CN101716463A - Simultaneous removing device and method of various pollutants by electrocatalytical oxidation combining lime-gypsum method - Google Patents

Simultaneous removing device and method of various pollutants by electrocatalytical oxidation combining lime-gypsum method Download PDF

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CN101716463A
CN101716463A CN201010039505A CN201010039505A CN101716463A CN 101716463 A CN101716463 A CN 101716463A CN 201010039505 A CN201010039505 A CN 201010039505A CN 201010039505 A CN201010039505 A CN 201010039505A CN 101716463 A CN101716463 A CN 101716463A
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flue gas
absorption tower
lime slurry
multiple pollutant
lime
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CN101716463B (en
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高翔
骆仲泱
岑可法
倪明江
吴祖良
张涌新
吴卫红
钟毅
施正伦
周劲松
方梦祥
余春江
王树荣
程乐鸣
王勤辉
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Zhejiang University ZJU
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Abstract

本发明公开了一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。装置包喷雾降温装置、静电增强反应器、文丘里装置、双循环多种污染物一体化吸收塔、湿式静电除雾器,烟气经喷雾降温装置降温后进入静电增强反应器,烟气在静电增强反应器内所形成的电晕放电区域中进行电晕放电处理,处理后的烟气进入双循环多种污染物一体化吸收塔,在吸收塔内的经喷淋除尘和喷淋吸收,净化后的烟气依次进入喷淋塔上部的波纹板除雾器和静电除雾器,脱除烟气中气溶胶。本发明具有以下优点:1)实现多种污染物同时脱除,同时有效的控制细微颗粒和气溶胶的污染;2)各种污染物都可达到较高的脱除效率;3)脱除吸收副产物对环境不会造成二次污染。

The invention discloses an electrocatalytic oxidation combined lime-gypsum method for simultaneous removal of multiple pollutants and a method. The device includes a spray cooling device, an electrostatically enhanced reactor, a Venturi device, a double-cycle multi-pollutant integrated absorption tower, and a wet electrostatic demister. The flue gas enters the electrostatically enhanced reactor after being cooled by the spray cooling device. The corona discharge treatment is carried out in the corona discharge area formed in the enhanced reactor, and the treated flue gas enters the double-cycle multi-pollutant integrated absorption tower, and the dust removal and spray absorption in the absorption tower are purified. The final flue gas enters the corrugated plate demister and electrostatic demister on the upper part of the spray tower in turn to remove the aerosol in the flue gas. The present invention has the following advantages: 1) realize simultaneous removal of various pollutants, and simultaneously effectively control the pollution of fine particles and aerosols; 2) high removal efficiency can be achieved for various pollutants; 3) remove absorption side The product will not cause secondary pollution to the environment.

Description

电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法 Device and method for simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method

技术领域technical field

本发明属于环保技术领域,尤其涉及一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。The invention belongs to the technical field of environmental protection, and in particular relates to a device and method for simultaneously removing multiple pollutants by electrocatalytic oxidation combined with a lime-gypsum method.

背景技术Background technique

目前国内外对于燃煤烟气中硫氧化物,氮氧化物,多环芳烃和二噁英等污染物的控制手段一般采用不同的设备和方法分别加以治理。国内外硫氧化物的主要控制技术是石灰石-石膏法脱硫技术和半干法脱硫技术。其中石灰石-石膏法脱硫技术存在投资大,运行费用较高,脱硫副产物难以回收利用等缺点;而半干法脱硫技术一般对高硫煤的适应性比较差,且主要应用于300MW以下机组的电厂及热电联产锅炉尾气脱硫。At present, different equipment and methods are generally used to control pollutants such as sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins in coal-fired flue gas at home and abroad. The main control technologies of sulfur oxides at home and abroad are limestone-gypsum desulfurization technology and semi-dry desulfurization technology. Among them, the limestone-gypsum desulfurization technology has disadvantages such as large investment, high operating costs, and difficult recycling of desulfurization by-products; while the semi-dry desulfurization technology generally has poor adaptability to high-sulfur coal, and is mainly used in units below 300MW. Power plant and combined heat and power boiler tail gas desulfurization.

国内外脱除烟气中氮氧化物的主要技术为选择性催化还原法(SCR)和选择性非催化还原法(SNCR)。但SCR和SNCR脱除氮氧化物都需要安装昂贵复杂的设备。如在SCR设备的安装中,其催化剂的费用占总投资额的35%,而且一般设备运行2~3年后需要跟换新的催化剂,运行成本很高。这两种工艺在发展中国家使用较少。The main technologies for removing nitrogen oxides in flue gas at home and abroad are selective catalytic reduction (SCR) and selective non-catalytic reduction (SNCR). However, both SCR and SNCR need to install expensive and complicated equipment to remove nitrogen oxides. For example, in the installation of SCR equipment, the cost of its catalyst accounts for 35% of the total investment, and the general equipment needs to be replaced with a new catalyst after 2 to 3 years of operation, and the operating cost is very high. These two processes are less used in developing countries.

国内外对于金属汞,多环芳烃和二噁英类物质的治理正处于起步阶段,还没有成熟的工艺技术,大都是采用活性炭吸附法进行去除。活性炭吸附后的产物属于危险固体废弃物,可能造成二次污染。此外,这类危险固体废弃物的处理成本也是相当昂贵的。At home and abroad, the treatment of metallic mercury, polycyclic aromatic hydrocarbons and dioxins is in its infancy, and there is no mature process technology, and most of them are removed by activated carbon adsorption. The product after activated carbon adsorption is hazardous solid waste, which may cause secondary pollution. In addition, the disposal cost of such hazardous solid waste is also quite expensive.

