CN101705115B - Poly-generation system and method of catalyzed and gasified coal-based energy chemical product - Google Patents

Poly-generation system and method of catalyzed and gasified coal-based energy chemical product Download PDF

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CN101705115B
CN101705115B CN200810240182.4A CN200810240182A CN101705115B CN 101705115 B CN101705115 B CN 101705115B CN 200810240182 A CN200810240182 A CN 200810240182A CN 101705115 B CN101705115 B CN 101705115B
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coal
hydrogen
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poly
methane
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CN101705115A (en
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甘中学
李金来
徐春保
曹文
张红梅
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ENN Science and Technology Development Co Ltd
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ENN Science and Technology Development Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

Abstract

The invention provides a poly-generation system and a method of a catalyzed and gasified coal-based energy chemical product. Coal is converted into clean energy chemical products and/or clean electricity such as methane by the techniques of integrated catalytic coal gasification, coal-based poly-generation, renewable energy source utilization and carbon dioxide emission reduction to form an ecocycling mode for development and utilization of coal resources.

Description

A kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method
Technical field
The invention belongs to the energy and chemical field, relate in particular to a kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method.
Background technology
In world's primary energy source consumption, coal is fastest-rising fuel, surmounts the growth that oil and natural gas realizes the market share for years.But coal is also the fossil oil that carbon content is the highest, in burning and conversion process, inevitably produce great amount of carbon dioxide, and Carbon emission on the impact of Global climate change by the world is paid close attention to, so it is very urgent to solve the problem of Carbon emission.
" rich coal, few oil, deficency " is the basic characteristics of China energy resource structures.In China's fossil energy total amount, 95.6% is coal, and coal production, consumption rank first in the world for successive years.This energy structure determines the general layout of Chinese primary energy source based on coal and is difficult to change within quite long period.But traditional coal mining and Land use systems, exist the problems such as coal resources comprehensive utilization ratio is very low, discharge great amount of carbon dioxide, in addition, the brown coal development and utilization not yet very well of China's 1,290 hundred million tons of reserves.Therefore, development of new coal chemical technology is badly in need of in China, changes traditional coal mining and use-pattern, efficient, clean, safely utilize comprise brown coal enrich coal resources.
Catalytic coal gasification and coal and water vapor generate methane, carbon monoxide, the effective constituents such as hydrogen and carbonic acid gas, a small amount of hydrogen sulfide and ammonia under the effect of catalyzer.Catalytic coal gasifaction generally adopts fluidized-bed, compared with other gasifying process, this technology has can without oxygen production methane, methane content is higher, temperature of reaction is lower, gasification can occur simultaneously, do not have independent transformationreation and methanation reaction in vapourizing furnace, need not arrange conversion section and methanation workshop section, large-scale fluidized bed use will improve turnout, greatly reduce investment outlay.Owing to not needing oxygen, ashes clogging problems is uncomplicated, can realize draining slag continuously, and the recovery of catalyzer is simple simultaneously, and gas residence time in vapourizing furnace is long, and catalyzer also can stop the generation of tar.Gasifier temperature is lower, requires also not harsh to reactor material and mechanical workout etc.But this technique also exists following shortcoming, catalyzer can not stop weak coking completely, and the actual conversion of carbon is no more than 90%, produces great amount of carbon dioxide gas in reaction, can not solve the emission problem of carbonic acid gas.
CN101024783A discloses a kind of chemical-power multi-combined production production system, this system adopts crude synthesis gas directly chemical industry synthesis after cooling, purification, a reacted synthetic gas part is used for circulation, and another part is used for fuel feeding Gas/Steam combined cycle system and generates electricity.This system main purpose utilizes synthetic gas waste heat to reach energy-saving effect, do not solve CO 2the problem of discharge, can not realize ecological circulation and produce.
When producing firedamp by syngas, methyl alcohol, ethylene glycol, low-carbon alcohol or dme etc., usually need to regulate hydrogen-carbon ratio (as added a certain amount of H in synthetic gas 2).Although the industrial hydrogen of about 96% derives from the fossil energies such as Sweet natural gas, oil and coal at present, the production technology of fossil energy hydrogen manufacturing and technique is used not to solve CO 2emission problem, thus can not realize ecological circulation and produce.In other hydrogen producing technology, water electrolysis hydrogen producing applies at present comparatively extensively and one of hydrogen production process of relative maturity.It is current most prospect and the most feasible technology that the electric energy (comprising sun power, wind energy etc.) utilizing renewable energy source to produce carrys out water electrolysis hydrogen producing as power, is called as the optimal path leading to hydrogen economy.But water electrolysis hydrogen producing and catalytic coal gasifaction coproduction yet there are no report at present.
