CN101496991A - Upper straight-down rotating dry-type circulating fluidized bed desulfurization reactor - Google Patents
Upper straight-down rotating dry-type circulating fluidized bed desulfurization reactor Download PDFInfo
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- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 44
- 230000023556 desulfurization Effects 0.000 title claims abstract description 44
- 239000000779 smoke Substances 0.000 claims abstract description 15
- 230000002745 absorbent Effects 0.000 claims description 16
- 239000002250 absorbent Substances 0.000 claims description 16
- 239000013505 freshwater Substances 0.000 claims 4
- 239000002245 particle Substances 0.000 abstract description 13
- 238000012423 maintenance Methods 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 24
- 239000003546 flue gas Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
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Abstract
上直-下旋干式循环流化床脱硫反应器,它涉及一种循环流化床脱硫反应器。本发明解决了现有的脱硫反应器工作效率低、壁面易形成颗粒贴壁以及高度过大的问题。所述内筒设置在外筒内且内筒的下端位于外筒的下方,所述旋流器设置在内筒的上端;所述一~四个切向旋流排烟管位于外筒的下方,且一~四个切向旋流排烟管沿切线方向均布设置在内筒的外侧壁上,每个切向旋流排烟管均与外筒和内筒之间的空腔连通,壳体的上端与外筒的内腔连通,壳体的下端与内筒连通,每块旋流板的一侧与中心轴连接,另一侧与壳体的内壁连接。本发明具有结构紧凑、负荷变化适应性强、成本低、便于系统的总体布置和运行维护,脱硫效率提高了10%以上。
The utility model relates to an up straight-down spin dry circulating fluidized bed desulfurization reactor, which relates to a circulating fluidized bed desulfurization reactor. The invention solves the problems of the existing desulfurization reactors, such as low working efficiency, easy particle formation on the wall surface and excessive height. The inner cylinder is arranged in the outer cylinder and the lower end of the inner cylinder is located below the outer cylinder, the swirler is arranged at the upper end of the inner cylinder; the one to four tangential swirl smoke exhaust pipes are located below the outer cylinder, And one to four tangential swirling smoke exhaust pipes are evenly arranged on the outer wall of the inner cylinder along the tangential direction, and each tangential swirling smoke exhaust pipe is connected with the cavity between the outer cylinder and the inner cylinder, and the shell The upper end of the body communicates with the inner cavity of the outer cylinder, the lower end of the shell communicates with the inner cylinder, one side of each swirl plate is connected with the central axis, and the other side is connected with the inner wall of the shell. The invention has the advantages of compact structure, strong adaptability to load changes, low cost, convenient overall layout and operation and maintenance of the system, and the desulfurization efficiency is increased by more than 10%.
Description
技术领域 technical field
本发明涉及烟气净化技术领域,具体涉及一种上直-下旋干式循环流化床脱硫反应器。The invention relates to the technical field of flue gas purification, in particular to an upper straight-down spin dry circulating fluidized bed desulfurization reactor.
