CN101531444B - Sewage recycling process for combination of biological rapid filtration and slow filtration - Google Patents
Sewage recycling process for combination of biological rapid filtration and slow filtration Download PDFInfo
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Abstract
本发明涉及一种生物快滤慢滤组合污水回用工艺,属于污水处理领域。包括生物快滤和慢滤步骤,进水依次进入生物快滤池和慢滤池,通过生物快滤和慢滤的组合,用以实现二级出水剩余有机物、氨氮、总氮、悬浮物、浊度、色度和臭味的去除。经过生物快滤和慢滤之后的污水,经消毒后成为合格的回用水,做为绿化或冲厕市政杂用水。本发明的生物快滤慢滤组合污水回用工艺通过将慢滤引入到污水回用工艺中,并与生物快滤组合,各取所长,从而成为一种经济高效的污水回用工艺。
The invention relates to a biological fast-filtration and slow-filtration combined sewage recycling process, which belongs to the field of sewage treatment. Including the biological fast filtration and slow filtration steps, the influent water enters the biological fast filter and the slow filter in sequence, and through the combination of the biological fast filtration and the slow filtration, it is used to realize the remaining organic matter, ammonia nitrogen, total nitrogen, suspended solids, turbidity in the secondary effluent. Removal of brightness, color and odor. The sewage after biological fast filtration and slow filtration becomes qualified reuse water after disinfection, which can be used as municipal water for greening or flushing toilets. The biological fast filtration and slow filtration combined sewage recycling process of the present invention introduces the slow filtration into the sewage recycling process and combines it with the biological fast filtration to take advantage of each, thereby becoming an economical and efficient sewage recycling process.
Description
技术领域technical field
本发明涉及一种生物快滤慢滤组合污水回用工艺,属于污水处理领域,是污水深度处理及回用的一种工艺。The invention relates to a bio-fast filtration and slow filtration combined sewage recycling process, which belongs to the field of sewage treatment and is a process for advanced treatment and reuse of sewage.
背景技术Background technique
我国是水资源匮乏的国家,同时水污染也非常严重。水危机至今未能得到有效遏制,并有进一步加剧的趋势。污水回用即开辟了新水源,又能减少污水排放量,可起到缓解水资源短缺和恢复良好水环境的双重目的,这已是国际水处理界和水资源界的共识。my country is a country that lacks water resources, and water pollution is also very serious. The water crisis has not been effectively curbed so far, and there is a tendency of further aggravation. Sewage reuse not only opens up new water sources, but also reduces sewage discharge, which can serve the dual purposes of alleviating water shortages and restoring a good water environment. This has become the consensus of the international water treatment and water resources circles.
污水再生后,可用于农田灌溉、工业冷却水补水,也可用作园林绿化、道路喷洒、冲厕、洗车等城镇杂用。依据回用用途的不同,回用水必须达到相应的水质标准。After the sewage is regenerated, it can be used for farmland irrigation, industrial cooling water replenishment, and can also be used for landscaping, road spraying, toilet flushing, car washing and other urban miscellaneous purposes. According to different reuse purposes, the reused water must meet the corresponding water quality standards.
当前,随着经济的持续发展和人民生活水平的不断提高,除了对回用水中传统的有机物、氨氮和浊度等指标要求外,人们对再生水的感观指标也提出了更高的要求。如当前普遍关注的再生水的臭味和颜色问题。At present, with the continuous development of the economy and the continuous improvement of people's living standards, in addition to the traditional indicators of organic matter, ammonia nitrogen and turbidity in recycled water, people have also put forward higher requirements for the sensory indicators of reclaimed water. Such as the odor and color of reclaimed water that are generally concerned at present.
当前传统的污水回用工艺是混凝沉淀(澄清)+过滤+消毒。该工艺投资和运行成本较低,对浊度和悬浮物有较好去除效果,但对有机物、氨氮等营养类物质去除效果有限,尤其是色度和臭味,几乎不能去除。The current traditional sewage reuse process is coagulation sedimentation (clarification) + filtration + disinfection. The process has low investment and operating costs, and has a good removal effect on turbidity and suspended solids, but has limited removal effects on organic matter, ammonia nitrogen and other nutrients, especially color and odor, which are almost impossible to remove.
