CN101974850A - Preparation method of ecological non-ironing silk fabric - Google Patents
Preparation method of ecological non-ironing silk fabric Download PDFInfo
- Publication number
- CN101974850A CN101974850A CN2010105111892A CN201010511189A CN101974850A CN 101974850 A CN101974850 A CN 101974850A CN 2010105111892 A CN2010105111892 A CN 2010105111892A CN 201010511189 A CN201010511189 A CN 201010511189A CN 101974850 A CN101974850 A CN 101974850A
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- China
- Prior art keywords
- silk
- preparation
- citric acid
- fibroin
- finishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004744 fabric Substances 0.000 title claims abstract description 12
- 238000010409 ironing Methods 0.000 title claims abstract description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 69
- 108010022355 Fibroins Proteins 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000002699 waste material Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 12
- 230000001153 anti-wrinkle Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 206010018987 Haemorrhage Diseases 0.000 claims description 3
- 230000000740 bleeding Effects 0.000 claims description 3
- 231100000319 bleeding Toxicity 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 239000012224 working solution Substances 0.000 claims description 3
- 239000004753 textile Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 210000003491 Skin Anatomy 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005289 physical deposition Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Abstract
The invention discloses a preparation method of ecological non-ironing silk fabric, which comprises the steps of preparing silk fibroin/citric acid anti-creasing and anti-shrinking finishing agents, and then finishing. In the method, waste silk and citric acid are taken as raw materials which are natural green health products, thus the ecological non-ironing silk fabric developed by the finishing agents meets the requirements for comfortable, clear and safe textile functional finishing in the 21st century, wherein, the silk fibroin finishing agent contains a great amount of silk fibroin, thus achieving better affinity for skin and catering to an 'environmental protection, health and fashion' consumption concept of people.
Description
Technical field: the present invention designs the preparation method of the non-ironing silk broadcloth of a kind of ecology
Background technology:
The silk broadcloth color and luster is soft, and drapability is good, and moisture absorption is ventilative, and is soft smooth, has good snugness of fit and certain health.But take with washing process in, be subjected to the effect of external force, often produce wrinkle.This greatly reduces the effect of taking of real silk clothes, and along with growth in the living standard, consumption changes to superior, fashion-orientation, is necessary real silk fabric is carried out functional treatment, improves its wearability, thereby makes real silk really become the textile fabric queen.For a long time, the anti-wrinkle shrink-proof finishing agent great majority that use are the formolation compound, can discharge ecological environment and the extremely harmful formaldehyde of human body in arrangement processing and wearing process, and can reduce the economic benefit of silk broadcloth greatly.
And useless silk is the second largest regenerated resources of nature, but is not all effectively utilized always as the main discarded object of Silk Industry.
Summary of the invention:
The object of the present invention is to provide a kind of preparation method of the silk broadcloth with anti-wrinkle shrink-proof function of ecology.
Technical solution of the present invention is:
The preparation method of the non-ironing silk broadcloth lining of a kind of ecology is characterized in that: adopt following method to make:
(1) preparation fibroin/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make the fibroin hydrolyzate that certain molecular weight distributes;
Composite: as the B citric acid slowly to be joined in the A liquid, add auxiliary reagents such as a certain amount of bleeding agent, softener again, fibroin that must be stable/citric acid anti-wrinkle shrink-proof finishing agent.
(2) put in order: silk fabrics is put in fibroin/citric acid finishing padded, get product after oven dry bakes.
In the step (1), when A liquid prepared, the concentration of NaOH was 1～5mol/L, and the waste silk consumption is 1%～10%, and hydrolysis temperature is 100 ℃, and hydrolysis time is 30～120min; B finishing agent and C citric acid are joined in the A liquid, and A and B solid content ratio are 5: 1
The concrete grammar of step (2) is: the silk broadcloth lining is put into fibroin/citric acid finishing working solution pad, pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 1～3min down at 130～170 ℃ again, wash then, dry product.
Useless silk is through washing the fibroin finishing agent that makes after the hydrolysis, has a certain amount of free active group, as hydroxyl, phenolic hydroxyl group, amino etc., and fibroin finishing agent and silk broadcloth itself are protein structure, can form stable combining by covalent cross-linking or physical deposition with silk fiber is intermolecular.Thereby improve the anti-wrinkle shrink-proof performance of silk fiber.
Citric acid has more reactive group, can form covalent cross-linking with hydroxyl on the silk fabrics, amino groups, simultaneously, and the crosslinking agent that can also combine with silk broadcloth as other finishing agents.
Fibroin hydrolyzate, citric acid under certain pH condition, are re-dubbed stable finishing agent by a certain percentage, have cooperative effect, and need not to add in addition crosslinking agent, make the silk fabrics after the arrangement have preferable anti-wrinkle shrink-proof effect.
The present invention is a raw material with useless silk, citric acid, both all belong to the natural green health-oriented products, meeting the 21 century finishing functions of textile fabrics with the ecological non-ironing silk broadcloth lining of this finishing agent exploitation should be that keynote is carried out the direction that arrangement is processed with safety with comfortable, cleaning, wherein contain a large amount of fibroin albumens in the fibroin finishing agent, have skin-friendly preferably, and catered to the consumption concept of people " environmental protection, health, fashion ".
