CN101967415A - Method for preparing coal-based fuel carbon - Google Patents

Method for preparing coal-based fuel carbon Download PDF

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Publication number
CN101967415A
CN101967415A CN2010105420896A CN201010542089A CN101967415A CN 101967415 A CN101967415 A CN 101967415A CN 2010105420896 A CN2010105420896 A CN 2010105420896A CN 201010542089 A CN201010542089 A CN 201010542089A CN 101967415 A CN101967415 A CN 101967415A
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China
Prior art keywords
coal
charcoal
fuel charcoal
based fuel
carbonization
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CN2010105420896A
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CN101967415B (en
Inventor
黄光许
刘全润
马名杰
张传祥
邢宝林
秦欣欣
黄山秀
夏浩
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Henan University of Technology
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Henan University of Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

一种煤基燃料炭的制作方法,包括下述步骤:a、按质量比取烟煤80~95、农作物秸秆0~10和有机粘结剂4~10,混拌均匀后,加入适量的水分再次拌匀;b、将步骤a所得到的物料在成型机上压制成球形体,之后将所得生球在空气中自然晾干;c、将经自然晾干的生球放入炭化炉中,在温度为400~700℃,炭化时间为90min~120min的条件下进行炭化,再经冷却得煤基燃料炭。本发明的煤基燃料炭具有原料廉价易得,有效利用生物质能;所得燃料炭产品抗压强度>25kg/个;固定炭>75%;挥发份>10%;灰份<10%;热值>6500千卡/kg;硫含量<0.4%;易点火、耐烧、燃烧完全、无烟味、无火星烟尘、炉表温度高;热稳定高,燃烧过程中不塌、不碎。A method for making coal-based fuel charcoal, comprising the following steps: a. Take bituminous coal 80-95, crop straw 0-10 and organic binder 4-10 according to the mass ratio, after mixing evenly, add an appropriate amount of water again Mix well; b, press the material obtained in step a into a spherical body on a molding machine, and then dry the obtained green balls naturally in the air; c, put the naturally dried green balls into a carbonization furnace, Carbonization is carried out under the conditions of 400-700°C, and the carbonization time is 90-120 minutes, and then cooled to obtain coal-based fuel charcoal. The coal-based fuel charcoal of the present invention has cheap and easy-to-obtain raw materials, and effectively utilizes biomass energy; the resulting fuel charcoal product has a compressive strength>25kg/piece; fixed charcoal>75%; volatile matter>10%; ash content<10%; Value > 6500 kcal/kg; sulfur content < 0.4%; easy to ignite, burn-resistant, complete combustion, no smoke, no Martian smoke, high furnace surface temperature; high thermal stability, not collapsed or broken during combustion.