为进一步提高水质,活性炭吸附、膜技术和臭氧等高级氧化技术被引入污水回用领域。这类工艺的突出优点是可去除部分水中微量有机物、嗅和色度,但也存在缺点。如一些高级氧化工艺不仅消耗化学物质和能量,还可能生成一些毒性更强的中间产物。膜法是极具前途的处理方法,但目前昂贵的价格及复杂的预处理及膜污染问题尚未解决。并且膜法产生的浓水必须进一步处理。吸附法(活性炭)的去除效率非常好,而且具有广谱性。吸附法的缺点是吸附剂的吸附容量有限,需要不断更换。另外饱和后的吸附剂需要进一步处理,否则极易造成二次污染。In order to further improve water quality, advanced oxidation technologies such as activated carbon adsorption, membrane technology and ozone have been introduced into the field of sewage reuse. The outstanding advantage of this type of process is that it can remove trace organic matter, odor and color in part of the water, but there are also disadvantages. For example, some advanced oxidation processes not only consume chemical substances and energy, but may also generate some more toxic intermediate products. Membrane method is a promising treatment method, but the problem of high price, complicated pretreatment and membrane fouling has not been solved yet. And the concentrated water produced by the membrane method must be further treated. The removal efficiency of the adsorption method (activated carbon) is very good and has a broad spectrum. The disadvantage of the adsorption method is that the adsorbent has a limited adsorption capacity and needs to be constantly replaced. In addition, the saturated adsorbent needs further treatment, otherwise it will easily cause secondary pollution.
综上,急需开发高效低耗的污水回用工艺。In summary, there is an urgent need to develop efficient and low-consumption wastewater reuse processes.
近年来曝气生物滤池等生物快滤工艺逐渐被应用到污水回用中。由于采用了大粒径滤料和较厚的滤床,污水厂二级出水可以不经过混凝沉淀直接进入曝气生物滤池。由于强化了生物作用,因此曝气生物滤池不仅能去除浊度,也能有效去除氨氮和常规有机物质。在污水回用领域,曝气生物滤池逐渐成了传统快滤池的替代品。国内很多新设计的再生水厂均采用了曝气生物滤池工艺。In recent years, biological rapid filtration processes such as biological aerated filter have been gradually applied to sewage reuse. Due to the use of large particle size filter material and thicker filter bed, the secondary effluent of the sewage plant can directly enter the biological aerated filter without coagulation and sedimentation. Due to the enhanced biological action, the biological aerated filter can not only remove turbidity, but also effectively remove ammonia nitrogen and conventional organic substances. In the field of sewage reuse, biological aerated filters have gradually become a substitute for traditional fast filters. Many newly designed reclaimed water plants in China have adopted the biological aerated filter process.
与传统工艺相比,曝气生物滤池虽然提高了再生水水质,并简化了再生水的生产流程,但对嗅和色度的去除效果有限。Compared with the traditional process, although the biological aerated filter improves the quality of reclaimed water and simplifies the production process of reclaimed water, it has limited removal effect on odor and color.
慢滤是一个古老的工艺,已有200多年历史。慢滤属于一种生物过滤方式,在运行良好的慢滤池表层会生成一层粘性膜(schmutzdecke)。大量细菌、真菌、藻类甚至微型动物等会在慢滤池内生长,并形成一个完整的生态系统。依靠这些微生物共同作用,慢滤对有机物具有良好的去除能力,能够较好地去除嗅和色度,同时对细菌和病毒的去除率可达到90%以上。Slow filtration is an ancient process with a history of more than 200 years. Slow filtration is a type of biological filtration in which a viscous film (schmutzdecke) is formed on the surface of a well-operated slow filter. A large number of bacteria, fungi, algae and even micro-animals will grow in the slow filter tank and form a complete ecosystem. Relying on the joint action of these microorganisms, slow filtration has a good ability to remove organic matter, and can better remove odor and color, and at the same time, the removal rate of bacteria and viruses can reach more than 90%.
