CN102167635A - Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof - Google Patents
Nutritious and high efficient foliar fertilizer for growth of humic acid plant and preparation method thereof Download PDFInfo
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- CN102167635A CN102167635A CN2010106244745A CN201010624474A CN102167635A CN 102167635 A CN102167635 A CN 102167635A CN 2010106244745 A CN2010106244745 A CN 2010106244745A CN 201010624474 A CN201010624474 A CN 201010624474A CN 102167635 A CN102167635 A CN 102167635A
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- humic acid
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- aqueous solution
- sodium salt
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 100
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 239000004021 humic acid Substances 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 230000012010 growth Effects 0.000 title abstract description 9
- 235000008935 nutritious Nutrition 0.000 title abstract 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 55
- 235000015097 nutrients Nutrition 0.000 claims abstract description 46
- HMGUIQPKFUZDPV-UHFFFAOYSA-L disodium;bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1C2C=CC1C(C(=O)[O-])C2C([O-])=O HMGUIQPKFUZDPV-UHFFFAOYSA-L 0.000 claims abstract description 43
- 239000002994 raw material Substances 0.000 claims abstract description 20
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004202 carbamide Substances 0.000 claims abstract description 15
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 15
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 15
- 239000011785 micronutrient Substances 0.000 claims abstract description 13
- 235000013369 micronutrients Nutrition 0.000 claims abstract description 13
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000003050 macronutrient Effects 0.000 claims abstract description 6
- 235000021073 macronutrients Nutrition 0.000 claims abstract description 6
- 240000000233 Melia azedarach Species 0.000 claims description 55
- 235000016709 nutrition Nutrition 0.000 claims description 49
- 230000035764 nutrition Effects 0.000 claims description 47
- 230000008635 plant growth Effects 0.000 claims description 45
- 239000000243 solution Substances 0.000 claims description 36
- 241000229143 Hippophae Species 0.000 claims description 34
- 235000003145 Hippophae rhamnoides Nutrition 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 229910021645 metal ion Inorganic materials 0.000 claims description 31
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 29
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 29
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 29
- 239000001099 ammonium carbonate Substances 0.000 claims description 29
- 239000002738 chelating agent Substances 0.000 claims description 25
- 235000013399 edible fruits Nutrition 0.000 claims description 25
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 23
- 239000011734 sodium Substances 0.000 claims description 23
- 229910052708 sodium Inorganic materials 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 21
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 20
- 238000005303 weighing Methods 0.000 claims description 20
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 16
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 13
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 13
- 239000002509 fulvic acid Substances 0.000 claims description 13
- 229940095100 fulvic acid Drugs 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- -1 polyoxyethylene, methyl phenyl triazole Polymers 0.000 claims description 12
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 239000003929 acidic solution Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 229910021538 borax Inorganic materials 0.000 claims description 10
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 10
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 10
- 239000011790 ferrous sulphate Substances 0.000 claims description 10
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 10
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 10
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 10
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 10
- 229940099596 manganese sulfate Drugs 0.000 claims description 10
- 239000011702 manganese sulphate Substances 0.000 claims description 10
- 235000007079 manganese sulphate Nutrition 0.000 claims description 10
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 10
- 239000004328 sodium tetraborate Substances 0.000 claims description 10
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 10
- 229910021655 trace metal ion Inorganic materials 0.000 claims description 10
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 10
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 10
- 229960001763 zinc sulfate Drugs 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000011573 trace mineral Substances 0.000 claims description 8
- 235000013619 trace mineral Nutrition 0.000 claims description 8
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims description 7
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 7
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 claims description 6
- DARPYRSDRJYGIF-PTNGSMBKSA-N (Z)-3-ethoxy-2-naphthalen-2-ylsulfonylprop-2-enenitrile Chemical compound C1=CC=CC2=CC(S(=O)(=O)C(\C#N)=C/OCC)=CC=C21 DARPYRSDRJYGIF-PTNGSMBKSA-N 0.000 claims description 6
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims description 6
- GVKDLCPTYCLSQW-YFKNTREVSA-N C(\C=C/C(=O)OC(C)CCCCCC)(=O)OC(C)CCCCCC.[Na] Chemical compound C(\C=C/C(=O)OC(C)CCCCCC)(=O)OC(C)CCCCCC.[Na] GVKDLCPTYCLSQW-YFKNTREVSA-N 0.000 claims description 6
- 239000005985 Paclobutrazol Substances 0.000 claims description 6
- 239000004317 sodium nitrate Substances 0.000 claims description 6
