CN102180609B - Preparation process of vitrified color sand - Google Patents

Preparation process of vitrified color sand Download PDF

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Publication number
CN102180609B
CN102180609B CN201110030163A CN201110030163A CN102180609B CN 102180609 B CN102180609 B CN 102180609B CN 201110030163 A CN201110030163 A CN 201110030163A CN 201110030163 A CN201110030163 A CN 201110030163A CN 102180609 B CN102180609 B CN 102180609B
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sintering
color sand
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sand
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CN102180609A (en
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牛智勇
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Guangdong Jiashili nano coating technology Co. Ltd.
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牛智勇
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Abstract

The invention relates to a preparation process of vitrified color sand, which is used for solving the technical problems of complex process, excessively high cost as well as poor rainwater resistance and easy fading of prepared color sand existing in the color sand preparation method. According to the adopted technical scheme, the vitrified color sand is obtained by coating quartz sand or refractory stone or glass micro-balloons serving as a substrate with color paste and sintering. The key point lies in the color sand sintering process step. Compared with the conventional sintering process, the sintering process step of the preparation process has the advantages that: due to limits on sintering equipment and technology in the prior art, the sintering temperature can only be controlled ina way that surface color paste just reaches initial molten state, so that inorganic pigments in the color paste are independently and lightly attached to the surface layer of the substrate; and in the process, the sintering temperature can be controlled in a way that the color paste and the surface layer of the substrate reach glass fluid state degree at the same time by using self-researched internal heating furnace kiln equipment, so that the color paste in the glass fluid state permeates and is bonded with the molten surface layer of the substrate, and finished color sand is prevented from fading in hundreds of years.

Description

The preparation technology of the color sand of a kind of vitreous
Technical field
The present invention relates to a kind of preparation technology of colour sand for decoration of building, belong to building field, particularly a kind of improved be that base-material passes through the painted color sand preparation technology of high temperature vitreous sintering with glass microballon or silica sand.
Background technology
Color sand occupies very consequence with the advantage of bright in luster, stable performance, rich texture, asepsis environment-protecting in building and ornament materials.Color sand is divided into natural colour sand and artificial color sand.Natural colour sand is to obtain through the natural coloured ore of direct destruction, most of natural colour sand color and luster chaos, and intensity difference, differentiation easily, a little less than the sticking power, and minority natural colour sand bright in colour costs an arm and a leg, and limitation is big.Artificial color sand is to obtain through coat colored coating on mineral grain surface, is characterized in that color even, color are lucid and lively, can process according to the color demand, thereby prepare colourful color sand kind, satisfies people's different demands.The classical production process of artificial color sand mainly contains three kinds: first kind, and the organic dye dyeing method; Second kind, the resin solidification method; The third high-temperature sintering process.But adopt the color sand of above-mentioned three kinds of methods preparation all to have defective in various degree: in the first method, the not ageing-resistant also not anti-rain-out of organic dye, fugitive color; Second method is to be coated on the silica sand top layer with the mixed with resin inorganic color, and baking-curing is painted under 200~300 ℃ of temperature then, and the color sand of this method preparation exists and is prone to aging, fugitive color, painted uneven problem; Because the sticker of its use costs an arm and a leg, increased the preparation cost of color sand simultaneously, the third method is that mineral dye and silica sand are mixed; Be integral through high temperature sintering, then through broken, sieve into color sand finished product, but the technology of the color sand of present this preparation that is that all right is ripe; The one, the color sand behind the sintering is united and is one-piece construction; Also need fragmentation once more, screening could form independently color sand particle, so not only strengthened and produced power consumption, the quality of the extrinsic color shell of color sand also can flaw occur in the process of fragmentation; Even cause whole color sand broken, become imperfections.
