CN101914873A - Water paint containing amorphous aluminum silicate for cigarette forming paper - Google Patents

Water paint containing amorphous aluminum silicate for cigarette forming paper Download PDF

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CN101914873A
CN101914873A CN 201010238805 CN201010238805A CN101914873A CN 101914873 A CN101914873 A CN 101914873A CN 201010238805 CN201010238805 CN 201010238805 CN 201010238805 A CN201010238805 A CN 201010238805A CN 101914873 A CN101914873 A CN 101914873A
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water
paint
deg
paper
amorphous
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CN 201010238805
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代家红
何金星
尹康德
常忠
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玉溪思润印刷有限公司
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Abstract

The invention provides a water paint containing amorphous aluminum silicate for cigarette forming paper, which can be well bonded to the forming paper, can reduce hazardous substances in cigarette smoke and has the advantages of simple production technology, safety and no pollution. The water paint is prepared from the following substances accounted by 100 weight parts: 8 to 12 parts of amorphous aluminum silicate powder, 6 to 15 parts of bonding agent and the balance of water. The water paint is realized by the following steps of: A, adding the amorphous aluminum silicate powder to 2 to 4 times quantity of water; stirring and mixing to prepare a mixed solution a; B, firstly heating the residual water to 80 DEG C to 100 DEG C in another container; stirring and mixing phenol potassium and the bonding agent with the water of 80 DEG C to 100 DEG C to form a crosslinking mixed solution b; and C, uniformly mixing products obtained in step A and the step B to prepare the water paint for the forming paper.

Description

含无定形硅酸铝的卷烟成型纸用水性涂料 Amorphous aluminosilicate-containing cigarette paper forming an aqueous coating

技术领域 FIELD

[0001] 本发明属于一种加工成品纸的涂料。 [0001] The present invention pertains to the coating of processing a finished paper. 背景技术 Background technique

[0002] 众所周知,卷烟烟雾中含有多种有害物质,吸烟后这些有害成份沉积在人体内会引发肺部、呼吸道以及胃部等脏器产生多种疾病,虽然大家都知道吸烟有害于健康,但香烟具有提神、安神的多种功能,适当吸烟能使人兴奋、激发灵感、提高工作效率,所以烟民们还是很难戒烟。 [0002] As we all know, cigarette smoke contains many harmful substances deposited after smoking these harmful ingredients in the human body can cause lung, stomach and respiratory tract and other organs produce a variety of diseases, although we all know that smoking is harmful to health, but cigarettes have multiple functions refreshing, sedative, appropriate smoking can make people excited, inspired, improve work efficiency, so smokers are still difficult to quit smoking. 无定形硅酸铝是硅和铝的混合氧化物,其中含有少量的水分。 Amorphous aluminosilicate is mixed oxides of silicon and aluminum, containing a small amount of water. 它可以是合成的,也可以从天然矿物原料得到,属于干凝胶类的多孔性物质。 It may be synthetic, it can be obtained from the natural mineral raw materials, porous substance belonging to the class of the xerogel. 它们的胶团骨架由平滑的球状胶体粒子组成。 Micelle skeleton thereof by a smooth spherical colloidal particles. 硅酸铝的孔就是粒子之间的空隙,形成一些不规则的微孔。 The gap between the hole is aluminum silicate particles, formation of some irregular micropores. 微孔的平均直径大约在(40〜80) X 10-10m。 The average pore diameter of about (40~80) X 10-10m in. 由于具有这些微孔,而使它具有很大的表面积,可供烃类分子在其上面进行化学反应。 Because of these pores, and it has a large surface area for chemical reactions hydrocarbon molecules thereon.

