CN102179850A - Manufacturing method for producing energy-saving and environmentally-friendly type high-strength wood plate substitutes or devices with straws - Google Patents
Manufacturing method for producing energy-saving and environmentally-friendly type high-strength wood plate substitutes or devices with straws Download PDFInfo
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- CN102179850A CN102179850A CN2011100381353A CN201110038135A CN102179850A CN 102179850 A CN102179850 A CN 102179850A CN 2011100381353 A CN2011100381353 A CN 2011100381353A CN 201110038135 A CN201110038135 A CN 201110038135A CN 102179850 A CN102179850 A CN 102179850A
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- 239000002023 wood Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000010902 straw Substances 0.000 title abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 42
- 239000000835 fiber Substances 0.000 claims abstract description 13
- 239000000853 adhesive Substances 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims abstract description 8
- -1 shaving boards Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 230000001954 sterilising effect Effects 0.000 claims abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims abstract 2
- 239000003292 glue Substances 0.000 claims description 11
- 238000013461 design Methods 0.000 claims description 8
- 230000007613 environmental effect Effects 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000004026 adhesive bonding Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 3
- 238000004898 kneading Methods 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 238000007731 hot pressing Methods 0.000 claims 1
- 239000011810 insulating material Substances 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 4
- 238000001125 extrusion Methods 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000011094 fiberboard Substances 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000011120 plywood Substances 0.000 abstract 1
- 239000002699 waste material Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 10
- 238000011161 development Methods 0.000 description 9
- 229920002472 Starch Polymers 0.000 description 8
- 239000008107 starch Substances 0.000 description 8
- 235000019698 starch Nutrition 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000012744 reinforcing agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000274582 Pycnanthus angolensis Species 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention relates to a manufacturing method for producing energy-saving and environmentally-friendly type high-strength wood plate substitutes or devices with straws, which comprises the following steps: processing various plant straws or other fibers into velvet or slurry type through special equipment; adding environmentally-friendly adhesives, additive filler and the like, carrying out high-speed and even mixing and stirring to obtain materials with solid content of 70+/-5 percent; injecting the material in an inlet of an energy-saving and environmentally-friendly type plate (device) forming machine, evenly laying the materials in a closed ring type strip-shaped mold by a metering device and a conveyor, carrying out microwave processing, leading the temperature of the materials to rise from normal temperature to more than 100 DEG C, thus achieving the purpose of firmly combination of the adhesive and the fiber, and sterilization; carrying out extrusion forming to obtain a veneer with a geometry shape, and compounding the veneer or other materials into hollow high-strength wood plate substitutes, namely completing the machining on the energy-saving and environmentally-friendly type high-strength wood plate substitutes. The plate can substitute wood plate, core boards, plywood, shaving boards, medium density fiber boards and other boards, can be further machined into light type walls, packaging boxes, heavy-duty pallets, decoration plates, furniture, house decoration members, artware and other products.
Description
The present invention " produces the manufacture method of energy saving and environment friendly high-strength board capable of replacing wood board material or device " and relates to stalk is with the comprehensive development and utilization of materials such as agricultural stalk and city waste wood and waste textile, turn waste into wealth.Particularly adopt the new and high technology of energy-conservation, water saving, low-carbon (LC), three-waste free discharge, microwave drying rapid shaping.Producing this product of the high-strength board capable of replacing wood board material of environmental type (or other device) can directly use, and also further deep processing becomes products such as light wall, packing case, heavy-duty tray, decorative panel, furniture, house decoraton member and handicraft.
Background technology:
The various careless class stalk of China's agricultural production reaches more than 600,000,000 ton approximately at present, and resource utilization is very low, and major part goes out of use, even burns, and causes resource waste and severe environmental pollution greatly.Development along with agricultural economy, the waste of stalk resource and the pollution of environment do not reduce yet, add the excessive felling of forest, the grassland overgraze, make ecological environment suffer serious destruction, soil erosion, desertification of land is serious day by day, natural and man-made calamities emerge in an endless stream, and have brought great harm for economic development and people's lives.Therefore making full use of stalk resource turns waste into wealth, and produce energy saving and environment friendly high-strength board capable of replacing wood board material or other device and be very important, be that market is badly in need of very much.Like this with the advantage of agricultural resource; be converted into the advantage of commodity economy; be the needs of situation; promoted the benign cycle of agricultural production; protected ecological environment; improved the rural economic structure, increased employment and peasant's income, to supporting that agriculture, rural areas and farmers have earth shaking realistic meaning and far-reaching historical meaning (economic implications and social effect)
In recent years, the economic develop rapidly of China, environmental protection, energy problem are unprecedentedly severe, and energy savings is the task of top priority.Resource is the important goal of optimizing the economic structure, and must firmly reverse the situation of high flow rate, high pollution, low output.Walk out the road for development of an environment-friendly and energy-efficient with Chinese characteristics.Become the only way of China's sustainable economic development." forest law " that country puts into effect taked a series of measure for protecting forest resources.The sheet material production industry has been subjected to great challenge and impact.Seek the development work of new material replacement natural timber, the important act of become sheet material industry figure existence, seeking development.And stalk is with the peculiar advantage of " inexhaustible ", becomes sheet material industry and focus that relevant departments paid close attention to.
