CN101716463A - Simultaneous removing device and method of various pollutants by electrocatalytical oxidation combining lime-gypsum method - Google Patents
Simultaneous removing device and method of various pollutants by electrocatalytical oxidation combining lime-gypsum method Download PDFInfo
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Abstract
本发明公开了一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。装置包喷雾降温装置、静电增强反应器、文丘里装置、双循环多种污染物一体化吸收塔、湿式静电除雾器,烟气经喷雾降温装置降温后进入静电增强反应器,烟气在静电增强反应器内所形成的电晕放电区域中进行电晕放电处理,处理后的烟气进入双循环多种污染物一体化吸收塔,在吸收塔内的经喷淋除尘和喷淋吸收,净化后的烟气依次进入喷淋塔上部的波纹板除雾器和静电除雾器,脱除烟气中气溶胶。本发明具有以下优点:1)实现多种污染物同时脱除,同时有效的控制细微颗粒和气溶胶的污染;2)各种污染物都可达到较高的脱除效率;3)脱除吸收副产物对环境不会造成二次污染。
The invention discloses an electrocatalytic oxidation combined lime-gypsum method for simultaneous removal of multiple pollutants and a method. The device includes a spray cooling device, an electrostatically enhanced reactor, a Venturi device, a double-cycle multi-pollutant integrated absorption tower, and a wet electrostatic demister. The flue gas enters the electrostatically enhanced reactor after being cooled by the spray cooling device. The corona discharge treatment is carried out in the corona discharge area formed in the enhanced reactor, and the treated flue gas enters the double-cycle multi-pollutant integrated absorption tower, and the dust removal and spray absorption in the absorption tower are purified. The final flue gas enters the corrugated plate demister and electrostatic demister on the upper part of the spray tower in turn to remove the aerosol in the flue gas. The present invention has the following advantages: 1) realize simultaneous removal of various pollutants, and simultaneously effectively control the pollution of fine particles and aerosols; 2) high removal efficiency can be achieved for various pollutants; 3) remove absorption side The product will not cause secondary pollution to the environment.
Description
技术领域technical field
本发明属于环保技术领域,尤其涉及一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。The invention belongs to the technical field of environmental protection, and in particular relates to a device and method for simultaneously removing multiple pollutants by electrocatalytic oxidation combined with a lime-gypsum method.
背景技术Background technique
目前国内外对于燃煤烟气中硫氧化物,氮氧化物,多环芳烃和二噁英等污染物的控制手段一般采用不同的设备和方法分别加以治理。国内外硫氧化物的主要控制技术是石灰石-石膏法脱硫技术和半干法脱硫技术。其中石灰石-石膏法脱硫技术存在投资大,运行费用较高,脱硫副产物难以回收利用等缺点;而半干法脱硫技术一般对高硫煤的适应性比较差,且主要应用于300MW以下机组的电厂及热电联产锅炉尾气脱硫。At present, different equipment and methods are generally used to control pollutants such as sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins in coal-fired flue gas at home and abroad. The main control technologies of sulfur oxides at home and abroad are limestone-gypsum desulfurization technology and semi-dry desulfurization technology. Among them, the limestone-gypsum desulfurization technology has disadvantages such as large investment, high operating costs, and difficult recycling of desulfurization by-products; while the semi-dry desulfurization technology generally has poor adaptability to high-sulfur coal, and is mainly used in units below 300MW. Power plant and combined heat and power boiler tail gas desulfurization.
国内外脱除烟气中氮氧化物的主要技术为选择性催化还原法(SCR)和选择性非催化还原法(SNCR)。但SCR和SNCR脱除氮氧化物都需要安装昂贵复杂的设备。如在SCR设备的安装中,其催化剂的费用占总投资额的35%,而且一般设备运行2~3年后需要跟换新的催化剂,运行成本很高。这两种工艺在发展中国家使用较少。The main technologies for removing nitrogen oxides in flue gas at home and abroad are selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR). However, both SCR and SNCR need to install expensive and complicated equipment to remove nitrogen oxides. For example, in the installation of SCR equipment, the cost of its catalyst accounts for 35% of the total investment, and the general equipment needs to be replaced with a new catalyst after 2 to 3 years of operation, and the operating cost is very high. These two processes are less used in developing countries.
