CN102225461B - Method for preparing selectively enhanced aluminum-based composite from ceramic particles - Google Patents

Method for preparing selectively enhanced aluminum-based composite from ceramic particles Download PDF

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CN102225461B
CN102225461B CN 201110083293 CN201110083293A CN102225461B CN 102225461 B CN102225461 B CN 102225461B CN 201110083293 CN201110083293 CN 201110083293 CN 201110083293 A CN201110083293 A CN 201110083293A CN 102225461 B CN102225461 B CN 102225461B
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base substrate
pore creating
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porous ceramics
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CN102225461A (en
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曲选辉
章林
何新波
任淑彬
秦明礼
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University of Science and Technology Beijing USTB
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Abstract

The invention relates to a method for preparing selectively enhanced aluminum-based composite from ceramic particles and belongs to the field of metal matrix composites (MMCs). The preparation method comprises the following steps: firstly, preparing porous ceramic blanks; and secondly, putting the porous ceramic blanks at a part needing to be enhanced, injecting molten alloy into a mould at 750-1,100 DEG C, applying pressure of 20-50MPa to forcibly fill the molten alloy into the porous ceramic blanks and a mold cavity, and solidifying, thus obtaining the selectively enhanced aluminum-based composite. The method has the advantages that a foaming technology, an injection molding and a gel casting process are combined, thus leading the porous ceramic blank to have designability; the MMC reinforcement and an aluminum matrix are integrally formed by adopting extrusion casting process, thus fully playing the advantages of high strength and high toughness of the aluminum matrix and wear resistance of the MMC reinforcement. The composite has the advantages of high thermal conductivity, good radiation capability, excellent wear resistance and light weight.

Description

The preparation method of the selective reinforced aluminum matrix composites of a kind of ceramic particle
Technical field
The invention belongs to field of research of metal, a kind of method for preparing the selective reinforced aluminum matrix composites of ceramic particle is provided especially.
Background technology
Aluminum matrix composite all is widely used at Aeronautics and Astronautics and automotive field.In some structural members, require composite that enough strength and stiffness should be arranged, possess again good heat conductivility and anti-wear performance, the brake drum that for example uses on the wheel, it must possess good comprehensive mechanical property (high strength and high tenacity) to bear very high torque load, excellent friction and wear behavior is arranged again to realize braking function, also require simultaneously it to have high thermal conductivity to discharge fricative amount of heat.Harsh requirement is that single aluminium alloy or single aluminum matrix composite are all implacable like this.Single aluminium alloy (such as reflectal and extra super duralumin alloy) can not satisfy local anti-wear performance requirement although can guarantee the comprehensive mechanical property of structural member excellence.There is the low problem of Material ductility in single aluminum matrix composite (Metal matrix composites, MMC) although can satisfy the requirement of anti-wear performance and thermophysical property excellence, makes composite lack enough toughness, has reduced fatigue strength.In addition, single aluminum matrix composite is difficult to hole and other mechanical process.If high strength alumin ium alloy and wear-resisting aluminum matrix composite are combined, just can give full play to the thermophysical property of two constituent elements and the characteristic of friction and wear behavior excellence, kept simultaneously the light-weighted huge advantage of aluminum matrix composite.
The Liquid preparation methods aluminum matrix composite is that molten aluminium alloy is infiltrated the porous ceramics base substrate by the method for pressure impregnation or pressure-free impregnation at present, and the single aluminum matrix composite that obtains can not satisfy the requirement to mechanical property, thermophysical property and anti-wear performance simultaneously.Therefore, need to adopt hard ceramic particles or fiber to strengthen.Ceramic phase is introduced with the form of porous ceramics base substrate, in casting process, place the privileged sites that need to strengthen selectively to strengthen the porous ceramics base substrate, and make under pressure molten aluminium alloy infiltrate porous ceramics base substrate and loading mould cavity, be equivalent in foundry goods, embed metal-base composites behind the alloy graining and strengthen body, and all the other positions still are Birmasil low-cost, that easily process.This part is that the aluminum matrix composite of metal-base composites enhancing body is called novel MMC/Al composite, and it not only has high strength and stiffness, also has excellent thermophysical property (high heat conductance and low thermal coefficient of expansion) and friction and wear behavior.The method is that a new road has been opened up in the research and development of aluminum matrix composite.
