CN101807446A - Cable composite core and manufacturing method thereof - Google Patents

Cable composite core and manufacturing method thereof Download PDF

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Publication number
CN101807446A
CN101807446A CN 201010138824 CN201010138824A CN101807446A CN 101807446 A CN101807446 A CN 101807446A CN 201010138824 CN201010138824 CN 201010138824 CN 201010138824 A CN201010138824 A CN 201010138824A CN 101807446 A CN101807446 A CN 101807446A
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resin
carbon fiber
glass fibre
composite core
mixture
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CN101807446B (en
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张国志
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Abstract

The invention provides a cable composite core with high temperature resistance, ageing resistance, high tensile strength, extremely high toughness, simple process and small equipment investment and a manufacturing method thereof. The cable composite core is formed by inner layer carbon fiber, outer layer glass fiber and mixed resin matrix adhered on the inner layer carbon fiber and the outer layer glass fiber in longitudinal directional distribution. The manufacturing method is implemented as follows: 1, preparing mixed resin and respectively pouring the mixed resin into three resin grooves; 2, placing the carbon fiber and the glass fiber on creels respectively, leading out by a yarn guide plate in a multi-beam manner, and drying by an infrared heater; 3, performing size soaking on the carbon fiber by an intermediate resin groove, performing size soaking on the glass fiber via the other two resin grooves at the two sides, and premolding; and 4, finishing moulding by a stock mould, entering in a thermocuring moulding mould for curing and moulding, drying, performing secondary curing, hauling by a hauling machine and rolling by a winding machine.

