CN101802293A - Compositions for treating fabric - Google Patents

Abstract

Compositions for treating fabric. The compositions of the present invention may be used to improve various properties of fabrics such as the olfactory perception and/or appearance of the fabric without requiring that the fabrics be put through an entire standard laundry process. Methods of treating the fabrics are also disclosed.

Description

Be used to handle the composition of fabric

Invention field

The present invention relates to Fabrid care composition and be used to handle the method for fabric with the various character of improving fabric.Specifically, recover or improve olfactory and/or recover outward appearance to need not to make their to experience the clothes washing process of standard by reducing stench or pure and freshization so that they are suitable for wearing by the fold in the removal fold fabric (especially clothing).

Background of invention

The method of washing and storage fabric (especially clothes) can cause fabric no longer decent under normal wearing and tearing and some situation, or no longer is suitable for being worn, especially on the angle of sense of smell and vision.Therefore, seeking " freshener " product is long-awaited needs.Clean with regard to handling/as to smell impure and fresh and/or do not have with regard to the purpose of fabric (especially clothes product) of visual attraction (especially on fold or static angle), described product is easy and be easy to use fabric can being returned to the state that can wear, and the standard that need not to make their experience adopt washing machine and dryer and clothes washing process consuming time.

Many compositions as fold control combination thing are disclosed in the prior art.The fold control combination thing of commercially available acquisition comprises being tending towards relying on and contains silicone compositions and reach those of smoothing wrinkle.These commercial compositions comprise by spray dispenser and are administered on the fabric those.

The shortcoming of these compositions is that they do not comprise the water-soluble quaternary surfactant microemulsion of capacity.The applicant finds that described microemulsion can be used for making the fabric of threadbare or fold to obtain excellent smoothing wrinkle and outward appearance recovery effects fast.

Summary of the invention

The present invention relates to stable, preferred homodisperse, the more preferably translucent even more preferably transparent pure and fresh composition of quaternary salt microemulsion fabric, and relate to pure and fresh method of fabric and the goods that use the pure and fresh composition of this kind fabric.The present invention relates to comprise the fabric refreshers product of water-soluble quaternary ammonium compound (" water-soluble quaternary salt ").Be surprisingly found out that, water, water-soluble quaternary salt and substantially the water-insoluble oil mixture that mixes thing can form microemulsion, described microemulsion can provide the suitable beneficial effect that reduces fold, stench and static.

The pure and fresh composition of fabric of the present invention comprises:

A. the water that adds as the following ingredients surplus.Common amount with about 30% to about 99.9% adds entry;

B. water-soluble quaternary surfactant, the typical minimum content of the water-soluble quaternary salt reagent that comprises in the wherein said composition is at least about 0.01%, preferably at least about 0.05%, more preferably at least about 0.1%, and the typical maximum level of water-soluble quaternary salt reagent is maximum about 20%, preferably less than about 10%, and be more preferably less than about 3%, and generally about 0.2% to about 1.0% scope;

C. water-insoluble substantially oil ingredient or oil mix thing, and wherein said oil ingredient must have the clogP greater than 1.The typical minimum content of the oil ingredient that comprises in the described composition is at least about 0.001%, preferably at least about 0.005%, and even more preferably at least about 0.01%, and the typical maximum level of oil ingredient is maximum about 5.0%, preferably less than about 3%, be more preferably less than 1.5%, and generally about 0.05% to about 1% scope;

D. in order to increase required physical characteristic, can choose the non-ionic surface active agent that adds effective dose wantonly.When using, the typical minimum content of non-ionic surface active agent is at least about 0.01%, preferably at least about 0.05%, and more preferably at least about 0.1%, wherein the typical maximum level of non-ionic surface active agent is maximum about 5%, preferred about 3% or lower, and more preferably from about 1.5% or lower.

E. can choose wantonly with effective dose and add buffer to improve the resistance that described composition changes pH, wherein when using, adding is at least about 0.01% buffer, the preferred buffer that adds at least about 0.05%, and more preferably add buffer at least about 0.1%, and the typical maximum level of described buffer is at most about 3%, preferably less than about 1.5%, and is more preferably less than about 0.5%.

F. choosing wantonly to use the odor control agent of effective dose to catch/completely cut off effect so that additional stench to be provided, wherein when using, the minimum of the described odor control agent that is added is about 0.01%, preferably at least about 0.1%, and more preferably at least about 0.2%, and the typical maximum level of described odor control agent is at most about 5%, preferably less than about 3%, and is more preferably less than about 2%;

G. the optional antimicrobial that can use effective dose is with killing microorganisms or slow down microbial growth, wherein when using, the typical minimum amount of described antimicrobial is at least about 0.001%, preferably at least about 0.002%, and more preferably at least about 0.005%, and the typical maximum level of described antimicrobial is at most about 0.5%, preferably less than about 0.2%, and is more preferably less than about 0.1%;

The pH regulator agent of H. optional effective dose wherein can use described pH regulator agent to obtain about 3 to about 11, preferred about 4 to about 10, and 5 to about 9 pH more preferably from about;

I. choose the water-soluble anti-microbial preservative of solubility of effective dose wantonly, especially when anti-microbial active matter is not enough to as preservative agent.When using, the typical minimum content of these anti-microbial preservatives is at least about 0.001%, preferably at least about 0.002%, and more preferably at least about 0.005%, and when using, its typical maximum level is maximum about 0.5%, preferably less than about 0.2%, and be more preferably less than about 0.1%; And

J. Ren Xuan other water-soluble solvent, wherein when using, the typical minimum content of these water-soluble solvents is at least about 0.05%, preferably at least about 0.1%, and more preferably at least about 0.2%, and when using, its typical maximum level is maximum about 8%, preferably less than about 5%, and be more preferably less than about 3%;

Wish that wherein described composition is substantially free of any material that will damage fabric under service condition.

In a non-limiting embodiments, fabric refreshers composition as herein described is incorporated in the spray dispenser to form goods, described goods are convenient to freshener compositions-treated fabric and/or the surface with effective dose, but when on fabric, becoming dry, except that the recovery of fading, it is difficult for being discovered.Described spray dispenser comprises the sprayer unit of manual drives and non-manual drives (operation) and comprises the container of described fabric refreshers composition.In an embodiment of fabric refreshers composition described herein, with non-volatile inert gas as the propellant in the aerosol dispenser.

In one embodiment, adopt device that composition of the present invention is delivered on the pending surface, described device produces the small diameter drops of this paper composition.The limiting examples of this type of device comprises pressure-type spray day with fog, Alevaire and sprinkler.Selected device is delivered to composition on fabric and other surface with very little particle (drop) form, described particle (drop) preferably has about 5 μ m to about 300 μ m, more preferably from about 10 μ m are to about 200 μ m, and even more preferably from about 20 μ m to the average particle size (diameter) of about 150 μ m.

Detailed Description Of The Invention

The present invention relates to be used to handle the composition of fabric.The invention still further relates to the method that is used to prepare the present composition.The invention still further relates to goods that comprise the present composition and the method for using the present composition.Now will be in detail with reference to a plurality of embodiments of the present invention.Except as otherwise noted, all percentages, ratio and the ratio of this paper are all by weight.Unless indicate in addition, all comprise that the amount of quantity, percentage, mark and ratio all is understood that to be subjected to speech " pact " to modify, and amount is not intended to represent significant digits.Unless otherwise indicated, " one " and " described " are meant " one or more ".

The present invention is meant and can adds other step and other composition that does not influence final result used " comprising ".This term comprise term " by ... form " and " basically by ... composition ".The compositions and methods of the invention/technology can comprise, by with form by basis as herein described and restrictive condition and any additional or optional member, component, step or restrictive condition as herein described basically.

Should be appreciated that each the greatest measure limit that provides in whole specification comprises each than low numerical value limit, just low numerical value limit like this is to write out clearly equally in this article.Each the minimum value limit that provides in whole specification comprises each high value limit, and just high value limit like this is to write out clearly equally in this article.Each number range that provides in whole specification comprises each the narrower number range that drops in this broader numerical, and just narrower number range like this is to write out clearly equally in this article.

This paper also comprises and is used to show that these compositions have the qualitative method of interception to static on the fabric.Static or electrostatic charge are the uneven electric charges on the fabric face.This produces by " triboelectric charging " usually, and when the textile material contact was separated then, electric charge make a kind of material keep relative positive charge, and another kind had negative electrical charge by described material exchange.Friction between two surfaces can strengthen this Process of Charge Separation, and material of further dividing according to " triboelectric series " is tending towards more effectively transfer charge.

Find that the static that is present on the fabric face can be shown by contactless AC voltage detector.Contactless AC voltage detector is used to detect AC voltage, and need not to connect or the AC electric wire of contact electrification.These devices are intended to stationary fixing near alternating electric field.For example, most common use is, the probe of these devices put in the AC power supplies outlet have AC voltage to show.With described device stationary fixing, and its induction alternating voltage, and the common existence that shows voltage with sound or light.Find, above fabric face, move, show that with described device the existence of static is possible and very effective on the fabric by making contactless AC voltage detector.Not bound by theory, it is believed that described device is moved above the non-homogeneous electrostatic field that is present on the fabric, can simulate AC line voltage alternating electric field.Usually above the described fabric less than about 12 feet places, move described device with the speed of about 1f t/s.Available described instrument shows with its usual manner and has static on the fabric.Do not have static on the fabric, described instrument will show and not have any voltage.Even this preferred embodiment is to use (Rockford, Illinois) Fen Xiao the contactless voltage detector of GREENLEE G-11 by Greenlee Textron.Composition described herein both can have been eliminated the existing static that is present on the fabric, can prevent electrostatic accumulation again.

Fabric is pure and fresh:

As mentioned above, the present invention relates to be used to the method and composition that makes fabric pure and fresh, the described composition that uses effective dose at least recovers former state with impure and fresh, fabric cacodorous and/or fold.