The advantage that the present invention is compared with prior art had:
1. finishing agent adopted is product harmless, environmental protection.The consumption concept that meets " environmental protection, health, fashion ".
2. do not add crosslinking agent, adopt citric acid as crosslinking agent, the fabric after the arrangement does not contain has the material that stimulation is toxic or ecological textile is forbidden to human body.
The invention will be further described below in conjunction with embodiment:
The specific embodiment:
The preparation method of the non-ironing silk broadcloth lining of a kind of ecology is characterized in that: adopt following method to make:
(1) preparation fibroin/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make the fibroin hydrolyzate;
Composite: as the B citric acid slowly to be joined in the A liquid, and can add auxiliary reagents such as (or not adding) bleeding agent, softener, fibroin that must be stable/citric acid anti-wrinkle shrink-proof finishing agent again.
(2) put in order: silk fabrics is put in fibroin/citric acid finishing padded, get product after oven dry bakes.
In the step (1), when A liquid prepared, the concentration of NaOH was 1～5mol/L, and the waste silk consumption is 1%～10%, and hydrolysis temperature is 100 ℃, and hydrolysis time is 30～120min; B finishing agent and C citric acid are joined in the A liquid, and A and B solid content ratio are 5: 1
The concrete grammar of step (2) is: the silk broadcloth lining is put into fibroin/citric acid finishing working solution pad, pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 1～3min down at 130～170 ℃ again, wash then, dry product.
Claims (4)
1. the preparation method of the non-ironing silk broadcloth lining of ecology is characterized in that: adopt following method to make:
(1) preparation fibroin/citric acid anti-wrinkle shrink-proof finishing agent
The preparation of A liquid: the silk alkaline washing that will give up, remove impurity such as its softener, adopt caustic soda hydrolysis waste silk again, filter through filter membrane, make the fibroin hydrolyzate;
Composite: as the B citric acid slowly to be joined in the A liquid, add auxiliary reagents such as bleeding agent, softener again, fibroin that must be stable/citric acid anti-wrinkle shrink-proof finishing agent;
(2) put in order: silk fabrics is put in fibroin/citric acid finishing padded, get product after oven dry bakes.
2. the non-ironing silk broadcloth lining of ecology according to claim 1 preparation method is characterized in that: when A liquid and B finishing agent were composite in the step (1), the solid content ratio was 5: 1.
3. the preparation method of the non-ironing silk broadcloth lining of a kind of ecology according to claim 1 is characterized in that: in the step (1), when A liquid prepares, the concentration of NaOH is 1～5mol/L, the waste silk consumption is 1%～10%, and hydrolysis temperature is 100 ℃, and hydrolysis time is 30～120min; A and B solid content ratio are 5: 1
4. the preparation method of the non-ironing silk broadcloth lining of a kind of ecology according to claim 1, it is characterized in that: the concrete grammar of step (2) is: the silk broadcloth lining is put into fibroin/citric acid finishing working solution pad, pick-up rate is 90%, and padding is two to soak two and roll; Then at 80 ℃ of following preliminary drying 5min, handle 1～3min down at 130～170 ℃ again, wash then, dry product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105111892A CN101974850A (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-ironing silk fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105111892A CN101974850A (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-ironing silk fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101974850A true CN101974850A (en) | 2011-02-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105111892A Pending CN101974850A (en) | 2010-10-18 | 2010-10-18 | Preparation method of ecological non-ironing silk fabric |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634973A (en) * | 2012-04-16 | 2012-08-15 | 盛虹集团有限公司 | Citric acid wrinkle proofing technology for real silk fabrics |
| CN103334303A (en) * | 2013-04-16 | 2013-10-02 | 淳安县千岛湖桑园丝绸有限公司 | Anti-shrinkage silk cotton fiber fabric finishing method |
| CN103668981A (en) * | 2013-11-29 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Crease-resistant and shrink-resistant finishing agent for hemp fabric |
| CN103770177A (en) * | 2014-01-16 | 2014-05-07 | 天津工业大学 | Preparation method of apocynum venetum natural functional finishing agent |
| CN105113245A (en) * | 2015-09-07 | 2015-12-02 | 江苏阳光股份有限公司 | Method for treating anti-wrinkle antibacterial anti-ultraviolet easy-care real silk shirt |
