CN101914870B - Attapulgite-containing water-based paint for cigarette wrap paper - Google Patents

Attapulgite-containing water-based paint for cigarette wrap paper Download PDF

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CN101914870B
CN101914870B CN 201010238777 CN201010238777A CN101914870B CN 101914870 B CN101914870 B CN 101914870B CN 201010238777 CN201010238777 CN 201010238777 CN 201010238777 A CN201010238777 A CN 201010238777A CN 101914870 B CN101914870 B CN 101914870B
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parts
water
attapulgite
mixed
cigarette
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CN 201010238777
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CN101914870A (en )
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代家红
何金星
尹康德
常忠
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玉溪思润印刷有限公司
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Abstract

The invention provides an attapulgite-containing water-based paint for cigarette wrap paper, which can be excellently adhered to wrap paper, can reduce harmful substances in cigarette smoke, and has simple production technology, good safety and no pollution; the water-based paint for wrap paper is prepared by the following technical steps of: adding 5-20 parts of attapulgite powder in 100 parts of water and stirring and mixing the powder and the water to result in mixed solution a; in another vessel, heating 100 parts of water to 80 to 100 DEG C at first, and then stirring and mixing 12-18 parts of carboxymethyl cellulose, 8-12 parts of arrowroot starch, 8-12 parts of guar gum with water at 80 to 100 DEG C to form crosslinking mixed solution b; and mixing the product in the step A with the product in the step B according to the proportion of 2: (0.8-1.5). The attapulgite-containing water-based paint can be excellently adhered to wrap paper and effectively guarantee the adsorption function of the attapulgite in order to reduce harmful substances in cigarette smoke; in addition, the production technology is simple, the cost is low, the problem of residual volatile organic solvent subsequent to coating is avoided due to the use of water as solvent, the energy is saved, the paint is safe and free from pollution, and the cigarette with the paint is safer during smoking.

Description

含凹凸棒石的卷烟成型纸用水性涂料 Cigarette paper containing attapulgite forming water-based coating

技术领域 FIELD

[0001] 本发明属于一种加工成品纸的涂料。 [0001] The present invention pertains to the coating of processing a finished paper.

背景技术 Background technique

[0002] 众所周知,卷烟烟雾中含有多种有害物质,吸烟后这些有害成份沉积在人体内会引发肺部、呼吸道以及胃部等脏器产生多种疾病,虽然大家都知道吸烟有害于健康,但香烟具有提神、安神的多种功能,适当吸烟能使人兴奋、激发灵感、提高工作效率,所以烟民们还是很难戒烟。 [0002] As we all know, cigarette smoke contains many harmful substances deposited after smoking these harmful ingredients in the human body can cause lung, stomach and respiratory tract and other organs produce a variety of diseases, although we all know that smoking is harmful to health, but cigarettes have multiple functions refreshing, sedative, appropriate smoking can make people excited, inspired, improve work efficiency, so smokers are still difficult to quit smoking. 随着人们对健康的关注越来越高,“吸烟与健康”问题已越来越受到重视,人们对卷烟提出了更高的要求,不但要求其具有很好的口感,而且要能降低卷烟对人体的危害。 As people become increasingly concerned about health, "smoking and health" issue has been more and more attention, people put forward higher requirements cigarettes, not only required to have good taste, but also to be able to reduce cigarette harm the human body.

[0003] 凹凸棒石是一种晶质水合镁铝硅酸盐矿物,它具有独特的分散、耐高温、抗盐碱等良好的胶体性质和较高的吸附脱色能力,是较为理想的吸附剂,可取代活性炭。 [0003] Attapulgite is a crystalline hydrated magnesium silicate minerals, it has a unique dispersion, high temperature, salt resistance and other good properties and high adsorption colloidal decolorization capacity, is an ideal adsorbent , can replace activated carbon. 它不仅能脱色,除臭、除味,还可除重金属离子和致癌物质,还具有一定的选择性,可作药物的填料、载体、添加剂、粘结剂。 It can not only bleaching, deodorizing, odor, in addition to heavy metal ions and also carcinogen, also has a certain selectivity, the filler may be a drug, carriers, additives, binders. 凹凸棒石还具有比较突出的环保性能,在吸附过程中可以再生,耗能少,对环境保护非常有利,是一种较好的卷烟辅料。 Attapulgite also has a more prominent environmental performance, can be regenerated during adsorption, low energy consumption, environmental protection is very advantageous, is a good cigarette materials.