Microemulsion is that macroscopic view goes up uniformly oil, water and surfactant mixtures on the microcosmic level, described microemulsion by the independent oily territory of being separated by the individual layer amphiphile and separately the waters constitute.As used herein, " amphiphile " is meant possess hydrophilic property and hydrophobic compound.During microemulsion had been used to recover the oil, the microemulsion that comprises anion surfactant and some micromolecule nonionic alcohol was estimated widely.There are many kinds of methods to describe microemulsion, the more common feature of describing them is: 1) outward appearance, promptly, have transparent or opaque slightly visual appearance, 2) complicated phase behavior, 3) be easy to mix and form, to obtain stable solution, 4) small grain size and big boundary area/unit volume, the 5) solvability and 6 of organic facies and water) excellent wettability.

Yet the emphasis of this work is to use microemulsion based on quaternary surfactant to reduce fold, control stench or to reduce static in the fabric environment.Be used for determining that these the key physical characteristics based on the size of the microemulsion of quaternary surfactant on the fabric are granularity and fabric wetting power.With regard to aesthetic property, the product of preferred clarification.Wish that these fabric treating microemulsion compositions have little oil-in-water granularity to help being penetrated in the fabric fibre and enough stability is provided.In addition, with regard to purpose attractive in appearance, small grain size can provide the homogeney and/or the transparency to a certain degree.As used herein, term " evenly " and " stablizing " are meant that after mixing or rocking at least 48 hours, composition can be described to have visually outward appearance uniformly.The granularity of described oil droplet is preferably about 300nm or littler, preferably about 100nm or littler, and 50nm or littler most preferably from about.For the present invention, typical oil droplet granularity can be at about 1nm to about 300nm scope.

Not bound by theory, it is believed that concrete surfactant and oil ingredient and their mol ratio are the deciding factors that forms microemulsion.The factor that helps to obtain suitable granularity is the solubility parameter of described component, their molecular dimension and molecular shape.

In addition, not bound by theory, it is believed that because the higher complete wetting ability and the hole of cotton fiber, the height effective wetting of present composition microemulsion helps described composition to permeate fabric (especially cotton) in mode fast and completely, thereby can be near the most of inner hydrogen bond in the cellulosic structure.For smoothing wrinkle, destroy and to help fixedly that the hydrogen bond of fold is important.The rapid osmotic fabric construction also helps to impel with the smoothing wrinkle better that stretches, and just applies under the situation of tension force soon after especially being administered to described composition on the fabric.This quick release can to by after applying said compositions immediately tractive or the stuetch fabrics consumer that applies tension force favourable support is provided.The quick humidification of described composition and sprawling is provided in a similar fashion on the fabric and better covers, and by better with cause stench be neutralized or the component of complexing contacts and has improved the efficient that reduces stench.Also help quaternary surfactant in the effective wetting on the fabric and covering and be distributed on the fabric face, to prevent electrostatic accumulation on fabric face, especially in the environment of drying or low humidity.

Can use wetting index to describe the wetting behavior of designated treatment composition.Of particular concern is the ability of wetting cotton clothing clothes.Wetting index is the test of measuring the wetting rate of product composition on various fabrics.Described test relates to a test products (water is the reference product) is placed on the fabric sample, and determines that a product composition is penetrated into the time required in the fabric face fully.Wetting index is defined as: be the ratio that the water reference substance of unit time of infiltrating the surface fully and test products composition infiltrate the time on surface fully with the second.Wetting index is big more, shows that wettability is good more, but and is considered to the fast multiple of speed ratio water of representative products composition wet fabric.Cotton wetting index is preferably 2 or bigger, more preferably greater than 5, and most preferably greater than 9.

Another aspect of the present invention is the improvement of moisture absorption arrangement aspect, and it can be realized by permeating fabric with described composition and they being become dry.In this regard, the moisture absorption arrangement is not meant with accepting pretreated those to be compared, and can better water be wicked into the ability in the processed fabric.This through the wicking capacity that improves can represent from skin water/sweat removed and is delivered to fabric/clothes that skin directly contacts to quicken drying and to improve the ability of skin comfort level.

With regard to the object of the invention, water-insoluble substantially oil ingredient is defined as having the calculating log P (" clogP ") greater than 1.The octanol/water distribution coefficient that described P value is the material of paying close attention to is measured, and is the ratio of its equilibrium concentration in octanol and in the water.Because the distribution coefficient of preferred component of the present invention has high numerical value, therefore represent that with their denary logarithm forms (logP) they are more easily, it is called as the logP value.These values can be calculated easily, obtain the clogP value.The clogP value of many fragrance components is reported; For example, derive from Daylight Chemical Information Systems, (Irvine, Pomona92 database Calif.) comprises many clogP values and quoting original document to Inc. (Daylight CIS).Yet the clogP value also can be calculated by " CLOGP " program that derives from Daylight CIS.The sheet phase method of described " clogP value " common Hansch and Leo is determined: referring to " Comprehensive Medicinal Chemistry " the 4th volume (C.Hansch of A.Leo, P.G.Sammens, J.B.Taylor and C.A.Ramsden edit, the 295th page, Pergamon Press, nineteen ninety).

Another source of calculating the logP value is by the Log P property prediction program (CSLogP) by ChemSilo LLC (Tewksbury, MA, 01816) issue.

A. composition

Water-soluble quaternary surfactant:

The typical minimum content of the water-soluble quaternary salt that the present composition comprises is counted at least about 0.01% by the gross weight of described composition, preferably at least about 0.05%, and more preferably at least about 0.1%, even more preferably at least about 0.2%.The typical maximum level of the water-soluble quaternary salt reagent that described composition comprises is counted at most about 20% by the gross weight of described composition, preferably less than about 10%, and be more preferably less than about 3%.The content of described reagent in described composition is generally about 0.2% to about 1.0%.

Specifically, preferred water-soluble quaternary salt compounds is a dialkyl group quaternary surfactant compound.The quaternary surfactant that suitable quaternary surfactant includes but not limited to have the following formula structure:

R wherein ₁And R ₂Be independently selected from the group of forming by following: C ₁-C ₄Alkyl, C ₁-C ₄Hydroxyalkyl, benzyl and-(C ₂H ₄O) _xH, wherein x has about 2 to about 5 value; X is an anion; And (1) R ₃And R ₄C respectively does for oneself ₆-C ₁₄Alkyl, or (2) R ₃Be C ₆-C ₁₈Alkyl, and R ₄Be selected from the group of forming by following: C ₁-C ₁₀Alkyl, C ₁-C ₁₀Hydroxyalkyl, benzyl and-(C ₂H ₄O) _xH, wherein x has 2 to 5 value.The preferred asymmetric quaternary salt compounds of the present invention is that wherein R3 and R4 are inequality, and a preferred branching and another is the compound of straight chain.

The example of preferred asymmetric quaternary salt compounds is ARQUAD HTL8-MS, and wherein X is the methyl esters sulfate ion, and R1 and R2 are methyl, and R3 is the h-tallow base that has less than 5% 1 degree of unsaturation, and R4 is the 2-ethylhexyl.ARQUAD HTL8-MS can derive from Akzo NobelChemical (Arnhem, Netherlands).

Suitable symmetry quaternary salt compounds example is UNIQUAT 22c50, and wherein X is carbonate and bicarbonate radical, and R1 and R2 are methyl, and R3 and R4 are the C10 alkyl.UNIQUAT 22c50 is the registration mark of Lonza, and in North America, can derive from Lonza Incorporated (Allendale, New Jersey).

Another example of suitable water-soluble quaternary salt compounds is the BARQUAT CME-35 that derives from Lonza, and it is a N-cetyl diethyl acetamidomalonate sulfuric acid morpholine, and has following array structure:

Oil ingredient:

Oil ingredient of the present invention representative is incorporated into water-insoluble substantially material in the described composition via microemulsion.The typical minimum content that is included in the oil ingredient in the described composition is at least about 0.001%, preferably at least about 0.005%, more preferably at least about 0.01%, and the typical maximum level of oil ingredient is maximum about 5%, preferably, be more preferably less than 1.5% less than about 3%; Typical content about 0.05% to about 1% scope.Described oil ingredient can be one-component, but is generally mixture, and represents some beneficial agent that is incorporated in the described composition usually.Described oil ingredient is generally the spices that is made of component mixture, but also can be non-fragrance material, such as replacement or unsubstituted hydrocarbon or the like.With regard to spray product, preferred described oil ingredient or mixture at room temperature for liquid to be easy to be incorporated in the described composition and to reduce the possibility of stopped nozzles when dry.

Oil ingredient of the present invention is water-insoluble substantially and can forms microemulsion.The water-insoluble substantially clogP of described composition that is meant is greater than about 1.ClogP for about 1 shows, is tending towards being assigned to described ratio of component in the octanol and is assigned in the water how about 10 times.In the oil mixture some is preferred but nonrestrictive component is branched-chain hydrocarbons and spices (when using spices).

Spices:

Fabric refreshers composition as herein described also provides joyful smell form " fragrance signal ", and it provides pure and fresh impression to handled fabric.Can set described fragrance signal to provide of short duration or long lasting fragrance more.When adding spices, it is only added with low-down content, for example by the operating weight of described composition about 0.001% to about 0.01% as the fragrance signal.

Spices also can be used as stronger smell and joins in the product and be added on the fabric.When the fabric of preferred higher degree is pure and fresh when spending, can add the spices of high level.These content can minimum is about 0.005%, and preferably at least about 0.01%, more preferably at least about 0.1%, and typical maximum level be maximum about 5%, preferably less than about 3%, and is more preferably less than about 1%.

Suitable spices, fragrance component and fragrance carrier is disclosed among the U.S. Patent Publication 2002/0035053A1 that announces with people such as Demeyere name in the U.S. Patent Publication 5,500,138 of authorizing people such as Bacon on March 19th, 1996 and on March 21st, 2002.