To sum up, the chemical poly-generation of coal-based energy technology that countries in the world are developed in succession does not all have system to consider Resources of Carbon Dioxide Utilizing question, how to control and to reduce coal at the carbonic acid gas transformed and produce in combustion processes, and by its recycling, become the matter of utmost importance of New Coal Chemical technical development.Although in view of the seriousness of " Greenhouse effect ", American-European countries begins one's study coal-based near zero release polygenerations systeme in recent years, but due to carbon dioxide chemistry stable in properties, this coal-based near zero release polygenerations systeme cannot realize carbon dioxide discharge-reduction in process of production, the method trapping and seal up for safekeeping can only be adopted to go to solve, and this method is with high costs, really can not reduce carbonic acid gas from amount, long-range it seems is only makeshift.Thoroughly to solve the problem of carbonic acid gas, just must break through the limitation of existing fossil energy, renewable energy source be introduced the production process of coal derived energy chemical product, realize the fusion of multiple-energy-source, be derived energy chemical product by carbon dioxide conversion, thus realize the near zero release of production process carbonic acid gas.
Summary of the invention
The invention belongs to the energy and chemical field, relate in particular to a kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method, comprise the system and method for the coal-based methane combined production of methanol and/or dme etc. based on catalytic coal gasifaction.The invention still further relates to the production method indirectly or directly realizing the required hydrogen related in the method for Resources of Carbon Dioxide and the method in conjunction with said system and method.
The object of the invention is to propose a kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method, form the production model of ecological circulation formula, realize the near zero release of carbonic acid gas.
For reaching this object, technical scheme provided by the invention is: a kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method, the cleaner production that coal changes methane, dme, methyl alcohol, ethylene glycol and low-carbon alcohol etc. into is realized by the coupling of catalytic coal gasifaction technology and coal-based energy chemical product poly-generation technology, and renewable energy source is introduced in coal poly-generation production process, integrate Coal Gasification Technology, novel coal-based energy multi-connection product technology, compound energy hydrogen manufacturing oxygen technology, algae bio suction carbon technique and generation technology etc.
In technique scheme, a kind of catalyzed and gasified coal-based energy chemical product polygenerations systeme and method, is characterized in that it catalytic gasification comprising coal and coal-based energy product Poly-generation two technical process.
The catalysis gasification technique of coal is, with boiler, water is heated to be steam, then after steam heater, pass into catalytic gasification fluidized-bed gasification furnace.Coal is pulverized in pulverizer and coal pulverizer, then by the aqueous solution of catalyzer and coal dust hybrid infusion, the coal dust drying device prepared laggard enter fluidized-bed gasification furnace, 600 DEG C-700 DEG C, under 3-4MPa, coal by reaction water steam and hydrogen and carbon monoxide cycle gas mixture gasification in the flowing that suspends.Circulation gas is preheating to about 800 DEG C, then vapourizing furnace reactant gases out first enters water wash column washing through gas-solid separator, interchanger, sour gas adopts industrial conventional technology to be sloughed, utilize the method for low-temperature distillation to be separated from carbon monoxide and hydrogen by product methane, and carbon monoxide and hydrogen recirculation enter vapourizing furnace.
In technique scheme, the main flow that described catalytic coal gasifaction technology and coal-based energy multi-connection produce technology composition is that leading with gasification, the raw gas obtained, by the desulfurization of purified synthesis gas workshop section and decarburization, obtains being rich in H 2, CO and CH 4smart synthetic gas.Essence synthetic gas is by allocating appropriate H into 2regulate hydrogen-carbon ratio with Reactive Synthesis methyl alcohol, methane, ethylene glycol, low-carbon alcohol and/or dme or their arbitrary combination.Wherein smart synthetic gas also separable methane rear portion direct methanation prepare methane, another part directly sends into Poly-generation workshop section synthesizing methanol, methyl alcohol further producing dimethyl ether by dehydrating again.The steam produced in Poly-generation process can be used for steam-electric power.
In technique scheme, described coal is connected with vapourizing furnace by feed system with catalyzer, is connected after source of water vapor is overheated with vapourizing furnace, and vapourizing furnace outlet connects purification system and lime-ash bin.In gasification reacting furnace, coal, catalyzer and steam reaction generate gas mixture, and comprise methane, carbon monoxide, hydrogen and carbonic acid gas etc., lime-ash enters in lime-ash bin.Be stored in catalyst storage tank after catalyst recovery in lime-ash.
In technique scheme, purified gas can be separated into methane and synthetic gas, and synthetic gas can return gasification reacting furnace.
In technique scheme, described coal-based energy multi-connection produces technology, and primary target product is methane, methyl alcohol and/or dme.Methane and dme are clean energy product, and methyl alcohol is then one of important basic organic chemical industry raw material, therefore their coproduction, and competitive edge is fairly obvious.Pass through Poly-generation technology, not only can reach the efficiency utilization of the energy, less energy-consumption, Low investment and low operating cost and minimum Life cycle pollutant emission, and product proportion can be adjusted neatly as required, realize optimum economic benefit and social benefit.
In technique scheme, described introduces renewable energy source and renewable resources in coal poly-generation production process, on the one hand by introducing in the production process of coal derived energy chemical by biomass energy, sun power, utilization is joined Hydrochemistry solid carbon and the CO in gasification is all converted into derived energy chemical product thus avoids or reduce CO 2generation; The CO produced in production process on the other hand 2algae bio is provided to inhale raw material required for carbon technique, one or more in hydrogen partial required in production biofuel, oxygen, methane and production process or ethanol; Algae residue and generation waste water are used for bioelectrochemistry hydrogen manufacturing; Electric energy required for last whole production process is by renewable energy power generation, nuclear power and valley electricities such as solar energy power generating, wind power generation, water power, tidal power generation, geothermal power generations, or the steam-electric power promoted for waste heat recovery in coal poly-generation production process provides, also can be that the arbitrary combination of above-mentioned electric power provides, required hydrogen and oxygen be obtained by compound energy hydrogen manufacturing oxygen technology.