国内外对于金属汞,多环芳烃和二噁英类物质的治理正处于起步阶段,还没有成熟的工艺技术,大都是采用活性炭吸附法进行去除。活性炭吸附后的产物属于危险固体废弃物,可能造成二次污染。此外,这类危险固体废弃物的处理成本也是相当昂贵的。At home and abroad, the treatment of metallic mercury, polycyclic aromatic hydrocarbons and dioxins is in its infancy, and there is no mature process technology, and most of them are removed by activated carbon adsorption. The product after activated carbon adsorption is hazardous solid waste, which may cause secondary pollution. In addition, the disposal cost of such hazardous solid waste is also quite expensive.
迄今为止,还没有一项技术可以同时脱除烟气中的硫氧化物,氮氧化物,多环芳烃和二噁英这四种污染物。进入90年代后,人们开始逐渐认识到对各种污染物分别治理,不仅占地面积大,而且投资费用高。为了降低烟气净化的费用,适应现有电厂的需要,开发可以同时脱除多种污染物的新技术和新设备已成为烟气净化技术的发展趋势。So far, there is no technology that can simultaneously remove the four pollutants of sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins in flue gas. After entering the 1990s, people began to gradually realize that the separate treatment of various pollutants not only occupies a large area, but also requires high investment costs. In order to reduce the cost of flue gas purification and meet the needs of existing power plants, it has become the development trend of flue gas purification technology to develop new technologies and new equipment that can simultaneously remove multiple pollutants.
一种采用电催化氧化联合石灰-石膏法吸收的烟气净化技术可以同时脱除烟气中的硫氧化物,氮氧化物,金属汞,多环芳烃和二噁英这四种污染物。其原理是利用烟气中的水蒸气和氧气等非污染物作为自由基生成源,在电晕区域的作用下,被分解成O,OH,O3,HO2等氧化性自由基,与烟气中的SO2,NOx,Hg0,多环芳烃和二噁英反应生成SO3,H2SO4,NO2,HNO3,二价汞,CO2和H2O,这些反应产物在后续的石灰-石膏法工艺中被吸收,从而实现多种污染物的同时脱除。A flue gas purification technology using electrocatalytic oxidation combined with lime-gypsum absorption can simultaneously remove sulfur oxides, nitrogen oxides, metallic mercury, polycyclic aromatic hydrocarbons and dioxins in flue gas. The principle is to use non-pollutants such as water vapor and oxygen in the flue gas as the source of free radicals, and under the action of the corona area, they are decomposed into oxidative free radicals such as O, OH, O 3 , HO 2 , etc. SO 2 , NOx, Hg 0 , polycyclic aromatic hydrocarbons and dioxins in the gas react to produce SO 3 , H 2 SO 4 , NO 2 , HNO 3 , divalent mercury, CO 2 and H 2 O, and these reaction products are It is absorbed in the lime-gypsum process, so as to realize the simultaneous removal of various pollutants.
发明内容Contents of the invention
本发明的目的是针对目前未有能够同时脱除烟气中的硫氧化物,氮氧化物,金属汞,多环芳烃和二噁英的技术空白,提供一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。The purpose of the present invention is to provide an electrocatalytic oxidation combined lime-gypsum method for the current technical blank that can simultaneously remove sulfur oxides, nitrogen oxides, metal mercury, polycyclic aromatic hydrocarbons and dioxins in flue gas A device and method for simultaneously removing multiple pollutants.
