CN101797086B - Antibacterial deodorizing insoles - Google Patents
Antibacterial deodorizing insoles Download PDFInfo
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- CN101797086B CN101797086B CN2010101430422A CN201010143042A CN101797086B CN 101797086 B CN101797086 B CN 101797086B CN 2010101430422 A CN2010101430422 A CN 2010101430422A CN 201010143042 A CN201010143042 A CN 201010143042A CN 101797086 B CN101797086 B CN 101797086B
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- chlorine dioxide
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Abstract
The invention relates to a pair of antibacterial deodorizing insoles. Each antibacterial deodorizing insole comprises a surface and a bottom, wherein a packing layer is arranged between the surface and the bottom; the surface, the bottom and the packing layer are fixed to each other; and the packing layer is blended from chlorine dioxide matrix, solid acid, solid buffering agent and water-absorbing fibers. The packing layer of the invention has the characteristic of quick water absorption due to the adoption of superfine fibers, can keep the inside of the shoe dry at any time and stably release the effective ingredient chlorine dioxide, has the advantages of high sterilization speed, obvious deodorizing effect, no side effect on the human body and safe use, and has obvious effect of relieving the symptoms of dermatophytosis after being used for a long time.
Description
Technical field
The present invention relates to a kind of shoe-pad, being specifically related to a kind of is the antibacterial deodorizing insoles of main functional component with chlorine dioxide.
Background technology
Chlorine dioxide be generally acknowledge at present a kind of efficient, low toxicity, fast, wide spectrum the 4th generation the disinfecting disinfectant, classified as A1 level disinfectant with extremely strong sterilizing power, characteristic not carcinogenic, non-secondary pollution by The World Health Organization (WHO).Through Environmental Protection Agency (EPA) and food and drug administration (FDA) approval, be used for sterilization, sterilization, deodorizing and industry, agricultural and the health care of food fresh keeping, processing, drinking water.Because of it has 100% killing rate to bacterium, fungi, virus, gemma, be widely used in medical disinfecting and fungus-caused treating for skin disease abroad, but also do not applied in China.The main cause that the restriction chlorine dioxide is used is that chlorine dioxide is a kind of gas, and aqueous solution instability is difficult to long term storage or fixing, must now do existing usefulness.
Beriberi, pin smelly mostly be because vigorous the causing of eccrine secretion of foot, the sweat gland secretion thing bacterium, mould divide take off produce dirty smelly, cause that the smelly arch-criminal of pin is a kind of fungi that cries the tinea alba bacterium, it produces unpleasant stench after decomposing the skin metabolism thing, go down for a long time to develop into serious beriberi symptom such as scaling, redness, bubble, breach can occur between serious patient's toe seam, fester.In order effectively to treat beriberi, it is smelly to suppress pin, and people have designed various shoe-pads with antibacterial and deodouring function.Existing antibacterial deodorizing insoles, usually adopt Chinese herbal medicine, Nano Silver, chitin, or some harmful chemosterilants are as antibacterial additives is though these antibacterial additives can sterilization, but can't fundamentally kill the fungi that causes beriberi, and cost is higher relatively, and preparation is complicated, is difficult to be subjected to consumer's approval.
It is the invention absorbing sweat deodorizing antibiotic environmental-protecting insoles of functional component with the chlorine dioxide that patent application 200720061021.X discloses a kind of, and its method is: water-absorbing resin mixes with sodium chlorite makes sodium chlorite emit chlorine dioxide by the slowly-releasing reaction.But in fact, sodium chlorite is difficult to be absorbed the resin activation, and the chlorine dioxide through measuring release does not have the effect of sterilization less than 0.01ppm at all.A large amount of bibliographical informations, sodium chlorite must be met sour could the activation and be emitted chlorine dioxide.And can become gel after absorbing the resin suction, and gas permeability is very poor, and foot can easier perspiration.