Described utilization is joined CO that gasification produces by the solid carbon of Hydrochemistry and is all converted into derived energy chemical product and refers to and make the hydrogen in the synthetic gas of synthesizing methanol, methane, dme, ethylene glycol and/or low-carbon alcohol and CO (also can comprise CO by joining hydrogen 2, such as, in methanation reaction, CO and CO 2methane can be produced with hydrogen reaction) ratio be adjusted to theoretical proportions higher than occurring needed for building-up reactions, then by controlling appropriate recycle ratio, make the CO in synthetic gas (also can comprise CO 2) all convert corresponding derived energy chemical product to.
In technique scheme, described compound energy hydrogen manufacturing oxygen technology, its energy mode preferably adopts wind-solar hybrid power station to power, and this power station comprises power generation system, inversion distribution grid-connected system and data monitoring system three part.
In technique scheme, hydrogen required in production process by the preparation of one or more hydrogen producing technology compounds, can include but not limited to that one or more combinations in water electrolysis to produce hydrogen and oxygen technology, bio-hydrogen production technology, bioelectrochemistry hydrogen producing technology or photoelectrocatalysis hydrogen producing technology provide.
Described bioelectrochemistry hydrogen producing technology is to contain organic waste water for raw material, using close anode microorganism as the hydrogen production process of anode catalyst.In this process, organism generates electronics and proton under microbial process, and electronics transfers to anode by external circuit, and proton transfers to negative electrode by the aqueous solution, and under faint external voltage, proton accepts electronics and generates hydrogen.Organism in the waste water of algae residue and generation can be removed by bioelectrochemistry hydrogen producing technology, and the hydrogen produced is fed back to synthesizing section.
In technique scheme, described water electrolysis to produce hydrogen and oxygen technology, its water electrolysis mode adopts solid polymer electrolyte (the SolidPolymer Electrolyte that environmental friendliness, gas purity are high, electrolytic efficiency is high, SPE or Proton Exchange Membrane, PEM) electrolyzer system, also can adopt traditional alkaline electrolysis tank systems, solid oxide electrolyte electrolyzer system can also be adopted.
In technique scheme, described bio-hydrogen production technology, includes but not limited to it is take biomass as the prepared using ermal physics principles of chemistry and technology hydrogen making and utilize bio-metabolic process that organic matter or water are converted into hydrogen.The latter includes but not limited to photosynthetic organism direct hydrogen production and biomass ferment hydrogen manufacturing.
In technique scheme, described photoelectrocatalysis hydrogen producing technology, includes but not limited to the hydrogen manufacturing of solar energy electrochemical process and solar energy and semiconductor light-catalyzed reaction hydrogen manufacturing.
In technique scheme, the hydrogen that described compound energy hydrogen manufacturing oxygen technology produces can connect catalytic gasification Reaktionsofen, also can connect Poly-generation reaction unit, and the oxygen of generation is collected and stored for export trade.In chemical poly-generation of coal-based energy production module methyl alcohol, methane, dme, ethylene glycol and/or low-carbon alcohol etc. building-up reactions in the adjustment of hydrogen-carbon ratio can not be regulated by water gas shift reaction, but carry out hydrogen supply to reach the hydrogen-carbon ratio needed for reaction by above-mentioned hydrogen manufacturing mode.
In technique scheme, described algae bio inhales carbon technique, it is characterized in that algae utilizes photosynthesis to absorb the CO produced in coal-based Energy production process 2, release oxygen, then extract biofuel by biological refinement technique, algae residue produces one or more in methane, hydrogen or ethanol through biological fermentation simultaneously; Hydrogen feeds back to synthesizing section, forms circulation technology.
In technique scheme, inhale with algae bio the reactor that the algae systems in carbon technique is connected and include but not limited to tripping device, Poly-generation reaction unit.
In technique scheme, the catalysis gasification technique employing of described coal is gasified, convert and the conjunction three of methanation is one.
Due to the utilization of such scheme, the present invention compared with prior art has following advantage:
(1) CO 2near zero release.Inhale carbon technique by algae bio on the one hand, catch, absorb CO 2, on the other hand by joining Hydrochemistry carbon-fixation-technology, CO all being changed into energy product, thus realizes CO 2near zero release.
(2) optimum use of resource.Coal is converted into the derived energy chemical product that the added values such as methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme are high; By compound energy hydrogen manufacturing oxygen technology, save Kong Fen workshop section, the facility investment of part boiler and water-gas shift workshop section and working cost and the traditional electric energy needed for whole system; Utilize biological refinement technique to obtain biofuel, carbon resource comprehensive utilization ratio can reach more than 80%.