电催化氧化联合石灰-石膏法的多种污染物同时脱除装置包括增压风机、喷雾降温装置、静电增强反应器、文丘里装置、双循环多种污染物一体化吸收塔、湿式静电除雾器、工艺水罐、工艺水泵、石灰浆液箱、石灰浆液泵、石灰浆液循环箱、石灰浆液循环泵、沉淀池、灰水循环泵、氧化风机,工艺水由工艺水罐经工艺水泵输送至喷雾降温装置、石灰浆液箱、湿式静电除雾器以及双循环多种污染物一体化吸收塔上层除雾器;烟气经增压风机进入喷雾降温装置经工艺水喷淋降温后,经静电增强反应器的电晕放电处理,其中空气由氧化风机输送,后经文丘里装置进入双循环多种污染物一体化吸收塔,在双循环多种污染物一体化吸收塔中烟气经灰水循环泵喷雾除尘及喷淋吸收处理后,烟气进入湿式静电除雾器,后由烟囱排出;喷淋后的灰水以及经喷雾降温装置的工艺水都进入沉淀池;石灰浆液由石灰浆液箱经石灰浆液泵进入石灰浆液循环箱,后经石灰浆液循环泵进入双循环多种污染物一体化吸收塔对烟气进行喷淋吸收处理。The simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method includes booster fan, spray cooling device, electrostatically enhanced reactor, Venturi device, double-cycle multi-pollutant integrated absorption tower, wet electrostatic demisting Process water tank, process water pump, lime slurry tank, lime slurry pump, lime slurry circulation box, lime slurry circulation pump, sedimentation tank, gray water circulation pump, oxidation fan, process water is transported from the process water tank to the spray cooling system through the process water pump device, lime slurry tank, wet electrostatic demister, and double-cycle multi-pollutant integrated absorption tower upper layer demister; the flue gas enters the spray cooling device through the booster fan, sprays the process water to cool down, and passes through the electrostatic enhancement reactor Corona discharge treatment, in which the air is transported by the oxidation fan, and then enters the double-cycle multi-pollutant integrated absorption tower through the Venturi device, and the flue gas in the double-cycle multi-pollutant integrated absorption tower is sprayed and dedusted by the gray water circulation pump After spraying and absorbing treatment, the flue gas enters the wet electrostatic demister and is discharged from the chimney; the gray water after spraying and the process water passed through the spray cooling device all enter the sedimentation tank; the lime slurry flows from the lime slurry tank through the lime slurry pump Enter the lime slurry circulation box, and then enter the dual-cycle multi-pollutant integrated absorption tower through the lime slurry circulation pump to spray and absorb the flue gas.
静电增强反应器是长方形结构,包括绝缘装置、上气室、喷嘴电极、电晕放电区域、极板、混气室、氧化风机接口、布风板、下气室,静电增强反应器内从上到下设有上气室、电晕放电区域、混气室、下气室,电晕放电区域分成多个电晕放电单元,每个电晕放电单元由极板分隔开,每个电晕放电单元内并排布置喷嘴电极,喷嘴电极垂直于极板放置,混气室与下气室之间设有布风板,混气室区域的静电增强反应器壳体上设有氧化风机接口,静电增强反应器顶部设有绝缘装置。The electrostatically enhanced reactor is a rectangular structure, including an insulation device, an upper air chamber, a nozzle electrode, a corona discharge area, an electrode plate, a gas mixing chamber, an oxidation fan interface, an air distribution plate, and a lower air chamber. There are an upper air chamber, a corona discharge area, a mixed air chamber, and a lower air chamber. The corona discharge area is divided into multiple corona discharge units, and each corona discharge unit is separated by an electrode plate. The nozzle electrodes are arranged side by side in the discharge unit, and the nozzle electrodes are placed perpendicular to the pole plate. There is an air distribution plate between the gas mixing chamber and the lower gas chamber. The electrostatic enhancement reactor shell in the gas mixing chamber area is equipped with an oxidation fan interface. The top of the reinforced reactor is provided with an insulating device.