[0003] 随着人们对健康的关注越来越高,“吸烟与健康”问题已越来越受到重视,人们对卷烟提出了更高的要求,不但要求其具有很好的口感,而且要能降低卷烟对人体的危害,而作为卷烟滤棒重要组成部分的成型纸,目前的功能仅限于将丝束捆绑起来,如何有效的对成型纸进行改进,将其同具有能吸附烟气中烃类物质、改善吸味功能的无定形硅酸铝结合起来,使其在对丝束进行包覆的同时,也能有效降低卷烟烟气中的有害成分,并且不会降低无定形硅酸铝自身的吸附功能,充分发挥其作为卷烟辅料的降害作用,已成为烟草科技发展的方向。 [0003] As people become increasingly concerned about health, "smoking and health" issue has been more and more attention, people put forward higher requirements cigarettes, not only required to have good taste, but also to be able to reducing cigarette on the human body, as an important part of the wrap cigarette filter, the functionality is limited to the current bundle tied up, how to effectively improve the molded sheet, with which the flue gas having adsorb hydrocarbons substances, improving smoke flavor amorphous aluminosilicate features combine to make it at the same time coated tow, can effectively reduce the harmful components in cigarette smoke, and does not reduce its amorphous aluminosilicate absorption features, give full play to its role of harm reduction cigarettes as accessories, tobacco has become the direction of technological development.

发明内容 SUMMARY

[0004] 本发明旨在提供一种能很好的粘附在成型纸上,并能减少卷烟烟气中的有害物质,生产工艺简单、安全无污染的含无定形硅酸铝的成型纸用水性涂料。 [0004] The present invention aims to provide a good adherence to the forming sheet, and can reduce the harmful substances in cigarette smoke, the production process is simple, safe and non-polluting containing amorphous aluminosilicate molded paper water-based paint.

[0005] 本发明通过以下技术手段来实现上述目的: [0005] The present invention achieves the above object is achieved by the following technical means:

[0006] 含无定形硅酸铝的卷烟成型纸用水性涂料,以100份重量计,该水性涂料由下列物质制成: [0006] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating, to 100 parts by weight of the aqueous coating is made of the following materials:

[0007] 8〜12份无定形硅酸铝粉末;6〜15份粘合剂;其余为水。 [0007] The amorphous aluminosilicate powder 8~12 parts; 6~15 parts binder; the rest is water.

[0008] 粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 [0008] The binder is a tapioca starch, potato starch and guar gum. 以100份重量计,该粘合剂配比如下: To 100 parts by weight of the binder was prepared as follows:

[0009] 5〜50份木薯淀粉;1-25份马铃薯淀粉;其余为瓜尔胶。 [0009] 5~50 parts of tapioca starch; 1-25 parts of potato starch; the balance being guar gum.

[0010] 含无定形硅酸铝的卷烟成型纸用水性涂料,是可以由以下步骤得到的产物: [0010] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material, can be obtained from the product of step:

[0011] A、在2〜4倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ; [0011] A, ~ 4-fold amount of water added in the amorphous aluminosilicate powder, the mixture was stirred and mixed to obtain a;

[0012] B、在另一容器中,先将剩余水量加热到80〜100°C,再将粘合剂与该80〜100°C 的水搅拌混合形成交联混合液b ; [0012] B, in another container, the remaining water is heated first to 80~100 ° C, and then stirring and mixing the binder with the water is 80~100 ° C to form a crosslinked mixture B;

[0013] C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 [0013] C, A and B in the above step to give the product mixed uniformly to prepare an aqueous coating wrap.

[0014] 优选地,无定形硅酸铝粉末是粒径为200〜800目。 [0014] Preferably, the amorphous aluminosilicate powder having a particle size of 200~800 mesh.