A kind of " vitrified color balls and preparation method thereof " disclosed in application number is 200910073164.6 patent documentation; There is great defective in its preparation technology; There is not exploitativeness, can not be prepared into superior in quality vitrified color balls, even possibly not be prepared into vitrified color balls.At first; Its basic soln that adopts has extremely strong corrodibility to beramic color; Can have a strong impact on the quality quality of beramic color; Even can cause decolouring, and this belongs to known technology in the art, and basic no one adopts the strong basic soln of corrodibility to mix the quality that influences color pearl with beramic color.Secondly, it is mentioned in background technology: " height contains harmful toxic substance in the glass pigment ", and in its technical characterictic, adopted upperseat concept-" beramic color " of glass pigment to replace glass pigment; This shows; The applicant does not also know glass pigment and beramic color is to divide according to the purposes of pigment, with a kind of pigment of composition, is used in the glass pigment that just is called as on glass; Be used on the pottery just by beramic color; General glass pigment can be regarded a kind of low-temperature condition of beramic color as, and therefore, just there is contradiction in this application self.This shows that application number is that 200910073164.6 the disclosed color pearl preparation technology of patent documentation does not have exploitativeness, can not be prepared into the vitrified color balls superior in quality, that color is bright and beautiful.
For addressing the above problem, we have developed a kind of durable color sand that does not fade and supporting preparation technology again through a large amount of experiments.
Summary of the invention
The objective of the invention is to solve the not anti-rain-out of color sand that complex procedures, cost are too high and making obtains of color sand making method existence, the technical problem of fugitive color; Preparation technology to existing color sand improves, and provides that a kind of operation is simple, the preparation technology of easy-operating colour sand for decoration of building.
The present invention for realizing the technical scheme that goal of the invention adopts is; The preparation technology of the color sand of a kind of vitreous; With silica sand or fire-resistant building stones or glass microballon is that base-material, parcel mill base sintering form; Its key is: this technology be by the internal-heated rotary furnace kiln plant, form with the stove center be the thermal-arrest point, to the dynamic high temperature sintering environment of stove wall dissipate heat, sintering forms color sand in above environment, the concrete steps of said technology comprise:
A, allotment mill base: mineral dye and the aqueous binders that will adopt MOX sintering quality is by weight being 1: the proportioning of (1~3) is uniformly mixed into the pasty state mill base, and is subsequent use;
B, base-material hang look: above mill base and base-material are inserted in the stirrer stir, evenly adhere to mill base, formation external parcel layer until the top layer of base-material, wherein the weight percent of mill base and base-material is:
Mill base: 1~5%, base-material: 95~99%;
C, oven dry: will hang the dynamic drying kiln body that base-material behind the look drops into the internal-heated rotary furnace kiln plant, control kiln body rotating speed is that 10~60 rev/mins, bake out temperature are 50~200 ℃, heating 10~30min oven dry formation look film integument;
D, sintering: will introduce dynamic sinter in the internal-heated rotary furnace kiln with the base-material of look film integument after the oven dry; Control kiln body rotating speed is that 10~60 rev/mins, sintering temperature are 450~1300 ℃; Heating 10~30min reaches molten state simultaneously, forms the color sand adventitia of vitreous state until look film integument and base-material top layer;
The dynamically cooling fast of the color sand of e, the color sand adventitia of formation vitreous state is until room temperature;
F, keep sample, numbering, packing are dispatched from the factory.
Key of the present invention is in the sintering process step of color sand; The present invention is in the agglomerating process step; The place that is superior to existing sintering process is: prior art is because agglomerating plant and technology limitation; Its sintering temperature can only be controlled at surperficial mill base and just reach the beginning melt, and the mineral dye in the mill base can only be many independently simple top layers that stick to base-material of particle like this; And this technology can be by the internal-heated rotary furnace kiln plant of independent research; Sintering temperature is controlled at the degree that mill base and base-material top layer reach the glass fluidised form simultaneously; Make the top layer of glass fluidised form mill base and base-material molten state interpenetrate, bond together, the color sand of finished product also can not decoloured going through in hundreds of years.