迄今为止,还没有一项技术可以同时脱除烟气中的硫氧化物,氮氧化物,多环芳烃和二噁英这四种污染物。进入90年代后,人们开始逐渐认识到对各种污染物分别治理,不仅占地面积大,而且投资费用高。为了降低烟气净化的费用,适应现有电厂的需要,开发可以同时脱除多种污染物的新技术和新设备已成为烟气净化技术的发展趋势。So far, there is no technology that can simultaneously remove the four pollutants of sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins in flue gas. After entering the 1990s, people began to gradually realize that the separate treatment of various pollutants not only occupies a large area, but also requires high investment costs. In order to reduce the cost of flue gas purification and meet the needs of existing power plants, it has become the development trend of flue gas purification technology to develop new technologies and new equipment that can simultaneously remove multiple pollutants.

一种采用电催化氧化联合石灰-石膏法吸收的烟气净化技术可以同时脱除烟气中的硫氧化物,氮氧化物,金属汞,多环芳烃和二噁英这四种污染物。其原理是利用烟气中的水蒸气和氧气等非污染物作为自由基生成源,在电晕区域的作用下,被分解成O,OH,O3,HO2等氧化性自由基,与烟气中的SO2,NOx,Hg0,多环芳烃和二噁英反应生成SO3,H2SO4,NO2,HNO3,二价汞,CO2和H2O,这些反应产物在后续的石灰-石膏法工艺中被吸收,从而实现多种污染物的同时脱除。A flue gas purification technology using electrocatalytic oxidation combined with lime-gypsum absorption can simultaneously remove sulfur oxides, nitrogen oxides, metallic mercury, polycyclic aromatic hydrocarbons and dioxins in flue gas. The principle is to use non-pollutants such as water vapor and oxygen in the flue gas as the source of free radicals, and under the action of the corona area, they are decomposed into oxidative free radicals such as O, OH, O 3 , HO 2 , etc. SO 2 , NOx, Hg 0 , polycyclic aromatic hydrocarbons and dioxins in the gas react to produce SO 3 , H 2 SO 4 , NO 2 , HNO 3 , divalent mercury, CO 2 and H 2 O, and these reaction products are It is absorbed in the lime-gypsum process, so as to realize the simultaneous removal of various pollutants.

发明内容Contents of the invention

本发明的目的是针对目前未有能够同时脱除烟气中的硫氧化物,氮氧化物,金属汞,多环芳烃和二噁英的技术空白,提供一种电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法。The purpose of the present invention is to provide an electrocatalytic oxidation combined lime-gypsum method for the current technical blank that can simultaneously remove sulfur oxides, nitrogen oxides, metal mercury, polycyclic aromatic hydrocarbons and dioxins in flue gas A device and method for simultaneously removing multiple pollutants.

电催化氧化联合石灰-石膏法的多种污染物同时脱除装置包括增压风机、喷雾降温装置、静电增强反应器、文丘里装置、双循环多种污染物一体化吸收塔、湿式静电除雾器、工艺水罐、工艺水泵、石灰浆液箱、石灰浆液泵、石灰浆液循环箱、石灰浆液循环泵、沉淀池、灰水循环泵、氧化风机,工艺水由工艺水罐经工艺水泵输送至喷雾降温装置、石灰浆液箱、湿式静电除雾器以及双循环多种污染物一体化吸收塔上层除雾器;烟气经增压风机进入喷雾降温装置经工艺水喷淋降温后,经静电增强反应器的电晕放电处理,其中空气由氧化风机输送,后经文丘里装置进入双循环多种污染物一体化吸收塔,在双循环多种污染物一体化吸收塔中烟气经灰水循环泵喷雾除尘及喷淋吸收处理后,烟气进入湿式静电除雾器,后由烟囱排出;喷淋后的灰水以及经喷雾降温装置的工艺水都进入沉淀池;石灰浆液由石灰浆液箱经石灰浆液泵进入石灰浆液循环箱,后经石灰浆液循环泵进入双循环多种污染物一体化吸收塔对烟气进行喷淋吸收处理。The simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method includes booster fan, spray cooling device, electrostatically enhanced reactor, Venturi device, double-cycle multi-pollutant integrated absorption tower, wet electrostatic demisting Process water tank, process water pump, lime slurry tank, lime slurry pump, lime slurry circulation box, lime slurry circulation pump, sedimentation tank, gray water circulation pump, oxidation fan, process water is transported from the process water tank to the spray cooling system through the process water pump device, lime slurry tank, wet electrostatic demister, and double-cycle multi-pollutant integrated absorption tower upper layer demister; the flue gas enters the spray cooling device through the booster fan, sprays the process water to cool down, and passes through the electrostatic enhancement reactor Corona discharge treatment, in which the air is transported by the oxidation fan, and then enters the double-cycle multi-pollutant integrated absorption tower through the Venturi device, and the flue gas in the double-cycle multi-pollutant integrated absorption tower is sprayed and dedusted by the gray water circulation pump After spraying and absorbing treatment, the flue gas enters the wet electrostatic demister and is discharged from the chimney; the gray water after spraying and the process water passed through the spray cooling device all enter the sedimentation tank; the lime slurry flows from the lime slurry tank through the lime slurry pump Enter the lime slurry circulation box, and then enter the dual-cycle multi-pollutant integrated absorption tower through the lime slurry circulation pump to spray and absorb the flue gas.

