CN102154949B - Method for manufacturing recyclable and reusable stone paper - Google Patents
Method for manufacturing recyclable and reusable stone paper Download PDFInfo
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- CN102154949B CN102154949B CN201010276851.0A CN201010276851A CN102154949B CN 102154949 B CN102154949 B CN 102154949B CN 201010276851 A CN201010276851 A CN 201010276851A CN 102154949 B CN102154949 B CN 102154949B
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Abstract
The invention discloses a method for manufacturing recyclable and reusable stone paper. The composition of the paper comprises 60 to 85 weight percent of natural inorganic mineral powder, 15 to 40 weight percent of polypropylene and 1 to 5 weight percent of auxiliary agent. A continuous calendaring forming mode is adopted in the manufacturing method; the composition of the paper material does not need to be processed into granular raw material master batch and is directly put into a calendaring papermaking device; and the calendaring papermaking device comprises an automatic raw material weighing machine, an automatic mixing stirrer, a mixing tablet press, a high-density flat extruder, a five-wheel calendaring former and a forming cooling setting machine. Therefore, the used paper can be recycled and regenerated, little polypropylene component is burnt during combustion; high temperature, black smoke or poison gas is not produced during combustion of the paper; many residues containing the natural inorganic mineral powder are produced after combustion, and the paper has environment-friendly property of regressing to the land and the nature.
Description
Technical field
The manufacture method of the relevant environment protecting paper of the present invention, espespecially a kind of manufacture method of stone paper of recyclable recycling.
Background technology
At present invented in the world multiple synthetic paper, wherein take polypropylene as Main Ingredients and Appearance material, and take individual layer that inorganic mineral powder makes as filler combination and the synthetic paper of sandwich construction, all with traditional plastic membrane product formula, manufactured; And with single or multiple lift co-extrusion, shaping mould is made sheet material with yi word pattern mould mouth structure in processing procedure, the sheet surface both sides after longitudinal stretching, then the sheet material or with film sheet material of fitting, then through cross directional stretch; This made synthetic paper intermediate layer has two-way extension, and superficial layer has simple tension, becomes the synthetic paper of sandwich construction.
As the sheet material after longitudinal stretching, directly again through cross directional stretch, the surface of made single or multiple lift synthetic paper has two-way elongation property, and though above-mentioned prepared synthetic paper has its advantage, but with the Performance Ratio of wood pulp paper under, difference is still very large, and the shortcoming of above-mentioned synthetic paper such as: folding property is bad, laterally differ too much with longitudinal tear or there is no a lancinating ... etc.; Separately, the synthetic paper that the polypropylene plastics of take makes as main material, after using, as being discarded in open air, oxidation Decomposition under large natural environment, can not reduce secondary pollution at short notice; And the synthetic paper cost of making is also much higher than wooden oar papermaking.Shortcoming based on above, synthetic paper fails favored by consumer always.
Summary of the invention
Problem in view of prior art, the object of the invention is to provide a kind of manufacture method of stone paper of recyclable recycling, so as to solving to commonly use, take the synthetic paper that polypropylene plastics makes as main material, use rear as being discarded in open air, oxidation Decomposition under large natural environment, fails to reduce secondary pollution at short notice; And the synthetic paper cost of making is also than the much higher problem of wooden oar papermaking.
Object of the present invention is the stone paper that is to provide a kind of recyclable recycling, and the material of this stone paper comprises: 60% to 85% natural inorganic breeze by weight, 15% to 40% polypropylene and 1% to 5% by weight auxiliary agent by weight.
This natural inorganic breeze is selected: calcium carbonate, flyash, calcium sulfate, barium sulfate, kaolin, mica powder, zinc oxide, dolomite dust, calcium silicates, glass fibre, hollow glass micropearl, Cab-O-sil, whiting, talcum powder, pigment, titanium dioxide, silica, bentonite, carclazyte or diatomite, or the mixture of at least two kinds of above-mentioned materials.
