CN102093773A - Varied discoloration material - Google Patents

Varied discoloration material Download PDF

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CN102093773A
CN102093773A CN 201010604093 CN201010604093A CN102093773A CN 102093773 A CN102093773 A CN 102093773A CN 201010604093 CN201010604093 CN 201010604093 CN 201010604093 A CN201010604093 A CN 201010604093A CN 102093773 A CN102093773 A CN 102093773A
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color
temperature
powder
discoloration
variety
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CN 201010604093
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丘兵
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广州市昌成陶瓷有限公司
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Abstract

The invention discloses a varied discoloration material. The critical temperature of the discoloration of the varied discoloration material is plus and minus 4 DEG C. The varied discoloration material mainly comprises the following components: a mixture of more than two colors of discoloration powder with same-layer temperature, and a transparent coating or silk screen transparent oil, wherein the same-layer temperature refers to the phenomenon that the discoloration temperature difference of the discoloration powder is plus and minus 4 DEG C. The color of the varied discoloration material is uniform harmonized deep color in a cold state at a temperature lower than the preset lowest temperature, and is uniform light color in a hot state. Particularly, during the return from coldness to normal temperature, or during the return from hotness to normal temperature, in a critical state when the color is regressed to deep color, because more than two hues are affected by temperature, water level, thickness, even body temperature, difference pressures are borne by discoloration positions, the regression of various colors has different scales, different sequences, is in a random state, and can present different changes every time, so that the color is changing harmonized color and rich colors are presented.

Description

百变变色材料 Variety color material

技术领域 FIELD

[0001] 本发明属于化工材料领域,具体是涉及一种百变变色材料。 [0001] The present invention belongs to the field of chemical materials, particularly, to a color changeable material. 背景技术 Background technique

[0002] 变色涂料之所以变色,是因为变色涂料里面的一种材料——变色微胶囊。 [0002] The reason why the discoloration of coating color, because the color of the inside coating of a material - discoloration microcapsule. 变色微胶囊会根据温度变化产生颜色变化,这种变色微胶囊的变色材料一般称为变色粉,它由隐色色剂、显色剂和增感剂(减敏剂)组成;当温度变化时,显色剂释放质子,隐色色剂吸收电子后就会变色,整个变色体系在一种特殊溶剂环境中才能变色,这些变色颜料经过包裹技术处理后,形成变色微胶囊即变色粉,才能投入正常使用。 Discoloration microcapsule according to a temperature change will produce a color change, this discoloration microcapsule electrochromic material is generally referred to as color powder, which consists of a leuco toner, developer and sensitizers (desensitizer) composition; when the temperature changes, chromogenic agent releases a proton, the electron leuco absorbent will change color toner, the entire system can color a particular color in a solvent environment, these color pigment after treatment technology packages, i.e. formed discoloration discoloration microcapsule powder, can be put into normal use .

[0003] 现有的变色分为冷变色和热变色,但都是分段变色,或者是混合分段变色,既加热水变色和冷水变色,在一定温度下单一的变色,其实也就是在冷的状态下是深色,在热状态下是浅色(或近似透明)。 [0003] The conventional color divided into cold and hot discoloration discoloration, but all discoloration segment, or a color mixing section, both heat and cold water discoloration color, single color at a certain temperature, in fact, is in the cold in the dark state, a light (or nearly transparent) in the hot state.

发明内容 SUMMARY

[0004] 本发明的目的在于提供一种可实现冷变,热变,临界温变的百变变色材料。 [0004] The object of the present invention to provide an electrochromic material Variety variable for cold and hot deformation conditions, the temperature becomes critical.

[0005] 实现上述目的的技术方案如下: [0005] The technical solution to achieve the above object are as follows:

[0006] 一种百变变色材料,其变色的临界温度为正负4摄氏度,其主要由以下成份组成: [0006] A Variety electrochromic material, discoloration critical temperature of plus or minus four degrees Celsius, which is mainly composed of the following ingredients:

[0007] (A)同层温度的两种以上颜色的变色粉的混合物,所述同层温度是指变色粉的变色温度差为正负4摄氏度; Mixture (A) of two or more colors of color powder with a surface temperature [0007] The color temperature is the same layer as the color temperature difference of plus or minus 4 degrees Celsius powder;

[0008] (B)透明涂料或丝印透明油。 [0008] (B) a clear coating, or screen printing a clear oil.

