CN102154827A - Silk broadcloth grafted cation process - Google Patents

Silk broadcloth grafted cation process Download PDF

Info

Publication number
CN102154827A
CN102154827A CN 201010586218 CN201010586218A CN102154827A CN 102154827 A CN102154827 A CN 102154827A CN 201010586218 CN201010586218 CN 201010586218 CN 201010586218 A CN201010586218 A CN 201010586218A CN 102154827 A CN102154827 A CN 102154827A
Authority
CN
China
Prior art keywords
silk
grafting agent
grafting
grafted
silk broadcloth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 201010586218
Other languages
Chinese (zh)
Inventor
徐海祥
陈东良
邵敏
俞金键
王春花
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUAJIA SILK CO Ltd JAINGSU
Original Assignee
HUAJIA SILK CO Ltd JAINGSU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUAJIA SILK CO Ltd JAINGSU filed Critical HUAJIA SILK CO Ltd JAINGSU
Priority to CN 201010586218 priority Critical patent/CN102154827A/en
Publication of CN102154827A publication Critical patent/CN102154827A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses a silk broadcloth grafted cation process. The method comprises the following steps of: performing grafting reaction on the preprocessed silk broadcloth fabric and a grafting agent at the temperature of 120 DEG C for 30 minutes, wherein the concentration of the grafting agent is 160 percent owf, and the pH value of the grafting agent is 9; and rolling and drying the grafted silk broadcloth fabric, curing at the temperature of between 60 and 70 DEG C for one hour, taking out, washing and drying. The bath ratio of the silk broadcloth fabric to the grafting agent is 1 to 40. The grafting agent is 1,2,3 glycidyl trimethyl ammonium chloride. In the process, the silk is grafted and is subjected to cationic modification, so that the silk dye-uptake and fixation rate of reactive dye can be improved; and the method has the advantages of saving energy, and contributing to clean production and environmental protection, along with simplicity and high efficiency and has wide application prospect.

Description

A kind of silk broadcloth grafting CATION technology
Technical field
The present invention relates to a kind of silk broadcloth grafting CATION technology, belong to textile technology field.
Technical background
Real silk refers generally to silk, comprises mulberry silk, tussah silk, ricinus silk, cassava silkwormsilk etc.Real silk is called as " fiber queen ", is subjected to people's through the ages favor with its unique glamour.Real silk belongs to protein fibre, contains 18 kinds of amino acid to the human body beneficial in the fibroin, can help skin to keep the metabolism of surperficial adipose membrane, so can make skin keep moist, smooth.Wear the real silk clothes, can prevent that not only ultraviolet radiation, defence pernicious gas from invading, the opposing harmful bacteria, and can also strengthen the vigor of skin surface cell, promote the metabolism of Skin Cell, simultaneously some skin disease is had good auxiliary curing effect.In addition, because special hygroscopicity and gas permeability also has the effect of regulate body temperature, adjusting moisture content.The medical worker makes various fabric according to the needs of partes corporis humani position with real silk, has selected 30 skin itching patients to treat, and the result shows, uses real silk fabric can receive curative effect preferably merely, need not to be used external used medicine.The patient that long-term bed does not rise has given birth to after the bedsore, if adopt real silk pad list and pure silk underwear, wraps up affected part with real silk again, just can play the effect that absorbs moisture and promote its evaporation, can keep the affected part plot, accelerates wound healing.Silk broadcloth can also protect people's skin to avoid the injury of solar ultraviolet.The snow-white silk that silkworm spues, meeting flavescence gradually under ultraviolet irradiation, reason is exactly that silk has absorbed the ultraviolet ray in the sunlight.Medical science general knowledge is told people, and too much ultraviolet irradiation is very harmful to human skin, therefore utilizes cocoon fiber can reach the ultraviolet purpose of defence to ultraviolet absorbent properties.
Silk is traditional high-grade fabric, fade easily with traditional ACID DYES, direct dyes, silk that mordant dye dyed, and dye silk with REACTIVE DYES, the silk COLOR FASTNESS that dyes is very high, along with science and technology development, it is found that the existing silk broadcloth printing and dyeing processing technology part that comes with some shortcomings.Need use a large amount of salt to urge to dye because REACTIVE DYES is dyed silk, and dye-uptake and degree of fixation are still lower, also produce a large amount of dyeing waste waters, shine the waste into resource, and are unfavorable for the protection of environment.
Summary of the invention
The object of the invention provides a kind of silk broadcloth grafting CATION technology, and this method can improve dye-uptake, the degree of fixation of REACTIVE DYES to silk effectively.
In order to achieve the above object, the present invention adopts technical scheme to be: a kind of silk broadcloth grafting CATION technology, this method step is as follows: at first will carry out graft reaction through pretreated silk fabrics and grafting agent, reaction condition: 120 ℃ of temperature, times 30 min, grafting agent concentration is 16%owf, pH=9; Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.
The bath raio of described silk fabrics and grafting agent is 1:40.
Described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.
Technology of the present invention is cation-modified by silk is carried out grafting, can improve dye-uptake, the degree of fixation of REACTIVE DYES to silk; And this kind method has, and technology is simple, efficient energy-saving, help the advantage of cleaner production and environmental protection, has a extensive future.
The specific embodiment
Example of the present invention is can not limit the present invention to explanation of the present invention, in implication suitable with the present invention and any change and the adjustment in the scope, all should think within the scope of the invention.
Embodiment 1
A kind of silk broadcloth grafting CATION technology, this method step is as follows: at first will carry out graft reaction, reaction condition through pretreated silk fabrics and grafting agent: 120 ℃ of temperature, times 30 min, grafting agent concentration is 16%owf, pH=9; The bath raio of described silk fabrics and grafting agent is 1:40.Described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.