背景技术 Background technique
脱硫反应器是脱硫工艺的核心装置,流态化技术已广泛应用于能源、环保及化工等工程领域。循环流化床烟气脱硫反应器以熟石灰等吸收剂为循环物料,在烟气的作用下,循环物料在反应器内流化,烟气中的二氧化硫与循环物料中的吸收剂发生中和反应,达到脱硫的目的。现有的循环流化床脱硫反应器存在的问题如下:一、国内锅炉的运行中,机组负荷变化较大也较为频繁,锅炉的负荷变化使烟气量的变化过大、直接引起塔内流态化湍流流场的不均匀分布,吸收剂物料与气体的接触面积降低且接触时间减少,致使脱硫反应效率低;二、脱硫反应器近壁区烟气流速很低,而且工艺水喷入吸收塔后颗粒湿度急速增大,这些湿度较大的颗粒进入脱硫反应器后极易附着在脱硫反应器的壁面,形成颗粒的贴壁现象;三、目前脱硫反应器的高度过大(一般高度为20~30米),不便于系统的总体布置和运行维护。The desulfurization reactor is the core device of the desulfurization process, and the fluidization technology has been widely used in energy, environmental protection and chemical engineering fields. The circulating fluidized bed flue gas desulfurization reactor uses absorbents such as slaked lime as the circulating material. Under the action of the flue gas, the circulating material is fluidized in the reactor, and the sulfur dioxide in the flue gas and the absorbent in the circulating material undergo a neutralization reaction. , to achieve the purpose of desulfurization. The problems existing in the existing circulating fluidized bed desulfurization reactor are as follows: 1. During the operation of domestic boilers, the load of the unit changes greatly and frequently. The non-uniform distribution of the state turbulent flow field reduces the contact area and contact time between the absorbent material and the gas, resulting in low desulfurization reaction efficiency; The humidity of the particles behind the tower increases rapidly, and these particles with high humidity enter the desulfurization reactor and are easily attached to the wall of the desulfurization reactor, forming a phenomenon of particle sticking to the wall; 3. The height of the current desulfurization reactor is too large (generally the height is 20-30 meters), it is not convenient for the overall layout and operation and maintenance of the system.
发明内容 Contents of the invention
本发明为了解决现有的脱硫反应器工作效率低、壁面易形成颗粒贴壁以及高度过大的问题,进而提供了一种上直-下旋干式循环流化床脱硫反应器。In order to solve the problems of the existing desulfurization reactors, such as low working efficiency, easy particle adhesion on the wall surface and excessive height, the present invention further provides an up-direct-down-spin-dry circulating fluidized bed desulfurization reactor.
本发明的技术方案是:一种上直-下旋干式循环流化床脱硫反应器包括外筒和内筒,所述外筒的上端设有上端盖,所述内筒为圆柱型直筒;所述脱硫反应器还包括旋流器和一~四个切向旋流排烟管,所述旋流器由三~二十块旋流板、中心轴和壳体组成,内筒设置在外筒内且内筒的下端位于外筒的下方,所述旋流器设置在内筒的上端;所述一~四个切向旋流排烟管位于外筒的下方,且一~四个切向旋流排烟管沿切线方向均布设置在内筒的外侧壁上,每个切向旋流排烟管均与外筒和内筒之间的空腔连通,壳体的上端与外筒的内腔连通,壳体的下端与内筒连通,所述三~二十块旋流板和中心轴均位于壳体内,所述三~二十块旋流板均布设置在中心轴的外表面上,每块旋流板的一侧与中心轴连接,另一侧与壳体的内壁连接,所述旋流板与中心轴之间的夹角α为45~60度。The technical solution of the present invention is: an upper straight-down spin dry circulating fluidized bed desulfurization reactor includes an outer cylinder and an inner cylinder, the upper end of the outer cylinder is provided with an upper end cover, and the inner cylinder is a cylindrical straight cylinder; The desulfurization reactor also includes a cyclone and one to four tangential swirl smoke exhaust pipes, the cyclone is composed of three to twenty swirl plates, a central shaft and a shell, and the inner cylinder is arranged on the outer cylinder The lower end of the inner cylinder is located below the outer cylinder, and the cyclone is arranged on the upper end of the inner cylinder; the one to four tangential swirl smoke exhaust pipes are located below the outer cylinder, and the one to four tangential The swirl smoke exhaust pipes are evenly distributed on the outer wall of the inner cylinder along the tangential direction, each tangential swirl smoke exhaust pipe communicates with the cavity between the outer cylinder and the inner cylinder, and the upper end of the shell is connected to the outer wall of the outer cylinder. The inner cavity is connected, the lower end of the shell is connected with the inner cylinder, the three to twenty swirl plates and the central shaft are located in the shell, and the three to twenty swirl plates are evenly arranged on the outer surface of the central shaft Above, one side of each swirl plate is connected to the central axis, and the other side is connected to the inner wall of the housing, and the angle α between the swirl plate and the central axis is 45-60 degrees.