Description

A kind of cable composite core and manufacture method thereof
Technical field
The present invention be more particularly directed to a kind of cable composite core and manufacture method thereof.
Background technology
Traditional cable core is a steel core, and steel core cable operating temperature range is little, the coefficient of expansion is big, modulus of elasticity is low.Composite core is being included at least a fortifying fibre in the thermosetting resin matrix, and its working temperature in 90-230 ℃ scope, has the higher modulus of elasticity and the littler coefficient of expansion greatly." aluminum conductor composite core strengthens cable and manufacture method " is provided in CN1649718A, and it is included in portrait orientation and basic continuous reinforcing fiber in the thermosetting resin matrix, can work in about 90~230 ℃ scope.Manufacture method is: the fibre bundle of predetermined number is provided, and the guiding fibre bundle uses B stage stove and a plurality of cover that separates by being full of the dip tank of resin, so that moulding and the described fibre bundle of compression, and solidify the composite core parts.Above-mentioned compound core reinforced cable is a thermosetting resin only owing to matrix, and toughness is undesirable, cost of raw material height, and heatproof is still not high enough, and the surface is not wear-resisting, complex process, equipment investment is big.
Summary of the invention
The technical problem to be solved in the present invention provide a kind of high temperature resistant, anti-aging, hot strength is high, have high toughness, raw material all domesticize, production cost is low, technology is simple, cable composite core that equipment investment is little and manufacture method thereof.
The cable composite core that the present invention relates to, be the internal layer carbon fiber that distributes by portrait orientation and glass outer fiber and constitute attached to the hybrid resin matrix on internal layer carbon fiber and the glass outer fiber, according to composite core total weight carbon fiber 56-66%, glass fibre 12-18% and hybrid resin 22-26%, described hybrid resin is by mixture A and the phosphorus chloride that accounts for mixture A weight 0.2-0.8%, the benzyl dimethylamine of 0.5-1.1%, the inner pattern releasing agent applicable INT-1846N of 1.7-2.3%, the dimethicone of 1.2-1.8% is formed, described mixture A is by two resorcinol four glycidol ether 2.8-3.2 parts according to ratio of weight and number, 1 part of FB resin, 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydride 2.8-3.2 part, 3,3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of composition of HET acid acid anhydride.
Above-mentioned cable composite core also adds the alumina in Nano level account for hybrid resin total amount 0.5-2% in attached to the hybrid resin of glass fibre, playing wear-resisting effect, and improve insulation property.
The manufacture method of the cable composite core that the present invention relates to, its step is as follows:
1, gets two resorcinol four glycidol ether 2.8-3.2 parts, 1 part of FB resin and 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydride 2.8-3.2 part, 3 according to weight ratio, 3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of mixing of HET acid acid anhydride make mixture A; Getting phosphorus chloride 0.2-0.8%, benzyl dimethylamine 0.5-1.1% in mixture A weight 100% adds among the mixture A as promoter, get inner pattern releasing agent applicable INT-1846N1.7-2.3%, dimethicone 1.2-1.8% and add among the mixture A, make hybrid resin as release agent; Hybrid resin is poured in the resin storage tank;
2, be that the carbon fiber of 4400-5500Mpa and glass fibre that hot strength is 3000-3800Mpa are placed on the creel respectively with hot strength, being multi beam through the guide plate draws, wherein carbon fiber is drawn at guide plate middle part, glass fibre is drawn in guide plate both sides, through the infrared heater oven dry, remove excessive moisture again;
3, after the oven dry of carbon fiber and glass fibre, through the guide plate carbon fiber process is positioned at a middle resin storage tank soaking paste, glass fibre through other two the resin storage tank soaking paste that being positioned at both sides, according to weight ratio carbon fiber 56-66%, glass fibre 12-18%, hybrid resin 22-26%; Draw through the guide plate respectively then, the glass fibre of both sides carries out preforming through the semicircular arc preformed board, the central socket that middle carbon fiber enters stock mould, the preformed glass fibre of process enters the circular horn mouth between stock mould and the hot curing mould inlet, simultaneously resin unnecessary on the fiber is removed and is back to resin storage tank and utilize;
4, the carbon fiber and the glass fibre of the unnecessary resin of removal enter the hot curing mould that length is 1.4-2.4 rice, draw with the speed that 120-240mm/ divides;
5, the thermoset forming mould is divided into first section and second section according to length at 1: 1; Control first section temperature 220-240 ℃, make the thick resin fusing that is immersed on the fiber; Control second section temperature 180-220 ℃, make the resin solidification moulding;
6, pass through oven for drying then, 120-180 ℃ of control oven temperature carries out regelate, passes through hauling machine again to the winder rolling.
The manufacture method of above-mentioned cable composite core adds the alumina in Nano level that accounts for hybrid resin total weight 0.5-2% at the resin storage tank that is positioned at both sides, so that outer field glass fibre is more wear-resisting.
The manufacture method of above-mentioned cable composite core, the control hauling speed is the 150-200mm/ branch during traction.
