CN102020360A - Treatment method of rubber production wastewater - Google Patents

Treatment method of rubber production wastewater Download PDF

Info

Publication number
CN102020360A
CN102020360A CN2010105735379A CN201010573537A CN102020360A CN 102020360 A CN102020360 A CN 102020360A CN 2010105735379 A CN2010105735379 A CN 2010105735379A CN 201010573537 A CN201010573537 A CN 201010573537A CN 102020360 A CN102020360 A CN 102020360A
Authority
CN
China
Prior art keywords
industrial wastewater
rubber
fermentation
solid substances
wastewater
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2010105735379A
Other languages
Chinese (zh)
Other versions
CN102020360B (en
Inventor
林文权
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XISHUANGBANNA SHIFENG LV FERTILIZERS CO Ltd
Original Assignee
XISHUANGBANNA SHIFENG LV FERTILIZERS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XISHUANGBANNA SHIFENG LV FERTILIZERS CO Ltd filed Critical XISHUANGBANNA SHIFENG LV FERTILIZERS CO Ltd
Priority to CN2010105735379A priority Critical patent/CN102020360B/en
Publication of CN102020360A publication Critical patent/CN102020360A/en
Application granted granted Critical
Publication of CN102020360B publication Critical patent/CN102020360B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

Abstract

The invention discloses a treatment method of rubber production wastewater. The rubber wastewater is adsorbed by a solid material, wherein the solid material is a biological organic material which is a single raw material or mixed material of plant residues such as sawdust, chaff, straw, pericarp and pomace, leftovers in production of agricultural products and the like; the rubber wastewater is added into the solid material so that the total water content of the solid material is 60-70%; and the solid material is fermented at the temperature of 70-85 DEG C in the presence of fermentation microbe groups, wherein during the fermentation, the rubber wastewater can be injected into the solid material stack for multiple times, and the fermentation microbe groups are high-temperature fermentation microbe groups. In the method provided by the invention, the concentration and conversion of the rubber wastewater are performed at the same time, per ton of solid carrier can absorb 4-6 tons of wastewater to prepare more than 1 ton of organic fertilizer, the rubber wastewater is completely utilized without odor and pollution, and wastes are turned into valuable things; and compared with the prior art, the method provided by the invention has the advantages of environmental-friendly benefits, social benefits and relatively high economic benefits.

