CN101596816A - Multicolor laser electric aluminum and production technology thereof - Google Patents

Multicolor laser electric aluminum and production technology thereof Download PDF

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Publication number
CN101596816A
CN101596816A CNA2008100585166A CN200810058516A CN101596816A CN 101596816 A CN101596816 A CN 101596816A CN A2008100585166 A CNA2008100585166 A CN A2008100585166A CN 200810058516 A CN200810058516 A CN 200810058516A CN 101596816 A CN101596816 A CN 101596816A
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color lump
chromatograph
coated
color
coating
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CNA2008100585166A
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Chinese (zh)
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CN101596816B (en
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陶荣光
雷鸣
周继东
洪加非
陈立新
高洪建
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陈立新
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Abstract

Multicolor laser electric aluminum and production technology thereof, the structure of multicolor laser electric aluminum is: be coated with release layer at the BOPET film surface, be coated with chromatograph on the release layer, chromatograph is made up of the color lump of a plurality of different colours, not miscible mutually on the contact-making surface of each color lump, printing, mold pressing have the pattern of band laser effect on the chromatograph, vacuum plating on chromatograph, and coated heat shifts glue-line on the aluminium lamination.Color lump consists predominantly of resin, colorant, solvent and stabilizing agent.Its production technology comprises: (1) is coated with release layer on the BOPET film; (2) chromatograph of printing bag different colours color lump on release layer; (3) use the laser molding plate, mold pressing chromatograph surface; (4) vacuum aluminum-coated; (5) coating glue-line.Do not produce misciblely among the present invention between different color lump, a thermoprint can be finished the transfer of a plurality of color color lumps, has saved the subsequent production operation, has improved production efficiency, has improved the yield rate of product.

Description

Multicolor laser electric aluminum and production technology thereof

Technical field

The invention belongs to radium-shine laser electrification aluminium printed apcksging material production technical field, relate to the laser multicolor laser electric aluminum new product and the production new technique thereof that have many colors color lump on a kind of radium-shine laser electrification aluminium chromatograph.

Background technology

Laser electrification aluminium is a kind of important packaging material in the printing packaging industry, and its surface has the mobile cangiante lustre of metal-like, and is printed with and has anti-fraud functional pattern, extensively applies in the external packing of various products.At present, on the laser electrification aluminium produce market, has only monochromatic product.Known one-wavelength laser laser electrochemical aluminum product, its structure is: on biaxially oriented polyester film (BOPET film) surface, be coated with one deck release layer, release layer plays the reduction basement membrane and peels off tension force, make the effect of whole electrochemical aluminium chromatograph sur-face peeling uniform tension in order, be coated with the chromatograph of one deck monochrome on release layer, the chromatograph patrix is pressed with the rainbow pattern of band laser effect, vacuum plating has the layer of metal aluminium lamination on the chromatograph surface, is coated with one deck heat on the aluminium lamination and shifts glue-line.

Release layer of the prior art mainly is made up of water wax and OP wax; Chromatograph is formed by resin, colorant and solvent, and the resin in the chromatograph mainly is made up of high temperature resistant laser molding resin, and colorant mainly is made of the organic metal toner, organic metal toner color difference, the color relation difference of the chromatograph of formation; Solvent mainly is ketone, the ester class organic solvent that dissolving resin and colorant are used.

In the known technology, the manufacture technology of monochromatic electrochemical aluminium comprises following step:

(1) be coated with release layer on the BOPET film: adopt Biaxially-oriented polyethylene film (BOPET film) to be basement membrane, blended wax layer (release layer) coating of one deck macromolecule water wax and OP wax being formed with coating machine (printing) uniformly is at film surface.

(2) coating chromatograph: after high temperature resistant laser molding resin and monochromatic organic metal toner mixed,, form monochromatic chromatograph material with ketone, ester class organic solvent dissolution, with coating machine or printing machine with its coating and printing on release layer.

