CN101962271A - Golden coated glass and preparation process thereof - Google Patents

Golden coated glass and preparation process thereof Download PDF

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CN101962271A
CN101962271A CN 201010203798 CN201010203798A CN101962271A CN 101962271 A CN101962271 A CN 101962271A CN 201010203798 CN201010203798 CN 201010203798 CN 201010203798 A CN201010203798 A CN 201010203798A CN 101962271 A CN101962271 A CN 101962271A
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glass
body
layer
coated
golden
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CN 201010203798
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张元胜
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张元胜
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Abstract

The invention relates to the technical field of vacuum coating, in particular to golden coated glass and a preparation method thereof. The golden coated glass comprises a glass body and a metal film layer coated on the glass body, wherein the metal film layer consists of there layers of metal films which are an argon-copper contained inner layer, an argon-titanium contained middle layer and a nitrogen-titanium contained outer layer in sequence outwards from the outer surface of the glass body. The interior and the exterior of the glass body both present golden color, and the glass body has the advantages of attractive appearance, high hardness, good scrape resistance, no decoloring or fading in harsh environments of high temperature, alcohol, and the like, and low preparation cost.

Description

一种金色镀膜玻璃及其制备工艺 Gold coated glass and one kind of preparation

技术领域 FIELD

[0001] 本发明涉及真空镀膜技术领域,特别是涉及一种金色镀膜玻璃及其制备工艺。 [0001] The present invention relates to vacuum coating technology, and more particularly, to a golden glass and its preparation process. 背景技术 Background technique

[0002] 金色玻璃制品体现富贵表现奢华,因而备受人们的喜爱。 [0002] Golden glass products reflect the performance of rich luxury, so much loved by the people. 目前我国在玻璃制品中做到玻璃表面金色效果的工艺有两种:一种为先用工业软水清洗玻璃制品表面,之后用干净的空气吹玻璃制品表面水分,并烘干水分,接着慢慢的降下玻璃制品的温度到室温,然后用人工用毛笔沾上含3%〜15%左右真金的黄金水画出各种各样的图案与人物等,最后将画上真黄金水的玻璃制品用300〜550°C左右度的温度烤30〜60左右分钟拿出,制得成品。 Currently the gold surface of glass to achieve the effect of the glass article in the process are two: one for the first soft water surface cleaning glass industry, blown glass article after the surface moisture with clean air, water and dried, and then slowly lowering the temperature of the glass article with the glass article to room temperature and then stained gold manually with a brush containing ~ 15% water, 3% gold and drawn variety of patterns such as a person, and finally the gold water aiming Videos of about 300~550 ° C temperature and bake for about 30~60 minutes out, to obtain the finished product. 另一种为先用工业软水清洗玻璃制品表面,接着用干净的空气吹玻璃制品表面水分,并烘干水分,慢慢降下玻璃制品的温度到室温,接着在玻璃制品的表面用转印技术印上无机水容性油漆做上图案,然后拿去喷一层塑脂油漆,再烘烤60〜90左右分钟拿出,接着用真空蒸发镀铝机在产品表面真空电镀上一层99. 9%的铝层,接着用塑脂油漆在里面加上色浆调出仿真黄金颜色在已真空镀铝好的产品表面喷上一层塑脂油漆、最后用70°C左右度的温度烤60〜90左右分钟取出制得成品。 Another is the cleaning of the surface of the glass article with soft water industry, clean air is then blown glass article with a surface moisture, water and dried, and slowly lowering the temperature of the glass article to room temperature, and then the surface of the glass article in a transfer printing technique inorganic water paint cook capacitive pattern layer of plastic resin and then take the paint spray, about 60~90 minutes and baked out, followed by vacuum aluminum evaporation layer on the surface of the product machine vacuum plating 99.9% aluminum layer, followed by paint on the inside with plastic resin paste gold color tone of the simulation plastic resin layer of paint on the surface of the product has a good spray aluminum vacuum, and finally a temperature of about 70 ° C 60~90 roast remove about minutes to obtain the finished product.

