CN101768398B - Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof - Google Patents

Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof Download PDF

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Publication number
CN101768398B
CN101768398B CN 200910201230 CN200910201230A CN101768398B CN 101768398 B CN101768398 B CN 101768398B CN 200910201230 CN200910201230 CN 200910201230 CN 200910201230 A CN200910201230 A CN 200910201230A CN 101768398 B CN101768398 B CN 101768398B
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China
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water
coating
temperature resistant
modified
transfer laser
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CN 200910201230
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Chinese (zh)
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CN101768398A (en
Inventor
董海普
张芳芳
张阳红
戴胜杰
邓庆仪
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上海维凯化学品有限公司
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Priority to CN 200910201230 priority Critical patent/CN101768398B/en
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Abstract

The invention relates to a water-based temperature resistant single-coating transfer laser aluminizing paint and a preparation method thereof; the paint includes the following components (by weight portion): 30-40 portions of water-based resin, 10-20 portions of temperature resistant water-based resin, 0-5 portions of water-based inorganic filler, 10-20 portions of cosolvent, 18-40 portions of deionized water, 0.2-0.3 portion of pH value regulator, 0.1-0.5 portion of wetting agent, 0.1-0.2 portion of leveling agent and 0.05-0.2 portion of defoamer; the resin component and the filler are loaded in a reactor to be stirred at low speed, and then pH value regulator, wetting agent, leveling agent and the defoamer are added to the reactor, and the mixture is stirred and filtered to obtain the product. Compared with prior art, the invention has advantages of environmental protection, lower cost, good printing adaptability, broader range of proper mould pressing temperature, and good mold pressing effect and can directly replace the solvent and water-based transfer laser aluminizing paint in prior art.

