CN102204535A - Antibacterial composition containing picoxystrobin and chlorothalonil - Google Patents
Antibacterial composition containing picoxystrobin and chlorothalonil Download PDFInfo
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- CN102204535A CN102204535A CN2011100914983A CN201110091498A CN102204535A CN 102204535 A CN102204535 A CN 102204535A CN 2011100914983 A CN2011100914983 A CN 2011100914983A CN 201110091498 A CN201110091498 A CN 201110091498A CN 102204535 A CN102204535 A CN 102204535A
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- chlorothalonil
- bactericidal composition
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Abstract
The invention discloses an antibacterial composition containing picoxystrobin and chlorothalonil. The ratio of the active ingredients, namely the ratio of the picoxystrobin and the chlorothalonil is (1-60 percent):(1-80 percent). The composition disclosed by the invention can be used for preventing and controlling various diseases, has an obvious synergetic effect, expands an antibacterial spectrum and has high activity for downy mildew, powdery mildew, leaf spot, anthracnose, rice blast, epidemic disease, rust disease, Septoria nodorum in wheat, leaf blight and brown spot; the dose of pesticide is reduced, the residual pesticide on crops is reduced, and environment pollution is relieved; and safety for human beings and livestock and environmental compatibility are high, and diseases are insusceptible to producing chemical resistance.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of application of bactericidal composition on corps diseases that contains ZEN 90160 and tpn.
Background technology
ZEN 90160, English common name (picoxystrobin), molecular formula: C
18H
16F
3NO
4, chemical name: (E)-3-methoxy-2-[2-[6-(trifluoromethyl)-2-pyridine oxygen methyl] phenyl] methyl acrylate.The mitochondrial respiratory inhibitor promptly shifts by electronics between cytochrome b and c1 and suppresses mitochondrial breathing.Control is effective to the bacterial strain that 14-demethylation enzyme inhibitor, benzamides, dicarboxylic dihydrazides amine and benzimidazole produce resistance.
Tpn, English common name (chlorothalonil), molecular formula: C
8Cl
4N
2, chemical name: daconil M (2,4,5,6-tetrachloro-1,3-benzene dicarbonitrile).Tpn can with the combined with protein of cysteine in the glyceraldehyde 3-phosphate dehydro-genase among the fungal cell, destroy the metabolism of cell and loss of life power.It mainly acts on is the prevention fungal infection, inhales conduction in not having, but at plant surface good adhesivity is arranged, and is not subject to rain drop erosion, and the long drug effect phase is arranged.
Yet in the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.
The different cultivars composition carries out composite, is to prevent and treat the very common method of disease resistance.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, find and will can produce good synergistic effect behind ZEN 90160 and the chlorothalonil compound, and still unexposed about the relevant report and the application of ZEN 90160 and chlorothalonil compound.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of the single agent of ZEN 90160 may bring, the drug effect, the bactericidal composition that the present invention proposes contains ZEN 90160 and two kinds of active components of tpn, and an amount of surfactant and carrier.
A kind of bactericidal composition that contains ZEN 90160 and tpn comprises effective active component, auxiliary agent and filler, it is characterized in that: ZEN 90160 and tpn percentage by weight are 1～60%: 1～80%.
Described a kind of bactericidal composition that contains ZEN 90160 and tpn is characterized in that: the percentage by weight of ZEN 90160 and tpn is 5～40%: 5～70%.
The described bactericidal composition that contains ZEN 90160 and tpn is characterized in that: the percentage by weight of ZEN 90160 and tpn is 10～30%: 10～60%.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, the aluminium chloride.
Described binding agent is selected from: one or more in gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (the pure APEO of fat) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the defoamer etc. one or more again.
Bactericidal composition of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent or suspension emulsion.