[0009] 本发明所述两种以上颜色的变色粉,优选为两种或三种颜色的变色粉。 [0009] The color of the powder of the present invention two or more colors, preferably two or three color powder colors. 变色粉的变色温度可以从5°C -90°C,本发明最优选为常温变色的变色粉,即其变色温度为180C -35"C。 The color temperature of the color powder from 5 ° C -90 ° C, and most preferably present invention discoloration color powder at room temperature, i.e., discoloration temperature of 180C -35 "C.

[0010] 所述变色粉的混合物与透明涂料或丝印透明油的用量比例优选为1 : 1-3。 [0010] The proportion of the amount of color powder coating or screen printing a mixture of a transparent clear oil is preferably 1: 1-3. 最优选为1 : 2。 And most preferably 1: 2. 如果希望透明度高些,可以增加透明涂料或丝印透明油,如1 : 3,以减少残余色;如果希望覆盖性好些,可采用1 : 1,或者增加印刷次数来达到。 If you want more transparent, clear coating, or screen printing can be increased as a clear oil, such as 1: 3, to reduce residual color; better coverage if desired, can be 1: 1, or to increase the number of printing is achieved.

[0011] 本发明所述百变变色材料有三种特性:冷变,热变,临界温变。 The electrochromic material Variety invention [0011] This has three characteristics: cold to hot deformation, the critical temperature change.

[0012] 本发明所述的百变变色材料,是一种新的变色配方,将变色粉(台湾、日本均可), 取同一层温度两种以上颜色以上的变色粉混合,再和透明涂料或者其它丝印透明油(如日本田中)混合搅拌,,再用球磨机或者其它搅拌机,使这些材料搅拌均勻(必要时可用纱布过滤)调成油墨、涂料或者其它。 [0012] Variety electrochromic material according to the present invention, a new recipe color, the color powder (Taiwan, Japan may be), taking color powder mixed with one or more of the temperature of two or more colors, and then clear paint screen printing or other clear oil (Japanese Tanaka) ,, mixed and stirred with a ball mill or other mixer, stir these materials (gauze filter, if necessary) into a printing ink, coating or other.

[0013] 所述的百变变色材料的颜色在冷的状态下低于最低所设定的温度是统一的调和深色(比例不同,颜色不同),在热的状态下是统一的浅色(或近似透明)——该特性与现有技术中的变色材料是相同的;特殊的在于:由冷回常温的过程中,或者由热回常温的过程中,由于两种以上色相在临界状态下,颜色回归深色的过程中,受温度,水位,厚薄,甚至于体温,变色部位所受的压力不同,各颜色回归的比例不同,先后不同,处于随机状态,每一次都会呈现不同变化,而让颜色处于变化的调和颜色,呈现出丰富多彩的颜色。 [0013] Color Variety electrochromic material is below the minimum temperature of the set is in the cold state harmonic uniform dark (in different proportions, different colors), in the hot state is uniform light ( or nearly transparent) - this property is the same as the prior art electrochromic material; special in that: the process back to the ordinary temperature by a cold, or room temperature by the heat recovery process, since two or more hues in a critical state , the process of return of color in the dark, by temperature, water level, thickness, and even body temperature, the pressure on different parts of color, different proportions of each color return, has different, in a random state, each will show different variations, and let the color change color in harmony, showing a variety of colors. 具体实施方式 Detailed ways

[0014] 发明所述的变色的临界温度约为正负4°C。 [0014] The discoloration of the invention, the critical temperature is about plus or minus 4 ° C. 同层温度:比如21°C,正负4°C, 17-25°C为同层温度。 Temperature same layer: for example, 21 ° C, plus or minus 4 ° C, 17-25 ° C temperature for the same layer.