The present invention's soaking paste in the resin storage tank that contains thermosetting resin (two resorcinol four glycidol ethers, FB resin), thermoplastic resin (thermoplasticity Peng Fen Chuo resin), curing agent, promoter and remover with carbon fiber and glass fibre, wherein two resorcinol four glycidol ethers are liquid, high temperature resistant (200-250 ℃), corrosion-resistant, anti-aging; The FB resin is Powdered, and anti-300-400 ℃ high temperature can anti-100 kilo-ampere electric currents, and high flame retardant is anti-aging; Thermoplasticity Peng Fen Chuo resin is Powdered, high flame retardant, and good toughness, and the climate change performance is good, can improve cable toughness, and can form bonding with thermosetting resin cured.Add curing agent in hybrid resin, wherein the methyl carbic anhydride is a liquid, and heat distortion temperature height, good electrical property are high temperature resistant, anti-aging; 3,3`, 4,4`-benzophenone tetracarboxylic dianhydride heatproof can reach 240-290 ℃, can speed curing rate.Theoretical Calculation, get two resorcinol four glycidol ethers, FB resin and 3,3`, 4,4`-benzophenone tetracarboxylic dianhydride's heatproof number range median can this composite core heatproof number range median be 280 ℃, through actual detected, adopt the cable heatproof of this composite core can reach 235-275 ℃, anti-aging more than 70 years, hot strength 2500~2800Mpa, hardness Barcol 58-65, take-up diameter is 100 times of composite core diameter.And the cost of material that adopts is low, performance good, intensity is high, and production technology is simple, and equipment investment is little, adopts common extruder to produce, and greatly reduces production cost.
Description of drawings
Fig. 1 is a process chart of the present invention;
Fig. 2 is an A-A cutaway view among Fig. 1.
Embodiment
Embodiment 1
As shown in the figure, the cable composite core that the present invention relates to, be the internal layer carbon fiber that distributes by portrait orientation and glass outer fiber and constitute attached to the hybrid resin matrix on internal layer carbon fiber and the glass outer fiber, according to composite core total weight carbon fiber 56%, glass fibre 18% and hybrid resin 26%, described hybrid resin is by mixture A and the phosphorus chloride that accounts for mixture A weight 0.2%, 0.5% benzyl dimethylamine, 1.7% inner pattern releasing agent applicable INT-1846N, 1.2% dimethicone is formed, described mixture A is by 2.8 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin) according to ratio of weight and number, 1 part of FB resin, 1 part of thermoplasticity Peng Fen Chuo resin, 2.8 parts of methyl carbic anhydrides, 3,3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride, 1 part of composition of HET acid acid anhydride, described FB resin model is THC-800.
Embodiment 2
The cable composite core that the present invention relates to, be the internal layer carbon fiber that distributes by portrait orientation and glass outer fiber and constitute attached to the hybrid resin matrix on internal layer carbon fiber and the glass outer fiber, according to composite core total weight carbon fiber 66%, glass fibre 12% and hybrid resin 22%, described hybrid resin is by mixture A and the phosphorus chloride that accounts for mixture A weight 0.8%, 1.1% benzyl dimethylamine, 2.3% inner pattern releasing agent applicable INT-1846N, 1.8% dimethicone is formed, described mixture A is by 3.2 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin) according to ratio of weight and number, 1 part of FB resin, 1 part of thermoplasticity Peng Fen Chuo resin, 3.2 parts of methyl carbic anhydrides, 3,3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride, 1 part of composition of HET acid acid anhydride, described FB resin model is THC-800.
Embodiment 3
The cable composite core that the present invention relates to is the internal layer carbon fiber that distributed by portrait orientation and glass outer fiber and constitutes attached to the hybrid resin matrix on internal layer carbon fiber and the glass outer fiber, according to composite core total weight carbon fiber 60%, glass fibre 16% and hybrid resin 24%, described hybrid resin is by mixture A and the phosphorus chloride that accounts for mixture A weight 0.5%, 0.9% benzyl dimethylamine, 2.0% inner pattern releasing agent applicable INT-1846N, 1.5% dimethicone is formed, described mixture A is by 3 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin) according to ratio of weight and number, 1 part of FB resin, 1 part of thermoplasticity Peng Fen Chuo resin, 3 parts of methyl carbic anhydrides, 3,3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride, 1 part of composition of HET acid acid anhydride, described FB resin model is THC-800.
Embodiment 4
Among the foregoing description 1-embodiment 3, in attached to the hybrid resin of glass fibre, also add the alumina in Nano level that accounts for hybrid resin total weight 1% (or 0.5 or 2%).
Embodiment 5
The manufacture method of the cable composite core that the present invention relates to, its step is as follows:
1, gets 2.8 parts of 2.8 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin), 1 part of FB resin and 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydrides, 3 according to weight ratio, 3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of mixing of HET acid acid anhydride, described FB resin model is THC-800, makes mixture A; Get phosphorus chloride 0.2%, benzyl dimethylamine 0.5% as among the promoter adding mixture A in mixture A weight 100%, take off in getting and touch agent INT-1846N 1.7%, dimethicone 1.2%, make hybrid resin as among the release agent adding mixture A; Respectively hybrid resin is poured into three resin storage tanks;
2, be that the carbon fiber of 4400-5500Mpa and glass fibre that hot strength is 3000-3800Mpa are placed on the creel respectively with hot strength, being multi beam through the guide plate draws, wherein carbon fiber is drawn at guide plate middle part, glass fibre is drawn in guide plate both sides, through the infrared heater oven dry, remove excessive moisture again;