本发明与现有技术相比具有以下有益效果:本发明通过旋流器将反应器分为内筒(一级直流反应器)和外筒(二级旋流反应器),烟气携带的吸收剂(脱硫用固体颗粒)到达旋流器时由于惯性的作用返回到一级直流反应器中,一级直流反应器内颗粒浓度增大,旋流反应器内烟气流通截面积得以增加,增大了气体在脱硫反应器内停留时间,脱硫效率提高10%以上;本发明提高了直流反应器内的烟气流速,结合旋流反应器的旋流,并且旋流板与中心轴之间的夹角的角度可调,对锅炉负荷变化引起的烟气量变化具有很好的适应性;本发明采用上直-下旋相结合的流场,直流反应器内采取较高的流速,旋流反应器内全程采取旋流形式,能够有效的缓解吸收塔近壁区吸收剂贴壁的现象;本发明采用上直-下旋相结合的流场,与现有的单向流场相比,大大降低了反应器的高度(仅为现有反应器的二分之一),便于系统的总体布置和运行维护。Compared with the prior art, the present invention has the following beneficial effects: the present invention divides the reactor into an inner cylinder (one-stage direct flow reactor) and an outer cylinder (two-stage cyclone reactor) through a cyclone, and the absorption When the agent (solid particles for desulfurization) reaches the cyclone, it returns to the first-stage DC reactor due to inertia, and the concentration of particles in the first-stage DC reactor increases, and the flow cross-sectional area of the flue gas in the cyclone reactor increases. The residence time of the gas in the desulfurization reactor is increased, and the desulfurization efficiency is increased by more than 10%. The angle of the included angle is adjustable, and it has good adaptability to the change of flue gas volume caused by the change of boiler load; the present invention adopts a flow field combining up straight and down swirling, and adopts a higher flow rate in the direct current reactor, swirling flow The whole process of the reactor is in the form of swirling flow, which can effectively alleviate the phenomenon of absorbent sticking to the wall near the wall of the absorption tower. The height of the reactor is greatly reduced (only 1/2 of the existing reactor), which is convenient for the overall layout and operation and maintenance of the system.
附图说明 Description of drawings
图1是脱硫反应器主体的整体结构主视图,图2是图1的俯视图,图3是旋流器的主视示意图(旋流板的数量用三块表示),图4是图3的俯视图。Fig. 1 is a front view of the overall structure of the main body of the desulfurization reactor, Fig. 2 is a top view of Fig. 1, Fig. 3 is a schematic front view of a cyclone (the number of swirl plates is represented by three pieces), and Fig. 4 is a top view of Fig. 3 .
具体实施方式 Detailed ways
具体实施方式一:如图1~4所示,本实施方式所述的上直-下旋干式循环流化床脱硫反应器包括外筒1和内筒2,所述外筒1的上端设有上端盖1-1,所述内筒2为圆柱型直筒;所述脱硫反应器还包括旋流器3和一~四个切向旋流排烟管4,所述旋流器3由三~二十块旋流板3-1、中心轴3-2和壳体3-3组成,内筒2设置在外筒1内且内筒2的下端位于外筒1的下方,所述旋流器3设置在内筒2的上端;所述一~四个切向旋流排烟管4位于外筒1的下方,且一~四个切向旋流排烟管4沿切线方向均布设置在内筒2的外侧壁上,每个切向旋流排烟管4均与外筒1和内筒2之间的空腔连通,壳体3-3的上端与外筒1的内腔连通,壳体3-3的下端与内筒2连通,所述三~二十块旋流板3-1和中心轴3-2均位于壳体3-3内,所述三~二十块旋流板3-1均布设置在中心轴3的外表面上,每块旋流板3-1的一侧与中心轴3-2连接,另一侧与壳体3-3的内壁连接,所述旋流板3-1与中心轴3-2之间的夹角α为45~60度。上直是指烟气在内筒2(一级直流反应器)内由下向上直流经过内筒2,固称为“上直”,下旋是指烟气通过旋流反应器3后由上向下旋流经过外筒(二级旋流反应器)内,固称为“下旋”。Specific embodiment 1: As shown in Figures 1 to 4, the upper straight-down spin dry circulating fluidized bed desulfurization reactor described in this embodiment includes an
具体实施方式二:如图3和图4所示,本实施方式所述旋流板3-1的数量为四~十八个。如此设置,可以改变进入二级旋流反应器的烟气流量和流速。其它组成及连接关系与具体实施方式一相同。Embodiment 2: As shown in FIG. 3 and FIG. 4 , the number of swirl plates 3 - 1 in this embodiment ranges from four to eighteen. With such setting, the flue gas flow rate and flow rate entering the secondary cyclone reactor can be changed. Other components and connections are the same as those in the first embodiment.