(3) mold pressing: on moulding press, use the mode of laser pressing plate, mold pressing chromatograph surface is compressed on radium-shine laser effect on the basement membrane.

(4) vacuum aluminum-coated: the good laser basement membrane of mold pressing be put into carry out in the vacuum aluminum-coated machine vacuum aluminum-coated, plating one deck aluminium lamination on chromatograph.

(5) coating glue-line: glue-line is shifted with coating machine or intaglio press coating and printing one deck heat in the surface at aluminium coated.

Monochromatic laser electrochemical aluminum product is transferred to package material surface by gilding press in uniform temperature and following laser pattern thermoprint of pressure in use, peels off the BOPET film with special-purpose stripping machine afterwards.Package material surface after the transfer has mobile rainbow pattern, and metallic luster and third dimension are strong.With the laser electrochemical aluminum that the mold pressing of special edition pattern is produced, after shifting thermoprint, the special edition pattern has very high antifalse effect.

Development along with printing technology, for the packaging pattern color that makes product more, antifalse effect is better, adopt monochromatic laser electrochemical aluminum gradation alignment thermoprint technology in the printing industry, in monochromatic electrochemical aluminium gradation thermoprint to the package design pattern with different colours, form the laser electrochemical aluminum multicolour pattern of polychrome piece, increase the attractive in appearance and antifalse effect of packing.

Existing laser electrochemical aluminum gradation alignment thermoprint technical matters, essential repeated thermoprint through monochromatic laser electrochemical aluminum, could on same packaging material, produce the multicolor laser electric aluminum pattern effect of polychrome piece, in this production technology, color lump of every thermoprint will repeat the thermoprint operation one time, reuse the laser electrochemical aluminum of another kind of color, and carries out the alignment of pattern colour piece, cause the repeatedly repetition of thermoprint operation, greatly reduce production efficiency; In the production process of same product, use the monochromatic laser electrochemical aluminum of multiple color to strive time thermoprint, cause laser electrochemical aluminum accumulation consumption excessive, leftover bits are many, and the raw materials for production waste is big; The laser electrochemical aluminum of a kind of color of every replacing in the production process will carry out the pattern alignment one time, and production efficiency is low, percent defective is high, unstable product quality.

Technology contents

For solving problems of the prior art, the invention provides a kind of multicolor laser electric aluminum new product and production new technique thereof, the technical scheme of its product structure is:

Multicolor laser electric aluminum, surface at biaxially oriented polyester film (BOPET film) is coated with one deck release layer, on release layer, be coated with one deck chromatograph, chromatograph is made up of the color lump of a plurality of different colours, not miscible mutually on the contact-making surface of separate between each color lump, color lump, printing, mold pressing have the pattern of band laser effect on chromatograph, and vacuum plating has the layer of metal aluminium lamination on chromatograph, are coated with one deck heat on the aluminium lamination and shift glue-line.

Release layer mainly is made up of water wax and OP wax; Chromatograph is made up of the color lump of different colours, color lump consists predominantly of resin, colorant, solvent and stabilizing agent, color lump is evenly mixed by each composition, resin in the chromatograph mainly is made up of high temperature resistant laser molding resin, colorant mainly is made of the organic metal toner, organic metal toner color difference, the color relation difference of the chromatograph of formation; Solvent mainly is ketone, the ester class mixed organic solvents that dissolving resin and colorant are used; Be added with stabilizing agent in each color lump respectively, stabilizing agent mainly comprises polyether modified siloxane compound, poly dimethyl silicone composites, amino containing silane compound, polyethylene and organic mixed solvent composition.Stabilizing agent plays the performance of stablizing color lump, and when the color lump that prevents different colours was in contact with one another, contact-making surface produced miscible phenomenon.

It is that (relation by weight ratio) is: high temperature resistant laser molding resin 46-66 part, colorant 2-8 part, solvent (ketone or ester class) 30-38 part, stabilizing agent 2-8 part that the high temperature resistant laser molding resin, colorant, solvent and the stabilizing agent composition that mainly comprise in the color lump, shared mass percent close.