In recent years, the development of domestic construction market and house ornamentation industry, consumption markets such as finishing, decoration, furniture increase fast, make the artificial board industry spatial development of China.China's artificial board year production in 2003 has surpassed 4000 ten thousand steres, is only second to the U.S. and occupies the second in the world.Several hundred million square metres of the annual newly constructed houses of China are fitted up used sheet material consumption and are accounted for the No. 1 in the world.The used adhesive of artificial board on the market mainly is Lauxite and melamine resin.In actual production and application process, must have a large amount of free formaldehydes and discharge, this pollution and infringement human body physical and mental health to environment seriously influences.Product on the market is all cried out the environmental type product, exceeds standard but survey most of aldehydes, and is defective, needs to discharge for a long time pernicious gas after the house decoration and just can move in.But also there are many users to suffer, got grave illness, even life threatening.Therefore these products all have very big fear and sense of insecurity in people mind; so environmental protection, the new and high technology with independent intellectual property right is adopted in the energy-saving and emission-reduction comprehensive utilization; produce the environmental type high added value market in urgent need for wood products, seem more important and be badly in need of.
Original production sheet material technology is power consumption, big power consumer.The product drying mode adopts modes such as electric heating, hot blast, steam, all be to utilize heat conducting principle, the object central temperature is raise heat, because of the object to be processed thermal conductivity relatively poor, the outside is coking, also heat up in inside, therefore consume energy big, shortcomings such as the time is long, of poor quality, efficient is low, production cost height are arranged.
Summary of the invention:
The art of this patent adopts heating using microwave, makes heating object itself be heated as heater, does not need heat transfer process, and frequency is 2450MHz, and with 24.5 hundred million vibrations of per second, hydrone rubs mutually between the molecule and produces heat too with 24.5 hundred million vibrations of per second.Heating simultaneously inside and outside the self-heating, temperature is even, only uses 1~3 minute time, and material to be machined just can rise to more than 100 ℃ by 20 ℃, water system environmental protection glue is fully reacted reach the purpose of firm with the fiber bonding in sterilization.The microwave energy that adds makes interior of articles produce heat and vapour pressure, moisture is driven to the surface, and is excluded rapidly.Therefore production efficiency and energy-saving effect are ten times of the numbers of the original mode of production.Therefore it meets " energy-saving and emission-reduction " " low-carbon economy " policy requirements, is worth us to adopt.
A kind of novel manufacture method of producing energy saving and environment friendly high-strength board capable of replacing wood board material or equipment with stalk, be to adopt modern design, energy-saving and emission-reduction, pollution-free, zero-emission, the various discarded resources of comprehensive utilization, the new technology that turns waste into wealth, be that production cost is low, the new and high technology of the high and low carbon economy of efficient, still belong to initiative so far.
Its preparation method is:
1, agricultural stalk is rubbed with the hands and is worn into the velvet shape through kneading or grinding leaser or efficient kibbling mill.Also can be again through steam or hot water softening fibre.With the fiber treatment pulp, mass dryness fraction is 80~90% stand-by (it is stand-by also city waste wood or other fibrid can be processed into the velvet shape) through high-density paste mill.
2, a kind of high-adhesion energy, protection against the tide, mildew-resistant, environment-friendly type starch glue, what relate to is to utilize the technology that ecological environment requires that meets, fully reasonably producing starch is made high cohesive force, protection against the tide, mildew-resistant, environment-friendly type starch glue.It is that starch is passed through oxidant consumption 10% ± 2, and oxidative degradation reaches needs viscosity and molecular weight.Under stirring condition, through the gelatinization of heating hydro-oxidation sodium, gelatinization point: 56~72 ℃, (deciding according to variety classes starch) paste agent consumption 1~10% adds complexing agent then, crosslinking agent, graft copolymerization reagent, terminator, waterproofing agent, reinforcing agent etc.Make glue solid content 40-50%, high-adhesion energy environment-friendly type starch glue is stand-by.(abbreviation adhesive)
3, with velvet shape fiber or slurry fiber and high-adhesion can amylan in 0.8~1: the ratio of 0.8~1 (dry substance is with 100%), and add an amount of reinforcing agent, functional aid, filler etc., drop in the multi-functional mixer, discongesting under the stirring condition at a high speed, be dispersed into highly evenly loose material body, solid content 70% ± 5.