Description

A kind of rubber production wastewater treatment method
Affiliated technical field
The invention belongs to a kind of wastewater treatment method, specifically, relate to a kind of treatment process of rubber production utilization of wastewater resource.
Background technology
Rubber production waste water has acid, the characteristics such as solid contents is high, nitrogen content height that are, be acidity and be because used in the glue process due to the peptizer such as acetate or formic acid, sulfuric acid, the rubber production discharge of wastewater is corrupt and produce stench in the environment, has a strong impact on resident's life.In the prior art, mostly rubber mill is to adopt anaerobism and facultative lagoon system, oxidation pond system, Sludge System, bio-disc system, ground release etc. to the processing of rubber production waste water, it is perfect that these methods are all not enough, can not carry out recycling to the organism in the waste water, can not make waste water reach discharging standards; Another kind of treatment process is to utilize methanobacteria to make anaerobic waste water fermentation and generation biogas, and with the part of heat energy as dry rubber, but the waste liquid after the fermentation does not still reach discharging standards; Also having a kind of treatment process is directly by liquid state fermentation, Rubber Industrial Wastewater is made liquid fertile, and the liquid fertile concentration that this method makes is too low, transportation inconvenience in the sales process, transportation cost height.
Summary of the invention
In order to overcome above-mentioned deficiency of the prior art, the object of the present invention is to provide a kind of rubber production wastewater treatment method, to Rubber Industrial Wastewater utilize fully, odorless is pollution-free, turning waste into wealth forms useful raw materials into biological organic fertilizer.
Technical scheme of the present invention is: utilize solid substances absorption Rubber Industrial Wastewater, described solid substances is biological organic materials, this biology organic materials is a sawdust, husk, stalk, the pericarp pomace, the single raw material of plant residues such as processing of farm products tankage, it also can be above mixture, Rubber Industrial Wastewater is added in the solid substances, make the total water content of solid substances reach 65% ± 5, solid substances is under the effect of organism of fermentation flora, 70~85 ℃ of fermentations, can repeatedly inject Rubber Industrial Wastewater to the solids stockpile between this yeast phase, described organism of fermentation flora is the thermophilic fermentation microorganism species.
As preferred implementation of the present invention, during the fermentation, the 3rd~9 day of fermentation divided and added Rubber Industrial Wastewater again to the solids stockpile for several times, and each addition is solid substances 100~125% of the back weight ratio of giving money as a gift.
Beneficial effect: rich in proteins in the rubber production waste water, natural resin, carbohydrate, ash (mineral element), ammonia, acetic acid etc., this mixing element is to produce the high quality raw material of biological organic fertilizer, the present invention makes full use of this characteristic, concentrated and the conversion of waste water is carried out synchronously, solid-state carrier per ton can absorb 4-6 ton waste water, make the biological organic fertilizer more than 1 ton, be equivalent to waste water has been concentrated more than 10 times, and whole concentration process is not increase energy consumption, do not prolong under the condition in compost fermentation cycle and realize, Rubber Industrial Wastewater is utilized fully, odorless is pollution-free, reach the treatment of wastes with processes of wastes against one another, changing waste into valuable, compared with prior art, both had environmental benefit, social benefit has higher economic benefit again.
The present invention is described in further detail below in conjunction with specific embodiment:
Embodiment
Embodiment 1,
80 tons of pineapple peel, the pineapple core, the Herba Passiflorae Caeruleae skin, pomaces such as passionflower seed (about 15 tons of the material of giving money as a gift) and 20 tons of sawdusts (about 15 tons of the material of giving money as a gift), organism of fermentation flora nutrient chemical, mix and be solid substances, make stockpile, fermentation, turning when waiting to pile more than the temperature rise to 70 ℃, the heap temperature descends after the turning, when treating that the stockpile temperature rises to more than 70 ℃ once more, inject Rubber Industrial Wastewater to stockpile, the solid substances moisture content reaches 65% after injecting waste water, afterwards, injected Rubber Industrial Wastewater every 2 days, the injection rate of each Rubber Industrial Wastewater and the ratio of solid materials dry weight are 1: 1, and turning immediately enters secondary fermentation after the 4th water filling, at last, make 35 tons of biological organic fertilizer finished products.
Redundant moisture in the high-heat fermentation process evaporative removal Rubber Industrial Wastewater, simultaneously, make the solid substance in the Rubber Industrial Wastewater under the effect of organism of fermentation flora, change into the necessary soil ulmin of growing process, solid-state carrier per ton (butt) can absorb 4~5 tons of waste water, makes 1.05 tons of biological organic fertilizers.In the treating processes of rubber production waste water because the leavening temperature height, the entire operation process does not have foul smell to produce, the nitrogenous source that is rich in the Rubber Industrial Wastewater, the organic content that finally makes finished product is up to 60~62%, 6,000 ten thousand of number of viable/gram are to improving soil physical and chemical property, increasing plant biomass and have better effect.
Embodiment 2,
30 tons on husk, 10 tons of rubber oil cakes, 10 tons in sawdust and organism of fermentation flora nutrient chemical, mix and be solid substances, to transfer to for the moisture content of solid substances about 65% with Rubber Industrial Wastewater, make the stockpile of high 80cm, turning when waiting to pile more than the temperature rise to 70 ℃, the heap temperature descends after the turning, when treating that the stockpile temperature rises to more than 70 ℃ once more, inject Rubber Industrial Wastewater, make that moisture content reaches 70% in the solid substances to stockpile, afterwards, injected Rubber Industrial Wastewater every 2 days, the ratio of each Rubber Industrial Wastewater injection rate and solid materials dry weight is 1: 1.25, and turning immediately enters secondary fermentation after the 5th water filling, at last, make 51 tons of biological organic fertilizer finished products.Redundant moisture in the high-heat fermentation process evaporative removal Rubber Industrial Wastewater, simultaneously, make the solid substance in the Rubber Industrial Wastewater under the effect of organism of fermentation flora, change into the necessary soil ulmin of growing process, solid-state carrier per ton (butt) can absorb 5~6 tons of waste water, makes 1.05 tons of biological organic fertilizers.In the treating processes of rubber production waste water because the leavening temperature height, its deodorizing, sterilization effect are remarkable, the nitrogenous source that is rich in the Rubber Industrial Wastewater, the organic content that finally makes finished product be up to 65%, to improving soil physical and chemical property, increasing plant biomass and have better effect.

Claims (4)