[0003] 上述两种工艺与都是在玻璃表面上做上各种各样的金黄色的图案,以起到装饰效果。 [0003] Both processes are to cook various golden pattern on the glass surface, to act as a decorative effect. 但是仍存在一些不足,第一种,由于使用真黄金,价格昂贵,成本较高,一般普通人员很难消费得起;第二种,由于制备过程中要使用到塑脂油漆,一方面由于油漆本身含有一些卤素或是重金属,对环境、对人体不友好,另一方面,所制得的成品,其表面金色层的硬度太小,很容易刮擦掉,且对酒精的耐受程度不高,限制了其应用范围,比如不能用作酒杯、酒瓶 But there are still some shortcomings, first, the use of real gold, expensive, high cost, difficult for ordinary consumer can afford; the second, due to the preparation process, we need to use plastic resin paint, on the one hand due to the paint itself contains a number of heavy metals or halogens, to the environment, human friendly, on the other hand, the obtained finished product, the surface hardness of the gold layer is too small, it is easy scraping off, and the degree is not high tolerance to alcohol , limiting its scope of application, such glasses can not be used, the bottle

发明内容 SUMMARY

[0004] 本发明的目的之一在于,提供一种耐高温、耐刮擦、耐酒精的金色镀膜玻璃。 [0004] One object of the present invention is to provide a high temperature resistance, scratch resistance, golden glass alcohol.

[0005] 本发明的目的之二在于,提供所述金色镀膜玻璃的其制备工艺。 [0005] Second object of the present invention is to provide a preparation process of the golden glass.

[0006] 本发明是通过以下技术方案来实现的: [0006] The present invention is achieved by the following technical solution:

[0007] —种金色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、钛夹膜和钛外膜。 [0007] - species golden glass, comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, three metal layers successively endometrial copper, titanium, and a titanium film clip adventitia.

[0008] 其中,所述铜内膜为在99. 9%以上氩气保护气体下,用真空多弧离子机镀在玻璃本体上的80%〜99. 999%的黄铜,铜内膜的厚度为0. 0005mm〜0. 08mm。 [0008] wherein, in the copper lining is 99.9% or more under the protection of argon gas, 80% ~99 plating 999% of the brass body in the glass by a vacuum arc ion machine, copper endocardium thickness of 0. 0005mm~0. 08mm.

[0009] 所述钛夹膜为在99. 9%以上氩气保护气体下,用真空多弧离子机镀在玻璃本体上的99. 9%〜99. 999%的钛,钛夹膜的厚度为0. 0005mm〜0. 08mm。 [0009] The thickness of the titanium film is sandwiched under argon gas over 99.9%, by vacuum arc ion plating machine ~99 99.9% 999% titanium on the glass body, the titanium film clip is 0. 0005mm~0. 08mm. 为了增加外观的丰富度, 钛夹膜层也可以用纯银替代,利用银对光的反射,能增加最终成品的美观度,使镀品色彩鲜艳、富丽堂皇。 In order to increase the appearance of richness, titanium clip silver film layer may be used alternatively, using a silver light reflection, can increase the aesthetics of the finished product, so colorful plating products, magnificent.

[0010] 所述钛外膜为99. 9%〜99. 999%的钛,钛夹膜的厚度为0. 0005mm〜0. 08mm。 [0010] The outer membrane was 99.9% titanium ~99 999% titanium, titanium clip film thickness of 0. 0005mm~0. 08mm.

3[0011] 所述钛外膜为复合膜,由按重量百分比计的钛和铁组成,其中钛为90%〜99%, 铁为〜10%。 3 [0011] The outer membrane is a composite film of titanium, the percentage by weight of titanium and iron, wherein the titanium is 90% ~99%, ~ 10% iron.

[0012] 所述钛外膜为在99. 9%以上氮气保护气体下,用真空多弧离子机镀在玻璃本体上的。 [0012] The outer membrane is a titanium at 99.9% or more nitrogen gas, a vacuum dryer multi-arc ion plating on the glass body.

[0013] 金色镀膜玻璃的制备方法,制备步骤如下, [0013] Preparation of golden glass, the following preparation steps,

[0014] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0014] a step of cleaning, the glass body was washed with industrial soft water;

[0015] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0015] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0016] 步骤三、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX ICT1〜1.0X10_3pa内;充氩气,使操作室内的气压保持在1. 0X10° 〜1. 0Xl(T3pa 内; [0016] Step three, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating air pressure is maintained within chamber 1. OX ICT1~1.0X10_3pa; argon gas, so that operating pressure in the chamber is maintained at 1. 0X10 ° ~1 0Xl (T3pa inside.;

[0017] 步骤四、释放铜靶,镀铜内膜层,温度控制在100〜400°C ; [0017] Step 4 releasing copper target, copper intimal layer, temperature controlled at 100~400 ° C;