Novel MMC/Al composite all has broad application prospects in military project and civil area, is suitable for preparing some brake assemblies and engine pack.In brake assemblies, can use this technology and prepare brake drum, clutch disc, brake disc and caliper.In engine pack, this novel MMC/Al composite can be used as the parts such as all-aluminium piston, cylinder jacket or connecting rod.This novel MMC/Al composite is substituted the structural members such as cast iron brake drum in the military vehicle and creeper tread and will play significant weight loss effect, to the lightweight of weaponry, and mobility and design freedom have very important significance.
Summary of the invention
The objective of the invention is to disclose the preparation technology of the selective reinforced aluminum matrix composites of a kind of ceramic body.By extrusion casint high strength alumin ium alloy matrix and local MMC are strengthened body in conjunction with as a whole, can be fully the characteristic wear-resistant, that thermophysical property is excellent of high strength, high tenacity and the MMC enhancing body of aluminum substrate be brought into play.
The technique that the present invention prepares selective reinforced aluminum matrix composites mainly is divided into two steps: the firstth, and the preparation of porous ceramics base substrate; The secondth, extrusion casint, integral forming.
1. the preparation of porous ceramics base substrate
The porous ceramics base substrate adopts " adding pore creating material+injection molding method " and " adding pore creating material+gel injection-moulding method " two kinds of techniques to prepare:
1.1 add pore creating material+injection molding method
The primary raw material of porous ceramics base substrate is that particle diameter is the SiC powder of 10 ~ 106 μ m.Purity is greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder is as sintering aid.Particle diameter is that the polymethyl methacrylate (PMMA) of 100 ~ 600 μ m serves as pore creating material, PMMA is suitable as the pore creating material of injection molding process, this is because its initial decomposition temperature is 340 ℃, removing temperature fully is 425 ℃, therefore under melting temperature (145-175 ℃), can not decompose, can occupy space certain in the base substrate.In addition, also added a kind of inorganic binder.
At first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid.Then in the SiC powder, add the Al of 5 ~ 30wt.% 2O 3-Y 2O 3-SiO 2The inorganic binder of sintering aid and 1 ~ 5wt.% (such as sodium silicate etc.), thus mixed-powder A obtained.The pore creating material PMMA that then adds 10 ~ 40 volume % in mixed-powder A obtains mixed powder B.Mixed powder B speed with 150 ~ 250 rev/mins on ball mill is mixed 8 ~ 24h.Powder B after mixing and polymer constituent element paraffinic base binding agent (45 ~ 70wt.% paraffin, 10 ~ 25wt.% high density polyethylene (HDPE), 15 ~ 20wt.% polypropylene and 5 ~ 10 weight stearic acid) carry out mixing and obtain even feeding at two roll press, and powder B accounts for 50 ~ 68 volume % of feeding.Subsequently with this feeding on the powder injection forming machine with 145~175 ℃ injection temperature and the injection pressure forming of 75~125MPa, obtain the preform of required form.Preform carries out solvent degreasing with after removing the part binding agent first in trichloro-ethylene solution, then with 0.5 ~ 5 ℃/minute speed be warmed up to 400 ~ 800 ℃ to remove most of binding agent and pore creating material, at last in vacuum atmosphere or air atmosphere, carrying out sintering under 1200~1700 ℃ the temperature, thereby obtain the porous ceramics base substrate.
1.2 add pore creating material+gel injection-moulding method
Injection molding technology is relatively more difficult when preparation large-size ceramic base substrate, adopts the gel injection-moulding method can overcome this shortcoming, and it can realize the near-net forming of large scale, complicated shape porous ceramics base substrate.Adopt water base acrylamide gel system that ceramic powders is carried out gel casting, control porosity by the addition of regulating pore creating material.At first with monomer (acrylamide) and crosslinking agent (N; N '-methylene-bisacrylamide) carries out proportioning for 10:1 ~ 40:1 in mass ratio; and be 10% ~ 30% to be dissolved in the premixed liquid of making transparent and homogeneous in the deionized water by total mass concentration; then mix ball milling 8 ~ 24h acquisition suspended nitride under the N2 protective atmosphere after adding the dispersant (ammoniacal liquor) of the mixed powder B that obtains in 1.1 joints and mixed powder B volume 0.1% ~ 5% and 0.05% ~ 3% defoamer (isooctanol) in the premixed liquid.Through after the froth in vacuum, slurry is injected mould and in 40 ℃ ~ 80 ℃ insulations gel reaction fully carried out, slurry curing becomes the base substrate of required form and size, and this base substrate just obtains preform through the vacuum constant temperature drying again.Preform is warmed up to 400 ~ 800 ℃ to remove binding agent and pore creating material with 30 ℃/hour speed, then in carrying out sintering under 1200~1700 ℃ the temperature in vacuum or air atmosphere, thereby obtains the porous ceramics base substrate.