The present invention adopts the mobile production line that forms by the internal-heated rotary furnace kiln plant to prepare color sand, but oven dry and sintering continuous uninterrupted carry out simultaneously, practiced thrift the PT greatly, improved production efficiency; The mill base food ingredient is simple, with low cost simultaneously, but does not influence final product quality, has practiced thrift production cost greatly; The color chiltern amount that adopts this technology to process is good, and under the condition of high temperature, color sand can keep not fading in 20 hours, and ageing-resistant performance can obtain improving greatly.
Embodiment
The preparation technology of the color sand of a kind of vitreous; With silica sand or fire-resistant building stones or glass microballon is that base-material, parcel mill base sintering form; Its key is: this technology be by the internal-heated rotary furnace kiln plant, form with the stove center be the thermal-arrest point, to the dynamic high temperature sintering environment of stove wall dissipate heat; Sintering forms color sand in above environment, and the concrete steps of said technology comprise:
A, allotment mill base: mineral dye and the aqueous binders that will adopt MOX sintering quality is by weight being 1: the proportioning of (1~3) is uniformly mixed into the pasty state mill base, and is subsequent use;
B, base-material hang look: above mill base and base-material are inserted in the stirrer stir, evenly adhere to mill base, formation external parcel layer until the top layer of base-material, wherein the weight percent of mill base and base-material is:
Mill base: 1~5%, base-material: 95~99%;
C, oven dry: will hang the dynamic drying kiln body that base-material behind the look drops into the internal-heated rotary furnace kiln plant, control kiln body rotating speed is that 10~60 rev/mins, bake out temperature are 50~200 ℃, heating 10~30min oven dry formation look film integument;
D, sintering: will introduce in the dynamic sinter kiln body of internal-heated rotary furnace kiln with the base-material of look film integument after the oven dry and carry out dynamic sinter; Control kiln body rotating speed is that 10~60 rev/mins, sintering temperature are 450~1300 ℃; Heating 10~30min reaches molten state simultaneously, forms the color sand adventitia of vitreous state until look film integument and base-material top layer;
The dynamically cooling fast of the color sand of e, the color sand adventitia of formation vitreous state is until room temperature;
F, keep sample, numbering, packing are dispatched from the factory.
Above-mentioned aqueous binders is that concentration is 1~3% cellulose aqueous solution.
The particle fineness of above-mentioned base-material is 10~120 orders.
In step a, the concrete steps of color paste deployment are: the mineral dye and the aqueous binders of MOX sintering quality are inserted in the whipping appts, stirred 3~15 minutes with 60~360 rev/mins speed.
Among the above-mentioned step b, the concrete steps that base-material is hung look are: base-material and mill base are inserted in the whipping appts, stirred 15~30 minutes with 10~60 rev/mins speed.
Among the above-mentioned step a, mineral dye is to be that colorant forms by the flux sintering with the MOX.
Above-mentioned MOX is the mixture of a kind of or at least two kinds of compositions in red stone, chromic oxide, powder blue, the zirconium white.
Above-mentioned flux can adopt boric acid.
In the above-mentioned steps d, the control of sintering temperature is to divide according to the composition of base-material, and adopting glass microballon is that base-material prepares color sand, and sintering temperature is controlled to be 450~700 ℃, and adopting silica sand is that base-material prepares color sand, and sintering temperature is controlled to be 700~1300 ℃.
The time that the color sand of the color sand adventitia of formation vitreous state dynamically is cooled to room temperature was controlled at 20-45 minute.
More than dynamically cooling be meant that color sand keeps a certain speed to cool off gradually, be that base-material can adopt dynamic cooling when preparing color sand with the glass microballon, can cool off gradually also and can cool off fast when adopting silica sand to prepare color sand.