Claims (3)

1. silk broadcloth grafting CATION technology is characterized in that this method step is as follows: at first will carry out graft reaction, reaction condition through pretreated silk fabrics and grafting agent: 120 ℃ of temperature, and times 30 min, grafting agent concentration is 16%owf, pH=9; Then the silk fabrics after the grafting is rolled driedly, then under 60-70 ℃ temperature, baked 1 hour, take out at last through washing, oven dry and get final product.
2. a kind of environment-friendly type silk fabric anti-wrinkle method according to claim 1, the bath raio that it is characterized in that described silk fabrics and grafting agent is 1:40.
3. a kind of environment-friendly type silk fabric anti-wrinkle method according to claim 1 is characterized in that described grafting agent is 1,2,3 epoxypropyl trimethylammonium chloride ammoniums.
CN 201010586218 2010-12-14 2010-12-14 Silk broadcloth grafted cation process Pending CN102154827A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201010586218 CN102154827A (en) 2010-12-14 2010-12-14 Silk broadcloth grafted cation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201010586218 CN102154827A (en) 2010-12-14 2010-12-14 Silk broadcloth grafted cation process

Publications (1)

Publication Number Publication Date
CN102154827A true CN102154827A (en) 2011-08-17

Family

ID=44436486

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 201010586218 Pending CN102154827A (en) 2010-12-14 2010-12-14 Silk broadcloth grafted cation process

Country Status (1)

Country Link
CN (1) CN102154827A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965927A (en) * 2012-12-07 2013-03-13 辽东学院 Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof
CN103031717A (en) * 2013-01-05 2013-04-10 席敏皓 Surface treatment technology for silk fiber
CN104727135A (en) * 2015-03-04 2015-06-24 哈尔滨工业大学 Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles
CN104831533A (en) * 2015-05-20 2015-08-12 东华大学 Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance
CN111411518A (en) * 2020-03-27 2020-07-14 席敏皓 Antibacterial and anti-virus silk fiber filtering base cloth and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1734009A (en) * 2004-12-17 2006-02-15 中国科学院上海应用物理研究所 The colouring method of silk broadcloth
CN101096823A (en) * 2007-07-03 2008-01-02 浙江理工大学 Real silk fabric coloring agent printing decoration light water developing and printing flowers method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1734009A (en) * 2004-12-17 2006-02-15 中国科学院上海应用物理研究所 The colouring method of silk broadcloth
CN101096823A (en) * 2007-07-03 2008-01-02 浙江理工大学 Real silk fabric coloring agent printing decoration light water developing and printing flowers method