2. extrusion casint integral forming
Adopt extrusion molding-extrusion casint integral forming technology to prepare novel MMC/Al composite.Figure 2 shows that Extrution casting technique prepares the schematic diagram of the selective reinforced aluminum matrix composites of ceramic body.Selected the high strength alumin ium alloy of two kinds of compositions: a kind of composition of aluminium alloy is 6.5 ~ 8wt.%Si, 3.5 ~ 4.5wt.%Cu and surplus Al.The composition of another kind of aluminium alloy is 6 ~ 9wt.%Zn, 1 ~ 3wt.%Mg, 1 ~ 3wt.%Cu and surplus Al.At first the porous ceramics base substrate is placed on the position that needs enhancing, in 750~1100 ℃ temperature range, molten aluminium alloy is slowly injected mould to avoid the base substrate displacement, crackle occurs and turbulent flow occurs subsequently, then under the pressure of 20 ~ 50MPa, force the filling porous ceramic body of molten aluminium alloy and die cavity, the ceramic body after the infiltration and aluminium alloy under the effect of pressure in conjunction with as a whole.High pressure helps the porous ceramics base substrate to be completely filled, and has effectively reduced casting flaw.Figure 3 shows that a kind of microscopic structure of novel MMC/Al composite, visible porous ceramics base substrate is filled fully by aluminium alloy, ceramic particle being evenly distributed in matrix, and the metallurgical interface combination that aluminium alloy and MMC strengthen between the body is good.
Advantage of the present invention is mainly reflected in the following aspects:
(1) the porous ceramics base substrate has designability.Can according to concrete instructions for use to geometry, size, the composition (content of friction component and lubricant component) of porous ceramics base substrate, porosity designs and select suitable preparation method.
(2) extrusion casint realizes integral forming.It not merely is a simple substrate in composite that metal-base composites strengthens body (MMC).MMC strengthens body and form an organic whole with alloy matrix aluminum in extrusion casint integral forming process, has avoided because coming off of causing of MMC enhancing body and the difference of aluminum substrate thermal coefficient of expansion or separate.The high strength alumin ium alloy matrix has given composite enough strength and stiffness, and MMC strengthens the wear-resisting effect of body performance, has therefore realized the unification of 26S Proteasome Structure and Function.
(3) excellent in abrasion resistance.The hard phase (ceramic particle or ceramic fibre) that MMC strengthens in the body has been given the friction and wear behavior of composite excellence.By the porosity of control porous ceramics base substrate, the type of ceramic phase, content, particle diameter, particle diameter distribute and add other friction component and lubricant component just can effectively be controlled friction and wear behavior.
(4) thermal conductivity is high, and heat-sinking capability is good.MMC strengthens body and the Al alloy substrate all has higher thermal conductivity, fricative amount of heat can be distributed timely, thereby keep stationary temperature.This is conducive to keep the stability of frictional behaviour and increase the service life.
(5) lightweight.MMC/Al composite lightweight, if this novel composite is replaced traditional cast iron product for military vehicle or other weaponrys such as panzers, to play significant weight loss effect, this all has very important significance to the lightweight of weaponry and fuel savings, minimizing discharging.
Description of drawings
Fig. 1 is process chart of the present invention
Fig. 2 is the schematic diagram that Extrution casting technique prepares selective reinforced aluminum matrix composites
Fig. 3 is the microscopic structure of the selective reinforced aluminum matrix composites of a kind of ceramic body
The specific embodiment
Embodiment 1: the ceramic phase volume mark is 35% aluminum matrix composite in the preparation MMC enhancing body
Powder stock is the SiC particle of 24 μ m, polymethyl methacrylate (PMMA), a kind of inorganic binder and purity that particle diameter is 100 μ m greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder.
