CN101595867B - Emamectin benzoate indoxacarb suspending agent and preparation method thereof - Google Patents
Emamectin benzoate indoxacarb suspending agent and preparation method thereof Download PDFInfo
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- CN101595867B CN101595867B CN 200810038677 CN200810038677A CN101595867B CN 101595867 B CN101595867 B CN 101595867B CN 200810038677 CN200810038677 CN 200810038677 CN 200810038677 A CN200810038677 A CN 200810038677A CN 101595867 B CN101595867 B CN 101595867B
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- 239000000375 suspending agent Substances 0.000 title claims abstract description 31
- 239000005907 Indoxacarb Substances 0.000 title claims abstract description 20
- VBCVPMMZEGZULK-NRFANRHFSA-N indoxacarb Chemical compound C([C@@]1(OC2)C(=O)OC)C3=CC(Cl)=CC=C3C1=NN2C(=O)N(C(=O)OC)C1=CC=C(OC(F)(F)F)C=C1 VBCVPMMZEGZULK-NRFANRHFSA-N 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- 239000000080 wetting agent Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 claims description 20
- 150000002469 indenes Chemical class 0.000 claims description 19
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000012071 phase Substances 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 14
- 230000002528 anti-freeze Effects 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 8
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 8
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 8
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 239000008346 aqueous phase Substances 0.000 claims description 5
- 239000003814 drug Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000003020 moisturizing effect Effects 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 239000002917 insecticide Substances 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 210000002784 stomach Anatomy 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 241000258937 Hemiptera Species 0.000 abstract description 2
- 241000255777 Lepidoptera Species 0.000 abstract description 2
- 206010033799 Paralysis Diseases 0.000 abstract description 2
- 206010034133 Pathogen resistance Diseases 0.000 abstract description 2
- 108010052164 Sodium Channels Proteins 0.000 abstract description 2
- 102000018674 Sodium Channels Human genes 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 210000002569 neuron Anatomy 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 241000238876 Acari Species 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000007798 antifreeze agent Substances 0.000 abstract 1
- 230000004071 biological effect Effects 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 abstract 1
- 235000013399 edible fruits Nutrition 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000011017 operating method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 150000005063 oxadiazines Chemical class 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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Abstract
The invention relates to an emamectin benzoate indoxacarb suspending agent and a preparation method thereof. The suspending agent is characterized by comprising the following components in percentage by weight: 0.5-1.5 percent of emamectin benzoate, 2-10 percent of indoxacarb, 2-8 percent of emulsifier, 1-5 percent of dispersant, 0.1-1 percent of anti-sludging agent, 2-10 percent of antifreeze agent, 0.5-2 percent of antioxidant, 0.5-2 percent of wetting agent, 1-3 percent of defoaming agent, 5-10 percent of solvent, and the balance of water. Compared with the prior art, the suspending agent has the advantages of having the effects of contact killing and stomach toxicity, blocking sodium channels in nerve cells of pests so as to ensure that target pests have poor harmony and paralysis and die finally, having no cross resistance with other insecticides, having higher biological activity to various lepidoptera and homoptera pests and mites, preventing various pests on crops of cereals, cottons, fruits, vegetables, and the like.
Description
Technical field
The present invention relates to agriculture chemical compounding agent and preparation method thereof, especially relate to a kind of by semisynthetic antibiotics insecticide emamectin-benzoate and the composite a kind of agriculture chemical compounding agent that forms of oxadiazines insecticides indenes worm prestige and preparation method thereof.
Background technology
Under the influence of world today's " mankind will get along amiably and peacefully with the Nature " ideological trend; human sense of self-protection, living standard improve day by day; various countries have put into effect increasing pact, rules improve environment for human survival and food quality, and the development of chemical pesticide has been subjected to increasing restriction.And the environmental protection factor has become many countries and has limited a kind of means that his home made article enters domestic markets in international trade, the international market is more and more higher to the requirement of agricultural chemicals, this certainly will increase the research and development expense and the production cost of China's exported product, has also restricted the outlet of China's portioned product simultaneously.
Along with the increasing of pesticide producing to China's environment build-up of pressure, country has strengthened the discharging management to pollutant in the production process.State Environmental Protection Administration has worked out " insecticide pollution discharge standard ", and clearly regulation has been made in the discharging of agricultural chemicals enterprise 10 pollutants.National Development and Reform Committee also spells out, and in order to reduce environmental pollution and to preserve the ecological environment, should progressively substitute existing conventional dosage forms with the particularly water base chemical preparation of environmental protection novel form, is the trend of current pesticidal preparations development.