- 235000010344 sodium nitrate Nutrition 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- HLWRUJAIJJEZDL-UHFFFAOYSA-M sodium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC([O-])=O HLWRUJAIJJEZDL-UHFFFAOYSA-M 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 244000025254 Cannabis sativa Species 0.000 claims description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000003415 peat Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- PWVXXGRKLHYWKM-UHFFFAOYSA-N 5-[2-(benzenesulfonyl)ethyl]-3-[(1-methylpyrrolidin-2-yl)methyl]-1h-indole Chemical compound CN1CCCC1CC(C1=C2)=CNC1=CC=C2CCS(=O)(=O)C1=CC=CC=C1 PWVXXGRKLHYWKM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 12
- 230000001965 increasing effect Effects 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 9
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000009736 wetting Methods 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 description 8
- 241000227653 Lycopersicon Species 0.000 description 6
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 6
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 5
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 5
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
- 235000005822 corn Nutrition 0.000 description 4
- 244000013123 dwarf bean Species 0.000 description 4
- 235000021331 green beans Nutrition 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920000832 Cutin Polymers 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229960000355 copper sulfate Drugs 0.000 description 2
- 229960001781 ferrous sulfate Drugs 0.000 description 2
- 229960003390 magnesium sulfate Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241000722921 Tulipa gesneriana Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 235000018343 nutrient deficiency Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000007180 physiological regulation Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001502 supplementing effect Effects 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a nutritious and high efficient foliar fertilizer for growth of humic acid plant and a preparation method thereof. The nutritious and high efficient foliar fertilizer for growth of humic acid plant comprises, by mass, 5 to 20 parts of humic acid sodium salt, 5 to 20 parts of urea, 4 to 10 parts of potassium dihydrogen phosphate, and 0.01 to 0.02 part of micronutrient element. The preparation method of the nutritious and high efficient foliar fertilizer for growth of humic acid plant includes the following steps of weighting the raw materials; preparing the humic acid sodium salt aqueous solution; and preparing the humic acid sodium salt macronutrient element aqueous solution. The advantages of the foliar fertilizer of the invention are that the foliar fertilizer having a wide range of concentration is applicable to a variety of crops; the foliar fertilizer can substantially increase and prolong the wetting time of the fertile liquid on the surface of most leaves, thus effectively prevent the happening of fertilizer damage, and further increasing the absorption efficiency of available nutrients in the foliar fertilizer; and the foliar fertilizer can realize the effects of good quality and high output.
Description
Technical Field
The invention relates to a high-efficiency plant foliage spray fertilizer and a preparation method thereof, in particular to a high-efficiency multifunctional foliar fertilizer containing a metal ion chelating agent, a non-ionic surfactant and traditional Chinese medicines and a preparation method thereof.
Background
At present, because the fertilizers of crops, vegetables, fruit trees and other plants are mainly solid fertilizers, such as mixed fertilizers, multi-element micro-fertilizers, solid special fertilizers, and various trace elements and major elements, which are prepared by stirring and processing through mechanical equipment, the fertilizers are not beneficial to field operation and easy to burn. Meanwhile, due to the long-term application of a large amount of chemical fertilizers, the comprehensive indexes of soil are reduced, the alkalinity is increased, the soil is hardened, the soil fertility is weakened, the quality of crops is reduced, and the taste of various fruits is poor; the retention of harmful substances in soil directly affects the health of human body after being absorbed by crops. With the progress of modern science and the long-term production practice of people, the deficiency of chemical fertilizers in crop fertilization is proved by various disciplines.
In recent years, the production and application of foliar fertilizer are very important at home and abroad. The foliar fertilizer can be divided into two categories of nutritional type and functional type in terms of action and function. The nutritional foliar fertilizer is prepared from one or more of a large amount of trace nutrient elements, medium amount of trace nutrient elements and has the main function of pertinently providing and supplementing the nutrition required by the growth of crops; the functional foliar fertilizer combines the functional type of some additives and the supplement of inorganic nutrient elements, thereby achieving the effects of mutual synergism and promotion, and is the mainstream of the current market.
A natural foliar fertilizer belongs to one of functional foliar fertilizers. The foliar fertilizer contains different natural substances such as: fermented product or metabolite extracted from marine algae, straw, peat, weathered coal, etc., such as amino acids, humic acid, alginic acid, etc. The substances have obvious physiological regulation effects on crops, such as stimulating the growth of the crops, promoting the metabolism of the crops, improving the stress resistance of the crops, and the like.
At present, more leaf fertilizer manufacturers containing humic acid have obvious income increasing effect although the formulas are different. However, the existing humic acid foliar fertilizer also has a plurality of technical problems:
1. in recent years, humic acid-containing foliar fertilizer products popularized in the market only solve the nutrition problem of crops and prevent the occurrence of nutrient deficiency, but lack the regulation capability on the growth of the crops, cannot effectively regulate the growth vigor of the crops and have an insufficient obvious effect on increasing the yield and the income.