This auxiliary agent comprises coupling agent, dispersant, antistatic additive, solid softener, activator, promoter, age resistor, antiscorching agent, adhesive and/or heat-resistant agent.
This coupling agent is β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane; Lubrication prescription is N-oleyl palmitamide; Antistatic additive is N, two (2-ethoxy) stearmide and/or the N of N-, two (2-ethoxy) coconut amines of N-.
The manufacture method of the stone paper of foregoing recyclable recycling, the composition of this paper material does not need to be processed into granular raw material master batch, directly drop into calendering papermaking apparatus, and calendering papermaking apparatus comprises that raw material automatic metering mechanism, automatic mixed stirring machine, mixed pressuring plate machine, high density squeeze flat machine, 5 and take turns calendering forming machine and moulding cooling calibrator, its step comprises:
First step: by raw material automatic metering mechanism by the composition of paper according to the direct charging of needed raw material ratio formula, metering, and deliver to automatic mixed stirring machine;
Second step: via the continuous mix and blend of automatic mixed stirring machine, the composition material of paper is on average mixed the composition of paper;
Third step: the composition of the paper mixing is delivered directly to mixed pressuring plate machine, utilizes mixed pressuring plate mode that the two-way extension of the composition of paper rubbing is average, make the composition of paper form continuous form sheet;
The 4th step: the average paper sheet delivery of rubbing to high density is squeezed to flat machine, paper is again mixed, flattened, make that its soft durometer is moderate and tension force is moderate;
The 5th step: utilize 5 take turns calendering forming machine by paper reverse to rolling sizing, and paper is done laterally and two-way extension longitudinally simultaneously;
The 6th step: recycling moulding cooling calibrator is pressed paper continuously, and paper is done laterally to control paper thickness with two-way extension longitudinally and adjustment, complete. simultaneously
This calendering papermaking apparatus can include an automatic paper winder and a trimmer, and the paper that the 6th step is completed utilizes automatic paper winder to be rolled into after paper roll shape, and recycling trimmer cuts into paper finished product on the plane paper of required size.
5 of the 5th step is taken turns calendering forming machine and is utilized high temperature calendering, with the characteristic of the composite formula according to paper, adjusts temperature, makes composition material hot melt, mixing, the two-way extension of paper.
The moulding cooling calibrator of the 6th step can be according to the paper sheet thickness of needs, the allotment calendering time.
The surface-coated oiliness coating fluid of the paper that the 6th step completes.
The surface of the paper that the 6th step completes can be coated with fabric aqueous coating fluid, by unicoater, uncoated paper is discharged to automatic evener, with traction, flatten and paper surface is carried out to corona treatment, make paper both side surface after electrion is processed, countless fine emptying apertures can be formed on paper surface, to improve the adhesion when paper surface is coated with; Paper tractor to front coating machine is done to coating for the first time; Again by Paper tractor to dry type baking box, make its dry tack free of paper conveniently carry out reverse side application; Via reverse side coating machine, utilize plural shower nozzle to control the coating weight of coating fluid, paper is carried out to reverse side coating; Again Paper tractor to dry type baking box is dried coating surface, make paper in heating the lower surface energy rapid draing being coated with that can allow, and reach the effect that paper surface is light face.
Beneficial effect of the present invention is: after the stone paper of manufacturing is finished, recyclable regeneration, during burning, only can burn the less polypropylene of composition, do not produce high temperature and black smoke and without poison gas, the residue that contains the more natural inorganic breeze of composition after burning, has and can return the earth and return in natural environmental protection characteristic.
Accompanying drawing explanation
Fig. 1 is calendering papermaking apparatus schematic diagram of the present invention.
Fig. 2 is raw material automatic metering mechanism schematic diagram of the present invention.
Fig. 3 is automatic mixed stirring machine schematic diagram of the present invention.
Fig. 4 is mixed pressuring plate machine schematic diagram of the present invention.
Fig. 5 is that high density of the present invention is squeezed flat machine schematic diagram.