Summary of the invention
The objective of the invention is to overcome the defective that existing antibacterial insoles exists, a kind of improved shoe-pad with antibacterial and deodouring function is provided.
For achieving the above object, technical scheme of the present invention is: a kind of antibacterial deodorizing insoles is provided, comprise pad face, rebasing, described pad face and rebasing between be provided with packed layer, fixedly connected between described pad face, the rebasing and packed layer, wherein, pressed powder and the hygroscopicity fibre blending be made up of chlorine dioxide matrix, solid acid, solid buffer of described packed layer forms.Wherein, the solid acid that adopts among the present invention is meant and has the solid matter that provides proton or accept the duplet ability.
Wherein, the mixed proportion between the pressed powder that described hygroscopicity fibre and chlorine dioxide matrix, solid acid, solid buffer are formed is (1-20): 1, and chlorine dioxide matrix wherein, the ratio of solid acid and solid buffer is 1: (0.1-1): (1-50).
Wherein, described pad face and rebasing be Biodegradable material, described chlorine dioxide matrix is a sodium chlorite; Described solid acid is a kind of in citric acid, tartaric acid, boric acid, oxalic acid, gluconic acid, the niter cake; The pH value of described solid buffer is 5.0-8.0, and the material of described hygroscopicity fibre is a kind of in cellulose, chitin, starch, shitosan, sodium alginate, polyvinyl alcohol, PLA, polycaprolactone, the polyglycolic acid.
Wherein, chlorine dioxide matrix is a sodium chlorite; A kind of in the composition of composition, acetate and the sodium acetate of composition, potassium dihydrogen phosphate and the sodium hydrogen phosphate of composition, boric acid and Boratex that described solid buffer is citric acid and natrium citricum, described hygroscopicity fibre is a kind of in shitosan, polyvinyl alcohol and the PLA.
Wherein, the average fineness of described hygroscopicity fibre is less than 0.3dtex.
Wherein, be connected and fixed by line between described pad face, the rebasing and packed layer, described line intersects mutually and is latticed,
Wherein, described pad face adopts suturing with thread management to be connected with rebasing periphery.
Wherein, adhesive linkage is arranged at described rebasing bottom.
Wherein, described adhesive linkage is two gums.
A kind of preparation method who is used for packed layer, comprising the steps: at first to select for use hygroscopicity fibre is matrix, in hygroscopicity fibre according to (1-20): 1 ratio is evenly mixed by chlorine dioxide matrix, and the pressed powder that solid acid and solid buffer are formed is then through blending and fluffy arrangement.
Advantage of the present invention and beneficial effect are: the used cost of raw material is cheap, and processing technology is simple, is suitable for promoting, and comfortable, softness can fold as required, and bending is convenient for carrying, and has good antibacterial and deodouring function.
Description of drawings
Fig. 1 is the plan structure schematic diagram of antibacterial deodorizing insoles of the present invention;
Fig. 2 is the structural representation of looking up of antibacterial deodorizing insoles of the present invention;
Fig. 3 is the structural representation of antibacterial deodorizing insoles of the present invention.
Among the figure:
1, pad face; 2, packed layer; 3, rebasing; 4, line; 5, gum.
The specific embodiment
The present invention is described further below in conjunction with drawings and Examples, and following examples are used to illustrate the present invention, but be not used for limiting the scope of the invention.
Embodiment 1
As Figure 1-3, chlorine dioxide antibacterial deodorizing insoles provided by the invention is made up of pad face 1, antibacterial and deodouring packed layer 2 and rebasing 3.Pad face 1, rebasing 3 and packed layer 2 between fixedly connected, be preferably pad face 1, packed layer 2 and rebasing 3 usefulness lines 4 carried out the latticed fixing of quilting formula.
Pad face 1 and rebasing 3 lining are selected the degradation material with gas permeability for use, are preferably the chitin non-weaving cloth.