2. Some leaf fertilizers, although overcoming the disadvantages, lack of chelation effect on metal ions, so that the absorption and utilization rate of trace elements is not high; meanwhile, due to the lack of drought resistant agents, the problems of flower and fruit dropping of the crops in dry seasons cannot be solved.
3. The problems that the fertilizer liquid has poor auxiliary spreading and permeability, the wetting time of leaves is short, the distribution is uneven, the fertilizer application effect is reduced and the fertilizer damage is caused commonly exist in the use of the leaf fertilizer. Some domestic leaf fertilizer manufacturers have long-term research and experiments on the selection of the leaf surface penetrating wetting agent, but have no great breakthrough in solving the key technical problem. Some leaf surface penetrating wetting agents selected in the formula of the leaf surface fertilizer comprise JFC (fatty alcohol ethylene oxide condensation product), AES (fatty alcohol polyoxyethylene ether sulfate sodium salt), citric acid or sodium citrate and the like, and some leaf surface fertilizer adopts a method of adding wetting agents and penetration aids such as dodecylbenzene sulfonic acid (neutral soap), a detergent with good quality, a defoaming agent and the like into the leaf surface fertilizer, so that the surface tension of the solution is reduced, and the contact area of the leaf surface penetrating wetting agents and the leaf blades is increased. Although the methods play a certain role, the effects are not obvious, and the effect of the fertilizer is influenced.
Disclosure of Invention
The invention aims to provide a humic acid plant growth nutrition high-efficiency foliar fertilizer.
The second purpose of the invention is to provide a preparation method of the humic acid plant growth nutrition high-efficiency foliar fertilizer.
The first purpose of the invention is implemented by the following technical scheme, and the humic acid plant growth nutrition high-efficiency foliar fertilizer comprises the following components in parts by mass: 5-20 parts of humic acid sodium salt, 5-20 parts of urea, 4-10 parts of monopotassium phosphate, 2-5 parts of a trace nutrient metal ion chelating agent, 4-6 parts of ammonium bicarbonate, 5-10 parts of a non-ionic surfactant, 0.5-5 parts of a chinaberry fruit preparation or a mixed preparation of chinaberry fruit and sea buckthorn mixed according to any ratio, and 0.01-1 part of a functional auxiliary agent.
The main raw material of the humic acid sodium salt is humic acid sodium salt containing 60 to 90 percent of fulvic acid, in particular to humic acid sodium salt containing 60 to 90 percent of fulvic acid extracted by grass peat ash through a chemical method.
The trace nutrient element metal ion chelating agent is prepared from the following components in parts by weight: 0.01-0.02 part of trace nutrient elements, 0.1-0.5 part of acidic solution with pH 1 and 4-6 parts of ammonium bicarbonate.
The micronutrient is a mixture of any two or more than two of copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax in any ratio.
The non-ionic surfactant is any one of ethylenediamine tetraacetic acid sodium salt, a compound of alkylphenol polyoxyethylene, methyl benzotriazole or sodium di-sec-octyl maleate sulfonate.
The functional auxiliary agent is any one or a mixture of more than one of mepiquat chloride, paclobutrazol, chlormequat chloride, compound sodium nitrate or alpha-naphthylacetic acid in any ratio.
The second purpose of the invention is implemented by the following technical scheme, and the preparation method of the humic acid plant growth nutrition high-efficiency foliar fertilizer comprises the following steps: (1) weighing raw materials; (2) preparing a humic acid sodium salt water solution; (3) preparing a large amount of nutrient element water solution of humic acid sodium salt; (4) preparing a trace nutrient element metal ion chelating agent; (5) preparing a chinaberry fruit aqueous solution or a chinaberry fruit and sea buckthorn mixed aqueous solution; (6) preparing a humic acid plant growth nutrition high-efficiency foliar fertilizer; wherein,
(1) weighing the following raw materials: weighing raw material components, namely 5-20 parts of humic acid sodium salt, 5-20 parts of urea, 4-10 parts of monopotassium phosphate, 5-10 parts of non-ionic surfactant and 0.01-1 part of functional auxiliary agent according to the formula of the humic acid plant growth nutrition high-efficiency leaf fertilizer;
(2) preparing a sodium humate saline solution: adding the weighed sodium humate into water, heating to 60-70 ℃, stirring for 3-4 hours for dissolution, and preparing a sodium humate salt water solution with the mass concentration of 5-10%;
(3) preparing a humic acid sodium salt large amount nutrient element water solution: adding the weighed urea and the weighed potassium dihydrogen phosphate into the sodium humate salt water solution, and stirring for 1-2 hours to dissolve the urea and the potassium dihydrogen phosphate to prepare a humic acid sodium salt large-amount nutrient element water solution;