Description

A kind of making method of coal derived fuel charcoal
Technical field
The present invention relates to a kind of fuel, relate to a kind of making method of coal derived fuel charcoal specifically.
Background technology
In recent years, increasing both at home and abroad to demand as the various fuel charcoals of heating and food and drink fuel, along with the protection increasing of country, be that the former char yield of raw material constantly descends with natural forest to the forest reserves.Machine-made charcoal is the substitute products of charcoal, and it is big to have density, the calorific value height, smokeless, tasteless, pollution-free, do not explode, advantage such as inflammable, be the Green Product of generally acknowledging in the world, current throughput even do not satisfy the market requirement.Machine-made carbon is a raw material with agricultural residuums such as sawdust, stalks, processes through operations such as super-dry, plasticizing forming, charing, cooling, packings.Plasticizing forming is to utilize the contained xylogen of biomass self cohesiveness that (140-280 ℃) produces when being heated, and adopts the screw rod extrusion forming technology, makes grain formings such as wood chip under certain pressure; Charing is the pyrolytic process of wood chip rod in kiln of moulding, finally obtains machine-made carbon, simultaneously recyclable inflammable gas and wood vinegar.
At present the problem that exists of machine-made carbon industry is, the screw rod extrusion forming technology yields poorly, the energy consumption height, the consumable accessory life-span is short, ingredient requirement is harsh; In addition, the production of machine-made carbon is difficult to obtain continuous and competent raw material supply.
Summary of the invention
Purpose of the present invention provides a kind of making method of coal derived fuel charcoal just at existing weak point in the above-mentioned prior art.
Purpose of the present invention can realize by following technique measures:
The making method of coal derived fuel charcoal of the present invention comprises the steps:
A, get bituminous coal 80 ~ 95, agricultural crop straw 0 ~ 10 and organic binder bond 4 ~ 10 by mass ratio, puddle evenly after, add an amount of moisture and mix thoroughly once more;
B, the resulting material of step a is pressed into spheroplast on shaper, afterwards the gained green-ball is dried in air naturally;
C, will put into charring furnace through natural air dried green-ball, be 400~700 ℃ in temperature, and carbonization time is to carry out charing under the condition of 90min~120min, again through cool off the coal derived fuel charcoal.
The granularity of bituminous coal described in the present invention is less than 3mm; Described agricultural crop straw is to be crushed to particle diameter less than 3mm with pulverizer behind natural air drying; Described organic binder bond is a Sodium salts humic acids; The moisture 14-16% of material before the moulding.
Shaper described in the present invention is a roller briquetting machine commonly used in the moulded coal industry.
Carbonization time described in the present invention contains the heating-up time.
Beneficial effect of the present invention is as follows:
Coal derived fuel charcoal of the present invention is main raw material with bituminous coal and agricultural crop straw, and is cheap and easy to get, adds the combustioncharacteristics that agricultural crop straw can effectively utilize biomass energy, improve fuel charcoal product.Material forming is selected roller briquetting machine for use, and the output height, energy consumption is low, equipment attrition is little.Carbonization temperature is low, the time is short, energy consumption is little.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength〉25kg/; Fixed carbon〉75%; Fugitive constituent〉10%; Ash<10%; Calorific value〉7000 kilocalories/Kg; Easily igniting, anti-burning, burning are complete, no smoke, no Mars flue dust, stove table temperature height.
 
Embodiment
The present invention is further described below with reference to embodiment:
Embodiment 1
Get granularity less than 3mm bituminous coal, pulverize the back granularity through the natural wind dry doubling and mix thoroughly according to the mass ratio mixing of 85:10:5 less than 3mm agricultural crop straw and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally; Through the charing in charring furnace of air dried green-ball, carbonization temperature is 600 ℃, and carbonization time is that 100min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 35kg/; Moisture 1.8%; Fixed carbon 83.5%; Fugitive constituent 7%; Ash 7.7 %; 7180 kilocalories/Kg of calorific value; Sulphur content 0.31%.
Embodiment 2
Get granularity less than 3mm bituminous coal, pulverize the back granularity through the natural wind dry doubling and mix thoroughly according to the mass ratio mixing of 82:10:8 less than 3mm and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally.Through the charing in charring furnace of air dried green-ball, carbonization temperature is 700 ℃, and carbonization time is that 120min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 30kg/; Moisture 2.0%; Fixed carbon 82.1%; Fugitive constituent 8.3%; Ash 6.8%; 7088 kilocalories/Kg of calorific value; Sulphur content 0.35%.
Embodiment 3
Get granularity and mix thoroughly according to the mass ratio mixing of 94:6 less than 3mm bituminous coal and Sodium salts humic acids, total mass is 5kg, adds water and mixes thoroughly once more, and the material total moisture is controlled at 14-16%; With the moulding on roller briquetting machine of above-mentioned material, the gained green-ball dries in air naturally; Through the charing in charring furnace of air dried green-ball, carbonization temperature is 500 ℃, and carbonization time is that 90min(contains the heating-up time), again through cool off the coal derived fuel charcoal.Gained coal derived fuel charcoal product physical strength height, ultimate compression strength 28kg/; Moisture 1.9%; Fixed carbon 84%; Fugitive constituent 6.5%; Ash 7.6%; 7178 kilocalories/Kg of calorific value; Sulphur content 0.33%.

Claims (4)