双循环多种污染物一体化吸收塔包括吸收塔入口、灰水储槽、灰水喷淋层、石灰浆液储槽、石灰浆液喷淋层、波纹板除雾器,双循环多种污染物一体化吸收塔采用两段式设计,双循环多种污染物一体化吸收塔下部为灰水储槽和灰水喷淋层,上部为石灰浆液储槽和石灰浆液喷淋层,石灰浆液喷淋层为2~4层喷淋结构,双循环多种污染物一体化吸收塔顶部为波纹板除雾器,烟气由吸收塔入口进入双循环多种污染物一体化吸收塔,先经灰水喷淋层与文丘里装置结合喷雾除尘,后进入石灰浆液喷淋层经石灰浆液空塔喷淋脱硫脱硝,后经波纹板除雾器除雾后排出双循环多种污染物一体化吸收塔。The double-cycle multi-pollutant integrated absorption tower includes the absorption tower inlet, gray water storage tank, gray water spray layer, lime slurry storage tank, lime slurry spray layer, corrugated plate demister, and double-cycle multi-pollutant integrated The chemical absorption tower adopts a two-stage design. The lower part of the double-cycle multi-pollutant integrated absorption tower is the gray water storage tank and the gray water spray layer, and the upper part is the lime slurry storage tank and the lime slurry spray layer, and the lime slurry spray layer It has a spray structure of 2 to 4 layers. The top of the double-cycle multi-pollutant integrated absorption tower is a corrugated plate demister. The flue gas enters the double-cycle multi-pollutant integrated absorption tower from the entrance of the absorption tower. The spray layer and Venturi device are combined with spray dedusting, and then enter the lime slurry spray layer to desulfurize and denitrify through the lime slurry empty tower spray, and then go through the corrugated plate demister to remove the fog and then discharge the dual-cycle multi-pollutant integrated absorption tower.
电催化氧化联合石灰-石膏法的多种污染物同时脱除方法是:烟气进入喷雾降温装置,将烟气的温度调节至70~80℃,烟气从静电增强反应器底部进入下气室,烟气在下气室中会有一个缓冲,在下气室的上部有布风板,布风板上部是混气室,补充的氧化空气会在混气室中加入并和烟气均匀混合,混气室的上部是电晕放电区域,电晕放电区域根据烟气处理量大小分成多个电晕放电单元,每个电晕放电单元由极板分隔开,每个电晕放电单元内并排布置多个的喷嘴电极,喷嘴电极数量根据实际烟气量可调,放电喷嘴电极垂直于极板放置,电晕放电反应器使用20kV~50kV直流高压电,喷嘴电极接正高压,极板接负高压,电晕放电区域的上部是上气室和烟气出口,经过上气室缓冲的烟气从出口流出进入双循环多种污染物一体化吸收塔,双循环多种污染物一体化吸收塔下部是灰水储槽和灰水喷淋层,灰水由沉淀池在灰水循环泵的作用下不断被输送到灰水喷淋层与文丘里装置结合对烟气进行喷雾除尘,双循环多种污染物一体化吸收塔上部安装有2~4层石灰浆液喷淋层和石灰浆液储槽,由石灰浆液循环泵的不断输送到石灰浆液喷淋层,和逆流而上的烟气充分接触反应,对烟气进行喷淋吸收除去烟气的多种污染物,喷淋液气比为8~20,系统出口烟尘排放小于30mg/m3;SO2排放小于200mg/m3,且系统脱硫效率不低于96%;NO排放浓度小于150mg/m3,且系统脱硝效率不低于60%,双循环多种污染物一体化吸收塔上下部的浆液循环分离;净化后的烟气进入双循环多种污染物一体化吸收塔上部的波纹板除雾器,经波纹板除雾器除雾后的烟气中的气溶胶量小于100mg/m3,烟气再通过湿式静电除雾器的进一步除雾后气溶胶量小于30mg/m3,后经烟囱排出。The method of simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method is: the flue gas enters the spray cooling device, adjusts the temperature of the flue gas to 70-80°C, and the flue gas enters the lower gas chamber from the bottom of the electrostatically enhanced reactor , the flue gas will have a buffer in the lower air chamber. There is an air distribution plate on the upper part of the lower air chamber. The upper part of the gas chamber is the corona discharge area. The corona discharge area is divided into multiple corona discharge units according to the amount of flue gas treatment. Each corona discharge unit is separated by an electrode plate, and each corona discharge unit is arranged side by side. Multiple nozzle electrodes, the number of nozzle electrodes can be adjusted according to the actual flue gas volume, the discharge nozzle