The spices of any kind can be incorporated in the composition of the present invention.Preferred perfume ingredients is to be applicable to be administered on fabric and the clothes those.The representative instance of this type of preferred component is shown in the U.S. Patent Publication of announcing August 29 nineteen ninety-five of authorizing people such as Kvietok 5,445,747.

When on being desirably in fabric, having lasting aromatic smell, preferably use having of effective dose at least about 240 ℃ or higher and preferred about 250 ℃ or more high boiling fragrance component.The limiting examples of this type of preferred component is shown in the U.S. Patent Publication of announcing on March 19th, 1996 of authorizing people such as Bacon 5,500,138.Also preferred the use at described fabric fold control combination described by the present invention thing handled the material that can slowly discharge fragrance component later.The limiting examples of this type of material is disclosed in authorized in people's such as Severns the U.S. Patent Publication 5,531,910 on July 2nd, 1996.

Other fragrance component can be used as solvent.In some cases, this can help to impel other spices or oil component to be incorporated in the total composition.The especially suitable example of this paper is a benzylalcohol.Benzylalcohol has limited water solubility (clogP is about 1.2), and has shown and can help other fragrance component mixture to be incorporated in these compositions.

Branched-chain hydrocarbons:

Use the effective dose hydrocarbon of abundant branching, it provides stable, preferred and evenly disperses, more preferably translucent and even the microemulsion of more preferably transparent high degree of water subtract the wrinkle composition.Described hydrocarbon component can be saturated or undersaturated, and be that volatile materials or solid are opposite, it preferably has certain carbon content and structure, at room temperature being liquid.

A limiting examples of suitable branched-chain hydrocarbons is ISOPAR V, its derive from ExxonMobileIncorporated (Irving, Texas).Another kind of suitable branched-chain hydrocarbons is PERMETHYL102A, and it derives from Presperse Incorporated (Somerset, New Jersey).

Use branched-chain hydrocarbons with suitable amount,, make preferably clear, stable microemulsion liquid mixture to mix with water-soluble quaternary surfactant and preferred perfume composition.Branched-chain hydrocarbons can be incorporated in the refresher sprays separately, or mix in advance with perfume composition and to be incorporated in the refresher sprays.

Optional other of the present invention of being used for is optional but desirable composition comprises non-ionic surface active agent, buffer, odor control agent, perfume microcapsule, cyclodextrin, low molecular weight polyols, slaine, antiseptic and preservative agent, pH regulator agent and other optional member:

Non-ionic surface active agent:

Optional but the preferred nonionic example is SURFYNOL 465, SURFYNOL104 (2,4,7,9-tetramethyl-5-decine-4,7-glycol), and the mixture of these two.Preferred mixture is 3: 1 SURFYNOL 465 and SURFYNOL 104.Described SURFYNOL surfactant can derive from Air Products and Chemicals, and Inc. (Allentown, Pennsylvania).

Another kind of preferred nonionic is the alkyl poly glucoside surfactant.The example of these surfactants is GLUCOPON 215, PLANTAREN 2000N UP and GLUCOPON 425, or the like.These surfactants can derive from Cognis Oleochemicals (Selangor, Malaysia).Because these surfactants are stable in wide pH scope, therefore as the described composition pH of appointment during away from neutrality (pH 7), these surfactants are especially available.

When the pH of product is 7 or near 7 the time, another kind of spendable nonionic surfactants type is the SILWET polyether silicon.The limiting examples of these polyether silicons is

Material, it can derive from GE Silicones.Only comprise ethyleneoxy (C ₂H ₄O) representational

Polyether silicon is as follows:

Comprise ethyleneoxy (C ₂H ₄O) and propenyloxy group (C ₃H ₆O)

The polyether silicon limiting examples is as follows:

Only comprise propenyloxy group (C ₃H ₆O)

The polyether silicon limiting examples is as follows:

When being comprised in the described composition, preferred with enough concentration

Help color restoration and flexibility can be provided.When siloxane polymer stayed harsh feeling on fabric face, this was especially preferred.Preferably

Limiting examples comprise L77, L7001, L7200, L7087, especially L-7600.

Some nonrestrictive preferred Dow

Polyether silicon comprises Dow

DC Q2-5247 (dimethyl methyl hydroxypropyl ethoxylation propoxylation siloxanes, main [CAS 68937-55-3] is made of siloxanes, EO and PO).Can be used for other limiting examples of polyether silicon among the present invention comprises and derives from Dow

Following compounds: 193,112,8600, FF-400 fluid, Q2-5220, Q4-3667, PP 5495, and derive from Toray Dow Corning Silicone Co. with title SH3771C, SH3772C, SH3773C, SH3746, SH3748, SH3749, SH8400, SF8410 and SH8700, Ltd. compound, derive from Shin-Etsu Chemical Co., Ltd. KF351 (A), KF352 (A), KF354 (A) and KF615 (A) derive from TSF4440, TSF4445, TSF4446, the TSF4452 of Toshiba SiliconeCompany.Another limiting examples is the SLM 21200 that derives from Wacker (Germany).

The emulsifying agent that some polyether silicons (especially more hydrophobic type) may need to add makes stable spray composite.This type of emulsifying agent is generally anion, nonionic, CATION, both sexes or zwitterionic surfactant or their mixture.Usually, emulsifying agent and surfactant also can be used as the spreading agent on the fabric, to sprawl active component such as siloxane polymer.

The typical minimum content of non-ionic surface active agent is at least about 0.01%, preferably at least about 0.05%, more preferably at least about 0.1%, and the typical maximum level of non-ionic surface active agent is maximum about 5%, preferably less than about 3%, and be more preferably less than about 1.5%.

Optional buffer:

Buffer can be incorporated among the present invention between preparation and operating period, to help to control the pH of product.If formulated product and spraying during use under alkaline pH, the pH that causes with carbon dioxide mix from air between then the buffer in preferred alkaline pH scope can help to prevent because of spray phase descends.With pH remain on designated value also help in and fabric on dirt or stench.Can use any suitable organic or inorganic buffer to reach suitable product pH, precondition is under used content, and it can provide enough stability to described mixture.Preferred alkaline buffer includes but not limited to, triethanolamine, glycine, arginine, carbonate, bicarbonate be such as sodium bicarbonate, or the like.

Optional odor control agent:

Provide additional stench to catch/completely cut off effect if desired, then can choose the stench controlling agent that uses effective dose wantonly.

The composition that is used for smell control belongs to U.S. Patent Publication: 5,534,165; 5,578,563; 5,663,134; 5,668,097; 5,670,475; With 5,714, disclosed type in 137.

Perfume microcapsule:

In one embodiment, described spices comprises perfume microcapsule.Suitable perfume microcapsule and spices milimicron vesicle comprise and are disclosed in the following document those: U.S. Patent Publication: 2003/215417A1; US 2003/216488A1; US 2003/158344A1; US2003/165692A1; US 2004/071742A1; US 2004/071746A1; US2004/072719A1; US 2004/072720A1; US 2003/203829A1; US2003/195133A1; US 2004/087477A1; US 2004/0106536A1.And be disclosed in U.S. Patent Publication: 6,645,479; US 6,200, and 949; US 4,882, and 220; US4,917,920; US 4,514, and 461; US RE 32713; US 4,234, and 627; And EP1,393, those among the 706A1.For the object of the invention, perfume microcapsule and spices milimicron vesicle described in term " perfume microcapsule ".In another embodiment, described spices comprises aforesaid perfume microcapsule and the spices sealed of capsule not.

Cyclodextrin:

As used herein, term " cyclodextrin " comprises any known cyclodextrin, such as the unsubstituted cyclodextrin, the especially alpha-cyclodextrin that comprise six to 12 glucose units, beta-schardinger dextrin-, gamma-cyclodextrin and/or their derivative and/or their mixture.Alpha-cyclodextrin is made of six glucose units, and beta-schardinger dextrin-is made of seven glucose units, and gamma-cyclodextrin is made of eight glucose units arranging with the concentric ring-shaped ring.The special coupling of glucose unit and conformation are given the conical molecular structure of cyclodextrin with rigidity, have the inner hollow space with designated volume.The unique shape of described cavity and physical-chemical property make described cyclodextrin molecular can absorb the organic molecule of suitable described cavity or the part (forming inclusion complex with it) of organic molecule.Many scent molecules are fit to described cavity, comprise many malodor molecules and aromatic molecules.Therefore, cyclodextrin especially has the cyclodextrin mixt of different size cavity, can be used for controlling the smell that is produced by the organic odorant of the wide spectrum that can comprise active function groups.In the presence of water, the complexing between initial ring dextrin and scent molecule fast.Yet, complex compound form degree also depend on absorb the polarity of molecule.In the aqueous solution, strongly hydrophilic molecule (those of high water soluble) only be partially absorbed (if any).Therefore, when they are present on the wetting fabric with low content, cyclodextrin not with some very low-molecular-weight organic amine and effectively complexing of acid.Yet along with water is removed, for example fabric is dried up, and some low-molecular-weight organic amine and acid have bigger affinity, and will be easier to and the cyclodextrin complexing.

When in solution, the internal cavity of cyclodextrin should keep not being filled substantially (cyclodextrin keeps not complexing) in the liquid composite as herein described, so that cyclodextrin can absorb various scent molecules when being administered to described solution on the surface.The beta-schardinger dextrin-content at room temperature of underivatized (standard) is about at most 1.85% (its solubility limit is about 1.85g in 100 gram water).Needing cyclodextrin content to be higher than in the composition of its water solubility limit, not preferred beta-schardinger dextrin-.When described composition comprised surfactant, the beta-schardinger dextrin-of underivatized generally was not preferred, because it can influence the surface-activity of the great majority preferred surfactant compatible with derivatized cyclodextrin.