The weight proportion relation of each composition that mainly comprises in the stabilizing agent (calculating by weight) is: polyether modified siloxane compound 3-8 part, poly dimethyl silicone composites 5-10 part, amino containing silane compound 6-10 part, polyethylene 1-5 part, organic mixed solvent 67-85 part, organic mixed solvent mainly are ketone or ester class mixed solvent.

Above-mentioned multicolor laser electric aluminum, its production new technique comprises following step:

(1) on the BOPET film, be coated with release layer: adopt Biaxially-oriented polyethylene film (BOPET film) to be basement membrane, with coating machine or printing machine with one deck macromolecule water wax and OP wax layer (release layer) uniformly coating and printing in membrane surface.

(2) coating chromatograph: the color lump that includes different colours in the chromatograph, color lump is no less than two, the color lump of different colours, print on the BOPET basement membrane with coating machine or printing machine gradation coating and printing or cover, the contact-making surface of each color lump is immiscible, promptly on the BOPET basement membrane, dry after the color lump coating and printing of a color or the chromatography, and then the color lump of coating and printing or the next different colours of chromatography, the contact-making surface of each color lump is not miscible, and the coating and printing of color lump is by being carried out to the order of light color by dark color.Chromatography can be carried out with intaglio press.

(3) mold pressing: on moulding press, use the mode of laser pressing plate, mold pressing chromatograph surface is compressed on radium-shine laser effect on the basement membrane.Pressing mold carries out at twice, carries out a low temperature mold pressing earlier, and then carries out hot press moulding one time.

Molding temperature when carrying out the low temperature mold pressing is controlled at: 150 ℃ to 190 ℃, machine speed is controlled at: 30 meters/minute to 50 meters/minute, when adopting the moulding press of air pressure control, pressure is controlled at: 2 kilograms to 5 kilograms, pressure is controlled at when adopting the moulding press of hydraulic control: 8 kilograms to 12 kilograms; The moulding press temperature is controlled at when carrying out hot press moulding: 190 ℃ to 240 ℃, machine speed is controlled at: 50 meters/minute to 90 meters/minute, when adopting the moulding press of air pressure control, pressure is controlled at: 5 kilograms to 8 kilograms, pressure is controlled at when adopting the moulding press of hydraulic control: 12 kilograms to 28 kilograms.

(4) vacuum aluminum-coated: the good laser basement membrane of mold pressing be put into carry out in the vacuum aluminum-coated machine vacuum aluminum-coated, plating one deck aluminium lamination on chromatograph.

(5) coating glue-line: glue-line is shifted with coating machine or intaglio press coating and printing one deck heat in the surface at aluminium coated.

Because the adding of stabilizing agent, make the color lump Stability Analysis of Structures of different colours, it is miscible to be difficult for production, prints through the gradation oven dry of different color blocks again, the different color blocks color is miscible mutually in the time of effectively preventing to print, and guarantees that burr, contact-making surface do not flow flower at the printed patterns edge; Owing to carry out twice mold pressing, guaranteed that the laser pattern of mold pressing on the different color blocks is even, become clear.

The multicolor laser electric aluminum product that adopts above-mentioned technology to produce, when the packaging material that apply to produce with radium-shine rainbow pattern, only need once shift thermoprint, the laser pattern of a plurality of color color lumps of comprising on the laser electrochemical aluminum can be transferred to package material surface simultaneously, having changed needs to carry out repeatedly the monochromatic production status that repeats thermoprint in the prior art, save printing enterprise greatly and produced the laser electrochemical aluminum consumption of radium-shine packing, saved production process, improved production efficiency, improved the yield rate of product.

