The specific embodiment
The invention provides a kind of body of wall link plate; Wherein, This body of wall link plate comprises hygroscopicity surface layer 1, water proofing property bottom 2 and link plate skeleton 3, and this link plate skeleton 3 is fixed in said hygroscopicity surface layer 1 or the water proofing property bottom 2, perhaps is fixed between said hygroscopicity surface layer 1 and the water proofing property bottom 2.Under the preferable case, said link plate skeleton 3 in this case, can make said body of wall link plate have better intensity and pulling capacity between said hygroscopicity surface layer 1 and water proofing property bottom 2.
According to the present invention; The moisture pick-up properties of said hygroscopicity surface layer 1 can in very large range change, and under the preferable case, the hygroscopic coefficient of said hygroscopicity surface layer 1 is a 0.1-1 gram/square centimeter; Said hygroscopic coefficient is meant the biggest quality that absorbs water in the unit area material, g/cm
2
The water resistance of said water proofing property low layer has no particular limits, and does not infiltrate bottom as long as can guarantee the moisture of hygroscopicity surface layer 1, and under the preferable case, the seepage flow coefficient of said water proofing property bottom 2 is 1 * 10
-6To 1 * 10
-12Cel, said seepage flow coefficient be in the Darcy's law expression water at normal temperature in material the measuring of penetration (cel, cm/s).
The present invention; Said hygroscopicity surface layer 1 contains the retaining property aggregate and first cementing agent; The content ratio of the said hygroscopicity aggregate and first cementing agent can in very large range change, under the preferable case, with respect to the retaining property aggregate of 100 weight portions; The content of said first cementing agent is the 3-20 weight portion, more preferably the 5-10% weight portion.The kind of said retaining property aggregate has no particular limits, and for example, can be silica sand and/or glass microballoon; And the mean particle diameter of said retaining property aggregate can in very large range change; Under the preferable case; The mean particle diameter of said retaining property aggregate is 20-900 μ m; More preferably 40-140 μ m can make said hygroscopicity surface layer 1 have better moisture pick-up properties in this mean particle diameter scope.
Said first cementing agent can be epoxy adhesive; Also can be the mixture of epoxy adhesive and unsaturated-resin cementing agent and/or polyurethane resin cementing agent; With respect to 100 parts by weight of epoxy resin cementing agents, the content of said unsaturated-resin cementing agent and/or polyurethane resin cementing agent is the 1-100 weight portion.The inventor is surprised to find that, uses the mixture of epoxy adhesive and unsaturated-resin cementing agent and/or polyurethane resin cementing agent that the intensity of hygroscopicity surface layer 1 is improved significantly.
Said epoxy adhesive can be commercially available; For example; The trade mark that west, Guangzhou card constructional materials Co., Ltd produces is the epoxy adhesive of Sika 731, and said unsaturated-resin cementing agent can be commercially available, for example; The unsaturated-resin cementing agent of the 168f model that Tianjin resin Co., Ltd of nation difficult to understand produces; Said polyurethane resin cementing agent can be commercially available, and for example, crosses the polyurethane resin cementing agent of the ws-5000 model of company of limit chemicals (Guangzhou) Co., Ltd production.
According to the present invention; In order further to improve the safety of said body of wall link plate, said hygroscopicity surface layer 1 can also contain fire retardant, and the content of said fire retardant can in very large range change; In order to guarantee that promptly anti-flammability does not influence the moisture pick-up properties of hygroscopicity surface layer 1 again; Under the preferable case, with respect to the retaining property aggregate of 100 weight portions, the content of said fire retardant is the 1-60 weight portion.
The kind of said fire retardant is conventionally known to one of skill in the art, for example, can be in aluminium hydroxide, magnesium hydroxide, phosphonium flame retardant, chlorine-containing flame retardant, antimony trioxide and the molybdenum trioxide one or more.The mean particle diameter of said fire retardant can in very large range change, and under the preferable case, the mean particle diameter of said fire retardant can be for below the 45 μ m.The kind of said phosphonium flame retardant and chlorine-containing flame retardant is conventionally known to one of skill in the art; Can be commercially available; For example, the Yoke TPP type phosphonium flame retardant that Jiangsu Yoke Technology Co., Ltd. produces, the chlorinated paraffin wax that Qingdao Yu Zhou chemical industry Co., Ltd produces etc.