When making wetting powder, composition comprises following constituent content: ZEN 90160 1～60%, tpn 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
Active component ZEN 90160, tpn, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: ZEN 90160 1～60%, tpn 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
Active component ZEN 90160, tpn, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is made suspending agent: ZEN 90160 1～20%, tpn 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, binding agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add active component ZEN 90160, tpn, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
Comprise following constituent content when composition is made suspension emulsion: ZEN 90160 1～20%, tpn 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of ZEN 90160, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the ZEN 90160 suspending agent, then with the former medicine of tpn, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
The invention has the advantages that: behind (1) ZEN 90160 and the chlorothalonil compound, have notable synergistic and lasting effect; (2) enlarged fungicidal spectrum, to downy mildew, powdery mildew, leaf spot, rice blast, eqpidemic disease, anthracnose, rust, wheat class glume blight, leaf blight, brown spot have greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), germ good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application Example one
Example 1 60% ZEN 90160 tpn wetting powder
ZEN 90160 5%, tpn 55%, naphthalene sulfonic acid-formaldehyde condensation product 7%, spaonin powder 6%, attapulgite to 100%, mixture carries out comminution by gas stream, makes 60% ZEN 90160 tpn wetting powder.
Example 2 70% ZEN 90160 tpn wetting powders
ZEN 90160 10%, tpn 60%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea are withered 6%, diatomite adds to 100%, and mixture carries out comminution by gas stream, makes 70% ZEN 90160 tpn wetting powder.
Example 3 80% ZEN 90160 tpn wetting powders
ZEN 90160 10%, tpn 70%, ester polyoxyethylene are phonetic 5%, soapberry powder 4%, white carbon to 100%, and mixture carries out comminution by gas stream, makes 80% ZEN 90160 tpn wetting powder.
Example 4 60% ZEN 90160 chlorothalonil water dispersible granules
ZEN 90160 10%, tpn 50%, alkylphenol-polyethenoxy are phonetic 8%, silkworm excrement 7%, ammonium sulfate 2.3%, kaolin add to 100%, mixed 60% ZEN 90160 chlorothalonil water dispersible granule.
Example 5 65% ZEN 90160 chlorothalonil water dispersible granules
ZEN 90160 5%, tpn 60%, lignosulfonates 7%, lauryl sodium sulfate 5%, bentonite add to 100%, the mixed 65% ZEN 90160 chlorothalonil water dispersible granule that gets.
Example 6 80% ZEN 90160 chlorothalonil water dispersible granules
ZEN 90160 30%, tpn 50%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 4%, urea 2.5%, white carbon add to 100%, the mixed 80% ZEN 90160 chlorothalonil water dispersible granule that gets.
Example 7 10% ZEN 90160 tpn suspending agents
ZEN 90160 5%, tpn 5%, polycarboxylate 8%, C
10～20Saturated fat acids 0.2%, PAA 1.8%, glycerine 1.6%, deionized water add to 100%, the mixed 10% ZEN 90160 tpn suspending agent that gets.
Example 8 35% ZEN 90160 tpn suspending agents
ZEN 90160 5%, tpn 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, silicone compound 0.4%, methylcellulose 1.4%, triethylene glycol 1.7%, deionized water add to 100%, the mixed 35% ZEN 90160 tpn suspending agent that gets.
Example 9 40% ZEN 90160 tpn suspending agents
ZEN 90160 10%, tpn 30%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, C
10～20Saturated fat acids 0.3%, polyvinylpyrrolidone 1.2%, polyethylene glycol 1.5%, deionized water add to 100%, the mixed 40% ZEN 90160 tpn suspending agent that gets.
Example 10 30% ZEN 90160 tpn suspension emulsions
ZEN 90160 5%, tpn 25%, aryl phenol polyoxyethylene succinate sulfonate 7%, spaonin powder 1%, polyvinyl alcohol 1.1%, Nongru-700 #7%, diethylene glycol (DEG) 1.3%, silicone oil 0.5%, water add to 100%, through the mixed 30% ZEN 90160 tpn suspension emulsion that gets.
Example 11 45% ZEN 90160 tpn suspension emulsions
ZEN 90160 10%, tpn 35%, polyoxyethylene carboxylate 6%, soapberry powder 2%, sodium phosphate trimer 1.7%, OP series phosphate 8%, glycerine 1.4%, C
8～10Aliphatic alcohols 0.2%, water add to 100%, through the mixed 45% ZEN 90160 tpn suspension emulsion that gets.