由于具有占地面积大的缺点,慢滤工艺曾一度被冷落并被快滤取代。由于对有机物,特别是微量有机物以及细菌、病毒具有良好的去除能力,在水环境恶化的今天,慢滤又重新得到重视。慢滤工艺在当前欧洲的自来水厂得到广泛应用,被认为是去除水中微量物质的有效手段。一直以来,慢滤池也被用于污水的脱氮和深度处理。Due to the disadvantage of occupying a large area, the slow filtration process was once neglected and replaced by fast filtration. Because of its good ability to remove organic matter, especially trace organic matter, bacteria, and viruses, slow filtration has gained attention again in today's deteriorating water environment. The slow filtration process is widely used in current European waterworks and is considered to be an effective means of removing trace substances in water. For a long time, slow filters have also been used for denitrification and advanced treatment of sewage.
发明内容Contents of the invention
基于上述对国内外现有污水回用技术的现状分析,本发明提出一种新的回用工艺,特别是一种生物快滤慢滤组合污水回用工艺。本发明将慢滤引入到污水回用工艺中,并与生物快滤组合,各取所长,使其组合成为一种经济高效的污水回用工艺。Based on the analysis of the current status of the existing domestic and foreign sewage recycling technologies, the present invention proposes a new recycling process, especially a biological fast-filtration and slow-filtration combined sewage recycling process. The present invention introduces the slow filtration into the sewage recycling process, and combines it with the biological fast filtration, and takes advantage of each, so that the combination becomes an economical and efficient sewage recycling process.
本发明的技术方案如下:Technical scheme of the present invention is as follows:
本发明是一种生物快滤慢滤组合污水回用工艺,包括生物快滤和慢滤步骤,其特征在于:该工艺利用生物快滤和慢滤的组合,实现二级出水剩余有机物、氨氮、总氮、悬浮物、浊度、色度和臭味的去除,其具体步骤如下:首先,采用污水二级处理后的出水作为进水,进水直接进入生物快滤池,生物快滤池同时具有生物作用和物理过滤作用,用以去除污水二级处理出水中的有机物、氨氮和悬浮物;然后,生物快滤池的出水再次进入慢滤池,慢滤池依靠滤料表层的一层粘性膜的生物作用进一步去除生物快滤池出水中残余的有机物、氨氮、悬浮物和浊度物质,同时,利用慢滤池良好的生物过滤性能,去除水中的色度、臭味和细菌,达到提高出水水质的目的;最后经过生物快滤和慢滤之后的污水,经消毒后成为合格的回用水,做为绿化或冲厕市政杂用水。The present invention is a biological fast filtration and slow filtration combined sewage recycling process, including biological fast filtration and slow filtration steps. The specific steps for the removal of total nitrogen, suspended solids, turbidity, color and odor are as follows: First, the effluent after the secondary treatment of sewage is used as the influent, and the influent directly enters the biological fast filter, and the biological fast filter simultaneously With biological function and physical filtration, it is used to remove organic matter, ammonia nitrogen and suspended solids in the effluent of secondary sewage treatment; then, the effluent from the biological fast filter enters the slow filter again, and the slow filter relies on a layer of viscosity on the surface of the filter material The biological function of the membrane further removes the residual organic matter, ammonia nitrogen, suspended solids and turbidity substances in the effluent of the biological fast filter. The purpose of effluent water quality; the sewage after biological fast filtration and slow filtration, after disinfection, becomes qualified reuse water, which is used as municipal miscellaneous water for greening or flushing toilets.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:采用活性污泥法或生物膜法工艺进行污水二级处理,并视回用水的用途决定在污水二级处理中是否进行脱氮除磷。The described biological fast-filtration and slow-filtration combined sewage recycling process is characterized in that: the activated sludge process or the biofilm process is used for the secondary treatment of sewage, and it is determined whether the secondary treatment of sewage depends on the purpose of the reused water Carry out nitrogen and phosphorus removal.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:所述生物过滤步骤中的生物过滤池为强化了生物作用的普通快滤池,其中的生物作用依靠下列途径得以强化:根据原水水质情况,滤池底部增设曝气装置或进行预曝气,调整滤池反冲洗策略,减少反冲洗对滤料上生物膜的破坏作用,生物快滤池进水不投加消毒剂。Described a kind of biological rapid filtration and slow filtration combined sewage recycling process is characterized in that: the biological filter in the biological filtration step is a common fast filter with enhanced biological action, wherein the biological action is strengthened by the following means : According to the raw water quality, add an aeration device or pre-aeration at the bottom of the filter, adjust the backwash strategy of the filter to reduce the damage to the biofilm on the filter material by backwash, and do not add disinfectant to the incoming water of the biological fast filter .