(4) preparing a trace nutrient element metal ion chelating agent: weighing 0.01-0.02 part of micronutrient elements, 0.1-0.5 part of acidic solution with the pH value of 1 and 4-6 parts of ammonium bicarbonate, and preparing an ammonium bicarbonate aqueous solution with the mass concentration of 3% by using the weighed ammonium bicarbonate; pouring the weighed trace nutrient elements into hydrochloric acid or sulfuric acid solution with pH 1, and stirring to completely dissolve the trace elements to prepare trace metal ion acid solution; pouring the ammonium bicarbonate aqueous solution into the trace metal ion acidic solution step by step and stirring to form a metal ion complex, then adding the rest of the ammonium bicarbonate aqueous solution when the pH value is 3 to prepare a trace nutrient element metal ion chelating agent, and weighing 2-5 parts of the trace nutrient element metal ion chelating agent for later use;
(5) preparing a chinaberry fruit aqueous solution or a chinaberry fruit and sea buckthorn mixed aqueous solution: weighing chinaberry seeds or a mixture of the chinaberry seeds and sea buckthorn according to any ratio, crushing the weighed chinaberry seeds or the chinaberry seeds and the sea buckthorn, soaking the crushed chinaberry seeds or the chinaberry seeds and the sea buckthorn in water at 100 ℃ for 10-50 minutes to prepare a chinaberry seed aqueous solution or a chinaberry seed and sea buckthorn mixed aqueous solution, and weighing 0.5-5 parts of the chinaberry seed aqueous solution or the chinaberry seed and sea buckthorn mixed aqueous solution for later use;
(6) preparing the humic acid plant growth nutrition high-efficiency foliar fertilizer: and (3) mixing the humic acid sodium salt macronutrient element aqueous solution prepared in the step (3), the micronutrient element metal ion chelating agent weighed in the step (4) and the chinaberry seed aqueous solution weighed in the step (5), or mixing the chinaberry seed aqueous solution and the sea buckthorn aqueous solution, adding the weighed nonionic surfactant, heating to 85-95 ℃ for dissolving, and then adding the weighed functional auxiliary agent to prepare the humic acid plant growth nutrition high-efficiency leaf fertilizer.
The main raw material of the humic acid sodium salt is humic acid sodium salt containing 60 to 90 percent of fulvic acid, in particular to humic acid sodium salt containing 60 to 90 percent of fulvic acid extracted by grass peat ash through a chemical method.
The micronutrient is a mixture of any two or more than two of copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax in any ratio.
The nonionic surfactant is any one of ethylenediamine tetraacetic acid sodium salt, a compound of alkylphenol polyoxyethylene, methyl benzotriazole or sodium di-sec-octyl maleate sulfonate.
The functional auxiliary agent is any one or a mixture of more than one of mepiquat chloride, paclobutrazol, chlormequat chloride, compound sodium nitrate or alpha-naphthylacetic acid in any ratio.
The invention has the advantages that (1) the humic acid used by the invention is prepared by taking the special grass carbon ash of the left flag of the inner Mongolian tuler as a raw material and extracting humic acid sodium salt containing 60-90% of fulvic acid by a chemical method. The humic acid sodium salt has the advantages that the content of fulvic acid in the humic acid sodium salt is higher than that of humic acid sodium salt produced by other raw materials (such as weathered coal), the molecular weight is small, the activity to crops is high, and the humic acid plant growth nutrition foliar fertilizer produced by taking the humic acid sodium salt as the main raw material has the characteristics of higher efficiency, no toxicity, no residue, broad spectrum and the like, and has the advantages of wide application range of crops, wide use concentration range and the like. Is widely applicable to grain crops, economic crops, vegetables, melons and fruits, fruit trees, oil crops, flowers and the like.
(2) The invention adopts the method of adding the nonionic surfactant into the foliar fertilizer, breaks the cutin wax layer of the foliar fertilizer, reduces the surface tension of the spraying solution, increases the contact area with the leaves, extends the fertilizer liquid on the foliar fertilizer, generates a uniform and stable liquid film, enhances the adhesive capacity and the penetrating power of the fertilizer liquid on the foliar fertilizer, helps the leaves to absorb, and obviously increases and prolongs the wetting time of the fertilizer liquid on the surfaces of most leaves. Can effectively prevent fertilizer damage and improve the absorption efficiency of the effective nutrients of the foliar fertilizer by more than 20 percent.
(3) The invention adopts a method of adding traditional Chinese medicinal materials of chinaberry fruit and sea buckthorn as a foliar repairing agent in a humic acid plant growth nutrition efficient foliar fertilizer, solves the problems that due to the addition of a nonionic surfactant foliar fertilizer, a foliar cutin wax layer is broken, the growth of crops is influenced to a certain extent, and enables the foliar to be repaired in time. The spraying concentration of the foliar fertilizer can be properly improved, the spraying times are increased, the absorption of the crops to the fertilizer is accelerated, and the requirements of the crops on nutrients are met to the maximum extent.