Embodiment

Embodiment one: multicolor laser electric aluminum, surface at biaxially oriented polyester film (BOPET film) is coated with one deck release layer, on release layer, be coated with one deck chromatograph, chromatograph is made up of the color lump of silver color, gold, red three different colours, not miscible mutually on the contact-making surface of separate between each color lump, color lump, printing, mold pressing have the pattern of band laser effect on chromatograph, and vacuum plating has the layer of metal aluminium lamination on chromatograph, are coated with one deck heat on the aluminium lamination and shift glue-line.

Release layer mainly is made up of water wax and OP wax; The color lump of chromatograph consists predominantly of resin, colorant, solvent and stabilizing agent, color lump is evenly mixed by each composition, resin in the color lump mainly is made up of high temperature resistant laser molding resin, colorant mainly is made of the organic metal toner, organic metal toner color difference, the color relation difference of the chromatograph that constitutes, used toner is respectively silver color, gold, red toner in this example, solvent mainly is ketone or the ester class organic solvent that dissolving resin and colorant are used.

The shared mass percent (relation by weight ratio) of each composition that comprises in each color lump is: 46 parts of high temperature resistant laser molding resins, 8 parts in colorant, 38 parts of solvents (ketone or ester class), 8 parts of stabilizing agents.Colorant is respectively silver color, gold, red colorant.

The weight proportion relation of each composition that comprises in the stabilizing agent (calculating by weight) is: 3 parts of polyether modified siloxane compounds, 5 parts of poly dimethyl silicone composites, 6 parts of amino containing silane compounds, 1 part of polyethylene, 85 parts of organic mixed solvents, organic mixed solvent mainly is ketone or esters solvent.

Embodiment two: multicolor laser electric aluminum, technical scheme and embodiment one are described basic identical, with the difference of embodiment one are: the chromatograph on the release layer is made up of golden, red two color lumps.

The shared mass percent (relation by weight ratio) of each composition is in the color lump: 66 parts of high temperature resistant laser molding resins, 2 parts in colorant, 30 parts of solvents (ketone or ester class), 2 parts of stabilizing agents.Colorant is respectively golden, red.

The weight proportion relation of each composition in the stabilizing agent (calculating by weight) is: 8 parts of polyether modified siloxane compounds, 10 parts of poly dimethyl silicone composites, 10 parts of amino containing silane compounds, 5 parts of polyethylene, 35 parts of organic mixed solvents, organic mixed solvent mainly is ketone or esters solvent.

Embodiment three: a kind of multicolor laser electric aluminum production technology comprises following step:

(1) on the BOPET film, be coated with release layer: adopt Biaxially-oriented polyethylene film (BOPET film) to be basement membrane, with coating machine or printing machine with one deck macromolecule water wax and OP wax layer (release layer) uniformly coating and printing in membrane surface.

(2) coating chromatograph: the color lump that includes silver color, gold and red three different colours in the chromatograph, the color lump of different colours, print on the BOPET basement membrane with coating machine or printing machine gradation coating and printing or cover, the contact-making surface of each color lump is immiscible, promptly on the BOPET basement membrane, dry after the color lump coating and printing of a color or the chromatography, and then the color lump of coating and printing or the next different colours of chromatography, the contact-making surface of each color lump is not miscible, the coating and printing of color lump is pressed by the order of dark color to light color, promptly earlier seal carries out redness, bronze printing look again, last Yin Yinse.

(3) mold pressing: on moulding press, use the mode of laser pressing plate, mold pressing chromatograph surface is compressed on radium-shine laser effect on the basement membrane.Pressing mold carries out at twice, carries out a low temperature mold pressing earlier, and then carries out hot press moulding one time.

The molding temperature that carries out the low temperature moulding press is controlled at: 150 ℃, machine speed is controlled at: 30 meters/minute, and the moulding press that adopts air pressure to control, pressure is controlled at: 2 kilograms; The moulding press temperature is controlled at when carrying out hot press moulding: 190 ℃, machine speed is controlled at: 50 meters/minute, and the moulding press that adopts air pressure to control, pressure is controlled at: 5 kilograms.