Key of the present invention is; In color paste deployment, get hold of the component ratio of batching, form the uniform pasty state mill base of particle suspension; After color paste layer has been wrapped up on the base-material top layer; Drop into the internal-heated rotary furnace kiln plant in batch and dry and dynamic sinter, make the base-material in oven dry and sintering process keep independent dispersion state always, avoid occurring the particle situation of uniting.
The present invention adopts the mobile production line that forms by the internal-heated rotary furnace kiln plant to prepare color sand, but oven dry and sintering continuous uninterrupted carry out simultaneously, practiced thrift the PT greatly, improved production efficiency; The mill base food ingredient is simple, with low cost simultaneously, but does not influence final product quality, has practiced thrift production cost greatly; The color chiltern amount of the vitreous of adopting this technology to process is good, has realized the form of ceramic post sintering, and ageing-resistant performance can obtain improving greatly.
The present invention is in the agglomerating process step; The place that is superior to existing sintering process is: prior art is because agglomerating plant and technology limitation; Its sintering temperature can only be controlled at surperficial mill base and just reach the beginning melt, and the mineral dye in the mill base can only be many independently simple top layers that stick to base-material of particle like this; And this technology can be by the internal-heated rotary furnace kiln plant of independent research; Sintering temperature is controlled at the degree that mill base and base-material top layer reach the glass fluidised form simultaneously; Make the top layer of glass fluidised form mill base and base-material molten state interpenetrate, bond together, the color sand of finished product also can not decoloured going through in hundreds of years.
During practical implementation, provide three specific embodiments below.
First example: with concentration is that 1% cellulose aqueous solution is as aqueous binders; Employing by the mineral dye of MOX sintering quality as toner; Inorganic dyestuff and 1% cellulose aqueous solution are carried out proportioning by weight the ratio that is 1: 1.5; And insert in the whipping appts, with the speed stirring 5min formation pasty state mill base of 120 commentaries on classics/min.Mill base and silica sand that allotment is good stir in the whipping appts together to insert; Whipping appts stirs 15min with the speed of 20 commentaries on classics/min; The top layer of silica sand evenly adhered to mill base, formed the external parcel layer this moment; Wherein the weight percent of mill base and silica sand is: mill base: 1%, and base-material: 99%.Silica sand behind the extension look is dropped into the drying kiln body of internal-heated rotary furnace kiln plant; Temperature with 200 ℃; Oven dry 10min forms look film integument, adopts the synchronization of rate of 10 commentaries on classics/min to stir silica sand in the time of oven dry, and avoiding quartz sand particle to unite influences quality product; The oven dry back gets into the agglomerating plant of rotary kiln kiln; With the temperature increase to 800 of agglomerating plant ℃; Insulation 10min; Sinter to mill base and silica sand top layer and reach molten state simultaneously, form the color sand adventitia of vitreous state, at last the color sand that sintering forms was slowly cooled to room temperature, packs and dispatch from the factory through 35 minutes, accomplish the preparation technology of color sand.
Second example: with concentration is that 3% cellulose aqueous solution is as aqueous binders; The mineral dye that employing is processed by MOX is as staining agent; Mineral dye and 3% cellulose aqueous solution are carried out proportioning by weight the ratio that is 1: 1; And insert in the whipping appts, with the speed stirring 15min formation pasty state mill base of 360 commentaries on classics/min.Mill base and silica sand that allotment is good stir in the whipping appts together to insert; Whipping appts stirs 30min with the speed of 30 commentaries on classics/min; The top layer of silica sand evenly adhered to mill base, formed the external parcel layer this moment; Wherein the weight percent of mill base and silica sand is: mill base: 3%, and silica sand: 97%.Silica sand behind the extension look is dropped into the internal-heated rotary furnace kiln plant, and with 200 ℃ temperature, oven dry 30min forms look film integument, adopts the synchronization of rate stirring silica sand of 20 commentaries on classics/min in the time of oven dry, and avoiding quartz sand particle to unite influences quality product; The oven dry back gets into the agglomerating plant of rotary kiln kiln; With the temperature increase to 1000 of agglomerating plant ℃; Insulation 30min; Sinter to mill base and silica sand top layer and reach molten state simultaneously, form the color sand adventitia of vitreous state, at last the color sand that sintering forms was slowly cooled to room temperature, packs and dispatch from the factory through 40 minutes, accomplish the preparation technology of color sand.
