CN101967352B - Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof - Google Patents

Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof Download PDF

Info

Publication number
CN101967352B
CN101967352B CN2010102251519A CN201010225151A CN101967352B CN 101967352 B CN101967352 B CN 101967352B CN 2010102251519 A CN2010102251519 A CN 2010102251519A CN 201010225151 A CN201010225151 A CN 201010225151A CN 101967352 B CN101967352 B CN 101967352B
Authority
CN
China
Prior art keywords
parts
waterproof
asphalt
polymer
antifouling paint
Prior art date
Application number
CN2010102251519A
Other languages
Chinese (zh)
Other versions
CN101967352A (en
Inventor
段霓华
王政昌
曹海涛
徐靖
Original Assignee
北京立高科技股份有限公司
北京立高防水工程有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 北京立高科技股份有限公司, 北京立高防水工程有限公司 filed Critical 北京立高科技股份有限公司
Priority to CN2010102251519A priority Critical patent/CN101967352B/en
Publication of CN101967352A publication Critical patent/CN101967352A/en
Application granted granted Critical
Publication of CN101967352B publication Critical patent/CN101967352B/en

Links

Abstract

The invention relates to a corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and a preparation method thereof. The paint comprises the following components in parts by weight: 30 to 50 parts of 10# asphalt, 0.8 to 2 parts of soluble polytetrafluoroethylene resin, 3 to 4.5 parts of poval, 1 to 3 parts of cetyltrimethylammonium chloride, 3 to 12 parts of neoprene rubber latex, 2 to 6 parts of organic silicon milk, 5 to 20 parts of calcium carbonate superfine powder, 2 to 5 parts of mica superfine powder, 1 to 3 parts of hydroxymethyl cellulose, 0.3 to 0.7 part of defoaming agent and 80 to 120 parts of water. The corrosion-prevention, waterproof and antifouling paint containing polymer asphalt of the invention has the advantages of wide temperature adaptability, no flowing at the high temperature of 180 DEG C, no cracking at the low temperature of below 30 DEG C, good film forming toughness, short film forming time, shortened waterproof construction time, no sediment in use, clean film forming and easy washing.