Be the smell on the control fabric, described composition preferably uses with the spray form.Composition therefor of the present invention preferably comprises a small amount of cyclodextrin, so that visible spot can not occur normal the use under the content on fabric.Under service condition, preferably vision is unrecognizable when becoming dry for the solution that is used for treatment surface.With regard to service condition, the typical content of cyclodextrin in composition therefor counts about 0.01% to about 5% by the weight of described composition, and preferred about 0.1% to about 4%, and more preferably from about 0.5% to about 2%.Along with solution evaporates from fabric, the composition with higher concentration can stay unacceptable visible spots on fabric.This especially is a problem on frivolous, painted synthetic textiles, for the appearance of avoiding textile stains occurring or making textile stains minimizes, preferably with less than about 5mg cyclodextrin/every gram fabric, the content that is more preferably less than about 2mg cyclodextrin/every gram fabric is handled described fabric.By local spot is minimized, the existence of surfactant can improve outward appearance.

Low molecular weight polyols:

When having cyclodextrin, with water than low molecular weight polyols with higher, such as ethylene glycol, propylene glycol and/or glycerine, be the optional member that is preferred for improving present composition smell control performance.Not bound by theory, it is believed that a small amount of low molecular weight diol is incorporated into the formation that can strengthen cyclodextrin inclusion complexes in the composition of the present invention when fabric becomes dry.

It is believed that the more lasting ability that is retained on the fabric of the comparable water of polyalcohol makes it to form ternary complexes with cyclodextrin and some malodor molecule when fabric becomes dry.It is believed that and add the void space that glycol comes can not be had by some in the ring type filling dextrin cavity malodor molecule filling of reduced size.Used dihydroxylic alcohols is preferably glycerine, ethylene glycol, propylene glycol, diethylene glycol (DEG), dipropylene glycol or their mixture, more preferably ethylene glycol and/or propylene glycol.The cyclodextrin that is made by the method that obtains a certain amount of this type of polyalcohol is high expectations, because can use them need not to remove under the situation of polyalcohol.

Also can use for example dipropylene glycol of some polyalcohol, be dissolved in the composition of the present invention to impel some fragrance component.

Usually, in by the weight of described composition about 0.01% to about 3%, preferred about 0.05% to about 1%, more preferably from about 0.1% to about 0.5% content joins glycol in the composition of the present invention.The preferred weight ratio of low molecular weight polyols and cyclodextrin is about 2: 1,000 to about 20: 100, and more preferably from about 3: 1,000 to about 15: 100, even more preferably from about 5: 1,000 to about 10: 100, and most preferably from about 1: 100 to about 7: 100.

Slaine:

When having cyclodextrin, the present invention can choose wantonly and comprise slaine to increase the odor adsorption and/or the antimicrobial beneficial effect of cyclodextrin solution.Described slaine is selected from the group of being made up of following: mantoquita, zinc salt and their mixture.

When slaine being joined in the composition of the present invention, their content is generally about 0.05% to about 5%, preferred about 0.1% to about 3% by the weight of composition therefor, and more preferably from about 0.2% to about 2%.When using zinc salt as slaine and when needing transparent solution, need with the pH regulator of solution to less than about 7 to keep solution transparent.

When adding any odor control agent in the present composition, their content is generally about 0.01% to about 5%, preferred about 0.1% to about 3% by the weight of described composition, and more preferably from about 0.2% to about 2%.

Antiseptic and preservative agent:

Freshener composition of the present invention can choose wantonly comprise effective dose anti-microbial active matter with killing microorganisms or slow down microbial growth, wherein when using, the amount of anti-microbial active matter is preferably about 0.001% to about 0.5% by the weight of composition therefor, more preferably from about 0.002% to about 0.2%, even more preferably from about 0.005% to about 0.1%.Effectively anti-microbial active matter can be used as bactericide/disinfectant, and can be used for providing protective action to the organism that is connected on the fabric.

The example of additional preservative agent comprises the material based on the hydantoins chemistry.Comprise as by deriving from Lonza Group Ltd. (Basel based on the suitable example of the material of hydantoins chemistry, Switzerland) Dantogard 2000 and Dantogard Plus be example based on dihydroxymethyl-5, the preservative agent of 5-dimethyl hydantoin (DMDMH).

Other limiting examples of the suitable preservative agent that can be used singly or in combination is with by Rohm﹠amp; The Neolone M-10 product that Haas provides is the 2-methyl-4-isothiazoline-3-ketone and 2-methyl-3 (2H) isothiazoline of example; With by Rohm﹠amp; The Koralone B-119 that Haas provides is 1 of an example, the 2-benzisothiazole-3-ketone; With the Acticide MBS that is provided by Thor/Actichem is the methylisothiazolinone of example and the mixture of benzene iso thiazoline ketone compound; With by Rohm﹠amp; The Kathon GC that Haas provides is the methylchloroisothiazandnone of example and the mixture of methylisothiazolinone; And be 1 of example with the Proxel GXL that provides by Arch Chemicals, the 2-benzisothiazole-3-ketone.

The pH regulator agent:

Can use acidic materials that the pH of described composition is reduced to required degree.The limiting examples of suitable acid is small molecular organic acid such as citric acid and inorganic acid such as sulfuric acid or hydrochloric acid.The preferred final pH of used acid and described composition of selecting is to obtain the mixture of chemistry and physically stable.

For the pH with described composition promotes required degree, can use alkaline matter.The limiting examples of suitable alkali is generally low-molecular-weight inorganic base, as NaOH.The preferred final pH of used alkali and described composition of selecting is to obtain the mixture of chemistry and physically stable.Composition of the present invention preferably has about 3 to about 11, and preferred about 4 to about 10, and 5 to about 9 pH more preferably from about.

Other optional member:

The present composition can be chosen wantonly and comprise smell control auxiliary substance, chelating agent, antistatic additive, softening agent, insect and moth repellent, colouring agent, antioxidant, chelant, bodying agent, the drape forming controlling agent, smooth agent, the fold controlling agent, disinfectant, bactericide, Microbiological Control, the mould controlling agent, the mildew controlling agent, antivirotic, drier, anti-fouling agent, detergent, the stench controlling agent, fabric refreshers and pure and fresh degree continuity agent, the chlorine bleach odor control agent, dye-fixing agent, dye transfer inhibitor, the color retention agent, Optical Bleaching Agent, color restoration/renewing agent, anti-decolourant, brightening agent, the anti scuffing agent, anti-wear agent, fabric integrity agent, antiwear additive, anti-pilling agent, defoaming agent and defoamer, the ultra-violet protecting agent of fabric and skin, the Exposure to Sunlight fade inhibitor, anti-allergic agent, enzyme, waterproofing agent, comfortable dose of fabric, antishrinking agent, the stretch-proof agent, the stretching restorative, except siloxane molecule, also comprise active material (such as spices, siloxanes, skin conditioner, glycerine and natural active matter are such as aloe, vitamin E, sher butter etc., and their mixture) functional microcapsule.The total content of optional member is low, preferably less than about 5%, is more preferably less than approximately 3% by the weight of composition therefor, and even is more preferably less than about 2%.These optional members do not comprise other composition of above specifically mentioning.Mix smell control auxiliary substance and can strengthen the ability of cyclodextrin control smell, and widened can controlled smell type and the scope of molecular dimension.This type of material comprises for example slaine, water-soluble cationic and anionic polymer, zeolite, water soluble carbonate hydrogen salt and their mixture.

Carrier:

Preferred vector of the present invention is a water.Used water can be distilled water, deionized water or running water.Because its low cost, be easy to get, safety and Environmental compatibility, so water is main liquid-carrier.When control of needs fold and smell control beneficial effect, go back preferred aqueous solutions.

Water is highly suitable for removing or reduces the fabric fold.Not bound by theory, it is believed that water can destroy in the many fibers that make fabric keep wrinkled state and hydrogen bond between fiber.It also makes fiber swelling, lubricated and lax to help the smoothing wrinkle process.

Water also as the liquid-carrier of cyclodextrin and help cyclodextrin molecular and processed fabric on any malodor molecule between complex reaction.Dilute aqueous also provides the maximum separation of cyclodextrin molecular on fabric, thereby makes scent molecule and the interactional possibility maximization of cyclodextrin molecular.Recently find also that water is to himself having unexpected smell control effect.Find that when fabric that the water solution-treated is polluted by smell, the odour intensity that is produced by some polarity low molecular weight organic amine, acid and mercaptan is reduced.Not bound by theory, it is believed that these polarity low molecular weight organic molecules of water-soluble and reduce their vapour pressure, thereby reduce their odour intensity.

The content of liquid-carrier in the present composition is generally at least about 80% by the weight of described composition, be preferably greater than about 90%, more preferably greater than about 95%.When using the concentrated type composition, the content of liquid-carrier is generally about 50% or lower by the weight of described composition, and is preferred about 40% or lower, and more preferably from about 30% or lower.

Water-soluble solvent:

Except water, described carrier is also chosen wantonly and is comprised water-soluble substantially low molecular weight organic solvent.Limiting examples is ethanol, normal propyl alcohol, isopropyl alcohol, n-butanol, tert-butyl alcohol deodorization acetone, acetone or the like and their mixture.Low-molecular-weight alcohol can help to make the faster exsiccation of processed fabric.Also can use other solvent, such as the ether (for example ethylene glycol one hexyl ether) of ethylene glycol and propylene glycol and glycol such as glycerine, propylene glycol, dipropylene glycol, ethylene glycol, or the like.Other limiting examples comprises 1, ammediol, diethylene glycol (DEG), 1,2, the 3-glycerol, propylene carbonate, benzyl carbinol, the 2-methyl isophthalic acid, ammediol, hexylene glycol, sorbierite, polyethylene glycol, 1, the 2-hexylene glycol, 1, the 2-pentanediol, 1, the 2-butanediol, 1, the 4-butanediol, 1, the 4-cyclohexanedimethanol, pinacol, 1, the 5-hexylene glycol, 1, the 6-hexylene glycol, 2,4-dimethyl-2,4-pentanediol, 2,2,4-trimethyl-1,3-pentanediol (and ethoxylate), 2-ethyl-1, the 3-hexylene glycol, phenoxetol (and ethoxylate), other glycol ethers such as BC and dipropylene glycol n-butyl ether, ester solvent is such as adipic acid, the dimethyl esters of glutaric acid and butanedioic acid, and their mixture.Optional solvent also can be used for dissolving some shape mentioned above and keeps polymer and some siloxane polymer.Optional water-soluble low molecular weight solvent load is counted about at most 8% by the weight of total composition, about 0.05% to about 8%, preferred about 0.1% to about 5% usually, and more preferably from about 0.2% to about 3%.When using the high-load solvent in described composition, the factor that needs to consider is cost, smell, inflammability and ambient influnence.If the desired use of described composition is when it being distributed (for example spraying) in automatic drier, then not preferred inflammable organic solvent.