(4) vacuum aluminum-coated: the good laser basement membrane of mold pressing be put into carry out in the vacuum aluminum-coated machine vacuum aluminum-coated, plating one deck aluminium lamination on chromatograph.

(5) coating glue-line: glue-line is shifted with coating machine or intaglio press coating and printing one deck heat in the surface at aluminium coated.

Embodiment four: a kind of multicolor laser electric aluminum production technology, technical scheme and embodiment three are described basic identical, with the difference of embodiment three are: form color lump and comprise black and gold.The molding temperature that carries out the low temperature moulding press is controlled at: 190 ℃, machine speed is controlled at: 50 meters part clocks, and the moulding press that adopts air pressure to control, pressure is controlled at 5 kilograms; The moulding press temperature is controlled at when carrying out hot press moulding: 240 ℃, machine speed is controlled at: 90 meters/minute, and the moulding press that adopts air pressure to control, pressure is controlled at: 8 kilograms.

Embodiment five: a kind of multicolor laser electric aluminum production technology, technical scheme and embodiment three are described basic identical, with the difference of embodiment three be: color lump has red and two kinds of blue looks, the moulding press of employing hydraulic control when carrying out the low temperature mold pressing, and pressure is controlled at: 8 kilograms; When carrying out hot press moulding, adopt the moulding press of hydraulic control, pressure is controlled at: 12 kilograms.

Embodiment six: a kind of multicolor laser electric aluminum production technology, technical scheme and embodiment four are described basic identical, with the difference of embodiment four be: color lump has silver color and two kinds of gold, adopts the moulding press of hydraulic control when carrying out the low temperature moulding press, and pressure is controlled at: 12 kilograms; Adopt the moulding press of hydraulic control when carrying out hot press moulding, pressure is controlled at: 28 kilograms.

Claims (7)