静电增强反应器是长方形结构,包括绝缘装置、上气室、喷嘴电极、电晕放电区域、极板、混气室、氧化风机接口、布风板、下气室,静电增强反应器内从上到下设有上气室、电晕放电区域、混气室、下气室,电晕放电区域分成多个电晕放电单元,每个电晕放电单元由极板分隔开,每个电晕放电单元内并排布置喷嘴电极,喷嘴电极垂直于极板放置,混气室与下气室之间设有布风板,混气室区域的静电增强反应器壳体上设有氧化风机接口,静电增强反应器顶部设有绝缘装置。The electrostatically enhanced reactor is a rectangular structure, including an insulation device, an upper air chamber, a nozzle electrode, a corona discharge area, an electrode plate, a gas mixing chamber, an oxidation fan interface, an air distribution plate, and a lower air chamber. There are an upper air chamber, a corona discharge area, a mixed air chamber, and a lower air chamber. The corona discharge area is divided into multiple corona discharge units, and each corona discharge unit is separated by an electrode plate. The nozzle electrodes are arranged side by side in the discharge unit, and the nozzle electrodes are placed perpendicular to the pole plate. There is an air distribution plate between the gas mixing chamber and the lower gas chamber. The electrostatic enhancement reactor shell in the gas mixing chamber area is equipped with an oxidation fan interface. The top of the reinforced reactor is provided with an insulating device.

双循环多种污染物一体化吸收塔包括吸收塔入口、灰水储槽、灰水喷淋层、石灰浆液储槽、石灰浆液喷淋层、波纹板除雾器,双循环多种污染物一体化吸收塔采用两段式设计,双循环多种污染物一体化吸收塔下部为灰水储槽和灰水喷淋层,上部为石灰浆液储槽和石灰浆液喷淋层,石灰浆液喷淋层为2~4层喷淋结构,双循环多种污染物一体化吸收塔顶部为波纹板除雾器,烟气由吸收塔入口进入双循环多种污染物一体化吸收塔,先经灰水喷淋层与文丘里装置结合喷雾除尘,后进入石灰浆液喷淋层经石灰浆液空塔喷淋脱硫脱硝,后经波纹板除雾器除雾后排出双循环多种污染物一体化吸收塔。The double-cycle multi-pollutant integrated absorption tower includes the absorption tower inlet, gray water storage tank, gray water spray layer, lime slurry storage tank, lime slurry spray layer, corrugated plate demister, and double-cycle multi-pollutant integrated The chemical absorption tower adopts a two-stage design. The lower part of the double-cycle multi-pollutant integrated absorption tower is the gray water storage tank and the gray water spray layer, and the upper part is the lime slurry storage tank and the lime slurry spray layer, and the lime slurry spray layer It has a spray structure of 2 to 4 layers. The top of the double-cycle multi-pollutant integrated absorption tower is a corrugated plate demister. The flue gas enters the double-cycle multi-pollutant integrated absorption tower from the entrance of the absorption tower. The spray layer and Venturi device are combined with spray dedusting, and then enter the lime slurry spray layer to desulfurize and denitrify through the lime slurry empty tower spray, and then go through the corrugated plate demister to remove the fog and then discharge the dual-cycle multi-pollutant integrated absorption tower.

电催化氧化联合石灰-石膏法的多种污染物同时脱除方法是:烟气进入喷雾降温装置,将烟气的温度调节至70~80℃,烟气从静电增强反应器底部进入下气室,烟气在下气室中会有一个缓冲,在下气室的上部有布风板,布风板上部是混气室,补充的氧化空气会在混气室中加入并和烟气均匀混合,混气室的上部是电晕放电区域,电晕放电区域根据烟气处理量大小分成多个电晕放电单元,每个电晕放电单元由极板分隔开,每个电晕放电单元内并排布置多个的喷嘴电极,喷嘴电极数量根据实际烟气量可调,放电喷嘴电极垂直于极板放置,电晕放电反应器使用20kV~50kV直流高压电,喷嘴电极接正高压,极板接负高压,电晕放电区域的上部是上气室和烟气出口,经过上气室缓冲的烟气从出口流出进入双循环多种污染物一体化吸收塔,双循环多种污染物一体化吸收塔下部是灰水储槽和灰水喷淋层,灰水由沉淀池在灰水循环泵的作用下不断被输送到灰水喷淋层与文丘里装置结合对烟气进行喷雾除尘,双循环多种污染物一体化吸收塔上部安装有2~4层石灰浆液喷淋层和石灰浆液储槽,由石灰浆液循环泵的不断输送到石灰浆液喷淋层,和逆流而上的烟气充分接触反应,对烟气进行喷淋吸收除去烟气的多种污染物,喷淋液气比为8~20,系统出口烟尘排放小于30mg/m3;SO2排放小于200mg/m3,且系统脱硫效率不低于96%;NO排放浓度小于150mg/m3,且系统脱硝效率不低于60%,双循环多种污染物一体化吸收塔上下部的浆液循环分离;净化后的烟气进入双循环多种污染物一体化吸收塔上部的波纹板除雾器,经波纹板除雾器除雾后的烟气中的气溶胶量小于100mg/m3,烟气再通过湿式静电除雾器的进一步除雾后气溶胶量小于30mg/m3,后经烟囱排出。The method of simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method is: the flue gas enters the spray cooling device, adjusts the temperature of the flue gas to 70-80°C, and the flue gas enters the lower gas chamber from the bottom of the electrostatically enhanced reactor , the flue gas will have a buffer in the lower air chamber. There is an air distribution plate on the upper part of the lower air chamber. The upper part of the gas chamber is the corona discharge area. The corona discharge area is divided into multiple corona discharge units according to the amount of flue gas treatment. Each corona discharge unit is separated by an electrode plate, and each corona discharge unit is arranged side by side. Multiple nozzle electrodes, the number of nozzle electrodes can be adjusted according to the actual flue gas volume, the discharge nozzle electrodes are placed perpendicular to the plate, the corona discharge reactor uses 20kV ~ 50kV DC high voltage, the nozzle electrodes are connected to positive high voltage, and the plate is connected to negative High voltage, the upper part of the corona discharge area is the upper air chamber and the flue gas outlet, the flue gas buffered by the upper air chamber flows out from the outlet into the double-cycle multi-pollutant integrated absorption tower, the double-cycle multi-pollutant integrated absorption tower The lower part is the gray water storage tank and the gray water spray layer. The gray water is continuously transported to the gray water spray layer by the sedimentation tank under the action of the gray water circulation pump and combined with the Venturi device to spray and dust the flue gas. The upper part of the integrated pollutant absorption tower is equipped with 2 to 4 layers of lime slurry spray layer and lime slurry storage tank, which is continuously transported to the lime slurry spray layer by the lime slurry circulating pump, and fully contacts and reacts with the countercurrent upward flue gas. The flue gas is sprayed to absorb and remove a variety of pollutants in the flue gas. The spray liquid-gas ratio is 8-20, the dust emission at the system outlet is less than 30mg/m 3 ; the SO 2 emission is less than 200mg/m 3 , and the desulfurization efficiency of the system is low. lower than 96%; the NO emission concentration is less than 150mg/m 3 , and the denitrification efficiency of the system is not lower than 60%. The corrugated plate demister on the upper part of the integrated absorption tower for various pollutants, the amount of aerosol in the flue gas after demisting by the corrugated plate demister is less than 100mg/m 3 , and the flue gas is further demistered by the wet electrostatic eliminator The amount of aerosol after fog is less than 30mg/m 3 , and then discharged through the chimney.