Therefore, China's agricultural chemicals enterprise more selections on product of still needing that want to get through the close siege.At present, environment-protection pesticide is just meeting rare opportunity to develop, compares with chemical pesticide, and environment-protection pesticide has following advantage: (1) is easily degraded in environment, is lacked residual or noresidue people, animal, beneficial organism low toxicity, does not have environmental issue; (2) replace organic solvent as main carrier with water, do not have the danger of catching fire, no unpleasant toxic odor, little to eye irritation, reduced pollution to environment, improved safety greatly to production, storing and user; (3) have good heat storage stability, cold cut stability and water dilution stability; (4) farming is originally low, and with respect to chemical pesticide, profit space is bigger; (5) energy savings.
In sum, face period of problems, exploitation and produce environment-protection pesticide bigger realistic meaning has just been arranged at current China chemical pesticide.
Summary of the invention
Purpose of the present invention be exactly provide in order to overcome the defective that above-mentioned prior art exists a kind of have tag, first dimension salt indoxacarb suspending agent of stomach poison function and preparation method thereof.
Purpose of the present invention can be achieved through the following technical solutions: a kind of first dimension salt indoxacarb suspending agent is characterized in that this suspension emulsion comprises following component and weight percentage:
Emamectin-benzoate 0.5%～1.5%,
Indenes worm prestige 2%～10%,
Emulsifier 2%～8%,
Dispersant 1%～5%,
Antiprecipitant 0.1～1%,
Antifreeze 2%～10%,
Antioxidant 0.5%～2%,
Wetting agent 0.5%～2%,
Defoamer 1%～3%,
Solvent 5%～10%,
Moisturizing to 100%.
Described emulsifier is the EO-PO block copolymer.
Described dispersant is the polyoxyethylene ether phosphate.
Described antiprecipitant is an xanthans.
Described antifreeze is an ethylene glycol.
Described antioxidant is 2, the 6-BHT.
Described wetting agent is a polyoxyethylene nonylphenol ether.
Described defoamer is an organosilicon.
Described solvent comprises dimethylbenzene.
A kind of preparation method of first dimension salt indoxacarb suspending agent is characterized in that this method may further comprise the steps:
(1) by weight percentage the former medicine 2%～10% of indenes worm prestige, dispersant 1%～5%, wetting agent 0.5%～2% and water are mixed with indenes worm prestige suspending agent;
(2) make oil phase
By weight percentage emamectin-benzoate 0.5%～1.5%, antioxidant 0.5%～2% are added with solvent 5%～10% and be in the same place, be stirred to emamectin-benzoate and be dissolved in fully in the solvent, become even oil phase;
(3) make water
By weight percentage emulsifier 2%～8%, antifreeze 2%～10%, defoamer 1%～3% and water are added in and are mixed together dissolving fully, one-tenth homogeneous water;
(4) mix shearing
The above-mentioned oil phase for preparing is joined aqueous phase, and high speed shear adds the indenes worm prestige suspending agent of step (1) preparation again, shears, and adds percentage by weight at last and be 0.1～1% antiprecipitant, and shear-mixed is even, promptly get first and ties up the salt indoxacarb suspending agent.
Compared with prior art, the present invention is by semisynthetic antibiotics insecticide emamectin-benzoate and the composite a kind of agriculture chemical compounding agent that forms of oxadiazines insecticides indenes worm prestige and preparation method thereof, this composite dose have tag, stomach poison function, sodium channel in the blocking-up insect nerve cell, cause target pest inaccurate coordination, paralysis, final dead, there is not cross resistance with other insecticide, multiple Lepidoptera, homoptera pest and evil mite are had high biologically active, can effectively prevent and treat grain, cotton, really, the various pests on the crop such as vegetables.
Description of drawings
Fig. 1 is preparation method's of the present invention flow chart.
Embodiment
Below in conjunction with specific embodiment the present invention is specifically described in detail.
Embodiment 1
A kind of prescription of first dimension salt indoxacarb suspending agent is as follows: emamectin-benzoate 0.5%, indenes worm prestige 2%, solvent (dimethylbenzene) 5.0%, emulsifier (EO-PO block copolymer) 2%, dispersant (polyoxyethylene ether phosphate) 1%, wetting agent (polyoxyethylene nonylphenol ether) 0.5%, antifreeze (ethylene glycol) 2%, antioxidant (2, the 6-BHT) 0.5%, defoamer (organosilicon) 1%, antiprecipitant (xanthans) 0.1%, surplus are water.