Among the present invention; Said water proofing property bottom 2 can contain water proofing property aggregate, heat insulating ability aggregate and second cementing agent; The content of said water proofing property aggregate, heat insulating ability aggregate and second cementing agent can in very large range change, under the preferable case, with respect to the water proofing property aggregate of 100 weight portions; The content of said heat insulating ability aggregate is the 1-20 weight portion, and the content of said second cementing agent is the 1-40 weight portion.
The kind of said water proofing property aggregate has no particular limits; For example, can be in waterproof sand, quartz powder and the swell soil one or more, said water proofing property aggregate can be commercially available; For example, Beijing Huichuang Technology Group Co., Ltd's production waterproof sand STS-303.In addition, the mean particle diameter of said water proofing property aggregate can in very large range change, and under the preferable case, the mean particle diameter of said water proofing property aggregate can be 50-150 μ m.
The kind of said heat insulating ability aggregate has no particular limits; For example; Can be in granular polystyrene, haydite, perlite and the vermiculite one or more; The mean particle diameter of said heat insulating ability aggregate can in very large range change, and under the preferable case, the mean particle diameter of said heat insulating ability aggregate can be 1-20mm.
According to the present invention; Said second cementing agent can be in inorganic binder, organic binder and the organic and inorganic compound binding agent one or more, and the kind of said inorganic binder is conventionally known to one of skill in the art, for example; Can be cement and/or water glass; Said inorganic binder can be commercially available, for example, and the cement of the 425# model that Lafarge SA produces.
The kind of said organic binder is conventionally known to one of skill in the art; For example; Can be in unsaturated-resin cementing agent, polyurethane resin cementing agent, the organic siliconresin cementing agent one or more; Said organic binder can be commercially available, for example, and the unsaturated-resin cementing agent of the 168f model that Tianjin resin Co., Ltd of nation difficult to understand produces; Cross the polyurethane resin cementing agent of the ws-5000 model of company of limit chemicals (Guangzhou) Co., Ltd production, the organic siliconresin cementing agent of the CN-8603 model that Dow Corning Corporation produces etc.
Among the present invention, the size of said body of wall link plate has no particular limits, and installs as long as be convenient to; The thickness of said hygroscopicity surface layer 1 and water proofing property bottom 2 has no particular limits, and uses the difference of regional condition and can in very large range change according to the body of wall scraper plate, for example; In the bigger area of air humidity, can suitably increase the thickness of hygroscopicity surface layer 1, at extremely frigid zones; The thickness that then can suitably increase water proofing property bottom 2 is considered the weight and the cost of production of body of wall link plate, under the preferable case to improve heat insulation effect; The thickness of said hygroscopicity surface layer 1 can be 1-20mm, and the thickness of said water proofing property bottom 2 can be 10-50mm.
According to the present invention; The distribution mode of said link plate skeleton 3 has no particular limits; Under the preferable case, said link plate skeleton 3 is fixed in the said hygroscopicity surface layer 1 equably or is fixed in the said water proofing property bottom 2, perhaps is fixed on equably between said hygroscopicity surface layer 1 and the said water proofing property bottom 2; For example, said link plate skeleton 3 can be the distribution of " well " word shape.The material of said link plate skeleton 3 has no particular limits, as long as can improve the intensity and the pulling capacity of said body of wall link plate, for example, what the material of said link plate skeleton 3 can be in reinforcing bar, nylon rod and the sticking plaster is at least a.Under the preferable case, said link plate skeleton 3 is a plurality of, and a plurality of said link plate skeletons 3 are connected to each other through link 4, through link 4 said link plate skeleton 3 is connected to each other, and makes the material of link plate skeleton 3 select not receive the restriction of processing technology.
The kind of said link 4 has no particular limits, as long as can said link plate skeleton 3 be connected together.
A kind of preferred embodiment in, said link 4 can comprise body 5, be used for fixing first hole 6 and second hole 7 of link plate skeleton 3, wherein, said first hole 6 and second hole 7 are arranged in body 5, and first hole 6 and second hole 7 are separated from one another.
