CN101914871A - Water-based paint containing zeolite molecular sieves for cigarette wrap paper - Google Patents

Water-based paint containing zeolite molecular sieves for cigarette wrap paper Download PDF

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CN101914871A
CN101914871A CN 201010238792 CN201010238792A CN101914871A CN 101914871 A CN101914871 A CN 101914871A CN 201010238792 CN201010238792 CN 201010238792 CN 201010238792 A CN201010238792 A CN 201010238792A CN 101914871 A CN101914871 A CN 101914871A
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water
parts
paper
wrap
paint
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CN 201010238792
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CN101914871B (en )
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代家红
何金星
尹康德
常忠
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玉溪思润印刷有限公司
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Abstract

The invention provides a water-based paint containing zeolite molecular sieves for cigarette wrap paper, which is realized by the technical means comprising the following steps: adding 20-30 parts of zeolite molecular sieve powder to 100 parts of water, and stirring and mixing to obtain a mixed liquid a; in another container, firstly, heating 100 parts of water to 80-100 DEG C, then adding 12-18 parts of carboxymethyl cellulose, 8-12 parts of cassava starch and 8-12 parts of guar gum to the water of 80-100 DEG C, stirring and mixing to form a cross linking mixed liquid b; and mixing the products obtained in the step A and the step B evenly according to the proportion of 1:(0.8-1.5) to obtain the water-based paint for the wrap paper. The water-based paint for the wrap paper of the invention can well adhere to the wrap paper, can effectively ensure the absorption function of the attapulgite to reduce harmful substances in the cigarette smoke, has simple production process, low cost, energy saving, safety and no pollution, adopts water as solvent, has no residue problem of a volatile organic solvent after coating, and is safer for smoking.

Description

含沸石分子筛的卷烟成型纸用水性涂料 Zeolite-containing cigarette paper forming an aqueous coating

技术领域 FIELD

[0001] 本发明属于一种加工成品纸的涂料。 [0001] The present invention pertains to the coating of processing a finished paper. 背景技术 Background technique

[0002] 众所周知,卷烟烟雾中含有多种有害物质,吸烟后这些有害成份沉积在人体内会引发肺部、呼吸道以及胃部等脏器产生多种疾病,虽然大家都知道吸烟有害于健康,但香烟具有提神、安神的多种功能,适当吸烟能使人兴奋、激发灵感、提高工作效率,所以烟民们还是很难戒烟。 [0002] As we all know, cigarette smoke contains many harmful substances deposited after smoking these harmful ingredients in the human body can cause lung, stomach and respiratory tract and other organs produce a variety of diseases, although we all know that smoking is harmful to health, but cigarettes have multiple functions refreshing, sedative, appropriate smoking can make people excited, inspired, improve work efficiency, so smokers are still difficult to quit smoking. 随着人们对健康的关注越来越高,“吸烟与健康”问题已越来越受到重视,人们对卷烟提出了更高的要求,不但要求其具有很好的口感,而且要能降低卷烟对人体的危害。 As people become increasingly concerned about health, "smoking and health" issue has been more and more attention, people put forward higher requirements cigarettes, not only required to have good taste, but also to be able to reduce cigarette harm the human body.

[0003] 沸石分子筛具有晶体的结构和特征,表面为固体骨架,内部的孔穴可起到吸附分子的作用。 [0003] Zeolites having the crystal structure and characteristics, surface solid framework, cavities may function inside the adsorbed molecules. 孔穴之间有孔道相互连接,分子由孔道经过。 There interconnected channels between the pores, molecules through the channels. 由于孔穴的结晶性质,分子筛的孔径分布非常均勻。 Since the crystalline nature of the hole, the molecular sieve pore size distribution is very uniform. 分子筛依据其晶体内部孔穴的大小对分子进行选择性吸附,吸附特定的分子而排斥其他的分子,分子筛作为卷烟辅料可以选择吸附烟气中的大颗粒物质,降低吸烟的危害。 Molecular sieve based on the intracrystalline pore size on selective adsorption molecules adsorbed to the exclusion of specific molecules into other molecules, molecular sieve materials can be selected as a cigarette smoke adsorption of large particulate matter, reducing the hazards of smoking.