[0018] 步骤五、保持操作室内氩气的气压在1. 0X10°〜1. 0X10_3pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在100〜400°c ; [0018] Step 5 holding the operating pressure in the argon chamber 1. 0X10 ° ~1 within 0X10_3pa;. Close a copper target, the release of the titanium target, titanium film clip, the temperature control at 100~400 ° c;

[0019] 步骤六、真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10°〜 1.0X10-3pa内,释放钛靶,镀钛外膜层,温度控制在100〜400 °C ; [0019] Step 6 vacuo deprived argon, purged with nitrogen, the nitrogen pressure holding operation in the indoor 1.0X10 ° ~ 1.0X10-3pa, releasing titanium target, titanium outer film layer, the temperature control at 100~400 ° C ;

[0020] 步骤七、将镀了三次金属膜层的玻璃本体冷却至常温,制得成品。 [0020] Step seven, three bulk glass plated metal film is cooled to room temperature to obtain the finished product. 其中,所述步骤六中,真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10°〜1.0X10_3pa内,关闭钛靶,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在100〜400°C。 Wherein said step six, the vacuum deprived argon, purged with nitrogen, keeping the air in the operating room nitrogen 1.0X10 ° ~1.0X10_3pa, close the titanium target, a titanium and iron release composition obtained target compound, titanium an outer film layer, the temperature control at 100~400 ° C.

[0021] 所述步骤二和步骤三之间增加了画隔离的步骤,相应步骤七中将镀了三次金属膜层的玻璃本体冷却至常温后,也要增加清洗隔离的步骤; [0021] The two step drawing step and the step increases the isolation between the three, seven in the respective steps after the plated metal film of three glass body was cooled to room temperature, the washing step should be increased isolation;

[0022] 所述的画隔离步骤为:在玻璃上不需要镀金色膜处,涂上用双飞粉做成的速干型隔离粉; [0022] The isolation step is painted: no gold-plated film on glass at a Flying coated powder powder made of quick-drying type isolation;

[0023] 所述的清洗隔离步骤为:用水冲洗掉隔离层。 [0023] The isolation step of washing: rinse off the isolation layer.

[0024] 可调节工艺制备出的全是金色的玻璃制品或者是金色与玻璃本色相间,且有一定图案的玻璃制品。 [0024] The process may be adjusted to prepare the whole glass article is gold or gold qualities of the glass phase, and there is a pattern of the glass article.

[0025] 本发明包括玻璃本体和镀在玻璃本体上的金属膜层;金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为加氩铜内膜、加氩钛夹膜和加氮钛外膜。 [0025] The present invention comprises a glass body and a plating metal film layer on a glass body; a metal layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, followed by a three-layer metal film of copper intima plus argon , argon plus nitrogen and processing the titanium film interposed titanium adventitia. 本发明不仅色彩鲜艳,而且制作成本低廉;尤其是一方面,由于最内层是铜膜层,且铜膜是在纯氩气氛围下镀的,所以使得本发明从玻璃制品内部看上去,是透明的玻璃本色加金色,而不是以往那样,只有外表面是金色,其内侧则是黑色的,大大提高了产品的档次和美观度;另一方面,由于最外层是纯钛或含铁的钛复合在在纯氮气氛围下镀,由于化学反应,使得原本银灰色的钛变成金色或金红色;且经过本发明所述工艺制备出来的成品,经检测具有如下优点: The present invention is not colorful, and low production cost; particular aspect, since the innermost layer is a copper layer, and the plated copper film in the pure argon gas atmosphere, so that the present invention appear from the interior of the glass article, is transparent glass qualities plus gold, and not, as conventional, only the outer surface is gold, the inside of which is black, greatly improving the quality and appearance of the product; the other hand, since the outermost layer is a titanium or iron in pure titanium composite under a nitrogen atmosphere plating, chemical reaction, so that the original gold silver or gold into titanium red; and finished products prepared therefrom through the process of the invention, the detection has the following advantages:

[0026] 1、耐高温,在150〜200°C高温下2〜4个小时不会脱色褪色掉色; [0026] 1, high temperature in 2 ~ 4 hours at 150~200 ° C temperature does not fade decolorization fade;

[0027] 2、硬度高,耐刮擦,金属器具刮擦200下,不褪色掉色,无划痕; [0027] 2, high hardness, scratch resistance, scratching the metal fixture 200, not fade fade, no scratches;

[0028] 3、耐酒精腐蚀,将制品置于浓度为100%的乙醇中浸泡24小时,取出擦拭,不褪色掉色。 [0028] 3, corrosion resistance to alcohol, the article is placed concentration of 100% ethanol for 24 hours, remove the wipe, fade fade.

