CN101982601B - Preparation method of ecological non-iron cotton high-grade fabric - Google Patents
Preparation method of ecological non-iron cotton high-grade fabric Download PDFInfo
- Publication number
- CN101982601B CN101982601B CN2010105112359A CN201010511235A CN101982601B CN 101982601 B CN101982601 B CN 101982601B CN 2010105112359 A CN2010105112359 A CN 2010105112359A CN 201010511235 A CN201010511235 A CN 201010511235A CN 101982601 B CN101982601 B CN 101982601B
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- CN
- China
- Prior art keywords
- preparation
- finishing agent
- fibroin
- shitosan
- citric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 29
- 239000004744 fabric Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052742 iron Inorganic materials 0.000 title abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 75
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 108010022355 Fibroins Proteins 0.000 claims abstract description 23
- 239000002699 waste material Substances 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 230000001153 anti-wrinkle Effects 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 8
- 238000010409 ironing Methods 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 6
- 229960000583 Acetic Acid Drugs 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 5
- 239000012362 glacial acetic acid Substances 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 206010018987 Haemorrhage Diseases 0.000 claims description 3
- 230000000740 bleeding Effects 0.000 claims description 3
- 231100000319 bleeding Toxicity 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000012224 working solution Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 239000004753 textile Substances 0.000 abstract description 5
- 229920001661 Chitosan Polymers 0.000 abstract description 4
- 210000003491 Skin Anatomy 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 230000002349 favourable Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 239000003431 cross linking reagent Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 amino hydroxyl Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative Effects 0.000 description 1
- 230000004059 degradation Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005289 physical deposition Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Abstract
The invention discloses a preparation method of an ecological non-iron cotton high-grade fabric. The method comprises the steps of preparation of fibroin/chitosan/citric acid anti-crease shrink-proof finishing agent, finishing and the like. In the invention, since waste silk, chitosan and citric acid, which are natural green healthy products, are utilized as raw materials, the ecological non-iron cotton high-grade fabric prepared by using the finishing agent conforms to the direction that the function classification of the textiles in the 21th century is required to be finished and processed on the premise of comfort, cleanness and safety. Since the fibroin finishing agent contains substantive fibroin proteins, the ecological non-iron cotton high-grade fabric has favorable skin affinity, and caters for the consumption concepts of environmental friendliness, health and fashion of people.
Description
Technical field:
The present invention designs the preparation method of the non-ironing cotton fabric of a kind of ecology
Background technology:
Cotton fiber is a kind of senior native cellulose fibre, is considered to " green fiber ".Its COTTON FABRIC quality is plentiful abundant, soft hand feeling, and good sucting wet air permeability and good wearing comfort always receive people's favor, and market and development prospect are widely at home and abroad arranged.In various fabrics, textile clothes are one of most popular consumer goods of back to nature, but COTTON FABRIC is wrinkling serious in dress, after washing, need flatiron could recover original outward appearance.For a long time, the anti-wrinkle shrink-proof finishing agent great majority that use are the formolation compound, in arrangement processing and wearing process, can discharge ecological environment and the extremely harmful formaldehyde of human body.
And useless silk is as the main discarded object of Silk Industry, and shitosan is the second largest regenerated resources of nature as the discarded object of materials such as shrimp, crab, is only second to cotton fiber, but is not all effectively utilized.
Summary of the invention:
The object of the present invention is to provide a kind of preparation method of the cotton high-grade fabric with anti-wrinkle shrink-proof function of ecology.
Technical solution of the present invention is:
The non-ironing cotton high-grade fabric of a kind of ecology preparation method is characterized in that: adopt following method to process:
(1) preparation fibroin/shitosan/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make the fibroin hydrolyzate that certain molecular weight distributes;
B finishing agent preparation: shitosan is adopted certain glacial acetic acid dissolving, handle and add hydrogen peroxide solution behind the certain hour and degrade, filter, the collecting precipitation thing makes the shitosan of degraded.
Composite: as B finishing agent and C citric acid slowly to be joined in the A liquid, add auxiliary reagents such as a certain amount of bleeding agent, softener again, fibroin/shitosan that must be stable/citric acid anti-wrinkle shrink-proof finishing agent.
(2) put in order: COTTON FABRIC is put in fibroin/shitosan/citric acid finishing padded, get product after oven dry bakes.