(3) the cleaning and high efficiency of coal-based Energy production and power generation process.It is one that catalytic coal gasifaction methane achieves gasification, conversion and the conjunction three of methanation reaction, has that cost is low, the simple advantage of technique compared with traditional coal process for producing natural.
Accompanying drawing explanation
Fig. 1 is the coal-based energy chemical product poly-generation technique general line based on catalytic coal gasifaction.
Fig. 2 is that catalyzed and gasified coal-based energy chemical product polygenerations systeme is always shown in detail figure.
Fig. 3 is that Poly-generation produces methane, methyl alcohol and/or dme operational path.
Fig. 4 is Poly-generation methanol, ethylene glycol and/or low-carbon alcohol operational path.
Fig. 5 is the production process route of embodiment five to ten five.
Wherein, Fig. 2 is Figure of abstract.
Embodiment
Below in conjunction with drawings and embodiments, the present invention will be further described in detail, the present invention includes but be not limited to these embodiments.Below be only preferred embodiment of the present invention, scope of the present invention can not be limited with this.Namely the equalization generally done according to the present patent application the scope of the claims changes and modifies, and all should still remain within the scope of the patent.
One of ordinary skill in the art will appreciate that the apparatus structure shown in accompanying drawing or embodiment is only schematic, presentation logic structure.Module wherein as separating component display may or may not be physically separate, and the parts as module display may be or may not be physical modules.
Embodiment one:
With reference to the operational path of Fig. 2, brown coal and catalyzer enter catalytic gasification stove in the form of dry powder after mixing, drying, water vapor is vaporized chemical, temperature 593 ~ 700 DEG C, pressure is 3 ~ 4MPa, under sylvite (content is 15%) catalyst action, in catalytic gasification stove, reaction generates crude synthesis gas, and main component is CH 4, H 2, CO, CO 2deng, crude synthesis gas goes out methane through purification separation, residue H 2and CO, and the hydrogen mixing of hydrogen generating system returns catalytic gasification Reaktionsofen continuation reaction through route 1.The lime-ash generated in vapourizing furnace enters in lime-ash bin, and catalyst recovery stores.Purification system isolates H 2s processes further and obtains sulphur, direct marketing.The isolated carbonic acid gas of synthetic gas of catalytic gasification reaction is sent into algae bio and is inhaled carbon system for the production of biofuel, and the oxygen of coproduction simultaneously, oxygen stores.Algae residue fermentation ethanol, methane and hydrogen, hydrogen returns synthesizing section.The waste water produced in algae residue after fermentation and system also can be used for bioelectrochemistry hydrogen manufacturing, and hydrogen returns synthesizing section, forms circulation technology.
Embodiment two:
With reference to the operational path of Fig. 2, the form of brown coal and catalyzer dry powder after mixing, drying enters catalytic gasification stove, take water vapor as vaporized chemical, temperature 593 ~ 700 DEG C, pressure is 3 ~ 4MPa, under sylvite (content is 15%) catalyst action, in catalytic gasification stove, reaction generates crude synthesis gas, and main component is CH 4, H 2, CO, CO 2deng, the synthetic gas of crude synthesis gas after purification separation methane (mainly comprises H 2, CO), the hydrogen mixing of a part and hydrogen generating system can be passed through route 1 and returns catalytic gasification Reaktionsofen continuation reaction, and another part can be passed through route 2 and sends into Poly-generation synthesizing section for the preparation of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme etc.After methanation reaction, the high-quality water of by-product returns catalytic gasification workshop section.The isolated carbonic acid gas of synthetic gas of catalytic gasification reaction is sent into algae bio and is inhaled carbon system for the production of biofuel, and the oxygen of coproduction simultaneously, oxygen directly discharges or stores export trade.
Embodiment three:
With reference to the operational path of Fig. 2 and Fig. 3, the synthetic gas of crude synthesis gas after purification separation methane (the mainly H that catalytic coal gasifaction is produced 2and CO) and the hydrogen of hydrogen generating system and algae bio inhale the byproduct hydrogen mixing of carbon system, send into Poly-generation synthesizing section through route 2, a part of direct methanation prepares methane, and byproduct water returns catalytic gasification workshop section; Another part synthesizing methanol, a part for the methyl alcohol of production is for the production of dme, and another part can direct marketing.Methanol purge gas mixes with synthetic gas, synthesizing methane.The carbonic acid gas generated is sent into algae bio and is inhaled carbon system production biofuel, the oxygen of coproduction simultaneously.Algae residue is for one or more in fermentative production byproduct hydrogen, methane or ethanol; Byproduct hydrogen returns synthesizing section.The waste water produced in algae residue after fermentation and system also can be used for bioelectrochemistry hydrogen manufacturing.