3[0015] 有益效果 3 [0015] Advantageous Effects

[0016] 本发明的有益效果在于: [0016] Advantageous effects of the present invention:

[0017] ①本发明所述的成型纸用水性涂料能很好的粘附在成型纸上,并能有效还原无定形硅酸铝的吸附功能,以减少卷烟烟气中的有害物质; [0017] ① wrap aqueous coating material according to the present invention can be formed in good adherence to the paper, and can effectively restore the adsorption function of the amorphous aluminosilicate to reduce the harmful substances in cigarette smoke;

[0018] ②本发明生产工艺简单,成本低,采用水作为溶剂,涂布后无挥发性有机溶剂残留问题,节约能源,安全无污染,抽吸更安全; [0018] ② of the present invention, the production process is simple, low cost, using water as a solvent, volatile organic solvent after coating residues, energy conservation, safety and pollution-free, safe pumping;

具体实施方式 detailed description

[0019] 下面结合具体实施例对本发明作进一步说明。 [0019] The following embodiments in conjunction with specific embodiments of the present invention will be further described.

[0020] 实施例1 [0020] Example 1

[0021] 含无定形硅酸铝的卷烟成型纸用水性涂料,以IOOkg重量计,该水性涂料由下列物质制成: [0021] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating, to IOOkg weight of the aqueous coating is made of the following materials:

[0022] 无定形硅酸铝粉末是粒径为200目。 [0022] The amorphous aluminosilicate powder having a particle size of 200 mesh.

[0023] 8kg无定形硅酸铝粉末;6kg粘合剂;84kg水。 [0023] 8kg amorphous aluminosilicate powder; 6kg binder; 84kg of water.

[0024] 粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 [0024] The binder is a tapioca starch, potato starch and guar gum. 以6kg重量计,该粘合剂配比如下: To 6kg weight, the adhesive was prepared as follows:

[0025] 3kg木薯淀粉;Ikg马铃薯淀粉;2kg瓜尔胶。 [0025] 3kg tapioca; IKG potato starch; 2kg guar gum.

[0026] 含无定形硅酸铝的卷烟成型纸用水性涂料,由以下步骤得到的产物: [0026] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material, the product obtained by the following steps:

[0027] A、在3倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ; [0027] A, the 3-fold amount of water added amorphous aluminosilicate powder, the mixture was stirred and mixed to obtain a;

[0028] B、在另一容器中,先将剩余水量加热到80°C,再将粘合剂与该80°C的水搅拌混合形成交联混合液b ; [0028] B, in another container, the remaining water is heated first to 80 ° C, and then stirring and mixing the binder with the water to 80 ° C to form a crosslinked mixture B;

[0029] C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 [0029] C, A and B in the above step to give the product mixed uniformly to prepare an aqueous coating wrap.

[0030] 实施例2 [0030] Example 2

[0031] 含无定形硅酸铝的卷烟成型纸用水性涂料,以IOOkg重量计,该水性涂料由下列物质制成: [0031] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating, to IOOkg weight of the aqueous coating is made of the following materials:

[0032] 无定形硅酸铝粉末是粒径为400目。 [0032] The amorphous aluminosilicate powder having a particle size of 400 mesh.

[0033] 12kg无定形硅酸铝粉末;15kg粘合剂;73kg水。 [0033] 12kg amorphous aluminosilicate powder; 15kg binder; 73kg of water.

[0034] 粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 [0034] The binder is a tapioca starch, potato starch and guar gum. 以15kg重量计,该粘合剂配比如下: In 15kg weight, the adhesive was prepared as follows:

[0035] 4kg木薯淀粉;2kg马铃薯淀粉;9kg瓜尔胶。 [0035] 4kg tapioca; 2kg potato starch; 9kg guar gum.

[0036] 含无定形硅酸铝的卷烟成型纸用水性涂料,由以下步骤得到的产物: [0036] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material, the product obtained by the following steps:

[0037] A、在2倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ; [0037] A, 2-fold amount of water added in the amorphous aluminosilicate powder, the mixture was stirred and mixed to obtain a;

[0038] B、在另一容器中,先将剩余水量加热到98°C,再将粘合剂与该98°C的水搅拌混合形成交联混合液b ; [0038] B, in another container, the remaining water is heated first to 98 ° C, and then stirring and mixing the binder with the water of 98 ° C to form a crosslinked mixture B;

[0039] C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 [0039] C, A and B in the above step to give the product mixed uniformly to prepare an aqueous coating wrap.