Above-mentioned prescription is tieed up the salt indoxacarb suspending agent by following operating procedure preparation first:
A, the former medicine of indenes worm prestige, dispersant (polyoxyethylene ether phosphate), wetting agent (polyoxyethylene nonylphenol ether) and water are joined in the container by formula rate, constantly stir, make suspending agent;
B, making oil phase: by above-mentioned formula rate emamectin-benzoate is joined in the solvent (dimethylbenzene), stir, till emamectin-benzoate dissolves fully, standby as oil phase;
C, making water: by above-mentioned formula rate emulsifier (EO-PO block copolymer), antifreeze (ethylene glycol), defoamer (organosilicon) and water are joined in the container, open and be stirred to dissolving fully, become the homogeneous water to get final product;
D, mixing are sheared: the above-mentioned oil phase for preparing is joined aqueous phase, shear, add the indenes worm prestige suspending agent of above-mentioned steps a preparation again, shear.Add antiprecipitant (xanthans) at last, shear-mixed is even.Be the emamectin-benzoate indoxacarb suspending agent.
Embodiment 2
A kind of prescription of first dimension salt indoxacarb suspending agent is as follows: emamectin-benzoate 1%, indenes worm prestige 6%, solvent (dimethylbenzene) 8%, emulsifier (EO-PO block copolymer) 5%, dispersant (polyoxyethylene ether phosphate) 3%, wetting agent (polyoxyethylene nonylphenol ether) 1.2%, antifreeze (ethylene glycol) 6%, antioxidant (2, the 6-BHT) 1.2%, defoamer (organosilicon) 2%, antiprecipitant 0.5%, surplus are water.
Above-mentioned prescription is tieed up the salt indoxacarb suspending agent by following operating procedure preparation first:
A, the former medicine of indenes worm prestige, dispersant (polyoxyethylene ether phosphate), wetting agent (polyoxyethylene nonylphenol ether) and water are joined in the container by formula rate, constantly stir, make suspending agent;
B, making oil phase: by above-mentioned formula rate emamectin-benzoate is joined in the solvent (dimethylbenzene), stir, till emamectin-benzoate dissolves fully, standby as oil phase;
C, making water: by above-mentioned formula rate emulsifier (EO-PO block copolymer), antifreeze (ethylene glycol), defoamer (organosilicon) and water are joined in the container, open and be stirred to dissolving fully, become the homogeneous water to get final product;
D, mixing are sheared: the above-mentioned oil phase for preparing is joined aqueous phase, shear, add the indenes worm prestige suspending agent of above-mentioned steps a preparation again, shear.Add antiprecipitant (xanthans) at last, shear-mixed is even.Be the emamectin-benzoate indoxacarb suspending agent.
Embodiment 3
A kind of prescription of first dimension salt indoxacarb suspending agent is as follows: emamectin-benzoate 1.5%, indenes worm prestige 10%, solvent (dimethylbenzene) 10%, emulsifier (EO-PO block copolymer) 8%, dispersant (polyoxyethylene ether phosphate) 5%, wetting agent (polyoxyethylene nonylphenol ether) 2%, antifreeze (ethylene glycol) 10%, antioxidant (2, the 6-BHT) 2%, defoamer (organosilicon) 3%, antiprecipitant 1%, surplus are water.
Above-mentioned prescription is tieed up the salt indoxacarb suspending agent by following operating procedure preparation first:
A, the former medicine of indenes worm prestige, dispersant (polyoxyethylene ether phosphate), wetting agent (polyoxyethylene nonylphenol ether) and water are joined in the container by formula rate, constantly stir, make suspending agent;
B, making oil phase: by above-mentioned formula rate emamectin-benzoate is joined in the solvent (dimethylbenzene), stir, till emamectin-benzoate dissolves fully, standby as oil phase;
C, making water: by above-mentioned formula rate emulsifier (EO-PO block copolymer), antifreeze (ethylene glycol), defoamer (organosilicon) and water are joined in the container, open and be stirred to dissolving fully, become the homogeneous water to get final product;
D, mixing are sheared: the above-mentioned oil phase for preparing is joined aqueous phase, shear, add the indenes worm prestige suspending agent of above-mentioned steps a preparation again, shear.Add antiprecipitant (xanthans) at last, shear-mixed is even.Be the emamectin-benzoate indoxacarb suspending agent.