本发明与现有技术相比具有的有益效果:The present invention has the beneficial effect compared with prior art:

1)可以实现多种污染物,如硫氧化物,氮氧化物,多环芳烃和二噁英的同时脱除,为烟气的治理大大节省了投资成本,工艺简单可靠;1) It can realize the simultaneous removal of various pollutants, such as sulfur oxides, nitrogen oxides, polycyclic aromatic hydrocarbons and dioxins, which greatly saves investment costs for flue gas treatment, and the process is simple and reliable;

2)污染物的脱除效率高,其中硫氧化物的脱除效率可以达到95%以上,氮氧化物的脱除效率可以达到60%以上,金属汞的脱除效率可以达到80%以上,多环芳烃以及二噁英类物质的脱除效率可达80%以上;2) The removal efficiency of pollutants is high, among which the removal efficiency of sulfur oxides can reach more than 95%, the removal efficiency of nitrogen oxides can reach more than 60%, and the removal efficiency of metal mercury can reach more than 80%. The removal efficiency of aromatic hydrocarbons and dioxins can reach more than 80%;

3)该装置脱除副产物对环境不会造成二次污染;3) The removal of by-products by the device will not cause secondary pollution to the environment;

4)该装置可以有效的控制细微颗粒(PM2.5)和气溶胶的污染。4) The device can effectively control fine particle (PM 2.5 ) and aerosol pollution.

附图说明Description of drawings

图1电催化氧化联合石灰-石膏法的多种污染物同时脱除装置及方法结构示意图;Figure 1 Schematic diagram of the simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method and method;

图2本发明的静电增强反应器结构示意图;Fig. 2 is the structural representation of the electrostatically enhanced reactor of the present invention;

图3本发明的双循环多种污染物一体化吸收塔结构示意图;Fig. 3 is the structural schematic diagram of the dual-cycle multi-pollutant integrated absorption tower of the present invention;

图中:增压风机1、喷雾降温装置2、静电增强反应器3、文丘里装置4、双循环多种污染物一体化吸收塔5、湿式静电除雾器6、工艺水罐7、工艺水泵8、石灰浆液箱9、石灰浆液泵10、石灰浆液循环箱11、石灰浆液循环泵12、沉淀池13、灰水循环泵14、氧化风机15、绝缘装置16、上气室17、喷嘴电极18、电晕放电区域19、隔板20、混气室21、氧化风机接口22、布风板23、下气室24、吸收塔入口25、灰水储槽26、灰水喷淋层27、石灰浆液储槽28、石灰浆液喷淋层29、波纹板除雾器30。In the figure: booster fan 1, spray cooling device 2, electrostatic enhanced reactor 3, Venturi device 4, double-cycle multi-pollutant integrated absorption tower 5, wet electrostatic demister 6, process water tank 7, process water pump 8. Lime slurry tank 9, lime slurry pump 10, lime slurry circulation box 11, lime slurry circulation pump 12, sedimentation tank 13, gray water circulation pump 14, oxidation fan 15, insulation device 16, upper air chamber 17, nozzle electrode 18, Corona discharge area 19, separator 20, gas mixing chamber 21, oxidation fan interface 22, air distribution plate 23, lower air chamber 24, absorption tower inlet 25, gray water storage tank 26, gray water spray layer 27, lime slurry Storage tank 28, lime slurry spray layer 29, corrugated plate demister 30.