Fig. 6 of the present invention 5 takes turns calendering forming machine schematic diagram.
Fig. 7 is moulding cooling calibrator schematic diagram of the present invention.
Fig. 8 is automatic paper winder schematic diagram of the present invention.
Fig. 9 is trimmer schematic diagram of the present invention.
Figure 10 is unicoater schematic diagram of the present invention.
Figure 11 is automatic evener schematic diagram of the present invention.
Figure 12 is front of the present invention coating machine schematic diagram.
Figure 13 is dry type baking box schematic diagram of the present invention.
Figure 14 is reverse side coating machine schematic diagram of the present invention.
Figure 15 is reel machine schematic diagram of the present invention.
[main element symbol description]
10, calendering papermaking apparatus
11, raw material automatic metering mechanism 12, automatic mixed stirring machine
13, mixed pressuring plate machine 14, high density are squeezed flat machine
15,5 take turns calendering forming machine 16, moulding cooling calibrator
17, automatic paper winder 18, trimmer
20, unicoater
21, automatic evener 22, front coating machine
23, dry type baking box 24, reverse side coating machine
25, reel machine
The specific embodiment
For the effect that makes to facilitate simple and direct understanding other features of the present invention and advantage and reach can more manifest, hereby the present invention is coordinated to accompanying drawing, describe feature of the present invention and advantage in detail, each following embodiment further describes viewpoint of the present invention, but non-to limit anyways category of the present invention.
Refer to shown in Fig. 1 to 9, the present invention discloses a kind of manufacture method of stone paper of recyclable recycling, wherein, the composition of this paper comprises that 60% to 85% weight natural inorganic breeze is (as calcium carbonate (comprises precipitated calcium carbonate, powdered whiting, calcene), flyash, calcium sulfate, barium sulfate, kaolin, mica powder, zinc oxide, dolomite dust, calcium silicates, glass fibre, hollow glass micropearl, Cab-O-sil, whiting, talcum powder, pigment, titanium dioxide, silica, bentonite, carclazyte, diatomite and composition thereof (it is through calcination or without calcination person) is made main raw material, 15% to 40% weight polyacrylamide (Polypropylene is called for short PP), 1% to 5% weight auxiliary agent.And polypropylene can comprise the combination of high density poly propylene, low density polypropylene and low density polyethylene (LDPE); Auxiliary agent can comprise coupling agent, lubrication prescription (dispersant), antistatic additive, solid softener, activator, promoter, age resistor, antiscorching agent, adhesive, heat-resistant agent ... wait raw material; Coupling agent can be β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane; Lubrication prescription can be N-oleyl palmitamide; Antistatic additive can be N, two (2-ethoxy) stearmide and the N of N-, two (2-ethoxy) coconut amines of N-.
The composition of aforementioned stone paper does not need to be processed into granular raw material master batch, and can directly drop into calendering papermaking apparatus 10, this calendering papermaking apparatus 10 comprises that raw material automatic metering mechanism 11, automatic mixed stirring machine 12, mixed pressuring plate machine 13, high density squeeze flat machine 14,5 and take turns calendering forming machine 15, moulding cooling calibrator 16, automatic paper winder 17, trimmer 18, and its step comprises:
First step: by raw material automatic metering mechanism 11 by the composition of paper according to the direct charging of needed raw material ratio formula, metering, and deliver to automatic mixed stirring machine 12.
Second step: via the continuous mix and blend of automatic mixed stirring machine 12, the composition material of paper is on average mixed the composition of paper.
Third step: the composition of the paper mixing is delivered directly to mixed pressuring plate machine 13, utilizes mixed pressuring plate mode that the two-way extension of the composition of paper rubbing is average, make the composition of paper form continuous form sheet.
The 4th step: the average paper sheet delivery of rubbing to high density is squeezed to flat machine 14, paper is again mixed, flattened, make that its soft durometer is moderate and tension force is moderate.