3, after the oven dry of carbon fiber and glass fibre, through the guide plate carbon fiber process is positioned at a middle resin storage tank soaking paste, glass fibre through other two the resin storage tank soaking paste that being positioned at both sides, according to weight ratio carbon fiber 56%, glass fibre 18% and hybrid resin 26%; Draw through the guide plate respectively then, the glass fibre of both sides carries out preforming through the semicircular arc preformed board, the central socket that middle carbon fiber enters stock mould, the preformed glass fibre of process enters the circular horn mouth between stock mould and the hot curing mould inlet, simultaneously resin unnecessary on the fiber is removed and is back to resin storage tank and utilize;
4, removing the carbon fiber of unnecessary resin and glass fibre, to enter length be 1.4 meters hot curing mould, draws with the speed that 120-160mm/ divides;
5, the thermoset forming mould is divided into first section and second section according to length at 1: 1; Control first section temperature 220-230 ℃, make the thick resin fusing that is immersed on the fiber; Control second section temperature 180-200 ℃, make the resin solidification moulding;
6, pass through oven for drying then, 120-150 ℃ of control oven temperature carries out regelate, passes through hauling machine again to the winder rolling.
Embodiment 6
The manufacture method of the cable composite core that the present invention relates to, its step is as follows:
1, gets 3.2 parts of 3.2 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin), 1 part of FB resin and 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydrides, 3 according to weight ratio, 3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of mixing of HET acid acid anhydride, described FB resin model is THC-800, makes mixture A; Get phosphorus chloride 0.8%, benzyl dimethylamine 1.1% as among the promoter adding mixture A in mixture A weight 100%, get inner pattern releasing agent applicable INT-1846N 2.3%, dimethicone 1.8%, make hybrid resin as among the release agent adding mixture A; Respectively hybrid resin is poured into three resin storage tanks;
2, be that the carbon fiber of 4400-5500Mpa and glass fibre that hot strength is 3000-3800Mpa are placed on the creel respectively with hot strength, being multi beam through the guide plate draws, wherein carbon fiber is drawn at guide plate middle part, glass fibre is drawn in guide plate both sides, through the infrared heater oven dry, remove excessive moisture again;
3, after the oven dry of carbon fiber and glass fibre, through the guide plate carbon fiber process is positioned at a middle resin storage tank soaking paste, glass fibre through other two the resin storage tank soaking paste that being positioned at both sides, according to weight ratio carbon fiber 66%, glass fibre 12% and hybrid resin 22%; Draw through the guide plate respectively then, the glass fibre of both sides carries out preforming through the semicircular arc preformed board, the central socket that middle carbon fiber enters stock mould, the preformed glass fibre of process enters the circular horn mouth between stock mould and the hot curing mould inlet, simultaneously resin unnecessary on the fiber is removed and is back to resin storage tank and utilize;
4, removing the carbon fiber of unnecessary resin and glass fibre, to enter length be 2.4 meters hot curing mould, draws with the speed that 200-240mm/ divides;
5, the thermoset forming mould is divided into first section and second section according to length at 1: 1; Control first section temperature 230-240 ℃, make the thick resin fusing that is immersed on the fiber; Control second section temperature 200-220 ℃, make the resin solidification moulding;
6, pass through oven for drying then, 150-180 ℃ of control oven temperature carries out regelate, passes through hauling machine again to the winder rolling.
Embodiment 7
1, gets 3 parts of 3 parts of two resorcinol four glycidol ethers (being F-76 epoxy resin), 1 part of FB resin and 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydrides, 3 according to weight ratio, 3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of mixing of HET acid acid anhydride, described FB resin model is THC-800, makes mixture A; Get phosphorus chloride 0.5%, benzyl dimethylamine 0.8% as among the promoter adding mixture A in mixture A weight 100%, get inner pattern releasing agent applicable INT-1846N 2.0%, dimethicone 1.5%, make hybrid resin as among the release agent adding mixture A; Respectively hybrid resin is poured into three resin storage tanks;
2, be that the carbon fiber of 4400-5500Mpa and glass fibre that hot strength is 3000-3800Mpa are placed on the creel respectively with hot strength, being multi beam through the guide plate draws, wherein carbon fiber is drawn at guide plate middle part, glass fibre is drawn in guide plate both sides, again through the infrared heater oven dry;
3, after the oven dry of carbon fiber and glass fibre, through the guide plate carbon fiber process is positioned at a middle resin storage tank soaking paste, glass fibre through other two the resin storage tank soaking paste that being positioned at both sides, according to weight ratio carbon fiber 60%, glass fibre 15% and hybrid resin 25%; Draw through the guide plate respectively then, the glass fibre of both sides carries out preforming through the semicircular arc preformed board, the central socket that middle carbon fiber enters stock mould, the preformed glass fibre of process enters the circular horn mouth between stock mould and the hot curing mould inlet, simultaneously resin unnecessary on the fiber is removed and is back to resin storage tank and utilize;
4, removing the carbon fiber of unnecessary resin and glass fibre, to enter length be 1.8 meters hot curing mould, draws with the speed that 150-200mm/ divides;
5, the thermoset forming mould is divided into first section and second section according to length at 1: 1; Control first section temperature 225-235 ℃, make the thick resin fusing that is immersed on the fiber; Control second section temperature 190-210 ℃, make the resin solidification moulding;
6, pass through oven for drying then, 140-160 ℃ of control oven temperature carries out regelate, passes through hauling machine again to the winder rolling.
Embodiment 8
Two resin storage tanks that are arranged in both sides in embodiment 5-embodiment 7 add the alumina in Nano level that accounts for hybrid resin total weight 1% (or 0.5 or 2%) respectively.