B. goods

The present invention also comprises composition and is used to distribute the distributor of described composition.Be applicable to the U.S. Patent Publication 7 that the limiting examples of distributing or comprising the distributor of described composition comprises sprayer such as self-pressurization formula automiser spray (such as aerosol container), triggers sprayer, distributor is authorized people such as Gerlach such as on June 13rd, 2006,059,065; Authorized people's such as Heilman U.S. Patent Publication 7,043,855 on May 16th, 2006; The U.S. Patent Publication 2004/0143994 that on July 29th, 2004 announced with people such as Barron name; With in the U.S. Patent Publication of announcing with people such as Pancheri name on July 1st, 2,004 2004/0123489 disclosed those, or the like; And sprinkler; Portability/comprise the substrate of described composition, its limiting examples comprises the substrate such as cleaning piece or pad or roller (an one limiting examples is an Adhensive dust device); Or their combination.If desired, described composition directly can be assigned on the pending fabric.

Preferably the fluid composition with effective dose is sprayed on the fabric, especially on the clothing.When with described composition spray on fabric the time, effective dose is deposited on the described fabric, make fabric become moist, or it is saturated fully by described composition, described effective dose is generally about 0.05% to about 150% by the weight of spraying fabric, preferred about 1.0% to about 75%, and more preferably from about 2% to about 25%.After fabric is sprayed, optional and preferred (for the smoothing wrinkle purpose) with fabric tension.Can be by mechanical device such as by counterweight, pulley etc., or by the method with hand tractive and stretching, implement to stretch.Usually fabric is stretched perpendicular to fold, if or its be draped, then adopt gravity as tensile force, stretch along the vertical axis of clothes.Also can be sprayed with after removing fold, it is smoothed and/or shake with hand at fabric.

Alternatively or in addition, described composition directly can be added and/or be assigned in the fabric treating utensil, its limiting examples comprises fabric washing equipment (an one limiting examples is a washing machine); Fabric drying device (an one limiting examples is a roller dryer); (an one limiting examples is disclosed in the U.S. Patent Publication 6,726,186 of authorizing people such as Gaaloul on April 27th, 2004 to the fabric refreshing apparatus; Authorized people's such as Van Hauwermeiren U.S.6 on May 17th, 2005,893,469; Authorize people's such as Pasin U.S.6 with on January 11st, 2005, in 840,068).

1. self-pressurization formula spray product

In a non-limiting embodiments, the present invention can be self-pressurization formula spray product:

(1) dispense container, it can bear required container internal pressure,

And can not break or be out of shape;

(2) propellant;

(3) the aqueous treatment preparation is to provide beneficial effect such as smoothing wrinkle and deodorizing, and described aqueous treatment preparation comprises water-soluble dialkyl group quaternary salt, comprises the oil of spices and/or hydrocarbon and the hydrocarbon and the aforesaid optional member of abundant branching;

(4) valve, spout and actuator assemblies, it can send the spray cone and the uniform surface coverage of uniform atomizing when starting.

Pressurised dispensing containers

Dispense container of the present invention can be to hold any appropriate vessel of composition under the pressure that propellant produces, and typically is called aerosol container.The people that are designed to of this type of container of metal can form know, and comprise steel (tinplate) and aluminium aerosol container.Recently, even developed plastic containers, it can be used for keeping the pressure that propellant is produced in the container.

Because aerosol container is a pressurizing vessel, therefore formulate according to contained pressure in the specification of this type of container of many countries.This has caused numerous standard industry specifications of aerosol container.For example, the standard aerosol container of the U.S. typically is categorized as no specification, 2P or 2Q container.These specifications are specified the minimum crooked pressure and the minimum wall thickness (MINI W.) of burst pressure and container.For example, show that when 54.5 ℃ (130) aerosol product have less than the pressure of 1070 kPas (" kPa ") is classified as no specification container, and typically do not discerned.Show that in the time of 54.5 ℃ the aerosol systems with the pressure between 1070kPa and 1200kPa need use and have 2P specification or higher jar structure.Show that in the time of 54.5 ℃ the aerosol systems with the pressure between 1200kPa and 1340kPa typically needs to use and has 2Q specification or higher jar structure.There is similar standard in Europe, and alternative name comprises 12 crust and 18 crust jar standards.These industrial standards have developed to keep the strictness control to the aerosol container structure.

For the present invention, the aluminium pot that satisfies the 2Q specification is desirable.This type of jar can be available from numerous aerosol container manufacturer, and these manufacturers include but not limited to CCL ContainerAerosol Division, Hermitage, Pennsylvania or Exal Container, Youngstown, Ohio.

Dispense container can have any suitable shape.The aerosol can that for example has cylindrical shape is industrially to know.In fact, also set up industrial standard jar size so that the storage tank size of certain limit to be provided.These jars are typically divided according to the overall diameter and the overall height of jar.Usually utilize the constriction jar, wherein container is towards the inside constriction in the top of jar.Also can utilize jar with shoulder.Container can have many many shapes in different embodiments, but constriction cylinder jar shape is desirable owing to be tending towards meeting the ergonomics principle.In a non-limiting embodiments of the present invention, can utilize constriction cylinder jar shape with 53mm diameter and about 205mm height.

Most of jar comprises that coating or lining are to help to protect container and avoid corroding and to avoid product and any possible chemical reaction of container itself.Even slight reaction also can cause the chemism forfeiture of fragrance change, color change, key component even the excessive situation of pressure that causes by the reaction that can produce other gas between interior product of container and the container metallurgy.Therefore, the industrial coating of having developed certain limit and lining are in case class reaction here.These include but not limited to enamel and the lining made by following kind resin: acrylic resin, maleic acid resinoid, polyamide, alkyd resins, vinylite, polybutadiene, phenolic resin, epoxy-amine resin, epoxy ester resin, epoxy phenol resin, oleoresin and other.The metallurgy of product performance and aerosol container is depended in the selection of coating or lining.Adopt an embodiment of polyamidoimide lining coating to sell, derive from PPG Packaging Coatings, HOBADivision, Grabenstrabe, Germany with PAM 8460N.

Propellant

Under 70 °F (21 ℃), propellant of the present invention can be kept the whole pressure tank that is higher than 50psig (446kPa), and has used at preparation and can keep the whole pressure tank that is higher than 40psig (377kPa) after 75%.Propellant can be selected from the numerous propellants that are generally used for aerosol industry.These typically are categorized as liquefied gas propellant or compressed gas propellant.The proper compression gaseous propellant includes but not limited to compressed air, nitrogen, nitrous oxide, carbon dioxide and their mixture.Suitable liquefied gas propellant includes but not limited to hydrocarbon propellants such as propane, iso-butane, different propane, isobutene, normal butane, dimethyl ether (" DME ") and their mixture, fluoric ether such as HFC 152a and HFC 134a.

The selection of propellant is the principal element of influence jar internal gas pressure, relevant delivery rate and the surge of spraying when jar internal gas pressure influences with valve driving then.In certain embodiments, liquefied gas propellant can be preferable over compressed gas propellant owing to it is tending towards keeping a jar internal pressure better in the whole use of product, this is because the boiling of liquid phase propellant is vaporized to keep-up pressure, just as gas volume in the jar increases owing to product burns.Control the content of the volatile organic compounds (VOC) that discharges by spraying if desired, then need Compressed Gas such as nitrogen.

Usually with propellants to realize required tank pressure.The mixture of propellant can comprise propane, iso-butane and normal butane.In a plurality of embodiments of the present invention, 70 following vapour pressures between about 70psig to the propane between about 100psig and the mixture of iso-butane may be desired.In a non-limiting embodiments of the present invention, can use to be called Aeron A85 and to derive from Diversified CPC International, Inc., Channahon, Illinois, the common blend of the propane of USA and iso-butane.This blend comprises the propane of 68.9 moles of % and the iso-butane of 31.1 moles of %, and the vapour pressure of 85psig is provided under 70 °F.

Randomly, under needs are avoided too much reciprocation situation between propellant and the product, researched and developed the barrier package system propellant and product in the aerosol container have been separated.These comprise bag packing in piston barrier package and the jar, for example

Senior baffle system derives from CCLContainer, and Advance Monobloc Aerosol Division (Hermitage, Pennsylvania).In some embodiments, can adopt these barrier package methods in the whole use of product, to obtain more consistent product attribute.

System

Can use the pure and fresh goods of self-pressurization formula of the present invention as pure and fresh goods separately, perhaps if desired, can choose wantonly with system combinations and use to remove fold and smell from fabric.For example, in a non-limiting example, described self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal can be united use to remove smell before clothes washing with the clothes washing process.For example, described self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal can be united use with fabric washing utensil (including but not limited to washing machine), wherein handle described fabric with described self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal, wash in the fabric washing machine then.Alternatively, before or after handling with self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal, can be with pure and freshization of fabric in pure and fresh utensil (including but not limited to pure and fresh cabinet), a limiting examples of described pure and fresh cabinet is disclosed in U.S. Patent Publication 6, in 726,186.If desired, can with described self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal as the part of preprocessing process with clothes washing and/or pure and fresh before come spot, especially stench zone on the pretreating fabrics.In addition, if desired, can handle fabric in the textile article drying equipment before or after handling with self-pressurization formula smoothing wrinkle and the pure and fresh goods of taste removal, an one limiting examples is a roller dryer.