[0004] 目前,成型纸的功能仅限于将丝束捆绑起来,对于卷烟减害、改善口感并没有直接的作用。 [0004] At present, the functionality is limited to wrap the tow tied up for a cigarette harm reduction, improved taste and has no direct effect. 如何将卷烟成型纸同卷烟辅料结合,使成型纸在对丝束进行包覆的同时,还能有效降低卷烟烟气中的有害成分、改善口感,并且也不影响卷烟辅料自身的吸附功能,充分发挥其降害作用,已成为烟草科技工作者研究的重点。 How cigarette wrap materials combined with cigarettes, while the molded sheet to be coated tow, but also effectively reduce the harmful components of cigarette smoke, to improve the taste, and does not affect their adsorption function cigarette excipients, fully to play its role in reducing harm, tobacco has become the focus of research scientists.

发明内容 SUMMARY

[0005] 本发明旨在提供一种能很好的粘附在成型纸上,并能减少卷烟烟气中的有害物质,生产工艺简单、安全无污染的含沸石分子筛的成型纸用水性涂料。 [0005] The present invention aims to provide a good adherence to the forming sheet, and can reduce the harmful substances in cigarette smoke, the production process is simple, safe and non-polluting zeolitic molecular sieve-containing aqueous coating plugwrap.

[0006] 本发明通过以下技术手段来实现上述目的: [0006] The present invention achieves the above object is achieved by the following technical means:

[0007] —种含沸石分子筛的卷烟成型纸用水性涂料,它是由下述重量配比的原料以水为溶剂制成的涂料:沸石分子筛20-30份,羧甲基纤维素12〜18份,木薯淀粉8〜12份,瓜尔胶8〜12份。 [0007] - species cigarette paper forming an aqueous coating containing a zeolitic molecular sieve, which is represented by the following weight proportion of the coating material made of water as a solvent: 20-30 parts of zeolite molecular sieve, carboxymethylcellulose 12~18 parts, parts of tapioca starch 8~12, 8~12 parts guar gum.

[0008] 上述含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0008] The zeolitic molecular sieve-containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0009] A、在100份水中加入20〜30份沸石分子筛粉末,搅拌混合制得混合液a ;和 [0009] A, 100 parts of water were added in 20 to 30 parts of zeolite molecular sieve powder, the mixture was stirred and mixed to obtain a; and

[0010] B、在另一容器中,先将100份水加热到80〜100°C,再将12〜18份羧甲基纤维素、8〜12份木薯淀粉、8〜12份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ; 和 [0010] B, in another container, 100 parts of water was first heated to 80~100 ° C, then 12~18 parts of carboxymethyl cellulose, 8~12 parts of tapioca starch, guar gum 8~12 parts stirring and mixing the mixture to form a crosslinked b with the water of 80~100 ° C; and

[0011] C、将上述步骤A与B得到的产物按1 : (0.8〜1.5)的比例混合均勻,制得成型纸用水性涂料。 [0011] C, the above step A and 1 B The product obtained by: mixing (0.8~1.5) ratio uniformly to prepare an aqueous coating wrap.

[0012] 优选的,一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物, 所用原料按重量份数计算: [0012] Preferably, the zeolitic molecular sieve containing cigarette paper forming an aqueous coating material, a product obtained by the following steps, parts by weight of the raw materials used:

[0013] A、在100份水中加入23〜26份沸石分子筛粉末,搅拌混合制得混合液a ;和[0014] B、在另一容器中,先将100份水加热到80〜100°C,再将14〜16份羧甲基纤维素、9. 5〜11份木薯淀粉、9. 5〜11份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;禾口 [0013] A, 100 parts of water were added in parts of 23~26 zeolitic molecular sieve powder, the mixture was stirred and mixed to obtain a; and [0014] B, in another container, 100 parts of water was first heated to 80~100 ° C ., then 14~16 parts of carboxymethyl cellulose, 9 parts of tapioca starch 5~11, 5~11 parts 9 of guar gum was stirred with water, the mixture 80~100 ° C to form a crosslinked mixture B; Wo mouth

[0015] C、将上述步骤A与B得到的产物按1 : (1〜1.2)的比例混合均勻,制得成型纸用水性涂料。 [0015] C, the above step A and 1 B The product obtained by: mixing (1~1.2) ratio uniformly to prepare an aqueous coating wrap.