[0015] 实施例1 [0015] Example 1

[0016] (1)本实施所述的百变变色材料,其组成如下: [0016] (1) of the present embodiment Variety electrochromic material, which is composed as follows:

[0017] 的红色变色粉、28°C的蓝色变色粉、光油(日本田中丝印透明油)按3 :1:8 的比例(质量比)。 [0017] The red color powder, blue color powder 28 ° C, the coatings (Japanese Tanaka screen clear oil) of 3: 1: 8 ratio (mass ratio).

[0018] (2)其制备方法为: [0018] (2) Method of preparation:

[0019] 将上述材料按比例称取相应重量,混合搅拌,用研磨机充分研磨,为调和粘稠度, 必要时可以加入适量ASTRO油墨稀释剂(田中),研磨完毕,用200目的网纱过滤,调成百变变色油墨。 [0019] The above materials were weighed in proportion to the respective weight, mixing, fully ground with a grinder, to reconcile the viscosity, if necessary, adding an appropriate amount ASTRO ink thinner (Tanaka), the grinding is completed, the filter mesh 200 mesh , into a color changeable ink.

[0020] (3)应用:将所得的百变变色材料丝印在水转印纸上,印成樱桃水果水转印花纸, 再将花纸贴在陶瓷杯等工件上,并在外表喷上涂料,烧烤成成品,做成一个带有樱桃图案的变色杯。 [0020] (3) Application: The resulting electrochromic material Variety on a water screen printing transfer paper, printed cherry fruit water transfer printing paper, colored paper and then affixed to the ceramic cup and other parts, and spray coating on the outer , barbecue into finished products, made of a cup with a cherry color pattern.

[0021] 由冷转热的过程:当加入温度低于的水时,樱桃呈现的是成熟的紫红颜色; 当加入温度达30°C的水时,是粉蓝色;当加入温度是32°C的水时,樱桃呈现是浅蓝偏白。 [0021] from the cold heat transfer process: when the temperature is below water was added, mature cherries are presented purple color; when the temperature reached 30 ° C was added water, was powder blue; added when the temperature is 32 ° C water, the whitish light blue cherries are presented. 而颜色的之间转变,在温度变化之间,可以明显看到蓝红之间调和色的渐变,看到樱桃成熟的各种状态。 And the transition between colors, between the temperature change, can clearly see harmonic color gradient between the blue and red, ripe cherries seen various states.

[0022] 由热转冷的过程:当加入温度是32°C的水时,樱桃呈现是浅蓝偏白。 [0022] The cold heat transfer process: when the temperature of water was added to 32 ° C, the cherry is rendered whitish light blue. 当加入温度达30°C的水时,是,红色;当加入温度低于的水时,樱桃呈现的是成热的紫红颜色;而颜色的之间转变,在温度变化之间,可以明显看到蓝红之间调和色的渐变。 When the temperature of the water was added to 30 ° C, is red; temperature is lower than when the added water, cherries is presented to heat purple color; the transition between colors, between the temperature change, can be clearly seen between the blue and red harmonic color gradient. 看到樱桃成熟的各种状态。 See cherry ripe various states. 当用手触摸或摩擦时,樱桃的颜色受压和温度变化也呈现不同的颜色渐变变化。 When a touch or friction, cherry color pressure and temperature variations are also rendered different color gradation change.

[0023] 实施例2 : [0023] Example 2:

[0024] (1)本实施所述的百变变色材料,其组成如下: [0024] (1) of the present embodiment Variety electrochromic material, which is composed as follows:

[0025] 250C的绿色变色粉、25°C的红色变色粉、25°C的蓝色变色粉、25°C的黄色变色粉和透明涂料(普乐化工)按4 :1:1::6: M混合(质量比)。 Blue color powder green color powder [0025] 250C, the red color powder of 25 ° C, of ​​25 ° C, 25 ° C and the yellow color powder and clear paint (Bullock Chemical) by 4: 1: 1 :: 6 : M mixture (mass ratio).