In addition, if desired, the pure and fresh goods of self-pressurization formula can be used, sell with other fabric treating product and/or mix to form the part of fabric treating product line, it can be used for providing the fabric treating beneficial effect, and needn't adopt laundry process.For example, in a limiting examples, the pure and fresh goods of self-pressurization formula can be with the products that is used for refreshing fabfrics and/or are used to remove the product of spot and/or color outward appearance reinforcing agent product (such as the U.S. Patent Application Serial Number of all submitting on January 11st, 2,008 12/008, in 427 and 12/008504 disclosed those) combination provide, all these all can be applied to fabric, and needn't use as the part of clothes washing process.The fabric treating product line can be different form obtain.For example, pure and fresh product and/or spot remove product and can be substrate form such as cloth, cleaning piece, pad, sponge, band (its limiting examples is Adhensive dust device or stain removal pen), or are the spray form.Equally, color outward appearance reinforcing agent product can be spray or substrate form.

Stretch

When with pure and freshization of textile article, the tension force that product is used and applied makes up and reduces that the amount of fold is favourable and preferred in the textile article.Especially advantageously apply tension force during " gap ", wherein wetting fabric becomes/keeps " mutability " (can be stretched) and do not become dry fully.As used herein, term " tension force " is meant and is applied on the fabric fibre substrate is produced tension, stretches or evens up the power of effect.Can non-homogeneous or uniform mode apply tension force.The example of non-homogeneous tension force includes but not limited to roll in dryer and use the wind hang airing.Uniform tension includes but not limited to, the handcontrolled manipulation on gravity, the concrete direction (for example tractive, smooth, stretch), presses, applies counterweight or other mechanical stretching system.Smooth/that fold reduces the big young pathbreaker of beneficial effect is proportional with type, value and the duration of the tension force that applies.In general, evenly the non-homogeneous stretching of draw ratio obtains better final effect, and the less power of bigger force rate obtains better final effect.

Composition of the present invention also can be used as the flatiron auxiliary agent.Can be to fabric with the composition spray of effective dose, and fabric should be ironed normal temperature under press fabric.The composition spray fabric of available effective dose becomes dry fabric and presses then, or spraying and flatiron immediately.

In another aspect of the present invention, can treat in smoothing wrinkle and/or the optional family expenses smoothing wrinkle chamber for the treatment of the deodorization fabric described composition spray on fabric comprising, thereby easy operating is provided.Conventional individual and industrial deodorizing and/or smoothing wrinkle equipment are applicable to this paper.Traditionally, these equipment work via making fiber produce lax decatize process.Alternatively, available pure and fresh composition spray fabric makes fabric be exposed in heating and/or the drying environment then.The example of family expenses smoothing wrinkle chamber comprises shower room.Indoor at described equipment then, or fabric is put into described indoor before, implement the spraying of described composition or compound to described fabric.Equally, sprayer unit should preferably can provide has about 8 to about 100 μ m, preferred about 10 drops to about 50 μ m weight-average diameters.Moisture load on the fabric that is made by natural fabric and synthetic fiber is by being counted about 0.05% to about 150%, preferred about 1% to about 75% by the weight of spraying fabric, and more preferably from about 2% to about 25%.Can implement other conventional steps that can in smoothing wrinkle equipment, carry out, such as heating and oven dry.In order to obtain best beneficial effect, described indoor temperature profile is preferably at about 30 ℃ to about 80 ℃, and more preferably from about 40 ℃ to about 70 ℃, and even more preferably from about 50 ℃ extremely in about 80 ℃ scope.Oven dry circulation duration is preferably about 3 to about 60 minutes, more preferably from about 10 to about 30 minutes.If described composition is maintained at about 22 ℃ (about 72 °F) to the temperature range of about 76 ℃ (170) before spraying, then also can save the steaming step in the smoothing wrinkle equipment.

The oneself instructs article of commerce

The present invention also comprises self-pressurization formula spraying smoothing wrinkle and the pure and fresh article of commerce of smell.One cover instructs can be with goods in conjunction with being included in, and its guiding user follows the method for removing fold and stench on the textiles with described goods.For example, in a non-limiting embodiments, this type of instructs bootable user with in the plication region of spray application to the textiles.In another non-limiting embodiments, the bootable user of described guidance is with in the fold or stench zone of spray application to the textiles.In another embodiment, the distance of the bootable user of described guidance from distance fabric face about 2 inches (5.08cm) to about 8 inches (20.32cm) used spraying.In another embodiment, the bootable user of described guidance will spray to concentrate and be sprayed on fold or the stench zone, and from the slow outside mobile sprayer of described regional center.In another embodiment, the bootable user of described guidance on the plication region of fabric, applies tension force to fabric with spray application then as mentioned above.

Herein, when relating to this type of specification, " relevant " be meant that described guidance directly is printed on the described goods; Directly be printed on the packing of goods; Be printed on attached on the label on the goods packing; Or present in a different manner, include but not limited to brochure, print advertisements, e-advertising, broadcasting or online advertisement; And/or other medium, so that a cover is instructed the consumer who conveys to goods.

Handle the method for textiles with self-pressurization formula spraying smoothing wrinkle of the present invention and the pure and fresh goods of smell

The present invention comprises that also use self-pressurization formula spray product of the present invention is so that the using method of textiles smoothing wrinkle and fresh scent.This comprises enables spray product so that fold or the stench zone on the spray flow contact textiles.After using method can be chosen wantonly and be included in textiles and described goods contact with described textiles wiping, blot or wash.

Method of testing

The wetting index test

Wetting index is the test of measuring the wetting rate of product on various fabrics.Described test relates to a test products (water is the reference product) is placed on the fabric sample, and determines that a product is penetrated into the time required in the fabric face fully.Wetting index is defined as: be the ratio that the water reference substance of unit time of infiltrating the surface fully and test products infiltrate the time on surface fully with the second.Therefore wetting index is big more, shows that then wettability is good more, but and is considered to the representative products wetting rate multiple faster than water.

Described method comprises the following steps:

1) use standard 6 " 2 embroidery of diameter fix textile material with annulus/tambour.The fabric sample bigger than described tambour is placed on the interior tambour, makes it keep flat.Outer/second tambour is placed on the sample, and is pressed in downwards on the interior tambour, fabric is clipped between two tambours.This should make the fabric sample be fixed between two tambours with flat condition, and tight slightly.

2) tambour that will have a fabric is placed on the horizontal surface.When being placed on it on the horizontal surface, carefully do not allow outer fabric folded under tambour of tambour.Purpose is to make (vertical or be orthogonal to gravity direction) that fabric becomes level to test.

3) VWR 20 to 200 μ L pipette are installed, make distribution tip apart from the fabric face top ¹/ ₄± 1/16 inch, described pipette is perpendicular to described surface simultaneously.Set pipette for distribution 30 μ L drops.

4) for the infiltration of observed drop clearly and determine terminal point, can install light source with the direction of surface into about miter angle on the fabric that throws light on.

5) begin test, distribute 30 μ L drops from pipette.Be assigned with and during contact fabric, just start timer immediately at drop one.When the visible face areflexia being determined, when not having the product residue of dissociating on the surface, determine terminal point according to environment light source.No longer observe light, but only see fabric face as the product surface reflection of a luminous point (or several luminous point).Stop timer this moment, and record wetting time (T).

6) implement the timing step with the distilled water tester, and the wetting time of water is designated as T _wAlso implement the timing step, and wetting time is designated as T with test products _p

7) wetting index is calculated as WI=T _w/ T _p

For carrying out the test of this paper report, use following fabric sample:

100% cotton Woven fabric: Style, 400 chintzs derive from Testfabrics, and Inc. (Middlesex, NJ).

75% polyester, 25% cotton Woven fabric: Style PC 49 polyester/cotton, derive from Empirical Manufacturing Company (Cincinnati, OH).

100% braided polyester thing, derive from Empirical Manufacturing Company (Cincinnati, OH).

100% woolen knitwear, derive from Empirical Manufacturing Company (Cincinnati, OH).

Moisture absorption arrangement test

On fabric, use the fabric refreshers composition, make the moisture absorption arrangement characteristic of processed fabric improve.Described characteristic is generally used for estimating whole moisture absorption arrangement ability, comprises wetting time, absorption rate, maximum wetting radius, wetting rate and one way transferring power.Wetting rate is to make moisture remove the parameter that takes place with the process of improving comfortableness from skin.As described in the wetting arrangement test of this paper, this test is easy to carry out in the laboratory.

Implement moisture absorption arrangement test to test similar mode with above-mentioned wetting index, but in this test, product is sprayed on the fabric face, they is retained in fixedly in the tambour as the preliminary treatment thing, and makes pretreated fabric drying at least 2 hours., being enough to obtain the even distance that covers on the fabric product is sprayed on the fabric with any suitable sprayer device.With regard to aerosol container and pressure activated Dey-Dose, the spraying distance is about 5 inches.1 to 2 gram product is administered to 6 " on the tambour test zone.After the pretreating fabrics drying,, measure the wetting time of described drop to test as wetting index after described mode is administered to distilled water drop (30 μ L) on the surface and goes up.With regard to moisture absorption arrangement effect, after with fabric refreshers compositions-treated fabric, the wetting time of water droplet is shorter with water pretreatment than separately.

The product pH test of spraying back

This measurements determination is before the product spraying and pH afterwards, writing down final spraying pH, and determines because Δ that spraying causes or pH variation.