具体实施方式Detailed ways

如图1所示,电催化氧化联合石灰-石膏法的多种污染物同时脱除装置包括增压风机1、喷雾降温装置2、静电增强反应器3、文丘里装置4、双循环多种污染物一体化吸收塔5、湿式静电除雾器6、工艺水罐7、工艺水泵8、石灰浆液箱9、石灰浆液泵10、石灰浆液循环箱11、石灰浆液循环泵12、沉淀池13、灰水循环泵14、氧化风机15,工艺水由工艺水罐7经工艺水泵8输送至喷雾降温装置2、石灰浆液箱9、湿式静电除雾器6以及双循环多种污染物一体化吸收塔5上层除雾器;烟气经增压风机1进入喷雾降温装置2经工艺水喷淋降温后,经静电增强反应器3的电晕放电处理,其中空气由氧化风机15输送,后经文丘里装置4进入双循环多种污染物一体化吸收塔5,在双循环多种污染物一体化吸收塔5中烟气经灰水循环泵14喷雾除尘及喷淋吸收处理后,烟气进入湿式静电除雾器6,后由烟囱排出;喷淋后的灰水以及经喷雾降温装置2的工艺水都进入沉淀池13;石灰浆液由石灰浆液箱9经石灰浆液泵10进入石灰浆液循环箱11,后经石灰浆液循环泵12进入双循环多种污染物一体化吸收塔5对烟气进行喷淋吸收处理。As shown in Figure 1, the simultaneous removal of multiple pollutants in the electrocatalytic oxidation combined lime-gypsum process includes a booster fan 1, a spray cooling device 2, an electrostatically enhanced reactor 3, a Venturi device 4, and a double-cycle multiple pollution Material integrated absorption tower 5, wet electrostatic demister 6, process water tank 7, process water pump 8, lime slurry tank 9, lime slurry pump 10, lime slurry circulation box 11, lime slurry circulation pump 12, sedimentation tank 13, ash Water circulation pump 14, oxidation blower 15, process water is transported from process water tank 7 through process water pump 8 to spray cooling device 2, lime slurry tank 9, wet electrostatic demister 6 and the upper layer of double-cycle multi-pollutant integrated absorption tower 5 Demister; the flue gas enters the spray cooling device 2 through the booster fan 1, and after being sprayed and cooled by process water, it is treated by the corona discharge of the electrostatic enhancement reactor 3, in which the air is transported by the oxidation fan 15, and then passes through the Venturi device 4 Enter the double-cycle multi-pollutant integrated absorption tower 5, after the flue gas in the double-cycle multi-pollutant integrated absorption tower 5 is sprayed and dusted by the gray water circulation pump 14 and sprayed and absorbed, the flue gas enters the wet electrostatic demister 6. Finally, it is discharged from the chimney; the gray water after spraying and the process water passed through the spray cooling device 2 all enter the sedimentation tank 13; the lime slurry enters the lime slurry circulation box 11 from the lime slurry tank 9 through the lime slurry pump 10, and then passes through the lime slurry tank 9. The slurry circulation pump 12 enters the dual-cycle multi-pollutant integrated absorption tower 5 to spray and absorb the flue gas.

如图2所示,静电增强反应器3是长方形结构,包括绝缘装置16、上气室17、喷嘴电极18、电晕放电区域19、极板20、混气室21、氧化风机接口22、布风板23、下气室24,静电增强反应器3内从上到下设有上气室17、电晕放电区域19、混气室21、下气室24,电晕放电区域19分成多个电晕放电单元,每个电晕放电单元由极板20分隔开,每个电晕放电单元内并排布置喷嘴电极18,喷嘴电极18垂直于极板20放置,混气室21与下气室24之间设有布风板23,混气室21区域的静电增强反应器3壳体上设有氧化风机接口22,静电增强反应器3顶部设有绝缘装置16。静电增强反应器采用自由基簇射专利技术,通过正电晕产生强氧化性的自由基,氧化烟气中的NO成易于吸收的NO2、HNO3和HNO2等物质。As shown in Figure 2, the electrostatic enhancement reactor 3 is a rectangular structure, including an insulating device 16, an upper gas chamber 17, a nozzle electrode 18, a corona discharge area 19, a pole plate 20, a gas mixing chamber 21, an oxidation fan interface 22, cloth Wind plate 23, lower air chamber 24, the electrostatic enhancement reactor 3 is provided with an upper air chamber 17, a corona discharge area 19, a gas mixing chamber 21, and a lower air chamber 24 from top to bottom, and the corona discharge area 19 is divided into multiple Corona discharge unit, each corona discharge unit is separated by pole plate 20, nozzle electrodes 18 are arranged side by side in each corona discharge unit, nozzle electrodes 18 are placed perpendicular to pole plate 20, gas mixing chamber 21 and lower gas chamber An air distribution plate 23 is provided between 24, an oxidation fan interface 22 is provided on the shell of the electrostatically enhanced reactor 3 in the area of the gas mixing chamber 21, and an insulating device 16 is provided on the top of the electrostatically enhanced reactor 3. The electrostatically enhanced reactor adopts the patented free radical shower technology, which generates strong oxidizing free radicals through positive corona, and oxidizes NO in the flue gas into easily absorbed NO2, HNO3 and HNO2 and other substances.