[0029] 说明书附图 [0029] The accompanying drawings

[0030] 图1为本发明的制备工艺流程图。 [0030] FIG. 1 process flow diagram of the present invention was prepared. [0031] 具体的实施方式 [0031] The specific embodiment

[0032] 下面结合具体实施方式对本发明作进一步的详细说明,以助于本领域技术人员理解本发明。 [0032] DETAILED DESCRIPTION The following embodiments of the present invention will be further described in detail, those skilled in the art to assist in understanding the present invention.

[0033] 实施例1 [0033] Example 1

[0034] 一种全金色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯钛夹膜和纯钛外膜。 [0034] An all golden glass, comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, the outer surface of the glass of the present reference outwardly, three layers of metal film layer followed endometrial copper, titanium and titanium capsular adventitia.

[0035] 制备方法,制备步骤如下, Preparation [0035] The method of preparing the following steps,

[0036] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0036] a step of cleaning, the glass body was washed with industrial soft water;

[0037] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0037] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0038] 步骤三、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX 10_3pa内;充99. 9%以上的纯氩气,使操作室内的气压保持在1. OXliT1Pa 内; [0038] Step three, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating air pressure is maintained within chamber 1. OX 10_3pa; charge of more than 99.9% pure argon gas, so that the operation is maintained within the pressure chamber 1. OXliT1Pa;

[0039] 步骤四、释放铜靶,镀铜内膜层,温度控制在120°C ; [0039] Step 4 releasing copper target, copper intimal layer, the temperature control at 120 ° C;

[0040] 步骤五、保持操作室内氩气的气压在1. OX 10_2pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在280°C ; [0040] Step 5 holding the operating pressure in the argon chamber 1. the OX 10_2pa; off a copper target, the release of the titanium target, titanium film clip, temperature controlled at 280 ° C;

[0041] 步骤六、真空抽掉氩气,充99. 9%氮气,保持操作室内氮气的气压在1.0X10_3pa 内,释放钛靶,镀钛外膜层,温度控制在350°C ; [0041] Step 6 vacuo deprived of argon, 99.9% nitrogen charge, maintaining the nitrogen pressure in the operating room within 1.0X10_3pa, releasing titanium target, titanium outer film layer, the temperature control at 350 ° C;

[0042] 步骤七、将镀了三次金属膜层的玻璃本体冷却至常温,制得整体全为金色的玻璃制品成品。 [0042] Step seven, three bulk glass plated metal film is cooled to room temperature to obtain a golden glass full overall product yield.

[0043] 实施例2 [0043] Example 2

[0044] 一种部分金色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯钛夹膜和纯钛外膜。 [0044] A portion of the golden glass, comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, the outer surface of the glass of the present reference outwardly, three layers of metal film layer followed endometrial copper, titanium and titanium capsular adventitia.

[0045] 制备方法,制备步骤如下, Preparation [0045] The method of preparing the following steps,

[0046] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0046] a step of cleaning, the glass body was washed with industrial soft water;

[0047] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0047] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0048] 步骤三、画隔离,在玻璃上不需要镀金色膜处,涂上用双飞粉做成的速干型隔离粉; [0048] Step three, draw isolation, need not gold-plated on glass at the membrane, coated with a powder made of quick-drying Flying isolate powder;

[0049] 步骤四、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1.0 Xicrfpa内;充99.9%以上的纯氩气,使操作室内的气压保持在1. 0X10_2pa 内; [0049] Step four, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating pressure in the chamber is maintained within 1.0 Xicrfpa; charge of 99.9% pure argon gas, so that operating pressure is maintained within chamber 1. 0X10_2pa;

[0050] 步骤五、释放铜靶,镀铜内膜层,温度控制在320°C ; [0050] Step 5 is released copper target, copper intimal layer, temperature controlled at 320 ° C;

[0051] 步骤六、保持操作室内氩气的气压在1.0X10° pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在400°C ; [0051] Step six, holding operating room argon gas pressure within 1.0X10 ° pa; off a copper target, the release of the titanium target, titanium clip film temperature was controlled at 400 ° C;