The preparation of porous ceramics base substrate: at first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid.Then in the SiC powder, add the Al of 10wt.% 2O 3-Y 2O 3-SiO 2The inorganic binder of sintering aid and 3wt.% (sodium metasilicate), thus mixed-powder A obtained.The pore creating material PMMA that then adds 20 volume % in mixed-powder A obtains mixed powder B.Mixed powder B speed with 200 rev/mins on ball mill is mixed 8h.Powder B after mixing and polymer constituent element paraffinic base binding agent (65wt.% paraffin, 15wt.% high density polyethylene (HDPE), 15wt.% polypropylene and 5wt.% stearic acid) carry out mixing and obtain uniform feeding at two roll press, and powder B accounts for 50 volume % of feeding.Subsequently, this feeding being shaped on the powder injection forming machine, is obtained the preform of required form under the injection pressure of 150 ℃ injection temperature, 75MPa.Preform carries out solvent degreasing with after removing the part binding agent first in trichloro-ethylene solution, then be warmed up to 750 ℃ to remove most of binding agent and pore creating material with 30 ℃/hour speed, at last under 1550 ℃ temperature, in vacuum atmosphere, carry out sintering, thereby obtain the porous ceramics base substrate.
Extrusion casint: extrusion casint is 7.5wt.%Si, 3.5wt.%Cu and surplus Al with the composition of aluminium alloy.The porous ceramics base substrate is placed on the position that needs enhancing, in 1000 ℃ temperature range, molten aluminium alloy is slowly injected graphite jig subsequently, then under the pressure of 20MPa, force the filling porous ceramic body of molten aluminium alloy and die cavity, in conjunction with as a whole, wherein the ceramic phase volume mark is 35% in the MMC enhancing body under the effect of pressure for ceramic body after the infiltration and aluminium alloy
Embodiment 2: the ceramic phase volume mark is 45% aluminum matrix composite in the preparation MMC enhancing body
Powder stock is the SiC particle of 40 μ m, polymethyl methacrylate (PMMA), a kind of inorganic binder and purity that particle diameter is 300 μ m greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder.
The preparation of porous ceramics base substrate: at first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid.Then in the SiC powder, add the Al of 20wt.% 2O 3-Y 2O 3-SiO 2The inorganic binder of sintering aid and 2wt.% (sodium metasilicate), thus mixed-powder A obtained.The pore creating material PMMA that then adds 10 volume % in mixed-powder A obtains mixed powder B.Mixed powder B speed with 250 rev/mins on ball mill is mixed 12h.Powder B after mixing and polymer constituent element paraffinic base binding agent (60wt.% paraffin, 20wt.% high density polyethylene (HDPE), 15wt.% polypropylene and 5wt.% stearic acid) carry out mixing and obtain even feeding at two roll press, and powder B accounts for 60 volume % of feeding.Subsequently, this feeding being shaped on the powder injection forming machine, is obtained the preform of required form under the injection pressure of 160 ℃ injection temperature, 80MPa.Preform carries out solvent degreasing with after removing the part binding agent first in trichloro-ethylene solution, then be warmed up to 700 ℃ to remove most of binding agent and pore creating material with 30 ℃/hour speed, at last under 1450 ℃ temperature, in air atmosphere, carry out sintering, thereby obtain the porous ceramics base substrate.
Extrusion casint: extrusion casint is 7wt.%Zn with the composition of aluminium alloy, 2.2wt.%Mg, 2.5wt.%Cu and surplus Al.The porous ceramics base substrate is placed on the position that needs enhancing, in 900 ℃ temperature range, molten aluminium alloy is slowly injected graphite jig subsequently, then under the pressure of 30MPa, force the filling porous ceramic body of molten aluminium alloy and die cavity, in conjunction with as a whole, wherein the ceramic phase volume mark is 45%. in the MMC enhancing body under the effect of pressure for ceramic body after the infiltration and aluminium alloy
Embodiment 3: the ceramic phase volume mark is 45% large scale aluminum matrix composite in the preparation MMC enhancing body
Powder stock is the SiC particle of 40 μ m, polymethyl methacrylate (PMMA), a kind of inorganic binder and purity that particle diameter is 300 μ m greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder.