Pad face 1 is sewed up with rebasing 3 peripheries and is connected, and pad face 1, packed layer 2 and rebasing 3 usefulness lines 4 carry out latticed fixing.
Rebasing two gums 5 are set, are used for this shoe-pad is fixed on sole.Article two, gum 5 lays respectively at the front and rear part of rebasing bottom.
The preparation method of packed layer 2 of the present invention, with the boric acid of the sodium chlorite pressed powder of 2g and 1g and pH value is after 5.0 5g citric acid and natrium citricum composition evenly mix, being doped to the 10g average fineness is in the PLA superfine fibre of 0.1dtex, forms packed layer after blending and fluffy arrangement.
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the citric acid of the sodium chlorite pressed powder of 2g and 2g and pH value is after 7.0 10g potassium dihydrogen phosphate and sodium hydrogen phosphate composition evenly mix, being doped to the 30g average fineness is in the polyvinyl alcohol superfine fibre of 0.2dtex, forms packed layer after blending and fluffy arrangement.
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the tartaric acid of the sodium chlorite pressed powder of 2g and 0.5g and pH value is after 15g acetate-sodium acetate composition of 6.0 evenly mixes, being doped to the 50g average fineness is in the chitin superfine fibre of 0.3dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 4
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the niter cake of the sodium chlorite pressed powder of 2g and 0.2g and pH value is after 15g boric acid-Boratex composition of 7.0 evenly mixes, being doped to the 60g average fineness is in the shitosan superfine fibre of 0.3dtex, forms packed layer after blending and fluffy arrangement.
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the citric acid of the sodium chlorite pressed powder of 2g and 1g and pH value is after 5g boric acid-Boratex composition of 8.0 evenly mixes, being doped to the 100g average fineness is in the PLA superfine fibre of 0.1dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 6
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the oxalic acid of the sodium chlorite pressed powder of 2g and 1g and pH value is after 30g boric acid-Boratex composition of 5.0 evenly mixes, being doped to the 200g average fineness is in the polyvinyl alcohol superfine fibre of 0.1dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 6
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the niter cake of the sodium chlorite pressed powder of 2g and 0.2g and pH value is after 6.5 30g citric acid-sodium citrate composition evenly mixes, being doped to the 150g average fineness is in the cellulose superfine fibre of 0.3dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 7
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the oxalic acid of the sodium chlorite pressed powder of 1g and 0.1g and pH value is after 20g boric acid-Boratex composition of 7.5 evenly mixes, being doped to the 100g average fineness is in the sodium alginate superfine fibre of 0.2dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 8
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the gluconic acid of the sodium chlorite pressed powder of 1g and 0.2g and pH value is after 6g boric acid-Boratex composition of 8.0 evenly mixes, being doped to the 200g average fineness is in the polycaprolactone superfine fibre of 0.05dtex, forms packed layer after blending and fluffy arrangement.
Embodiment 9
Basic identical with embodiment 1, different is, the preparation method of packed layer 2, with the tartaric acid of the sodium chlorite pressed powder of 2g and 2g and pH value is after 8.0 15g potassium dihydrogen phosphate and sodium hydrogen phosphate composition evenly mix, being doped to the 100g average fineness is in the poly-hexanol acid superfine fibre of 0.1dtex, forms packed layer after blending and fluffy arrangement.
The test example:
Detect foundation and analytical method referring to " disinfection technology standard (Ministry of Public Health's version in 2002) " 2.1.1.7.4 and 2.1.1.9.