Embodiment four:
With reference to the operational path of Fig. 2 and Fig. 3, the synthetic gas of crude synthesis gas after purification separation methane (the mainly H that catalytic coal gasifaction is produced 2and CO) and the hydrogen of hydrogen generating system and algae bio inhale the byproduct hydrogen mixing of carbon system, mix through route 2 and send into Poly-generation synthesizing section, part direct methanation prepares methane, byproduct water returns catalytic gasification workshop section, and in reaction process, liberated heat produces steam for generating after reclaiming; Another part synthesizing methanol, a part for the methyl alcohol of production is for the production of dme, and another part can direct marketing.The tower top off-gas of methanol-fueled CLC, a part can be joined hydrogen and be returned methanation workshop section synthesizing methane, and another part can be directly used in steam-electric power.Synthetic gas also can produce methane, ethylene glycol and/or low-carbon alcohol according to the operational path of Fig. 4.Synthetic gas produces ethylene glycol and/or low-carbon alcohol respectively by joining hydrogen, and the off-gas that ethylene glycol and/or low-carbon alcohol produce and synthetic gas mixing, then produce methane by joining hydrogen.The off-gas that another part ethylene glycol and/or low-carbon alcohol produce can be directly used in steam-electric power.The carbonic acid gas generated is sent into algae bio and is inhaled carbon system production biofuel, the oxygen of coproduction simultaneously.The residue of algae is for one or more in fermentative production byproduct hydrogen, methane or ethanol; Byproduct hydrogen returns synthesizing section.The waste water produced in algae residue after fermentation and system also can be used for bioelectrochemistry hydrogen manufacturing.
Embodiment five:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the Euglena absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Euglena is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment six:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the green alga absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Green alga is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment seven:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the stonewort absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Stonewort is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment eight:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the chrysophyceae absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Chrysophyceae is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment nine:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the dinoflagellate absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Dinoflagellate is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment ten:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the red algae absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Red algae is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 11:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the brown alga absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Brown alga is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 12:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the blue-green algae absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Blue-green algae is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 13:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the diatom absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Diatom is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 14:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the chlamydomonas absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Chlamydomonas is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 15:
In system, isolated carbon dioxide, removes solid particulate after filtration, and be collected into by air pump lead-in light bio-reactor after gas reservoir, the breather be connected with bioreactor can choose nozzle-type, aeration hair style or other all kinds.Under certain temperature range (10 ~ 40 DEG C), intensity of illumination (300 ~ 40000LUX), the xanthophyta absorbing carbon dioxide cultivated in bioreactor, carry out photosynthesis, under visible light illumination, be glucose by carbon dioxide transitions, and then be converted into the nutritive substances such as protein, fat, VITAMIN, discharge a large amount of oxygen simultaneously.Xanthophyta is converted into biomass through cultivation, and biomass are through biological refinement technique production biofuel.
Embodiment 16:
With reference to the operational path of Fig. 2, the energy source needed for compound energy hydrogen manufacturing oxygen, in wind light mutual complementing power generation station, mates valley electricity simultaneously, adopts solid polymer electrolyte electrolytic bath water electrolysis system to carry out water electrolysis.Water electrolysis produce oxygen store can supply export trade, electrolysis produce hydrogen be then transported to gasify and Poly-generation workshop section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, direct marketing after the methane processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation workshop section for the production of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The carbonic acid gas that synthetic gas goes out after being separated is sent into algae bio and is inhaled carbon system for the production of biofuel.
Embodiment 17:
With reference to the operational path of Fig. 2, the energy source needed for compound energy hydrogen manufacturing oxygen, in wind light mutual complementing power generation station, mates valley electricity simultaneously, adopts means of solid oxide electrolytic cell water electrolysis system to carry out water electrolysis.Water electrolysis produce oxygen store can supply export trade, electrolysis produce hydrogen be then transported to gasify and Poly-generation workshop section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, direct marketing after the methane processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation workshop section for the production of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The carbonic acid gas that synthetic gas goes out after being separated is sent into algae bio and is inhaled carbon system for the production of biofuel.
Embodiment 18:
With reference to the operational path of Fig. 2, the energy source needed for compound energy hydrogen manufacturing oxygen, in wind light mutual complementing power generation station, mates valley electricity simultaneously, adopts alkaline electrolytic bath water electrolysis system to carry out water electrolysis.Water electrolysis produce oxygen store can supply export trade, electrolysis produce hydrogen be then transported to gasify and Poly-generation workshop section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, direct marketing after the methane processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation workshop section for the production of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The carbonic acid gas that synthetic gas goes out after being separated is sent into algae bio and is inhaled carbon system for the production of biofuel.
Embodiment 19:
With reference to the operational path of Fig. 2, compound energy hydrogen manufacturing oxygen module adopts bio-hydrogen production technology, and the hydrogen of generation is then transported to the different sites of synthesizing section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, methane direct marketing after processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation operation for the preparation of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The isolated carbonic acid gas of synthetic gas is sent into algae bio and is inhaled carbon system for the production of biofuel.
Embodiment 20:
With reference to the operational path of Fig. 2, compound energy hydrogen manufacturing oxygen module adopts bioelectrochemistry hydrogen producing technology, and the hydrogen of generation is then transported to the different sites of synthesizing section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, methane direct marketing after processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation operation for the preparation of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The isolated carbonic acid gas of synthetic gas is sent into algae bio and is inhaled carbon system for the production of biofuel.