[0004]目前,成型纸的功能仅限于将丝束捆绑起来,对于卷烟减害、改善口感并没有直接的作用。 [0004] At present, the functionality is limited to wrap the tow tied up for a cigarette harm reduction, improved taste and has no direct effect. 如何将卷烟成型纸同具有吸附功能的凹凸棒石进行结合,使成型纸在对丝束进行包覆的同时,还能有效降低卷烟烟气中的有害成分、改善口感,并且也不影响凹凸棒石自身的吸附功能,充分发挥其降害作用,已成为烟草科技工作者研究的方向。 How to be combined with the wrap cigarette attapulgite with an adsorption function, while the molded sheet to be coated tow, but also effectively reduce the harmful components of cigarette smoke, to improve the taste, and does not affect Attapulgite stone's own absorption features, give full play to its role in reducing harm, tobacco has become the direction of research scientists.

发明内容 SUMMARY

[0005] 本发明旨在提供一种能很好的粘附在成型纸上,并能减少卷烟烟气中的有害物质,生产工艺简单、安全无污染的含凹凸棒石的成型纸用水性涂料。 [0005] The present invention aims to provide a good adherence to the forming sheet, and can reduce the harmful substances in cigarette smoke, the production process is simple, safe and non-polluting attapulgite plugwrap containing water-based coating .

[0006] 本发明通过以下技术手段来实现上述目的: [0006] The present invention achieves the above object is achieved by the following technical means:

[0007] —种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0007] - Species containing attapulgite cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0008] A、在100份水中加入5〜20份凹凸棒石粉末,搅拌混合得混合液a ;和 [0008] A, in 100 parts of water were added 5~20 parts of attapulgite powder mixture was stirred and mixed to obtain a; and

[0009] B、在另一容器中,先将100份水加热到80〜100°C,再将12〜18份羧甲基纤维素、8〜12份木薯淀粉、8〜12份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;和 [0009] B, in another container, 100 parts of water was first heated to 80~100 ° C, then 12~18 parts of carboxymethyl cellulose, 8~12 parts of tapioca starch, guar gum 8~12 parts stirring and mixing the mixture to form a crosslinked b with the water of 80~100 ° C; and

[0010] C、将上述步骤A与B得到的产物按2 : (0. 8〜I. 5)的比例混合均匀,制得成型纸用水性涂料。 [0010] C, the above-described steps A and B of the product obtained by 2: (. 0. 8~I 5) mixed ratio to prepare a water paint wrap.

[0011] 优选的,一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0011] Preferably, attapulgite containing cigarette paper forming an aqueous coating material, a product obtained by the following steps:

[0012] A、在100份水中加入8〜15份凹凸棒石粉末,搅拌混合制得混合液a ;和 [0012] A, in 100 parts of water were added 8~15 parts of attapulgite powder mixture was mixed with stirring to prepare a; and

[0013] B、在另一容器中,先将100份水加热到80〜100°C,再将14〜16份羧甲基纤维素、9. 5〜11份木薯淀粉、9. 5〜11份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;和 [0013] B, in another container, 100 parts of water was first heated to 80~100 ° C, and then parts of 14~16 carboxymethylcellulose, 9. 5~11 parts of tapioca starch, 9. 5~11 parts of guar gum mixture was stirred and mixed to form a crosslinked b with the water of 80~100 ° C; and

[0014] C、将上述步骤A与B得到的产物按2 : (I〜I. 2)的比例混合均匀,制得成型纸用水性涂料。 [0014] C, the above-described steps A and B of the product obtained by 2: (. I~I 2) mixed ratio to prepare a water paint wrap.