[0052] 步骤七、真空抽掉氩气,充99. 9%氮气,保持操作室内氮气的气压在l.OXliTpa 内,释放钛靶,镀钛外膜层,温度控制在180°C ; [0052] Step 7 vacuo deprived of argon, 99.9% nitrogen charge, maintaining the nitrogen pressure in the operating room within l.OXliTpa, releasing titanium target, titanium outer film layer, temperature was controlled at 180 ° C;

[0053] 步骤八、将镀了三次金属膜层的玻璃本体冷却至常温,用水冲洗掉隔离层。 [0053] Step eight, three bulk glass plated metal film is cooled to room temperature, rinse off the isolation layer. 制作出来的是金色与玻璃本色(或其他颜色)相间的,且有一定图案的玻璃制品。 It is made out of gold and glass gray (or other color) and white, and a pattern of the glass article.

5[0054] 实施例3 5 [0054] Example 3

[0055] 一种全金红色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯钛夹膜和钛复合外膜;所述钛复合外膜中纯钛占99% (重量),铁占(重量)。 [0055] An all red gold coated glass comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, three metal film endometrial layer are copper, titanium and titanium composite outer membrane capsular; titanium in the titanium complex adventitia 99% (by weight), iron comprises (by weight).

[0056] 制备方法,制备步骤如下, Preparation [0056] The method of preparation steps,

[0057] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0057] a step of cleaning, the glass body was washed with industrial soft water;

[0058] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0058] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0059] 步骤三、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX 10_2pa内;充99. 9%以上的纯氩气,使操作室内的气压保持在1. OXlCTpa 内; [0059] Step three, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating air pressure is maintained within chamber 1. OX 10_2pa; charge of more than 99.9% pure argon gas, so that the operation is maintained within the pressure chamber 1. OXlCTpa;

[0060] 步骤四、释放铜靶,镀铜内膜层,温度控制在300°C ; [0060] Step 4 releasing copper target, copper intimal layer, temperature controlled at 300 ° C;

[0061] 步骤五、保持操作室内氩气的气压在l.OXliTpa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在200°C ; [0061] Step 5 holding operation of the indoor argon gas pressure within l.OXliTpa; off a copper target, the release of the titanium target, titanium film clip, the temperature control at 200 ° C;

[0062] 步骤六、真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10_3pa内,关闭钛靶,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在200°C ; [0062] Step 6 vacuo deprived argon, purged with nitrogen, keeping the air in the operating room nitrogen 1.0X10_3pa, close the titanium target, a titanium and iron release composition obtained target compound, titanium outer film layer, temperature control at 200 ° C;

[0063] 步骤七、将镀了三次金属膜层的玻璃本体冷却至常温,制得整体全为金红色的玻璃制品成品。 [0063] Step seven, three bulk glass plated metal film layer cooled to ordinary temperature, to obtain the overall red and gold are all finished glass article.

[0064] 实施例4 [0064] Example 4

[0065] 一种全金红色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯钛夹膜和钛复合外膜;所述钛复合外膜中,纯钛占90% (重量),铁占10% (重量)。 [0065] An all red gold coated glass comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, three metal film endometrial layer are copper, titanium and titanium composite outer membrane capsular; the outer membrane complex of titanium, titanium 90% (by weight), iron comprises (by weight) of 10%.

[0066] 制备方法,制备步骤如下, Preparation [0066] The method of preparation steps,

[0067] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0067] a step of cleaning, the glass body was washed with industrial soft water;

[0068] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0068] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0069] 步骤三、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX KT1pa内;充99. 9%以上的纯氩气,使操作室内的气压保持在1. 0X10° pa 内; [0069] Step three, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating pressure in the chamber is maintained at 1. OX within KT1pa; charge of more than 99.9% pure argon, the operator remains in the pressure chamber 1. 0X10 ° pa;

[0070] 步骤四、释放铜靶,镀铜内膜层,温度控制在100°C ; [0070] Step 4 releasing copper target, copper intimal layer, the temperature control at 100 ° C;

[0071] 步骤五、保持操作室内氩气的气压在1.0X10° pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在100°C ; [0071] Step 5 holding operation of the indoor argon gas pressure within 1.0X10 ° pa; off a copper target, the release of the titanium target, titanium film clip, the temperature control at 100 ° C;

[0072] 步骤六、真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10° pa内,关闭钛靶,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在100°C ; [0072] Step 6 vacuo deprived argon, purged with nitrogen, keeping the air in the operating room nitrogen 1.0X10 ° pa, close the titanium target, a titanium and iron release composition obtained target compound, titanium outer film layer, temperature was controlled at 100 ° C;

[0073] 步骤七、将镀了三次金属膜层的玻璃本体冷却至常温,制得整体全为金红色的玻璃制品成品。 [0073] Step seven, three bulk glass plated metal film layer cooled to ordinary temperature, to obtain the overall red and gold are all finished glass article.