[0026] (2)其制备方法为: [0026] (2) Method of preparation:

[0027] 将上述材料按比例称取相应重量,混合搅拌,用研磨机充分研磨,必要时可以加入适量ASTRO油墨稀释剂(田中),研磨完毕,用200目的网纱过滤,调成百变变色油墨。 [0027] The above materials were weighed in proportion to the respective weight, mixed and stirred sufficiently with a grinding mill, if necessary, adding an appropriate amount ASTRO ink thinner (Tanaka), the grinding is completed, filtered through a 200-mesh yarn, into a color Variety ink.

[0028] (3)应用: [0028] (3) Application:

[0029] 将所得的百变变色材料,直接喷涂在玻璃板上成树叶形状,烤制200°C成树叶的玻璃板块成品。 [0029] The resulting Variety electrochromic material, applied directly on a glass plate into the shape of leaves, baked to 200 ° C leaves the finished glass plate. 树叶在21°C以下,是灰青色;在以上是嫩黄色,在2H9°C间是灰青、绛红、浅红、青色、嫩黄的临界变色状态。 It leaves at 21 ° C or less, blue gray; above is bright yellow, 2H9 ° C between gray cyan, magenta, light red, cyan, yellow discoloration of the critical state.

[0030] 实施例3 : [0030] Example 3:

[0031] (1)本实施所述的百变变色材料,其组成如下: [0031] (1) of the present embodiment Variety electrochromic material, which is composed as follows:

[0032] 280C的红色变色粉、蓝色变色粉)和31°C的绿色变色粉与光油(日本田中丝印透明油)按3 :1:1: 10的比例(质量比)。 Varnish red and green color powder color powder [0032] 280C, and blue color powder) and 31 ° C (Japanese Tanaka screen clear oil) of 3: 1: 1: 10 ratio (mass ratio). [0033] (2)其制备方法为: [0033] (2) Method of preparation:

[0034] 将上述材料按比例称取相应重量,混合搅拌,用研磨机充分研磨,必要时可以加入适量ASTRO油墨稀释剂(田中),研磨完毕,用200目的网纱过滤,调成百变变色油墨。 [0034] The above materials were weighed in proportion to the respective weight, mixed and stirred sufficiently with a grinding mill, if necessary, adding an appropriate amount ASTRO ink thinner (Tanaka), the grinding is completed, filtered through a 200-mesh yarn, into a color Variety ink.

[0035] (3)应用:将所得的百变变色材料丝印在水转印纸上,印成衣服水转印花纸,再将花纸贴在瓷砖等工件上,并在外表喷上涂料,烧烤成成品,做成一个带有衣服图案的瓷板画。 [0035] (3) Application: The resulting electrochromic material Variety on a water screen printing transfer paper, clothes, water transfer printing paper printed, then the paper flowers and other parts attached to the tile, and spray coating on the outer grill into finished products, made of porcelain painting with a garment pattern.

[0036] 由冷转热的过程:开始衣服颜色是墨红色,当加入温度低于的水时,衣服呈现的是紫蓝颜色;当加入温度达31°C的水时,衣服是蓝红色;水温是32°C时,衣服是蓝色; 当加入温度是35°C的水时,云彩呈现是浅紫偏白。 [0036] The process of heat transfer from the cold: Start dress color is red ink, when the temperature is below water was added, the purplish blue clothes presentation; added when the temperature reached 31 ° C water, the blue dress is red; when the water temperature is 32 ° C, the clothes are blue; was added when the temperature of water 35 ° C, the cloud is rendered whitish purple. 而颜色的之间转变,在温度变化之间,可以明显看到紫色、蓝色之间调和色的渐变,看到衣服的各种颜色变化。 And the transition between colors, between the temperature change, can clearly see harmonic color between purple, blue gradient, see the color change of various clothes.