Example 12 48% ZEN 90160 tpn suspension emulsions
ZEN 90160 8%, tpn 40%, lignosulfonates 4%, lauryl sodium sulfate 3%, xanthans 1.5%, tween series 5%, ethylene glycol 1.3%, silicone compound 1.8%, water add to 100%, through the mixed 48% ZEN 90160 tpn suspension emulsion that gets.
Implementation of an application example two: ZEN 90160 and chlorothalonil compound are to the cucumber downy mildew Toxicity Determination
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
After the effective inhibition concentration scope of each medicament was determined in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament cucumber downy mildew.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively ZEN 90160 and tpn shared ratio in combination
A is a ZEN 90160
B is a tpn
Result of the test is as shown in table 1:
Table 1 ZEN 90160, tpn and composite toxicity test analysis of results table thereof to cucumber downy mildew
As shown in Table 1, ZEN 90160, tpn are to the EC of cucumber downy mildew
50Be respectively 7.35mg/L and 42.82mg/L.The virulence of tpn is lower than the virulence of ZEN 90160.Be mixed synergy ratio all greater than 1.5 in ZEN 90160 and 60: 1 to 1: 80 the scope of tpn proportioning, illustrating that ZEN 90160 and tpn were mixed in the scope at 60: 1 to 1: 80 all shows synergistic effect, especially when the two proportioning during at 6: 1 to 1: 18, synergistic effect is more obvious, synergy ratio SR maximum when ZEN 90160 and tpn weight ratio are 1: 6 wherein, synergistic effect is the most obvious.
Implementation of an application example three ZEN 90160, tpn and the composite control cucumber downy mildew test of pesticide effectiveness thereof
This experimental establishment is at the Xian City, Shanxi Province Baqiao District, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% ZEN 90160 suspending agent (commercial), 75% tpn wetting powder (commercial).
Investigation cucumber downy mildew disease index before the medicine, in the their early stage dispenser, dispenser in per 10 days once, dispenser is 3 times altogether, investigates disease index respectively and calculates preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 2 ZEN 90160, tpn and the composite control cucumber downy mildew test of pesticide effectiveness thereof
As can be seen from Table 2, can effectively prevent and treat cucumber downy mildew behind ZEN 90160 and the chlorothalonil compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Wetting powder the key technical indexes of the present invention:
Table 3
Application Example four ZEN 90160, tpn and the composite control wheat powdery mildew test of pesticide effectiveness thereof
This experimental establishment is in Sanyuan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% ZEN 90160 suspending agent (commercial), 75% tpn wetting powder (commercial).
Investigation wheat powdery mildew disease index before the medicine, in the their early stage dispenser, dispenser in per 10 days once, dispenser is 3 times altogether, investigates disease index respectively and calculates preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 4 ZEN 90160, tpn and the composite control wheat powdery mildew test of pesticide effectiveness thereof
As can be seen from Table 4, can effectively prevent and treat wheat powdery mildew behind ZEN 90160 and the chlorothalonil compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Water dispersible granules the key technical indexes of the present invention:
Table 5
Application Example five ZEN 90160, tpn and the composite control apple anthracnose test of pesticide effectiveness thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% ZEN 90160 suspending agent (commercial), 75% tpn wetting powder (commercial).
Investigation apple anthracnose disease index before the medicine, in the their early stage dispenser, dispenser in per 7 days once, dispenser is 3 times altogether, investigates disease index respectively and calculates preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 6 ZEN 90160, tpn and the composite control apple anthracnose test of pesticide effectiveness thereof
As can be seen from Table 6, can effectively prevent and treat apple anthracnose behind ZEN 90160 and the chlorothalonil compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Suspending agent the key technical indexes of the present invention:
Table 7
Application Example six ZEN 90160, tpn and the composite early blight of tomato test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 25% ZEN 90160 suspending agent (commercial), 75% tpn wetting powder (commercial).