Said first hole 6 and second hole 7 can be through holes, also can make blind hole, as long as can link plate skeleton 3 be fixed together, under the preferable case, said first hole 6 and second hole 7 are through holes.Angle between the center line in said first hole 6 and second hole 7 has no particular limits; Can in very large range change according to the trend of said link plate skeleton 3; For example, the center line in said first hole 6 and second hole 7 can be perpendicular to one another, parallel or with other angle, under the preferable case; The center line in said first hole 6 and second hole 7 is perpendicular to one another, and distributes thereby can make said link plate skeleton 3 be " well " word shape.
The shape of the body 5 of said link 4 has no particular limits, and for example, said body 5 can be spheroid, ellipsoid, cuboid or square, and under the preferable case, said body 5 is a square.
According to the present invention, said body of wall link plate can be arranged on the body of wall through various modes well known in the art, for example, and through the mode of pasting.For the ease of said body of wall link plate fixing on building, under the preferable case, the body 5 of said link 4 can also have 8, the three holes 8, the 3rd hole and be used for fixing securing member, and said body of wall link plate is connected with body of wall through securing member.
Angle between the center line in said first hole 6, second hole 7 and the 3rd hole 8 has no particular limits; As long as be convenient to said body of wall link plate is fixed on the building; Under the preferable case, the center line in said first hole 6, second hole 7 and the 3rd hole 8 is perpendicular to one another.
The kind of said securing member is conventionally known to one of skill in the art, for example, can be in screw, screw rod, rivet and the back of the body bolt one or more.
According to the present invention, said body of wall link plate can be used sheet material with sheet material and/or inner wall of building as skin, is preferably used as inner wall of building and uses sheet material.
The preparation method of said body of wall link plate has no particular limits; For example; Can be respectively the material of hygroscopicity surface layer 1 and water proofing property bottom 2 be joined in the mould, link plate skeleton 3 is set, solidify; Said link plate skeleton 3 is arranged in said hygroscopicity surface layer 1 or the water proofing property bottom 2, perhaps is arranged between said hygroscopicity surface layer 1 and the water proofing property bottom 2.
The material of the material of the material of said hygroscopicity surface layer 1, water proofing property bottom 2 and link plate skeleton 3 and content are on the books hereinbefore, repeat no more at this.
According to the present invention; The set-up mode of said link plate skeleton 3 has no particular limits; Under the preferable case, said link plate skeleton 3 is arranged in the said hygroscopicity surface layer 1 equably or is arranged in the said water proofing property bottom 2, perhaps is arranged on equably between said hygroscopicity surface layer 1 and the said water proofing property bottom 2; For example, said link plate skeleton 3 can be the distribution of " well " word shape.
Under the preferable case, said link plate skeleton 3 is connected to each other through link 4, through link 4 said link plate skeleton 3 is connected to each other, and makes the material of link plate skeleton 3 select not receive the restriction of processing technology.The kind of said link 4 has no particular limits, as long as can said link plate skeleton 3 be connected together.Preferred use link 4 provided by the invention, the structure of said link 4 is as indicated above, repeats no more at this.
According to the present invention; The method of said curing has no particular limits, as long as hygroscopicity surface layer 1 and water proofing property bottom 2 are solidified, under the preferable case; Can be through being heating and curing and/or the method for microwave curing is cured; Preferably be cured through the mode that is heating and curing, the temperature of said curing is 20-120 ℃, and the time of curing is 1-24 hour.
Through embodiment the present invention is described in more details below.
Embodiment 1
Present embodiment is used to explain body of wall link plate provided by the invention.
(1) silica sand (mean particle diameter is 500 μ m), the 6 parts by weight of epoxy resin cementing agents (west, Guangzhou card constructional materials Co., Ltd, Sika 731) with 100 weight portions mix, and obtain the hygroscopicity surface layer and use material.
(2) with the waterproof sand (Beijing Huichuang Technology Group Co., Ltd of 100 weight portions; STS-303; Mean particle diameter is 120 μ m), the perlite (mean particle diameter is 2mm) of 3 weight portions, (Lafarge 425#) mixes the cement of 25 weight portions, obtains the water proofing property bottom and uses material.