Description

A kind of water-based temperature resistant single-coating transfer laser aluminizing coating and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, especially relate to a kind of water-based temperature resistant single-coating transfer laser aluminizing coating and preparation method thereof.
Background technology
Latter stage in 20th century; Advantages such as transfer aluminum plated technology compares that traditional recombining process relies on that it is low in resources consumption, environmental protection, the sense of outward appearance metal are strong, can make laser effect, cost is low; Started a revolution at wrapping material circle, transfer aluminum platedly obtained a large amount of applying with coating (hereinafter to be referred as transfer coatings) for what it was customized.The basic property of laser transfer coatings is its separability and mold pressing effect; The easy degree that separability is promptly totally peeled off with basement membrane (PET polyester film, OPP stretched polypropene film etc.); The quality of separability generally can characterize through the peeling force of transfer coatings and basement membrane.The mold pressing effect is meant through mould pressing process and on coating, demonstrates the holographic laser effect.
Existing heat-resistance type laser transfer coatings major part is the water-based system of solvent-based system and few part; Wherein solvent-based system in a large number with an organic solvent; Volatile organic matter (VOCs) content height causes severe contamination to producing with environment for use on the one hand, also exists the problem that solvent cost is limited by the international oil price fluctuation on the other hand; And used few part water-based system temperature tolerance does not reach requirement, can not use in the plurality of applications field.Water-borne coatings itself has the unrivaled environment-friendly advantage of solvent based coating has become extensive common recognition; The road that the laser transfer coatings of heat-resistance type is walked Water-borne modification also is trend of the times, and tool feature of environmental protection heat-resistance type moldable aqueous transfer coating does not see as yet that then related patent U.S. Patent No. or bibliographical information are arranged.
Summary of the invention
The object of the invention is exactly for the defective that overcomes above-mentioned prior art existence a kind of tool feature of environmental protection, heat-resistance type, moldable water-based temperature resistant single-coating transfer laser aluminizing coating and preparation method thereof to be provided.
The object of the invention can be realized through following technical scheme:
A kind of water-based temperature resistant single-coating transfer laser aluminizing coating is characterized in that, this coating comprises following component and weight part content:
Water-base resin 30-40;
Heatproof water-base resin 10-20;
Aqueous inorganic filler 0-5;
Solubility promoter 10-20;
Deionized water 18-40;
PH value regulator 0.2-0.3;
Wetting agent 0.1-0.5;
Flow agent 0.1-0.2;
Skimmer 0.05-0.2.
Described water-base resin comprises ACRYLIC EMULSION, Z 150PH (PVA), water-based chlorine vinegar, polyurethane aqueous dispersion body, acrylic acid modified polyurethane emulsion; Plant oil modified urethane or water-dispersion nitro-cotton; The second-order transition temperature of described ACRYLIC EMULSION is 0-30 ℃; Molecular weight >=200,000, the alcoholysis degree of described Z 150PH >=85.
Described heatproof water-base resin comprises that softening temperature is at 140-160 ℃ water-based aldehyde ketone resin or polycarbonate polyurethane water dispersion.
Described aqueous inorganic filler is the nanometer transparent filler, comprises nano silicon water dispersion or nano aluminium oxide water dispersion.
Described solubility promoter comprises ethanol, Virahol or propylene glycol.
Described pH value regulator comprises ammoniacal liquor, triethylamine, dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol or dimethylethanolamine.
Described wetting agent comprises anionic wetting agent or non-ionic wetting agent; Described anionic wetting agent comprises sodium alkyl sulfate, X 2073 or methylol dodecyl carboxylic acid sodium, and described non-ionic wetting agent comprises TX10 (APEO), high-carbon fatty alcohol polyoxyethylene ether (AEO) or polyoxyethylene carboxylate (AE).
Described flow agent comprises modified organic silicon, and described modified organic silicon comprises polyethers upgrading ZGK 5 or amino-modified silicone oxygen alkane.
Described skimmer comprises non-ionic interfacial agent, modified polyorganosiloxane, special hydrogen carbon cpd, modified silicone defoamer or hydrophobic particles and hydrocarbon polymer; Described non-ionic interfacial agent comprises T 46155 amine or polyoxyethylate amide; Described modified polyorganosiloxane comprises amino modified polysiloxane or vinylformic acid ZGK 5; Described special hydrogen carbon cpd comprises modest W-090 of commercially available moral or the modest W-092 of moral; Described modified silicone defoamer comprises commercially available KLD-970 or commercially available LH-511, and described hydrophobic particles and hydrocarbon polymer comprise commercially available BYK-016 or the modest W-082 of moral.
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating is characterized in that, this method may further comprise the steps:
(1) get the raw materials ready according to following component and weight part content:
Water-base resin 30-40,
Heatproof water-base resin 10-20,
Aqueous inorganic filler 0-5,
Solubility promoter 10-20,
Deionized water 18-40,
PH value regulator 0.2-0.3,
Wetting agent 0.1-0.5,
Flow agent 0.1-0.2,
Skimmer 0.05-0.2;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 100-200rpm, stirring at low speed 5-10min;
(3) in reaction kettle, add the aqueous inorganic filler, the control stir speed (S.S.) is 100-200rpm, stirring at low speed 5-10min;
(4) in reaction kettle, add pH value regulator, the pH value of regulation system is 7.5-8.5;
(5) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 500-600rpm, and middling speed stirs 8-15min;
(6) in reaction kettle, add skimmer, the control stir speed (S.S.) is 800-900rpm, and high-speed stirring 20-30min through filtering, promptly obtains product again.
Compared with prior art, the present invention has the following advantages:
(1) environment-friendly advantage: with water is main dispersing medium, does not contain organic solvent basically, and volatile organic matter (VOCs) content is extremely low;
(2) cost control advantage: owing to do not contain organic solvent, the problem that the cost of having avoided organic solvent brought by the high enterprise of international oil price significantly raises;
(3) printing adaptability is good: compare solvent-based system, water-based system different on resin and solvent-based system polarity have been given its good solvent resistance, more are applicable to the mode of printing (like intaglio printing, silk screen printing) that solvent resistance is had relatively high expectations.Because the surface tension of water-base resin generally will be higher than oleoresin, offset printing also there is certain benefit in addition;
(4) suitable molding temperature scope is than broad during mold pressing, and mold pressing is effective, easy control productions in;