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《纺织科技进展》 20091231 朱清等 真丝绸接枝阳离子工艺条件探讨 , 第05期 2 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102965927A (en) * 2012-12-07 2013-03-13 辽东学院 Tussah silk fiber or fabric cation modified finishing agent thereof and modified technique thereof
CN103031717A (en) * 2013-01-05 2013-04-10 席敏皓 Surface treatment technology for silk fiber
CN103031717B (en) * 2013-01-05 2014-10-29 席敏皓 Surface treatment technology for silk fiber
CN104727135A (en) * 2015-03-04 2015-06-24 哈尔滨工业大学 Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles
CN104727135B (en) * 2015-03-04 2017-04-12 哈尔滨工业大学 Surface copper ion grafting method for improving mildew resistance and mechanical properties of flax fiber bundles
CN104831533A (en) * 2015-05-20 2015-08-12 东华大学 Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance
CN104831533B (en) * 2015-05-20 2017-05-03 东华大学 Processing method for endowing surface of protein fabric with anti-microbial and anti-static performance
CN111411518A (en) * 2020-03-27 2020-07-14 席敏皓 Antibacterial and anti-virus silk fiber filtering base cloth and application thereof
CN111411518B (en) * 2020-03-27 2022-09-09 席敏皓 Antibacterial and anti-virus silk fiber filtering base cloth and application thereof

Similar Documents

Publication Publication Date Title
CN102127871B (en) Dyeing technique of true silk-tencel/cotton interwoven cloth
CN102154827A (en) Silk broadcloth grafted cation process
CN102061619B (en) Process for dyeing and finishing by using bamboo vinegar
CN103255538A (en) Ultraviolet-preventing antibacterial fabric and preparation technology thereof
CN106245315A (en) The production method of antibiotic property quick-drying shell fabric
CN102154830B (en) Method for dyeing wool fabric at low temperature
CN101871168B (en) Collagen functional finish process for textile fabric containing natural color cotton
CN109930392B (en) Preparation method of washable long-acting cool cotton-containing knitted fabric
CN104878516B (en) A kind of knitting fabric and preparation method
CN101974850A (en) Preparation method of ecological non-ironing silk fabric
CN103174000A (en) Bio-enzyme felt proofing technology of knitted woolen sweater
CN100487189C (en) Finishing method high-hygroscopic and perspire fibre with cotton-dispersion
CN106436329A (en) Skin-care permanently-antibacterial DP finishing liquid for shirts and finishing method
CN105862387A (en) Dyeing and finishing method of anti-microbial and anti-wrinkling lyocell-cotton blended fabric
CN102733204A (en) Dyeing process of spun silk cotton underwear
CN101285267B (en) Anti-stain finishing method for natural colored cotton knit goods
CN108342786B (en) Acrylic fiber with magnet physiotherapy health-care function and preparation method thereof
CN102154821A (en) Crease resistant method for environment-friendly silk fabric
CN103614925A (en) Healthy and environmental protection fabrics treating method
CN101781849B (en) Method for curing chitosan on fabrics
CN112553757A (en) Antibacterial health-care interlayer knitted fabric and production process thereof
JP6196654B2 (en) Manufacturing method and production line of environmentally friendly denim fabric
CN102154853A (en) Cold pad batch dyeing process for silk broadcloth
CN108894034A (en) A kind of wool fabric method of modifying
CN102409544A (en) Collagen functional finishing process of woven fabric containing natural colored cotton

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20110817