The preparation of porous ceramics base substrate: at first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid.Then in the SiC powder, add the Al of 10wt.% 2O 3-Y 2O 3-SiO 2The inorganic binder of sintering aid and 3wt.%, thus mixed-powder A obtained.The pore creating material PMMA that then adds 30 volume % in mixed-powder A obtains mixed powder B.Mixed powder B speed with 250 rev/mins on ball mill is mixed 24h.With acrylamide, N, N '-methylene-bisacrylamide carries out proportioning for 24:1 in mass ratio, and be 20% to be dissolved in the premixed liquid of making transparent and homogeneous in the deionized water by total mass concentration, then add in the premixed liquid behind the ammoniacal liquor dispersant of mixed powder B and mixed powder B volume 1% and 0.3% the isooctanol defoamer and carry out mix and blend, at N 2Ball milling 24h obtains suspended nitride under the protective atmosphere.After froth in vacuum, slurry is injected mould and in 60 ℃ of insulations gel reaction fully carried out, slurry curing becomes the base substrate of required form and size.Base substrate is through the dry dry body that obtains of vacuum constant temperature.Then be warmed up to 650 ℃ to remove binding agent and pore creating material with 30 ℃/hour speed, then under 1550 ℃ temperature, in vacuum atmosphere, carry out sintering, thereby obtain the porous ceramics base substrate.
Extrusion casint: extrusion casint is 6.5wt.%Si, 4.5wt.%Cu and surplus Al with the composition of aluminium alloy.The porous ceramics base substrate is placed on the position that needs enhancing, in 1100 ℃ temperature range, molten aluminium alloy is slowly injected graphite jig subsequently, then under the pressure of 30MPa, force the filling porous ceramic body of molten aluminium alloy and die cavity, the ceramic body after the infiltration and aluminium alloy under the effect of pressure in conjunction with as a whole.Wherein the ceramic phase volume mark is 45% in the MMC enhancing body.
Embodiment 4: the ceramic phase volume mark is 65% aluminum matrix composite in the preparation MMC enhancing body
Powder stock is the SiC particle of 24 μ m, polymethyl methacrylate (PMMA), a kind of inorganic binder and purity that particle diameter is 100 μ m greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder.
The preparation of porous ceramics base substrate: at first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid.Then in the SiC powder, add the Al of 15wt.% 2O 3-Y 2O 3-SiO 2The inorganic binder of sintering aid and 5wt.%, thus mixed-powder A obtained.The pore creating material PMMA that then adds 20 volume % in mixed-powder A obtains mixed powder B.Mixed powder B speed with 200 rev/mins on ball mill is mixed 16h.With acrylamide, N, N '-methylene-bisacrylamide carries out proportioning for 30:1 in mass ratio, and be 18% to be dissolved in the premixed liquid of making transparent and homogeneous in the deionized water by total mass concentration, then carry out mix and blend after adding the ammoniacal liquor dispersant of mixed powder B and mixed powder B volume 0.5% and 0.1% isooctanol defoamer in the premixed liquid, at N 2Ball milling 24h obtains suspended nitride under the protective atmosphere.After froth in vacuum, slurry is injected mould and in 65 ℃ of insulations gel reaction fully carried out, slurry curing becomes the base substrate of required form and size.Base substrate is through the dry dry body that obtains of vacuum constant temperature.Then be warmed up to 650 ℃ to remove binding agent and pore creating material with 30 ℃/hour speed, then under 1500 ℃ temperature, in vacuum atmosphere, carry out sintering, thereby obtain the porous ceramics base substrate.
Extrusion casint: extrusion casint is 7wt.%Zn with the composition of aluminium alloy, 2wt.%Mg, 2.5wt.%Cu and surplus Al.The porous ceramics base substrate is placed on the position that needs enhancing, in 1100 ℃ temperature range, molten aluminium alloy is slowly injected graphite jig subsequently, then under the pressure of 20MPa, force the filling porous ceramic body of molten aluminium alloy and die cavity, in conjunction with as a whole, wherein the ceramic phase volume mark is 65% in the MMC enhancing body under the effect of pressure for ceramic body after the infiltration and aluminium alloy.