(5) existing relatively aqueous transfer laser aluminium-plating coating, heatproof has had large increase, can reach the level of solvent-borne type product;
(6) can directly be used for substituting existing solvent-borne type and aqueous transfer laser aluminium-plating coating.
Embodiment
Below in conjunction with specific embodiment the present invention is elaborated.
Embodiment 1
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating, this method may further comprise the steps:
(1) gets the raw materials ready according to following component and content: 30kg water-base resin, 20kg heatproof water-base resin, 10kg solubility promoter, 39.45kg deionized water, 0.2kgpH value regulator, 0.1kg wetting agent, 0.2kg flow agent, 0.05kg skimmer; Wherein water-base resin is an ACRYLIC EMULSION; The second-order transition temperature of this ACRYLIC EMULSION is 0-30 ℃, molecular weight >=200,000; The heatproof water-base resin is a softening temperature at 120 ℃ water-based aldehyde ketone resin for the heatproof water-base resin; Solubility promoter is an ethanol; PH value regulator is an ammoniacal liquor; Wetting agent is an X 2073; Flow agent is a polyethers upgrading ZGK 5; Skimmer is commercially available KLD-970;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 100rpm, stirring at low speed 10min;
(3) in reaction kettle, add pH value regulator, the pH value of regulation system is 7.5;
(4) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 600rpm, and middling speed stirs 10min;
(5) in reaction kettle, add skimmer, the control stir speed (S.S.) is 900rpm, and high-speed stirring 20min through filtering, promptly obtains product again.
Embodiment 2
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating, this method may further comprise the steps:
(1) gets the raw materials ready according to following component and content: 40kg water-base resin, 10kg heatproof water-base resin, 5kg aqueous inorganic filler, 20kg solubility promoter, 24kg deionized water, 0.2kgpH value regulator, 0.5kg wetting agent, 0.1kg flow agent, 0.2kg skimmer; Wherein water-base resin is a PVAC polyvinylalcohol, alcoholysis degree >=85; The heatproof water-base resin is the polycarbonate polyurethane water dispersion; The aqueous inorganic filler is the nano silicon water dispersion; Solubility promoter is a Virahol; PH value regulator is a trolamine; Wetting agent is polyoxyethylene carboxylate (AE); Flow agent is an amino-modified silicone oxygen alkane; Skimmer is a T 46155 amine;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 200rpm, stirring at low speed 5min;
(3) in reaction kettle, add the aqueous inorganic filler, the control stir speed (S.S.) is 200rpm, stirring at low speed 10min;
(4) in reaction kettle, add pH value regulator, the pH value of regulation system is 8.5;
(5) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 500rpm, and middling speed stirs 15min;
(6) in reaction kettle, add skimmer, the control stir speed (S.S.) is 800rpm, and high-speed stirring 30min through filtering, promptly obtains product again.
Embodiment 3
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating, this method may further comprise the steps:
(1) get the raw materials ready according to following component and content: 35kg water-base resin, 15kg heatproof water-base resin, 2kg aqueous inorganic filler, 15kg solubility promoter, 32.35kg deionized water, 0.2kgpH value regulator, 0.2kg wetting agent, 0.15kg flow agent, 0.1kg skimmer, wherein water-base resin is plant oil modified urethane; The heatproof water-base resin is a softening temperature at 140 ℃ water-based aldehyde ketone resin for the heatproof water-base resin; The aqueous inorganic filler is the nano aluminium oxide water dispersion; Solubility promoter is a Virahol; PH value regulator is a triethylamine; Wetting agent is a methylol dodecyl carboxylic acid sodium; Flow agent is a polyethers upgrading ZGK 5; Skimmer is commercially available LH-511;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 150rpm, stirring at low speed 8min;
(3) in reaction kettle, add the aqueous inorganic filler, the control stir speed (S.S.) is 200rpm, stirring at low speed 10min;
(4) in reaction kettle, add pH value regulator, the pH value of regulation system is 8;
(5) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 600rpm, and middling speed stirs 10min;
(6) in reaction kettle, add skimmer, the control stir speed (S.S.) is 900rpm, and high-speed stirring 25min through filtering, promptly obtains product again.
Embodiment 4
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating, this method may further comprise the steps:
(1) get the raw materials ready according to following component and content: 37kg water-base resin, 12kg heatproof water-base resin, 3kg aqueous inorganic filler, 12kg solubility promoter, 18kg deionized water, 0.3kgpH value regulator, 0.5kg wetting agent, 0.1kg flow agent, 0.2kg skimmer, wherein water-base resin is the water-dispersion nitro-cotton; The heatproof water-base resin is the polycarbonate polyurethane water dispersion; The aqueous inorganic filler is the nano silicon water dispersion; Solubility promoter is a propylene glycol; PH value regulator is a 2-amino-2-methyl-1-propanol; Wetting agent is a methylol dodecyl carboxylic acid sodium; Flow agent is a polyethers upgrading ZGK 5; Skimmer is the vinylformic acid ZGK 5;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 100rpm, stirring at low speed 7min;
(3) in reaction kettle, add the aqueous inorganic filler, the control stir speed (S.S.) is 200rpm, stirring at low speed 6min;
(4) in reaction kettle, add pH value regulator, the pH value of regulation system is 7.5;
(5) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 500rpm, and middling speed stirs 10min;
(6) in reaction kettle, add skimmer, the control stir speed (S.S.) is 900rpm, and high-speed stirring 20min through filtering, promptly obtains product again.
Embodiment 5
A kind of preparation method of water-based temperature resistant single-coating transfer laser aluminizing coating, this method may further comprise the steps:
(1) get the raw materials ready according to following component and content: 33kg water-base resin, 16kg heatproof water-base resin, 1kg aqueous inorganic filler, 12kg solubility promoter, 1840kg deionized water, 0.3kgpH value regulator, 0.35kg wetting agent, 0.15kg flow agent, 0.15kg skimmer, wherein water-base resin is the acrylic acid modified polyurethane emulsion; The heatproof water-base resin is the polycarbonate polyurethane water dispersion; The aqueous inorganic filler is the nano aluminium oxide water dispersion; Solubility promoter is a propylene glycol; PH value regulator is a dimethyl amine; Wetting agent is polyoxyethylene carboxylate (AE); Flow agent is a polyethers upgrading ZGK 5; Skimmer is the vinylformic acid ZGK 5;
(2) water-base resin and heatproof water-base resin are placed reaction kettle, the control stir speed (S.S.) is 180rpm, stirring at low speed 9min;
(3) in reaction kettle, add the aqueous inorganic filler, the control stir speed (S.S.) is 200rpm, stirring at low speed 6min;
(4) in reaction kettle, add pH value regulator, the pH value of regulation system is 7.5;
(5) in reaction kettle, add wetting agent, flow agent successively, the control stir speed (S.S.) is 550rpm, and middling speed stirs 14min;
(6) in reaction kettle, add skimmer, the control stir speed (S.S.) is 900rpm, and high-speed stirring 30min through filtering, promptly obtains product again.