[0040] 实施例3 [0040] Example 3

[0041] 含无定形硅酸铝的卷烟成型纸用水性涂料,以IOOkg重量计,该水性涂料由下列物质制成: [0041] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating, to IOOkg weight of the aqueous coating is made of the following materials:

[0042] 无定形硅酸铝粉末是粒径为600目。 [0042] The amorphous aluminosilicate powder having a particle size of 600 mesh.

4[0043] IOkg无定形硅酸铝粉末;IOkg粘合剂;80kg水。 4 [0043] IOkg amorphous aluminosilicate powder; IOkg binder; 80kg of water.

[0044] 粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 [0044] The binder is a tapioca starch, potato starch and guar gum. 以IOkg重量计,该粘合剂配比如下: In IOkg weight, the adhesive was prepared as follows:

[0045] 5kg木薯淀粉;2kg马铃薯淀粉;3kg瓜尔胶。 [0045] 5kg tapioca; 2kg potato starch; 3kg guar gum.

[0046] 含无定形硅酸铝的卷烟成型纸用水性涂料,由以下步骤得到的产物: [0046] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material, the product obtained by the following steps:

[0047] A、在4倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ; [0047] A, 4-fold amount of water added in the amorphous aluminosilicate powder, the mixture was stirred and mixed to obtain a;

[0048] B、在另一容器中,先将剩余水量加热到98°C,再将粘合剂与该98°C的水搅拌混合形成交联混合液b ; [0048] B, in another container, the remaining water is heated first to 98 ° C, and then stirring and mixing the binder with the water of 98 ° C to form a crosslinked mixture B;

[0049] C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 [0049] C, A and B in the above step to give the product mixed uniformly to prepare an aqueous coating wrap.

[0050] 实施例4 [0050] Example 4

[0051] 含无定形硅酸铝的卷烟成型纸用水性涂料,以IOOkg重量计,该水性涂料由下列物质制成: [0051] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating, to IOOkg weight of the aqueous coating is made of the following materials:

[0052] 无定形硅酸铝粉末是粒径为800目。 [0052] The amorphous aluminosilicate powder having a particle size of 800 mesh.

[0053] Ilkg无定形硅酸铝粉末;9kg粘合剂;80kg水。 [0053] Ilkg amorphous aluminosilicate powder; 9kg binder; 80kg of water.

[0054] 粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 [0054] The binder is a tapioca starch, potato starch and guar gum. 以9kg重量计,该粘合剂配比如下: In 9kg weight, the adhesive was prepared as follows:

[0055] 5kg木薯淀粉;2kg马铃薯淀粉;2kg瓜尔胶。 [0055] 5kg tapioca; 2kg potato starch; 2kg guar gum.

[0056] 含无定形硅酸铝的卷烟成型纸用水性涂料,由以下步骤得到的产物: [0056] The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material, the product obtained by the following steps:

[0057] A、在3倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ; [0057] A, the 3-fold amount of water added amorphous aluminosilicate powder, the mixture was stirred and mixed to obtain a;

[0058] B、在另一容器中,先将剩余水量加热到85°C,再将粘合剂与该85°C的水搅拌混合形成交联混合液b ; [0058] B, in another container, the remaining water is heated first to 85 ° C, then stirred and mixed with the water in the binder of 85 ° C to form a crosslinked mixture B;

[0059] C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 [0059] C, A and B in the above step to give the product mixed uniformly to prepare an aqueous coating wrap.