electrodes are placed perpendicular to the plate, the corona discharge reactor uses 20kV ~ 50kV DC high voltage, the nozzle electrodes are connected to positive high voltage, and the plate is connected to negative High voltage, the upper part of the corona discharge area is the upper air chamber and the flue gas outlet, the flue gas buffered by the upper air chamber flows out from the outlet into the double-cycle multi-pollutant integrated absorption tower, the double-cycle multi-pollutant integrated absorption tower The lower part is the gray water storage tank and the gray water spray layer. The gray water is continuously transported to the gray water spray layer by the sedimentation tank under the action of the gray water circulation pump and combined with the Venturi device to spray and dust the flue gas. The upper part of the integrated pollutant absorption tower is equipped with 2 to 4 layers of lime slurry spray layer and lime slurry storage tank, which is continuously transported to the lime slurry spray layer by the lime slurry circulating pump, and fully contacts and reacts with the countercurrent upward flue gas. The flue gas is sprayed to absorb and remove a variety of pollutants in the flue gas. The spray liquid-gas ratio is 8-20, the dust emission at the system outlet is less than 30mg/m 3 ; the SO 2 emission is less than 200mg/m 3 , and the desulfurization efficiency of the system is low. lower than 96%; the NO emission concentration is less than 150mg/m 3 , and the denitrification efficiency of the system is not lower than 60%. The corrugated plate demister on the upper part of the integrated absorption tower for various pollutants, the amount of aerosol in the flue gas after demisting by the corrugated plate demister is less than 100mg/m 3 , and the flue gas is further demistered by the wet electrostatic eliminator The amount of aerosol after fog is less than 30mg/m 3 , and then discharged through the chimney.
本发明与现有技术相比具有的有益效果:The present invention has the beneficial effect compared with prior art:
1)可以实现多种污染物,如硫氧化物,氮氧化物,多环芳烃和二噁英的同时脱除,为烟气的治理大大节省了投资成本,工艺简单可靠;1) It can realize the simultaneous removal of various pollutants, such as sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins, which greatly saves investment costs for flue gas treatment, and the process is simple and reliable;
2)污染物的脱除效率高,其中硫氧化物的脱除效率可以达到95%以上,氮氧化物的脱除效率可以达到60%以上,金属汞的脱除效率可以达到80%以上,多环芳烃以及二噁英类物质的脱除效率可达80%以上;2) The removal efficiency of pollutants is high, among which the removal efficiency of sulfur oxides can reach more than 95%, the removal efficiency of nitrogen oxides can reach more than 60%, and the removal efficiency of metal mercury can reach more than 80%. The removal efficiency of aromatic hydrocarbons and dioxins can reach more than 80%;
3)该装置脱除副产物对环境不会造成二次污染;3) The removal of by-products by the device will not cause secondary pollution to the environment;
4)该装置可以有效的控制细微颗粒(PM2.5)和气溶胶的污染。4) The device can effectively control fine particle (PM 2.5 ) and aerosol pollution.