(4) The invention adopts a method of adding the metal ion chelating agent into the humic acid plant growth nutrition high-efficiency foliar fertilizer, so as to enhance the nutrient absorption capacity of crops, enable ions of trace nutrient elements to form chelates, improve the absorption utilization rate of the trace elements and facilitate the absorption and utilization of plants.
Detailed Description
Example 1: the humic acid plant growth nutrition high-efficiency foliar fertilizer for the rapes and the Chinese cabbages comprises the following components in parts by mass: 10 parts of humic acid sodium salt containing 60% of fulvic acid, 20 parts of urea, 10 parts of monopotassium phosphate, 0.01 part of trace nutrient element, 0.1 part of sulfuric acid solution with pH value of 1 and 4 parts of ammonium bicarbonate are extracted from unique plant ash of leftflag of Mongolian montmorillonoid by a chemical method, wherein the trace nutrient element is formed by mixing copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax according to the mass ratio of 1: 1, 10 parts of ethylenediamine tetraacetic acid sodium salt and 0.5 part of a mixed preparation of chinaberry fruit and sea buckthorn, wherein the chinaberry fruit and the sea buckthorn are mixed according to the ratio of 3: 2, and 0.1 part of compound sodium nitrate is added.
The humic acid plant growth nutrition high-efficiency foliar fertilizer for the rapes and the Chinese cabbages is prepared by the following steps:
(1) weighing the following raw materials: weighing the raw material components according to the formula;
(2) preparing a sodium humate saline solution: adding the weighed sodium humate into water, heating to 60 ℃, stirring for 4 hours to dissolve, and preparing a sodium humate aqueous solution with the mass concentration of 5%;
(3) preparing a humic acid sodium salt large amount nutrient element water solution: adding weighed urea and potassium dihydrogen phosphate into the sodium humate salt water solution, stirring for 2 hours to dissolve, and preparing the sodium humate salt nutrient element water solution;
(4) preparing a trace nutrient element metal ion chelating agent: preparing an ammonium bicarbonate aqueous solution with the mass concentration of 3% by using the weighed ammonium bicarbonate; mixing the weighed copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax, pouring the mixture into a sulfuric acid solution with pH of 1, and stirring to completely dissolve trace elements to prepare a trace metal ion acidic solution; pouring the prepared ammonium bicarbonate aqueous solution into the trace metal ion acidic solution step by step, stirring to form a metal ion complex, and then adding the rest ammonium bicarbonate aqueous solution when the pH value is 3 to prepare the trace nutrient element metal ion chelating agent;
(5) preparing a mixed aqueous solution of chinaberry seeds and sea buckthorn: pulverizing the weighed chinaberry seeds and sea buckthorn, and soaking in water at 100 ℃ for 10 minutes to prepare a mixed aqueous solution of the chinaberry seeds and the sea buckthorn;
(6) preparing the humic acid plant growth nutrition high-efficiency foliar fertilizer: and (3) completely mixing the humic acid sodium salt macronutrient element aqueous solution prepared in the step (3), the micronutrient element metal ion chelating agent prepared in the step (4), the chinaberry seed prepared in the step (5) and the sea buckthorn aqueous solution, adding the weighed ethylene diamine tetraacetic acid sodium salt, heating to 85 ℃ for dissolving, and then adding the weighed compound sodium nitrate to prepare the humic acid plant growth nutrition efficient foliar fertilizer for the rapes and the Chinese cabbages.
The humic acid plant growth nutrition high-efficiency foliar fertilizer of rape and Chinese cabbage is compared with the existing humic acid foliar fertilizer, and the test results are shown in the following table:
the humic acid plant growth nutrition high-efficiency foliar fertilizer for the rapes and the Chinese cabbages can promote plant absorption and improve the absorption efficiency. Can promote development of rhizome, grow rapidly, and improve quality, with dark green leaf color, and thick leaf surface. As can be seen from the data in the table above, the yield of the crops is increased by more than 30%.
Example 2: the humic acid plant growth nutrition high-efficiency foliar fertilizer for tomatoes and green beans comprises the following components in parts by mass: 5 parts of humic acid sodium salt containing 90% of fulvic acid, 10 parts of urea, 4 parts of monopotassium phosphate, 0.02 part of trace nutrient element, 0.5 part of hydrochloric acid solution with pH being 1 and 6 parts of ammonium bicarbonate are extracted from unique plant ash of leftflag of Mongolian tulip by a chemical method, wherein the trace nutrient element is formed by mixing copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid and borax according to the mass ratio of 1: 2: 5: 1, 5 parts of compound of alkylphenol polyoxyethylene and 5 parts of mixed preparation of chinaberry fruit and sea buckthorn, wherein the chinaberry fruit and the sea buckthorn are mixed according to the mass ratio of 3: 7, and the mepiquat chloride and paclobutrazol are mixed according to the mass ratio of 1: 4 to form 1 part.