Claims (5)

1. cable composite core, be the internal layer carbon fiber that distributes by portrait orientation and glass outer fiber and constitute attached to the hybrid resin matrix on internal layer carbon fiber and the glass outer fiber, it is characterized in that: according to composite core total weight internal layer carbon fiber 56-66%, glass outer fiber 12-18% and hybrid resin 22-26%, described hybrid resin is by mixture A and the phosphorus chloride that accounts for mixture A weight 0.2-0.8%, the benzyl dimethylamine of 0.5-1.1%, take off in the 1.7-2.3% and touch agent INT-1846N, the dimethicone of 1.2-1.8% is formed, described mixture A is by two resorcinol four glycidol ether 2.8-3.2 parts according to ratio of weight and number, 1 part of FB resin, 1 part of thermoplasticity Peng Fen Chuo resin, methyl carbic anhydride 2.8-3.2 part, 3,3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride, 1 part of composition of HET acid acid anhydride.
2. cable composite core according to claim 1 is characterized in that: also add the alumina in Nano level that accounts for hybrid resin total amount 0.5-2% in attached to the hybrid resin of glass fibre.
3. the manufacture method of a cable composite core is characterized in that:
3.1, get two resorcinol four glycidol ether 2.8-3.2 parts, 1 part of FB resin and 1 part of thermoplasticity boron phenolic acid resin, methyl carbic anhydride 2.8-3.2 part, 3 according to weight ratio, 3`, 4,1 part of 4`-benzophenone tetracarboxylic dianhydride and 1 part of mixing of HET acid acid anhydride make mixture A; Getting phosphorus chloride 0.2-0.8%, benzyl dimethylamine 0.5-1.1% in mixture A weight 100% adds among the mixture A as promoter, get inner pattern releasing agent applicable INT-1846N1.7-2.3%, dimethicone 1.2-1.8% and add among the mixture A, make hybrid resin as release agent; Respectively hybrid resin is poured into three resin storage tanks;
3.2, be that the carbon fiber of 4400-5500Mpa and glass fibre that hot strength is 3000-3800Mpa are placed on the creel respectively with hot strength, being multi beam through the guide plate draws, wherein carbon fiber is drawn at guide plate middle part, glass fibre is drawn in guide plate both sides, through the infrared heater oven dry, remove excessive moisture again;
3.3, after the oven dry of carbon fiber and glass fibre, through the guide plate carbon fiber process is positioned at a middle resin storage tank soaking paste, glass fibre through other two the resin storage tank soaking paste that being positioned at both sides, according to weight ratio carbon fiber 56-66%, glass fibre 12-18%, hybrid resin 22-26%; Draw through the guide plate respectively then, the glass fibre of both sides carries out preforming through the semicircular arc preformed board, the central socket that middle carbon fiber enters stock mould, the preformed glass fibre of process enters the circular horn mouth between stock mould and the hot curing mould inlet, simultaneously resin unnecessary on the fiber is removed and is back to resin storage tank and utilize;
3.4, carbon fiber and the glass fibre of removing unnecessary resin enter the hot curing mould that length is 1.4-2.4 rice, draw with the speed that 120-240mm/ divides;
3.5, the thermoset forming mould is divided into first section and second section according to length at 1: 1; Control first section temperature 220-240 ℃, make the thick resin fusing that is immersed on the fiber; Control second section temperature 180-220 ℃, make the resin solidification moulding;
3.6, pass through oven for drying then, 120-180 ℃ of control oven temperature carries out regelate, passes through hauling machine again to the winder rolling.
4. the manufacture method of cable composite core according to claim 3 is characterized in that: add the alumina in Nano level that accounts for hybrid resin total weight 0.5-2% at the resin storage tank that is arranged in both sides.
5. the manufacture method of cable composite core according to claim 3 is characterized in that: the control hauling speed is the 150-200mm/ branch during traction.
CN2010101388247A 2010-04-01 2010-04-01 Cable composite core and manufacturing method thereof Expired - Fee Related CN101807446B (en)

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Cited By (12)

