CN102154827A - Silk broadcloth grafted cation process - Google Patents
Silk broadcloth grafted cation process Download PDFInfo
- Publication number
- CN102154827A CN102154827A CN 201010586218 CN201010586218A CN102154827A CN 102154827 A CN102154827 A CN 102154827A CN 201010586218 CN201010586218 CN 201010586218 CN 201010586218 A CN201010586218 A CN 201010586218A CN 102154827 A CN102154827 A CN 102154827A
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- Prior art keywords
- silk
- grafting agent
- grafting
- grafted
- silk broadcloth
- Prior art date
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- 150000001768 cations Chemical class 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000004744 fabric Substances 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 4
- 239000012467 final product Substances 0.000 claims description 3
- 230000001153 anti-wrinkle Effects 0.000 claims 2
- 239000000985 reactive dye Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000006011 modification reaction Methods 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 abstract 1
- 210000003491 Skin Anatomy 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 230000036740 Metabolism Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 230000035786 metabolism Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- 206010011985 Decubitus ulcer Diseases 0.000 description 1
- 108010022355 Fibroins Proteins 0.000 description 1
- 206010022114 Injury Diseases 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 208000004210 Pressure Ulcer Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 235000003846 Ricinus Nutrition 0.000 description 1
- 241000322381 Ricinus <louse> Species 0.000 description 1
- 208000006641 Skin Disease Diseases 0.000 description 1
- 210000004927 Skin cells Anatomy 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 210000004027 cells Anatomy 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000983 mordant dye Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000505 pernicious Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
Abstract
The invention discloses a silk broadcloth grafted cation process. The method comprises the following steps of: performing grafting reaction on the preprocessed silk broadcloth fabric and a grafting agent at the temperature of 120 DEG C for 30 minutes, wherein the concentration of the grafting agent is 160 percent owf, and the pH value of the grafting agent is 9; and rolling and drying the grafted silk broadcloth fabric, curing at the temperature of between 60 and 70 DEG C for one hour, taking out, washing and drying. The bath ratio of the silk broadcloth fabric to the grafting agent is 1 to 40. The grafting agent is 1,2,3 glycidyl trimethyl ammonium chloride. In the process, the silk is grafted and is subjected to cationic modification, so that the silk dye-uptake and fixation rate of reactive dye can be improved; and the method has the advantages of saving energy, and contributing to clean production and environmental protection, along with simplicity and high efficiency and has wide application prospect.
Description
Technical field
The present invention relates to a kind of silk broadcloth grafting CATION technology, belong to textile technology field.
Technical background
Real silk refers generally to silk, comprises mulberry silk, tussah silk, ricinus silk, cassava silkwormsilk etc.Real silk is called as " fiber queen ", is subjected to people's through the ages favor with its unique glamour.Real silk belongs to protein fibre, contains 18 kinds of amino acid to the human body beneficial in the fibroin, can help skin to keep the metabolism of surperficial adipose membrane, so can make skin keep moist, smooth.Wear the real silk clothes, can prevent that not only ultraviolet radiation, defence pernicious gas from invading, the opposing harmful bacteria, and can also strengthen the vigor of skin surface cell, promote the metabolism of Skin Cell, simultaneously some skin disease is had good auxiliary curing effect.In addition, because special hygroscopicity and gas permeability also has the effect of regulate body temperature, adjusting moisture content.The medical worker makes various fabric according to the needs of partes corporis humani position with real silk, has selected 30 skin itching patients to treat, and the result shows, uses real silk fabric can receive curative effect preferably merely, need not to be used external used medicine.The patient that long-term bed does not rise has given birth to after the bedsore, if adopt real silk pad list and pure silk underwear, wraps up affected part with real silk again, just can play the effect that absorbs moisture and promote its evaporation, can keep the affected part plot, accelerates wound healing.Silk broadcloth can also protect people's skin to avoid the injury of solar ultraviolet.The snow-white silk that silkworm spues, meeting flavescence gradually under ultraviolet irradiation, reason is exactly that silk has absorbed the ultraviolet ray in the sunlight.Medical science general knowledge is told people, and too much ultraviolet irradiation is very harmful to human skin, therefore utilizes cocoon fiber can reach the ultraviolet purpose of defence to ultraviolet absorbent properties.
Silk is traditional high-grade fabric, fade easily with traditional ACID DYES, direct dyes, silk that mordant dye dyed, and dye silk with REACTIVE DYES, the silk COLOR FASTNESS that dyes is very high, along with science and technology development, it is found that the existing silk broadcloth printing and dyeing processing technology part that comes with some shortcomings.Need use a large amount of salt to urge to dye because REACTIVE DYES is dyed silk, and dye-uptake and degree of fixation are still lower, also produce a large amount of dyeing waste waters, shine the waste into resource, and are unfavorable for the protection of environment.
Summary of the invention
The object of the invention provides a kind of silk broadcloth grafting CATION technology, and this method can improve dye-uptake, the degree of fixation of REACTIVE DYES to silk effectively.