Description

Polymer-asphalt is anticorrosion, waterproof, antifouling paint and preparation method thereof
Technical field
The present invention relates to a kind of building water-proof paint, particularly a kind of waterproof paint of polymer and asphalt and preparation method thereof.
Background technology
Building water-proof paint has easy construction, and to the adaptable characteristics of complex construction, consumption is very big in building operation.Waterproof paint is mainly used in buildings, and some possibly receive waterproof, protection against the tide and the antiseepage etc. of the structure position of water erosion.Therefore high-and low-temperature resistance performance, the antiseptic property to waterproof paint has certain requirement.
Existing building water-proof paint mainly contains polyurethane water-proof paint, polymer cement waterproof paint, pitch class waterproof paint and modifying asphalt class waterproof paint, waterproof paint of polymer and asphalt, silicon rubber waterproof coating etc.Wherein waterproof paint of polymer and asphalt is to be base-material with pitch, and admixture high molecular polymer rubber resin and auxiliary agent carry out modification and form water-emulsifying type waterproof coatings.Waterproof paint of polymer and asphalt has excellent waterproof property and performances such as well extension, cracking resistance, shearing resistance.
There is following problem in existing waterproof paint of polymer and asphalt:
1, erosion resistance, strong acid-base resistance salt poor performance.
2, not low temperature resistant, when temperature is lower than below-15 ℃, the situation of embrittlement can appear.
3, heat-resisting undesirable, trickling can appear when temperature surpasses 80 ℃.
4, not antifouling, because material deposition, be difficult for obtaining homogeneous thickness after making conjunctiva behind the coating lacquering.
Summary of the invention
The present invention provides that a kind of polymer-asphalt is anticorrosion, waterproof, antifouling paint and preparation method thereof, solve existing waterproof paint of polymer and asphalt corrosion-resistant, and thermal adaptability is bad, not antifouling technical problem.
The technical solution adopted for the present invention to solve the technical problems is:
This polymer-asphalt is anticorrosion, waterproof, antifouling paint, and in weight part, the proportioning of this coating is following:
10 #30~50 parts of pitches;
0.8~2 part of soluble poly tetrafluoroethylene resin;
3~4.5 parts of Z 150PH;
1~3 part of palmityl trimethyl ammonium chloride;
3~12 parts of polychloroprene latexs;
2~6 parts of organosilicon breasts;
5~20 parts of calcium carbonate superfine powders;
2~5 parts of ultra-fine mica powders;
1~3 part of Walocel MT 20.000PV;
0.3~0.7 part of skimmer;
80~120 parts in water.
In weight part, the best proportioning of this coating is following:
10 #40 parts of pitches;
1 part of soluble poly tetrafluoroethylene resin;
3.7 parts of Z 150PH;
2 parts of palmityl trimethyl ammonium chlorides;
6 parts of polychloroprene latexs;
4.5 parts of organosilicon breasts;
12.5 parts of calcium carbonate superfine powders;
3.3 parts of ultra-fine mica powders;
2 parts of Walocel MT 20.000PVs;
0.5 part of skimmer;
100 parts in water.
Said skimmer is silicone antifoam agent or tributyl phosphate.
Also be added with 1~3 part calcium chloride stablizer in the said prescription.
This polymer-asphalt is anticorrosion, the preparation method of waterproof, antifouling paint, and preparation process is following:
Step 1 is with 10 #Pitch is heated in reaction kettle to 200 ℃~230 ℃, and the dehydration back adds the soluble poly tetrafluoroethylene resin and stirred 1.5 hours;
Step 2 is mixed Z 150PH, palmityl trimethyl ammonium chloride, calcium carbonate superfine powder, ultra-fine mica powder, Walocel MT 20.000PV with water, under 70~90 ℃, stir;
Step 3, with the material of above-mentioned steps one and step 2 with colloidal mill 180 ℃ of following ground and mixed 30 minutes;
Step 4 adds polychloroprene latex, organosilicon breast and skimmer and mixes in the material that step 3 mixes, obtain that polymer-asphalt is anticorrosion, waterproof, antifouling paint finished product.
Said skimmer can add half the when the improved grinding of step 3, in the lacquering process of step 4, adds second half.
Beneficial effect of the present invention is following:
The present invention has been owing to added the soluble poly tetrafluoroethylene resin, makes coating have low temperature resistant, alkali resistance and acidity, and has good corrosion resistance.