Claims (6)

  1. 一种含无定形硅酸铝的卷烟成型纸用水性涂料,其特征是,以100份重量计,该水性涂料由下列物质制成:8~12份无定形硅酸铝粉末;6~15份粘合剂;其余为水。 Containing amorphous aluminosilicate cigarette paper forming an aqueous coating material, characterized in that, based on 100 parts by weight of the aqueous coating made from the following materials: 8 to 12 parts amorphous aluminosilicate powder; 6 ~ 15 parts binder; the rest is water.
  2. 2.根据权利要求1所述的含无定形硅酸铝的卷烟成型纸用水性涂料,其特征是,所述粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成。 According to claim 1 containing amorphous aluminosilicate cigarette paper forming an aqueous coating material as claimed in claim, wherein said binder is a tapioca starch, potato starch and guar gum.
  3. 3.根据权利要求2所述的含无定形硅酸铝的卷烟成型纸用水性涂料,其特征是,所述粘合剂是由木薯淀粉、马铃薯淀粉和瓜尔胶组成,以100份重量计,该粘合剂配比如下:5〜50份木薯淀粉;1-25份马铃薯淀粉;其余为瓜尔胶。 According to claim 2 containing amorphous aluminosilicate cigarette paper forming an aqueous coating material as claimed in claim, wherein said binder is a tapioca starch, potato starch and guar gum, based on 100 parts by weight the adhesive was prepared as follows: 5~50 parts of tapioca starch; 1-25 parts of potato starch; the balance being guar gum.
  4. 4.根据权利要求1〜3中任意一项所述的含无定形硅酸铝的卷烟成型纸用水性涂料, 其特征是,是由以下步骤得到的产物:A、在2〜4倍量水中加入无定形硅酸铝粉末,搅拌混合制得混合液a ;B、在另一容器中,先将剩余水量加热到80〜100°C,再将粘合剂与该80〜100°C的水搅拌混合形成交联混合液b ;C、将上述步骤A与B得到的产物混合均勻,制得成型纸用水性涂料。 The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating 1~3 any one of claims, characterized in that, was the product by the following steps: A, water in an amount of 2 ~ 4 times amorphous aluminosilicate powder was added, the mixture was stirred and mixed to obtain a; B, in another container, the remaining water is heated first to 80~100 ° C, and then the aqueous binder of 80~100 ° C stirring and mixing the mixture to form a crosslinked b; C, the above step a and product B obtained mixed to prepare an aqueous coating wrap.
  5. 5.根据权利要求1〜3中任意一项所述的含无定形硅酸铝的卷烟成型纸用水性涂料, 其特征是,所述无定形硅酸铝粉末是粒径为200〜800目。 The amorphous aluminosilicate-containing cigarette paper forming an aqueous coating material as claimed in any one of the claims 1 ~ 3, characterized in that said amorphous aluminosilicate powder having a particle size of 200~800 mesh.
  6. 6.根据权利要求4所述的含无定形硅酸铝的卷烟成型纸用水性涂料,其特征是,所述无定形硅酸铝粉末是粒径为200〜800目。 According to claim 4 containing amorphous aluminosilicate cigarette paper forming an aqueous coating material as claimed in claim, characterized in that said amorphous aluminosilicate powder having a particle size of 200~800 mesh.
CN 201010238805 2010-07-28 2010-07-28 Water paint containing amorphous aluminum silicate for cigarette forming paper CN101914873A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2755207A (en) * 1953-12-04 1956-07-17 Gen Cigar Co Cigarette paper
US4225636A (en) * 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1306401A (en) * 1998-04-16 2001-08-01 乐富门.本森及赫奇斯有限公司 Cigarette sidestream smoke treatment material
WO2004057986A2 (en) * 2002-12-20 2004-07-15 R.J. Reynolds Tobacco Company Materials, equipment, and methods for manufacturing cigarettes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2755207A (en) * 1953-12-04 1956-07-17 Gen Cigar Co Cigarette paper
US4225636A (en) * 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1306401A (en) * 1998-04-16 2001-08-01 乐富门.本森及赫奇斯有限公司 Cigarette sidestream smoke treatment material
US20030116169A1 (en) * 1998-04-16 2003-06-26 Rothmans, Benson & Hedges Inc. Cigarette sidestream smoke treatment material
WO2004057986A2 (en) * 2002-12-20 2004-07-15 R.J. Reynolds Tobacco Company Materials, equipment, and methods for manufacturing cigarettes

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