Claims (2)
1. a first is tieed up the salt indoxacarb suspending agent, it is characterized in that this suspension emulsion comprises following component and weight percentage:
Emamectin-benzoate 0.5%～1.5%,
Indenes worm prestige 2%～10%,
Emulsifier 2%～8%,
Dispersant 1%～5%,
Antiprecipitant 0.1～1%,
Antifreeze 2%～10%,
Antioxidant 0.5%～2%,
Wetting agent 0.5%～2%,
Defoamer 1%～3%,
Solvent 5%～10%,
Moisturizing to 100%;
Described emulsifier is the EO-PO block copolymer;
Described dispersant is the polyoxyethylene ether phosphate;
Described antiprecipitant is an xanthans;
Described antifreeze is an ethylene glycol;
Described antioxidant is 2,6-BHT;
Described wetting agent is a polyoxyethylene nonylphenol ether;
Described defoamer is an organosilicon;
Described solvent is a dimethylbenzene.
2. the preparation method of a first as claimed in claim 1 dimension salt indoxacarb suspending agent is characterized in that this method may further comprise the steps:
(1) by weight percentage the former medicine 2%～10% of indenes worm prestige, dispersant 1%～5%, wetting agent 0.5%～2% and water are mixed with indenes worm prestige suspending agent;
(2) make oil phase
By weight percentage emamectin-benzoate 0.5%～1.5%, antioxidant 0.5%～2% are added with solvent 5%～10% and be in the same place, be stirred to emamectin-benzoate and be dissolved in fully in the solvent, become even oil phase;
(3) make water
By weight percentage emulsifier 2%～8%, antifreeze 2%～10%, defoamer 1%～3% and water are added in and are mixed together dissolving fully, one-tenth homogeneous water;
(4) mix shearing
The above-mentioned oil phase for preparing is joined aqueous phase, and high speed shear adds the indenes worm prestige suspending agent of step (1) preparation again, shears, and adds percentage by weight at last and be 0.1～1% antiprecipitant, and shear-mixed is even, promptly get first and ties up the salt indoxacarb suspending agent.
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| CN 200810038677 CN101595867B (en) | 2008-06-06 | 2008-06-06 | Emamectin benzoate indoxacarb suspending agent and preparation method thereof |
Applications Claiming Priority (1)
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| CN 200810038677 CN101595867B (en) | 2008-06-06 | 2008-06-06 | Emamectin benzoate indoxacarb suspending agent and preparation method thereof |
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| CN101595867A CN101595867A (en) | 2009-12-09 |
| CN101595867B true CN101595867B (en) | 2013-07-31 |
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| CN105494402A (en) * | 2014-10-17 | 2016-04-20 | 中国农科院植保所廊坊农药中试厂 | Preparation method of indoxacarb-emamectin benzoate water emulsion formula |
| CN105475275A (en) * | 2016-01-20 | 2016-04-13 | 河北天发化工科技有限公司 | Emamectin benzoate and indoxacarb suspending agent and preparation method thereof |
| WO2019179309A1 (en) * | 2018-03-22 | 2019-09-26 | Jiangsu Rotam Chemistry Co., Ltd | Pesticidal compositions having emamectin benzoate and indoxacarb and methods for using such compositions |
| CN111053085B (en) * | 2019-11-20 | 2021-08-10 | 河北威远生物化工有限公司 | Emamectin benzoate B2a and indoxacarb suspoemulsion and preparation method thereof |
| CN114208840A (en) * | 2021-12-30 | 2022-03-22 | 江苏仁信作物保护技术有限公司 | Emamectin benzoate indoxacarb suspending agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1299596A (en) * | 2001-01-05 | 2001-06-20 | 深圳市诺普信农化有限公司 | Imidacloprid-chlorpyrifos pesticide composition |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1299596A (en) * | 2001-01-05 | 2001-06-20 | 深圳市诺普信农化有限公司 | Imidacloprid-chlorpyrifos pesticide composition |
Non-Patent Citations (2)
| Title |
|---|
| 刘步林等.第八章.《农药剂型加工技术》.1998,(第二版),344-350. * |
| 李丽芳等.悬乳剂及其稳定性.《农药》.2000,第39卷(第5期),14-16. * |
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Denomination of invention: Emamectin benzoate indoxacarb suspending agent and preparation method thereof Effective date of registration: 20190813 Granted publication date: 20130731 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS CO.,LTD. Registration number: Y2019310000006 |
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Denomination of invention: A kind of Emamectin and indoxacarb suspension emulsion and its preparation method Effective date of registration: 20201010 Granted publication date: 20130731 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2020310000044 |
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Denomination of invention: The invention relates to a methotrexate ninchongwei suspension emulsion and a preparation method thereof Effective date of registration: 20210930 Granted publication date: 20130731 Pledgee: Fengxian Branch of Shanghai Rural Commercial Bank Co.,Ltd. Pledgor: SHANGHAI NONG LE BIOLOGICAL PRODUCTS Co.,Ltd. Registration number: Y2021310000091 |
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