Investigation early blight of tomato disease index before the medicine, in the their early stage dispenser, dispenser in per 10 days once, dispenser is 3 times altogether, investigates disease index respectively and calculates preventive effect in 7 days, 14 days, 30 days after the dispenser for the third time.Experimental result is as follows:
Table 8 ZEN 90160, tpn and the composite early blight of tomato test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 8, can effectively prevent and treat early blight of tomato behind ZEN 90160 and the chlorothalonil compound, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Suspension emulsion the key technical indexes of the present invention:
Table 9
Claims (6)
1. a bactericidal composition that contains ZEN 90160 and tpn comprises effective active component, auxiliary agent and filler, it is characterized in that: ZEN 90160 and tpn percentage by weight are 1～60%: 1～80%.
2. a kind of bactericidal composition that contains ZEN 90160 and tpn according to claim 1 is characterized in that: the percentage by weight of ZEN 90160 and tpn is 5～40%: 5～70%.
3. the bactericidal composition that contains ZEN 90160 and tpn according to claim 2 is characterized in that: the percentage by weight of ZEN 90160 and tpn is 10～30%: 10～60%.
4. the bactericidal composition that contains ZEN 90160 and tpn according to claim 1 is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent or suspension emulsion.
5. the bactericidal composition that contains ZEN 90160 and tpn according to claim 1 is used to prevent and treat the disease on cereal class, vegetables, the fruit tree.
6. the bactericidal composition that contains ZEN 90160 and tpn according to claim 5 is used to prevent and treat downy mildew, powdery mildew, leaf spot, rice blast, eqpidemic disease, anthracnose, rust, the application of wheat class glume blight, leaf blight, brown spot.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100914983A CN102204535A (en) | 2011-04-12 | 2011-04-12 | Antibacterial composition containing picoxystrobin and chlorothalonil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100914983A CN102204535A (en) | 2011-04-12 | 2011-04-12 | Antibacterial composition containing picoxystrobin and chlorothalonil |
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| CN102204535A true CN102204535A (en) | 2011-10-05 |
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|---|---|---|---|
| CN2011100914983A Pending CN102204535A (en) | 2011-04-12 | 2011-04-12 | Antibacterial composition containing picoxystrobin and chlorothalonil |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103651368A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low-volume liquid containing picoxystrobin and preparation method of ultra-low-volume liquid |
| CN111642503A (en) * | 2013-11-26 | 2020-09-11 | Upl 有限公司 | Method for controlling rust |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1455641A (en) * | 2000-09-12 | 2003-11-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| US20040014800A1 (en) * | 2000-09-05 | 2004-01-22 | Warrington Roger Paul | Pesticidal formulations |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
-
2011
- 2011-04-12 CN CN2011100914983A patent/CN102204535A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040014800A1 (en) * | 2000-09-05 | 2004-01-22 | Warrington Roger Paul | Pesticidal formulations |
| CN1455641A (en) * | 2000-09-12 | 2003-11-12 | 辛根塔参与股份公司 | Fungicidal compositions |
| CN101808521A (en) * | 2007-09-26 | 2010-08-18 | 巴斯夫欧洲公司 | ternary fungicidal compositions comprising boscalid and chlorothalonil |
Non-Patent Citations (2)
| Title |
|---|
| 无: "Picoxystrobin compositions", 《RESEARCH DISCLOSURE》 * |
| 无: "Strobilurin compositions", 《RESEARCH DISCLOSURE》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111642503A (en) * | 2013-11-26 | 2020-09-11 | Upl 有限公司 | Method for controlling rust |
| EP4014738A1 (en) * | 2013-11-26 | 2022-06-22 | UPL Ltd | A method for controlling rust |
| CN103651368A (en) * | 2013-12-13 | 2014-03-26 | 广西田园生化股份有限公司 | Ultra-low-volume liquid containing picoxystrobin and preparation method of ultra-low-volume liquid |
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Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Applicant after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710077, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shanxi Thompson Biological Technology Co., Ltd. |
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Application publication date: 20111005 |