具体实施方式三:如图3和图4所示,本实施方式所述旋流板3-1的数量为六~十六个。如此设置,可以改变进入二级旋流反应器的烟气流量和流速。其它组成及连接关系与具体实施方式一相同。Embodiment 3: As shown in Fig. 3 and Fig. 4, the number of swirl plates 3-1 in this embodiment is six to sixteen. With such setting, the flue gas flow rate and flow rate entering the secondary cyclone reactor can be changed. Other components and connections are the same as those in the first embodiment.
具体实施方式四:如图3和图4所示,本实施方式所述旋流板3-1的数量为八~十四个。如此设置,可以改变进入二级旋流反应器的烟气流量和流速。其它组成及连接关系与具体实施方式一相同。Embodiment 4: As shown in FIG. 3 and FIG. 4 , the number of swirl plates 3 - 1 in this embodiment is eight to fourteen. With such setting, the flue gas flow rate and flow rate entering the secondary cyclone reactor can be changed. Other components and connections are the same as those in the first embodiment.
具体实施方式五:如图3和图4所示,本实施方式所述旋流板3-1的数量为十~十二个。如此设置,可以改变进入二级旋流反应器的烟气流量和流速。其它组成及连接关系与具体实施方式一相同。Embodiment 5: As shown in FIG. 3 and FIG. 4 , the number of swirl plates 3 - 1 in this embodiment is ten to twelve. With such setting, the flue gas flow rate and flow rate entering the secondary cyclone reactor can be changed. Other components and connections are the same as those in the first embodiment.
具体实施方式六:如图1所示,本实施方式所述脱硫反应器还包括工艺水雾化器6,所述工艺水雾化器6设置在上端盖1-1的上方且与外筒1相连通。如此设置,可以对进入二级旋流反应器的烟气进行增湿,提高反应器的脱硫效率。其它组成及连接关系与具体实施方式一、二、三、四或五相同。Specific embodiment six: As shown in Figure 1, the desulfurization reactor described in this embodiment also includes a process water atomizer 6, and the process water atomizer 6 is arranged above the upper end cover 1-1 and connected to the
具体实施方式七:如图1所示,本实施方式所述脱硫反应器还包括吸收剂调节器7,所述吸收剂调节器7设置在上端盖1-1的上方且与外筒1相连通。如此设置,用以补充流化床脱硫系统所需消石灰吸收剂,保证送入二级反应器的吸收剂均匀。其它组成及连接关系与具体实施方式六相同。Embodiment 7: As shown in Figure 1, the desulfurization reactor in this embodiment also includes an absorbent regulator 7, which is arranged above the upper end cover 1-1 and communicates with the
工作原理:working principle:
内筒2与干式循环流化床脱硫工艺的烟气流化布风装置相连接,由燃烧设备送来的烟气经工艺水增湿后携带吸收剂(脱硫用固体颗粒)进入内筒2(一级直流反应器)内,吸收剂和雾化工艺水在烟气的带动下自下而上湍流运动,并形成气、液、固三相间强烈的热量和质量交换;吸收剂形成悬浮流化状态,气固两相间滑移速度较大,吸收剂在气流中上升、回窜以及在壁面附近的下降回流,使床内混合、湍流十分强烈,传热传质速率快。当烟气上升到旋流器3时,烟气携带的部分吸收剂由于惯性的作用返回到一级直流反应器中,提高反应器中颗粒浓度,形成密相湍流区,床内强烈的湍流效应和较高的循环倍率加强了固体颗粒间的碰撞以及固体颗粒与烟气的接触,一级反应器中的脱硫效率提高。The