[0074] 实施例5 [0074] Example 5

[0075] —种部分金红色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯钛夹膜和钛复合外膜;所述钛复合外膜中,纯钛占97% (重量),铁占3% (重量)。 [0075] - red part of the gold species coated glass comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, three metal film endometrial layer are copper, titanium and titanium composite outer membrane capsular; the outer membrane complex of titanium, titanium 97% (by weight), iron comprises (by weight) 3%.

[0076] 制备方法,制备步骤如下,[0077] 步骤一、清洗,将玻璃本体用工业软水进行清洗; Preparation [0076] The method of preparation steps are as follows, [0077] a step of cleaning, the glass body was washed with industrial soft water;

[0078] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0078] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0079] 步骤三、画隔离,在玻璃上不需要镀金色膜处,涂上用双飞粉做成的速干型隔离粉; [0079] Step three, draw isolation, need not gold-plated on glass at the membrane, coated with a powder made of quick-drying Flying isolate powder;

[0080] 步骤四、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX 10_3pa内;充99. 9%以上的纯氩气,使操作室内的气压保持在1. 0Xl(T3pa 内; [0080] Step four, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating air pressure is maintained within chamber 1. OX 10_3pa; charge of more than 99.9% pure argon and held at the operating pressure in the chamber 1. 0Xl (T3pa inside;

[0081] 步骤五、释放铜靶,镀铜内膜层,温度控制在400°C ; [0081] Step 5 is released copper target, copper intimal layer, temperature was controlled at 400 ° C;

[0082] 步骤六、保持操作室内氩气的气压在1. OX 10_3pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在400°C ; [0082] Step six, holding operating room argon gas pressure in the 1 OX 10_3pa; off a copper target, the release of the titanium target, titanium clip film temperature was controlled at 400 ° C;

[0083] 步骤七、真空抽掉氩气,充99. 9%氮气,保持操作室内氮气的气压在1.0X10_3pa 内,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在400°C ; [0083] Step 7 vacuo deprived of argon, 99.9% nitrogen charge, maintaining the nitrogen pressure in the operating room 1.0X10_3pa, released from a composite target of titanium and iron compositions obtained, an outer titanium film, temperature control at 400 ° C;

[0084] 步骤八、将镀了三次金属膜层的玻璃本体冷却至常温,用水冲洗掉隔离层。 [0084] Step eight, three bulk glass plated metal film is cooled to room temperature, rinse off the isolation layer. 制作出来的是金红色与玻璃本色(或其他颜色)相间的,且有一定图案的玻璃制品。 Made out of red and gold glass gray (or other color) and white, and a pattern of the glass article.

[0085] 实施例6 [0085] Example 6

[0086] 一种部分金红色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、纯银夹膜和钛复合外膜;所述钛复合外膜中,纯钛占94% (重量),铁占6% (重量)。 [0086] A red part of the gold coated glass, comprising a glass body and the glass body is plated on the metal film layer; the metal film layer composed of a metal film composed of three layers, according to the glass surface as a reference out in vitro, three metal film endometrial layer are copper, silver and titanium composite outer membrane capsular; the outer membrane complex of titanium, titanium 94% (by weight), iron comprises (by weight) 6%.

[0087] 制备方法,制备步骤如下, Preparation [0087] The method of preparation steps,

[0088] 步骤一、清洗,将玻璃本体用工业软水进行清洗; [0088] a step of cleaning, the glass body was washed with industrial soft water;

[0089] 步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分; [0089] Step two, the above-described cleaned glass body baking, drying of the moisture on the surface thereof;

[0090] 步骤三、画隔离,在玻璃上不需要镀金色膜处,涂上用双飞粉做成的速干型隔离粉; [0090] Step three, draw isolation, need not gold-plated on glass at the membrane, coated with a powder made of quick-drying Flying isolate powder;