[0015] 更优选地,步骤A将凹凸棒石粉末放入水中搅拌混合后,过辊间隙为1000纳米以下的三辊研磨机,制得混合液a。 After [0015] More preferably, step A attapulgite powder was stirred and mixed into the water, through the roll gap to 1000 nanometers or less three-roll mill to prepare a mixture of a.

[0016] 有益效果 [0016] beneficial effects

[0017] 本发明的有益效果在于: [0017] Advantageous effects of the present invention:

[0018] ①本发明所述的成型纸用水性涂料能很好的粘附在成型纸上,能有效保证凹凸棒石的吸附功能,以减少卷烟烟气中的有害物质; [0018] ① wrap aqueous coating material according to the present invention can be formed in good adherence to the paper, can effectively guarantee attapulgite adsorption function to reduce the harmful substances in cigarette smoke;

[0019] ②本发明生产工艺简单,成本低,采用水作为溶剂,涂布后无挥发性有机溶剂残留问题,节约能源,安全无污染,抽吸更安全; [0019] ② of the present invention, the production process is simple, low cost, using water as a solvent, volatile organic solvent after coating residues, energy conservation, safety and pollution-free, safe pumping;

[0020] ③羧甲基纤维素能够增强纸的强度,提高了涂布成型纸的成品率。 [0020] ③ carboxymethylcellulose paper strength can be enhanced, improving the yield of coated wrap.

具体实施方式 detailed description

[0021] 下面结合具体实施例对本发明作进一步说明。 [0021] The following embodiments in conjunction with specific embodiments of the present invention will be further described.

[0022] 实施例I [0022] Example I

[0023] 一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0023] A cigarette paper forming an aqueous coating containing attapulgite, is the product obtained by the following steps:

[0024] A、在IOOg水中加入5g凹凸棒石粉末,搅拌混合制得混合液a ;和 [0024] A, 5g of water in IOOg attapulgite powder mixture was mixed with stirring to prepare a; and

[0025] B、在另一容器中,先将IOOg水加热到80°C,再将12g羧甲基纤维素、8g木薯淀粉、Sg瓜尔胶与该80°C的水搅拌混合形成交联混合液b ;和 [0025] B, in another container, heated water first IOOg to 80 ° C, and then 12g carboxymethylcellulose, 8g tapioca starch, Sg guar gum with water to 80 ° C the mixture was stirred to form a crosslinked mixture b; and

[0026] C、将上述步骤A与B得到的产物按2 :0. 8的比例混合均匀,制得成型纸用水性涂料。 [0026] C, the above-described steps A and B of the product obtained by the 2: 08 ratio of mixed to prepare an aqueous coating wrap.

[0027] 实施例2 [0027] Example 2

[0028] 一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0028] A cigarette paper forming an aqueous coating containing attapulgite, is the product obtained by the following steps:

[0029] A、在IOOg水中加入20g凹凸棒石粉末,搅拌混合制得混合液a ;和 [0029] A, was added in 20g water IOOg attapulgite powder mixture was mixed with stirring to prepare a; and

[0030] B、在另一容器中,先将IOOg水加热到100°C,再将18g羧甲基纤维素、12g木薯淀粉、12g瓜尔胶与该100°C的水搅拌混合形成交联混合液b ;和 [0030] B, in another container, heated water first IOOg to 100 ° C, and then the carboxymethyl cellulose 18g, 12g tapioca starch, 12g guar gum and water of 100 ° C the mixture was stirred to form a crosslinked mixture b; and

[0031] C、将上述步骤A与B得到的产物按2 :1. 5的比例混合均匀,制得成型纸用水性涂料。 [0031] C, the above-described steps A and B of the product obtained by the 2: 1 ratio of 5 is mixed to prepare an aqueous coating wrap.