The 3rd example: with concentration is that 2% cellulose aqueous solution is as aqueous binders; The mineral dye that adopts MOX to process is a staining agent; Is that 1: 3 ratio is carried out proportioning with mineral dye and 2% cellulose aqueous solution in the grammes per square metre ratio; And insert in the whipping appts, with the speed stirring 15min formation pasty state mill base of 120 commentaries on classics/min.Mill base and glass microballon that allotment is good stir in the whipping appts together to insert; Whipping appts stirs 30min with the speed of 30 commentaries on classics/min; The top layer of glass microballon evenly adhered to mill base, formed the external parcel layer this moment; Wherein the weight percent of mill base and glass microballon is: mill base: 3%, and glass microballon: 97%.Glass microballon behind the extension look is dropped into the drying kiln body of internal-heated rotary furnace kiln plant; Temperature with 100 ℃; Oven dry 30min forms look film integument, adopts the synchronization of rate stirred glass microballon of 20 commentaries on classics/min in the time of oven dry, and avoiding the glass microballon particle to unite influences quality product; The oven dry back gets into the dynamic sinter kiln body of rotary kiln kiln; With the temperature increase to 500 of agglomerating plant ℃; Insulation 30min; Sinter to mill base and glass microballon top layer and reach molten state simultaneously, form the color sand adventitia of vitreous state, at last the color sand that sintering forms was slowly cooled to room temperature, packs and dispatch from the factory through 45 minutes, accomplish the preparation technology of color sand.

Claims (9)

1. the preparation technology of the color sand of a vitreous; With silica sand or fire-resistant building stones or glass microballon is that base-material, parcel mill base sintering form; It is characterized in that: this technology be by the internal-heated rotary furnace kiln plant, form with the stove center be the thermal-arrest point, to the dynamic high temperature sintering environment of stove wall dissipate heat; Sintering forms color sand in above environment, and the concrete steps of said technology comprise:
A, allotment mill base: will adopt the mineral dye of MOX sintering quality and aqueous binders to be uniformly mixed into the pasty state mill base by weight the proportioning that is 1: 1~3, subsequent use;
B, base-material hang look: above mill base and base-material are inserted in the stirrer stir, evenly adhere to mill base, formation external parcel layer until the top layer of base-material, wherein the weight percent of mill base and base-material is:
Mill base: 1~5%, base-material: 95~99%;
C, oven dry: will hang the dynamic drying kiln body that base-material behind the look drops into the internal-heated rotary furnace kiln plant, control kiln body rotating speed is that 10~60 rev/mins, bake out temperature are 50~200 ℃, heating 10~30min oven dry formation look film integument;
D, sintering: will introduce dynamic sinter in the internal-heated rotary furnace kiln with the base-material of look film integument after the oven dry; Control kiln body rotating speed is that 10~60 rev/mins, sintering temperature are 450~1300 ℃; Heating 10~30min reaches molten state, forms the color sand adventitia of vitreous state until look film integument;
The color sand of e, the color sand adventitia of formation vitreous state is cooled to room temperature;
F, keep sample, numbering, packing are dispatched from the factory.
2. the preparation technology of the color sand of a kind of vitreous according to claim 1, it is characterized in that: described aqueous binders is that concentration is 1~3% cellulose aqueous solution.
3. the preparation technology of the color sand of a kind of vitreous according to claim 1, it is characterized in that: the particle fineness of said base-material is 10~120 orders.