4, mass dryness fraction 70% ± 5 material body is injected into energy-saving and environment-friendly making sheet (or device) make-up machine, through microwave treatment, temperature of charge is raised to more than 100 ℃ by normal temperature, makes environmental-protection type adhesive and fiber bonding firmly, also reaches sterilization effects simultaneously.Material is progressively pressurization in mould, and single face sheet material (or device) mass dryness fraction that mold pressing goes out the geometry shape of design configuration is 80~90%.
5, the geometry shape single face sheet material of design configuration with millboard (various boxboard) or other ornament materials, is combined into hollow high-strength environment-friendly board capable of replacing wood board material behind gluing.
6, mould employing polytetrafluoroethylene (PTFE) glass fiber tape, the material that nonpolar molecules such as polyethylene, poly-two alkene, rubber are formed, it can see through microwave and come spent material to heat up, and brings into play the adhesive bonds effect and reaches bactericidal effect.
When 7, producing other structure devices, production procedure is all identical, and just the mould difference in the former can design the different structure mould according to product requirement, as producing products such as ornament member and handicraft.
Good effect after invention is implemented is:
1, stalk is a fibrinoid material, be that nature gives human precious resources, utilize energy-conservation, the water saving, the no three wastes, pollution-free, low-carbon energy-saving, production new technology make the agricultural stalk resource, turn waste into wealth, support agriculture, rural areas and farmers, save timber, keep ecological balance, develop the economy, there are major and immediate significance and far-reaching historical meaning in China.
2, most of artificial boards on the former market: materials such as core-board, glued board, particieboard, medium density fibre board (MDF), not only aldehyde-containing type, benzene class harmful substance exceed standard, and weakness such as power consumption is high, efficient is low, speed is slow, of poor quality, cost height, advantage such as the sheet material that adopts this patent new technology to produce has that power consumption is low, efficient is high, speed is fast, Functionality, quality and appealing design, cost are low.Be not aldehyde-containing type, benzene class, nontoxic, waterproof, mildew-resistant simultaneously, anti-ly damage by worms, fire-retardant, sound insulation, heat insulation environmental type product, and have important light, intensity is high, can saw, can glue, can follow closely, the characteristics of good processability.Further light wall, heavily loaded packing case, heavy-duty tray, furniture, decorative panel, house decoraton member and the equivalent wood products of handicraft are made in deep processing.Be the urgent need in market, market is extremely huge! The employing and the enforcement of this patented technology route and method, the processing stalk for scientific and reasonable makes its resource, preserves the ecological environment, and has opened up a new way.
Embodiment: (the runoff yield journey of growing nonparasitically upon another plant schematic diagram)
1, get 1000 kilograms of wheat straws (or straw), directly enter kneading or grinding leaser, it is stand-by that the velvet shape is worn in the raw material stranding.
2, boil high-adhesion environment-friendly type starch glue: 1050 kilograms of extracting corn starch, add 1300 kilograms in water, be placed with in the glue reactor of agitator, add the 105 kg hydrogen peroxide, oxidation 60 minutes, 40 ℃ of oxidizing temperatures add 28 kilograms of NaOH, half gelatinization 30 minutes, 45 ℃ of gelatinization points, add 10.5 kilograms of complexing agent boraxs, add 26 kilograms of ARG water repellent agents, add the PAE100 kilogram, when boiling 68 ℃, be incubated 30 minutes, milky paste (environment-friendly type starch glue) promptly, stand-by (solid content 45% ± 5).
3, get 260 kilograms of velvet shape wheat straw fibers, 50 kilograms in potter's clay, 400 kilograms of amylans.In multi-functional mixer, discongest stirring through high speed, fully mix and be uniformly dispersed, this material is injected energy saving and environment friendly making sheet (or device) make-up machine inlet, the even place mat of device through measuring conveying is in mould, through 1~3 minute, microwave treatment, material is raised to more than 100 ℃ by normal temperature, the demoulding that moves on of extrusion die conveyer belt.Mold pressing goes out the single sided board of the geometry shape of design configuration, and this single sided board is through glue spreader gluing and 500 gram/rice
2Kraft paperboard compoundly roll through hot-rolling, then the high-strength board capable of replacing wood board of hollow cements, that is: energy saving and environment friendly high-strength board capable of replacing wood board section product machines.And then cutting into commodity according to the market demand specification, water content is 10~15%, through warehouse-in after the assay was approved.