Embodiment 21:
With reference to the operational path of Fig. 2, compound energy hydrogen manufacturing oxygen module adopts photoelectrocatalysis hydrogen producing technology, and the hydrogen of generation is then transported to the different sites of synthesizing section for joining hydrogen.Synthetic gas after part vapourizing furnace purification separation methane is joined hydrogen route via 1 and is returned catalytic gasification Reaktionsofen continuation reaction, methane direct marketing after processing of separation.Another part synthetic gas also can be passed through route 2 and sends into coal poly-generation operation for the preparation of methane, methyl alcohol, ethylene glycol, low-carbon alcohol and/or dme after joining hydrogen.The isolated carbonic acid gas of synthetic gas is sent into algae bio and is inhaled carbon system for the production of biofuel.

Claims (33)

1. a catalyzed and gasified coal-based energy chemical product Poly-generation method, comprising: the coupling of catalytic coal gasifaction technology and coal-based energy chemical product poly-generation technology;
Catalytic coal gasifaction comprises: catalytic coal gasifaction stove and purification system;
In catalytic gasification Reaktionsofen, add the dry powder raw material of coal and catalyzer, pass into water vapor, be obtained by reacting gas mixture and lime-ash, lime-ash enters in lime-ash bin, and further separating catalyst stores;
Wherein, the described dry powder raw material adding coal and catalyzer in catalytic gasification Reaktionsofen, passes into water vapor, is obtained by reacting gas mixture step and comprises:
With boiler, water is heated to be steam,
Catalytic gasification fluidized-bed gasification furnace is passed into after steam heater,
Coal is pulverized in pulverizer and coal pulverizer,
By the aqueous solution of catalyzer and coal dust hybrid infusion,
The coal dust drying device prepared laggard enter fluidized-bed gasification furnace, 600 DEG C-700 DEG C, under 3-4MPa, coal by reaction water steam and hydrogen and carbon monoxide cycle gas mixture gasification in the flowing that suspends;
Isolate methane after gas mixture purification, residual gas returns catalytic gasification Reaktionsofen or enters Poly-generation workshop section;
Or one or more in multi-production process synthesizing methane, low-carbon alcohol or dme of gas mixture purified gas;
The steam produced in Poly-generation process is for steam-electric power;
The carbon monoxide that catalytic coal gasifaction purification system is separated and hydrogen recirculation enter vapourizing furnace or enter Poly-generation workshop section.
2. method according to claim 1, is characterized in that, coal is connected with vapourizing furnace with catalyzer, and source of water vapor is connected with vapourizing furnace, and vapourizing furnace outlet connects purification system and lime-ash bin.
3. method according to claim 2, is characterized in that, the catalytic coal gasifaction catalyzer in lime-ash bin can reclaim, and is stored in catalyst storage tank.
4. method according to claim 3, is characterized in that, Poly-generation realizes one or more the coproduction in methane, low-carbon alcohol, dme or generating.
5. method according to claim 4, it is characterized in that, the raw gas that catalytic coal gasifaction obtains obtains smart synthetic gas by purified synthesis gas, and smart synthetic gas regulates hydrogen-carbon ratio with Reactive Synthesis methane, low-carbon alcohol and/or dme or their arbitrary combination by allocating appropriate H2 into; Or smart synthetic gas separation of methane rear portion direct methanation prepares methane, and another part directly sends into Poly-generation workshop section synthesizing methanol, and methyl alcohol produces dme more further, and the byproduct water after methanation reaction returns catalytic gasification workshop section.
6. a catalyzed and gasified coal-based energy chemical product Poly-generation method, comprising: catalytic coal gasifaction technology, coal-based energy chemical product poly-generation technology and algae bio inhale the coupling of carbon technique;
Catalytic coal gasifaction comprises: catalytic coal gasifaction stove and purification system;
In catalytic gasification Reaktionsofen, add the dry powder raw material of coal and catalyzer, pass into water vapor, be obtained by reacting gas mixture and lime-ash; Lime-ash enters in lime-ash bin, and further separating catalyst stores;
Wherein, the described dry powder raw material adding coal and catalyzer in catalytic gasification Reaktionsofen, passes into water vapor, is obtained by reacting gas mixture step and comprises:
With boiler, water is heated to be steam,
Catalytic gasification fluidized-bed gasification furnace is passed into after steam heater,
Coal is pulverized in pulverizer and coal pulverizer,
By the aqueous solution of catalyzer and coal dust hybrid infusion,
The coal dust drying device prepared laggard enter fluidized-bed gasification furnace, 600 DEG C-700 DEG C, under 3-4MPa, coal by reaction water steam and hydrogen and carbon monoxide cycle gas mixture gasification in the flowing that suspends;
Mixed gas separation obtains methane storing, and residue synthetic gas turns back to catalytic gasification reaction workshop section or enters Poly-generation workshop section;
Or one or more in multi-production process synthesizing methane, low-carbon alcohol or dme of gas mixture purified gas;
The steam produced in Poly-generation process is for steam-electric power;
The carbonic acid gas that catalytic gasification and/or Poly-generation process produce is converted into one or more in biofuel, oxygen, methane, hydrogen or ethanol by algae bio suction carbon;
The carbon monoxide that catalytic coal gasifaction purification system is separated and hydrogen recirculation enter vapourizing furnace or enter Poly-generation workshop section.