The humic acid plant growth nutrition high-efficiency foliar fertilizer for tomatoes and green beans is prepared by the following steps:
(1) weighing the following raw materials: weighing the raw material components according to the formula;
(2) preparing a sodium humate saline solution: adding the weighed sodium humate into water, heating to 70 ℃, stirring for 3 hours to dissolve, and preparing a sodium humate salt water solution with the mass concentration of 10%;
(3) preparing a humic acid sodium salt large amount nutrient element water solution: adding weighed urea and potassium dihydrogen phosphate into the sodium humate salt water solution, stirring for 1 hour to dissolve, and preparing the sodium humate salt nutrient element water solution;
(4) preparing a trace nutrient element metal ion chelating agent: preparing an ammonium bicarbonate aqueous solution with the mass concentration of 3% by using the weighed ammonium bicarbonate; mixing the weighed copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid and borax, pouring into a hydrochloric acid solution with pH being 1, and stirring to completely dissolve trace elements to prepare a trace metal ion acid solution; pouring the prepared ammonium bicarbonate aqueous solution into the trace metal ion acidic solution step by step, stirring to form a metal ion complex, and then adding the rest ammonium bicarbonate aqueous solution when the pH value is 3 to prepare the trace nutrient element metal ion chelating agent;
(5) preparing a mixed aqueous solution of chinaberry seeds and sea buckthorn: pulverizing the weighed chinaberry seeds and sea buckthorn, and soaking the pulverized chinaberry seeds and sea buckthorn in water at 100 ℃ for 50 minutes to prepare a mixed aqueous solution of the chinaberry seeds and the sea buckthorn;
(6) preparing the humic acid plant growth nutrition high-efficiency foliar fertilizer: and (3) completely mixing the humic acid sodium salt macronutrient element aqueous solution prepared in the step (3), the micronutrient element metal ion chelating agent prepared in the step (4) and the chinaberry seed and sea buckthorn aqueous solution prepared in the step (5), adding the weighed alkylphenol polyoxyethylene ether, heating to 95 ℃ for dissolving, then adding the weighed mepiquat chloride and paclobutrazol to prepare the humic acid plant growth nutrition efficient leaf fertilizer for the tomatoes and the beans.
The humic acid plant growth nutrition high-efficiency foliar fertilizer of the tomatoes and the beans is compared with the existing humic acid foliar fertilizer, and the test results are shown in the following table:
the humic acid plant growth nutrition high-efficiency foliar fertilizer for the tomatoes and the green beans can promote plant absorption and improve the absorption efficiency. Can increase the fruit bearing rate, and has large and uniform fruit and good quality. As can be seen from the data in the table above, the yield of the crops is increased by more than 30%.
Example 3: the humic acid plant growth nutrition high-efficiency foliar fertilizer for the corn comprises the following components in parts by mass: 20 parts of humic acid sodium salt containing 70% of fulvic acid, 5 parts of urea, 8 parts of monopotassium phosphate, 0.015 part of trace nutrient elements, 0.3 part of hydrochloric acid solution with pH being 1 and 5 parts of ammonium bicarbonate, wherein the trace nutrient elements are formed by mixing copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, molybdic acid and borax according to the mass ratio of 3: 1: 2: 1, 8 parts of di-sec-octyl maleate sodium sulfonate, 2 parts of chinaberry fruit preparation and 0.01 part of alpha-naphthylacetic acid.
The humic acid plant growth nutrition high-efficiency foliar fertilizer for corn is prepared by the following steps:
(1) weighing the following raw materials: weighing the raw material components according to the formula;
(2) preparing a sodium humate saline solution: adding the weighed sodium humate into water, heating to 65 ℃, stirring for 3 hours to dissolve, and preparing a sodium humate aqueous solution with the mass concentration of 8%;
(3) preparing a humic acid sodium salt large amount nutrient element water solution: adding weighed urea and potassium dihydrogen phosphate into the sodium humate salt water solution, stirring for 1.5 hours to dissolve, and preparing the sodium humate salt nutrient element water solution;
(4) preparing a trace nutrient element metal ion chelating agent: preparing an ammonium bicarbonate aqueous solution with the mass concentration of 3% by using the weighed ammonium bicarbonate; mixing the weighed copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, molybdic acid and borax, pouring the mixture into a hydrochloric acid solution with the pH value of 1, and stirring to completely dissolve trace elements to prepare a trace metal ion acid solution; pouring the prepared ammonium bicarbonate aqueous solution into the trace metal ion acidic solution step by step, stirring to form a metal ion complex, and then adding the rest ammonium bicarbonate aqueous solution when the pH value is 3 to prepare the trace nutrient element metal ion chelating agent;
(5) preparing a mixed aqueous solution of chinaberry seeds and sea buckthorn: pulverizing the weighed chinaberry seeds and sea buckthorn, and soaking in water at 100 ℃ for 30 minutes to prepare a chinaberry seed aqueous solution;
(6) preparing the humic acid plant growth nutrition high-efficiency foliar fertilizer: and (3) completely mixing the humic acid sodium salt macronutrient element aqueous solution prepared in the step (3), the micronutrient element metal ion chelating agent prepared in the step (4) and the chinaberry seed aqueous solution prepared in the step (5), adding the weighed di-sec-octyl maleate sodium sulfonate, heating to 90 ℃ for dissolving, and then adding the weighed alpha-naphthylacetic acid to prepare the humic acid plant growth nutrition efficient leaf fertilizer for the tomatoes and the green beans.