(3) in being of a size of 30 * 60 * 3 centimetres steel die, add the hygroscopicity surface layer that obtains in the step (1) and use material; Afterwards; " well " font link plate skeleton (diameter is 4mm, cold-drawn bar) is set, afterwards the water proofing property bottom that obtains in the step (2) is joined in the mould with material; Solidified 6 hours down at 80 ℃, obtain body of wall link plate A1.
The addition of the material that step (1) and step (2) obtain, the thickness that makes the surface layer of the sheet material that obtains is 0.8 centimetre, the thickness of bottom is 2.2 centimetres.
Embodiment 2
Present embodiment is used to explain body of wall link plate provided by the invention.
(1) silica sand (mean particle diameter is 80 μ m), the 25 parts by weight of epoxy resin cementing agents (west, Guangzhou card constructional materials Co., Ltd, Sika 731) with 100 weight portions mix, and obtain the hygroscopicity surface layer and use material.
(2) with the waterproof sand (Beijing Huichuang Technology Group Co., Ltd of 100 weight portions; STS-303; Mean particle diameter is 100 μ m), the haydite (mean particle diameter is 10mm) of 15 weight portions, (Lafarge 425#) mixes the cement of 35 weight portions, obtains the water proofing property bottom and uses material.
(3) in being of a size of 30 * 60 * 3 centimetres steel die, add the hygroscopicity surface layer that obtains in the step (1) and use material; Afterwards; " well " font link plate skeleton (diameter is 4mm, cold-drawn bar) is set, afterwards the water proofing property bottom that obtains in the step (2) is joined in the mould with material; Solidified 20 hours down at 40 ℃, obtain body of wall link plate A2.
The addition of the material that step (1) and step (2) obtain, the thickness that makes the surface layer of the sheet material that obtains is 1.5 centimetres, the thickness of bottom is 3.5 centimetres.
Embodiment 3
Present embodiment is used to explain body of wall link plate provided by the invention.
(1) with the silica sand (mean particle diameter is 100 μ m) of 100 weight portions, 5 parts by weight of epoxy resin cementing agents (west, Guangzhou card constructional materials Co., Ltd; Sika 731), the polyurethane resin cementing agent of 5 weight portions (crosses company of limit chemicals (Guangzhou) Co., Ltd; Ws-5000) mix, obtain the hygroscopicity surface layer and use material.
(2) with the waterproof sand (Beijing Huichuang Technology Group Co., Ltd of 100 weight portions; STS-303; Mean particle diameter is 120 μ m), the vermiculite (mean particle diameter is 5mm) of 10 weight portions, (Lafarge 425#) mixes the cement of 10 weight portions, obtains the water proofing property bottom and uses material.
(3) in being of a size of 45 * 90 * 4 centimetres steel die, add the hygroscopicity surface layer that obtains in the step (1) and use material; Afterwards; " well " font link plate skeleton (diameter is 4mm, cold-drawn bar) is set, afterwards the water proofing property bottom that obtains in the step (2) is joined in the mould with material; Solidified 4 hours down at 100 ℃, obtain body of wall link plate A3.
The addition of the material that step (1) and step (2) obtain, the thickness that makes the surface layer of the sheet material that obtains is 1 centimetre, the thickness of bottom is 3 centimetres.
Embodiment 4
Present embodiment is used to explain body of wall link plate provided by the invention.
(1) with the silica sand (mean particle diameter is 120 μ m) of 100 weight portions, the fire retardant (aluminium hydroxide of 10 weight portions; Mean particle diameter is 20 μ m), 5 parts by weight of epoxy resin cementing agents (Guangzhou west card constructional materials Co., Ltd; Sika 731) mix, obtain the hygroscopicity surface layer and use material.
(2) with the waterproof sand (Beijing Huichuang Technology Group Co., Ltd of 100 weight portions; Mean particle diameter is 100 μ m), unsaturated-resin cementing agent (the Tianjin resin Co., Ltd of nation difficult to understand of the vermiculite (mean particle diameter is 5mm) of 8 weight portions, 8 weight portions; 168f) mix, obtain the water proofing property bottom and use material.
(3) in being of a size of 30 * 60 * 3 centimetres steel die, add the hygroscopicity surface layer that obtains in the step (1) and use material; Afterwards; " well " font link plate skeleton (diameter is 4mm, cold-drawn bar) is set, afterwards the water proofing property bottom that obtains in the step (2) is joined in the mould with material; Solidified 4 hours down at 120 ℃, obtain body of wall link plate A4.