Claims (7)

1. a water-based temperature resistant single-coating transfer laser aluminizing coating is characterized in that, this coating comprises following component and weight part content:
Described heatproof water-base resin comprises that softening temperature is at 140-160 ℃ water-based aldehyde ketone resin or polycarbonate polyurethane water dispersion;
Described water-base resin comprises ACRYLIC EMULSION, water-based chlorine vinegar, polyurethane aqueous dispersion body, acrylic acid modified polyurethane emulsion, plant oil modified urethane or water-dispersion nitro-cotton, and the second-order transition temperature of described ACRYLIC EMULSION is 0-30 ℃, molecular weight >=200,000.
2. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1 is characterized in that described aqueous inorganic filler is the nanometer transparent filler, is selected from nano silicon water dispersion or nano aluminium oxide water dispersion.
3. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1 is characterized in that described solubility promoter comprises ethanol, Virahol or propylene glycol.
4. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1 is characterized in that, described pH value regulator comprises ammoniacal liquor, triethylamine, dimethyl amine, trolamine, 2-amino-2-methyl-1-propanol or dimethylethanolamine.
5. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1; It is characterized in that; Described wetting agent comprises anionic wetting agent or non-ionic wetting agent; Described anionic wetting agent is selected from sodium alkyl sulfate, X 2073 or methylol dodecyl carboxylic acid sodium, and described non-ionic wetting agent is selected from TX10 (APEO), high-carbon fatty alcohol polyoxyethylene ether (AEO) or polyoxyethylene carboxylate (AE).
6. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1 is characterized in that described flow agent comprises modified organic silicon, and described modified organic silicon comprises polyether-modified ZGK 5 or amino-modified silicone oxygen alkane.
7. a kind of water-based temperature resistant single-coating transfer laser aluminizing coating according to claim 1; It is characterized in that; Described skimmer comprises non-ionic interfacial agent, modified polyorganosiloxane, special hydrogen carbon cpd, modified silicone defoamer or hydrophobic particles and hydrocarbon polymer; Described non-ionic interfacial agent is selected from T 46155 amine or polyoxyethylate amide; Described modified polyorganosiloxane is selected from amino modified polysiloxane or vinylformic acid ZGK 5; Described special hydrogen carbon cpd is modest W-090 of commercially available moral or the modest W-092 of moral, and described modified silicone defoamer is selected from commercially available KLD-970 or commercially available LH-511, and described hydrophobic particles and hydrocarbon polymer are commercially available BYK-016 or the modest W-082 of moral.
CN 200910201230 2009-12-16 2009-12-16 Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof CN101768398B (en)

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