subordinate phase: produce hydrogen and produce the acetate stage
Phase III: produce methane phase
(2), the major microorganisms in each stage
A. acidication stage
Major function:
Hydrolysis: under the effect of extracellular enzyme, insoluble hydrolysis of organic matter is become dissolved organic matter;
Acidifying: the soluble large molecule organism is converted into lipid acid, alcohols, lactic acid, ammonia, hydrogen sulfide etc.;
Predominantly bacteria:
Fusobacterium, Bacteroides, Butyrivibrio, Bifidobacterium etc.;
B. produce hydrogen and produce the acetate stage
Major function: various higher fatty acid and oxidation of alcohols are decomposed into acetate
With H2Deng;
Principal reaction:
Ethanol: CH 3 CH 2 OH+H 2 O CH 3 COOH+2H 2
Figure 2010101714176100002DEST_PATH_IMAGE004
Propionic acid: CH 3 CH 2 COOH+2 H 2 O CH 3 COOH+3H 2 + CO 2
Figure DEST_PATH_IMAGE006
Butyric acid: CH 3 CH 2CH 2 COOH+2 H 2 O 2CH 3 COOH+2H 2
Predominantly bacteria:
Syntrophism zygosaccharomyces, syntrophism Bacillaceae, fusobacterium, dark Bacillaceae etc.;
This stage acidication back pH value is fully reduced to 4.0-4.5 from 6.0 of water inlet.
C. produce methane phase
Major function: the product acetate and the H that will produce the hydrogen acetogen 2 / CO 2 , formic acid, methyl alcohol etc. is converted into CH 4 And CO 2 , guarantee that anaerobic digestion process is smooth;
Main type: acetate nutritional type and H2 nutritional type methanogen;
4?CH 3 COOH?→?CH 4 +3CO 2 +2H 2 O
4?H 2 +CO 2 ?→?CH 4 +2H 2 O
In the application of anaerobic treatment of waste water, owing to producing acid and producing methane and in same structures, carry out mostly,, often keep the interior pH value of reactor at 6.5-7.5 so, avoid too much acid accumulation in order to keep balance, preferred PH is in the scope of 6.8-7.2.For guaranteeing that this stage can carry out more smoothly, water outlet pH value generally needs be adjusted to 6.8 with liquid lime or liquid caustic soda---between 7.2, be beneficial to the smooth propagation and the metabolism of methanogen.
The principle of anaerobic treatment is to utilize anaerobion in suitable temperature, the process of degradation of contaminant under the conditions such as potential of hydrogen.Reactor is divided into, cloth pool, biochemical reaction zone, settlement separate district, exhalant region etc.Technology is, pollutent enters with anaerobion in the cloth pool and fully contacts absorption, in the current uphill process, fully decompose digestion, entering settlement separate district back microorganism separates with aqueous vapor, microorganism returns the cloth pool and biochemical zone repeats degraded, flow out from exhalant region after the water treatment, gas is drawn by pipeline and is delivered to boiler combustion.Form the successive treating processes.Microorganism adds about 30 percent of reactor volume in the reactor at the beginning of starting.Along with the raising normal dimensions of processing power is held in about 50 percent.Because microorganism is in constantly breeding growth, redundance can be sold.
The invention has the beneficial effects as follows:Adopt this its efficient height of art breading xanthan gum waste water, technology is simple, easy to operate, have do not run stable, the anti-high loading of mud, effluent index impact, form granule sludge fast, produce advantages such as the natural pond is large-minded, and realized recovery of resources.Processing efficiency can improve 20% the processing rate of going than traditional anaerobic treatment process, and operating load can improve more than 80%.
Description of drawings
Fig. 1 is the Xanthan gum waste water treatment process schema.
Embodiment
Further specify technical scheme of the present invention below by specific embodiment, but the present invention is not exceeded with specific embodiment.
Embodiment 1
Xanthan gum waste water is handled through cooling, adjusting mud granule proportion and intensity, acidifying, adjusting pH value, anaerobic biological.Its concrete steps are:
(1) cooling with the dry in the air water tower cooling of xanthan gum waste water through plural serial stage, is cooled to 38 and spends between 43 degree, and winter temperature is lower, and cooling is relatively easy, advances a jar water temperature and is controlled at 38 degree;
(2) regulate mud granule proportion and intensity, warm equalizing tank during the xanthan gum waste water after the cooling is imported adds liquid lime to regulate mud granule proportion 1.05;
(3) acidifying adds in the acidification pool in the xanthan gum waste water, is converted into small molecular organic acid class material through acidication, and the time in the acidization is 5 hours;
(4) regulate the pH value, the basicity of the xanthan gum waste water after the acidifying is adjusted, reaching the required pH value of anaerobic biological processing is 6.0;
(5) the xanthan gum waste water in the step (4) is imported anaerobic reactor and carry out the anaerobic biological processing, the temperature in the anaerobic jar is 37 ℃, and duration of the reaction is 11 hours, and pH value is 6.5.
Embodiment 2
Xanthan gum waste water is handled through cooling, adjusting mud granule proportion and intensity, acidifying, adjusting pH value, anaerobic biological.Its concrete steps are:
(1) cooling with the dry in the air water tower cooling of xanthan gum waste water through plural serial stage, is cooled to 38 and spends between 43 degree, and summer temperature is higher, and the water relative difficult of drying in the air is advanced a jar water temperature and is controlled at 41 degree;
(2) regulate mud granule proportion and intensity, warm equalizing tank during the xanthan gum waste water after the cooling is imported,, add liquid lime to regulate mud granule proportion 1.1;
(3) acidifying adds in the acidification pool in the xanthan gum waste water, is converted into small molecular organic acid class material through acidication, and the time in the acidization is 7 hours;
(4) regulate the pH value, the basicity of the xanthan gum waste water after the acidifying is adjusted, reaching the required pH value of anaerobic biological processing is 6.3;
(5) the xanthan gum waste water in the step (4) is imported anaerobic reactor and carry out the anaerobic biological processing, the temperature in the anaerobic jar is 38 ℃, and duration of the reaction is 13 hours, and pH value is 7.0.
Embodiment 3
Xanthan gum waste water is handled through cooling, adjusting mud granule proportion and intensity, acidifying, adjusting pH value, anaerobic biological.Its concrete steps are:
(1) cooling with the dry in the air water tower cooling of xanthan gum waste water through plural serial stage, is cooled to 38 and spends between 43 degree, and winter temperature is lower, and cooling is relatively easy, advances a jar water temperature and is controlled at 40 degree;
(2) regulate mud granule proportion and intensity, warm equalizing tank during the xanthan gum waste water after the cooling is imported,, add liquid lime to regulate mud granule proportion 1.2;
(3) acidifying adds in the acidification pool in the xanthan gum waste water, is converted into small molecular organic acid class material through acidication, and the time in the acidization is 8 hours;
(4) regulate the pH value, the basicity of the xanthan gum waste water after the acidifying is adjusted, reaching the required pH value of anaerobic biological processing is 6.5;
(5) the xanthan gum waste water in the step (4) is imported anaerobic reactor and carry out the anaerobic biological processing, the temperature in the anaerobic jar is 38 ℃, and duration of the reaction is 12 hours.PH value is 7.5.