The bactericidal effect of packed layer (embodiment 1):
| Microorganism | The disease that may cause | Killing rate (90 seconds) |
| Escherichia coli | Enteritis, diarrhoea, urethritis, cystitis, pyelonephritis, peritonitis, appendicitis, septicemia | ＞99.999? |
| Staphylococcus aureus | Diarrhoea, chordapsus, vomiting, heating | ＞99.999? |
| Pseudomonas aeruginosa | Purulent lesion | ＞99.999? |
| White is read coccus | Thrush, vaginitis | ＞99.999? |
| Friedlander | Tracheitis, pneumonia, meningitis, Urinary system inflammation, wound pathology | ＞99.999? |
| Staphylococcus albus | Vomiting, diarrhoea | ＞99.999? |
| Aspergillus niger | Grain goes mouldy | 96.111? |
Practical function of the present invention is: (1) lining and packed layer are selected Biodegradable material for use, have the characteristics of environmental protection; (2) every secondary shoe-pad can continue to use 1-2 week, and the used cost of raw material is cheap, and processing technology is simple, is suitable for promoting; (3) superfine fibre of packed layer employing has the characteristics of quick suction, can keep dry and comfortable in the footwear constantly; (4) the functional component chlorine dioxide discharges and stablizes, and sterilization speed is fast, and deodorizing effect is obvious, and is without any side effects to human body, safe in utilization, and long-term use has tangible mitigation to the symptom of beriberi; (5) comfortable, softness can fold as required, and bending is convenient for carrying; (6) rebasing gum can make shoe-pad be fixed in the sole, prevents shoe-pad position skew in motion process.
More than be preferred forms of the present invention, according to content disclosed by the invention, those of ordinary skill in the art can expect some identical, replacement schemes apparently, but these schemes all should fall into the scope of protection of the invention.
Claims (10)
1. antibacterial deodorizing insoles, comprise pad face, rebasing, described pad face and rebasing between be provided with packed layer, fixedly connected between described pad face, the rebasing and packed layer, it is characterized in that pressed powder and hygroscopicity fibre blending that described packed layer is made up of chlorine dioxide matrix, solid acid, solid buffer form;
Described chlorine dioxide matrix is a sodium chlorite;
Described solid acid is a kind of in citric acid, tartaric acid, boric acid, oxalic acid, gluconic acid, the niter cake;
A kind of in the composition of composition, boric acid and the Boratex of composition, acetate and the sodium acetate of composition, potassium dihydrogen phosphate and sodium hydrogen phosphate that described solid buffer is citric acid and natrium citricum;
Described hygroscopicity fibre is a kind of in cellulose, chitin, starch, shitosan, sodium alginate, polyvinyl alcohol, PLA, polycaprolactone, the polyglycolic acid.
2. antibacterial deodorizing insoles as claimed in claim 1, it is characterized in that, mixed proportion between the pressed powder that described hygroscopicity fibre and chlorine dioxide matrix, solid acid, solid buffer are formed is (1-20): 1, chlorine dioxide matrix wherein, the ratio of solid acid and solid buffer is 1: (0.1-1): (1-50).
3. antibacterial deodorizing insoles as claimed in claim 1 or 2 is characterized in that, described pad face and rebasing be Biodegradable material; The pH value of described solid buffer is 5.0-8.0.
4. antibacterial deodorizing insoles as claimed in claim 3 is characterized in that, chlorine dioxide matrix is a sodium chlorite; A kind of in the composition of composition, acetate and the sodium acetate of composition, potassium dihydrogen phosphate and the sodium hydrogen phosphate of composition, boric acid and Boratex that described solid buffer is citric acid and natrium citricum; Described hygroscopicity fibre is a kind of in shitosan, polyvinyl alcohol and the PLA.
5. antibacterial deodorizing insoles as claimed in claim 4 is characterized in that the average fineness of described hygroscopicity fibre is less than 0.3dtex.
6. antibacterial deodorizing insoles as claimed in claim 5 is characterized in that, is connected and fixed by line between described pad face, the rebasing and packed layer, and described line intersects mutually and is latticed,
7. antibacterial deodorizing insoles as claimed in claim 6 is characterized in that, described pad face adopts suturing with thread management to be connected with rebasing periphery.
8. antibacterial deodorizing insoles as claimed in claim 7 is characterized in that, adhesive linkage is arranged at described rebasing bottom.