7. method according to claim 6, is characterized in that, Poly-generation realizes one or more the coproduction in methane, low-carbon alcohol, dme or generating.
8. method according to claim 7, it is characterized in that, the raw gas that catalytic coal gasifaction obtains obtains smart synthetic gas by purified synthesis gas, and smart synthetic gas regulates hydrogen-carbon ratio with Reactive Synthesis methane, low-carbon alcohol and/or dme or their arbitrary combination by allocating appropriate H2 into; Or smart synthetic gas separation of methane rear portion direct methanation prepares methane, and another part directly sends into Poly-generation workshop section synthesizing methanol, and methyl alcohol produces dme more further, and the byproduct water after methanation reaction returns catalytic gasification workshop section.
9. method according to claim 8, is characterized in that, algae bio inhales the carbonic acid gas that carbon technique is used for absorption system generation.
10. method according to claim 9, is characterized in that, algae bio is inhaled carbon technique and generated biofuel and/or oxygen.
11. methods according to claim 10, is characterized in that, the algae residue after algae bio inhales carbon produces one or more in methane, hydrogen or ethanol through biological fermentation; The waste water produced in algae residue after fermentation and system is for bioelectrochemistry hydrogen manufacturing.
12. methods according to claim 11, is characterized in that, the hydrogen that algae bio produces after inhaling carbon feeds back to synthesizing section, form circulation technology.
13. methods according to claim 12, is characterized in that, algae bio is inhaled carbon and adopted Euglena, green alga, stonewort, chrysophyceae, dinoflagellate, red algae, diatom, chlamydomonas, xanthophyta, brown alga or blue-green algae.
14. 1 kinds of catalyzed and gasified coal-based energy chemical product Poly-generation methods, comprising: the coupling of catalytic coal gasifaction technology, coal-based energy chemical product poly-generation technology and compound energy hydrogen manufacturing oxygen technology;
Catalytic coal gasifaction comprises: catalytic coal gasifaction stove and purification system;
In catalytic gasification Reaktionsofen, add the dry powder raw material of coal and catalyzer, pass into water vapor, be obtained by reacting gas mixture and lime-ash; Lime-ash enters in lime-ash bin, and further separating catalyst stores;
Wherein, the described dry powder raw material adding coal and catalyzer in catalytic gasification Reaktionsofen, passes into water vapor, is obtained by reacting gas mixture step and comprises:
With boiler, water is heated to be steam,
Catalytic gasification fluidized-bed gasification furnace is passed into after steam heater,
Coal is pulverized in pulverizer and coal pulverizer,
By the aqueous solution of catalyzer and coal dust hybrid infusion,
The coal dust drying device prepared laggard enter fluidized-bed gasification furnace, 600 DEG C-700 DEG C, under 3-4MPa, coal by reaction water steam and hydrogen and carbon monoxide cycle gas mixture gasification in the flowing that suspends;
Mixed gas separation obtains methane storing, and residue synthetic gas turns back to catalytic gasification reaction workshop section or enters Poly-generation workshop section;
Or one or more in multi-production process synthesizing methane, low-carbon alcohol or dme of gas mixture purified gas;
The steam produced in Poly-generation process is for steam-electric power;
The hydrogen needed for catalytic gasification and/or Poly-generation is provided by compound energy hydrogen manufacturing oxygen technology;
The carbon monoxide that catalytic coal gasifaction purification system is separated and hydrogen recirculation enter vapourizing furnace or enter Poly-generation workshop section.
15. methods according to claim 14, is characterized in that, Poly-generation realizes one or more the coproduction in methane, low-carbon alcohol, dme or generating.
16. methods according to claim 15, it is characterized in that, the raw gas that catalytic coal gasifaction obtains obtains smart synthetic gas by purified synthesis gas, and smart synthetic gas regulates hydrogen-carbon ratio with Reactive Synthesis methane, low-carbon alcohol and/or dme or their arbitrary combination by allocating appropriate H2 into; Or smart synthetic gas separation of methane rear portion direct methanation prepares methane, and another part directly sends into Poly-generation workshop section synthesizing methanol, and methyl alcohol produces dme more further, and the byproduct water after methanation reaction returns catalytic gasification workshop section.
17. methods according to claim 16, is characterized in that, compound energy hydrogen manufacturing oxygen technology comprises one or more combinations in water electrolysis hydrogen producing technology, bio-hydrogen production technology, bioelectrochemistry hydrogen producing technology, PhotoelectrochemicalSystem System for Hydrogen Production technology.
18. methods according to claim 17, it is characterized in that, energy required in compound energy hydrogen manufacturing oxygen module adopts steam-electric power that in sun power, wind energy, water energy, Geothermal energy, tidal energy, nuclear power, valley electricity, coal poly-generation production process, waste heat recovery promotes or using off-gas wherein as one or more in fuel gas generation or common electric energy.
19. methods according to claim 18, is characterized in that, the hydrogen that compound energy hydrogen manufacturing oxygen produces connects catalytic gasification Reaktionsofen and/or connects Poly-generation reaction unit, and the oxygen of generation stores.