Claims (7)
1. with various careless class stalks or other fiber, through kneading or grinding leaser or efficient kibbling mill, velvet shape or pulpous state (mass dryness fraction is 80~90%) are worn in stranding, this fiber and environmental-protection type adhesive and function preparation, filler etc., disperse to stir through multi-functional mixer high-speed mixing, the solid content of this material body is 70% ± 5, prepares stand-by.
2. its characteristics of the high-strength board capable of replacing wood board material of energy saving and environment friendly production (or device) make-up machine: the polytetrafluoroethylene glass fiber tape is arranged in the machine, and insulating materials such as PEF, polypropylene, rubber are made closed loop hollow sheeting mould, and microwave generating apparatus is housed in the machine.
3. the high-strength board capable of replacing wood board material of energy saving and environment friendly production (or device) make-up machine can make material through microwave treatment 1~3 minute, and material is risen to more than 100 ℃ by normal temperature, and water system environmental protection glue is fully reacted, and reaches the purpose of the bonding firm and sterilization of adhesive and fiber.Microwave energy makes material inner generation heat and vapour pressure exclude moisture content rapidly.
4. the continuously extruded single sided board that goes out design configuration (having the geometry that needs) of the banded mould of closed loop is combined into the hollow high-strength panel through gluing and millboard or other material.
5. the banded mould of closed loop can be designed to multiple geometry shapes such as equilateral hexagonal, garden shape, square, triangle, rhombus, and according to product requirement, interchangeable mould is produced multiple single face sheet material with solid.
6. have geometry shape single face sheet material and millboard (or other material) through set composite, behind gluing between the composite bed, roll through the hot pressing roller and to cement, form the hollow high-strength panel, promptly energy saving and environment friendly high-strength board capable of replacing wood board section product machines.
7. when producing other structure devices, production procedure is all identical, and just the mould difference of former can design the different structure mould according to product requirement, as producing products such as ornament member and handicraft.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110038135.3A CN102179850B (en) | 2011-02-15 | 2011-02-15 | Manufacturing method for producing high-strength wood plate substitutes with straws |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110038135.3A CN102179850B (en) | 2011-02-15 | 2011-02-15 | Manufacturing method for producing high-strength wood plate substitutes with straws |
Publications (2)
| Publication Number | Publication Date |
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| CN102179850A true CN102179850A (en) | 2011-09-14 |
| CN102179850B CN102179850B (en) | 2014-04-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110038135.3A Expired - Fee Related CN102179850B (en) | 2011-02-15 | 2011-02-15 | Manufacturing method for producing high-strength wood plate substitutes with straws |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102505576A (en) * | 2011-11-21 | 2012-06-20 | 何学信 | Economic and environmental friendly technology for manufacturing cardboard paper and straw boards by using straws |
| CN103590284A (en) * | 2013-11-06 | 2014-02-19 | 枣庄超越玉米淀粉有限公司 | Production process of starch emulsion for papermaking |
| CN104210008A (en) * | 2014-08-04 | 2014-12-17 | 中山升科科技开发有限公司 | Composite material capable of replacing solid wood and preparation method thereof |
| CN118003608A (en) * | 2024-03-04 | 2024-05-10 | 保定市富新包装有限公司 | Preparation method for improving compression resistance of environment-friendly packaging material |
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| CH572696A5 (en) * | 1973-09-05 | 1976-02-13 | Siemens Ag Oesterreich | |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102505576A (en) * | 2011-11-21 | 2012-06-20 | 何学信 | Economic and environmental friendly technology for manufacturing cardboard paper and straw boards by using straws |
| CN103590284A (en) * | 2013-11-06 | 2014-02-19 | 枣庄超越玉米淀粉有限公司 | Production process of starch emulsion for papermaking |
| CN104210008A (en) * | 2014-08-04 | 2014-12-17 | 中山升科科技开发有限公司 | Composite material capable of replacing solid wood and preparation method thereof |
| CN118003608A (en) * | 2024-03-04 | 2024-05-10 | 保定市富新包装有限公司 | Preparation method for improving compression resistance of environment-friendly packaging material |
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| Publication number | Publication date |
|---|---|
| CN102179850B (en) | 2014-04-09 |
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