如图3所示,双循环多种污染物一体化吸收塔5包括吸收塔入口25、灰水储槽26、灰水喷淋层27、石灰浆液储槽28、石灰浆液喷淋层29、波纹板除雾器30,双循环多种污染物一体化吸收塔5采用两段式设计,除尘和脱硫脱硝分段实施。双循环多种污染物一体化吸收塔5下部为灰水储槽26和灰水喷淋层27,与文丘里装置4结合进行喷雾除尘,实现除尘效果,上部为石灰浆液储槽28和石灰浆液喷淋层29,石灰浆液喷淋层29为2~4层喷淋结构,采用石灰浆液进行空塔喷淋脱硫脱硝,实现脱硫脱硝功能。双循环多种污染物一体化吸收塔5顶部为波纹板除雾器30,烟气由吸收塔入口25进入双循环多种污染物一体化吸收塔5,先经灰水喷淋层27与文丘里装置4结合喷雾除尘,后进入石灰浆液喷淋层29经石灰浆液空塔喷淋脱硫脱硝,后经波纹板除雾器30除雾后排出双循环多种污染物一体化吸收塔5。双循环多种污染物一体化吸收塔上下部的水循环分离,可以解决吸收塔内部设备的堵塞问题。As shown in Figure 3, the dual-cycle multi-pollutant integrated absorption tower 5 includes an absorption tower inlet 25, a gray water storage tank 26, a gray water spray layer 27, a lime slurry storage tank 28, a lime slurry spray layer 29, corrugated The plate demister 30 and the double-cycle multi-pollutant integrated absorption tower 5 adopt a two-stage design, and dust removal, desulfurization and denitrification are implemented in stages. The lower part of the double-cycle multi-pollutant integrated absorption tower 5 is the gray water storage tank 26 and the gray water spray layer 27, which is combined with the Venturi device 4 to perform spray dust removal to achieve the dust removal effect, and the upper part is the lime slurry storage tank 28 and lime slurry The spray layer 29, the lime slurry spray layer 29 has a 2-4 layer spray structure, and the lime slurry is used to spray desulfurization and denitrification in an empty tower to realize the function of desulfurization and denitrification. The top of the double-cycle multi-pollutant integrated absorption tower 5 is a corrugated plate demister 30, and the flue gas enters the double-cycle multi-pollutant integrated absorption tower 5 from the absorption tower inlet 25, and first passes through the gray water spray layer 27 and the venturi. The device 4 is combined with spray dedusting, and then enters the lime slurry spray layer 29, desulfurizes and denitrates through the lime slurry empty tower spray, and then discharges the double-cycle multi-pollutant integrated absorption tower 5 after demisting by the corrugated plate demister 30. The water circulation separation in the upper and lower parts of the double-cycle multi-pollutant integrated absorption tower can solve the problem of blockage of the internal equipment of the absorption tower.