[0032] 实施例3 [0032] Example 3

[0033] 一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0033] A cigarette paper forming an aqueous coating containing attapulgite, is the product obtained by the following steps:

[0034] A、在IOkg水中加入0. 8kg凹凸棒石粉末,搅拌混合制得混合液a ;和 [0034] A, the water added 0. 8kg IOkg attapulgite powder mixture was mixed with stirring to prepare a; and

[0035] B、在另一容器中,先将IOkg水加热到90°C,再将I. 4kg羧甲基纤维素、Ikg木薯淀粉、Ikg瓜尔胶与该90°C的水搅拌混合形成交联混合液b ;和 [0035] B, in another container, IOkg first heated to 90 ° C water, then I. 4kg carboxymethylcellulose, IKG tapioca starch, guar gum IKG water with stirring to 90 ° C the formed mixed crosslinking the mixture B; and

[0036] C、将上述步骤A与B得到的产物按2 :1. I的比例混合均匀,制得成型纸用水性涂料。 [0036] C, the above-described steps A and B of the product obtained by the 2:. 1 I of the mixed ratio to prepare a water paint wrap.

[0037] 实施例4 [0037] Example 4

[0038] 一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0038] A cigarette paper forming an aqueous coating containing attapulgite, is the product obtained by the following steps:

[0039] A、在IOkg水中加入I. 2kg凹凸棒石粉末,搅拌混合后过辊间隙为1000纳米的三辊研磨机,制得混合液a;和 [0039] A, the water added in IOkg I. 2kg attapulgite powder mixture was stirred over the roll gap to 1000 nanometers three-roll mill to prepare a mixture of a; and

[0040] B、在另一容器中,先将IOkg水加热到90°C,再将I. 4kg羧甲基纤维素、Ikg木薯淀粉、Ikg瓜尔胶与该90°C的水搅拌混合制得交联混合液b ;和 [0040] B, in another container, IOkg first heated to 90 ° C water, then I. 4kg carboxymethylcellulose, IKG tapioca starch, guar gum IKG prepared by mixing with stirring the water to 90 ° C a crosslinked mixture B; and

[0041] C、将上述步骤A与B得到的产物按2 :1的比例混合均匀,制得成型纸用水性涂料。 [0041] C, the above-described steps A and B of the product obtained by the 2: 1 ratio mixed to prepare an aqueous coating wrap.

[0042] 实施例5 [0042] Example 5

[0043] 一种含凹凸棒石的卷烟成型纸用水性涂料,是由以下步骤得到的产物: [0043] A cigarette paper forming an aqueous coating containing attapulgite, is the product obtained by the following steps:

[0044] A、在IOkg水中加入Ikg凹凸棒石粉末,搅拌混合后过辊间隙为800纳米的三辊研磨机,制得混合液a;和 [0044] A, the water added Ikg IOkg attapulgite powder mixture was stirred over the roll gap of 800 nm three-roll mill to prepare a mixture of a; and

[0045] B、在另一容器中,先将IOkg水加热到85°C,再将I. 6kg羧甲基纤维素、I. Ikg木薯淀粉、I. Ikg瓜尔胶与该85°C的水搅拌混合制得交联混合液b ;和 [0045] B, in another container, first IOkg water was heated to 85 ° C, and then I. 6kg carboxymethylcellulose, I. Ikg tapioca starch, I. Ikg the guar gum to 85 ° C water was stirred and mixed to obtain a mixture of cross-linked B; and

[0046] C、将上述步骤A与B得到的产物按2 :1. I的比例混合均匀,制得成型纸用水性涂料。 [0046] C, the above-described steps A and B of the product obtained by the 2:. 1 I of the mixed ratio to prepare a water paint wrap.

Claims (3)