Claims (2)

1. Xanthan gum waste water treatment process, it is characterized in that: described processing step is: cooling, regulate mud granule proportion, acidifying, adjusting pH value, anaerobic biological treatment step.
2. Xanthan gum waste water treatment process as claimed in claim 1 is characterized in that: described cooling step is specially: with the dry in the air water tower cooling of xanthan gum waste water through plural serial stage, be cooled to 38 and spend between 43 degree.
3. Xanthan gum waste water treatment process as claimed in claim 1, it is characterized in that: regulating mud granule proportion concrete steps is: warm equalizing tank during the xanthan gum waste water after will lowering the temperature imports, in warm temperature range be 38-43 ℃, adding liquid lime is 1.05-1.2 to regulate mud granule proportion.
4. Xanthan gum waste water treatment process as claimed in claim 1, it is characterized in that: acidification step is specially:, join acidification pool in the xanthan gum waste water, be converted into small molecular organic acid class material through acidication, the time in the acidization is 5-8 hour.
5. Xanthan gum waste water treatment process as claimed in claim 1 is characterized in that: regulate pH value step and be specially: the potential of hydrogen of the xanthan gum waste water after utilizing liquid caustic soda to acidifying is adjusted, and reaches the required pH value of anaerobic biological processing and is 6.0-6.5.
6. Xanthan gum waste water treatment process as claimed in claim 1, it is characterized in that: the anaerobic biological treatment step is specially: the xanthan gum waste water in the step (4) is imported anaerobic reactor carry out the anaerobic biological processing, temperature in the anaerobic jar is 35-38 ℃, duration of the reaction is 11-13 hour, and pH value is 6.5-7.5 in the reactor.
7. the Xanthan gum waste water treatment process described in claim 6, it is characterized in that: the PH in the described reactor is preferably 6.8-7.2.
CN2010101714176A 2010-05-13 2010-05-13 Xanthan waste water treatment process Pending CN102241458A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102524394A (en) * 2011-12-14 2012-07-04 淄博中轩生化有限公司 Preparing process of xanthan gum applicable to acid dairy beverages
CN104261636A (en) * 2014-10-20 2015-01-07 内蒙古阜丰生物科技有限公司 Method for treating xanthan gum production sewage
CN104313004A (en) * 2014-10-20 2015-01-28 内蒙古阜丰生物科技有限公司 Preparation for treating sewage produced by production of xanthan gum
CN107176765A (en) * 2017-07-12 2017-09-19 南通醋酸化工股份有限公司 A kind of process for handling sorbic acid wastewater treatment

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265003A (en) * 2008-04-21 2008-09-17 北京水气蓝德环保科技有限公司 Method for treating high-concentration organic sewage difficult to degrade

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101265003A (en) * 2008-04-21 2008-09-17 北京水气蓝德环保科技有限公司 Method for treating high-concentration organic sewage difficult to degrade

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《Journal of Chemical Technology and Biotechnology》 20020418 Burak Demirel等 Two-phase anaerobic digestion processes: a review 第743-755页 1-7 第77卷, 第7期 *
《济南大学学报(自然科学版)》 20090731 臧立华等 黄原胶废水UASB反应器快速启动 第237-240页 1-7 第23卷, 第3期 *
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102524394A (en) * 2011-12-14 2012-07-04 淄博中轩生化有限公司 Preparing process of xanthan gum applicable to acid dairy beverages
CN102524394B (en) * 2011-12-14 2013-09-25 淄博中轩生化有限公司 Preparing process of xanthan gum applicable to acid dairy beverages
CN104261636A (en) * 2014-10-20 2015-01-07 内蒙古阜丰生物科技有限公司 Method for treating xanthan gum production sewage
CN104313004A (en) * 2014-10-20 2015-01-28 内蒙古阜丰生物科技有限公司 Preparation for treating sewage produced by production of xanthan gum
CN104261636B (en) * 2014-10-20 2016-02-24 内蒙古阜丰生物科技有限公司 A kind of method for administering xanthan gum production waste
CN107176765A (en) * 2017-07-12 2017-09-19 南通醋酸化工股份有限公司 A kind of process for handling sorbic acid wastewater treatment

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Application publication date: 20111116