电催化氧化联合石灰-石膏法的多种污染物同时脱除方法是:烟气进入喷雾降温装置2,将烟气的温度调节至70~80℃,烟气从静电增强反应器3底部进入下气室24,烟气在下气室24中会有一个缓冲,在下气室24的上部有布风板23,布风板23上部是混气室21,补充的氧化空气会在混气室21中加入并和烟气均匀混合,混气室21的上部是电晕放电区域19,电晕放电区域19根据烟气处理量大小分成多个电晕放电单元,每个电晕放电单元由极板20分隔开,极板20间距采用80~120mm,每个电晕放电单元内并排布置多个的喷嘴电极18,喷嘴电极数量根据实际烟气量可调,放电喷嘴电极垂直于极板放置,电晕放电反应器使用20kV~50kV直流高压电,喷嘴电极18接正高压,极板接负高压,接通电源后,喷嘴电极18和极板20间形成强烈的电晕放电,那么从喷嘴喷出的湿烟气在静电增强反应器3中被分解成具有强氧化性的自由基(如O,OH,O3,HO2等)。这些自由基物质能有效氧化烟气中的SO2为SO3和H2SO4等,氧化NOx为NO2和HNO3等,氧化Hg0成二价汞,降解多环芳烃和二噁英为无害物质(如CO2,H2O等)。电晕放电区域19的上部是上气室17和烟气出口,经过上气室17缓冲的烟气从出口流出进入双循环多种污染物一体化吸收塔5,双循环多种污染物一体化吸收塔5下部是灰水储槽26和灰水喷淋层27,灰水由沉淀池13在灰水循环泵14的作用下不断被输送到灰水喷淋层27与文丘里装置4结合对烟气进行喷雾除尘,双循环多种污染物一体化吸收塔5上部安装有2~4层石灰浆液喷淋层29和石灰浆液储槽28,由石灰浆液循环泵12的不断输送到石灰浆液喷淋层29,和逆流而上的烟气充分接触反应,对烟气进行喷淋吸收除去烟气的多种污染物,喷淋液气比为8~20,系统出口烟尘排放小于30mg/m3;SO2排放小于200mg/m3,且系统脱硫效率不低于96%;NO排放浓度小于150mg/m3,且系统脱硝效率不低于60%,双循环多种污染物一体化吸收塔5上下部的浆液循环分离,可以解决吸收塔内部设备的堵塞问题;净化后的烟气进入双循环多种污染物一体化吸收塔5上部的波纹板除雾器30,经波纹板除雾器30除雾后的烟气中的气溶胶量小于100mg/m3,烟气再通过湿式静电除雾器6,湿式静电除雾器6能够高效捕集吸收塔内出来的酸雾和未捕集的烟尘,解决湿法吸收塔尾部的腐蚀问题,以及进一步提高除尘效果,经湿式静电除雾器的进一步除雾后气溶胶量小于30mg/m3,后经烟囱排出。The simultaneous removal of multiple pollutants by electrocatalytic oxidation combined with lime-gypsum method is as follows: the flue gas enters the spray cooling device 2, the temperature of the flue gas is adjusted to 70-80°C, and the flue gas enters the bottom of the electrostatically enhanced reactor 3 into the lower Air chamber 24, the flue gas will have a buffer in the lower air chamber 24, there is an air distribution plate 23 on the upper part of the lower air chamber 24, and the upper part of the air distribution plate 23 is the air mixing chamber 21, and the supplementary oxidized air will be in the air mixing chamber 21 Add and mix evenly with the flue gas. The upper part of the gas mixing chamber 21 is a corona discharge area 19. The corona discharge area 19 is divided into multiple corona discharge units according to the amount of flue gas treatment. Each corona discharge unit is composed of a plate 20 Separated, the distance between the pole plates 20 is 80-120mm, and multiple nozzle electrodes 18 are arranged side by side in each corona discharge unit. The number of nozzle electrodes 18 can be adjusted according to the actual smoke volume. The corona discharge reactor uses 20kV ~ 50kV DC high voltage, the nozzle electrode 18 is connected to positive high voltage, and the pole plate is connected to negative high voltage. The wet flue gas is decomposed into strong oxidizing free radicals (such as O, OH, O 3 , HO 2 , etc.) in the electrostatic enhancement reactor 3 . These free radical substances can effectively oxidize SO 2 in flue gas to SO 3 and H 2 SO 4 , etc., oxidize NOx to NO 2 and HNO 3 , etc., oxidize Hg 0 to divalent mercury, and degrade polycyclic aromatic hydrocarbons and dioxins to Harmless substances (such as CO 2 , H 2 O, etc.). The upper part of the corona discharge area 19 is the upper air chamber 17 and the flue gas outlet. The flue gas buffered by the upper air chamber 17 flows out from the outlet and enters the double-cycle multi-pollutant integrated absorption tower 5, and the double-cycle multi-pollutant integration The lower part of the absorption tower 5 is the gray water storage tank 26 and the gray water spray layer 27. The gray water is continuously transported to the gray water spray layer 27 by the sedimentation tank 13 under the action of the gray water circulation pump 14, and is combined with the Venturi device 4 to counteract the smoke. 2 to 4 lime slurry spray layers 29 and lime slurry storage tanks 28 are installed on the upper part of the double-cycle multi-pollutant integrated absorption tower 5, which are continuously transported to the lime slurry spray by the lime slurry circulation pump 12 Layer 29 fully contacts and reacts with the countercurrent flue gas, and sprays the flue gas to absorb and remove various pollutants in the flue gas. The spray liquid-gas ratio is 8-20, and the flue gas emission at the system outlet is less than 30 mg/m 3 ; SO 2 emission is less than 200mg/m 3 , and the desulfurization efficiency of the system is not less than 96%; NO emission concentration is less than 150mg/m 3 , and the system denitrification efficiency is not less than 60%, and the double-cycle multi-pollutant integrated absorption tower 5 up and down Slurry cycle separation at the bottom of the absorption tower can solve the problem of blockage of the equipment inside the absorption tower; the purified flue gas enters the corrugated plate demister 30 on the upper part of the double-cycle multi-pollutant integrated absorption tower 5, and is demistered by the corrugated plate demister 30 The amount of aerosol in the fogged flue gas is less than 100mg/m3, and the flue gas passes through the wet electrostatic demister 6, which can efficiently capture the acid mist and uncaptured smoke from the absorption tower, Solve the corrosion problem at the tail of the wet absorption tower and further improve the dust removal effect. After further demisting by the wet electrostatic demister, the aerosol amount is less than 30mg/m3, and then discharged through the chimney.

Claims (4)

