CN101864265B - Photocured adhesive for repairing micro cracks of automotive glass and preparation method thereof - Google Patents
Photocured adhesive for repairing micro cracks of automotive glass and preparation method thereof Download PDFInfo
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- CN101864265B CN101864265B CN201010178267.1A CN201010178267A CN101864265B CN 101864265 B CN101864265 B CN 101864265B CN 201010178267 A CN201010178267 A CN 201010178267A CN 101864265 B CN101864265 B CN 101864265B
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- photocurable adhesive
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Abstract
The invention discloses a photocured adhesive for repairing micro cracks of automotive glass and a preparation method thereof. The preparation method mainly comprises: firstly, adding acrylic acid isobornyl ester, hydroxyethyl methacrylate and lauryl acrylate into a container and uniformly mixing the mixture; secondly, slowly adding pretreated nano silicon dioxide, stirring the mixture at the same time for preventing agglomeration till the nano silicon dioxide disperses completely and colorless transparent solution is formed; and finally, adding aliphatic polyester type polyurethane-acrylate, a pure acrylate oligomer, 2-hydroxy-2-methyl-1- phenyl-1-propyl ketone, 1-hydroxycyclohexyl phenyl ketone, 2,4,6-trimethyl benzoyldiphenyl phosphine oxide and 3-mercaptopropyl trimethoxysilane, and continuously stirring the mixture for 0.5 to 1 hour. The product of the invention is simple in use and high performance and tests show that the product of the invention has good repair effect on the micro cracks of the automotive glass.
Description
Technical field
The present invention relates to a kind of UV-light to visible light solidifying material, relate in particular to a kind of Photocurable adhesive that is applicable to vehicle glass fine crack Rapid-Repair and preparation method thereof.
Background technology
Along with rapid economic development, expect Chinese automobile output in 2010 and will reach 10,000,000, recoverable amount reaches 55,000,000, as the shatter proof glass of important subsidiary material, also will have a larger increase.In automobile use procedure, glass unavoidably can produce fine crack problem due to unexpected, affects attractive in appearance; If do not processed, along with time lengthening, due to reasons such as vibrations, crackle is expansion constantly, until break, affects security, and how economic, easy, this crackle of fast processing, prevents trouble before it happens, and is the problem that officer and car owner have to face.
Summary of the invention
The invention provides a kind of Photocurable adhesive of repairing for vehicle glass fine crack and preparation method thereof, this Photocurable adhesive is used simple fast, and repair efficiency is very good.
The present invention is achieved by the following technical solutions: a kind of Photocurable adhesive of repairing for vehicle glass fine crack, and its component and content are as follows:
Aliphatic polyester type polyurethane diacrylate 20-30%
Pure acrylic acid ester oligomer 10-20%
Isobornyl acrylate 20-30%
Hydroxyethyl methylacrylate 15-25%
Dodecylacrylate 20-30%
Pre-treatment nano silicon 1-5%
2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone 1-5%
1-hydroxy cyclohexyl phenylketone 1-5%
TMDPO 0.5-2%
3-sulfydryl propyl trimethoxy silicane 1-2%.
Preferably, described pre-treatment nano silicon is, with γ-methacryloxypropyl trimethoxy silane, silicon-dioxide is carried out to surface grafting pre-treatment.
Preferably, the molecular weight of described aliphatic polyester type polyurethane diacrylate is 5000, and the molecular weight of described pure acrylic acid ester oligomer is 3000.
The present invention also provides the preparation method of this Photocurable adhesive, comprises the steps:
(1). first by isobornyl acrylate, hydroxyethyl methylacrylate, dodecylacrylate, add container to mix;
(2). secondly slowly add pre-treatment nano silicon, stir to prevent caking simultaneously, after disperseing completely, become colourless transparent liquid;
(3). then add aliphatic polyester type polyurethane diacrylate and pure acrylic acid ester oligomer, 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxy cyclohexyl phenylketone, 2; 4; 6-trimethylbenzoyl diphenyl phosphine oxide, 3-sulfydryl propyl trimethoxy silicane, continue stirring and within 0.5~1 hour, make described Photocurable adhesive.
After prepared by product of the present invention, after tested, automaobile glass repairing-mending has been reached to better effects.
Its advantage main manifestations is:
1, use simply, use simply, glue is splashed into cracks and get final product rapid permeability, Automated shade hair line.
2, solidify conveniently, with 100W, from ballast high voltage mercury lamp, press close to irradiate 30-50 second, or with solar radiation, also can meet the demands.
3, excellent property, water white transparency after repairing, crackle on glass disappears, and glued membrane is tough, water-tolerant, automobile continues, in use procedure, crack propagation phenomenon can not occur.
Photocurable adhesive of the present invention, various constituent materials convenient sources, preparation process is simple, has reduced the final product quality fluctuation that material slight error may cause.
Embodiment
Below by embodiment, the present invention is further elaborated.
Under normal temperature and pressure, respectively according to each component of appointment in following table by isobornyl acrylate, hydroxyethyl methylacrylate, dodecylacrylate, add container to mix; Then slowly add pre-treatment nano silicon, stir to prevent caking simultaneously, after disperseing completely, become colourless transparent liquid; Finally add aliphatic polyester type polyurethane diacrylate and pure acrylic acid ester oligomer, 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxy cyclohexyl phenylketone, 2; 4; 6-trimethylbenzoyl diphenyl phosphine oxide, 3-sulfydryl propyl trimethoxy silicane, continue to stir 0.5-1 hour.After sampling Detection is qualified, filters and make this Photocurable adhesive.Whole making processes should be noted moistureproof lucifuge.