The addition of the material that step (1) and step (2) obtain, the thickness that makes the surface layer of the sheet material that obtains is 1 centimetre, the thickness of bottom is 2 centimetres.
Embodiment 5
Present embodiment is used to explain body of wall link plate provided by the invention.
(1) with the silica sand (mean particle diameter is 70 μ m) of 100 weight portions, the fire retardant (antimony trioxide of 20 weight portions; Mean particle diameter is 10 μ m), (magnesium hydroxide of 10 weight portions; Mean particle diameter is 8 μ m), 10 parts by weight of epoxy resin cementing agents (Guangzhou west card constructional materials Co., Ltd; Sika 731), (Tianjin resin Co., Ltd of nation difficult to understand 168f) mixes, and obtains the hygroscopicity surface layer and uses material for the unsaturated-resin cementing agent of 5 weight portions.
(2) with the waterproof sand (Beijing Huichuang Technology Group Co., Ltd of 100 weight portions; Mean particle diameter is 100 μ m), unsaturated-resin cementing agent (the Tianjin resin Co., Ltd of nation difficult to understand of the vermiculite granule (mean particle diameter is 1mm) of 5 weight portions, 8 weight portions; 168f) mix, obtain the water proofing property bottom and use material.
(3) in being of a size of 30 * 60 * 5 centimetres steel die, add the hygroscopicity surface layer that obtains in the step (1) and use material; Afterwards; " well " font link plate skeleton (diameter is 4mm, cold-drawn bar) is set, afterwards the water proofing property bottom that obtains in the step (2) is joined in the mould with material; Solidified 5 hours down at 120 ℃, obtain body of wall link plate A5.
The addition of the material that step (1) and step (2) obtain, the thickness that makes the surface layer of the sheet material that obtains is 1.0 centimetres, the thickness of bottom is 4.0 centimetres.
Embodiment 6-10
Respectively the body of wall link plate A1-A5 that makes among the embodiment 1-5 is weighed, in the submergence entry, from water, pulls out then, place till not dripping, weigh again, obtain water content, compare with the area of the hygroscopicity surface layer of body of wall link plate the hygroscopic coefficient of surface layer.Afterwards, use that (tianjin building material instrument company HP-30) detects the deep water coefficient of the bottom of body of wall link plate A1-A5 respectively with pressurization concrete water-permeating property testing appearance test automatically.And with thermal conductivity measuring apparatus (Tianjin English Bel development in science and technology Co., Ltd imDRY3001-II) detects the coefficient of thermal conductivity of body of wall link plate A1-A5 respectively.The result is as shown in table 1 below.
Table 1
| The embodiment numbering |
The link plate numbering |
Hygroscopic coefficient (g/cm
2)
|
Seepage flow coefficient (cm/s) |
Coefficient of thermal conductivity W/ (mK) |
| Embodiment 1 |
A1 |
0.25 |
1×10
-9 |
0.15 |
| Embodiment 2 |
A2 |
0.48 |
1.5×10
-10 |
0.1 |
| Embodiment 3 |
A3 |
0.4 |
1.8×10
-7 |
0.12 |
| Embodiment 4 |
A4 |
0.6 |
1.5×10
-7 |
0.11 |
| Embodiment 5 |
A5 |
0.5 |
1×10
-6 |
0.08 |
Can find out that from the data of last table 1 coefficient of thermal conductivity of body of wall link plate provided by the invention can reach requirement, and the seepage flow coefficient of the hygroscopic coefficient on hygroscopicity top layer and water proofing property bottom also can reach requirement; Thereby make body of wall link plate provided by the invention except having thermal property, also have the function of regulating air humidity, when airborne water content is big; But the moisture content of the hygroscopicity surface layer absorption portion of said body of wall link plate; Simultaneously because bottom has water proofing property, guaranteed that moisture can not get into body of wall and only remains in the surface layer through bottom, the evaporation of moisture goes out in the said hygroscopicity surface layer when air is comparatively dry; Therefore; Can regulate the humidity of air, thereby when guaranteeing thermal property, reduce the life energy consumption of building further.