The humic acid plant growth nutrition high-efficiency foliar fertilizer of the corn is compared with the existing humic acid foliar fertilizer, and the test results are shown in the following table:
the humic acid plant growth nutrition high-efficiency foliar fertilizer for the corn can promote plant absorption and improve the absorption efficiency. Can make the stems and leaves of the crops strong, the ears and the bags are neat, the seed setting rate is increased, and the quality is good. As can be seen from the data in the table above, the yield of the crops is increased by more than 10%.
Claims (11)
1. The humic acid plant growth nutrition high-efficiency foliar fertilizer is characterized by comprising the following components in parts by mass: 5-20 parts of humic acid sodium salt, 5-20 parts of urea, 4-10 parts of monopotassium phosphate, 2-5 parts of a trace nutrient metal ion chelating agent, 4-6 parts of ammonium bicarbonate, 5-10 parts of a non-ionic surfactant, 0.5-5 parts of a chinaberry fruit preparation or a mixed preparation of chinaberry fruit and sea buckthorn mixed according to any ratio, and 0.01-1 part of a functional auxiliary agent.
2. The humic acid plant growth nutrition high-efficiency foliar fertilizer as claimed in claim 1, wherein the main raw material of the humic acid sodium salt is humic acid sodium salt containing fulvic acid 60-90%, especially humic acid sodium salt containing fulvic acid 60-90% extracted from grass peat ash by a chemical method.
3. The humic acid plant growth nutrition high-efficiency foliar fertilizer as claimed in claim 1, wherein the micronutrient metal ion chelating agent is prepared from the following components by weight: 0.01-0.02 part of trace nutrient elements, 0.1-0.5 part of acidic solution with pH 1 and 4-6 parts of ammonium bicarbonate.
4. The humic acid plant growth nutrition high-efficiency foliar fertilizer as claimed in claim 3, wherein the micronutrient is any two or more of copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax in any ratio.
5. The humic acid plant growth nutrition high-efficiency foliar fertilizer as claimed in claim 1, wherein the non-ionic surfactant is any one of ethylene diamine tetraacetic acid sodium salt, compound of alkylphenol polyoxyethylene, methyl phenyl triazole or sodium di-sec-octyl maleate sulfonate.
6. The humic acid plant growth nutrition high-efficiency foliar fertilizer as claimed in claim 1, wherein the functional type auxiliary agent is any one or a mixture of more than one of mepiquat chloride, paclobutrazol, chlormequat chloride, compound sodium nitrate or alpha-naphthylacetic acid in any ratio.
7. The preparation method of the humic acid plant growth nutrition high-efficiency foliar fertilizer is characterized by comprising the following steps: (1) weighing raw materials; (2) preparing a humic acid sodium salt water solution; (3) preparing a large amount of nutrient element water solution of humic acid sodium salt; (4) preparing a trace nutrient element metal ion chelating agent; (5) preparing a chinaberry fruit aqueous solution or a chinaberry fruit and sea buckthorn mixed aqueous solution; (6) preparing a humic acid plant growth nutrition high-efficiency foliar fertilizer; wherein,
(1) weighing the following raw materials: weighing raw material components, namely 5-20 parts of humic acid sodium salt, 5-20 parts of urea, 4-10 parts of monopotassium phosphate, 5-10 parts of non-ionic surfactant and 0.01-1 part of functional auxiliary agent according to the formula of the humic acid plant growth nutrition high-efficiency leaf fertilizer;
(2) preparing a sodium humate saline solution: adding the weighed sodium humate into water, heating to 60-70 ℃, stirring for 3-4 hours for dissolution, and preparing a sodium humate salt water solution with the mass concentration of 5-10%;
(3) preparing a humic acid sodium salt large amount nutrient element water solution: adding the weighed urea and the weighed potassium dihydrogen phosphate into the sodium humate salt water solution, and stirring for 1-2 hours to dissolve the urea and the potassium dihydrogen phosphate to prepare a humic acid sodium salt large-amount nutrient element water solution;