烟气流出内筒2(一级直流反应器)后,在旋流器3的作用下,以旋流的方式进入外筒1(二级旋流反应器)内,环绕一级反应器外壁旋转自上而下流动。在外筒1(二级旋流反应器)中形成稀相反应区,利用吸收剂调节器7补充消石灰颗粒(粒度不大于200目),提高烟气流经旋流器3后缺失的吸收剂浓度,同时外筒1(二级旋流反应器)内的旋流状态提高了反应器内的湍流强度,然后根据机组负荷的变化,调整旋流板3-1的角度,也就相当于调整了外筒1(二级旋流反应器)内烟气旋流的角度;对于流量较大的烟气,增加漩流板3-1的角度,可增加反应器内的烟气旋流角度,延长流通截面积、提高烟气的停留时间,强化外筒1(二级旋流反应器)内的脱硫效率。After the flue gas flows out of the inner cylinder 2 (first-stage direct current reactor), under the action of the cyclone 3, it enters the outer cylinder 1 (secondary cyclone reactor) in a swirling manner, and rotates around the outer wall of the first-stage reactor Flow from top to bottom. A dilute-phase reaction zone is formed in the outer cylinder 1 (secondary cyclone reactor), and the absorbent regulator 7 is used to supplement slaked lime particles (particle size not greater than 200 mesh) to increase the concentration of absorbent lost after the flue gas flows through the cyclone 3 , at the same time, the swirl flow state in the outer cylinder 1 (secondary swirl flow reactor) increases the turbulent flow intensity in the reactor, and then adjusts the angle of the swirl flow plate 3-1 according to the change of unit load, which is equivalent to adjusting the The angle of the flue gas swirl in the outer cylinder 1 (secondary swirl reactor); for the flue gas with a large flow rate, increasing the angle of the swirl plate 3-1 can increase the swirl angle of the flue gas in the reactor and extend the The flow cross-sectional area is increased, the residence time of flue gas is increased, and the desulfurization efficiency in the outer cylinder 1 (secondary cyclone reactor) is enhanced.
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CN102614768A (en) * | 2012-01-19 | 2012-08-01 | 新乡市亚洲金属循环利用有限公司 | Desulfurization reactor device |
CN106733243A (en) * | 2017-01-23 | 2017-05-31 | 重庆科技学院 | Down-hole oil production multi-chamber spiral-flow type crude separation device |
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CN101099920A (en) * | 2006-07-06 | 2008-01-09 | 王国华 | Integration dust-removing and desulfurizing device |
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CN102614768A (en) * | 2012-01-19 | 2012-08-01 | 新乡市亚洲金属循环利用有限公司 | Desulfurization reactor device |
CN102614768B (en) * | 2012-01-19 | 2014-02-26 | 新乡市亚洲金属循环利用有限公司 | Desulfurization reactor device |
CN106733243A (en) * | 2017-01-23 | 2017-05-31 | 重庆科技学院 | Down-hole oil production multi-chamber spiral-flow type crude separation device |
CN106733243B (en) * | 2017-01-23 | 2023-02-24 | 重庆科技学院 | Multi-chamber Cyclone Rough Separation Device for Downhole Oil Production |
CN111389216A (en) * | 2020-05-11 | 2020-07-10 | 中煤科工清洁能源股份有限公司 | Dry flue gas desulfurization device |
CN114832594A (en) * | 2021-02-01 | 2022-08-02 | 中国石油化工股份有限公司 | Efficient treatment device and treatment method for hydrogen sulfide tail gas |
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