4. the preparation technology of the color sand of a kind of vitreous according to claim 1; It is characterized in that: in step a; The concrete steps of color paste deployment are: the mineral dye and the aqueous binders of MOX sintering quality are inserted in the whipping appts, stirred 3~15 minutes with 60~360 rev/mins speed.
5. the preparation technology of the color sand of a kind of vitreous according to claim 1 is characterized in that: among the described step b, the concrete steps that base-material is hung look are: base-material and mill base are inserted in the whipping appts, stirred 15~30 minutes with 10~60 rev/mins speed.
6. the preparation technology of the color sand of a kind of vitreous according to claim 1, it is characterized in that: among the described step a, mineral dye is to be that colorant forms by the flux sintering with the MOX.
7. according to the preparation technology of claim 1 or the color sand of 6 described a kind of vitreous, it is characterized in that: described MOX is the mixture of a kind of or at least two kinds of compositions in red stone, chromic oxide, powder blue, the zirconium white.
8. the preparation technology of the color sand of a kind of vitreous according to claim 1; It is characterized in that: in the described steps d; The control of sintering temperature is to divide according to the composition of base-material, and adopting glass microballon is that base-material prepares color sand, and sintering temperature is controlled to be 450~700 ℃; Adopting silica sand is that base-material prepares color sand, and sintering temperature is controlled to be 700~1300 ℃.
9. the preparation technology of the color sand of a kind of vitreous according to claim 1 is characterized in that: the time that the color sand of the color sand adventitia of formation vitreous state dynamically is cooled to room temperature was controlled at 20-45 minute.
CN201110030163A 2011-01-28 2011-01-28 Preparation process of vitrified color sand Active CN102180609B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826787B (en) * 2012-07-25 2014-12-10 亚士漆(上海)有限公司 Artificial colored sand
CN103910502A (en) * 2013-01-05 2014-07-09 潍坊龙成建材有限公司 Colored sand capable of coloring by reaction and its preparation method
CN104230214B (en) * 2014-09-17 2016-03-09 常州明清新材料技术有限公司 A kind of method of being synthesized stone by colorful quartz sands making artificial colo red quartz
CN104478258B (en) * 2014-11-21 2017-01-25 苏州大乘环保建材有限公司 Preparation method of resin coated color quartz sand

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100473A (en) * 1987-01-28 1988-02-03 湘潭市化工研究设计所 Utilize frit for porcelain enamel to produce the method for coloured sandstone
CN87102240A (en) * 1987-03-23 1988-10-12 牛智勇 Corrosion-resistant colour sand for decoration of building and method for making thereof and equipment
CN1644553A (en) * 2004-12-23 2005-07-27 江阴采麟彩砂制品有限公司 Color sand and production thereof
KR20060072782A (en) * 2004-12-23 2006-06-28 주식회사부성케미칼 Glass tile and fabricating method thereof
CN1807358A (en) * 2006-01-24 2006-07-26 陈云 Ceramic colorful sand and its preparation process
CN101139179A (en) * 2007-08-14 2008-03-12 陈云 Ceramic coating burning colorful sand and method for making same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87100473A (en) * 1987-01-28 1988-02-03 湘潭市化工研究设计所 Utilize frit for porcelain enamel to produce the method for coloured sandstone
CN87102240A (en) * 1987-03-23 1988-10-12 牛智勇 Corrosion-resistant colour sand for decoration of building and method for making thereof and equipment
CN1644553A (en) * 2004-12-23 2005-07-27 江阴采麟彩砂制品有限公司 Color sand and production thereof
KR20060072782A (en) * 2004-12-23 2006-06-28 주식회사부성케미칼 Glass tile and fabricating method thereof
CN1807358A (en) * 2006-01-24 2006-07-26 陈云 Ceramic colorful sand and its preparation process
CN101139179A (en) * 2007-08-14 2008-03-12 陈云 Ceramic coating burning colorful sand and method for making same

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