9. antibacterial deodorizing insoles as claimed in claim 8 is characterized in that, described adhesive linkage is two gums.
10. preparation method who is used for the described packed layer of claim 1, it is characterized in that, comprising the steps: at first to select for use hygroscopicity fibre is matrix, in hygroscopicity fibre according to 1-20: 1 ratio is evenly mixed by chlorine dioxide matrix, the pressed powder that solid acid and solid buffer are formed is then through blending and fluffy arrangement.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101430422A CN101797086B (en) | 2010-04-07 | 2010-04-07 | Antibacterial deodorizing insoles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101430422A CN101797086B (en) | 2010-04-07 | 2010-04-07 | Antibacterial deodorizing insoles |
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| Publication Number | Publication Date |
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| CN101797086A CN101797086A (en) | 2010-08-11 |
| CN101797086B true CN101797086B (en) | 2011-03-23 |
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| CN2010101430422A Expired - Fee Related CN101797086B (en) | 2010-04-07 | 2010-04-07 | Antibacterial deodorizing insoles |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102960905A (en) * | 2012-11-30 | 2013-03-13 | 范淑芳 | Health shoe pad with microbicidal effect |
| CN104082906A (en) * | 2014-06-25 | 2014-10-08 | 无锡市崇安区科技创业服务中心 | Anti-perspiration sterilizing insole filler powder and preparation method thereof |
| CN105962538A (en) * | 2016-07-01 | 2016-09-28 | 苏贻东 | Antibacterial and deodorizing insole |
| CN108523307A (en) * | 2018-04-18 | 2018-09-14 | 青岛高德法美生物钛技术有限公司 | A kind of health insoles containing chitin derivativ |
| CN109468748B (en) * | 2019-01-15 | 2021-07-02 | 山东蓝色时光新材料有限公司 | Preparation method of efficient filtering and intelligent antibacterial porous nanofiber membrane |
| CN109620996A (en) * | 2019-01-29 | 2019-04-16 | 青岛中腾生物技术有限公司 | A kind of medical antibacterial dressing |
| CN112006377B (en) * | 2020-09-02 | 2021-10-08 | 北京泰欣源鞋业有限公司 | Traditional Chinese medicine wormwood antibacterial health-care insole |
| CN112226865B (en) * | 2020-09-28 | 2022-09-09 | 郑菊红 | Deodorant insole material and preparation method thereof |
| CN113207904A (en) * | 2021-04-30 | 2021-08-06 | 深圳市安保医疗感控科技股份有限公司 | Chlorine dioxide slow-release material, manufacturing method of related fabric and foot product |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101176446A (en) * | 2006-11-10 | 2008-05-14 | 宋小芳 | Novel mildew resistant tablet and preparation method thereof |
| CN201157039Y (en) * | 2007-12-06 | 2008-12-03 | 邓飞英 | Sweat-absorbing deodorizing antimicrobial environment friendly shoe pad |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3520093A1 (en) * | 1985-06-05 | 1986-12-11 | Fa. Carl Freudenberg, 6940 Weinheim | COVER OR INSOLE |
| JP2000354502A (en) * | 1999-06-15 | 2000-12-26 | Hisao Ishiguro | Sock for shoe |
| CN101134116A (en) * | 2006-08-31 | 2008-03-05 | 天津雪赢世纪专利技术有限公司 | Deodorizing moisture desorption agent for shoes |
-
2010
- 2010-04-07 CN CN2010101430422A patent/CN101797086B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101176446A (en) * | 2006-11-10 | 2008-05-14 | 宋小芳 | Novel mildew resistant tablet and preparation method thereof |
| CN201157039Y (en) * | 2007-12-06 | 2008-12-03 | 邓飞英 | Sweat-absorbing deodorizing antimicrobial environment friendly shoe pad |
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| CN101797086A (en) | 2010-08-11 |
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