Each component concentration (mass percent) | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
Isobornyl acrylate | 20 | 23 | 28 | 21 | 21 | 20 |
Hydroxyethyl methylacrylate | 18 | 15 | 16 | 15 | 15 | 22 |
Dodecylacrylate | 20 | 24 | 20 | 20 | 21 | 20 |
Pre-treatment nano silicon | 3 | 1 | 1 | 2 | 1 | 4.5 |
Aliphatic polyester type polyurethane diacrylate | 20 | 20 | 21 | 26 | 20 | 20 |
Pure acrylic acid ester oligomer | 13 | 10 | 10 | 10 | 16.5 | 10 |
2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone | 1 | 3 | 1 | 2 | 1 | 1 |
1-hydroxy cyclohexyl phenylketone | 3 | 2 | 1.5 | 2.5 | 1 | 1 |
TMDPO | 0.5 | 1 | 0.5 | 0.5 | 1.5 | 0.5 |
3-sulfydryl propyl trimethoxy silicane | 1.5 | 1 | 1 | 1 | 2 | 1 |
The light curing agent product that the various embodiments described above are made carries out performance test, and result is as follows:
Glue characteristic:
Vapour density: overweight density of air (25 ℃): 1.15 grams/cc
Viscosity: (25 ℃) are 100 smells (CP): low
Outward appearance: yellowish transparent refractive rate (25 ℃): 1.51
Glue film performance:
Transmittance (%) > 90
Elongation at break (%) 15
Hardness (Shao D) 80
Test result shows that the Photocurable adhesive of this patent has extraordinary effect for the repairing of vehicle glass fine crack.
Those skilled in the art will recognize that; above-mentioned embodiment is exemplary; in order to make those skilled in the art can better understand this patent content; should not be understood as the restriction to this patent protection domain; so long as disclose spiritual do any according to this patent, be equal to change or modify, all falling into this patent protection domain.
Claims (3)
1. for a Photocurable adhesive for vehicle glass sand holes and crackle Rapid-Repair, it is characterized in that, component and the mass percent of described Photocurable adhesive are as follows
Described pre-treatment nano silicon is, with γ-methacryloxypropyl trimethoxy silane, silicon-dioxide is carried out to surface grafting pre-treatment.
2. Photocurable adhesive according to claim 1, is characterized in that, the viscosity-average molecular weight of described aliphatic polyester type polyurethane diacrylate is 5000, and the viscosity-average molecular weight of described pure acrylic acid ester oligomer is 3000.
3. a method of preparing Photocurable adhesive as claimed in claim 1 or 2, is characterized in that:
(1). first by isobornyl acrylate, hydroxyethyl methylacrylate, dodecylacrylate, add container to mix;
(2). secondly slowly add pre-treatment nano silicon, stir to prevent caking simultaneously, after disperseing completely, become colourless transparent liquid;
(3). then add aliphatic polyester type polyurethane diacrylate and pure acrylic acid ester oligomer, 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxy cyclohexyl phenylketone, 2; 4; 6-trimethylbenzoyl diphenyl phosphine oxide, 3-sulfydryl propyl trimethoxy silicane, continue stirring and within 0.5~1 hour, make described Photocurable adhesive.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201010178267.1A CN101864265B (en) | 2010-05-18 | 2010-05-18 | Photocured adhesive for repairing micro cracks of automotive glass and preparation method thereof |
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CN201010178267.1A CN101864265B (en) | 2010-05-18 | 2010-05-18 | Photocured adhesive for repairing micro cracks of automotive glass and preparation method thereof |
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CN101864265A CN101864265A (en) | 2010-10-20 |
CN101864265B true CN101864265B (en) | 2014-10-15 |
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CN201010178267.1A Expired - Fee Related CN101864265B (en) | 2010-05-18 | 2010-05-18 | Photocured adhesive for repairing micro cracks of automotive glass and preparation method thereof |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105295822A (en) * | 2015-12-09 | 2016-02-03 | 刘义贤 | Photo-curing glass remediation glue as well as preparation method and application thereof |
CN106281176B (en) * | 2016-07-28 | 2019-04-19 | 孙涛 | A kind of windshield renovation agent and preparation method thereof |
GB201715588D0 (en) * | 2017-09-26 | 2017-11-08 | Belron Int Ltd | Curing repair resin |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101356247A (en) * | 2005-12-15 | 2009-01-28 | 亨斯迈先进材料(瑞士)有限公司 | Multiphase acrylic adhesives |
CN101649175A (en) * | 2009-08-14 | 2010-02-17 | 成都航天明江科技实业有限公司 | Ultraviolet curing urethane acrylate adhesive and preparation method thereof |
CN101701143A (en) * | 2009-09-23 | 2010-05-05 | 上海鼎道科技发展有限公司 | Ultraviolet light curing adhesive and preparation method thereof |
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2010
- 2010-05-18 CN CN201010178267.1A patent/CN101864265B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101356247A (en) * | 2005-12-15 | 2009-01-28 | 亨斯迈先进材料(瑞士)有限公司 | Multiphase acrylic adhesives |
CN101649175A (en) * | 2009-08-14 | 2010-02-17 | 成都航天明江科技实业有限公司 | Ultraviolet curing urethane acrylate adhesive and preparation method thereof |
CN101701143A (en) * | 2009-09-23 | 2010-05-05 | 上海鼎道科技发展有限公司 | Ultraviolet light curing adhesive and preparation method thereof |
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