In the step (1), when A liquid prepared, the concentration of NaOH was 1～5mol/L, and the waste silk consumption is 1%～10%, and hydrolysis temperature is 100 ℃, and hydrolysis time is 30～120min; When B arrangement thing prepares, take by weighing certain amount of chitosan, it is added in the entry, add a certain amount of glacial acetic acid again, stir 24h down, shitosan fully is dissolved in the acetum at 30～60 ℃.Slowly add 30% hydrogen peroxide solution then at a certain temperature, behind reaction 1～3h, filter collecting precipitation; B finishing agent and C citric acid are joined in the A liquid, and A and B solid content ratio are 4: 1, and the citric acid consumption is 1%～10%
The concrete grammar of step (2) is: cotton fabric is put into fibroin/shitosan/citric acid finishing working solution pad, pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 3～5min down at 100～150 ℃ again, wash then, dry product.
Useless silk has a certain amount of free active group through washing the fibroin finishing agent that makes after the hydrolysis, like hydroxyl, phenolic hydroxyl group, amino etc., can form stable combining through covalent cross-linking or physical deposition with cotton fiber is intermolecular.Thereby improve the anti-wrinkle shrink-proof performance of cotton fiber.
The shitosan film forming is strong; And with the cellulose chemistry structural similarity, they have good absorption and compatibility, and the amino hydroxyl with fiber of the hydroxyl of shitosan and a part forms numerous intermolecular hydrogen bondings; Add proper amount of cross-linking agent, make the shitosan arrangement can play certain anti-wrinkle shrink-proof wrinkle effect.
Citric acid has more reactive group, can form covalent cross-linking with hydroxyl on the COTTON FABRIC, simultaneously, and the crosslinking agent that can also close as other finishing agents and cotton knot.
Fibroin hydrolyzate, degradation of chitosan thing and citric acid under certain pH condition, are re-dubbed stable finishing agent by a certain percentage, have cooperative effect, and need not to add in addition crosslinking agent, make the all-cotton fabric after the arrangement have preferable anti-wrinkle shrink-proof effect.
The present invention is a raw material with useless silk, shitosan and citric acid; The three all belongs to the natural green health-oriented products; Using the ecological non-ironing textile high-grade fabric of this finishing agent exploitation to meet the 21 century finishing functions of textile fabrics should carry out as keynote with safety with comfortable, cleaning and put the direction of processing in order; Wherein contain a large amount of fibroin albumens in the fibroin finishing agent, have skin-friendly preferably, and catered to the consumption concept of people " environmental protection, health, fashion ".
The advantage that the present invention is compared with prior art had:
1, finishing agent adopted is product harmless, environmental protection.The consumption concept that meets " environmental protection, health, fashion ".
2, only contain hydroxyl on the all-cotton fabric, after arrangement, contain fibroin albumens such as part amino, phenolic hydroxyl group on the fabric, human body skin is had compatibility preferably.Can improve the sucting wet air permeability and the snugness of fit of cotton fiber.
3, do not add crosslinking agent, adopt citric acid as crosslinking agent, the fabric after the arrangement does not contain has the material that stimulation is toxic or ecological textile is forbidden to human body.
Below in conjunction with embodiment the present invention is described further:
The specific embodiment:
The non-ironing cotton high-grade fabric of a kind of ecology preparation method, adopt following method to process:
(1) preparation fibroin/shitosan/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make fibroin hydrolyzate (A liquid);
B finishing agent preparation: shitosan is adopted the glacial acetic acid dissolving, so add hydrogen peroxide solution and degrade, filter, the collecting precipitation thing makes the shitosan (B finishing agent) of degraded.
Composite: as B finishing agent and C citric acid slowly to be joined in the A liquid, can add (or not adding) bleeding agent, softener again, fibroin/shitosan that must be stable/citric acid anti-wrinkle shrink-proof finishing agent.
(2) put in order: COTTON FABRIC is put in fibroin/shitosan/citric acid finishing padded, get product after oven dry bakes.
In the step (1), when A liquid prepared, the concentration of NaOH was 1～5mol/L, and the waste silk consumption is 1%～10%, and hydrolysis temperature is 100 ℃, and hydrolysis time is 30～120min; When B arrangement thing prepares, take by weighing shitosan, it is added in the entry, add glacial acetic acid again, stir 24h down, shitosan fully is dissolved in the acetum at 30～60 ℃.Slowly add 30% hydrogen peroxide solution then, reaction 1～3h filters collecting precipitation; B finishing agent and C citric acid are joined in the A liquid, and A and B solid content ratio are 4: 1, and the citric acid consumption is 1%～10%;
The concrete grammar of step (2) is: cotton fabric is put into fibroin/shitosan/citric acid finishing working solution pad, pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 3～5min down at 100～150 ℃ again, wash then, dry product.