Use derives from VWR International, and (West Chester, outfit gel 3-PA) close the VWR Symphony SP80PI pH meter of-1 pH of latex gel electrode, measure before the spraying and sample pH afterwards.Before using every day, adopt minimum two parts of buffers of containing sample pH scope, according to the step of manufacturer, described pH meter is proofreaied and correct.

At first measure the pH (initial pH) of preceding pure test sample book of spraying or original test sample book, then above the cup end 6 " distance; use to have standard eddy chamber atomizer and each pulling distributes about 1.0 to 1.5cc Calmar pressure activated formula sprayer, 35 to 40 gram test sample books be sprayed in the suitable plasticity cup (compatible with solution).

Pulls trigger is to impel best atomizing fast.After spraying is finished, record final pH.Step is repeated 5 times, and be averaged, the final pH after obtaining representational initial pH and spraying.

Following calculating pH changes (Δ pH): Δ pH=(spraying back pH)-(initial pH) is if Δ pH for just, represents that then spraying makes pH raise, and this is unsuitable for acidic products.If Δ pH is for negative, then the expression spraying makes pH reduce, and this is unsuitable for basic products.

Stench removes test A

Adopting this method of testing to evaluate composition is reducing or is removing the effect aspect the stench on the fabric.At first use the laundry detergent compositions of British plain spirits, the washing test fabric is dried in cloth drying machine then in washing machine.On eight area in square inches of each test fabric, evenly use the synthetic body odor composition of about 5mL dilution.The test fabric of using stench to handle becomes dry, and is sealed in the bag then, and makes its equilibrate overnight at ambient temperature.The initial stench degree of the test fabric that qualified smell evaluation person evaluation was handled with stench, and, choose the stench grade according to hereinafter stench evaluation criteria.Use the test composition of equivalent then, be sprayed on the test fabric and test fabric is become dry by test composition (about by weight 60%) and handle the test fabric of handling with stench effective dose.After the test fabric drying, qualified smell evaluation person evaluates the stench degree of test fabric once more, and chooses the stench grade according to stench evaluation criteria hereinafter.Write down initial stench grade and handle back stench grade, and calculate the described difference that waits inter-stage, determine that " stench reduction " is worth.

The stench evaluation criteria

0 does not exist stench/fragrance

10 I think and have stench/fragrance

25 exist a little stench/fragrance

50 exist moderate stench/fragrance

75 exist strong stench/fragrance

100 exist extremely strong stench/fragrance

Stench removes test b

Adopting this method of testing to evaluate composition is reducing or is removing the effect aspect the stench on the fabric.Provide new clothes to the panelist, wear several times, between each dress, do not wash.Qualified smell evaluation person evaluates the initial stench degree of the test fabric of handling with stench, and chooses the stench grade according to stench evaluation criteria above.Use the test composition of equivalent then, be sprayed on the test clothes and the test clothes is become dry by test composition (about by weight 2% to 5%) and handle the test fabric of handling with stench effective dose.After test clothes drying, qualified smell evaluation person evaluates the stench degree of test fabric once more, and chooses the stench grade according to stench evaluation criteria above.Write down initial stench grade and handle back stench grade, and calculate the described difference that waits inter-stage, determine that " stench reduction " is worth.

The smoothing wrinkle test

Adopt this method of testing to evaluate composition effect aspect the fold on minimizing or removal fabric.According to the definition of American Association of Textile Chemists and Colorists (" AATCC "), prepare test fabric by introducing smooth appearance degree (" SA ") (i.e. the fold that washing causes) or wrinkle recovery degree (" WR ") (i.e. the fold that dress causes).Qualified fold evaluation person evaluates the incipient fold degree of fabric according to AATCC method of testing 128 and method of testing 143, and evaluation fold score.Use the test composition of equivalent then, handle test fabric on the test fabric by test composition is sprayed at.When fabric is wetting, apply tension force to promote smoothing wrinkle and test fabric is become dry to them by for example test fabric being strained, stretch or evened up.After the test fabric drying, qualified fold evaluation person evaluates fold once more according to the AATCC standard.

The evaluation of microemulsion granularity:

Adopt Malvern Zetasizer Nano ZS dynamic light scattering element to measure particle mean size.In clean disposable 10mm cuvette, adopt the viscosity of 0.954mPa-sec, under 22 ℃, carry out all mensuration.National standard and technical research institute (" NIST ") examination criteria thing that use is dispersed in the 100nm among the 10mmol NaCl come checked operation.Made the sample balance 10 minutes.

Use the inside optimization algorithm in the function software, instrument is set decay and measuring position.Operation in per 20 seconds once moves 30 times altogether, is averaged as a result of.Each sample operation three times, each sample is totally 3 results.Before analysis, sample is filtered by 0.5 micron filter to remove any big pollutant.

Malvern software is recorded as the Z-Ave parameter with the average grain diameter of each sample.

Embodiment

Table 1

(1) derive from Akzo Nobel Chemical (Arnhem, Netherlands)

(2) derive from Dow Corning Corporation (Midland, Michigan)

(3) derive from Presperse Inc. (Somerset, New Jersey)

(4) derive from ExxonMobile Inc. (Irving, Texas)

(5) derive from Air Products and Chemicals, and Inc. (Allentown, Pennsylvania)

(6) derive from GE Silicones (Wilton, Connecticut)

(7) derive from Croda Inc. (Edison, New Jersey)

(8) derive from Lonza Group Ltd. (Basel, Switzerland)

(9) derive from Cognis Oleochemicals (Selangor, Malaysia)

Table 1 (continuing)

(1) derive from Akzo Nobel Chemical (Arnhem, Netherlands)

(2) derive from Dow Corning Corporation (Midland, Michigan)

(3) derive from Presperse Inc. (Somerset, New Jersey)

(4) derive from ExxonMobile Inc. (Irving, Texas)

(5) derive from Air Products and Chemicals, and Inc. (Allentown, Pennsylvania)

(6) derive from GE Silicones (Wilton, Connecticut)

(7) derive from Croda Inc. (Edison, New Jersey)

(8) derive from Lonza Group Ltd. (Basel, Switzerland)

(9) derive from Cognis Oleochemicals (Selangor, Malaysia)

(10) derive from Rohm﹠amp; Haas (Philadelphia, Pennsylvania)

Embodiment 1 and 2: remove stench and smoothing wrinkle

Composition A in the use in the table 1.Under agitation hydroxypropyl and TEA are joined (mixture A) in the purified water.In independent container, under agitation Permethyl102A is joined among the ARQUAD HTL8MS.Add spices then, and stir the mixture, make to obtain single-phase transparent mixture (mixture B).In independent container, under agitation make SURFYNOL 104pg and SURFYNOL 465 mix (mixture C) with 3: 2 ratio.Under agitation mixture B is joined among the mixture A.After stirring 10 minutes, add mixture C then.With the pH regulator to 8.4 of HCl, final mixture was stirred 10 minutes again this mixture.The surface tension of this mixture is between about 26 to 29 dynes per centimeter.

(Hermitage, in the 53 * 205mm 2Q aluminium pot with PAM lining PA), A is sprayed on the fabric with composition, and makes its evaporation from deriving from CCL Container.(Cary, Moritz locking aerosol actuator IL) is complementary described jar with deriving from SeaquistPerfect Dispensing LLC.Described actuator is complementary with the XT-96 type valve with 0.016 inch valve rod orifice diameter and 0.016 inch valve body orifice diameter.Use has the DU3027 type plug-in unit of 0.012 inch orifice diameter.Load about 60% volume with composition A with described jar.Add nitrogen by valve rod, to 70 following about 140psi, and about 155psi under 130.When starting, product is sent spraying jet with the quality delivery rate of about 1.1 Grams Per Seconds.Level of coverage is even, makes under suitably using, and has avoided the conspicuous product wet patch of consumer.Simplification of using and convenience are better than conventional hand sprayer.Method of testing described in this open test method part records, and obtains effective stench via product and reduces and pure and fresh sending, and when stuetch fabrics, also can realize effective smoothing wrinkle.

Fold WR

Embodiment 3: the smoothing wrinkle test

Adopt SA fold method of testing, the wrinkle improvement effect of three kinds of different fabrics of evaluation.According to said method, 100% cotton system capri pants, 55/40 polyester/cotton system Mrs white are weaved shirt and 100% cotton weave blue cotton system shirt and wrinkle in advance.The pressure activated formula that use derives from Calmar is manually sprayed sundries, with the one side spraying of clothes with even covering.Use hand tractive and stretching then, then clothes is stretched.The amount that is sprayed on capri pants, white polyester/cotton system shirt and the blue cotton system shirt is respectively about 10 grams, 5 grams and 8 grams.The each processing carried out three spraying parallel determinations to every clothing.Write down the incipient fold grade and the final grade of 3 evaluation person's evaluations, and calculate the ensemble average Δ fold grade (average final grade-average initial grade) of every class clothing.Ensemble average Δ grade result then shows smoothing wrinkle for just.Numerical value is big more, then represents effect good more (fold reduces many more).

These embodiment show that aspect the fold grade, composition of the present invention can provide about improvement of 1 to 1.5 to these different clothes.This is the improvement level that the consumer sees easily.The good smoothing wrinkle performance that should be pointed out that these compositions is consistent with their good wetting indexs.

Embodiment 4: the product pH test of spraying back

As above make composition C, and repeat once more, but do not have triethanolamine (TEA) buffer.With the pH regulator to 7.8 of watery hydrochloric acid, and make the sample equilibrate overnight with sample.

The result:

PH Δ pH after the initial pH spraying of sample

Composition C 7.7 7.7 0.0

The composition C 7.7 7.5-0.2 that does not contain TEA

Top embodiment shows, when seeing through air-atomizing, adds buffer and helps to reduce the degree that basic products pH changes.

Embodiment 5: the wetting index test

Prepare composition C, D, E, F, G based on water-soluble quaternary salt as mentioned above, and use the substrate of cotton system, evaluation in the wetting index test.Carry out three parallel determinations (repetition), average then.