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:依据滤料、滤床厚度和进水水质情况,生物快滤池的滤速控制在0.5~10m/h之间。Said biological fast filtration and slow filtration combined sewage recycling process is characterized in that: according to the filter material, the thickness of the filter bed and the water quality of the influent, the filtration rate of the biological fast filter is controlled between 0.5-10m/h.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:所述的生物快滤池为曝气生物滤池、生物活性滤池或好气滤池。The above-mentioned combined sewage reuse process of biological fast filtration and slow filtration is characterized in that: the biological fast filter is an aerated biological filter, a biologically active filter or an aerobic filter.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:所述慢滤池具有生物作用和过滤作用,慢滤池不需要反冲洗,但需要周期性刮砂。The biological fast filtration and slow filtration combined sewage recycling process is characterized in that: the slow filter has biological and filtering functions, and the slow filter does not need backwashing, but requires periodic sand scraping.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:依据进水水质情况,慢滤池的滤速控制在0.1~0.5m/h之间。The biological fast-filtration and slow-filtration combined sewage recycling process is characterized in that: according to the influent water quality, the filtration rate of the slow filter is controlled between 0.1-0.5m/h.
所述的一种生物快滤慢滤组合污水回用工艺,其特征在于:慢滤出水采用氯气、紫外线、二氧化氯或臭氧消毒方法进行消毒。The said biological fast filtration and slow filtration combined sewage recycling process is characterized in that: the slowly filtered water is sterilized by chlorine gas, ultraviolet rays, chlorine dioxide or ozone disinfection methods.
本发明的生物快滤慢滤组合污水回用工艺将生物快滤(曝气生物滤池)和慢滤结合起来,利用生物快滤来去除污水厂二级出水的浊度和悬浮物,并进一步去除水中的有机物和硝化氨氮。同时为后续的慢滤提供了优质进水,以减少和避免慢滤的堵塞。利用慢滤去除嗅和色度,并进一步去除快滤出水残留的有机物、氨氮、悬浮物和浊度等,以此提高再生水的感观和保障再生水的安全。同时慢滤对细菌和病毒良好的去除功效也能减轻后续的消毒负荷,提高消毒效果。The biological fast filtration and slow filtration combined sewage reuse process of the present invention combines the biological fast filtration (biological aerated filter) and the slow filtration, utilizes the biological fast filtration to remove the turbidity and suspended matter of the secondary effluent of the sewage plant, and further Remove organic matter and nitrated ammonia nitrogen from water. At the same time, high-quality water is provided for the subsequent slow filtration to reduce and avoid the clogging of the slow filtration. Use slow filtration to remove odor and color, and further remove residual organic matter, ammonia nitrogen, suspended solids and turbidity in the fast-filtered water, so as to improve the sensory perception of reclaimed water and ensure the safety of reclaimed water. At the same time, the good removal effect of slow filtration on bacteria and viruses can also reduce the subsequent disinfection load and improve the disinfection effect.
附图说明Description of drawings
图1是本发明生物快滤慢滤组合污水回用工艺的工艺流程图。Fig. 1 is a process flow diagram of the biological fast filtration and slow filtration combined sewage reuse process of the present invention.
具体实施方式Detailed ways
如图1所示,本发明的具体实施方式如下。As shown in Fig. 1, the specific embodiment of the present invention is as follows.