[0016] 更优选地, [0016] More preferably,

[0017] 步骤A将沸石分子筛粉末放入水中搅拌后,研细,直至沸石分子筛为纳米粉体。 After [0017] Step A zeolite molecular sieve powder was stirred into the water, fine grinding, until the zeolite nano powder.

[0018] 有益效果 [0018] beneficial effects

[0019] 本发明的有益效果在于: [0019] Advantageous effects of the present invention:

[0020] ①本发明所述的成型纸用水性涂料能很好的粘附在成型纸上,能有效保证沸石分子筛的吸附功能,以减少卷烟烟气中的有害物质; [0020] ① wrap aqueous coating material according to the present invention can be formed in good adherence to the paper, can effectively guarantee the zeolite molecular sieve adsorption function to reduce the harmful substances in cigarette smoke;

[0021] ②本发明生产工艺简单,成本低,采用水作为溶剂,涂布后无挥发性有机溶剂残留问题,节约能源,安全无污染,抽吸更安全; [0021] ② of the present invention, the production process is simple, low cost, using water as a solvent, volatile organic solvent after coating residues, energy conservation, safety and pollution-free, safe pumping;

[0022] ③羧甲基纤维素能够增强纸的强度,提高涂布成型纸的成品率。 [0022] ③ carboxymethyl cellulose, paper strength can be enhanced to improve the yield of coated wrap. 具体实施方式 detailed description

[0023] 下面结合具体实施例对本发明作进一步说明。 [0023] The following embodiments in conjunction with specific embodiments of the present invention will be further described.

[0024] 实施例1 [0024] Example 1

[0025] 一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0025] Zeolites containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0026] A、在IOOg水中加入20g沸石分子筛粉末,搅拌混合制得混合液a ;和 [0026] A, in IOOg water was added 20g of zeolite molecular sieve powder, the mixture was stirred and mixed to obtain a; and

[0027] B、在另一容器中,先将IOOg水加热到80°C,再将12g羧甲基纤维素、8g木薯淀粉、 Sg瓜尔胶与该80°C的水搅拌混合形成交联混合液b ;和 [0027] B, in another container, heated water first IOOg to 80 ° C, and then 12g carboxymethylcellulose, 8g tapioca starch, Sg guar gum with water to 80 ° C the mixture was stirred to form a crosslinked mixture b; and

[0028] C、将上述步骤A与B得到的产物按1 : 0.8的比例混合均勻,制得成型纸用水性涂料。 [0028] C, the above-described steps A and B obtained by the product ratio of 1: 0.8 uniform, to prepare an aqueous coating wrap.

[0029] 实施例2 [0029] Example 2

[0030] 一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0030] Zeolites containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0031] A、在IOOg水中加入30g沸石分子筛粉末,搅拌混合制得混合液a ;和 [0031] A, in IOOg water was added 30g of zeolite molecular sieve powder, the mixture was stirred and mixed to obtain a; and

[0032] B、在另一容器中,先将IOOg水加热到100°C,再将18g羧甲基纤维素、12g木薯淀粉、12g瓜尔胶与该100°C的水搅拌混合形成交联混合液b ;和 [0032] B, in another container, heated water first IOOg to 100 ° C, and then the carboxymethyl cellulose 18g, 12g tapioca starch, 12g guar gum and water of 100 ° C the mixture was stirred to form a crosslinked mixture b; and

[0033] C、将上述步骤A与B得到的产物按1 : 1.5的比例混合均勻,制得成型纸用水性涂料。 [0033] C, the above-described steps A and B obtained by the product ratio of 1: 1.5 uniform, to prepare an aqueous coating wrap.