附图说明Description of drawings
图1电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法结构示意图;Figure 1 Schematic diagram of the simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method and method;
图2本发明的静电增强反应器结构示意图;Fig. 2 is the structural representation of the electrostatically enhanced reactor of the present invention;
图3本发明的双循环多种污染物一体化吸收塔结构示意图;Fig. 3 is the structural schematic diagram of the dual-cycle multi-pollutant integrated absorption tower of the present invention;
图中:增压风机1、喷雾降温装置2、静电增强反应器3、文丘里装置4、双循环多种污染物一体化吸收塔5、湿式静电除雾器6、工艺水罐7、工艺水泵8、石灰浆液箱9、石灰浆液泵10、石灰浆液循环箱11、石灰浆液循环泵12、沉淀池13、灰水循环泵14、氧化风机15、绝缘装置16、上气室17、喷嘴电极18、电晕放电区域19、隔板20、混气室21、氧化风机接口22、布风板23、下气室24、吸收塔入口25、灰水储槽26、灰水喷淋层27、石灰浆液储槽28、石灰浆液喷淋层29、波纹板除雾器30。In the figure: booster fan 1,
具体实施方式Detailed ways
如图1所示,电催化氧化联合石灰-石膏法的多种污染物同时脱除装置包括增压风机1、喷雾降温装置2、静电增强反应器3、文丘里装置4、双循环多种污染物一体化吸收塔5、湿式静电除雾器6、工艺水罐7、工艺水泵8、石灰浆液箱9、石灰浆液泵10、石灰浆液循环箱11、石灰浆液循环泵12、沉淀池13、灰水循环泵14、氧化风机15,工艺水由工艺水罐7经工艺水泵8输送至喷雾降温装置2、石灰浆液箱9、湿式静电除雾器6以及双循环多种污染物一体化吸收塔5上层除雾器;烟气经增压风机1进入喷雾降温装置2经工艺水喷淋降温后,经静电增强反应器3的电晕放电处理,其中空气由氧化风机15输送,后经文丘里装置4进入双循环多种污染物一体化吸收塔5,在双循环多种污染物一体化吸收塔5中烟气经灰水循环泵14喷雾除尘及喷淋吸收处理后,烟气进入湿式静电除雾器6,后由烟囱排出;喷淋后的灰水以及经喷雾降温装置2的工艺水都进入沉淀池13;石灰浆液由石灰浆液箱9经石灰浆液泵10进入石灰浆液循环箱11,后经石灰浆液循环泵12进入双循环多种污染物一体化吸收塔5对烟气进行喷淋吸收处理。As shown in Figure 1, the simultaneous removal of multiple pollutants in the electrocatalytic oxidation combined lime-gypsum process includes a booster fan 1, a
如图2所示,静电增强反应器3是长方形结构,包括绝缘装置16、上气室17、喷嘴电极18、电晕放电区域19、极板20、混气室21、氧化风机接口22、布风板23、下气室24,静电增强反应器3内从上到下设有上气室17、电晕放电区域19、混气室21、下气室24,电晕放电区域19分成多个电晕放电单元,每个电晕放电单元由极板20分隔开,每个电晕放电单元内并排布置喷嘴电极18,喷嘴电极18垂直于极板20放置,混气室21与下气室24之间设有布风板23,混气室21区域的静电增强反应器3壳体上设有氧化风机接口22,静电增强反应器3顶部设有绝缘装置16。静电增强反应器采用自由基簇射专利技术,通过正电晕产生强氧化性的自由基,氧化烟气中的NO成易于吸收的NO2、HNO3和HNO2等物质。As shown in Figure 2, the