1, multicolor laser electric aluminum, surface at biaxially oriented polyester film (BOPET film) is coated with one deck release layer, release layer mainly is made up of water wax and OP wax, on release layer, be coated with one deck chromatograph, include resin in the chromatograph, colorant and solvent, on chromatograph, print, mold pressing has the pattern of band laser effect, vacuum plating has the layer of metal aluminium lamination on chromatograph, be coated with one deck heat on the aluminium lamination and shift glue-line, it is characterized in that: chromatograph is made of the color lump of different colours, the color lump of different colours has and is no less than two in the chromatograph, and is separate between the color lump, promptly not miscible mutually on the contact-making surface of color lump.
2, multicolor laser electric aluminum as claimed in claim 1, it is characterized in that: the color lump in the chromatograph includes resin, colorant and solvent, resin mainly is made up of high temperature resistant laser molding resin, colorant mainly is made up of the organic metal toner, and solvent mainly is ketone or the ester class organic solvent that dissolving resin and colorant are used; Color lump is evenly mixed by its composition; Be added with stabilizing agent in each color lump; The different color lump colors that constitute of the color of colorant are also different; The shared mass percent (relation by weight ratio) of each composition that comprises in the color lump is: high temperature resistant laser molding resin 46-66 part, colorant 2-8 part, solvent (ketone or ester class) 30-38 part, stabilizing agent 2-8 part.
3, multicolor laser electric aluminum as claimed in claim 2, it is characterized in that: be added with stabilizing agent in each color lump respectively, stabilizing agent mainly comprises polyether modified siloxane compound, poly dimethyl silicone composites, amino containing silane compound, polyethylene and organic mixed solvent.
4, multicolor laser electric aluminum as claimed in claim 3, it is characterized in that: the weight proportion relation of each composition that comprises in the stabilizing agent (calculating by weight) is: polyether modified siloxane compound 3-8 part, poly dimethyl silicone composites 5-10 part, amino containing silane compound 6-10 part, polyethylene 1-5 part, organic mixed solvent 67-85 part, organic mixed solvent mainly are ketone or ester class mixed solvent.
5, a kind of production technology of multicolor laser electric aluminum comprises following step:
(1) on the BOPET film, be coated with release layer: adopt Biaxially-oriented polyethylene film (BOPET film) to be basement membrane, with coating machine or printing machine with one deck macromolecule water wax and OP wax layer (release layer) uniformly coating and printing in membrane surface.
(2) coating chromatograph: with coating machine or printing machine with the chromatograph coating and printing on release layer.
(3) mold pressing: on moulding press, use the mode of laser pressing plate, mold pressing chromatograph surface is compressed on radium-shine laser effect on the basement membrane.
(4) vacuum aluminum-coated: the good laser basement membrane of mold pressing be put into carry out in the vacuum aluminum-coated machine vacuum aluminum-coated.
(5) coating glue-line: glue-line is shifted with coating machine or intaglio press coating and printing one deck heat in the surface at aluminium coated.
It is characterized in that: in above-mentioned (2) step, include the color lump of different colours in the chromatograph, color lump is no less than two; The color lump of different colours, print on the BOPET basement membrane with coating machine or printing machine gradation coating and printing or cover, the contact-making surface of each color lump is immiscible, promptly on the BOPET basement membrane, dry after the color lump coating and printing of a color or the chromatography, and then the color lump of coating and printing or the next different colours of chromatography, the contact-making surface of each color lump is not miscible, and the coating and printing of color lump is by being carried out to the order of light color by dark color.
6, multicolor laser electric aluminum production technology as claimed in claim 5 is characterized in that: in (3) step, pressing mold carries out at twice, carries out a low temperature mold pressing earlier, and then carries out hot press moulding one time.
7, multicolor laser electric aluminum production technology as claimed in claim 6, it is characterized in that: the molding temperature when carrying out the low temperature mold pressing is controlled at: 150 ℃ to 190 ℃, machine speed is controlled at: 30 meters/minute to 50 meters/minute, when adopting the moulding press mold pressing of air pressure control, pressure is controlled at: 2 kilograms to 5 kilograms, pressure is controlled at when adopting the moulding press mold pressing of hydraulic control: 8 kilograms to 12 kilograms; The moulding press temperature is controlled at when carrying out hot press moulding: 190 ℃ to 240 ℃, machine speed is controlled at: 50 meters/minute to 90 meters/minute, when adopting the moulding press mold pressing of air pressure control, pressure is controlled at: 5 kilograms to 8 kilograms, pressure is controlled at when adopting the moulding press mold pressing of hydraulic control: 12 kilograms to 28 kilograms.
CN2008100585166A 2008-06-05 2008-06-05 Multicolor laser electric aluminum and production technology thereof CN101596816B (en)

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CN103770492A (en) * 2014-01-14 2014-05-07 汕头市龙湖昌丰化工有限公司 Method for manufacturing transfer film and transfer aluminum-plating paper
CN104002574A (en) * 2014-05-20 2014-08-27 青岛嘉泽包装有限公司 Efficient and energy-saving hot stamping method for cigarette splicing paper
CN105346296A (en) * 2015-12-04 2016-02-24 张家港保税区康得菲尔实业有限公司 Multicolor pre-coating film
CN105346296B (en) * 2015-12-04 2018-01-09 张家港保税区康得菲尔实业有限公司 A kind of polychrome pre-coating film
CN105647255A (en) * 2016-01-26 2016-06-08 扬州市祥华新材料科技有限公司 Laser alumite color layer coating and preparation method thereof
CN105647255B (en) * 2016-01-26 2018-07-17 扬州市祥华新材料科技有限公司 A kind of laser electrochemical aluminum chromatograph coating and preparation method thereof
CN107253409A (en) * 2017-06-22 2017-10-17 安徽集友新材料股份有限公司 Anodized aluminium
CN109532132A (en) * 2018-12-18 2019-03-29 东莞光群雷射科技有限公司 One kind can scrape electrochemical aluminized coating and its preparation method and application

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