(4) preparing a trace nutrient element metal ion chelating agent: weighing 0.01-0.02 part of micronutrient elements, 0.1-0.5 part of acidic solution with the pH value of 1 and 4-6 parts of ammonium bicarbonate, and preparing an ammonium bicarbonate aqueous solution with the mass concentration of 3% by using the weighed ammonium bicarbonate; pouring the weighed trace nutrient elements into hydrochloric acid or sulfuric acid solution with pH 1, and stirring to completely dissolve the trace elements to prepare trace metal ion acid solution; pouring the ammonium bicarbonate aqueous solution into the trace metal ion acidic solution step by step and stirring to form a metal ion complex, then adding the rest of the ammonium bicarbonate aqueous solution when the pH value is 3 to prepare a trace nutrient element metal ion chelating agent, and weighing 2-5 parts of the trace nutrient element metal ion chelating agent for later use;
(5) preparing a chinaberry fruit aqueous solution or a chinaberry fruit and sea buckthorn mixed aqueous solution: weighing chinaberry seeds or a mixture of the chinaberry seeds and sea buckthorn according to any ratio, crushing the weighed chinaberry seeds or the chinaberry seeds and the sea buckthorn, soaking the crushed chinaberry seeds or the chinaberry seeds and the sea buckthorn in water at 100 ℃ for 10-50 minutes to prepare a chinaberry seed aqueous solution or a chinaberry seed and sea buckthorn mixed aqueous solution, and weighing 0.5-5 parts of the chinaberry seed aqueous solution or the chinaberry seed and sea buckthorn mixed aqueous solution for later use;
(6) preparing the humic acid plant growth nutrition high-efficiency foliar fertilizer: and (3) mixing the humic acid sodium salt macronutrient element aqueous solution prepared in the step (3), the micronutrient element metal ion chelating agent weighed in the step (4) and the chinaberry seed aqueous solution weighed in the step (5), or mixing the chinaberry seed aqueous solution and the sea buckthorn aqueous solution, adding the weighed nonionic surfactant, heating to 85-95 ℃ for dissolving, and then adding the weighed functional auxiliary agent to prepare the humic acid plant growth nutrition high-efficiency leaf fertilizer.
8. The preparation method of the humic acid plant growth nutrition high efficiency foliar fertilizer as claimed in claim 7, characterized in that the main raw material of the humic acid sodium salt is humic acid sodium salt containing fulvic acid 60-90%, especially humic acid sodium salt containing fulvic acid 60-90% extracted by a chemical method with grass peat ash.
9. The preparation method of the humic acid plant growth nutrition and high efficiency foliar fertilizer as claimed in claim 7, wherein the micronutrient is any two or more than two of copper sulfate, magnesium sulfate, ferrous sulfate, zinc sulfate, manganese sulfate, strontium nitrate, molybdic acid, selenium dioxide and borax in any ratio.
10. The preparation method of the humic acid plant growth nutrition high efficiency foliar fertilizer as claimed in claim 7, wherein the non-ionic surfactant is any one of ethylene diamine tetraacetic acid sodium salt, compound of alkylphenol polyoxyethylene, methyl phenyl triazole or sodium di-sec-octyl maleate sulfonate.
11. The preparation method of the humic acid plant growth nutrition high efficiency foliar fertilizer as claimed in claim 7, wherein the functional type auxiliary agent is any one or a mixture of more than one of mepiquat chloride, paclobutrazol, chlormequat chloride, compound sodium nitrate or alpha-naphthylacetic acid in any ratio.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1217309A (en) * | 1997-11-15 | 1999-05-26 | 李桂英 | Organic liquid fertilizer mainly containing yellow humic-acid |
| CN1445202A (en) * | 2002-03-20 | 2003-10-01 | 王兴中 | Fertilizer for spraying on leaf surface with biologic raw materials as main material |
| CN1803737A (en) * | 2005-12-16 | 2006-07-19 | 朱有明 | Insect and disease resistant ammonium humate organic composite fertilizer |
-
2010
- 2010-12-31 CN CN201010624474.5A patent/CN102167635B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1217309A (en) * | 1997-11-15 | 1999-05-26 | 李桂英 | Organic liquid fertilizer mainly containing yellow humic-acid |
| CN1445202A (en) * | 2002-03-20 | 2003-10-01 | 王兴中 | Fertilizer for spraying on leaf surface with biologic raw materials as main material |
| CN1803737A (en) * | 2005-12-16 | 2006-07-19 | 朱有明 | Insect and disease resistant ammonium humate organic composite fertilizer |
Non-Patent Citations (1)
| Title |
|---|
| 孙涛等: "腐植酸叶面肥和控释肥对水稻生长发育的影响研究", 《腐植酸》, no. 5, 31 December 2006 (2006-12-31), pages 28 - 32 * |
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