[0091] 步骤四、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧离子机操作室内的气压保持在1. OX KT1pa内;充99. 9%以上的纯氩气,使操作室内的气压保持在1. 0Xl(T2pa 内; [0091] Step four, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum arc ion operating pressure in the chamber is maintained at 1. OX within KT1pa; charge of more than 99.9% pure argon and held at the operating pressure in the chamber 1. 0Xl (T2pa inside;

[0092] 步骤五、释放铜靶,镀铜内膜层,温度控制在200°C ; [0092] Step 5 is released copper target, copper intimal layer, the temperature control at 200 ° C;

[0093] 步骤六、保持操作室内氩气的气压在l.OXliTpa内;关闭铜靶,释放银靶,镀钛夹膜层,温度控制在240°C ; [0093] Step six, holding operating room argon gas pressure within l.OXliTpa; off a copper target, a target release silver, titanium film clip, temperature controlled at 240 ° C;

[0094] 步骤七、真空抽掉氩气,充99. 9 %氮气,保持操作室内氮气的气压在1.0X10° pa,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在320°C ; [0094] Step 7 vacuo deprived of argon, 99.9% nitrogen charge, maintaining the nitrogen pressure in the operation chamber 1.0X10 ° pa, released by the combination of titanium and iron obtained target compound, titanium outer film layer, the temperature control 320 ° C;

[0095] 步骤八、将镀了三次金属膜层的玻璃本体冷却至常温,用水冲洗掉隔离层。 [0095] Step eight, three bulk glass plated metal film is cooled to room temperature, rinse off the isolation layer. 制作出来的是金红色与玻璃本色(或其它颜色)相间的,且有一定图案的玻璃制品。 Made out of red and gold glass gray (or other color) and white, and a pattern of the glass article.

[0096] 上述实施例,只是本发明的较佳实施例,并非用来限制本发明实施范围,故凡以本发明权利要求所述的特征及原理所做的等效变化或修饰,均应包括在本发明权利要求范围之内。 [0096] the above-described embodiment, only the preferred embodiment of the present invention, not intended to limit the scope of the present invention, so any of the claims of the invention to features and principles made equivalent variations or modifications should be included within the scope of the claimed invention.

7 7

Claims (9)