The present invention adopts organic silicon emulsion and neoprene latex to cooperate as the composite membrane-forming material, and film-forming is fast, the film forming good toughness, and the short period of time is a film forming, can shorten the waterproof construction time.
The present invention has used nano material calcium carbonate superfine powder and ultra-fine mica powder as filler; Can improve coating; The glossiness of paint can form the space multistory structure simultaneously in filming, can play the raising material and pretend usefulness outward; The material deposition that density is bigger in preventing to fill a prescription, the snappiness and the leveling characteristics of increase coating, thus reach self-cleaning purpose.
The present invention is following through the PT detected result:
1, product has broad thermal adaptability, under 180 ℃ high temperature, does not trickle, and is non-foaming, not delamination; Low temperature at-30 ℃ does not ftracture.
2, cohesive force is strong, and integral waterproofing property is strong.
3, acid resistance: use 10%H 2SO 428 days no changes of solution soaking.
4, alkali resistance: with 28 days no changes of NaOH solution soaking.
10, nonflammable, extinguish immediately in the fire insulation source.
11, product does not have deposition, and film forming is self-cleaning, is prone to clean.
Embodiment
Embodiment one, and this polymer-asphalt is anticorrosion, waterproof, antifouling paint, and in weight part, the best proportioning of this coating is following:
10 #40 parts of pitches;
1 part of soluble poly tetrafluoroethylene resin;
3.7 parts of Z 150PH;
2 parts of palmityl trimethyl ammonium chlorides;
6 parts of polychloroprene latexs;
4.5 parts of organosilicon breasts;
12.5 parts of calcium carbonate superfine powders;
3.3 parts of ultra-fine mica powders;
2 parts of Walocel MT 20.000PVs;
0.5 part of silicone antifoam agent;
100 parts in water.
Embodiment two, and this polymer-asphalt is anticorrosion, waterproof, antifouling paint, and in weight part, the best proportioning of this coating is following:
10 #50 parts of pitches;
2 parts of soluble poly tetrafluoroethylene resins;
3 parts of Z 150PH;
3 parts of palmityl trimethyl ammonium chlorides;
10 parts of polychloroprene latexs;
6 parts of organosilicon breasts;
20 parts of calcium carbonate superfine powders;
2 parts of ultra-fine mica powders;
2 parts of Walocel MT 20.000PVs;
0.6 part of tributyl phosphate;
120 parts in water.
Embodiment three, and this polymer-asphalt is anticorrosion, waterproof, antifouling paint, and in weight part, the proportioning of this coating is following:
10 #30 parts of pitches;
1 part of soluble poly tetrafluoroethylene resin;
3 parts of Z 150PH;
1 part of palmityl trimethyl ammonium chloride;
3 parts of polychloroprene latexs;
3 parts of organosilicon breasts;
5 parts of calcium carbonate superfine powders;
2 parts of ultra-fine mica powders;
1 part of Walocel MT 20.000PV;
0.3 part of silicone antifoam agent;
80 parts in water.
Embodiment four, and this polymer-asphalt is anticorrosion, waterproof, antifouling paint, and in weight part, the proportioning of this coating is following:
10 #45 parts of pitches;
1.8 parts of soluble poly tetrafluoroethylene resins;
4 parts of Z 150PH;
2 parts of palmityl trimethyl ammonium chlorides;
12 parts of polychloroprene latexs;
4 parts of organosilicon breasts;
13 parts of calcium carbonate superfine powders;
5 parts of ultra-fine mica powders;
3 parts of Walocel MT 20.000PVs;
0.5 part of silicone antifoam agent;
2 parts of calcium chloride stablizers;
110 parts in water.
Polymer-asphalt in the foregoing description is anticorrosion, the preparation method of waterproof, antifouling paint, and preparation process is following:
Step 1 is with 10 #Pitch is heated in reaction kettle to 200 ℃~230 ℃, and the dehydration back adds the soluble poly tetrafluoroethylene resin and stirred 1.5 hours;
Step 2 is mixed Z 150PH, palmityl trimethyl ammonium chloride, calcium carbonate superfine powder, ultra-fine mica powder, Walocel MT 20.000PV with water, under 70~90 ℃, stir;
Step 3, with the material of above-mentioned steps one and step 2 with colloidal mill 180 ℃ of following ground and mixed 30 minutes;
Step 4 adds polychloroprene latex, organosilicon breast and skimmer and mixes in the material that step 3 mixes, obtain that polymer-asphalt is anticorrosion, waterproof, antifouling paint finished product.
Said skimmer also can add half the when the improved grinding of step 3, in the lacquering process of step 4, adds second half.