1. the multiple pollutant of a catalytic oxidation associating lime-gypsum method removes device simultaneously, it is characterized in that comprising booster fan (1), mist cooling device (2), static enhancing reactor (3), Venturi (4), the integrated absorption tower of the multiple pollutant of two circulations (5), wet electrostatic demister (6), technology water pot (7), technology water pump (8), lime slurry case (9), lime white liquid pump (10), lime slurry circulating box (11), lime slurry circulating pump (12), sedimentation basin (13), ash water-circulating pump (14), oxidation fan (1 5), fresh water (FW) is delivered to mist cooling device (2) by technology water pot (7) through technology water pump (8), lime slurry case (9), wet electrostatic demister (6) and upper strata, the integrated absorption tower of the multiple pollutant of two circulation (5) demister; Flue gas enters mist cooling device (2) behind the fresh water (FW) spraying cooling through booster fan (1), Corona discharge Treatment through static enhancing reactor (3), wherein air is carried by oxidation fan (15), after Venturi (4) enters two circulations integrated absorption tower of multiple pollutant (5), flue gas is after grey water-circulating pump (14) spray for dust suppression and spray absorption processing in the integrated absorption tower of the multiple pollutant of two circulations (5), flue gas enters wet electrostatic demister (6), and the back is discharged by chimney; Buck behind the spray and all enter sedimentation basin (13) through the fresh water (FW) of mist cooling device (2); Lime slurry enters lime slurry circulating box (11) by lime slurry case (9) through lime white liquid pump (10), after lime slurry circulating pump (12) enters two circulation integrated absorption towers of multiple pollutant (5) flue gas is sprayed the absorption processing.
2. the multiple pollutant of a kind of catalytic oxidation associating lime-gypsum method according to claim 1 removes device simultaneously, it is characterized in that described static enhancing reactor (3) is a rectangle structure, comprise seal (16), upper chamber (17), injector electrode (18), corona discharging area (19), pole plate (20), mixing chamber (21), oxidation fan interface (22), air distribution plate (23), lower chamber (24), be provided with upper chamber (17) in the static enhancing reactor (3) from top to bottom, corona discharging area (19), mixing chamber (21), lower chamber (24), corona discharging area (19) is divided into a plurality of corona discharges unit, each corona discharge unit is separated by pole plate (20), injector electrode (18) is arranged side by side in each corona discharge unit, injector electrode (18) is placed perpendicular to pole plate (20), be provided with air distribution plate (23) between mixing chamber (21) and the lower chamber (24), static enhancing reactor (3) housing in mixing chamber (21) zone is provided with oxidation fan interface (22), and static enhancing reactor (3) top is provided with seal (16).
3. the multiple pollutant of a kind of catalytic oxidation associating lime-gypsum method according to claim 1 removes device simultaneously, it is characterized in that described two circulation integrated absorption towers of multiple pollutant (5) comprise absorption tower inlet (25), buck storage tank (26), buck spraying layer (27), lime slurry storage tank (28), lime slurry spraying layer (29), corrugated plating demister (30), two-piece design is adopted on the integrated absorption tower of the multiple pollutant of two circulations (5), bottom, the integrated absorption tower of the multiple pollutant of two circulations (5) is buck storage tank (26) and buck spraying layer (27), top is lime slurry storage tank (28) and lime slurry spraying layer (29), lime slurry spraying layer (29) is 2~4 layers of spray structure, top, the integrated absorption tower of the multiple pollutant of two circulations (5) is corrugated plating demister (30), flue gas enters two circulations integrated absorption tower of multiple pollutant (5) by absorption tower inlet (25), earlier combine spray for dust suppression with Venturi (4) through buck spraying layer (27), after enter lime slurry spraying layer (29) through lime slurry hollow-spraying-tower desulphurization denitration, after discharge two circulations integrated absorption towers of multiple pollutant (5) after corrugated plating demister (30) demist.
4. the multiple pollutant of catalytic oxidation associating lime-gypsum method removal methods simultaneously, it is characterized in that flue gas enters mist cooling device (2), with adjustment to 70~80 of flue gas ℃, flue gas enters lower chamber (24) from static enhancing reactor (3) bottom, flue gas has a buffering in lower chamber (24), on the top of lower chamber (24) air distribution plate (23) is arranged, air distribution plate (23) top is mixing chamber (21), the oxidation air that replenishes can add in mixing chamber (21) also and flue gas evenly mixes, the top of mixing chamber (21) is corona discharging area (19), corona discharging area (19) is divided into a plurality of corona discharges unit according to the flue gas process lot size, each corona discharge unit is separated by pole plate (20), a plurality of injector electrode (18) is arranged side by side in each corona discharge unit, injector electrode quantity is adjustable according to actual exhaust gas volumn, the discharge injector electrode is placed perpendicular to pole plate, corona discharge reactor uses 20kV~50kV dc high-voltage, injector electrode (18) connects positive high voltage, pole plate connects negative high voltage, the top of corona discharging area (19) is upper chamber (17) and exhanst gas outlet, flue gas through upper chamber (17) buffering enters two circulations integrated absorption tower of multiple pollutant (5) from the outlet outflow, bottom, the integrated absorption tower of the multiple pollutant of two circulations (5) is buck storage tank (26) and buck spraying layer (27), buck constantly is transported to buck spraying layer (27) by sedimentation basin (13) and combines with Venturi (4) flue gas is carried out spray for dust suppression under the effect of grey water-circulating pump (14), top, the integrated absorption tower of the multiple pollutant of two circulations (5) is equipped with 2~4 layers of lime slurry spraying layer (29) and lime slurry storage tank (28), constantly be transported to lime slurry spraying layer (29) by lime slurry circulating pump (12), with the abundant haptoreaction of upstream flue gas, flue gas is sprayed the multiple pollutant that flue gas is removed in absorption, the spray liquid-gas ratio is 8~20, and the system outlet soot emissions are less than 30mg/m 3SO 2Discharging is less than 200mg/m 3, and system's desulfuration efficiency is not less than 96%; The NO concentration of emission is less than 150mg/m 3And system's denitration efficiency is not less than 60%, the slurries circulation of top and the bottom, the integrated absorption tower of the multiple pollutant of two circulations (5) separates, flue gas after being purified enters the corrugated plating demister (30) on two circulations top, the integrated absorption tower of multiple pollutant (5), and the aerosol amount in the flue gas after corrugated plating demister (30) demist is less than 100mg/m 3, the aerosol amount was less than 30mg/m after flue gas passed through the further demist of wet electrostatic demister (6) again 3, after chimney is discharged.
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CN102179146A (en) * 2011-04-26 2011-09-14 华北电力大学 Smoke desulfuration and denitration system absorbed by dielectric barrier discharge combined lye and process thereof
CN102240500A (en) * 2011-06-28 2011-11-16 华北电力大学 System and process for desulfuration and denitration by pure oxygen dielectric barrier discharge in flue
CN102527215A (en) * 2011-12-27 2012-07-04 安徽皖维高新材料股份有限公司 Method for recycling ethylene gas from tail gas and water alkaline washing tower thereof
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