The 5th step: utilize 5 take turns calendering forming machine 15 by paper reverse to rolling sizing, and paper is done laterally and two-way extension longitudinally simultaneously.
The 6th step: recycling moulding cooling calibrator 16 is pressed paper continuously, and paper is done laterally to control paper thickness with two-way extension longitudinally and adjustment, complete. simultaneously
The 7th step: can utilize automatic paper winder 17 that paper finished product coil paper is become to paper roll shape.
The 8th step: can utilize trimmer 18 paper finished product to be cut into the plane paper of required size.
So, the composition of paper of the present invention comprises the composition manufacturing paper of the paper of 60% to 85% weight natural inorganic breeze, 15% to 40% weight polyacrylamide (PP) and 1% to 5% weight auxiliary agent, heterogeneity according to auxiliary agent, can be distinguished into, Biodegradable material, resolves into carbon dioxide and water by microorganism in environment it.Another is light decomposability material, utilizes ultraviolet ray in daylight to impel the macromolecular backbone breaking of decomposing material, makes its decomposition.The 3rd is oxidation Decomposition material, utilizes material and oxygen effect form oxide and decompose.Allow used paper reach recyclable regeneration, while even burning, only can burn the less polypropylene of composition, do not produce high temperature and black smoke and without poison gas, residue containing the more natural inorganic breeze of composition after burning can return the earth, back to nature, do not produce poison gas or polluted source, can accord with environmental requirement completely; In addition, the composition of stone paper of the present invention can must not reproduce a program according to the direct automatic feed of material rate formula, metering, can reduce to mix to manufacture the required cost of raw material master batch.
5 of aforementioned the 5th step is taken turns calendering forming machine 15 and is utilized high temperature calendering, with the characteristic of the composite formula according to stone paper, adjusts temperature, makes composition material hot melt, mixing, the two-way extension of stone paper; The 6th step by moulding cooling calibrator 16 can be according to paper sheet thickness, the product characteristics of needs, the allotment calendering time; And in abovementioned steps, what need as stone paper finished product is paper roll pattern, can omit the 8th step.
And manufacture method one embodiment of the stone paper of the recyclable recycling of the present invention, wherein the composition of paper can be the natural inorganic breeze (wherein calcium carbonate account for 32 % by weight, titanium dioxide account for 7 % by weight, diatomite accounts for 26 % by weight) of 65 % by weight; The polypropylene of 33 % by weight and 2 % by weight auxiliary agents (0.8 % by weight β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane, 0.4 % by weight N-oleyl palmitamide and 0.8 % by weight N, two (2-ethoxy) stearmides of N-).Above composition composition adds up to 100 % by weight, after mixing extruding is mixing, drops into calendering papermaking apparatus 10, according to the requirement of product thickness, produces the paper of adjusting the recyclable recycling that produces 0.1mm.
And another embodiment of the manufacture method of the stone paper of the recyclable recycling of the present invention, wherein the composition of paper can be the natural inorganic breeze (wherein calcium carbonate accounts for 40 % by weight, titanium dioxide and accounts for that 4 % by weight, diatomite account for 25 % by weight, carclazyte accounts for 6 % by weight) of 75 % by weight; 21 % by weight polypropylene and 4 % by weight auxiliary agents (1.5 % by weight β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane, 1 % by weight N-oleyl palmitamide and 1.5 % by weight N, two (2-ethoxy) stearmides of N-).Above material composition adds up to 100 % by weight, after mixing extruding is mixing, drops into calendering papermaking apparatus 10, according to the requirement of product thickness, produces the paper of adjusting the recyclable recycling that produces 0.2mm.
And the manufacture method of the stone paper of the recyclable recycling of a present invention embodiment again, wherein the composition of paper can be the natural inorganic breeze (wherein calcium carbonate accounts for 50 % by weight, titanium dioxide and accounts for that 8 % by weight, diatomite account for 24 % by weight, talcum powder accounts for 3 % by weight) of 85 % by weight; 10 % by weight polypropylene and 5 % by weight auxiliary agents (2.2 % by weight β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane, 0.6 % by weight N-oleyl palmitamide and 2.2 % by weight N, two (2-ethoxy) stearmides of N-).Above material composition adds up to 100 % by weight, after mixing extruding is mixing, drops into calendering manufacturing machine, according to the requirement of product thickness, produces the paper of adjusting the recyclable recycling that produces 0.7mm.