Claims (5)

1. anticorrosion, the waterproof of a polymer-asphalt, antifouling paint, it is characterized in that: in weight part, the proportioning of this coating is following:
10 #30~50 parts of pitches;
0.8~2 part of soluble poly tetrafluoroethylene resin;
3~4.5 parts of Z 150PH;
1~3 part of palmityl trimethyl ammonium chloride;
3~12 parts of polychloroprene latexs;
2~6 parts of organosilicon breasts;
5~20 parts of calcium carbonate superfine powders;
2~5 parts of ultra-fine mica powders;
1~3 part of Walocel MT 20.000PV;
0.3~0.7 part of skimmer;
80~120 parts in water.
2. polymer-asphalt according to claim 1 is anticorrosion, waterproof, antifouling paint, and it is characterized in that: in weight part, the best proportioning of this coating is following:
10 #40 parts of pitches;
1 part of soluble poly tetrafluoroethylene resin;
3.7 parts of Z 150PH;
6 parts of polychloroprene latexs;
4.5 parts of organosilicon breasts;
2 parts of palmityl trimethyl ammonium chlorides;
12.5 parts of calcium carbonate superfine powders;
3.3 parts of ultra-fine mica powders;
2 parts of Walocel MT 20.000PVs;
0.5 part of skimmer;
100 parts in water.
3. polymer-asphalt according to claim 1 is anticorrosion, waterproof, antifouling paint, and it is characterized in that: said skimmer is silicone antifoam agent or tributyl phosphate.
4. anticorrosion, the waterproof of a polymer-asphalt, antifouling paint, it is characterized in that: in weight part, the proportioning of this coating is following:
10 #30~50 parts of pitches;
0.8~2 part of soluble poly tetrafluoroethylene resin;
3~4.5 parts of Z 150PH;
1~3 part of palmityl trimethyl ammonium chloride;
3~12 parts of polychloroprene latexs;
2~6 parts of organosilicon breasts;
5~20 parts of calcium carbonate superfine powders;
2~5 parts of ultra-fine mica powders;
1~3 part of Walocel MT 20.000PV;
0.3~0.7 part of skimmer;
80~120 parts in water;
1~3 part of calcium chloride stablizer.
5. the preparation method of a, waterproof anticorrosion like any described polymer-asphalt of claim 1~3, antifouling paint is characterized in that preparation process is following:
Step 1 is with 10 #Pitch is heated in reaction kettle to 200 ℃~230 ℃, and the dehydration back adds the soluble poly tetrafluoroethylene resin and stirred 1.5 hours;
Step 2 is mixed Z 150PH, palmityl trimethyl ammonium chloride, calcium carbonate superfine powder, ultra-fine mica powder, Walocel MT 20.000PV with water, under 70~90 ℃, stir;
Step 3, with the material of above-mentioned steps one and step 2 with colloidal mill 180 ℃ of following ground and mixed 30 minutes;
Step 4 adds polychloroprene latex, organosilicon breast and skimmer and mixes in the material that step 3 mixes, obtain that polymer-asphalt is anticorrosion, waterproof, antifouling paint finished product.
CN2010102251519A 2010-07-13 2010-07-13 Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof CN101967352B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102251519A CN101967352B (en) 2010-07-13 2010-07-13 Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102251519A CN101967352B (en) 2010-07-13 2010-07-13 Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof

Publications (2)

Publication Number Publication Date
CN101967352A CN101967352A (en) 2011-02-09
CN101967352B true CN101967352B (en) 2012-08-29

Family

ID=43546580

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010102251519A CN101967352B (en) 2010-07-13 2010-07-13 Corrosion-prevention, waterproof and antifouling paint containing polymer asphalt and preparation method thereof

Country Status (1)

Country Link
CN (1) CN101967352B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102775910A (en) * 2012-08-06 2012-11-14 启东安升润液设备有限公司 Water-resistant corrosion-resistant and anti-rust clear lacquer
CN103045030B (en) * 2012-12-16 2015-11-18 青岛文创科技有限公司 A kind of waterproof paint
CN103396707B (en) * 2013-07-09 2015-07-08 贵州省复合改性聚合物材料工程技术研究中心 Color-adjusting spraying rapid-hardening liquid rubber waterproof material and using method thereof
CN103627260B (en) * 2013-10-22 2016-02-24 江苏博思源防火材料科技有限公司 Exterior coating of a kind of waterproof heat resistant and preparation method thereof
CN104293184A (en) * 2014-09-16 2015-01-21 天长市银狐漆业有限公司 Heat-resistant and sun-proof fiber asphalt paint and preparation method thereof
CN105086640A (en) * 2015-08-05 2015-11-25 天长市巨龙车船涂料有限公司 Waterproof neoprene latex coating
CN106065288A (en) * 2016-07-19 2016-11-02 董芬芳 A kind of metal water-repellent preservation antirusting paint
CN106147597A (en) * 2016-08-01 2016-11-23 太仓顺如成建筑材料有限公司 A kind of ground waterproof coating
CN107083191A (en) * 2017-05-11 2017-08-22 冯智勇 A kind of super-hydrophobic self-cleaning asphalt caulk for having lotus leaf effect