20. methods according to claim 19, it is characterized in that, in chemical poly-generation of coal-based energy production module methane, dme and/or low-carbon alcohol building-up reactions in the adjustment of hydrogen-carbon ratio by compound energy hydrogen manufacturing oxygen module hydrogen supply to reach the hydrogen-carbon ratio needed for reaction.
21. 1 kinds of catalyzed and gasified coal-based energy chemical product Poly-generation methods, comprising: catalytic coal gasifaction technology, coal-based energy chemical product poly-generation technology, algae bio inhale the coupling of carbon technique and compound energy hydrogen manufacturing oxygen technology;
Catalytic coal gasifaction comprises: catalytic coal gasifaction stove and purification system;
In catalytic gasification Reaktionsofen, add the dry powder raw material of coal and catalyzer, pass into water vapor, be obtained by reacting gas mixture and lime-ash; Lime-ash enters in lime-ash bin, and further separating catalyst stores;
Wherein, the described dry powder raw material adding coal and catalyzer in catalytic gasification Reaktionsofen, passes into water vapor, is obtained by reacting gas mixture step and comprises:
With boiler, water is heated to be steam,
Catalytic gasification fluidized-bed gasification furnace is passed into after steam heater,
Coal is pulverized in pulverizer and coal pulverizer,
By the aqueous solution of catalyzer and coal dust hybrid infusion,
The coal dust drying device prepared laggard enter fluidized-bed gasification furnace, 600 DEG C-700 DEG C, under 3-4MPa, coal by reaction water steam and hydrogen and carbon monoxide cycle gas mixture gasification in the flowing that suspends;
Mixed gas separation obtains methane storing, and residue synthetic gas turns back to catalytic gasification reaction workshop section or enters Poly-generation workshop section;
Or one or more in multi-production process synthesizing methane, low-carbon alcohol or dme of gas mixture purified gas;
The steam produced in Poly-generation process is for steam-electric power;
The carbonic acid gas that catalytic gasification and/or Poly-generation process produce is converted into one or more in biofuel, oxygen, methane, hydrogen or ethanol by algae bio suction carbon;
The hydrogen needed for catalytic gasification and/or Poly-generation is provided by compound energy hydrogen manufacturing oxygen technology.
22. methods according to claim 21, is characterized in that, the carbon monoxide that catalytic coal gasifaction purification system is separated and hydrogen recirculation enter vapourizing furnace or enters Poly-generation workshop section.
23., according to any one method described in claim 21 ~ 22, is characterized in that, Poly-generation realizes one or more the coproduction in methane, low-carbon alcohol, dme or generating.
24. methods according to claim 22, it is characterized in that, the raw gas that catalytic coal gasifaction obtains obtains smart synthetic gas by purified synthesis gas, and smart synthetic gas regulates hydrogen-carbon ratio with Reactive Synthesis methane, low-carbon alcohol and/or dme or their arbitrary combination by allocating appropriate H2 into; Or smart synthetic gas separation of methane rear portion direct methanation prepares methane, and another part directly sends into Poly-generation workshop section synthesizing methanol, and methyl alcohol produces dme more further, and the byproduct water after methanation reaction returns catalytic gasification workshop section.
25. methods according to claim 24, is characterized in that, algae bio inhales the carbonic acid gas that carbon technique is used for absorption system generation.
26. methods according to claim 25, is characterized in that, algae bio is inhaled carbon technique and generated biofuel and/or oxygen.
27. methods according to claim 26, is characterized in that, the algae residue after algae bio inhales carbon produces one or more in methane, hydrogen or ethanol through biological fermentation; The waste water produced in algae residue after fermentation and system is for bioelectrochemistry hydrogen manufacturing.
28. methods according to claim 27, is characterized in that, the hydrogen that algae bio produces after inhaling carbon feeds back to synthesizing section, form circulation technology.
29. methods according to claim 28, is characterized in that, algae bio is inhaled carbon and adopted Euglena, green alga, stonewort, chrysophyceae, dinoflagellate, red algae, diatom, chlamydomonas, xanthophyta, brown alga or blue-green algae.
30. methods according to claim 29, is characterized in that, compound energy hydrogen manufacturing oxygen technology comprises one or more combinations in water electrolysis hydrogen producing technology, bio-hydrogen production technology, bioelectrochemistry hydrogen producing technology, PhotoelectrochemicalSystem System for Hydrogen Production technology.
31. methods according to claim 30, it is characterized in that, energy required in composite hydrogen manufacturing oxygen module adopts steam-electric power that in sun power, wind energy, water energy, Geothermal energy, tidal energy, nuclear power, valley electricity, coal poly-generation production process, waste heat recovery promotes or using off-gas wherein as one or more in fuel gas generation or common electric energy.
32. methods according to claim 31, is characterized in that, the hydrogen that compound energy hydrogen manufacturing oxygen module produces connects catalytic gasification Reaktionsofen and/or connects Poly-generation reaction unit, and the oxygen of generation stores.
33. methods according to claim 32, it is characterized in that, in chemical poly-generation of coal-based energy production module methane, dme and/or low-carbon alcohol building-up reactions in the adjustment of hydrogen-carbon ratio by compound energy hydrogen manufacturing module hydrogen supply to reach the hydrogen-carbon ratio needed for reaction.
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