Claims (3)
1. the non-ironing cotton high-grade fabric of ecology preparation method is characterized in that: adopt following method to process:
(1) preparation fibroin/shitosan/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make the fibroin hydrolyzate;
B finishing agent preparation: shitosan is adopted the glacial acetic acid dissolving, add hydrogen peroxide solution then and degrade, filter, the collecting precipitation thing makes the shitosan of degraded;
Composite: as B finishing agent and C citric acid slowly to be joined in the A liquid, add bleeding agent, softener auxiliary reagent again, fibroin/shitosan that must be stable/citric acid anti-wrinkle shrink-proof finishing agent;
(2) put in order: COTTON FABRIC is put in fibroin/shitosan/citric acid anti-wrinkle shrink-proof finishing agent padded, get product after oven dry bakes.
2. the non-ironing cotton high-grade fabric of ecology according to claim 1 preparation method is characterized in that: when A liquid and B finishing agent were composite in the step (1), the solid content ratio was 4: 1.
3. the preparation method of a kind of ecological full-cotton high-grade fabric according to claim 1; It is characterized in that: the concrete grammar of step (2) is: COTTON FABRIC is put into fibroin/shitosan/citric acid anti-wrinkle shrink-proof finishing agent working solution pad; Pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 3～5min down at 100～150 ℃ again, wash then, dry product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105112359A CN101982601B (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-iron cotton high-grade fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105112359A CN101982601B (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-iron cotton high-grade fabric |
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| Publication Number | Publication Date |
|---|---|
| CN101982601A CN101982601A (en) | 2011-03-02 |
| CN101982601B true CN101982601B (en) | 2012-02-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010105112359A Expired - Fee Related CN101982601B (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-iron cotton high-grade fabric |
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Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747603B (en) * | 2012-07-18 | 2014-01-15 | 绍兴文理学院 | Dyeing afterfinish process of cotton knitted fabric |
| CN103103751A (en) * | 2012-12-14 | 2013-05-15 | 常熟市赵市华达染整有限责任公司 | Method for resisting bacteria, preventing crease and finishing silk fabric in biological enzymatic way |
| CN103668981A (en) * | 2013-11-29 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Crease-resistant and shrink-resistant finishing agent for hemp fabric |
| CN104233884A (en) * | 2014-09-11 | 2014-12-24 | 苏州印丝特纺织数码科技有限公司 | Chitosan modified silk fabric staining method |
| CN104264472B (en) * | 2014-09-25 | 2016-09-14 | 苏州印丝特纺织数码科技有限公司 | A kind of silk fabric anti-corrosive antibacterial method for sorting |
| CN104762821A (en) * | 2015-03-25 | 2015-07-08 | 苏州威尔德工贸有限公司 | Noniron finishing method of silk fabric |
| CN105063803A (en) * | 2015-09-22 | 2015-11-18 | 南通大学 | Preparation method of chitosan precipitation fiber |
| CN105544209B (en) * | 2016-01-21 | 2018-02-09 | 徐岩军 | A kind of fabric post-treatment technique using fibroin albumen as medium |
| CN105648771B (en) * | 2016-04-01 | 2018-03-23 | 深圳市歌中歌服饰有限公司 | The antibacterial deodourizing and anti-crease finishing technique of cotton/silk blend fabric |
| CN106245313B (en) * | 2016-09-21 | 2018-03-30 | 宁波荣昌祥服饰股份有限公司 | A kind of bamboo fibre fabric of noniron finish and preparation method thereof |
| CN107190506A (en) * | 2017-06-15 | 2017-09-22 | 江苏金太阳纺织科技股份有限公司 | fibroin finishing agent and its preparation method and application |
| CN109137511B (en) * | 2018-07-09 | 2020-12-04 | 安徽农业大学 | Chitosan sericin compound finishing agent and finishing method for cotton fabric |
| CN109137514B (en) * | 2018-08-01 | 2021-11-19 | 浙江轩日科技股份有限公司 | Non-ironing all-cotton fabric and preparation method thereof |
| CN111321536B (en) * | 2020-03-03 | 2020-11-27 | 浙江环发纺织印染有限公司 | Low-loss fabric printing and dyeing process |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7166135B2 (en) * | 2003-01-13 | 2007-01-23 | North Carolina State University | Product and method for treating cotton |
| CN1282795C (en) * | 2004-06-03 | 2006-11-01 | 上海应用技术学院 | Antimicrobial moisture retaining finishing agent for cotton fabric and antimicrobial moisture retaining finishing method |
| CN101725045A (en) * | 2009-09-14 | 2010-06-09 | 陕西科技大学 | Ecological anti-felting finishing method for wools |
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