1. the making method of a coal derived fuel charcoal, it is characterized in that: described method comprises the steps:
A, get bituminous coal 80 ~ 95, agricultural crop straw 0 ~ 10 and organic binder bond 4 ~ 10 by mass ratio, puddle evenly after, add an amount of moisture and mix thoroughly once more;
B, the resulting material of step a is pressed into spheroplast on shaper, afterwards the gained green-ball is dried in air naturally;
C, will put into charring furnace through natural air dried green-ball, be 400~700 ℃ in temperature, and carbonization time is to carry out charing under the condition of 90min~120min, again through cool off the coal derived fuel charcoal.
2. making method according to claim 1 is characterized in that: the granularity of bituminous coal described in the step a is less than 3mm; Described agricultural crop straw is to be crushed to particle diameter less than 3mm with pulverizer behind natural air drying; Described organic binder bond is a Sodium salts humic acids; The moisture of material is 14-16% before the moulding.
3. making method according to claim 1 is characterized in that: described shaper is a roller briquetting machine commonly used in the moulded coal industry.
4. making method according to claim 1 is characterized in that: described carbonization time contains the heating-up time.
CN 201010542089 2010-11-13 2010-11-13 A kind of preparation method of coal-based fuel charcoal Expired - Fee Related CN101967415B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925178A (en) * 2012-10-19 2013-02-13 西安建筑科技大学 Method for preparing iron alloy, calcium carbide and formed coke for gasification industry from low-metamorphic powdered coal
CN103466616A (en) * 2013-08-23 2013-12-25 宁夏宝塔石化科技实业发展有限公司 Preparation method for coal-based activated carbon for recovery of organic solvent
CN104694191A (en) * 2014-12-09 2015-06-10 山东大学 Gas-containing coal similar material and preparation method thereof
CN105316013A (en) * 2014-07-31 2016-02-10 宝山钢铁股份有限公司 Method for producing coke by replacing part of coal by sawdust
CN106190410A (en) * 2016-08-24 2016-12-07 太湖县享有新能源有限责任公司 A kind of straw biomass rod of combustion-supporting type desulfurization and preparation method thereof
CN104962334B (en) * 2015-06-16 2017-11-10 中南大学 A kind of agglomeration for iron mine biomass char hybrid fuel

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54146803A (en) * 1978-05-10 1979-11-16 Nippon Kokan Kk <Nkk> Production of metallurgical briquette coke
CN1337441A (en) * 2001-09-03 2002-02-27 李志远 Metallurgical coke briquette
CN1560195A (en) * 2004-03-12 2005-01-05 李玉林 Production method of formed coke using coking powder as row-material and special formed coke furnace
CN101139537A (en) * 2007-10-09 2008-03-12 赵宜文 High-temperature casting molded coal and method for producing the same
CN101550372A (en) * 2009-05-16 2009-10-07 山西中元煤洁净技术有限公司 Method for producing carbonized coal with coal material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54146803A (en) * 1978-05-10 1979-11-16 Nippon Kokan Kk <Nkk> Production of metallurgical briquette coke
CN1337441A (en) * 2001-09-03 2002-02-27 李志远 Metallurgical coke briquette
CN1560195A (en) * 2004-03-12 2005-01-05 李玉林 Production method of formed coke using coking powder as row-material and special formed coke furnace
CN101139537A (en) * 2007-10-09 2008-03-12 赵宜文 High-temperature casting molded coal and method for producing the same
CN101550372A (en) * 2009-05-16 2009-10-07 山西中元煤洁净技术有限公司 Method for producing carbonized coal with coal material

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925178A (en) * 2012-10-19 2013-02-13 西安建筑科技大学 Method for preparing iron alloy, calcium carbide and formed coke for gasification industry from low-metamorphic powdered coal
CN103466616A (en) * 2013-08-23 2013-12-25 宁夏宝塔石化科技实业发展有限公司 Preparation method for coal-based activated carbon for recovery of organic solvent
CN103466616B (en) * 2013-08-23 2015-11-04 宁夏宝塔石化科技实业发展有限公司 Preparation method for recovering coal-based activated carbon from organic solvents
CN105316013A (en) * 2014-07-31 2016-02-10 宝山钢铁股份有限公司 Method for producing coke by replacing part of coal by sawdust
CN105316013B (en) * 2014-07-31 2018-03-09 宝山钢铁股份有限公司 A kind of method that coal production coke in part is substituted using wood chip
CN104694191A (en) * 2014-12-09 2015-06-10 山东大学 Gas-containing coal similar material and preparation method thereof
CN104694191B (en) * 2014-12-09 2017-04-19 山东大学 Gas-containing coal similar material and preparation method thereof
CN104962334B (en) * 2015-06-16 2017-11-10 中南大学 A kind of agglomeration for iron mine biomass char hybrid fuel
CN106190410A (en) * 2016-08-24 2016-12-07 太湖县享有新能源有限责任公司 A kind of straw biomass rod of combustion-supporting type desulfurization and preparation method thereof

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