| CN105220486A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | A kind of anti-crease finishing auxiliary agent of silk fabric |
| CN105220460A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | The silk fabric that a kind of crease-resistant drapability is good |
| CN105274875A (en) * | 2015-11-13 | 2016-01-27 | 长兴县三星纺织有限公司 | Finishing process for improving dyeing performance of real silk |
| CN105506985A (en) * | 2016-01-08 | 2016-04-20 | 盐城工学院 | Soybean protein fiber textile finishing solution |
| CN107841578A (en) * | 2017-11-30 | 2018-03-27 | 英泰时尚服饰（苏州）有限公司 | A kind of corium soft finishing agent and preparation method thereof |
| CN107841873A (en) * | 2017-11-30 | 2018-03-27 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of environment-protection weight increasing silk fabrics |
| CN108330678A (en) * | 2018-02-02 | 2018-07-27 | 宜州市壮之都丝绸家纺有限公司 | A kind of maintenance method of silk |
| CN108486882A (en) * | 2018-04-08 | 2018-09-04 | 苏州经贸职业技术学院 | A kind of preparation method of antibacterial crease-resistant Silk Finishing agent |
| CN111395015A (en) * | 2020-04-15 | 2020-07-10 | 淄博大染坊丝绸集团有限公司 | Dyeing and finishing process of real silk fabric for summer wear |
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|---|---|---|---|---|
| JPH01246458A (en) * | 1988-03-24 | 1989-10-02 | Shiga Pref Gov | Method for shrinkproofing silk fabric |
| CN101187164A (en) * | 2007-11-28 | 2008-05-28 | 南通大学 | Anti-creasing anti-bacterial anti-violet composite function silk fabric and its preparation method |
| CN101638847A (en) * | 2009-07-24 | 2010-02-03 | 东莞市德能化工有限公司 | Formaldehyde-free durable crease-proof finishing agent used for cellulosic fiber fabric |
-
2010
- 2010-10-18 CN CN2010105111892A patent/CN101974850A/en active Pending
Patent Citations (3)
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|---|---|---|---|---|
| JPH01246458A (en) * | 1988-03-24 | 1989-10-02 | Shiga Pref Gov | Method for shrinkproofing silk fabric |
| CN101187164A (en) * | 2007-11-28 | 2008-05-28 | 南通大学 | Anti-creasing anti-bacterial anti-violet composite function silk fabric and its preparation method |
| CN101638847A (en) * | 2009-07-24 | 2010-02-03 | 东莞市德能化工有限公司 | Formaldehyde-free durable crease-proof finishing agent used for cellulosic fiber fabric |
Non-Patent Citations (4)
| Title |
|---|
| 《山东纺织科技》 20050620 陈春侠等 乙二醛与丝素复配整理剂对棉织物的防皱整理 第53-56页 1-2 , 第3期 2 * |
| 《高分子学报》 20000430 葛学武等 蚕丝辐射接枝丙烯腈 第205-209页 1-2 , 第2期 2 * |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634973A (en) * | 2012-04-16 | 2012-08-15 | 盛虹集团有限公司 | Citric acid wrinkle proofing technology for real silk fabrics |
| CN103334303A (en) * | 2013-04-16 | 2013-10-02 | 淳安县千岛湖桑园丝绸有限公司 | Anti-shrinkage silk cotton fiber fabric finishing method |
| CN103334303B (en) * | 2013-04-16 | 2015-05-27 | 淳安县千岛湖桑园丝绸有限公司 | Anti-shrinkage silk cotton fiber fabric finishing method |
| CN103668981A (en) * | 2013-11-29 | 2014-03-26 | 南通市通州区大达麻纺织有限公司 | Crease-resistant and shrink-resistant finishing agent for hemp fabric |
| CN103770177A (en) * | 2014-01-16 | 2014-05-07 | 天津工业大学 | Preparation method of apocynum venetum natural functional finishing agent |
| CN105113245A (en) * | 2015-09-07 | 2015-12-02 | 江苏阳光股份有限公司 | Method for treating anti-wrinkle antibacterial anti-ultraviolet easy-care real silk shirt |
| CN105274875A (en) * | 2015-11-13 | 2016-01-27 | 长兴县三星纺织有限公司 | Finishing process for improving dyeing performance of real silk |
| CN105220460A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | The silk fabric that a kind of crease-resistant drapability is good |
| CN105220486A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | A kind of anti-crease finishing auxiliary agent of silk fabric |
| CN105274875B (en) * | 2015-11-13 | 2018-04-24 | 长兴县三星纺织有限公司 | A kind of finishing technique for improving silk dyeing performance |
| CN105506985A (en) * | 2016-01-08 | 2016-04-20 | 盐城工学院 | Soybean protein fiber textile finishing solution |
| CN105506985B (en) * | 2016-01-08 | 2017-12-08 | 盐城工学院 | A kind of soybean fiber textile finishing liquid |
| CN107841578A (en) * | 2017-11-30 | 2018-03-27 | 英泰时尚服饰（苏州）有限公司 | A kind of corium soft finishing agent and preparation method thereof |
| CN107841873A (en) * | 2017-11-30 | 2018-03-27 | 苏州绣艳天下刺绣工艺有限公司 | A kind of preparation method of environment-protection weight increasing silk fabrics |
| CN108330678A (en) * | 2018-02-02 | 2018-07-27 | 宜州市壮之都丝绸家纺有限公司 | A kind of maintenance method of silk |
| CN108486882A (en) * | 2018-04-08 | 2018-09-04 | 苏州经贸职业技术学院 | A kind of preparation method of antibacterial crease-resistant Silk Finishing agent |
| CN111395015A (en) * | 2020-04-15 | 2020-07-10 | 淄博大染坊丝绸集团有限公司 | Dyeing and finishing process of real silk fabric for summer wear |
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Application publication date: 20110216 |