该生物快滤慢滤组合污水回用工艺包括生物快滤和慢滤步骤,该工艺利用生物快滤和慢滤的组合,实现二级出水剩余有机物、氨氮、总氮、悬浮物、浊度、色度和臭味的去除,其具体步骤如下:首先,采用污水二级处理后的出水作为进水,进水直接进入生物快滤池,生物快滤池同时具有生物作用和物理过滤作用,用以去除污水二级处理出水中的有机物、氨氮、悬浮物和浊度物质;然后,生物快滤池的出水再次进入慢滤池,慢滤池依靠滤料表层的一层粘性膜的生物作用进一步去除生物快滤池出水中残余的有机物、氨氮和悬浮物,同时,利用慢滤池良好的生物过滤性能,去除水中的色度、臭味和细菌,达到提高出水水质的目的;最后经过生物快滤和慢滤之后的污水,经消毒后成为合格的回用水,做为绿化或冲厕市政杂用水。The biological fast filtration and slow filtration combined sewage recycling process includes biological fast filtration and slow filtration steps. The specific steps for the removal of chromaticity and odor are as follows: First, the effluent after the secondary treatment of sewage is used as the influent, and the influent directly enters the biological fast filter. The biological fast filter has both biological and physical filtration functions. To remove organic matter, ammonia nitrogen, suspended solids and turbidity substances in the effluent of the secondary sewage treatment; then, the effluent of the biological fast filter enters the slow filter again, and the slow filter relies on the biological action of a layer of viscous film on the surface of the filter material to further Remove the residual organic matter, ammonia nitrogen and suspended solids in the effluent of the biological fast filter. At the same time, use the good biological filtration performance of the slow filter to remove the chroma, odor and bacteria in the water, so as to improve the water quality of the effluent; The sewage after filtration and slow filtration becomes qualified reuse water after disinfection, which can be used as municipal miscellaneous water for greening or flushing toilets.
其中,污水的二级处理可以采用活性污泥法、生物膜法等工艺。二级处理是否需要脱氮除磷取决于回用水的用途。Among them, the secondary treatment of sewage can adopt processes such as activated sludge method and biofilm method. Whether secondary treatment requires nitrogen and phosphorus removal depends on the use of reused water.
生物过滤步骤中的生物过滤池为强化了生物作用的普通快滤池,其中的生物作用依靠下列途径得以强化:根据原水水质情况,滤池底部增设曝气装置或进行预曝气,调整滤池反冲洗策略,减少反冲洗对滤料上生物膜的破坏作用,生物快滤池进水不投加氯等消毒剂。依据滤料、滤床厚度和进水水质情况,生物快滤池的滤速控制在0.5~10m/h之间。生物快滤池可以为曝气生物滤池、生物活性滤池或好气(好氧)滤池。The biological filter in the biological filtration step is an ordinary fast filter with enhanced biological action, and the biological action can be enhanced by the following ways: according to the raw water quality, add an aeration device or pre-aeration at the bottom of the filter, adjust the filter The backwashing strategy reduces the destructive effect of backwashing on the biofilm on the filter material, and does not add chlorine and other disinfectants to the incoming water of the biological fast filter. According to the filter material, the thickness of the filter bed and the quality of the influent water, the filtration rate of the biological fast filter is controlled between 0.5 and 10m/h. The biological fast filter can be an aerated biological filter, a biologically active filter or an aerobic (aerobic) filter.
上述生物快滤慢滤组合污水回用工艺中的慢滤池具有生物作用和过滤作用,慢滤池不需要反冲洗,但需要周期性刮砂。依据进水水质情况,慢滤池的滤速控制在0.1~0.5m/h之间。The slow filter in the above-mentioned combined sewage reuse process of biological fast filtration and slow filtration has biological function and filtering function, and the slow filter does not need backwashing, but requires periodic sand scraping. According to the influent water quality, the filtration rate of the slow filter is controlled between 0.1 and 0.5m/h.