  1. 一种金色镀膜玻璃,包括玻璃本体和镀在玻璃本体上的金属膜层;其特征在于:所述金属膜层由三层金属膜组成,以玻璃本体外表面为基准往外,三层金属膜层依次为铜内膜、钛夹膜和钛外膜。 One kind of golden glass, comprising a glass body and the glass body is plated on the metal film layer; characterized in that: said metal film layer composed of a metal film composed of three layers, the outer surface of the glass of the present reference outwardly, three layers of metal film layer followed by copper lining, a titanium film and a titanium clip adventitia.
  2. 2.根据权利要求1所述的金色镀膜玻璃,其特征在于:所述铜内膜为在99. 9%以上氩气保护气体下,用真空多弧离子机镀在玻璃本体上的80%〜99. 999%的黄铜,铜内膜的厚度为0. 0005mm 〜0. 08mm。 2. Gold coated glass according to claim 1, wherein: said copper lining under argon gas is more than 99.9%, coated on a glass body, 80% of the machine by vacuum arc ion ~ brass, copper, endometrial thickness was 99.999% 0. 0005mm ~0. 08mm.
  3. 3.根据权利要求1所述的金色镀膜玻璃,其特征在于:所述钛夹膜为在99. 9%以上氩气保护气体下,用真空多弧离子机镀在玻璃本体上的99. 9%〜99. 999%的钛,钛夹膜的厚度为0. 0005mm 〜0. 08mm。 The golden glass according to claim 1, wherein: said film is a titanium clip under argon gas over 99.9%, by vacuum arc ion plating machine on the glass body 99.9 ~99% 999% titanium, the thickness of the titanium film is interposed 0. 0005mm ~0. 08mm.
  4. 4.根据权利要求1所述的金色镀膜玻璃,其特征在于:所述钛外膜为99. 9%〜 99. 999%的钛,钛夹膜的厚度为0. 0005mm〜0. 08mm。 The golden glass according to claim 1, wherein: the outer membrane is 99.9% titanium - 99.999% titanium, the thickness of the titanium film is interposed 0. 0005mm~0 08mm..
  5. 5.根据权利要求1所述的金色镀膜玻璃,其特征在于:所述钛外膜为钛复合膜,由按重量百分比计的钛和铁组成,其中钛为90%〜99%,铁为〜10%。 The golden glass according to claim 1, wherein: the outer membrane is a titanium titanium composite membrane, the percentage by weight of titanium and iron, wherein the titanium is 90% ~99%, iron - 10%.
  6. 6.根据权利要求4或5所述的金色镀膜玻璃,其特征在于:所述钛外膜为在99. 9%以上氮气保护气体下,用真空多弧离子机镀在玻璃本体上的。 The golden glass 4 or claim 5, wherein: the titanium is in the outer membrane under nitrogen gas more than 99.9%, with multiple vacuum arc ion plating machine on the glass body.
  7. 7.权利要求1所述金色镀膜玻璃的制备方法,其特征在于:制备步骤如下:步骤一、清洗,将玻璃本体用工业软水进行清洗;步骤二、将上述清洗好的玻璃本体进行烘烤,干燥其表面的水分;步骤三、将干燥好的玻璃本体置于真空多弧离子机内,抽真空,使真空多弧6离子机操作室内的气压保持在1. OX ICT1〜1.0X10_3pa内;充氩气,使操作室内的气压保持在1. 0X10° 〜1. 0Xl(T3pa 内;步骤四、释放铜靶,镀铜内膜层,温度控制在100〜400°C ;步骤五、保持操作室内氩气的气压在1.0X10°〜1.0X10_3pa内;关闭铜靶,释放钛靶,镀钛夹膜层,温度控制在100〜400°C ;步骤六、真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10°〜1.0X10_3pa 内,释放钛靶,镀钛外膜层,温度控制在100〜400°C ;步骤七、将镀了三次金属膜层的玻璃本体冷却至常温,制得成品。 The method of preparing a golden glass of claim 1, wherein: prepared as follows: Step a cleaning, the glass body was washed with industrial soft water; step two, the above-described cleaned glass body is baked, drying water on the surface thereof; step three, the dried glass body will be placed in a vacuum arc ion machines, vacuum, vacuum multi-arc ion 6 operating air pressure is maintained within chamber 1. OX ICT1~1.0X10_3pa; charge argon and held at the operating pressure in the chamber 1. 0X10 ° ~1 0Xl (within T3pa;. step four, a copper target is released, the intimal layer of copper, the temperature control at 100~400 ° C; step five, holding operating room argon gas pressure within 1.0X10 ° ~1.0X10_3pa; off a copper target, the release of the titanium target, titanium film clip, temperature controlled at 100~400 ° C; step 6 vacuo deprived argon, purged with nitrogen, holding operation the pressure in the nitrogen chamber 1.0X10 ° ~1.0X10_3pa, releasing titanium target, titanium outer film layer, the temperature control at 100~400 ° C; step seven, three bulk glass plated metal film is cooled to room temperature, Ltd. finished.
  8. 8.根据权利要求7所述金色镀膜玻璃的制备方法,其特征在于:所述步骤六中,真空抽掉氩气,充氮气,保持操作室内氮气的气压在1.0X10°〜 LOXlO-3Pa内,关闭钛靶,释放由钛和铁组合而得的复合靶,镀钛外膜层,温度控制在100 〜400"C。 8. The method of claim 7 Preparation golden glass according to claim, wherein: said step six, the vacuum deprived argon, purged with nitrogen, keeping the air in the operating room nitrogen 1.0X10 ° ~ LOXlO-3Pa, Close titanium target, a composite target release composition obtained titanium and iron, titanium outer film layer, the temperature control in the 100 ~400 "C.
  9. 9.根据权利要求7或8所述金色镀膜玻璃的制备方法,其特征在于:步骤二和步骤三之间增加了画隔离的步骤,相应步骤七中将镀了三次金属膜层的玻璃本体冷却至常温后, 也要增加清洗隔离的步骤;所述的画隔离步骤为:在玻璃上不需要镀金色膜处,涂上用双飞粉做成的速干型隔离粉;所述的清洗隔离步骤为:用水冲洗掉隔离层。 9. A method of preparing the 78 or golden glass according to claim, wherein: the step of increasing the isolation between the painting step two and step three, the respective steps will be seven times the cooling body coated glass metal film to normal temperature, the washing step should be increased isolation; Videos said isolation step is: not required at the gold-plated film on glass, coated with a powder made of quick-drying Flying isolate powder; isolating said cleaning step is: rinse off the isolation layer.
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CN101628789A (en) * 2009-08-06 2010-01-20 钱中良 Method for producing glass mirrors with colors from brown to dark brown by vacuum coating machine
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