Claims (2)

1. the preparation method of the selective reinforced aluminum matrix composites of ceramic particle, it is characterized in that: the preparation method is divided into two steps: step 1 is the preparation of porous ceramics base substrate; Step 2 is extrusion casint, integral forming;
The preparation of step 1, porous ceramics base substrate
The porous ceramics base substrate adopts " adding pore creating material+injection molding method " or " adding pore creating material+gel injection-moulding method " to prepare:
1) adds pore creating material+injection molding method
The primary raw material of porous ceramics base substrate is that particle diameter is the SiC powder of 10~106 μ m, adopts purity greater than 98% Al 2O 3, Y 2O 3And SiO 2Powder is as sintering aid, is that the polymethyl methacrylate of 100-600 μ m serves as pore creating material with particle diameter, also adds polymer constituent element paraffinic base binding agent;
At first with Al 2O 3, Y 2O 3And SiO 2Powder makes Al after mixing by the weight ratio of 6:3:1 2O 3-Y 2O 3-SiO 2Sintering aid; Then in the SiC powder, add 5~30% Al of SiC powder weight 2O 3-Y 2O 3-SiO 2Sintering aid and 1~5% inorganic binder obtain mixed-powder A; 10~40% of interpolation A volume pore creating material polymethyl methacrylate obtains mixed powder B in mixed-powder A; Mixed powder B speed with 150~250 rev/mins on ball mill was mixed 8~24 hours, add in the powder B that mixes behind the polymer constituent element paraffinic base binding agent at two roll press and carry out mixing and obtain even feeding, wherein powder B accounts for 50~68% of feeding volume; With this feeding on the powder injection forming machine with 145~175 ℃ injection temperature and the injection pressure forming of 75~125MPa, obtain the preform of required form; Preform carries out solvent degreasing with after removing the part binding agent first in trichloro-ethylene solution, then with 0.5~5 ℃/minute speed be warmed up to 400~800 ℃ to remove most of binding agent and pore creating material, at last in vacuum atmosphere or air atmosphere, carrying out sintering under 1200~1700 ℃ the temperature, thereby obtain the porous ceramics base substrate;
2) add pore creating material+gel injection-moulding method
Adopt water base acrylamide gel system that ceramic powders is carried out gel casting, control porosity by the addition of regulating pore creating material; At first with acrylamide and N, N '-methylene-bisacrylamide carries out proportioning for 10:1~40:1 in mass ratio, and be 10%~30% to be dissolved in the premixed liquid of making transparent and homogeneous in the deionized water by total mass concentration, then mix after adding 0.05%~3% isooctanol of 0.1%~5% ammoniacal liquor of mixed powder B that step 1) obtains, mixed powder B volume and mixed powder B volume in the premixed liquid, at N 2Ball milling 8~24h obtains suspended nitride under the protective atmosphere; Through after the froth in vacuum, slurry is injected mould and in 40 ℃~80 ℃ insulations gel reaction fully carried out, slurry curing becomes the base substrate of required form and size, and this base substrate is again through obtaining preform after the vacuum constant temperature drying; Preform is warmed up to 400~800 ℃ to remove binding agent and pore creating material with 30 ℃/hour speed, then under 1200~1700 ℃ the temperature in vacuum or air atmosphere sintering, thereby obtain the porous ceramics base substrate;
Step 2, extrusion casint integral forming
Select high strength alumin ium alloy to adopt extrusion molding-extrusion casint integral forming technology to prepare the selective reinforced aluminum matrix composites of ceramic particle; Selected high strength alumin ium alloy composition weight percentage is: the Al of 6.5~8% Si, 3.5~4.5% Cu and surplus or weight percentage are 6~9% Zn, 1~3% Mg, 1~3% Cu and the Al of surplus; At first the porous ceramics base substrate is placed on the position that needs enhancing, in 750~1100 ℃ temperature range, the melting high strength alumin ium alloy is slowly injected mould subsequently; Under the pressure of 20~50MPa, force the filling porous ceramic body of melting high strength alumin ium alloy and die cavity, the ceramic body after the infiltration and aluminium alloy under the effect of pressure in conjunction with as a whole.
2. the preparation method of the selective reinforced aluminum matrix composites of ceramic particle as claimed in claim 1, it is characterized in that: described polymer constituent element paraffinic base Binder Composition and weight percentage are: 45~70% paraffin, 10~25% high density polyethylene (HDPE), 15~20% polypropylene and 5~10% stearic acid.
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CN117267285B (en) * 2023-11-21 2024-02-02 山西汤荣机械制造股份有限公司 Brake drum convenient to heat dissipation and casting device thereof

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