  1. 1. 一种含凹凸棒石的卷烟成型纸用水性涂料,其特征在于,是由以下步骤得到的产物,所用原料按重量份数计算: A、在100份水中加入5〜20份凹凸棒石粉末,搅拌混合制得混合液a ;和B、在另一容器中,先将100份水加热到80〜100°C,再将12〜18份羧甲基纤维素、8〜12份木薯淀粉、8〜12份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;和C、将上述步骤A与B得到的产物按2 : (0. 8〜I. 5)的比例混合均匀,制得成型纸用水性涂料。 A cigarette paper forming an aqueous coating containing attapulgite, wherein the steps are obtained by the product, the raw material is calculated in parts by weight: A, 5~20 parts of attapulgite was added in 100 parts of water powders stirred and mixed to obtain a mixture of a; and B, and in another container, 100 parts of water was first heated to 80~100 ° C, then 12~18 parts of carboxymethyl cellulose, 8~12 parts of tapioca starch , 8~12 parts of guar gum was stirred with water, the mixing of 80~100 ° C to form a crosslinked mixture B; and C, step a above and the product obtained according to B 2: (0. 8~I 5.) mixed ratio to prepare a water paint wrap.
  2. 2.根据权利要求I所述的含凹凸棒石的卷烟成型纸用水性涂料,其特征在于,是由以下步骤得到的产物,所用原料按重量份数计算: A、在100份水中加入8〜15份凹凸棒石粉末,搅拌混合制得混合液a ;和B、在另一容器中,先将100份水加热到80〜100°C,再将14〜16份羧甲基纤维素、9. 5〜11份木薯淀粉、9. 5〜11份瓜尔胶与该80〜100°C的水搅拌混合形成交联混合液b ;和C、将上述步骤A与B得到的产物按2 : (I〜I. 2)的比例混合均匀,制得成型纸用水性涂料。 The cigarette paper containing attapulgite forming an aqueous coating material according to claim I, wherein the steps are obtained by the product, the raw material is calculated in parts by weight: A, 100 parts of water were added 8~ 15 parts of attapulgite powder mixture was mixed with stirring to prepare a; and B, and in another container, 100 parts of water was first heated to 80~100 ° C, and then parts of 14~16 carboxymethylcellulose, 9 . 5~11 parts of tapioca starch, guar gum 9 5~11 parts 80~100 ° C with the stirring and mixing water to form a crosslinked mixture B; and C, a and B in the above step to give the product 2: (I~I. 2) mixed ratio to prepare a water paint wrap.
  3. 3.根据权利要求I所述的含凹凸棒石的卷烟成型纸用水性涂料,其特征在于,步骤A将凹凸棒石粉末放入水中搅拌混合后,过辊间隙为1000纳米以下的三辊研磨机,制得混合液B o The cigarette paper containing attapulgite forming an aqueous coating material according to claim I, wherein step A attapulgite powder was mixed into water with stirring, over a three roll mill roll gap is 1000 nm or less machines, a mixed solution B o
CN 201010238777 2010-07-28 2010-07-28 Attapulgite-containing water-based paint for cigarette wrap paper CN101914870B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225636A (en) 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1306401A (en) 1998-04-16 2001-08-01 乐富门.本森及赫奇斯有限公司 Cigarette sidestream smoke treatment material
CN1818210A (en) 2006-03-28 2006-08-16 刘波 Formed paper coating for lowering harm and decreasing coking smoke
CN101363206A (en) 2008-09-28 2009-02-11 湖南中烟工业有限责任公司 Coating for reducing carbon monoxide and injurants in smoke
CN101363205A (en) 2008-09-28 2009-02-11 湖南中烟工业有限责任公司 Molding paper coating for reducing injurants CO, NOx in cigarette smoke
CN101748652A (en) 2009-12-08 2010-06-23 湖南中烟工业有限责任公司 Cool additive for mint type cigarettes, preparation thereof and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225636A (en) 1979-03-08 1980-09-30 Olin Corporation High porosity carbon coated cigarette papers
CN1306401A (en) 1998-04-16 2001-08-01 乐富门.本森及赫奇斯有限公司 Cigarette sidestream smoke treatment material
CN1818210A (en) 2006-03-28 2006-08-16 刘波 Formed paper coating for lowering harm and decreasing coking smoke
CN101363206A (en) 2008-09-28 2009-02-11 湖南中烟工业有限责任公司 Coating for reducing carbon monoxide and injurants in smoke
CN101363205A (en) 2008-09-28 2009-02-11 湖南中烟工业有限责任公司 Molding paper coating for reducing injurants CO, NOx in cigarette smoke
CN101748652A (en) 2009-12-08 2010-06-23 湖南中烟工业有限责任公司 Cool additive for mint type cigarettes, preparation thereof and application thereof

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