慢滤池出水消毒后,即成为合格的回用水。本发明工艺不对消毒方法做限制。即慢滤出水后可以采用常规的氯气、紫外、二氧化氯、臭氧等消毒剂。消毒剂的投加量应通过试验确定。After the effluent of the slow filter is disinfected, it becomes qualified reuse water. The process of the present invention does not limit the disinfection method. That is, after the water is slowly filtered out, conventional chlorine, ultraviolet, chlorine dioxide, ozone and other disinfectants can be used. The dosage of disinfectant should be determined through experiments.
本发明的有益效果可以通过下述实验结果加以验证。The beneficial effects of the present invention can be verified by the following experimental results.
建立了一套快滤慢滤组合系统。分别利用两个DN100的有机玻璃管模拟生物快滤池和慢滤池。两个模拟滤池的主要参数见表1。A combined system of fast and slow filtration was established. Two DN100 plexiglass tubes were used to simulate the biological fast filter and the slow filter respectively. The main parameters of the two simulated filters are shown in Table 1.
表1生物快滤慢滤组合系统主要参数Table 1 Main parameters of biological fast filter and slow filter combined system
该组合工艺采用一套生活污水二级处理装置的出水作为进水。该生活污水主要来自一个居民小区。二级处理采用普通SBR工艺,没有考虑氮磷的去除。二级出水首先进入生物快滤池底部,然后以1m/h的滤速上向流经过滤床。为了给滤床内的微生物提供足够的氧气,在生物快滤池底部设一套曝气装置,气水比为3∶1。生物快滤池出水后下向流再进入慢滤池,以0.1m/h滤速经过慢滤后出水。The combined process uses the effluent of a set of domestic sewage secondary treatment device as the influent. The domestic sewage mainly comes from a residential area. The secondary treatment adopts ordinary SBR process, without considering the removal of nitrogen and phosphorus. The secondary effluent first enters the bottom of the biological rapid filter, and then flows upward through the filter bed at a filtration rate of 1m/h. In order to provide enough oxygen for the microorganisms in the filter bed, a set of aeration device is installed at the bottom of the biological fast filter, and the air-water ratio is 3:1. After the biological fast filter, the water flows downwards and then enters the slow filter, and the water is discharged after passing through the slow filter at a filtration rate of 0.1m/h.
组合系统采用了自然挂膜的启动方式,之后进入稳定运行期。表2是组合系统冬季水温较低(12℃-15℃)阶段的平均实验结果。由表2可以看出,生物快滤慢滤组合工艺对有机物(COD)、浊度有良好的去除效果。色度也有较好的去除。氨氮虽然有52%的去除率,但最终出水依然有10.2mg/L。这是因为二级处理中没有考虑氨氮的去除,二级出水中的氨氮就达到了20.3mg/L。另外一个原因是水温过低的缘故。组合工艺对细菌总数也有很好的去除效果,去除率达到61%。这可减少后续消毒负荷,降低消毒剂的投加量。另外,二级出水经过生物快滤慢滤组合工艺后,臭味也有相当程度的降低(因为臭味检测的主观性较强,表2没有给出数据)。The combined system adopts the start-up method of natural film formation, and then enters a stable operation period. Table 2 shows the average experimental results of the combined system in the winter water temperature period (12°C-15°C). It can be seen from Table 2 that the combination process of biological fast filtration and slow filtration has a good removal effect on organic matter (COD) and turbidity. There is also better removal of chroma. Although the removal rate of ammonia nitrogen is 52%, the final effluent still has 10.2mg/L. This is because the removal of ammonia nitrogen was not considered in the secondary treatment, and the ammonia nitrogen in the secondary effluent reached 20.3mg/L. Another reason is that the water temperature is too low. The combined process also has a good removal effect on the total number of bacteria, and the removal rate reaches 61%. This can reduce the subsequent disinfection load and reduce the dosage of disinfectant. In addition, after the secondary effluent was passed through the combination process of biological fast filtration and slow filtration, the odor was also reduced to a considerable extent (because the odor detection is highly subjective, no data is given in Table 2).
表2生物快滤慢滤组合工艺冬季对主要污染物的去除效果Table 2 The removal effect of biological fast filtration and slow filtration combined process on main pollutants in winter
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