Moreover the manufacture method of the stone paper of the recyclable recycling of the present invention can be according to paper sheet thickness, characteristic, range of application can be more afterwards processing and manufacturing processed become monthly calendar, year calendar, hang picture, traffic map, notebook, description, industrial and commercial daily record, letter paper, books, trade mark, placard, drop, various handbags, wrapping paper, decoration plane material, wallpaper, the laminating of woven bag surface, release liners, heat sealed package bag, stickers paper, laminating plane materiel, map, self-adhesion trade mark, plastic floor tile surface laminating material, shopping bag, all kinds of handbags, wallpaper, newspaper, loose-leaf paper, notebook, books, table is gone through, envelope, reflective sheeting, description, teaching material, festival celebration greeting card, Three-dimensional greeting card, playing card, business card, famous brand, elevator, picture, cover, various packing boxes, footwear box, cigarette case, tea caddy, meal pad, curtain, list, food package box, frozen food tray, disposable utensils, convenient lunch box, sun-shading curtain for automobile, artistic lamp-ornaments, the super freezing plug-in card of business, 3D three-dimensional paper carving, coupon, scorecard, catalogue, plate mat, plastic floor tile, large-scale advertisement, lamp box advertisement.The cultural papers such as printing, writing paper, computer coinage paper using, and decorate paper using, package paper etc.Some paper can be directly for, some needs surface-coated to make cloudy surface or the light face of specific use.
Referring again to shown in Figure 10 to 15, the surface-coated of the stone paper of the recyclable recycling of the present invention can adopt oiliness coating fluid or water-based coating fluid.And if during with water-based coating fluid, water-based coating fluid formula can be the coating fluid that acryl resin, isopropyl alcohol, polyvinyl alcohol, carclazyte, antistatic additive, 28% ammoniacal liquor, pure water, vinyl acetate are formed by combining.By unicoater 20, uncoated paper is discharged to automatic evener 21, with traction, flatten and paper surface is carried out to corona treatment, make paper both side surface after electrion is processed, countless fine emptying apertures can be formed on paper surface, to improve the adhesion when paper surface is coated with; Paper tractor to front coating machine 22 is done to coating for the first time; Again by Paper tractor to dry type baking box 23, make its dry tack free of paper conveniently carry out reverse side application; Via reverse side coating machine 24, utilize plural shower nozzle to control the coating weight of coating fluid, paper is carried out to reverse side coating; Again Paper tractor to 23 pairs of coating surfaces of dry type baking box are dried, make paper in heating the lower surface energy rapid draing being coated with that can allow, and reach the effect that paper surface is light face.In addition,, if when Paper Coating surface needs cloudy surface to process,, with the pressurization of cloudy surface treatment wheel, order becomes cloudy surface through being coated with dried smooth surface, then through reel machine 25, the paper after coating is rolled into paper roll.
In sum, the present invention is breaking through under previous technical pattern, really reached the wish effect of promoting, and also non-for having and conventionally know that the prior art that the knowledgeable complies with before application can complete easily in technical field under it, application for a patent for invention is hence proposed in accordance with the law.