1. rubber production wastewater treatment method, it is characterized in that: utilize solid substances absorption Rubber Industrial Wastewater, described solid substances is biological organic materials, this biology organic materials is a sawdust, husk, stalk, the pericarp pomace, the single raw material of plant residues such as processing of farm products tankage, it also can be above mixture, Rubber Industrial Wastewater is added in the solid substances, make the total water content of solid substances reach 65% ± 5, solid substances is under the effect of organism of fermentation flora, 70~85 ℃ of fermentations, can repeatedly inject Rubber Industrial Wastewater to the solids stockpile between this yeast phase, described organism of fermentation flora is the thermophilic fermentation microorganism species.
2. treatment process according to claim 1 is characterized in that: during the fermentation, the 3rd~9 day of fermentation divided for several times to the solids stockpile Rubber Industrial Wastewater of reinjecting, and each addition is solid substances 100~125% of the back weight ratio of giving money as a gift.
3. treatment process according to claim 1, it is characterized in that: 80 tons of pineapple peel, the pineapple core, the Herba Passiflorae Caeruleae skin, passionflower seed pomace and 20 tons of sawdusts, organism of fermentation flora nutrient chemical, mix and be solid substances, solid substances is made stockpile, fermentation, turning when waiting to pile more than the temperature rise to 70 ℃, the heap temperature descends after the turning, when treating that the stockpile temperature rises to more than 70 ℃ once more, inject Rubber Industrial Wastewater to stockpile, the solid substances moisture content reaches 65% behind the injection waste water, afterwards, every 2 days Rubber Industrial Wastewater of reinjecting, the injection rate of each Rubber Industrial Wastewater and the ratio of solid materials dry weight were 1: 1, the described Rubber Industrial Wastewater 4 times of reinjecting.
4. treatment process according to claim 1, it is characterized in that: 30 tons on husk, 10 tons of rubber oil cakes, 10 tons in sawdust and organism of fermentation flora nutrient chemical, mix and be solid substances, to transfer to for the moisture content of solid substances about 70% with Rubber Industrial Wastewater, make the stockpile of high 80cm, turning when waiting to pile more than the temperature rise to 70 ℃, the heap temperature descends after the turning, when treating that the stockpile temperature rises to more than 70 ℃ once more, inject Rubber Industrial Wastewater, make that moisture content reaches 70% in the solid substances to stockpile, afterwards, injected Rubber Industrial Wastewater every 2 days, the ratio of each Rubber Industrial Wastewater injection rate and solid materials dry weight is 1: 1.25, the described Rubber Industrial Wastewater 4 times of reinjecting.
CN2010105735379A 2010-12-01 2010-12-01 Treatment method of rubber production wastewater Expired - Fee Related CN102020360B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105735379A CN102020360B (en) 2010-12-01 2010-12-01 Treatment method of rubber production wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010105735379A CN102020360B (en) 2010-12-01 2010-12-01 Treatment method of rubber production wastewater

Publications (2)

Publication Number Publication Date
CN102020360A true CN102020360A (en) 2011-04-20
CN102020360B CN102020360B (en) 2012-05-30

Family

ID=43862190

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010105735379A Expired - Fee Related CN102020360B (en) 2010-12-01 2010-12-01 Treatment method of rubber production wastewater

Country Status (1)

Country Link
CN (1) CN102020360B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104529061A (en) * 2014-12-13 2015-04-22 山东永泰化工有限公司 Treatment process for rubber accelerator production wastewater
CN104529054A (en) * 2014-11-26 2015-04-22 山东永泰化工有限公司 Rubber accelerant NOBS production wastewater treatment method
CN104529055A (en) * 2014-11-26 2015-04-22 山东永泰化工有限公司 Method for treating wastewater produced in waste tire recycling
CN105693398A (en) * 2016-03-15 2016-06-22 海南医学院 Method for producing agricultural biological agent with natural latex separating liquid
CN108101679A (en) * 2018-01-10 2018-06-01 成都金昌旺农业科技有限公司 A kind of preparation method for inhibiting soil nematodes fertilizer
CN111362518A (en) * 2020-04-08 2020-07-03 辽宁大力化工科技开发有限公司 Separation and recovery method of glue-making wastewater
CN111499427A (en) * 2020-03-31 2020-08-07 云南省热带作物科学研究所 Method for preparing organic fertilizer by using natural rubber whey wastewater and product thereof
CN113264566A (en) * 2021-06-30 2021-08-17 江南大学 Method for synchronously realizing harmless treatment of azo dye and straw recycling treatment
CN113998837A (en) * 2021-11-01 2022-02-01 南京工业大学 Method for treating dye wastewater by using biomass and fungi

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1192427A (en) * 1998-04-02 1998-09-09 毕文芳 Organic ecology fertilizer
JP3340437B2 (en) * 1993-04-22 2002-11-05 ベーエーゲー ビオエネルギー ゲゼルシャフト ミット ベシュレンクテル ハフツング Method and apparatus for converting biological waste into fertilizer and wet fermentation
CN1793074A (en) * 2005-11-21 2006-06-28 江苏省农业科学院 Process for producing multielement fertilizer by plant straw ash
US20100031896A1 (en) * 2003-12-03 2010-02-11 Kabushiki Kaisha Miike Tekkosho Method for manufacturing feedstuff