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1267695A (en) * 2000-04-14 2000-09-27 天津市禹王防水公司 Waterproof paint specially for bridge surface
CN101525514A (en) * 2009-04-07 2009-09-09 沈福昌 Resin anti-corrosive paint
RU90527U1 (en) * 2008-10-14 2010-01-10 Талгат Вилевич Галиуллин Roll anti-corrosion material (options)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1267695A (en) * 2000-04-14 2000-09-27 天津市禹王防水公司 Waterproof paint specially for bridge surface
RU90527U1 (en) * 2008-10-14 2010-01-10 Талгат Вилевич Галиуллин Roll anti-corrosion material (options)
CN101525514A (en) * 2009-04-07 2009-09-09 沈福昌 Resin anti-corrosive paint

Also Published As

Publication number Publication date
CN101967352A (en) 2011-02-09

Similar Documents

Publication Publication Date Title
CN105713472B (en) Aqueous damping coating and preparation method thereof with microcosmic constrained damping structure
CN103409033B (en) Conductive anticorrosive coating and preparation method thereof
CN105838195B (en) A kind of water corrosion-resistant epoxy paint and preparation method thereof containing graphene oxide
CN103305041B (en) Modified water-soluble inorganic zinc coating and preparation method thereof
CN101747825B (en) Environment-friendly solvent-free humidified and rusted anticorrosive paint
CN100383205C (en) Anticorrosive waterproof nano industrial coating and its preparing method
CN102977553B (en) Epoxy/silicone polymer composite material, and preparation method and application thereof
CN104109439B (en) True mineral varnish of a kind of insulation and preparation method thereof
CN101195724B (en) Surface insulation varnish paint for wind power generation and method for producing the same
CN101698754B (en) Low-temperature curing temperature-resistant heavy-duty anticorrosive paint
CN104230240A (en) Flexible cement-base waterproof coating and preparation and application methods thereof
CN100584911C (en) High temperature resistant anti-corrosion modified epoxy silicone coating
CN102898926A (en) High temperature-resistant and wear-resistant heavy-duty anticorrosive paint and preparation method thereof
CN104909662A (en) Double-component polymer-cement-base waterproof mortar and preparation method thereof
CN105694550B (en) The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology
CN100537687C (en) SBS elastic waterproof paint and its preparation
CN102382553A (en) Solvent-free epoxy primer for high temperature corrosion prevention of steel pipeline welded junction position
CN103059304A (en) Preparation and application of long-acting anticorrosion temperature-resistant coating
CN102492338B (en) Elastic heat-insulation fluorocarbon coating and preparation method and use method thereof
CN105860761A (en) Epoxy polysiloxane graphene heavy-duty anticorrosion coating and preparation method
CN104789100B (en) A kind of aqueous polyurethane moisture-proof anticorrosive coating and preparation method thereof
CN102731052A (en) Aqueous organic-inorganic composite coating and preparation method thereof
CN102701662A (en) Two-component cement-based polymer rigid waterproof mortar
CN102408220A (en) All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof
CN104497868A (en) Graphene waterproof paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
RINS Preservation of patent right or utility model and its discharge
PP01 Preservation of patent right

Effective date of registration: 20140408

Granted publication date: 20120829

RINS Preservation of patent right or utility model and its discharge
PD01 Discharge of preservation of patent

Date of cancellation: 20141008

Granted publication date: 20120829

EXPY Termination of patent right or utility model
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120829

Termination date: 20150713