[0034] 实施例3 [0034] Example 3

[0035] 一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0035] The zeolitic molecular sieve containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0036] A、在IOkg水中加入2. 3kg沸石分子筛粉末,搅拌混合制得混合液a ;和 [0036] A, the water added in IOkg 2. 3kg zeolitic molecular sieve powder, the mixture was stirred and mixed to obtain a; and

[0037] B、在另一容器中,先将IOkg水加热到90°C,再将1. 4kg羧甲基纤维素、Ikg木薯淀粉、Ikg瓜尔胶与该90°C的水搅拌混合形成交联混合液b ;和 [0037] B, in another container, IOkg first heated to 90 ° C water, then 1. 4kg carboxymethylcellulose, IKG tapioca starch, guar gum IKG water with stirring to 90 ° C the formed mixed crosslinking the mixture B; and

[0038] C、将上述步骤A与B得到的产物按1 : 1. 1的比例混合均勻,制得成型纸用水性涂料。 [0038] C, the above-described steps A and B obtained by the product ratio of 1: 1.1 uniform, to prepare an aqueous coating wrap.

[0039] 实施例4[0040] 一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: 4 [0040] Zeolite containing cigarette paper forming an aqueous coating material, a product obtained by the steps of [0039] Example:

[0041] A、在IOkg水中加入2. 3kg沸石分子筛粉末,用磨石研细,直至沸石分子筛为纳米粉体;和 [0041] A, the water added in IOkg 2. 3kg zeolitic molecular sieve powder, fine grinding grindstone, until the zeolite powder nanometers; and

[0042] B、在另一容器中,先将IOkg水加热到90°C,再将1. 4kg羧甲基纤维素、Ikg木薯淀粉、Ikg瓜尔胶与该90°C的水搅拌混合制得交联混合液b ;和 [0042] B, in another container, IOkg first heated to 90 ° C water, then 1. 4kg carboxymethylcellulose, IKG tapioca starch, guar gum IKG prepared by mixing with stirring the water to 90 ° C a crosslinked mixture B; and

[0043] C、将上述步骤A与B得到的产物按1 : 1的比例混合均勻,制得成型纸用水性涂料。 [0043] C, the above-described steps A and B of the product obtained by 1: 1 mixing ratio uniformly to prepare an aqueous coating wrap.

[0044] 实施例5 [0044] Example 5

[0045] 一种含沸石分子筛的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0045] The zeolitic molecular sieve containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0046] A、在IOkg水中加入2. 6kg,220目的沸石分子筛粉末,用磨石研细,直至沸石分子筛为纳米粉体;和 [0046] A, the water added in IOkg 2. 6kg, 220 object of the zeolite molecular sieve powder, fine grinding grindstone, until the zeolite powder nanometers; and

[0047] B、在另一容器中,先将IOkg水加热到85°C,再将1.6kg羧甲基纤维素、1. Ikg木薯淀粉、1. Ikg瓜尔胶与该85°C的水搅拌混合制得交联混合液b ;和 [0047] B, in another container, first IOkg water was heated to 85 ° C, and then 1.6kg of carboxymethyl cellulose, 1. Ikg tapioca starch, 1. Ikg guar gum with the water to 85 ° C stirring and mixing to prepare a crosslinked mixture B; and

[0048] C、将上述步骤A与B得到的产物按1 : 1. 1的比例混合均勻,制得成型纸用水性涂料。 [0048] C, the above-described steps A and B obtained by the product ratio of 1: 1.1 uniform, to prepare an aqueous coating wrap.