如图3所示,双循环多种污染物一体化吸收塔5包括吸收塔入口25、灰水储槽26、灰水喷淋层27、石灰浆液储槽28、石灰浆液喷淋层29、波纹板除雾器30,双循环多种污染物一体化吸收塔5采用两段式设计,除尘和脱硫脱硝分段实施。双循环多种污染物一体化吸收塔5下部为灰水储槽26和灰水喷淋层27,与文丘里装置4结合进行喷雾除尘,实现除尘效果,上部为石灰浆液储槽28和石灰浆液喷淋层29,石灰浆液喷淋层29为2~4层喷淋结构,采用石灰浆液进行空塔喷淋脱硫脱硝,实现脱硫脱硝功能。双循环多种污染物一体化吸收塔5顶部为波纹板除雾器30,烟气由吸收塔入口25进入双循环多种污染物一体化吸收塔5,先经灰水喷淋层27与文丘里装置4结合喷雾除尘,后进入石灰浆液喷淋层29经石灰浆液空塔喷淋脱硫脱硝,后经波纹板除雾器30除雾后排出双循环多种污染物一体化吸收塔5。双循环多种污染物一体化吸收塔上下部的水循环分离,可以解决吸收塔内部设备的堵塞问题。As shown in Figure 3, the dual-cycle multi-pollutant
电催化氧化联合石灰-石膏法的多种污染物同时脱除方法是:烟气进入喷雾降温装置2,将烟气的温度调节至70~80℃,烟气从静电增强反应器3底部进入下气室24,烟气在下气室24中会有一个缓冲,在下气室24的上部有布风板23,布风板23上部是混气室21,补充的氧化空气会在混气室21中加入并和烟气均匀混合,混气室21的上部是电晕放电区域19,电晕放电区域19根据烟气处理量大小分成多个电晕放电单元,每个电晕放电单元由极板20分隔开,极板20间距采用80~120mm,每个电晕放电单元内并排布置多个的喷嘴电极18,喷嘴电极数量根据实际烟气量可调,放电喷嘴电极垂直于极板放置,电晕放电反应器使用20kV~50kV直流高压电,喷嘴电极18接正高压,极板接负高压,接通电源后,喷嘴电极18和极板20间形成强烈的电晕放电,那么从喷嘴喷出的湿烟气在静电增强反应器3中被分解成具有强氧化性的自由基(如O,OH,O3,HO2等)。这些自由基物质能有效氧化烟气中的SO2为SO3和H2SO4等,氧化NOx为NO2和HNO3等,氧化Hg0成二价汞,降解多环芳烃和二噁英为无害物质(如CO2,H2O等)。电晕放电区域19的上部是上气室17和烟气出口,经过上气室17缓冲的烟气从出口流出进入双循环多种污染物一体化吸收塔5,双循环多种污染物一体化吸收塔5下部是灰水储槽26和灰水喷淋层27,灰水由沉淀池13在灰水循环泵14的作用下不断被输送到灰水喷淋层27与文丘里装置4结合对烟气进行喷雾除尘,双循环多种污染物一体化吸收塔5上部安装有2~4层石灰浆液喷淋层29和石灰浆液储槽28,由石灰浆液循环泵12的不断输送到石灰浆液喷淋层29,和逆流而上的烟气充分接触反应,对烟气进行喷淋吸收除去烟气的多种污染物,喷淋液气比为8~20,系统出口烟尘排放小于30mg/m3;SO2排放小于200mg/m3,且系统脱硫效率不低于96%;NO排放浓度小于150mg/m3,且系统脱硝效率不低于60%,双循环多种污染物一体化吸收塔5上下部的浆液循环分离,可以解决吸收塔内部设备的堵塞问题;净化后的烟气进入双循环多种污染物一体化吸收塔5上部的波纹板除雾器30,经波纹板除雾器30除雾后的烟气中的气溶胶量小于100mg/m3,烟气再通过湿式静电除雾器6,湿式静电除雾器6能够高效捕集吸收塔内出来的酸雾和未捕集的烟尘,解决湿法吸收塔尾部的腐蚀问题,以及进一步提高除尘效果,经湿式静电除雾器的进一步除雾后气溶胶量小于30mg/m3,后经烟囱排出。The simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method is as follows: the flue gas enters the
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| CN115445406A (en) * | 2022-09-30 | 2022-12-09 | 广东青扬环保科技有限公司 | Dust removal, desulfurization and denitrification integrated treatment method and integrated treatment device |
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