In order to achieve the above object, the present invention adopts technical scheme to be: a kind of silk broadcloth grafting CATION technology, this method step is as follows: at first will carry out graft reaction through pretreated silk fabrics and grafting agent, reaction condition: 120 ℃ of temperature, times 30 min, grafting agent concentration is 16%owf, pH=9; Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.
The bath raio of described silk fabrics and grafting agent is 1:40.
Described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.
Technology of the present invention is cation-modified by silk is carried out grafting, can improve dye-uptake, the degree of fixation of REACTIVE DYES to silk; And this kind method has, and technology is simple, efficient energy-saving, help the advantage of cleaner production and environmental protection, has a extensive future.
The specific embodiment
Example of the present invention is can not limit the present invention to explanation of the present invention, in implication suitable with the present invention and any change and the adjustment in the scope, all should think within the scope of the invention.
Embodiment 1
A kind of silk broadcloth grafting CATION technology, this method step is as follows: at first will carry out graft reaction, reaction condition through pretreated silk fabrics and grafting agent: 120 ℃ of temperature, times 30 min, grafting agent concentration is 16%owf, pH=9; The bath raio of described silk fabrics and grafting agent is 1:40.Described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.
Claims (3)
1. silk broadcloth grafting CATION technology is characterized in that this method step is as follows: at first will carry out graft reaction, reaction condition through pretreated silk fabrics and grafting agent: 120 ℃ of temperature, and times 30 min, grafting agent concentration is 16%owf, pH=9; Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.
2. a kind of environment-friendly type silk fabric anti-wrinkle method according to claim 1, the bath raio that it is characterized in that described silk fabrics and grafting agent is 1:40.
3. a kind of environment-friendly type silk fabric anti-wrinkle method according to claim 1 is characterized in that described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010586218 CN102154827A (en) | 2010-12-14 | 2010-12-14 | Silk broadcloth grafted cation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010586218 CN102154827A (en) | 2010-12-14 | 2010-12-14 | Silk broadcloth grafted cation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102154827A true CN102154827A (en) | 2011-08-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010586218 Pending CN102154827A (en) | 2010-12-14 | 2010-12-14 | Silk broadcloth grafted cation process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102154827A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965927A (en) * | 2012-12-07 | 2013-03-13 | 辽东学院 | Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof |
| CN103031717A (en) * | 2013-01-05 | 2013-04-10 | 席敏皓 | Surface treatment technology for silk fiber |
| CN104727135A (en) * | 2015-03-04 | 2015-06-24 | 哈尔滨工业大学 | Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles |
| CN104831533A (en) * | 2015-05-20 | 2015-08-12 | 东华大学 | Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance |
| CN111411518A (en) * | 2020-03-27 | 2020-07-14 | 席敏皓 | Antibacterial and anti-virus silk fiber filtering base cloth and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1734009A (en) * | 2004-12-17 | 2006-02-15 | 中国科学院上海应用物理研究所 | The colouring method of silk broadcloth |
| CN101096823A (en) * | 2007-07-03 | 2008-01-02 | 浙江理工大学 | Real silk fabric coloring agent printing decoration light water developing and printing flowers method |
-
2010
- 2010-12-14 CN CN 201010586218 patent/CN102154827A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1734009A (en) * | 2004-12-17 | 2006-02-15 | 中国科学院上海应用物理研究所 | The colouring method of silk broadcloth |
| CN101096823A (en) * | 2007-07-03 | 2008-01-02 | 浙江理工大学 | Real silk fabric coloring agent printing decoration light water developing and printing flowers method |
Non-Patent Citations (1)
| Title |
|---|
| 《纺织科技进展》 20091231 朱清等 真丝绸接枝阳离子工艺条件探讨 , 第05期 2 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102965927A (en) * | 2012-12-07 | 2013-03-13 | 辽东学院 | Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof |
| CN103031717A (en) * | 2013-01-05 | 2013-04-10 | 席敏皓 | Surface treatment technology for silk fiber |
| CN103031717B (en) * | 2013-01-05 | 2014-10-29 | 席敏皓 | Surface treatment technology for silk fiber |
| CN104727135A (en) * | 2015-03-04 | 2015-06-24 | 哈尔滨工业大学 | Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles |
| CN104727135B (en) * | 2015-03-04 | 2017-04-12 | 哈尔滨工业大学 | Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles |
| CN104831533A (en) * | 2015-05-20 | 2015-08-12 | 东华大学 | Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance |
| CN104831533B (en) * | 2015-05-20 | 2017-05-03 | 东华大学 | Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance |
| CN111411518A (en) * | 2020-03-27 | 2020-07-14 | 席敏皓 | Antibacterial and anti-virus silk fiber filtering base cloth and application thereof |
| CN111411518B (en) * | 2020-03-27 | 2022-09-09 | 席敏皓 | Antibacterial and anti-virus silk fiber filtering base cloth and application thereof |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20110817 |