[0037] 由热转冷的过程:开始颜色是浅紫偏白,当加入温度是32°C的水时,衣服呈现是蓝色、红色。 [0037] The cold heat transfer process: Start whitish color is purple, was added when the water temperature is 32 ° C when the clothes presentation blue, red. 当加入温度达30°C的水时,衣服呈现是蓝紫色;当加入温度低于的水时, 衣服呈现的是黑红颜色;而颜色的之间转变,在温度变化之间,可以明显看到紫色、蓝色之间调和色的渐变。 When the temperature reached 30 ° C was added water, clothes presentation of the blue violet; when the temperature is lower than water added, black and red colors presented clothes; the transition between colors, between the temperature change, can be clearly seen to purple, harmonic color gradient between the blue. 看到衣服的各种颜色。 See the various colors of clothes. 当用手触摸或摩擦时,衣服的颜色受压和温度变化也呈现不同的颜色渐变变化。 When a touch or friction, clothing color temperature changes and pressure show different change of color gradient.

[0038] 以上仅为本发明的具体实施例,并不以此限定本发明的保护范围;在不违反本发明构思的基础上所作的任何替换与改进,均属本发明的保护范围。 [0038] The above are only specific embodiments of the present invention, not meant to limit the scope of the present invention; replace any basis without violating the spirit of the invention and improvement made, belong to the scope of the present invention.

Claims (7)

  1. 1. 一种百变变色材料,其特征是,其变色的临界温度为正负4°c,其主要由以下成份组成:(A)同层温度的两种以上颜色的变色粉的混合物,所述同层温度是指变色粉的变色温度差为正负4摄氏度;(B)透明涂料或丝印透明油。 A Variety electrochromic material, characterized in that the critical temperature of discoloration of plus or minus 4 ° c, which is composed mainly of the following components: a mixture of two or more colors in the color of the powder (A) with the surface temperature, the said color temperature is the same layer as the color temperature difference of powder plus or minus 4 degrees C; (B) a clear coating, or screen printing a clear oil.
  2. 2.根据权利要求1所述的百变变色材料,其特征是,所述变色粉的变色温度为180C -35"C。 2. Variety electrochromic material according to claim 1, wherein said color powder color temperature 180C -35 "C.
  3. 3.根据权利要求1所述的百变变色材料,其特征是,所述两种以上颜色的变色粉,为两种或三种颜色的变色粉。 3. Variety electrochromic material according to claim 1, characterized in that the two or more color powder colors, or three colors of two color powder.
  4. 4.根据权利要求1-3任一项所述的百变变色材料,其特征是,所述变色粉的混合物与透明涂料或丝印透明油的用量比例为1 : 1-3。 Variety electrochromic material according to claim any one of claims 1-3, characterized in that the ratio of the amount of the powder mixture and the color clear coating or screen printing a clear oil is 1: 1-3.
  5. 5.根据权利要求1所述的百变变色材料,其特征是,其组成为的红色变色粉:的蓝色变色粉:丝印透明油的质量比例为3 : 1 : 8的混合物。 5. Variety electrochromic material according to claim 1, characterized in that the composition of the powder as a red color: blue color powder: mass ratio of the screen 3 as a clear oil: a mixture of 8: 1.
  6. 6.根据权利要求1所述的百变变色材料,其特征在于,其组成为:25°C的绿色变色粉:25°C的红色变色粉:25°C的蓝色变色粉:25°C的黄色变色粉:透明涂料的质量比例为4 : 1 : 1 : 6 : M的混合物。 Variety of the electrochromic material according to claim 1, characterized in that it consists of: a green color powder of 25 ° C: red color powder of 25 ° C: Blue color powder of 25 ° C: 25 ° C yellow color powder: clear coating mass ratio of 4: 1: 1: 6: mixture M.
  7. 7.根据权利要求1所述的百变变色材料,其特征是,其组成为的红色变色粉、 蓝色变色粉、31°C的绿色变色粉与光油的质量比例为3 :1:1: 10的混合物。 7. Variety electrochromic material according to claim 1, characterized in that the composition of the powder as red color, blue color powder mass ratio, and the green color powder coatings of 31 ° C was 3: 1: 1 : 10 mixture.
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CN104194496A (en) * 2014-09-05 2014-12-10 句容市给力包装制品厂 Anti-counterfeiting ink and preparation method thereof

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