Fabric is formed: 100% cotton	Distilled water wetting time (second)	Embodiment C wetting time (second)	Embodiment D wetting time (second)	Embodiment E wetting time (second)	Embodiment F wetting time (second)	Embodiment G wetting time (second)
							Repeat 1	??51	??5	??2	??5	??2	??5
Repeat 2	??49	??5	??2	??5	??2	??5
							Repeat 3	??44	??5	??2	??5	??2	??5

Fabric is formed: 100% cotton	Distilled water wetting time (second)	Embodiment C wetting time (second)	Embodiment D wetting time (second)	Embodiment E wetting time (second)	Embodiment F wetting time (second)	Embodiment G wetting time (second)
							Mean value	??48	??5	??2	??5	??2	??5
Wetting index	??1.0％	??9.6	??24.0	??9.6	??24.0	??9.6

* the acquiescence wetting index of water is 1.0

Embodiment 6: the wetting index test

Prepare composition C, D, E, F, G based on water-soluble quaternary salt as mentioned above, and use 75/25 polyester-cotton substrate, evaluation in the wetting index test.Carry out three parallel determinations (repetition), average then.

Fabric is formed: 75% polyester/25% cotton	Distilled water wetting time (second)	Embodiment C wetting time (second)	Embodiment D wetting time (second)	Embodiment E wetting time (second)	Embodiment F wetting time (second)	Embodiment G wetting time (second)
							Repeat 1	??90	??7	??3	??13	??3	??10
Repeat 2	??96	??8	??4	??13	??3	??12
							Repeat 3	??89	??9	??3	??14	??4	??10
Mean value	??91.7	??8	??2	??13.3	??3.3	??10.7
							Wetting index	??1.0％	??11.5	??27.5	??6.9	??27.5	??8.6

* the acquiescence wetting index of water is 1.0

Embodiment 7: the wetting index test

Prepare composition C and D based on water-soluble quaternary salt as mentioned above, and use polyester and wool substrate, evaluation in the wetting index test.Carry out three parallel determinations (repetition), average then.In this test, the water droplet infiltration is very slow, ends test after 3 minutes, and the time was designated as greater than 180 seconds.

* the acquiescence wetting index of water is 1.0

Embodiment 8: moisture absorption arrangement test

Two kinds of fabrics that moisture absorption arrangement property is paid close attention to especially are 100% cotton and 100% polyester.Prepare composition C and D based on water-soluble quaternary salt as mentioned above, and use polyester and the substrate of cotton system, evaluation in moisture absorption arrangement test.Carry out four parallel determinations (repetition), average then.In this test, the infiltration of water droplet on polyester is very slow, ends test after 5 minutes, and the time was designated as greater than 300 seconds.

Data among the embodiment illustrate, with disclosed some fabric of composition preliminary treatment, and the significant difference degree that obtains on by processing fabric face absorption rate at water subsequently.

Embodiment 9: the microemulsion grain size analysis

Composition H and I that preparation has the similar face active agent content, and they are similar to composition C and D respectively, but H and I have removed cyclodextrin, obtaining the granularity reading of the microemulsion that formed as far as possible accurately, and do not have add the possible interference effect of cyclodextrin generation.

Constitute three types composition H with the spices of three kinds of different contents.In the case, oil ingredient comprises that clogP is that 3.79 spices and clogP are 6.58 Permethyl 102A, and described clogP calculates according to the LogP predictor that derives from ChemSilo LLC and obtains.At room temperature oil and Arquad HTL8MS surfactant are mixed, join then in the mixture of water and TEA.Adopt low sheared helical oar to mix to obtain final mixture.As final step, use H ₂SO ₄The solution titration with pH regulator to its end value.

Constitute three types composition I with the spices of three kinds of different contents.In the case, oil ingredient comprises that CLogP is 3.79 spices.At room temperature oil and UNIQUAT 22c50 surfactant are mixed, join then in the mixture of water and TEA.Adopt low sheared helical oar to mix, to obtain final mixture.As final step, use H ₂SO ₄The solution titration with pH regulator to its end value.

Via granularity method as herein described, analyze various types of composition H and composition I, and every kind of sample gets the average of three parallel determinations, being the diameter of unit with the nanometer as what finally report.

Sample	Visual appearance in the 20mL bottle	Average grain diameter (Z-Ave) nanometer
			The composition H that contains 0.1% spices	Very transparent and even	?10.0
The composition H that contains 0.2% spices	Gloomy slightly/translucent and even	?94.8
			The composition H that contains 0.4% spices	Emulsus/opaque and inhomogeneous (observing slight separation)	?337.4
The composition I that contains 0.1% spices	Transparent and even	?114.5
			The composition I that contains 0.2% spices	Gloomy slightly/translucent and even	?128.9
The composition I that contains 0.4% spices	Half is opaque and even	?135.0

Above data show, exist the quaternary surfactant system can tolerate and keep the oil content limit of microemulsion characteristic.Particle mean size shows as huge emulsion greater than the system of about 300nm, observes highly opaque in 2 days and homogeneity not.

Embodiment 10: Electrostatic Control

The Electrostatic Control characteristic of these compositions on 100% polyester shirt shown in this test confirms.

In this test, use representational 100% Mrs polyester jacket Lady Edwards ^TMThe 5050-00 money, the SN0414 pattern.By a masking tape vertically is placed on shirt central authorities, with the front of shirt be divided into one half-sum right side, left side half.The oversleeve of each side of shirt vertically rubbed along the shirt length direction on half side before its shirt separately back and forth produce static with that side 8 times at shirt.Use the contactless voltage detector of foregoing Greenlee GT-11 type to evaluate the existence of each side static.Then, working pressure trigger-type hand sprayer, and on its each side even spraying, the composition C spraying in the left half side usefulness 6 gram tables 1, and the 6 gram distilled water sprayings of right half side usefulness.After the spraying, wait for 15 seconds, when still moist, evaluate the static of each side then.Make shirt dry 90 minutes, and then oversleeve was rubbed 8 times once more to attempt to produce once more static on their sides separately.After the friction, use the contactless voltage detector of GT-11, evaluate the static of each side once more.

Testing procedure	The voltage detector result
		The shirt left side that rubbed with oversleeve before handling	The voltage detector reaction, showing has static
The shirt right side that rubbed with oversleeve before handling	The voltage detector reaction, showing has static
		The left side of spraying with composition C, and when humidity evaluation static	Voltage detector is reactionless, shows not have tangible static

Testing procedure	The voltage detector result
		The right side of spraying with distilled water, and when humidity evaluation static	Voltage detector is reactionless, shows not have tangible static
After the shirt drying, the left side that rubbed with oversleeve	Voltage detector is reactionless, shows not have tangible static
		After the shirt drying, the right side that rubbed with oversleeve	The voltage detector reaction, showing has static

This test result shows that though water can temporarily disperse the static that forms already on fabric, it can not stop electrostatic accumulation subsequently.Microemulsion based on quaternary salt not only can disperse the static that has formed on fabric face, and because the fabulous wetting covering that quaternary salt characteristic and these compositions provide can stop static subsequently to form.

Though illustrated and described specific embodiments of the present invention, it will be apparent to one skilled in the art that and under the situation that does not deviate from essence of the present invention and scope, can make a plurality of other changes and modification.Therefore, claims all such changes and modification of being intended to be included in the scope of the present invention.This paper the relevant part of all references is all incorporated into way of reference.Should not be interpreted as admitting that for quoting of any file it is relevant prior art of the present invention.

Claims (12)

1. composition that is used to handle fabric, described composition comprises:

A) about 0.01% to about 20% water-soluble quaternary surfactant;

B) about 0.001% to about 5% water-insoluble substantially oil ingredient;

C) randomly, about 0.01% to about 5% non-ionic surface active agent;

D) randomly, about 0.01% to about 3% buffer;

E) randomly, about 0.01% to about 5% odor control agent;

F) randomly, about 0.001% to about 0.5% anti-microbial active matter;

G) randomly, be enough to reach the pH regulator agent of about 3 to about 11 pH;

H) randomly, about 0.001% to about 0.5% preservative agent;

I) randomly, about 0.05% to about 8% water miscible substantially solvent; With

J) excess water;

Make described composition even and stable.

2. composition as claimed in claim 1, wherein said composition also comprises the microemulsion with about 300nm or littler particle mean size.

3. composition as claimed in claim 2, wherein said composition is transparent.

4. composition as claimed in claim 1, wherein said composition has about 2 wetting index on COTTON FABRIC.

5. method that is used to handle fabric said method comprising the steps of:

A) provide composition, wherein said composition comprises:

I) about 0.01% to about 20% water-soluble quaternary surfactant;

Ii) about 0.001% to about 5% water-insoluble substantially oil ingredient; With

Iii) excess water; And

B) described composition is administered on the fabric.

6. method as claimed in claim 5, wherein said composition by spray application to described fabric.

7. method as claimed in claim 6, described method also are included in the step of the described fabric that stretched before or after the step of applying said compositions on the described fabric.

8. method as claimed in claim 5 wherein before or after the step of applying said compositions on the described fabric, is put into described fabric in the washing machine.

9. method as claimed in claim 5 wherein before or after the step of applying said compositions on the described fabric, is put into described fabric in the refreshing device.

10. method as claimed in claim 5 wherein before the step of applying said compositions on the described fabric, is put into described fabric in the drying unit.

11. the pure and fresh goods of self-pressurization formula fabric, the pure and fresh goods of wherein said self-pressurization formula fabric comprise composition as claimed in claim 1.

12. the pure and fresh goods of self-pressurization formula fabric as claimed in claim 11, the pure and fresh goods of wherein said self-pressurization formula fabric are parts of a series of products, and described a series of products also comprise the product that is used for decontamination or are used for hyperchromic product.