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CN102024518A (en) * 2010-11-01 2011-04-20 山东大学 Composite wire core bar with thermoplastic resin substrate and preparation die and process thereof
CN102063969A (en) * 2010-12-15 2011-05-18 沈阳中恒新材料有限公司 Manufacturing method of carbon fiber composite mandril
CN102176345A (en) * 2010-12-16 2011-09-07 北京化工大学 Hybrid fiber pultruded composite material, and preparation method and molding device thereof
CN102394149A (en) * 2011-11-09 2012-03-28 王兆进 Processing mold used for carbon fiber complex core pressing moulding
CN102427618A (en) * 2011-11-09 2012-04-25 王兆进 Heating device for manufacturing carbon fiber composite core
CN102810346A (en) * 2012-08-07 2012-12-05 中复碳芯电缆科技有限公司 Carbon fiber composite material cable and preparation method of cable core thereof
CN103459314A (en) * 2011-03-31 2013-12-18 株式会社Orc制作所 Carbon fiber bulk
CN103858181A (en) * 2011-04-12 2014-06-11 提克纳有限责任公司 Composite core for electrical transmission cables
CN104183328A (en) * 2013-05-23 2014-12-03 河南科信电缆有限公司 Carbon fiber core photoelectric composite self-temperature-measurement cable
CN105118574A (en) * 2013-02-05 2015-12-02 胡妍 Manufacturing method for cable with excellent heatproof and mechanical properties
CN106611628A (en) * 2015-10-21 2017-05-03 国网智能电网研究院 Composite core and preparation method thereof
CN114368172A (en) * 2021-12-24 2022-04-19 四川东树新材料有限公司 Squeezing and drawing method of polyurethane carbon glass hybrid drawing plate for wind power blade

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EP1124235A2 (en) * 2000-02-08 2001-08-16 William Brandt Goldsworthy Composite reinforced electrical transmission conductor
CN1649718A (en) * 2002-04-23 2005-08-03 合成科技公司 Aluminum conductor composite core reinforced cable and method of manufacture
CN101002288A (en) * 2004-06-17 2007-07-18 3M创新有限公司 Cable and method of making the same
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102024518B (en) * 2010-11-01 2012-03-07 山东大学 Composite wire core bar with thermoplastic resin substrate and preparation die and process thereof
CN102024518A (en) * 2010-11-01 2011-04-20 山东大学 Composite wire core bar with thermoplastic resin substrate and preparation die and process thereof
CN102063969A (en) * 2010-12-15 2011-05-18 沈阳中恒新材料有限公司 Manufacturing method of carbon fiber composite mandril
CN102063969B (en) * 2010-12-15 2012-02-01 沈阳中恒新材料有限公司 Manufacturing method of carbon fiber composite mandril
CN102176345B (en) * 2010-12-16 2013-01-02 北京化工大学 Hybrid fiber pultruded composite material, and preparation method and molding device thereof
CN102176345A (en) * 2010-12-16 2011-09-07 北京化工大学 Hybrid fiber pultruded composite material, and preparation method and molding device thereof
CN103459314B (en) * 2011-03-31 2016-08-17 株式会社Orc制作所 Carbon fiber bulk
CN103459314A (en) * 2011-03-31 2013-12-18 株式会社Orc制作所 Carbon fiber bulk
CN103858181B (en) * 2011-04-12 2016-03-30 提克纳有限责任公司 For the composite core of electrical transmission cable
CN103858181A (en) * 2011-04-12 2014-06-11 提克纳有限责任公司 Composite core for electrical transmission cables
CN102394149A (en) * 2011-11-09 2012-03-28 王兆进 Processing mold used for carbon fiber complex core pressing moulding
CN102427618A (en) * 2011-11-09 2012-04-25 王兆进 Heating device for manufacturing carbon fiber composite core
CN102810346A (en) * 2012-08-07 2012-12-05 中复碳芯电缆科技有限公司 Carbon fiber composite material cable and preparation method of cable core thereof
CN105118574A (en) * 2013-02-05 2015-12-02 胡妍 Manufacturing method for cable with excellent heatproof and mechanical properties
CN105336429A (en) * 2013-02-05 2016-02-17 胡妍 Method for manufacturing composite-material cable
CN104183328A (en) * 2013-05-23 2014-12-03 河南科信电缆有限公司 Carbon fiber core photoelectric composite self-temperature-measurement cable
CN106611628A (en) * 2015-10-21 2017-05-03 国网智能电网研究院 Composite core and preparation method thereof
CN106611628B (en) * 2015-10-21 2019-02-19 国网智能电网研究院 A kind of composite core and preparation method thereof
CN114368172A (en) * 2021-12-24 2022-04-19 四川东树新材料有限公司 Squeezing and drawing method of polyurethane carbon glass hybrid drawing plate for wind power blade

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