Claims (3)
1. a manufacture method for the stone paper of recyclable recycling, is characterized in that,
The material of this stone paper comprises: 75% to 85% natural inorganic breeze by weight, and 15% to 21% polypropylene and 4% to 5% by weight auxiliary agent by weight, wherein:
This natural inorganic breeze is selected: calcium carbonate, flyash, calcium sulfate, barium sulfate, kaolin, mica powder, zinc oxide, dolomite dust, calcium silicates, glass fibre, hollow glass micropearl, Cab-O-sil, whiting, talcum powder, pigment, titanium dioxide, silica, bentonite, carclazyte or diatomite, or the mixture of at least two kinds of above-mentioned materials;
This auxiliary agent comprises coupling agent, lubrication prescription, dispersant, antistatic additive, solid softener, activator, promoter, age resistor, antiscorching agent, adhesive and heat-resistant agent, and this coupling agent is β-(3,4-epoxy radicals cyclohexyl) ethyl trimethoxy silane; Lubrication prescription is N-oleyl palmitamide; Antistatic additive is N, two (2-ethoxy) stearmide and/or the N of N-, two (2-ethoxy) coconut amines of N-;
The composition of this paper material does not need to be processed into granular raw material master batch, directly drop into calendering papermaking apparatus, and calendering papermaking apparatus comprises that raw material automatic metering mechanism, automatic mixed stirring machine, mixed pressuring plate machine, high density squeeze flat machine, 5 and take turns calendering forming machine and moulding cooling calibrator, its step comprises:
First step: by raw material automatic metering mechanism by the composition of paper according to the direct charging of needed raw material ratio formula, metering, and deliver to automatic mixed stirring machine;
Second step: via the continuous mix and blend of automatic mixed stirring machine, the composition material of paper is on average mixed the composition of paper;
Third step: the composition of the paper mixing is delivered directly to mixed pressuring plate machine, utilizes mixed pressuring plate mode that the two-way extension of the composition of paper rubbing is average, make the composition of paper form continuous form sheet;
The 4th step: the average paper sheet delivery of rubbing to high density is squeezed to flat machine, paper is again mixed, flattened, make that its soft durometer is moderate and tension force is moderate;
The 5th step: utilize 5 take turns calendering forming machine utilize high temperature calendering by paper reverse to rolling sizing, and paper is done laterally and two-way extension longitudinally simultaneously;
The 6th step: utilize moulding cooling calibrator that paper is pressed continuously, paper is done laterally to control paper thickness with two-way extension longitudinally and adjustment simultaneously, and according to the paper sheet thickness allotment calendering time;
The surface of the paper that the 6th step completes can be coated with oiliness or water-based coating fluid, by unicoater, uncoated paper is discharged to automatic evener, with traction, flatten and paper surface is carried out to corona treatment, make paper both side surface after electrion is processed, countless fine emptying apertures can be formed on paper surface, to improve the adhesion when paper surface is coated with; Paper tractor to front coating machine is done to coating for the first time; Again by Paper tractor to dry type baking box, make its dry tack free of paper conveniently carry out reverse side application; Via reverse side coating machine, utilize plural shower nozzle to control the coating weight of coating fluid, paper is carried out to reverse side coating; Again Paper tractor to dry type baking box is dried coating surface, make paper in heating the lower surface energy rapid draing being coated with that can allow, and reach the effect that paper surface is light face.
2. the manufacture method of the stone paper of recyclable recycling as claimed in claim 1, it is characterized in that, this calendering papermaking apparatus can include an automatic paper winder and a trimmer, the paper that the 6th step is completed utilizes automatic paper winder to be rolled into after paper roll shape, and recycling trimmer cuts into paper finished product on the plane paper of required size.
3. the manufacture method of the stone paper of recyclable recycling as claimed in claim 1, is characterized in that, the characteristic according to the composite formula of paper in the 5th step is adjusted temperature, makes composition material hot melt, mixing, the two-way extension of paper.
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| CN201010276851.0A CN102154949B (en) | 2010-09-09 | 2010-09-09 | Method for manufacturing recyclable and reusable stone paper |
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| CN201010276851.0A CN102154949B (en) | 2010-09-09 | 2010-09-09 | Method for manufacturing recyclable and reusable stone paper |
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| CN201310307711.9A Division CN103483681A (en) | 2010-09-09 | 2010-09-09 | Preparation method of recyclable and reusable stone paper |
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| CN102154949A (en) | 2011-08-17 |
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