5 5

Claims (4)

  1. 一种含沸石分子筛的卷烟成型纸用水性涂料,其特征在于,它是由下述重量配比的原料以水为溶剂制成的涂料:沸石分子筛20~30份,羧甲基纤维素12~18份,木薯淀粉8~12份,瓜尔胶8~12份。 Zeolites containing cigarette paper forming an aqueous coating material, characterized in that it is prepared from the following raw materials by weight of water as a solvent to prepare a coating: 20 to 30 parts Zeolite, carboxymethylcellulose ~ 12 18 parts of tapioca starch 8-12 parts, guar gum 8 to 12 parts.
  2. 2. 一种含沸石分子筛的卷烟成型纸用水性涂料,其特征在于,是由以下步骤得到的产物,所用原料按重量份数计算:A、在100份水中加入20〜30份沸石分子筛粉末,搅拌混合制得混合液a ;和B、在另一容器中,先将100份水加热到80〜100°C,再将12〜18份羧甲基纤维素、8〜 12份木薯淀粉、8〜12份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;和C、将上述步骤A与B得到的产物按1 : (0.8〜1.5)的比例混合均勻,制得成型纸用水性涂料。 2. A zeolitic molecular sieve-containing cigarette paper forming an aqueous coating material, characterized in that the following steps are obtained by the product, the raw material is calculated in parts by weight: A, 100 parts of water were added in 20 to 30 parts of zeolite molecular sieve powder, stirring and mixing to prepare a mixture of a; and B, and in another container, 100 parts of water was first heated to 80~100 ° C, and then parts of 12~18 carboxymethylcellulose, 8~ 12 parts of tapioca starch, 8 ~ 12 parts of guar gum was stirred with water, the mixing of 80~100 ° C to form a crosslinked mixture B; and C, step a above and the product obtained according to B 1: (0.8~1.5) mixed ratio to prepare water to give wrap coating.
  3. 3.根据权利要求1所述的含沸石分子筛的卷烟成型纸用水性涂料,其特征在于,是由以下步骤得到的产物,所用原料按重量份数计算:A、在100份水中加入23〜26份沸石分子筛粉末,搅拌混合制得混合液a ;和B、在另一容器中,先将100份水加热到80〜100°C,再将14〜16份羧甲基纤维素、 9. 5〜11份木薯淀粉、9. 5〜11份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;禾口C、将上述步骤A与B得到的产物按1 : (1〜1.2)的比例混合均勻,制得成型纸用水性涂料。 The cigarette paper forming an aqueous coating containing a zeolitic molecular sieve according to claim 1, wherein the steps are obtained by the product, the raw material is calculated in parts by weight: A, 100 parts of water were added at 23~26 parts of zeolite molecular sieve powder, the mixture was stirred and mixed to obtain a; and B, and in another container, 100 parts of water was first heated to 80~100 ° C, then 14~16 parts of carboxymethyl cellulose, 9.5 . ~ 11 parts tapioca starch, guar gum 9 5~11 parts 80~100 ° C with the stirring and mixing water to form a crosslinked mixture B; Wo port C, the above step a and 1 B the product obtained by: ( 1~1.2) mixed ratio to prepare a water paint wrap.
  4. 4.根据权利要求1或2中任意一项所述的含沸石分子筛的卷烟成型纸用水性涂料,其特征在于,步骤A将沸石分子筛粉末放入水中搅拌后,研细,直至沸石分子筛为纳米粉体。 The cigarette wrap 1 containing Zeolite Waterborne Coating 2 or any one of the preceding claims, wherein step A zeolite molecular sieve powder was stirred into the water after fine grinding, until the zeolite nanometers powder.
CN 201010238792 2010-07-28 2010-07-28 Water-based paint containing zeolite molecular sieves for cigarette wrap paper CN101914871B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225636A (en) * 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1696401A (en) * 2005-03-31 2005-11-16 玉溪红塔烟草(集团)有限责任公司 Shaped paper with activated adsorption layer in use for filter plug of cigarette

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225636A (en) * 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1696401A (en) * 2005-03-31 2005-11-16 玉溪红塔烟草(集团)有限责任公司 Shaped paper with activated adsorption layer in use for filter plug of cigarette

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