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3340437B2 (en) * 1993-04-22 2002-11-05 ベーエーゲー ビオエネルギー ゲゼルシャフト ミット ベシュレンクテル ハフツング Method and apparatus for converting biological waste into fertilizer and wet fermentation
CN1192427A (en) * 1998-04-02 1998-09-09 毕文芳 Organic ecology fertilizer
US20100031896A1 (en) * 2003-12-03 2010-02-11 Kabushiki Kaisha Miike Tekkosho Method for manufacturing feedstuff
CN1793074A (en) * 2005-11-21 2006-06-28 江苏省农业科学院 Process for producing multielement fertilizer by plant straw ash

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《中国生态农业学报》 20100531 张鸣等 麦秆和羊粪混合高温堆肥腐熟进程研究 第18卷, 第3期 2 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104529054A (en) * 2014-11-26 2015-04-22 山东永泰化工有限公司 Rubber accelerant NOBS production wastewater treatment method
CN104529055A (en) * 2014-11-26 2015-04-22 山东永泰化工有限公司 Method for treating wastewater produced in waste tire recycling
CN104529054B (en) * 2014-11-26 2016-02-17 山东永泰化工有限公司 Rubber accelerator NOBS production wastewater treatment method
CN104529055B (en) * 2014-11-26 2016-02-24 山东永泰化工有限公司 The method of wastewater treatment produced during junked tire reclaims
CN104529061A (en) * 2014-12-13 2015-04-22 山东永泰化工有限公司 Treatment process for rubber accelerator production wastewater
CN104529061B (en) * 2014-12-13 2016-02-17 山东永泰化工有限公司 Rubber accelerant wastewater treatment process
CN105693398A (en) * 2016-03-15 2016-06-22 海南医学院 Method for producing agricultural biological agent with natural latex separating liquid
CN108101679A (en) * 2018-01-10 2018-06-01 成都金昌旺农业科技有限公司 A kind of preparation method for inhibiting soil nematodes fertilizer
CN111499427A (en) * 2020-03-31 2020-08-07 云南省热带作物科学研究所 Method for preparing organic fertilizer by using natural rubber whey wastewater and product thereof
CN111362518A (en) * 2020-04-08 2020-07-03 辽宁大力化工科技开发有限公司 Separation and recovery method of glue-making wastewater
CN113264566A (en) * 2021-06-30 2021-08-17 江南大学 Method for synchronously realizing harmless treatment of azo dye and straw recycling treatment
CN113998837A (en) * 2021-11-01 2022-02-01 南京工业大学 Method for treating dye wastewater by using biomass and fungi

Also Published As

Publication number Publication date
CN102020360B (en) 2012-05-30

Similar Documents

Publication Publication Date Title
CN102020360B (en) Treatment method of rubber production wastewater
Neshat et al. Anaerobic co-digestion of animal manures and lignocellulosic residues as a potent approach for sustainable biogas production
Ibrahim et al. An introduction to anaerobic digestion of organic wastes
Shah et al. Co-digestion, pretreatment and digester design for enhanced methanogenesis
CN104926541B (en) A kind of production technology of joint wheat bran stalk vinasse seaweed mixed fungus fermentation efficient biologic-organic fertilizer
CN102173507B (en) Method for comprehensively recycling fecal sewage of large-scale livestock and poultry farms and farmland crop straws
CN103740764B (en) A kind of biogas fermentation functional biological catalyst and the method that utilizes catalyzer to ferment
Meena et al. Biohythane production from food processing wastes–Challenges and perspectives
CN104370582B (en) A kind of organic waste odorless aerobic compost method
CN100387551C (en) Method of producing active nutritional fertilizer using old domostic garbage
CN101255074B (en) Novel method for comprehensive utilization of banana haulm by-product
CN103103216B (en) Biogas composite material
CN104045385B (en) A kind of biological organic fertilizer and production method thereof
CN105948841B (en) Organic fertilizer tank type fermentation method taking mushroom dregs as substrate
CN103664255A (en) Organic waste facultative aerobic fermentation composting treatment process
CN101973682A (en) Wet and dry coupling anaerobic fermentation process method
Coats et al. Effect of organic loading and retention time on dairy manure fermentation
CN101874567A (en) Method for resource utilization of plant wastes
CN101851127A (en) Preparation process of multifunctional bamboo-shell organic-inorganic composite fertilizer
CN111793656A (en) Treatment method of agricultural organic waste
CN103980011A (en) Method for preparing liquid biological organic fertilizer by utilizing domestic garbage
CN102173897A (en) Method for treating and utilizing agricultural solid waste through aerobic high-temperature hydrolysis and fermentation
CN103641593B (en) Method for preparing garden media from biogas slurry
CN101664103A (en) Method for manufacturing feed by lactic acid fermentation by using waste residues of potato starch under anaerobic condition
CN101696426A (en) Composite material of marsh gas and method for preparing same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120530

Termination date: 20171201